Abstract: A method of depositing tungsten over a substrate includes disposing the substrate into a vacuum enclosure of a tungsten deposition apparatus, performing a first tungsten deposition process that deposits a first tungsten layer over a physically exposed surface of the substrate by flowing a fluorine-containing tungsten precursor gas into the vacuum enclosure, performing an in-situ oxidation process by exposing the first tungsten layer to an oxidation agent gas while the substrate remains within the vacuum enclosure without breaking vacuum and forming a tungsten oxyfluoride gas which is pumped out of the vacuum enclosure, and performing a second tungsten deposition process that deposits a second tungsten layer on the first tungsten layer by flowing the fluorine-containing tungsten precursor gas into the vacuum enclosure in a second tungsten deposition process after the in-situ oxidation process.

Abstract: A three-dimensional memory device includes an alternating stack of insulating layers and electrically conductive layers located over a substrate, and a memory stack structure extending through the alternating stack. The memory stack structure includes a vertical semiconductor channel, a vertical stack of majority germanium layers each containing at least 51 atomic percent germanium, and a vertical stack of ferroelectric dielectric layers.

Abstract: A three-dimensional memory device includes an alternating stack of insulating layers and electrically conductive layers located over a substrate and memory stack structures extending through the alternating stack. Each of the electrically conductive layers includes a stack of a compositionally graded diffusion barrier and a metal fill material portion, and the compositionally graded diffusion barrier includes a substantially amorphous region contacting the interface between the compositionally graded diffusion barrier and a substantially crystalline region that is spaced from the interface by the amorphous region. The substantially crystalline region effectively blocks atomic diffusion, and the amorphous region induces formation of large grains during deposition of the metal fill material portions.

Abstract: A source-level sacrificial layer and an alternating stack of insulating layers and spacer material layers are formed over a substrate. The spacer material layers are formed as, or are subsequently replaced with, electrically conductive layers. Memory openings are formed through the alternating stack and the source-level sacrificial layer, and memory opening fill structures are formed. A source cavity is formed by removing the source-level sacrificial layer, and exposing an outer sidewall of each vertical semiconductor channel in the memory opening fill structures. A metal-containing layer is deposited on physically exposed surfaces of the vertical semiconductor channel and the vertical semiconductor channel is crystallized using metal-induced lateral crystallization. Alternatively or additionally, cylindrical metal-semiconductor alloy regions can be formed around the vertical semiconductor channels to reduce contact resistance. A source contact layer can be formed in the source cavity.

Abstract: A first semiconductor die includes first semiconductor devices located over a first substrate, first interconnect-level dielectric material layers embedding first metal interconnect structures and located on the first semiconductor devices, and a first pad-level dielectric layer located on the first interconnect-level dielectric material layers and embedding first bonding pads. Each of the first bonding pads includes a first proximal horizontal surface and at least one first distal horizontal surface that is more distal from the first substrate than the first proximal horizontal surface is from the first substrate and has a lesser total area than a total area of the first proximal horizontal surface. A second semiconductor die including second bonding pads that are embedded in a second pad-level dielectric layer can be bonded to a respective distal surface of the first bonding pads.

Abstract: Multiple bonded units are provided, each of which includes a respective front-side die and a backside die. The two dies in each bonded unit may be a memory die and a logic die configured to control operation of memory elements in the memory die. Alternatively, the two dies may be memory dies. The multiple bonded units can be attached such that front-side external bonding pads have physically exposed surfaces that face upward and backside external bonding pads of each bonded unit have physically exposed surfaces that face downward. A first set of bonding wires can connect a respective pair of front-side external bonding pads, and a second set of bonding wires can connect a respective pair of backside external bonding pads.

