Abstract: An SOFC unit cell 100 includes a fuel-side electrode 110, an electrolyte 120 stacked on the fuel-side electrode 110, and an oxygen-side electrode 130 stacked on the electrolyte 120. The fuel-side electrode 110 is formed of NiO and/or Ni and YSZ. The amount by volume of Ni and/or NiO is 35 to 55 vol. %, as reduced to Ni, on the basis of the entirety of the fuel-side electrode, and the amount by volume of YSZ is 45 to 65 vol. % on the basis of the entirety of the fuel-side electrode. The ratio of the mean particle size of YSZ (R2) to the mean particle size of Ni and/or NiO (R1); i.e., R2/R1, is 0.5 or more. Reduction treatment of the fuel-side electrode 110 after firing is carried out by supplying a reducing gas containing a reducing agent (hydrogen) in an amount of 4 to 100 vol. % at a high temperature of 800° C.

Abstract: Provided is a connected body connecting electrically between power generation parts of SOFCs, which has high connection strength and high reliability of electric connection. Adjacent two segmented-in-series type SOFCs (100), (100) are connected to each other with a metallic connecting member (300). A “left side end portion of the connecting member (300)” and an “interconnector (30) electrically connected to an air electrode (60) provided on the SOFC (100) on the left side” are electrically connected to each other with a connecting material (80), and a “right side end portion of the connecting member (300)” and the “interconnector (30) electrically connected to a fuel electrode (20) provided on the SOFC (100) on the right side” are electrically connected to each other with the connecting material (80). Both of the interconnectors (30), (30) to be respectively connected to both ends of the metallic connecting member (300) with the connecting material (80) are formed of dense conductive materials.

Abstract: A solid oxide fuel cell having a fuel electrode, a solid electrolyte film, an air electrode, and a conductive current-collecting mesh bonded to an upper surface, opposite to a lower bonding surface with the solid electrolyte film, of the air electrode. Plural bonding portions that are bonded to the current-collecting mesh and plural non-bonding portions that are not bonded to the current-collecting mesh are present on the upper surface of the air electrode. In the air electrode, regions having a porosity smaller than a porosity of the other region are respectively formed on the position in the middle of the thickness of the air electrode from each bonding portion. The average of the porosity of the dense portion is 20% or more and less than 35%, while the average of the porosity of the porous portion is 35% or more and less than 55%.

Abstract: Provided is an SOFC, including a fuel electrode (20), a thin-plate-like interconnector (30) provided on the fuel electrode and formed of a conductive ceramics material, and a conductive film (70) formed on a surface of the interconnector (30) opposite to the fuel electrode (20). The conductive film (70) is formed of an N-type semiconductor (e.g., LaNiO3). The N-type semiconductor generally has the property of exhibiting a smaller conductivity (a current hardly flows) at higher temperature. Therefore, a portion with a higher current density (thus, a portion with higher temperature) in the conductive film (70) in the vicinity of the interconnector (30) has a smaller conductivity (a current hardly flows). By virtue of this action, even though a “fluctuation in current density of a current flowing through the interconnector (30) and an area in the vicinity thereof” occurs for some reasons, the fluctuation can be suppressed.

Abstract: A solid oxide fuel cell is provided that includes an anode current collecting layer, a cathode, an electrolyte layer, and an anode active layer. The anode current collecting layer contains Ni or NiO, and an oxide represented by a general formula AEZrO3 where AE is one or a combination of two or more selected from the group consisting of Ca, Sr, Mg, and Ba. The electrolyte layer is disposed between the anode current collecting layer and the cathode. The anode active layer is disposed between the electrolyte layer and the anode current collecting layer.

Abstract: A solid oxide fuel cell includes two or more power generating elements each having a cathode, an anode, and an electrolyte layer placed between the cathode and the anode; an interconnector electrically connecting the power generating elements and containing a chromite-based material; and a sealing portion provided between the electrolyte layer and the interconnector and not containing either Ni or ZrO2.

