Abstract: The disclosure is directed to an apparatus comprising feedback-assisted control of the heating process in rapid discharge heating and forming of metallic glass articles.

Abstract: The present disclosure provides specified ranges in the Fe—Mo—Ni—Cr—P—C—B alloys such that the alloys are capable of forming bulk glasses having unexpectedly high glass-forming ability. The critical rod diameter of the disclosed alloys is at least 10 mm.

Abstract: Ni-based Cr- and P-bearing alloys that can from centimeter-thick amorphous articles are provided. Within the family of alloys, millimeter-thick bulk-glassy articles can undergo macroscopic plastic bending under load without fracturing catastrophically.

Abstract: Ni—Co—Cr—Ta—P—B alloys and metallic glasses with controlled ranges are provided. The alloys demonstrate a combination of good glass forming ability, high toughness, and high stability of the supercooled liquid. The disclosed alloys are capable of forming metallic glass rods of diameters at least 3 mm and up to about 8 mm or greater. Certain alloys with good glass forming ability also have high notch toughness approaching 100 MPa m1/2, and stability of the supercooled liquid approaching 60° C.

Abstract: Surface treatment methods for Ni-based metallic glasses are provided that promote passivation and decrease the amount of Ni released when the Ni-based metallic glass is exposed to a saline containing environment.

Abstract: The disclosure is directed to methods of forming metallic glass multilayers by depositing a liquid layer of a metallic glass forming alloy over a metallic glass layer, and to multilayered metallic glass articles produced using such methods.

Abstract: A bulk-glass forming Ni—Cr—Nb—P—B alloy is provided. The alloy includes Ni(100?a?b?c?d)CraTabPcBd, where the atomic percent a is between 3 and 11, the atomic percent b is between 1.75 and 4, the atomic percent c is between 14 and 17.5, and the atomic percent d is between 2.5 and 5. The alloy is capable of forming a metallic glass having a lateral dimension of at least 3 mm.

Abstract: Ni—Fe—Si—B and Ni—Fe—Si—B—P metallic glass forming alloys and metallic glasses are provided. Metallic glass rods with diameters of at least one, up to three millimeters, or more can be formed from the disclosed alloys. The disclosed metallic glasses demonstrate high yield strength combined with high corrosion resistance, while for a relatively high Fe contents the metallic glasses are ferromagnetic.

Abstract: Methods and apparatus for forming high aspect ratio metallic glass objects, including metallic glass sheets and tubes, by a melt deposition process are provided. In some methods and apparatus a molten alloy is deposited inside a channel formed by two substrates moving relative to each other, and shaped and quenched by conduction to the substrates in a manner that enables the molten alloy to vitrify without undergoing substantial shear flow.

Abstract: The disclosure provides Pt—P metallic glass-forming alloys and metallic glasses comprising at least two of Ni, Pd, Ag, and Au and optionally Si as well as potentially other elements, where the weight fraction of Pt is between 74 and 91 percent, and where the at least two of Ni, Pd, Ag, and Au contribute to increase the critical rod diameter of the alloy in relation to a Pt—P alloy free of Ni, Pd, Ag, and Au or a Pt—P alloy comprising only one of these elements. In embodiments where the PT850 hallmark is satisfied, alloys according to the disclosure are capable of forming metallic glass rods with diameters in excess of 3 mm, and in some embodiments 30 mm or larger.

Abstract: An apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via any number of techniques including, for example, injection molding, dynamic forging, stamp forging, and blow molding in a time frame of Less than 1 second.

Abstract: An apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via any number of techniques including, for example, injection molding, dynamic forging, stamp forging, sheet forming, and blow molding in a time frame of less than 1 second.

Abstract: An automated rapid capacitive discharge apparatus is provided for sequentially or simultaneously rapidly heating and shaping a plurality of metallic glass feedstock samples. The apparatus includes a sample feeder defining a body for holding a plurality of samples and being capable of sequentially positioning at least one feedstock sample into a discharge position within the processing compartment. In the processing compartment the sample is heated by a discharge of a quantum of electrical energy supplied via electrodes, then shaped into a desired shape by means of a shaping tool, and subsequently moved out of the discharge position as a second feedstock moves into a discharge position.

Abstract: An alloy comprising Fe, Ni, P, B and Ge is disclosed, having a composition according to the formula [Fe1-yNiy](100-a-b-c)PaBbGec, where a, b, c subscripts denote atomic percent; y subscript denotes atomic fraction, a is between 9 and 12, b is between 5.5 and 7.5, c is between 2 and 6, and y is between 0.45 and 0.55. Metallic glass rods with diameter of at least 1 mm can be formed from the alloy by rapid quenching from the molten state.

Abstract: A family of iron-based, phosphor-containing bulk metallic glasses having excellent processibility and toughness, methods for forming such alloys, and processes for manufacturing articles therefrom are provided. The inventive iron-based alloy is based on the observation that by very tightly controlling the composition of the metalloid moiety of the Fe-based, P-containing bulk metallic glass alloys it is possible to obtain highly processable alloys with surprisingly low shear modulus and high toughness.

Abstract: Ferromagnetic cores made from amorphous glasses and methods of forming ferromagnetic cores from metallic glasses are provided. The method forms a magnetic core from a section of a series of concentrically nested ferromagnetic tubes formed of an amorphous metallic material having a Curie-point temperature above room temperature and demonstrating soft ferromagnetic properties, thereby simplifying the manufacturing process and improving the electrical and mechanical performance of the core itself.

Abstract: An apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via any number of techniques including, for example, injection molding, dynamic forging, stamp forging, and blow molding in a time frame of less than 1 second.

Abstract: Ni—Co—Cr—Ta—P—B alloys and metallic glasses with controlled ranges are provided. The alloys demonstrate a combination of good glass forming ability, high toughness, and high stability of the supercooled liquid. The disclosed alloys are capable of forming metallic glass rods of diameters at least 3 mm and up to about 8 mm or greater. Certain alloys with good glass forming ability also have high notch toughness approaching 100 MPa m1/2, and stability of the supercooled liquid approaching 60° C.

Abstract: An apparatus and method of uniformly heating, softening, and thermoplastically forming magnetic metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via any number of techniques including, for example, injection molding, dynamic forging, stamp forging, sheet forming, and blow molding in a time frame of less than 1 second.

Abstract: Ni-based Cr- and P-bearing alloys that can from centimeter-thick amorphous articles are provided. Within the family of alloys, millimeter-thick bulk-glassy articles can undergo macroscopic plastic bending under load without fracturing catastrophically.