Abstract: A memory opening or a line trench is formed through an alternating stack of insulating layers and sacrificial material layers. A memory opening fill structure or a memory stack assembly is formed, which includes a vertical stack of discrete intermediate metallic electrodes formed on sidewalls of the sacrificial material layers, a gate dielectric layer, and a vertical semiconductor channel. Backside recesses are formed by removing the sacrificial material layers selective to the insulating layers, and a combination of a ferroelectric dielectric layer and an electrically conductive layer within each of the backside recesses. The electrically conductive layer is laterally spaced from a respective one of the discrete intermediate metallic electrodes by the ferroelectric dielectric layer. Ferroelectric-metal-insulator memory elements are formed around the vertical semiconductor channel.

Abstract: A memory opening or a line trench is formed through an alternating stack of insulating layers and sacrificial material layers. A memory opening fill structure or a memory stack assembly is formed, which includes a vertical stack of discrete intermediate metallic electrodes formed on sidewalls of the sacrificial material layers, a gate dielectric layer, and a vertical semiconductor channel. Backside recesses are formed by removing the sacrificial material layers selective to the insulating layers, and a combination of a ferroelectric dielectric layer and an electrically conductive layer within each of the backside recesses. The electrically conductive layer is laterally spaced from a respective one of the discrete intermediate metallic electrodes by the ferroelectric dielectric layer. Ferroelectric-metal-insulator memory elements are formed around the vertical semiconductor channel.

Abstract: A method of forming a three-dimensional memory device includes forming an alternating stack of insulating layers and sacrificial material layers over a substrate, forming a memory opening through the alternating stack, forming lateral recesses at levels of the sacrificial material layers around the memory opening, forming a vertical stack of discrete clam-shaped semiconductor liners in the lateral recesses, replacing the vertical stack of discrete clam-shaped semiconductor liners with a vertical stack of inner clam-shaped metallic liners, forming a vertical stack of discrete charge storage elements on the vertical sack of inner clam-shaped metallic liners, forming a tunneling dielectric layer and a vertical semiconductor channel over the vertical stack of discrete charge storage elements and the vertical stack of inner clam-shaped metallic liners, and replacing each of the sacrificial material layers with an electrically conductive layer.

Abstract: A method of forming a three-dimensional memory device includes forming an alternating stack of insulating layers and sacrificial material layers over a substrate, forming a memory opening through the alternating stack, forming lateral recesses at levels of the sacrificial material layers around the memory opening, forming a vertical stack of discrete clam-shaped semiconductor liners in the lateral recesses, replacing the vertical stack of discrete clam-shaped semiconductor liners with a vertical stack of inner clam-shaped metallic liners, forming a vertical stack of discrete charge storage elements on the vertical sack of inner clam-shaped metallic liners, forming a tunneling dielectric layer and a vertical semiconductor channel over the vertical stack of discrete charge storage elements and the vertical stack of inner clam-shaped metallic liners, and replacing each of the sacrificial material layers with an electrically conductive layer.

Abstract: A first semiconductor die includes first semiconductor devices located over a first substrate, first interconnect-level dielectric material layers embedding first metal interconnect structures and located on the first semiconductor devices, and a first pad-level dielectric layer located on the first interconnect-level dielectric material layers and embedding first bonding pads. Each of the first bonding pads includes a first proximal horizontal surface and at least one first distal horizontal surface that is more distal from the first substrate than the first proximal horizontal surface is from the first substrate and has a lesser total area than a total area of the first proximal horizontal surface. A second semiconductor die including second bonding pads that are embedded in a second pad-level dielectric layer can be bonded to a respective distal surface of the first bonding pads.

Abstract: A first semiconductor die includes first semiconductor devices located over a first substrate, first interconnect-level dielectric material layers embedding first metal interconnect structures and located on the first semiconductor devices, and a first pad-level dielectric layer located on the first interconnect-level dielectric material layers and embedding first bonding pads. Each of the first bonding pads includes a first proximal horizontal surface and at least one first distal horizontal surface that is more distal from the first substrate than the first proximal horizontal surface is from the first substrate and has a lesser total area than a total area of the first proximal horizontal surface. A second semiconductor die including second bonding pads that are embedded in a second pad-level dielectric layer can be bonded to a respective distal surface of the first bonding pads.