Abstract: On each of upper and lower surfaces of a flat-plate-like support substrate having a longitudinal direction and having fuel gas flow channels formed therein, a plurality of power-generating elements A connected electrically in series are disposed at predetermined intervals along the longitudinal direction. On each of the upper and lower surfaces of the support substrate, a plurality of recesses are formed at predetermined intervals along the longitudinal direction. Each of the recesses is a rectangular-parallelepiped-like depression defined by four side walls arranged in a circumferentially closed manner and a bottom wall. That is, in the support substrate, frames are formed to surround the respective recesses. Fuel electrodes of the power-generating elements A are embedded in the respective recesses, and inter connectors are embedded in respective recesses formed on the outer surfaces of the fuel electrodes.

Abstract: A second mold is placed on a planar surface of a first mold to form a first mold cavity, which is filled with a first material slurry containing a first material powder and the molded slurry is caused to set, thereby forming a first molded part on the planar surface of the first mold. A third mold is placed on the planar surface of the first mold from which the second mold is removed and on which the first molded part is formed, thereby forming a second mold cavity. The second mold cavity is filled with a second material slurry which contains a second material powder different from the first material powder so as to mold the slurry in contact with the first molded part. The molded slurry is caused to set, thereby forming a second molded part on the planar surface of the first mold.

Abstract: On each of upper and lower surfaces of a flat-plate-like support substrate having a longitudinal direction and having fuel gas flow channels formed therein, a plurality of power-generating elements A connected electrically in series are disposed at predetermined intervals along the longitudinal direction. On each of the upper and lower surfaces of the support substrate, a plurality of recesses are formed at predetermined intervals along the longitudinal direction. Each of the recesses is a rectangular-parallelepiped-like depression defined by four side walls arranged in a circumferentially closed manner and a bottom wall. That is, in the support substrate, frames are formed to surround the respective recesses. Fuel electrodes of the power-generating elements A are embedded in the respective recesses.

Abstract: The electrode material contains a complex oxide and at least one of ZrO2 and a compound comprising ZrO2. The complex oxide has a perovskite structure represented by a general formula ABO3. ZrO2 is contained in an amount of 0.3'10?2 wt % to 1 wt % relative to the entire electrode material.

Abstract: The electrode material contains a complex oxide having a perovskite structure represented by a general formula ABO3. Each A-site element having a standard deviation of an atomic concentration of 10.3 or less. The atomic concentration is measured by energy dispersive X-ray spectroscopy at ten spots within one field of view.

Abstract: A fuel cell is provided that includes an anode, a cathode, a solid electrolyte layer, a barrier layer, and an intermediate layer. The solid electrolyte layer includes zirconium and is provided between the anode and the cathode. The barrier layer includes cerium and is provided between the solid electrolyte layer and the cathode. The intermediate layer includes zirconium and cerium, and has a first surface facing the solid electrolyte layer, a second surface facing the barrier layer, and pores. The pore ratio of the intermediate layer is higher than the pore ratio of the barrier layer.

Abstract: A fuel cell is provided that includes an anode, a cathode, a solid electrolyte layer, a barrier layer, and an buffer layer. The solid electrolyte layer includes zirconium and is provided between the anode and the cathode. The barrier layer includes cerium and is provided between the solid electrolyte layer and the cathode. The barrier layer has pores. The buffer layer includes zirconium and cerium and is provided between the barrier layer and the solid electrolyte layer. The barrier layer has a first barrier layer provided near to the buffer layer with a first pore ratio and a second barrier layer provided between the first barrier layer and the cathode with a second pore ratio. The first pore ratio of the first barrier layer is larger than the second pore ratio of the second barrier layer.

Abstract: A stack structure includes plate-like electrochemical cells of ceramic, each having a pair of main surfaces and a side surface, and plate-like retainer pieces. The cell includes a first electrode in contact with first gas, a solid electrolyte, and a second electrode in contact with second gas. The first electrode has a gas flow channel formed therein and adapted to allow flow of the first gas. The cell has gas inflow and outflow ports. The retainer piece includes a body portion having a through-hole formed therein, and a pair of protrusions protruding from the body portion. The retainer piece has a communication hole formed therein and adapted to establish communication between the through-hole and a space formed between the protrusions. The cell is held by the paired protrusions, thereby establishing communication between the gas inflow or outflow port of the cell and the communication hole of the retainer piece.

