Abstract: Silica-containing substrates including vias with a narrow waist, electronic devices incorporating a silica-containing substrate, and methods of forming vias with narrow waist in silica-containing substrates are disclosed. In one embodiment, an article includes a silica-containing substrate including greater than or equal to 85 mol % silica, a first surface, a second surface opposite the first surface, and a via extending through the silica-containing substrate from the first surface toward the second surface. The via includes a first diameter at the first surface wherein the first diameter is less than or equal to 100 ?m, a second diameter at the second surface wherein the first diameter is less than or equal to 100 ?m, and a via waist between the first surface and the second surface. The via waist has a waist diameter that is less than the first diameter and the second diameter such that a ratio between the waist diameter and each of the first diameter and the second diameter is less than or equal to 75%.

Abstract: Articles and semiconductor packages that incorporate glass-based substrates are disclosed, as well as methods of forming thereof. An article includes a glass-based substrate comprising first and second major surfaces spaced a distance from and parallel to each other, and a tapered via extending through the substrate. The tapered via includes a cross section that is symmetrical about a plane that is between and equidistant to the first and second major surfaces of the glass-based substrate and an interior wall with a first tapered region and a second tapered region positioned between the first major surface and the plane. The respective slopes of the first and second tapered regions are constant and the slope of the first tapered region is not equal to the slope of the second tapered region.

Abstract: A patterned article that includes: an alkali silicate glass substrate comprising a thickness and a primary surface, the substrate having a bulk composition; a patterned region defined by at least a portion of the primary surface; and a compressive stress region that extends from the at least a portion of the primary surface to a first depth within the substrate. The patterned region comprises a surface roughness (Ra) from about 1 nm to about 600 nm and at least one of a plurality of protrusions and a plurality of depressions. Further, each of the compressive stress region and the patterned region comprises a concentration of at least one alkali metal ion that is different than the concentration of the at least one alkali metal ion in the bulk composition.

Abstract: A chemical ion exchange process, including: dissolving a carbonate salt in a molten salt bath disposed in a furnace and including a non-lithium non-carbonate alkali salt; immersing a lithium-containing glass-based substrate in the molten salt bath including the dissolved carbonate salt and the non-lithium non-carbonate alkali salt, where immersing the lithium-containing glass-based substrate in the molten salt bath results in an ion-exchange between the lithium-containing glass-based substrate and the molten salt bath and results in the formation of a lithium-containing carbonate salt in the molten salt bath; and reducing a concentration of the lithium-containing carbonate salt in the molten salt bath or increasing a solubility limit of the lithium-containing carbonate salt in the molten salt bath.

Abstract: An article includes a substrate; a first layer disposed on the first major surface of the substrate, wherein the first layer has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17; and at least one ink layer disposed on the first layer having a surface roughness Ra greater than or equal 50 nm to provide a textured surface. Also disclosed is an article a substrate a coating disposed on the first major surface, wherein the coating has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set, a gauge hardness greater than or equal to 4H according to a pencil test, and a scratch hardness greater than or equal to 3H according to a pencil test set.

Abstract: Methods and apparatus provide for an improved visual and optionally tactile features on a visible element of an article, such as a consumer electronic device (e.g., a mobile electronic device, a mobile phone, a smartphone, a tablet, a phablet, a notebook computer, a laptop, etc.).

Abstract: Embodiments of anti-glare substrates and articles including the same are disclosed. In one or more embodiments, the anti-glares substrate includes a textured surface with a plurality of features having an average cross-sectional dimension of about 30 micrometers or less. The substrate or article exhibits a transmission haze of 10% or less, a PPDr of about 7% or less or 6% or less, and a DOI of about 80 or less. Method for forming the anti-glare substrates are also disclosed and include etching a surface of a substrate with an etchant having low water solubility to provide an etched surface, and removing a portion of the etched surface. The method includes generating a plurality of insoluble crystals (e.g., any one or more of K2SiF6 and K3AlF6) on the surface while etching the surface. The etchant may include a potassium salt, an organic solvent and a fluoride containing acid.

