Patents by Inventor Naoto Kijima

Naoto Kijima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8828272
    Abstract: A phosphor includes a crystal phase of a formula (Ln,Ca,Ce)3+?Si6N11. In this formula, ? is from ?0.1 to 1.5, inclusive. When an object color of the phosphor is expressed by the L*a*b* color system, the value of (a*2+b*2)1/2 satisfies 71?(a*2+b*2)1/2. Also in the formula, Ln is La, Gd, Lu, Y, Sc, or any combination of these. When the phosphor is excited with light having a wavelength of 455 nm, it emits a color wherein x is from 0.400 to 0.570 inclusive, and y is from 0.420 to 0.590, inclusive, as expressed in the CIE standard coordinate system.
    Type: Grant
    Filed: October 18, 2013
    Date of Patent: September 9, 2014
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Takatoshi Seto, Naoto Kijima, Keiichi Seki, Ryuji Adachi, Hiroyasu Yamada, Tatsuya Inoue
  • Patent number: 8801970
    Abstract: A nitride phosphor contains europium as an activating element and strontium, or strontium and calcium, as divalent metal elements. The phosphor further includes aluminum and silicon. Of the europium in the phosphor, at least 85% is in the form of Eu2+. The phosphor has a peak emission wavelength of from 590 nm to 650 nm. A phosphorescent body that includes the phosphor can be suitable for converting a wavelength of at least a portion of light emitted from an excitation light source in a light-emitting device.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: August 12, 2014
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hiromu Watanabe, Masumi Itou, Keiichi Seki, Hiroshi Wada, Motoyuki Shigeiwa, Kaoru Terada, Naoto Kijima
  • Patent number: 8710741
    Abstract: An illuminating device comprises one or more luminescent devices (1). The luminescent device comprises a semiconductor light emitting element (10) emitting a excitation light having an peak within a wavelength range from 350 nm to 430 nm, and a luminescent part (20) comprising a sealing member (22) and a phosphor (21) absorbing the light from the semiconductor light emitting element (10) and emitting a light with different emission spectrum. For the luminescent device (1), an excitation light contribution degree ?E, an index quantitatively representing what extent of a visible component of the excitation light is involved in color mixing of a combined light of the luminescent device (1), is 0.005 or less, and a mean color rendering index Ra is 70 or more.
    Type: Grant
    Filed: July 5, 2012
    Date of Patent: April 29, 2014
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Akeo Kasakura, Kazuhiko Kagawa, Naoto Kijima
  • Patent number: 8703019
    Abstract: A phosphor which emits light having high brightness, serves as an excellent orange or red phosphor whose light brightness is less decreased when exposed to an excitation source contains a crystal phase having the chemical composition expressed by the general formula [1]: (1?a?b)(Ln?pMII?1?pMIII?MIV?N3).a(MIV?(3n+2)/4NnO).b(AMIV?2N3)??[1] wherein Ln? represents a metal element selected from the group consisting of lanthanoids, Mn, and Ti; MnII? represents a divalent metal element except the Ln? element; MIII? represents a trivalent metal element; MIV? represents a tetravalent metal element; A represents a metal element selected from the group consisting of Li, Na, and K; 0<p?0.2; 0?a, 0?b, a+b>0, 0?n, and 0.002?(3n+2)a/4?0.9.
    Type: Grant
    Filed: May 22, 2012
    Date of Patent: April 22, 2014
    Assignees: Mitsubishi Chemical Corporation, Independent Administrative Institution National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takatoshi Seto, Naoto Kijima
  • Publication number: 20140042898
    Abstract: To provide a yellow to orange phosphor which has high luminance and excellent temperature characteristics and which also has high luminance when mixed with a phosphor of a different color. A phosphor containing a crystal phase represented by the following formula [I], wherein when its object color is expressed by the L*a*b* color system, the values of a*, b* and (a*2+b*2)1/2 satisfy ?20?a*??2, 71?b* and 71?(a*2+b*2)1/2, respectively: R3?x?y?z+w2MzA1.
