Abstract: Provided are an electron donor that is easy to handle and can be used to carry out a coupling reaction economically and efficiently through simple operations under mild conditions in a short period of time, and a method for synthesizing 4,4?-bipyridine using the electron donor. The electron donor includes a mixture of a dispersion product obtained by dispersing sodium in a dispersion solvent and 1,3-dimethyl-2-imidazolidinone, and this electron donor is used in the method for synthesizing 4,4?-bipyridine.

Abstract: Provided is an abrasion-resistant steel plate which has high hardness up to the mid-thickness part thereof although the steel plate is 50 mm or more, and can be manufactured at low cost. The abrasion-resistant steel plate has a specific chemical composition having DI* of 120 or more, where DI* is defined by the following Formula (1): DI*=33.85×(0.1×C)0.5×(0.7×Si+1)×(3.33×Mn+1)×(0.35×Cu+1)×(0.36×Ni+1)×(2.16×Cr+1)×(3×Mo+1)×(1.75×V+1)×(1.5×W+1) . . . (1), has HB1 of 360 HBW10/3000 to 490 HBW10/3000, HB1 being a Brinell hardness at a depth of 1 mm from a surface, has a hardness ratio, HB1/2 to HB1, of 75% or more, HB1/2 being a Brinell hardness at a mid-thickness position, and has a plate thickness of 50 mm or more.

Abstract: A target bipyridine compound is synthesized with high purity and a high yield in a simple and safe manner in a short period of time. A method for synthesizing a di-tert-butyl-2,2?-bipyridine compound is provided, and the method includes a step of reacting, in a reaction solvent, a tert-butylpyridine compound with a dispersion product obtained by dispersing an alkali metal in a dispersion solvent. A method for synthesizing a bipyridine compound having no substituents is also provided, and the method includes a step of reacting, in a reaction solvent, pyridine with a dispersion product obtained by dispersing an alkali metal in a dispersion solvent.

Abstract: There is a demand for the development of a technique according to which sodium 2,2,6,6-tetramethylpiperidides (Na-TMPs) can be economically and efficiently synthesized through simple operations including a small number of steps under mild conditions in a short period of time. Also, there is a demand for the development of a technique according to which high-quality Na-TMPs that do not contain lithium or lithium compounds such as Li-TMP can be synthesized. The method for synthesizing sodium 2,2,6,6-tetramethylpiperidides includes a step of obtaining sodium 2,2,6,6-tetramethylpiperidides by reacting, in a reaction solvent, 2,2,6,6-tetramethylpiperidines with a dispersion product obtained by dispersing sodium in a dispersion solvent or an organosodium compound having an aromatic ring obtained through a reaction with a dispersion product obtained by dispersing sodium in a dispersion solvent.

Abstract: A steel material for high heat input welding used for low-temperature storage tanks, and has excellent joint strength and low-temperature toughness at ?55° C. of a weld heat-affected zone when high heat input welding at a heat input exceeding 80 kJ/cm is performed. The steel material has a specified chemical composition in which Mn, Cu, and Ni are contained so as to satisfy: 1.85?Mn+0.4×(Cu+Ni)?2.10, where Mn, Cu, and Ni represent the contents, by mass%, of respective components or are set to zero if not contained.

Abstract: An impact absorbing structure includes an impact absorbing member made of CFRP, and the impact absorbing member includes a pair of left and right side wall portions and upper and lower coupling wall portions each coupling the side wall portions. Each of the pair of side wall portions includes a plurality of curved portions. Each of the curved portions is formed such that a leftward/rightward direction depth thereof decreases toward a front side. Each of the pair of side wall portions includes: a plurality of first carbon fibers arranged to extend in a forward/rearward direction and constituting most of reinforced fibers contained in the side wall portion; and a plurality of second carbon fibers arranged to extend in a direction intersecting with the first carbon fibers. The plurality of second carbon fibers are arranged at both thickness direction end vicinity parts of each of the side wall portions.

Abstract: A target bipyridine compound is synthesized with high purity and a high yield in a simple and safe manner in a short period of time. A method for synthesizing a di-tert-butyl-2,2?-bipyridine compound is provided, and the method includes a step of reacting, in a reaction solvent, a tert-butylpyridine compound with a dispersion product obtained by dispersing an alkali metal in a dispersion solvent. A method for synthesizing a bipyridine compound having no substituents is also provided, and the method includes a step of reacting, in a reaction solvent, pyridine with a dispersion product obtained by dispersing an alkali metal in a dispersion solvent.

Abstract: An impact absorbing structure includes an impact absorbing member made of CFRP, and the impact absorbing member includes a pair of left and right side wall portions and upper and lower coupling wall portions each coupling the side wall portions. Each of the pair of side wall portions includes a plurality of curved portions. Each of the curved portions is formed such that a leftward/rightward direction depth thereof decreases toward a front side. Each of the pair of side wall portions includes: a plurality of first carbon fibers arranged to extend in a forward/rearward direction and constituting most of reinforced fibers contained in the side wall portion; and a plurality of second carbon fibers arranged to extend in a direction intersecting with the first carbon fibers. The plurality of second carbon fibers are arranged at both thickness direction end vicinity parts of each of the side wall portions.

Abstract: A cabin in a construction machine has a door having a vertically extending door frame and a door glass attached to the door frame. The door frame has a pulling handle portion which is attached to the cabin frame pivotally around a vertical pivot axis and projects in a direction having a component extending away from the door glass. The pulling handle portion is aligned with the riding handle in front and rear directions outside the cabin when the door is fully opened. The pulling handle portion satisfies at least one of a first condition that the height position of the second gripped portion is offset upward from the height position of the riding handle, and a second condition that the second gripped portion of the pulling handle portion extends in a second extending direction different from the first extending direction.

