Patents by Inventor Naoto Kijima

Naoto Kijima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20100090585
    Abstract: To provide a phosphor that stably shows high emission intensity and brightness as well as superior temperature characteristics, under excitation by near-ultraviolet light, the phosphor contains an alkaline-earth metal aluminate and has a crystal phase comprising an alkali metal element and, in that crystal phase, the rate of substituted Eu (europium) to the number of sites which can be substituted with Eu of the crystal phase is 25% or higher and the ratio of the alkali metal element to the number of sites which can be substituted with Eu of the crystal phase is 3% or lower.
    Type: Application
    Filed: September 29, 2009
    Publication date: April 15, 2010
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Takatoshi SETO, Naoto KIJIMA, Etsuo SHIMIZU, Kumie SHIMIZU
  • Publication number: 20100085728
    Abstract: To provide a new phosphor of which fluorescence contains much red light component and has a large full width at half maximum, the crystal phase represented by the formula [I] is included in the phosphor. R3?x?y?z+w2MzA1.5x+y?w2Si6?w1?w2AlW1+w2Oy+w1N11?y?w1 ??[I] (R represents La, Gd, Lu, Y and/or Sc, M represents Ce, Eu, Mn, Yb, Pr and/or Tb, A represents Ba, Sr, Ca, Mg and/or Zn, and x, y, z, w1 and w2 are the numeric values in the following ranges: ( 1/7)?(3?x?y?z+w2)/6<(½), 0<(1.5x+y?w2)/6<(9/2), 0<x<3, 0?y<2, 0<z<1, 0?w1?5, 0?w2?5, and 0?w1+w2?5.
    Type: Application
    Filed: October 19, 2009
    Publication date: April 8, 2010
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Takatoshi Seto, Naoto Kijima
  • Publication number: 20100052515
    Abstract: The present invention relates to a phosphor comprising a nitride or an oxynitride, comprising an X-ray powder diffraction pattern comprising at least one Region having at least one peak with an intensity ratio I of 8% or less, the X-ray powder diffraction pattern measured in the 2? range from 10° to 60° using a CuK? line (1.54184 {acute over (?)}), wherein the Region is the 2? range from 41.5° to 47°, the intensity of each peak is a value obtained after background correction, and the intensity ratio I is defined by the formula (Ip×100)/Imax (%), where Imax represents the height of the most intense peak present in the 2? range from 34° to 37° and Ip represents the height of each peak.
    Type: Application
    Filed: November 9, 2009
    Publication date: March 4, 2010
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Hiromu WATANABE, Masumi Itou, Keiichi Seki, Hiroshi Wada, Motoyuki Shigeiwa, Kaoru Terada, Naoto Kijima
  • Publication number: 20090322990
    Abstract: To attain a high color reproducibility as a whole image without impairing the brightness of the entire image. A color image display device comprising a combination of light shutters, a color filter having color elements of at least three colors of red, green and blue corresponding to the light shutters, and a backlight for transmission illumination, wherein a light source to be used for the backlight comprises a combination of a blue or deep blue LED and a phosphor, and the relationship between the NTSC ratio W as a color reproduction range of the color image display element and the light use efficiency Y is represented Y?0.38W+51 (wherein W?87).
    Type: Application
    Filed: April 19, 2007
    Publication date: December 31, 2009
    Inventors: Shin Kawana, Hideaki Kaneda, Naoto Kijima, Naoki Sako, Noriko Endou
  • Publication number: 20090267484
    Abstract: An illuminating device comprises one or more luminescent devices (1). The luminescent device comprises a semiconductor light emitting element (10) emitting a excitation light having an peak within a wavelength range from 350 nm to 430 nm, and a luminescent part (20) comprising a sealing member (22) and a phosphor (21) absorbing the light from the semiconductor light emitting element (10) and emitting a light with different emission spectrum. For the luminescent device (1), an excitation light contribution degree ?E, an index quantitatively representing what extent of a visible component of the excitation light is involved in color mixing of a combined light of the luminescent device (1), is 0.005 or less, and a mean color rendering index Ra is 70 or more.
    Type: Application
    Filed: June 27, 2007
    Publication date: October 29, 2009
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Akeo Kasakura, Kazuhiko Kagawa, Naoto Kijima
  • Patent number: 7608200
    Abstract: An object of the present invention is to provide a high-efficiency red light emitting phosphor and white light emitting phosphor for using in a display or lighting which high-efficiently emits light in combination with a light source which emits light in the region from near-ultraviolet light to visible light. The present invention relates to a phosphor having a crystal phase having a specified chemical composition.