    Type: Application
    Filed: October 18, 2013
    Publication date: February 13, 2014
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Takatoshi Seto, Naoto Kijima, Keiichi Seki, Ryuji Adachi, Hiroyasu Yamada, Tatsuya Inoue
  • Patent number: 8636920
    Abstract: A method for industrially producing a phosphor with high performance, in particular, high brightness. Also disclosed is a nitrogen-containing alloy and an alloy powder useful for producing the high performance phosphor. The method for producing the phosphor includes heating a raw material for a phosphor in whole or in part comprising an alloy containing two or more different metal elements under a nitrogen-containing atmosphere and heating the raw material for a phosphor under conditions such that the temperature change per minute is 50° C. or lower. Using an alloy as all or part of the raw material constituting the phosphor precursor, it is possible to suppress the rapid progression of nitridation during heat treatment and industrially produce a phosphor with high performance, in particular, high brightness.
    Type: Grant
    Filed: January 5, 2012
    Date of Patent: January 28, 2014
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Naoto Kijima, Hiromu Watanabe, Keiichi Seki
  • Patent number: 8574459
    Abstract: To provide a yellow to orange phosphor which has high luminance and excellent temperature characteristics and which also has high luminance when mixed with a phosphor of a different color. A phosphor containing a crystal phase represented by the following formula [I], wherein when its object color is expressed by the L*a*b* color system, the values of a*, b* and (a*2+b*2)1/2 satisfy ?20?a*??2, 71?b* and 71?(a*2+b*2)1/2, respectively: R3?x?y?z+w2MzA1.5x+y?w2Si6?w1?w2Alw1+w2Oy+w1N11?y?w1??[I].
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: November 5, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Takatoshi Seto, Naoto Kijima, Keiichi Seki, Ryuji Adachi, Hiroyasu Yamada, Tatsuya Inoue
  • Publication number: 20130271960
    Abstract: To provide a semiconductor light emitting device which is capable of accomplishing a broad color reproducibility for an entire image without losing brightness of the entire image. A light source provided on a backlight for a color image display device has a semiconductor light emitting device comprising a solid light emitting device to emit light in a blue or deep blue region or in an ultraviolet region and phosphors, in combination. The phosphors comprise a green emitting phosphor and a red emitting phosphor. The green emitting phosphor and the red emitting phosphor are ones, of which the rate of change of the emission peak intensity at 100° C. to the emission intensity at 25° C., when the wavelength of the excitation light is 400 nm or 455 nm, is at most 40%.
    Type: Application
    Filed: June 10, 2013
    Publication date: October 17, 2013
    Inventors: Byungchul HONG, Naoki SAKO, Naoto KIJIMA, Masahiko YOSHINO, Takashi HASE, Fumiko YOYASU, Kentarou HORIBE
  • Publication number: 20130264937
    Abstract: The present invention provides a technology that allows reducing the used amount of a Mn4+-activated fluoride complex phosphor without loss of luminous efficiency, in a white light-emitting device that is provided with the Mn4+-activated fluoride complex phosphor and an LED element that is an excitation source of the phosphor. The present invention provides a white light-emitting device comprises a blue LED element, as well as a yellow phosphor and/or a green phosphor and a red phosphor as phosphors that are excited by the blue LED element. The red phosphor contains a Mn4+-activated fluoride complex phosphor and a Eu2+-activated alkaline earth silicon nitride phosphor.
    Type: Application
    Filed: March 15, 2013
    Publication date: October 10, 2013
    Inventors: Hiroaki SAKUTA, Yoshihito SATOU, Naoto KIJIMA, Byungchul HONG
  • Publication number: 20130241397
    Abstract: Provided is a phosphor having enhanced luminance with respect to that of conventional ?-type sialon phosphors. A phosphor having enhanced luminance is obtained by causing Al, O (oxygen) and Eu to be present at specific concentrations in a produced ?-type sialon phosphor. Specifically, provided is a ?-type sialon phosphor containing Si, Al, O, N and Eu, wherein the Al concentration in the phosphor ranges from 0.80 mass % or higher to 2.25 mass % or lower, the O concentration ranges from 0.36 mass % or higher to 1.15 mass % or lower, the Eu concentration ranges from 0.40 mass % or higher to 0.80 mass % or lower and a ratio (Al/O) of the Al concentration with respect to the O concentration ranges from 2.0 or higher to 3.0 or lower.