Abstract: Striped sheets each having a structure in which two types of first layers and second layers are stacked in the X direction are prepared. More specifically, first raw material sheets having the same composition as the first layers and second raw material sheets having the same composition as the second layers are regularly alternately stacked in the X direction to prepare a uniaxial stack. The uniaxial stack is then cut along the X direction to prepare the striped sheets. A large number of striped sheets and a large number of homogeneous sheets are then collected to form a sheet group. The striped sheets and the homogeneous sheets are alternately stacked in the Y direction different from the X direction to prepare a biaxial stack having two stacking axes in the X direction and the Y direction. The biaxial stack is fired to produce a ceramic structure.

Abstract: A compact of a support-member divided-member, which has a shape formed by dividing a support member into two in the thickness direction so as to divide the fuel channel into two in the thickness direction, is manufactured by a gel cast method in which slurry is filled in a molding die. A compact of a fuel-side electrode and a compact of an electrolyte are successively stacked on the upper surface of the compact of the support-member divided-member, whereby a compact of a cell divided member is obtained. The two compacts of the cell divided member are bonded and sintered, whereby an SOFC cell (sintered body) in which an oxygen-side electrode is not formed is formed. A compact of the oxygen-side electrode is formed respectively on the upper and lower surfaces of the sintered body, and then, the compact of the oxygen-side electrode is sintered, whereby the SOFC cell is completed.

Abstract: A fuel cell has a stack structure in which fired sheet bodies (laminates each including a fuel electrode layer, a solid electrolyte layer, and an air electrode layer) and support members for supporting the sheet bodies are stacked in alternating layers. Each of the sheet bodies is warped downward (toward an air-electrode-layer side). Because of a magnitude relationship of thermal expansion coefficient among the layers in the sheet body and that between the support member and the sheet body, a warp height gradually lessens in the course of temperature rise at start-up. However, even when a working temperature (800° C. or the like) is reached, the sheet bodies are still warped downward. By virtue of presence of the warp, the sheet bodies become unlikely to be deformed at the working temperature.

Abstract: Powders of respective metal elements (Mn, Co) constituting a transition metal oxide (MnCo2O4) having a spinel type crystal structure are used as a starting material. A paste containing the mixture of the powders is interposed between an air electrode and an interconnector, and with this state, a sintering is performed, whereby a bonding agent (sintered body) is formed to obtain the bonding member according to the present invention. In the bonding member, a chromia layer including Cr2O3, a first layer including elements of Mn, Co, Fe, Cr, and O, and a second layer including elements of Mn, Co, Fe, and O are provided in this order from the side close to the interconnector at the bonding portion between the bonding agent and the interconnector. The bonding member has sufficiently great bonding strength between the interconnector and the bonding agent.

Abstract: Powders of respective metal elements (Mn, Co) constituting a transition metal oxide (MnCo2O4) having a spinel type crystal structure are used as a starting material of the coating film. A film of a paste containing the mixture of the powders is formed on the surface of the interconnector, and with this state, the paste is sintered to form the coating film. In the coating body, a chromia layer including Cr2O3, a first layer including elements of Mn, Co, Fe, Cr, and O, and a second layer including elements of Mn, Co, Fe, and O are provided in this order from the side close to the interconnector at the boundary between the coating film and the interconnector. With this structure, the coating film is difficult to be peeled even if the coating body is placed in a severe temperature change.

Abstract: A thin plate member is a thin plate member that is formed by sintering, contains a ceramic layer, and comprises a thin part having two or more types of layers laminated, each of which is made of a material having a different thermal expansion coefficient, and a thick part that is made by laminating plural layers including at least all of the layers constituting the thin part, and has a thickness greater than the thickness of the thin part. The thin part has a shape warping in the direction perpendicular to the plane of the thin plate member. By virtue of this configuration, the internal electrical resistance of the thin part can be reduced. Further, the thin plate member can be provided that is difficult to be deformed with respect to the internal stress caused by the difference in thermal expansion coefficient between layers.