    Type: Grant
    Filed: January 14, 2005
    Date of Patent: October 27, 2009
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Takatoshi Seto, Naoto Kijima, Masahiko Yoshino, Masayoshi Mikami, Motoyuki Shigeiwa, Hiroyuki Imura
  • Publication number: 20090243467
    Abstract: To provide a phosphor having nearly spherical shapes, the phosphor has an elemental ratio represented by the formula below, and contains at least two kinds of Li, Na, K, Rb, Cs, P, Cl, F, Br, I, Zn, Ga, Ge, In, Sn, Ag, Au, Pb, Cd, Bi and Ti. M1aM2bM3cOd (M1 represents Cr, Mn, Fe, Co, Ni, Cu, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm or Yb, M2 mainly represents a bivalent metal element, M3 mainly represents a trivalent metal element, and a, b, c and d are 0.0001?a?0.2, 0.8?b?1.2, 1.6?c?2.4 and 3.2?d?4.8, respectively.
    Type: Application
    Filed: March 13, 2009
    Publication date: October 1, 2009
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Etsuo SHIMIZU, Kumie Shimizu, Naoto KIJIMA, Yasuo SHIMOMURA
  • Publication number: 20090166584
    Abstract: To provide a green phosphor with high conversion efficiency of blue of near-ultraviolet light and excellent color purity, a multinary oxynitride phosphor represented by the general formula [I] is proposed. M1xBayM2zLuOvNw??[I] In the formula [I], M1 represents Cr, Mn, Fe, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm and Yb, M2 represents Sr, Ca, Mg and Zn, L represents metal elements belonging to the fourth group or the fourteenth group of the periodic table, and x, y, z, u, v and w are the numeric values in the following ranges: 0.00001?x?3 0?y?2.99999 2.6?x+y+z?3 0<u?11 6<v?25 0<w?17.
    Type: Application
    Filed: March 9, 2009
    Publication date: July 2, 2009
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Satoshi SHIMOOKA, Kyota Ueda, Masayoshi Mikami, Naoto Kijima, Hiroyuki Imura, Kentaro Horibe
  • Publication number: 20090140630
    Abstract: To achieve a light-emitting device emitting light with high brightness, closer to natural light, and less color shift due to a small change in intensity of emitted light, in a light-emitting device including a light source emitting light by driving current and at least one wavelength-converting material absorbing at least part of the light from the light source and emitting light having a different wavelength, the color coordinate x1(17.5) and the color coordinate y1(17.5) of the light emitted at a driving current density of 17.5 A/cm2 and the color coordinate x1(70) and the color coordinate y1(70) of the light emitted at a driving current density of 70 A/cm2 satisfy the following Expressions (D) and (E): ?0.006?x1(17.5)?x1(70)?0.006??(D), ?0.006?y1(70)?y1(70)?0.006??(E).
    Type: Application
    Filed: March 17, 2006
    Publication date: June 4, 2009
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Naoto Kijima, Yasuo Shimomura, Hideaki Kaneda, Kimiya Takeshita
  • Publication number: 20090140205
    Abstract: There is provided a method for industrially producing a phosphor with high performance, in particular, high brightness. There is also provided a nitrogen-containing alloy and an alloy powder that can be used for the production method. A method for producing a phosphor includes a step of heating a raw material for the phosphor under a nitrogen-containing atmosphere, in which an alloy containing two or more different metal elements constituting the phosphor is used as the whole or part of the raw material for the phosphor, and in the heating step, the heating is performed under conditions such that the temperature change per minute is 50° C. or lower. It is possible to suppress the rapid progress of a nitridation reaction in heat treatment in producing the phosphor using an alloy for a phosphor precursor as the whole or part of the raw material, thereby industrially producing the phosphor with high performance, in particular, high brightness.
    Type: Application
    Filed: May 18, 2007
    Publication date: June 4, 2009
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Naoto Kijima, Hiromu Watanabe, Keiichi Seki
  • Publication number: 20090134775
    Abstract: The present invention provides an alloy powder that is a material for producing inorganic functional materials such as phosphors, a phosphor with high brightness, and a method for producing the phosphor. An alloy powder for an inorganic functional material precursor contains at least one metal element and at least one activating element M1 and has a weight-average median diameter D50 of 5 ?m to 40 ?m. A method for producing a phosphor includes a step of heating an alloy, containing two or more metal elements for forming the phosphor, in a nitrogen-containing atmosphere.
