Patents by Inventor Rolf Mulhaupt

Rolf Mulhaupt has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4963636
    Abstract: Compounds of formula (I) ##STR1## wherein one of the radicals R.sup.1 or R.sup.2 is --N.dbd.C.dbd.O and the other is --NHC(O)S(CH.sub.2).sub.3 Si(OR.sup.3).sub.3, wherein R.sup.3 is C.sub.1 -C.sub.4 alkyl or phenyl, are most suitable for use as adhesion promoters for polyurethane single-component or two-component adhesives and also as primers.
    Type: Grant
    Filed: February 12, 1990
    Date of Patent: October 16, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Mulhaupt, Hubert Simon
  • Patent number: 4952645
    Abstract: The present invention relates to compositions containing (a) at least one compound having at least one 1,2-epoxide group in its molecule and (b) at least one compound of the formulae I, II, III or IV ##STR1## in which m and n independently of one another are 1 or 2, y is an integer from 2 to 10, p is 3 or 4, R.sup.1, R.sup.3 and R.sup.4 are derived from radicals of aliphatic, cycloaliphatic or aromatic carboxylic acids, R.sup.1 being a divalent or trivalent radical, R.sup.3 being a divalent radical and R.sup.4 being a trivalent or tetravalent radical, after the removal of the carboxyl groups, R.sup.5 is a divalent radical of an aromatic hydroxycarboxylic acid after the removal of the carboxyl group and of the phenolic hydroxyl group and R.sup.2 is the radical of an aliphatic or cycloaliphatic diol after the removal of the two hydroxyl groups, subject to the proviso that at least 70% by weight of the radicals R.sup.1 or R.sup.
    Type: Grant
    Filed: December 16, 1988
    Date of Patent: August 28, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Mulhaupt, Julia Mockel-Weber
  • Patent number: 4920182
    Abstract: Compositions are described containing(A) an epoxy resin having on average at least two 1,2-epoxy groups per molecule or a mixture of these epoxy resins,(B) a compound of the formula I or a mixture of these compounds ##STR1## in which a and b independently of one another are 1 or 2, R.sup.1 is a .pi.-arene, R.sup.2 is a .pi.-arene, an indenyl anion or a cyclopentadienyl anion, X.sup..crclbar. is an [LQ.sub.m ].sup..crclbar. or an anion of a partially fluorinated or perfluorinated aliphatic or aromatic sulfonic acid, L is B, P, As or Sb, Q is fluorine or some of the radicals Q can also be hydroxyl groups and m corresponds to the valence of L increased by one, and(C) a flexible polyester which is terminated by, on average, at least two carboxyl groups and which is derived from an aliphatic or cycloaliphatic polyol or a mixture of such polyols and from an aliphatic, cycloaliphatic or aromatic polycarboxylic acid or a mixture of such polycarboxylic acids.
    Type: Grant
    Filed: December 5, 1988
    Date of Patent: April 24, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Aloysius H. Manser, Dieter Strasilla, Rolf Mulhaupt
  • Patent number: 4908406
    Abstract: Curable mixtures, comprising(a) a cycloaliphatic polyol of the formula I ##STR1## in which z is ##STR2## m is a number from 2 to 5, n is zero or a number from 1 to 10 and X is a direct bond or an aliphatic or cycloaliphatic radical, and(b) a prepolymeric polyhydroxy compound blocked by an aliphatic or cycloaliphatic diisocyanate, are advantageously suitable for producing adhesive bonds and seals having high tensile shear strengths.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: March 13, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Mulhaupt, Hubert Simon, Jacques-Alain Cotting
  • Patent number: 4874805
    Abstract: Compounds of the general formula I ##STR1## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or benzyl and R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is a group of the formula --CH.sub.2 OR.sup.7 (II) in which R.sup.7 is C.sub.1- C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is --C(O)--R.sup.8, and R.sup.8 is C.sub.1 -C.sub.12 -alkyl, and also not more than two of the radicals R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are one or two groups of the formula --CH.sub.2 CH.sub.2 Si(OR.sup.9).sub.3 (III), --CH.
    Type: Grant
    Filed: June 29, 1988
    Date of Patent: October 17, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Mulhaupt, Hubert Simon
  • Patent number: 4772716
    Abstract: Compounds of the general formula I ##STR1## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or benzyl and R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is a group of the formula --CH.sub.2 OR.sup.7 (II) in which R.sup.7 is C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is --C(O)--R.sup.8, and R.sup.8 is C.sub.1 -C.sub.12 -alkyl, and also not more than two of the radicals R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are one or two groups of the formula --CH.sub.2 CH.sub.2 Si(OR.sup.9).sub.3 (III), --CH.
    Type: Grant
    Filed: July 6, 1987
    Date of Patent: September 20, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Mulhaupt, Hubert Simon
  • Patent number: 4769428
    Abstract: A solution process, and a catalyst therefor, for the preparation of high molecular weight polymers of alph-olefins viz. homopolymers of ethylene and copolymers of ethylene and C.sub.3 -C.sub.12 alpha-olefins, is disclosed. The process is operated under solution polymerization conditions at 105.degree.-320.degree.. The catalyst is obtained from titanium tetrahalides, vanadium oxytrihalides and organoaluminum compounds, in which an admixture of catalyst components is heat-treated at 150.degree.-320.degree. C., and activated with an aluminoxane. The catalyst has good activity and the polymer obtained has improved color.
    Type: Grant
    Filed: October 16, 1986
    Date of Patent: September 6, 1988
    Assignee: Du Pont Canada Inc.
    Inventors: Vaclav G. Zboril, Rolf Mulhaupt
  • Patent number: 4740570
    Abstract: Metal halide particles useful, among other things, as olefin polymerization catalyst precursors and catalyst supports, are prepared by vaporizing the metal halide and then condensing it in the presence of a diluent.
    Type: Grant
    Filed: November 13, 1986
    Date of Patent: April 26, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ulrich Klabunde, Rolf Mulhaupt
  • Patent number: 4713428
    Abstract: The invention relates to compounds with structures of the formulae I to IV ##STR1## in which formulae Tr is a radical of formula V or VI ##STR2## A is --O-- or --NR.sup.1 --, R.sup.1 is hydrogen or a monovalent organic radical,X is a di- or trifunctional radical of a hydroxycarboxylic or amino-carboxylic acid after removal of the functional groups,R.sup.2, if m is 1, has one of the meanings of R.sup.1, or R.sup.
    Type: Grant
    Filed: September 12, 1986
    Date of Patent: December 15, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Mulhaupt, Alfred Renner, Horst Lauterbach
  • Patent number: 4650778
    Abstract: Metal halide particles useful, among other things, as olefin polymerization catalyst precursors and catalyst supports are prepared by vaporizing the metal halide and then condensing it in the presence of a diluent.
    Type: Grant
    Filed: January 18, 1985
    Date of Patent: March 17, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ulrich Klabunde, Rolf Mulhaupt