Abstract: An electrically responsive ink composition comprising at least one electrically responsive optical-state change material, at least one electrolyte material, at least one solvent, and at least one binder material, wherein the ink composition has a viscosity between about 0.1 centipoise and about 10,000 centipoise, and a maximum optical absorbance in a range from about 200 nanometers to about 800 nanometers; and wherein the ink composition is capable of transforming from a first optical state to a second optical state upon exposure to an electrical stimulus. The electrically responsive ink composition may be used to deposit an electrically responsive coating composition, which may be used as part of an anti-theft system for optical articles. Articles comprising electrically responsive coating compositions are also disclosed, as are methods for activation.

Abstract: A separation matrix comprises a porous surface layer; and a bulk porous support, wherein both the porous surface layer and the bulk porous support comprising a block copolymer. The block copolymer comprises A-B or A-B-A repeating units, wherein A and B at each occurrence are two different blocks of oligomer, or polymer. A structural unit of block A is derived from one or more atom transfer radical polymerization (ATRP)-active monomer or oligomer and a structural unit of block B is derived from a thermoplastic ATRP-active macro initiator. A poly dispersity index of the block copolymer is at least about 2.

Abstract: A thermally responsive ink composition consisting of at least one halochromic optical-state change material, at least one base, at least one solvent, and at least one binder material. The pH of the ink composition is such that the halochromic optical-state change material remains in its basic state until it is acted upon by a thermal stimulus. The ink composition is capable of transforming from a first optical state to a second optical state upon a change in pH caused by exposure to a thermal stimulus. A thermally responsive ink composition consisting of at least one quaternary onium salt of an halochromic optical-state change material, at least one solvent, and at least one binder material is also disclosed. Coating compositions prepared using these ink compositions and optical articles comprising these coating compositions are also disclosed.

Abstract: An optical data storage medium is provided. The optical data storage medium includes a polymer matrix; a reactant capable of undergoing a change upon triplet excitation, thereby causing a refractive index change; and a non-linear sensitizer capable of absorbing actinic radiation to cause upper triplet energy transfer to said reactant. The refractive index change capacity of the medium is at least about 0.1. The reactant comprises polyvinyl chlorocinnamate, polyvinyl methoxycinnamate, or a combination thereof.

Abstract: An optical article is provided. The optical article includes a first layer. The first layer includes an active holographic layer configured to store holographic data. The first layer has a first surface and a second surface. A second layer includes a low birefringence material. The second layer also has a first surface and a second surface. Guide grooves are present in any one of the first layer or the second layer. In certain embodiments, the article may further include a reflective layer, an anti-reflective layer, a barrier layer, and a combination thereof.

Abstract: An optical data storage article is configured to transform from a pre-activated state of functionality to an activated state of functionality. The optical data storage article includes a physical surface modification configured to alter an optical integrity of the optical data storage article upon interaction with an external stimulus.

Abstract: A thermally responsive ink composition consisting of at least one halochromic optical-state change material, at least one base, at least one solvent, and at least one binder material. The pH of the ink composition is such that the halochromic optical-state change material remains in its basic state until it is acted upon by a thermal stimulus. The ink composition is capable of transforming from a first optical state to a second optical state upon a change in pH caused by exposure to a thermal stimulus. A thermally responsive ink composition consisting of at least one quaternary onium salt of an halochromic optical-state change material, at least one solvent, and at least one binder material is also disclosed. Coating compositions prepared using these ink compositions and optical articles comprising these coating compositions are also disclosed.

Abstract: An optical article comprising at least one data side and configured for transformation from a pre-activated state of functionality to an activated state of functionality is provided. The optical article includes an optical data layer for storing data. Furthermore, the optical article includes an electrically responsive layer having a first surface and a second surface, wherein the electrically responsive layer is characterized by an optical absorbance in the range of about 200 nm to about 800 nm. The electrically responsive layer being configured to transform from a first optical state to a second optical state upon exposure to an external stimulus, and being capable of irreversibly transforming the optical article from the pre-activated state of functionality to the activated state of functionality. The electrically responsive layer includes a binder polymeric material, an electrically responsive material, and an electrolyte.