    Type: Application
    Filed: March 31, 2006
    Publication date: May 28, 2009
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Hiromu Watanabe, Masumi Itou, Keiichi Seki, Hiroshi Wada, Motoyuki Shigeiwa, Kaoru Terada, Naoto Kijima
  • Publication number: 20090072255
    Abstract: The present invention relates to a phosphor that satisfies requirements (1) to (3): (1) the phosphor satisfies Formula [2] and/or Formula [3]: 85?{R455(125)/R455(25)}×100<110??[2] 92?{R405(100)/R405(25)}×100<110??[3] wherein R455(125) represents an emission peak intensity when the phosphor is excited by light having a peak wavelength of 455 nm at 125° C., (2) the emission peak wavelength is in the range of 570 nm to 680 nm, and (3) the full width at half maximum of an emission peak is 90 nm or less. The phosphor of the present invention has a high luminous efficiency and emits light of orange to red with high luminance. The use of the phosphor makes it possible to produce a light-emitting device, an illumination apparatus, and an image display, having a high efficiency and excellent color rendering properties.
    Type: Application
    Filed: August 10, 2006
    Publication date: March 19, 2009
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Tomoko Takahashi, Nobuhiro Kodama, Yasuo Shimomura, Naoto Kijima, Tomoyuki Kurushima, Takashi Hase, Eiji Hattori, Kouichi Adachi, Keiichi Seki, Yutaka Mori
  • Publication number: 20090066230
    Abstract: A phosphor which emits light having high brightness, serves as an excellent orange or red phosphor whose light brightness is less decreased when exposed to an excitation source contains a crystal phase having the chemical composition expressed by the general formula [1]: (1?a?b)(Ln?pMII?1?pMIII?MIV?N3)·a(MIV?(3n+2)/4NnO)·b(AMIV?2N3)??[1] wherein Ln? represents a metal element selected from the group consisting of lanthanoids, Mn, and Ti; MnII? represents a divalent metal element except the Ln? element; MIII? represents a trivalent metal element; MIV? represents a tetravalent metal element; A represents a metal element selected from the group consisting of Li, Na, and K; 0<p?0.2; 0?a, 0?b, a+b>0, 0?n, and 0.002?(3n+2)a/4?0.9.
    Type: Application
    Filed: May 24, 2006
    Publication date: March 12, 2009
    Applicants: Mitsubishi Chemical Corporation, Ind Admin Ins NATIONAL INSTITUTE FOR MATERIALS SCI
    Inventors: Naoto Hirosaki, Takatoshi Seto, Naoto Kijima
  • Publication number: 20090033201
    Abstract: To provide a green phosphor with high conversion efficiency of blue of near-ultraviolet light and excellent color purity, a multinary oxynitride phosphor represented by the general formula [I] is proposed. M1xBayM2zLuOvNw??[I] In the formula [I], M1 represents Cr, Mn, Fe, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm and Yb, M2 represents Sr, Ca, Mg and Zn, L represents metal elements belonging to the fourth group or the fourteenth group of the periodic table, and x, y, z, u, v and w are the numeric values in the following ranges: 0.00001?x?3 0?y?2.99999 2.6?x+y+z?3 0<u?11 6<v?25 0<w?17.
    Type: Application
    Filed: February 2, 2007
    Publication date: February 5, 2009
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Satoshi Shimooka, Kyota Ueda, Masayoshi Mikami, Naoto Kijima, Hiroyuki Imura, Kentaro Horibe
  • Publication number: 20090026920
    Abstract: The present invention relates to a phosphor represented by the following general formula (I), comprising: a composite oxide containing a divalent and trivalent metal elements as a host crystal; and at least Ce as an activator element in said host crystal, wherein the phosphor has a maximum emission peak in a wavelength range of from 485 nm to 555 nm in the emission spectrum at room temperature: M1aM2bM3cOd??(I) wherein M1 represents an activator element containing at least Ce; M2 represents a divalent metal element; M3 represents a trivalent metal element; a is a number within a range of 0.0001?a?0.2; b is a number within a range of 0.8?b?1.2; c is a number within a range of 1.6?c?2.4; and d is a number within a range of 3.2?d?4.8. Further, a light emitting device comprising said phosphor and a display and a lighting system having said light emitting device as a light source are disclosed.