    Type: Application
    Filed: March 28, 2013
    Publication date: September 19, 2013
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Byungchul HONG, Naoto KIJIMA
  • Publication number: 20130234588
    Abstract: To provide a new phosphor of which fluorescence contains much red light component and has a large full width at half maximum, the crystal phase represented by the formula [I] is included in the phosphor. R3?x?y?z+w2MzA1.5x+y?w2Si6?w1?w2AlW1+w2Oy+w1N11?y?w1??[I] (R represents La, Gd, Lu, Y and/or Sc, M represents Ce, Eu, Mn, Yb, Pr and/or Tb, A represents Ba, Sr, Ca, Mg and/or Zn, and x, y, z, w1 and w2 are the numeric values in the following ranges: (1/7)?(3?x?y?z+w2)/6<(1/2), 0<(1.5x+y?w2)/6<(9/2), 0<x<3, 0?y<2, 0<z<1, 0?w1?5, 0?w2?5, and 0?w1+w2?5.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 12, 2013
    Inventors: Takatoshi SETO, Naoto Kijima
  • Patent number: 8491816
    Abstract: To provide a semiconductor light emitting device which is capable of accomplishing a broad color reproducibility for an entire image without losing brightness of the entire image. A light source provided on a backlight for a color image display device has a semiconductor light emitting device comprising a solid light emitting device to emit light in a blue or deep blue region or in an ultraviolet region and phosphors, in combination. The phosphors comprise a green emitting phosphor and a red emitting phosphor. The green emitting phosphor and the red emitting phosphor are ones, of which the rate of change of the emission peak intensity at 100° C. to the emission intensity at 25° C., when the wavelength of the excitation light is 400 nm or 455 nm, is at most 40%.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: July 23, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Byungchul Hong, Naoki Sako, Naoto Kijima, Masahiko Yoshino, Takashi Hase, Fumiko Yoyasu, Kentarou Horibe
  • Patent number: 8460580
    Abstract: The present invention relates to a phosphor comprising a nitride or an oxynitride, comprising an X-ray powder diffraction pattern comprising at least one Region having at least one peak with an intensity ratio I of 8% or less, the X-ray powder diffraction pattern measured in the 2? range from 10° to 60° using a CuK? line (1.54184 {acute over (?)}), wherein the Region is the 2? range from 41.5° to 47°, the intensity of each peak is a value obtained after background correction, and the intensity ratio I is defined by the formula (Ip×100)/Imax (%), where Imax represents the height of the most intense peak present in the 2? range from 34° to 37° and Ip represents the height of each peak.
    Type: Grant
    Filed: November 9, 2009
    Date of Patent: June 11, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hiromu Watanabe, Masumi Itou, Keiichi Seki, Hiroshi Wada, Motoyuki Shigeiwa, Kaoru Terada, Naoto Kijima
  • Patent number: 8451401
    Abstract: To attain a high color reproducibility as a whole image without impairing the brightness of the entire image. A color image display device comprising a combination of light shutters, a color filter having color elements of at least three colors of red, green and blue corresponding to the light shutters, and a backlight for transmission illumination, wherein a light source to be used for the backlight comprises a combination of a blue or deep blue LED and a phosphor, and the relationship between the NTSC ratio W as a color reproduction range of the color image display element and the light use efficiency Y is represented Y??0.38 W+51 (wherein W?87).
    Type: Grant
    Filed: April 19, 2007
    Date of Patent: May 28, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Shin Kawana, Hideaki Kaneda, Naoto Kijima, Naoki Sako, Noriko Endou
  • Patent number: 8427044
    Abstract: To enhance luminance and color rendering of a light emitting device comprising phosphors as wavelength converting material and at least one semiconductor light emitting device that emits visible light, as said phosphors, are used phosphors which are one or more kinds of phosphors selected from a group consisting of oxides, oxynitrides and nitrides, and are a mixture consisting of two or more kinds of phosphors whose luminous efficiency is 35% or higher when excited by the visible light from said semiconductor light emitting device at room temperature. In addition, said mixture contains a first phosphor, and a second phosphor that is different from said first phosphor and capable of absorbing emitted light from said first phosphor, and said first phosphor is contained 85 weight % or more of said mixture of phosphors.
    Type: Grant
    Filed: March 28, 2011
    Date of Patent: April 23, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yasuo Shimomura, Hideaki Kaneda, Naoto Kijima
  • Publication number: 20130092965
    Abstract: An object of the present invention is to provide a light emitting device exhibiting a superior emission efficiency which enables easy adjustment of an emission spectrum. The above object is achieved by a light emitting device comprising a semiconductor light emitting element and a phosphor layer, which has an area A and an area B of different emission spectra, and in which a plurality of phosphor portions are disposed on a plane such that identical phosphor portions do not adjoin one another, and the surface area occupied by specific phosphor portions in the phosphor layer is different in area A and area B.