Abstract: Provided is a front window formed in a cabin including an upper window formed in a front face of the cabin and having a window frame with an underside portion, and a lower window disposed below the upper window so as to contact the upper window, while being capable of inhibiting condensed water from building up on the underside portion and rusting the underside portion. The upper window is provided with a glass plate having a periphery to be attached to an outer face of the window frame, defining a clearance between the underside portion and the glass plate to let out the condensed water generated on an inner face of the glass plate downwardly from the underside portion.

Abstract: In a construction machine such as a hydraulic excavator in which a boom of a working attachment is arranged to one of the left and right sides of a cab into which an operator gets on, a load transmission member for transmitting a lateral load imposed on the cab at the time of rollover of a machine main body to the boom serving as a load receiving member is attached to a side surface of the boom in a state that the load transmission member is elastically deformable taking a boom attachment point as a supporting point, further, a projection piece is provided for this load transmission member, and a clearance is formed between this projection piece and a left end surface of a top plate of the boom.

Abstract: In a construction machine wherein a cab is mounted on an upper frame of an upper rotating body through an anti-vibration mount, a guard member for protecting the cab in the event of a roll over of the construction machine is mounted so as to extend from a front face portion to a ceiling of the cab, and a lower end of a front portion of the guard member which front portion covers the front face portion of the cab is fixed to a front end portion of the upper frame by a fixing mechanism which permits movement of the cab created in both vertical and horizontal directions by the anti-vibration mount.

Abstract: A rear beam has a first beam with right and left ends welded to right and left rear supports and a second beam welded to a front surface of the first beam along the right and left direction. The second beam is welded to the first beam so that an upper end portion of the second beam is above an upper end portion of the first beam and a lower end portion of the second beam is above a lower end portion of the first beam.

Abstract: A dynamic quantity sensor includes a sensor chip, a base member, and bumps. The sensor chip includes a semiconductor substrate, a sensor part, and sensor pads electrically coupled with the sensor part. The base member includes a base substrate and base pads disposed on the base substrate. The bumps mechanically and electrically couple the sensor pads and the base pads, respectively, in a state where the sensor chip is curved with respect to the base member. The sensor pads include input pads and output pads. The first surface of the semiconductor substrate includes a first portion and a second portion. The first portion is closer to the base substrate than the second portion is. At least one of the input pads is disposed on the first portion and at least one of the output pads is disposed on the second portion.

Abstract: A working machine is provided with a pressing mechanism 40 for pressing a pressing plate 20 toward an upper frame 11, and a restricting mechanism 41 fixed to the upper frame 11 between a fuel tank 15 and the upper frame 11. The fuel tank 15 is pressed toward the upper frame 11 by the pressing mechanism 40 at a bottom surface of the fuel tank 15, whereby a lower recess 32a vertically engageable with at least a part of the restricting mechanism 41 is formed.

Abstract: The invention provides a door for a cabin in a construction machine, the door including a pulling handle portion to be pulled in a closing direction of the door from the inside of the cabin and preventing the pulling handle portion from misuse as a riding handle, the riding handle including a first gripped portion extending in a first extending direction to be gripped by an operator when the operator rides in the cabin. The door includes a cabin frame having an entrance and a riding handle projecting from an fringe portion fringing the entrance of the cabin frame in a specific direction. The door has a door frame vertically extending and a door glass to be attached to the door frame.

Abstract: Provided is a front window formed in a cabin including an upper window formed in a front face of the cabin and having a window frame with an underside portion, and a lower window disposed below the upper window so as to contact the upper window, while being capable of inhibiting condensed water from building up on the underside portion and rusting the underside portion. The upper window is provided with a glass plate having a periphery to be attached to an outer face of the window frame, defining a clearance between the underside portion and the glass plate to let out the condensed water generated on an inner face of the glass plate downwardly from the underside portion.

Abstract: An exhaust-gas purification device disposition structure of a vehicle, comprises a fuel tank with a fuel supply port which is disposed so as to be open to an outside of a vehicle compartment, and a urea tank to accommodate urea water solution as deoxidizer to purify exhaust gas. The urea tank is disposed outside the vehicle compartment, and a pouring port of the urea tank is provided inside the vehicle compartment. Accordingly, the urea water solution can be surely prevented from entering into the vehicle compartment even in case of the breakage of the urea tank, and the mistake of supplying the wrong liquid into the wrong supply (pouring) port tank which may be made by confusing the ports can be avoided.

Abstract: A reinforced structure for a cabin of a working machine is disclosed, which comprises a cabin, a boom installed along the cabin, and a reinforcing member provided for the cabin. The cabin includes front pillars, upper pillars and rear pillars. The reinforcing member includes a first member located longitudinally between upper ends of the front and rear pillars located on the working apparatus side of the cabin, the first member being fixed to the upper pillar located on the same side, and a second member, one end of the second member being fixed to an intermediate position of the first member, and the other end thereof being fixed to the other upper pillar.

Abstract: In a construction machine wherein a cab is mounted on an upper frame of an upper rotating body through an anti-vibration mount, a guard member for protecting the cab in the event of a roll over of the construction machine is mounted so as to extend from a front face portion to a ceiling of the cab, and a lower end of a front portion of the guard member which front portion covers the front face portion of the cab is fixed to a front end portion of the upper frame by a fixing mechanism which permits movement of the cab created in both vertical and horizontal directions by the anti-vibration mount.