Abstract: A method for building three-dimensional articles using a thermal polymerization process in provided. The articles are built by using a composition that includes a thermally polymerizable composition, a thermal initiator, and a nonlinear light-to-heat conversion material such as a reverse saturable dye. The article is built by the sequential exposure of adjacent voxels with a laser beam. Microlens arrays can be used to expose more than one voxel at a time.

Abstract: Hardenable and hardened dental compositions that include radiation-to-heat converters, and articles including such hardenable and hardened compositions, are provided. Upon irradiating, the hardened compositions increase in temperature, which can be useful for reducing the bond strengths of orthodontic appliances adhered to tooth structures with the hardened compositions.

Abstract: A one-part epoxy structural adhesive comprising an epoxy resin, a toughening agent, a reactive liquid modifier present in an amount ranging from about 5% to about 15% by weight structural adhesive, and a latent amine curing agent. The structural adhesive may optionally include reactive diluents, synthetic mineral fibers, fillers, pigments and combinations th The structural adhesive may be used to form bonded joints between metal parts having clean surfaces, as well as those having surfaces contaminated with hydrocarbon-containing materials, such as oils, processing aids and lubricating agents.

Abstract: The present disclosure describes methods for making an electronic device. Methods for making electronic devices include providing a first electrode, an electro-responsive layer, and a second electrode. A first conductive nanostructured grid is deposited on a surface of the first electrode. The electro-responsive layer is facing the first conductive nanostructured grid. The electro-responsive layer is positioned between the first electrode and the second electrode. An electronic device having a first nanostructured grid deposited on a first electrode is described.

Abstract: Methods of forming nanostructures with chromonic materials are disclosed. A method includes coating a substrate surface with a chromonic solution to form a chromonic layer, removing at least a portion of the water to form a dried chromonic layer, and exposing the dried chromonic layer to an organic solvent to form a pattern of channels within the dried chromonic layer. The chromonic solution includes a chromonic material and water. Materials can be deposited within the channels to form a pattern of nanostructures.

Abstract: Multilayer articles having acoustical absorbance properties are disclosed. Methods of making and using the multilayer articles are also disclosed.

Abstract: A method for forming channels within a dried chromonic layer is described. A coating composition is applied to a substrate, dried, and exposed to a hydrophilic organic solvent forming a channel pattern having a first set of channels, and a second set of channels that are substantially perpendicular to the first set of channels. A deposition material may be disposed within the channels to form a nanostructured pattern. An article having a channel pattern is further described.

Abstract: Provided is an article that comprises a substrate comprising an acid-etchable layer, a water-soluble polymer matrix, and a photoacid generator. Also provided is a method for patterning that can provide patterned layers that can be used to form electroactive devices.

Abstract: A method for forming channels within a dried chromonic layer is described. A coating composition is applied to a substrate, dried, and exposed to a hydrophilic organic solvent forming a channel pattern having a first set of channels, and a second set of channels that are substantially perpendicular to the first set of channels. A deposition material may be disposed within the channels to form a nanostructured pattern. An article having a channel pattern is further described.

Abstract: Provided is an article that comprises a substrate comprising an acid-etchable layer, a water-soluble polymer matrix, and a photoacid generator. Also provided is a method for patterning that can provide patterned layers that can be used to form electroactive devices.

Abstract: Multilayer articles having acoustical absorbance properties are disclosed. Methods of making and using the multilayer articles are also disclosed.

Abstract: Methods of forming nanostructures with chromonic materials are disclosed. A method includes coating a substrate surface with a chromonic solution to form a chromonic layer, removing at least a portion of the water to form a dried chromonic layer, and exposing the dried chromonic layer to an organic solvent to form a pattern of channels within the dried chromonic layer. The chromonic solution includes a chromonic material and water. Materials can be deposited within the channels to form a pattern of nanostructures.

Abstract: A cationically curable composition comprises (a) at least one cationically curable species; (b) at least one cationic photoinitiator; and (c) at least one encapsulated, polymer-bound base.

Abstract: A process for preparing a polarizer is described whereby a pre-polarizing article comprising an oriented, vinylalcohol polymer film layer, and an acid donor layer comprising a thermal acid generator, is exposed to radiant energy at a temperature sufficient to effect a partial dehydration of the vinylalcohol polymer to a vinylalcohol/poly(acetylene) copolymer.

Abstract: A process for preparing a polarizer is described whereby a pre-polarizing article comprising an oriented, vinylalcohol polymer film layer, and an acid donor layer comprising a thermal acid generator, is exposed to radiant energy at a temperature sufficient to effect a partial dehydration of the vinylalcohol polymer to a vinylalcohol/poly(acetylene) copolymer.

Abstract: Accelerators that can be useful for an energy polymerizable composition comprising a cationically curable material; energy polymerizable compositions comprising at least one cationically curable material and an initiation system therefor, the initiation system comprising at least one organometallic complex salt and at least one accelerator; and a method for curing the compositions. The cured compositions can provide useful articles. The invention also provides compositions of matter comprising an organometallic complex salt and at least one compound selected from the Class 1 through Class 4 compounds disclosed herein.

Abstract: Accelerators that can be useful for an energy polymerizable composition comprising a cationically curable material; energy polymerizable compositions comprising at least one cationically curable material and an initiation system therefor, the initiation system comprising at least one organometallic complex salt and at least one accelerator; and a method for curing the compositions. The cured compositions can provide useful articles. The invention also provides compositions of matter comprising an organometallic complex salt and at least one compound selected from the Class 1 through Class 4 compounds disclosed herein.

Abstract: A thermomechanical-shock-resistant cured composition for solventless, hydrophobic resin encapsulation of electronic components having a glass transition temperature below 0° C. and containing a non-silicone oligomer including a flexible hydrocarbon backbone with reactive functionality, up to about 40% by weight of an adhesion promoter, and a optional viscosity-modifying component.

Abstract: Accelerators that can be useful for an energy polymerizable composition comprising a cationically curable material; energy polymerizable compositions comprising at least one cationically curable material and an initiation system therefor, the initiation system comprising at least one organometallic complex salt and at least one accelerator; and a method for curing the compositions. The cured compositions can provide useful articles. The invention also provides compositions of matter comprising an organometallic complex salt and at least one compound selected from the Class 1 through Class 4 compounds disclosed herein.

Abstract: A process for preparing a polarizer is described whereby a pre-polarizing article comprising an oriented, vinylalcohol polymer film layer, and an acid donor layer comprising a thermal acid generator, is exposed to radiant energy at a temperature sufficient to effect a partial dehydration of the vinylalcohol polymer to a vinylalcohol/poly(acetylene) copolymer.