    Type: Application
    Filed: October 1, 2012
    Publication date: April 18, 2013
    Inventors: NAOTO KIJIMA, TADAHIRO KATSUMOTO, FUMIKO YOYASU, HIROYA KODAMA, TOSHIAKI YOKOO, TORU TAKEDA, SHUUJI ONAKA
  • Publication number: 20130075773
    Abstract: An object of the present invention is to provide a light emitting device which increases the emission efficiency of phosphor by reducing self-absorption of light by phosphor and by reducing absorption of fluorescent light by an encapsulating resin, and which increases the efficiency of light extraction from the phosphor layer by preventing light scattering caused by the phosphor. The above object was achieved by a light emitting device comprising a semiconductor light emitting element and a phosphor layer wherein the phosphor layer was made dense by setting specific values for particle distribution of phosphor contained in the phosphor layer and for the packing ratio of the phosphor contained in the phosphor layer.
    Type: Application
    Filed: October 1, 2012
    Publication date: March 28, 2013
    Inventors: Naoto KIJIMA, Toshiaki Yokoo, Tadahiro Katsumoto, Hiroya Kodama, Fumiko Yoyasu
  • Patent number: 8398890
    Abstract: To provide a new phosphor of which fluorescence contains much red light component and has a large full width at half maximum, the crystal phase represented by the formula [I] is included in the phosphor. R3?x?y?z+w2MzA1.5x+y?w2Si6?w1?w2AlW1+w2Oy+w1N11?y?w1??[I] (R represents La, Gd, Lu, Y and/or Sc, M represents Ce, Eu, Mn, Yb, Pr and/or Tb, A represents Ba, Sr, Ca, Mg and/or Zn, and x, y, z, w1 and w2 are the numeric values in the following ranges: ( 1/7)?(3?x?y?z+w2)/6<(½), 0<(1.
    Type: Grant
    Filed: October 19, 2009
    Date of Patent: March 19, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Takatoshi Seto, Naoto Kijima
  • Patent number: 8384285
    Abstract: The present invention relates to a phosphor represented by the following general formula (I), comprising: a composite oxide containing a divalent and trivalent metal elements as a host crystal; and at least Ce as an activator element in said host crystal, wherein the phosphor has a maximum emission peak in a wavelength range of from 485 nm to 555 nm in the emission spectrum at room temperature: M1aM2bM3cOd??(I) wherein M1 represents an activator element containing at least Ce; M2 represents a divalent metal element; M3 represents a trivalent metal element; a is a number within a range of 0.0001?a?0.2; b is a number within a range of 0.8?b?1.2; c is a number within a range of 1.6?c?2.4; and d is a number within a range of 3.2?d?4.8. Further, a light emitting device comprising said phosphor and a display and a lighting system having said light emitting device as a light source are disclosed.
    Type: Grant
    Filed: May 6, 2011
    Date of Patent: February 26, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yasuo Shimomura, Naoto Kijima
  • Publication number: 20120286646
    Abstract: The present invention provides a blue (blue-green) phosphor that has sufficient emission intensity in the wavelength region around 490 nm and that has high emission luminance at a temperature region reached during LED operation. The present invention also provides a white light-emitting device that uses a high-luminance green phosphor having an emission peak wavelength of 535 nm or greater and that has improved bright blue reproducibility. A phosphor having a chemical composition of general formula [1] has sufficient emission intensity in a wavelength region around 490 nm, and a white light-emitting device that uses such a phosphor has improved bright blue reproducibility. (Sr, Ca)aBabEux(PO4)cXd??[1] (In general formula [1], X is Cl; c, d and x are numbers satisfying 2.7?c?3.3, 0.9?d?1.1 and 0.3?x?1.2; and a and b satisfy the conditions a+b=5?x and 0.12?b/(a+b)?0.4.
    Type: Application
    Filed: April 26, 2012
    Publication date: November 15, 2012
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Hiroaki SAKUTA, Kazuhiko Kagawa, Yoshihito Sato, Takatoshi Seto, Naoto Kijima