Abstract: An activation system for optical media in one embodiment includes a tag having at least one pair of conductors with at least one heating element coupled to the conductors. The heating element is oriented proximate one or more activation regions on the optical media, and wherein the heating element activates the optical media. The tag in one embodiment is an elongate flexible tag material with a number of conductors that couple on one end to heating elements wherein the heating elements are disposed within a media case such that they are proximate activation regions on a media article.

Abstract: An optical article comprising a plurality of optically detectable marks disposed on a surface of the optical article; a removable electrical device disposed on the surface of the optical article; wherein the electrical device is operatively coupled to the optical article; and wherein the electrical device is configured to interact with an activation signal when brought in direct contact with a communication device that applies the activation signal to the electrical device. A removable electrical device is also provided. A system and a method for activation are also provided.

Abstract: An equipment comprising a receptacle for receiving an optical article; a first set of electrical connectors configured to be in direct contact with a second set of electrical connectors disposed on the optical article, when the optical article is received by the receptacle; an activation device operably coupled with the first set of electrical connectors; wherein the activation device is configured to generate an activation signal which is transmitted to the second set of electrical connectors by the first set of electrical connectors, wherein an electrical device is configured to provide a power component to the optical article via the first set of electrical connectors and the second set of electrical connectors which are in direct contact. A system comprising the equipment is also provided. Also provided is a checkout device.

Abstract: An optical article comprising a first file encoded on the optical article comprising data structure information; a second file encoded on the optical article comprising a backup of the first file; wherein at least one of the first file or the second file must be fully readable for the player to read the data on the optical article; and a mark disposed on at least a portion of the optical article where the first file is encoded and at least a portion of the optical article where the second file is encoded; wherein the mark comprises an optical state change material; wherein the optical state change material undergoes a change in its optical state when exposed to an activation signal selected from one or more of a laser, thermal energy, infrared rays, X-rays, gamma rays, microwaves, visible light, ultraviolet light, ultrasound waves, radio frequency waves, electrical energy, chemical energy, magnetic energy, and mechanical energy; wherein the optical article is transformed from a pre-activated state to an activ

Abstract: An optical article comprising a mark disposed on the optical article; wherein the mark comprises an optical state change material; wherein the optical state change material undergoes a change in its optical state when exposed to an activation signal selected from one or more of a laser, thermal energy, infrared rays, X-rays, gamma rays, microwaves, visible light, ultraviolet light, ultrasound waves, radio frequency waves, electrical energy, chemical energy, magnetic energy, and mechanical energy; wherein the optical article is transformed from a pre-activated state to an activated state when an authorized activation method is used; and wherein the optical article is transformed from a pre-activated state to an incorrectly activated state when an unauthorized activation method is used. A method and a system for changing the functionality of the optical article are also provided.

Abstract: An optical article comprising a primary mark disposed on the optical article and a secondary mark disposed on the optical article in close proximity to the primary mark. The primary mark comprises a first optical-state change material and the secondary mark comprises a second optical-state change material. The optical article is transformed from a pre-activated state to an activated state when a localized authorized activation method is used that selectively activates the primary mark. The optical article is transformed from a pre-activated state to an deactivated state when a non-localized unauthorized activation method is used that activates the secondary mark along with the primary mark resulting in the second optical-state change material undergoing a reverse color change when compared to the first optical-state change material. An optical article with a single mark including multiple color change optical-state change material is also disclosed.

Abstract: A thermochromic ink composition comprises at least one thermochromic optical-state change material, at least one thermally responsive pH modifier, at least one solvent, and at least one binder material, wherein the thermochromic ink composition has a viscosity between about 0.1 centipoise (cPs) and about 10,000 cps, and a maximum optical absorbance in a range from about 200 nm (nanometers) to about 800 nm, and wherein the thermochromic ink composition is capable of transforming from a first optical state to a second optical state upon exposure to a thermal stimulus. The thermochromic ink composition may be used to deposit a thermochromic coating composition which may be used as part of an anti-theft system for optical articles. Methods for thermal activation of the compositions are also provided.