Abstract: A bonded assembly includes a first semiconductor die that includes first semiconductor devices, and a first pad-level dielectric layer and embedding first bonding pads; and a second semiconductor die that includes second semiconductor devices, and a second pad-level dielectric layer embedding second bonding pads that includes a respective second pad base portion. Each of the first bonding pads includes a respective first pad base portion and a respective first metal alloy material portion having a higher coefficient of thermal expansion (CTE) than the respective first pad base portion. Each of the second bonding pads is bonded to a respective one of the first bonding pads.

Abstract: A first semiconductor die includes first semiconductor devices located over a first substrate, first interconnect-level dielectric material layers embedding first metal interconnect structures and located on the first semiconductor devices, and a first pad-level dielectric layer located on the first interconnect-level dielectric material layers and embedding first bonding pads. Each of the first bonding pads includes a first proximal horizontal surface and at least one first distal horizontal surface that is more distal from the first substrate than the first proximal horizontal surface is from the first substrate and has a lesser total area than a total area of the first proximal horizontal surface. A second semiconductor die including second bonding pads that are embedded in a second pad-level dielectric layer can be bonded to a respective distal surface of the first bonding pads.

Abstract: A support die includes complementary metal-oxide-semiconductor (CMOS) devices, front support-die bonding pads electrically connected to a first subset of the peripheral circuitry, and backside bonding structures electrically connected to a second subset of the peripheral circuitry. A first memory die including a first three-dimensional array of memory elements is bonded to the support die. First memory-die bonding pads of the first memory die are bonded to the front support-die bonding pads. A second memory die including a second three-dimensional array of memory elements is bonded to the support die. Second memory-die bonding pads of the second memory die are bonded to the backside bonding structures.

Abstract: A ferroelectric tunnel junction memory device includes a bit line, a word line and a memory cell located between the bit line and the word line. The memory cell includes a ferroelectric tunneling dielectric portion and an ovonic threshold switch material portion.

Abstract: A three-dimensional memory device includes an alternating stack of source layers and drain layers located over a substrate, memory openings vertically extending through the alternating stack, vertical word lines located in each one of the memory openings and vertically extending through each of the source layers and the drain layers of the alternating stack, vertical stacks of discrete semiconductor channels located in each one of the memory openings and contacting horizontal surfaces of a respective vertically neighboring pair of a source layer of the source layers and a drain layer of the drain layers, and vertical stacks of discrete memory material portions located in each one of the memory openings and laterally surrounding a respective one of the vertical word lines. Each memory material portion is laterally spaced from a respective one of the semiconductor channels by a respective gate dielectric layer.

Abstract: A memory device includes an alternating stack of insulating layers, dielectric barrier liners and electrically conductive layers located over a substrate and a memory stack structure extending through each layer in the alternating stack. Each of the dielectric barrier liners is located between vertically neighboring pairs of an insulating layer and an electrically conductive layer within the alternating stack. The memory stack structure includes a memory film and a vertical semiconductor channel, the memory film includes a tunneling dielectric layer and a vertical stack of discrete memory-level structures that are vertically spaced from each other without direct contact between them, and each of the discrete memory-level structures includes a lateral stack including, from one side to another, a charge storage material portion, a silicon oxide blocking dielectric portion, and a dielectric metal oxide blocking dielectric portion.

Abstract: A three-dimensional memory device includes an alternating stack of source layers and drain layers located over a substrate, a memory opening vertically extending through the alternating stack, a vertical word line located in the memory opening and vertically extending through each of the source layers and the drain layers of the alternating stack, discrete semiconductor channels contacting horizontal surfaces of a respective vertically neighboring pair of a source layer of the source layers and a drain layer of the drain layers, and a vertical stack of discrete memory material portions laterally surrounding the vertical word line.

Abstract: A ferroelectric tunnel junction memory device includes a bit line, a word line and a memory cell located between the bit line and the word line. The memory cell includes a ferroelectric tunneling dielectric portion and an ovonic threshold switch material portion.