    Type: Application
    Filed: June 30, 2005
    Publication date: January 29, 2009
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Yasuo Shimomura, Naoto Kijima
  • Publication number: 20090008663
    Abstract: A phosphor containing a crystal phase having a chemical composition expressed by the following general formula [1], and exhibiting an average variation rate of the emission intensity of 1.3 or less upon excitation with light having a peak in the wavelength range of 420 nm to 480 nm, the variation rate of the emission intensity being calculated by the following general formula [2]. (Ln1-a-bCeaTbb)3M5O12??[1] wherein Ln is at least one element selected from the group consisting of Y, Gd, Sc, Lu, and La, M represents at least one element selected from the group consisting of Al, Ga, and In, and a and b satisfy 0.001?a?0.3 and 0?b?0.5, respectively. Variation rate of emission intensity=[(I(?+1)?I(?))/I(?)]2??[2] wherein I(?) is the emission intensity of the phosphor at an excitation wavelength of ?nm, and I(?+1) is the emission intensity of the phosphor at an excitation wavelength of (?+1) nm.
    Type: Application
    Filed: February 23, 2006
    Publication date: January 8, 2009
    Applicant: Mitshubishi Chemcial
    Inventors: Etsuo Shimizu, Masahiko Yoshino, Naoto Kijima
  • Patent number: 7474050
    Abstract: A light emitting device for enhancing emission efficiency and color rendering, comprising: a light source; a first emitting section having a luminescent material emitting light including a wavelength component longer than that of light from the light source when excited by the light from the light source; a second emitting section having a luminescent material emitting light including a wavelength component longer than that of the light from the first emitting section when excited by the lights from the light source and the first emitting section; and a light exit side from which the light from the light source, the first light-emitting section and the second light-emitting section emerges outside; and the first emitting section and the second emitting section are opened at the light exit side, and an area of a boundary surface between the first emitting section and the second emitting section is equal to or less than fifty percent of the surface area of the first emitting section.
    Type: Grant
    Filed: June 29, 2005
    Date of Patent: January 6, 2009
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hideaki Kaneda, Naoto Kijima, Eiji Hattori
  • Publication number: 20080303410
    Abstract: To enhance emission efficiency and color rendering, a light emitting device includes: at least one light source; at least one first emitting section having at least one sort of luminescent material that can emit light including a wavelength component that is longer than the light emitted from light source when excited by the light emitted from light source; at least one second emitting section having at least one sort of luminescent material that can emit light including a wavelength component that is longer than the light emitted from first emitting section when excited by the light emitted from light source and first emitting section; wherein light emitting device includes at least one light shielding unit that protects at least a part of the light emitted from first emitting section from entering second emitting section.
    Type: Application
    Filed: June 29, 2005
    Publication date: December 11, 2008
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Hideaki Kaneda, Naoto Kijima, Eiji Hattori
  • Publication number: 20080290786
    Abstract: To enhance luminance and color rendering of a light emitting device comprising phosphors as wavelength converting material and at least one semiconductor light emitting device that emits visible light, as said phosphors, are used phosphors which are one or more kinds of phosphors selected from a group consisting of oxides, oxynitrides and nitrides, and are a mixture consisting of two or more kinds of phosphors whose luminous efficiency is 35% or higher when excited by the visible light from said semiconductor light emitting device at room temperature. In addition, said mixture contains a first phosphor, and a second phosphor that is different from said first phosphor and capable of absorbing emitted light from said first phosphor, and said first phosphor is contained 85 weight % or more of said mixture of phosphors.
    Type: Application
    Filed: June 29, 2005
    Publication date: November 27, 2008
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yasuo Shimomura, Hideaki Kaneda, Naoto Kijima
  • Publication number: 20080218060
    Abstract: A phosphor (A) comprising a host material composed of a compound having a garnet crystal structure represented by the general formula (I): M1aM2bM3cOd ??(I) (wherein M1 is a divalent metal element, M2 is a trivalent metal element, M3 is a tetravalent metal element containing at least Si, a is the number of 2.7 to 3.3, b is the number of 1.8 to 2.2, c is the number of 2.7 to 3.3, and d is the number of 11.0 to 13.0), and a luminescent center ion incorporated in the host material; a light emitting device (B) comprising the phosphor as a wavelength conversion material and a semiconductor light emitting element capable of emitting a light in the range of from ultraviolet light to visible light; and a display (C) and a lighting system (D) using the light emitting device (B) as a light source. The above phosphor can be readily produced, and can provide a light emitting device having a high color rendering property.
    Type: Application
    Filed: May 21, 2008
    Publication date: September 11, 2008
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yasuo Shimomura, Naoto Kijima