Abstract: Polymer-based portions comprise an index of refraction ranging from about 1.49 to about 1.55. In some embodiments, the polymer-based portion comprises the product of curing 45-75 wt % of a difunctional urethane-acrylate oligomer with 25-55 wt % of a difunctional cross-linking agent and optionally a reactive diluent. In some embodiments, the polymer-based portion comprises the product of curing 75-100 wt % of a reactive diluent and optionally one or more a difunctional urethane-acrylate oligomer and/or a difunctional cross-linking agent. Adhesives comprise an index of refraction ranging from about 1.49 to about 1.55. In some embodiments, the adhesive comprises the product of heating 10-35 wt % of a silane-hydride-terminated siloxane and 65-90 wt % of a vinyl-terminated siloxane. In some embodiments, the adhesive comprises the product of irradiating a thiol-containing siloxane and a photo-initiator with at least one wavelength of light that the photo-initiator is sensitive to.

Abstract: Foldable apparatus can comprise a foldable substrate comprising a thickness (T) and a plurality of grooves extending through a first major surface. A groove spacing (Gs) is defined between a pair of grooves. A first groove of the plurality of grooves comprises a groove depth (Gd) and a groove width (Gw). In some embodiments, 7.93-6.19*(Gw/T) ?9.52*(Gd/T) +6.05*(Gs/T) <0. In some embodiments, (Gw/T) ?0.1, (Gs/T) ?1.5, 0.3?Gd/T 0.95. In some embodiments, a combined groove volume divided by a central volume can be about 0.3 or more. Methods of making a foldable apparatus comprise drawing a ribbon from a quantity of molten material off a forming device. Methods further comprising impinging a target location of the ribbon traveling in a draw direction with a laser beam to form a groove in the ribbon. In some embodiments, the groove can comprise a plurality of grooves.

Abstract: A glass article is provided that includes: a glass substrate comprising a thickness and a primary surface; and a textured region defined by the primary surface. The textured region comprises a low spatial frequency region and a high spatial frequency region substantially superimposed within the low spatial frequency region. Further, the low spatial frequency region comprises an average lateral feature size that exceeds an average lateral feature size of the high spatial frequency region. In addition, the textured region comprises a surface roughness (Ra) from about 10 nm to about 1000 nm.

Abstract: Glass-based articles comprise stress profiles providing improved scratch resistance. The glass-based articles comprise: a thickness t; a lithium aluminosilicate composition; and a molar ratio of sodium oxide (Na2O) to lithium oxide (Li2O) that is less than or equal to 0.63 at the center of the glass-based article. The articles have a molar ratio of sodium dioxide (Na2O) to lithium dioxide (Li2O) in a post-spike near region that is greater than or equal to 0.9 and/or less than 1.5.

Abstract: Embodiments of an electronic device comprising an enclosure and electrical components disposed at least partially inside the enclosure, wherein the enclosure comprises a substrate having a tactile surface are disclosed. The tactile surface may include a textured surface, a coated surface or a coated textured surface that exhibits a low fingerprint visibility, when a fingerprint is applied to the tactile surface. In one or more embodiments, the substrate exhibits an average transmittance of about 80% or greater over the visible spectrum, a coefficient of friction less than about 0.3, a surface roughness Ra of about 500 nm or greater, and either one or both a transmission haze greater than about 60%, and a reflection haze at either 2 degrees from specular or 5 degrees from specular greater than 60%.

Abstract: An article is described herein that includes: a glass, glass-ceramic or ceramic substrate comprising a primary surface; at least one of an optical film and a scratch-resistant film disposed over the primary surface; and an easy-to-clean (ETC) coating comprising a fluorinated material that is disposed over an outer surface of the at least one of an optical film and a scratch-resistant film. The at least one of an optical film and a scratch-resistant film comprises an average hardness of 10 GPa or more. Further, the outer surface of the at least one of an optical film and a scratch-resistant film comprises a surface roughness (Rq) of less than 1.0 nm.

Abstract: An article includes a substrate; a first layer disposed on the first major surface of the substrate, wherein the first layer has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17; and at least one ink layer disposed on the first layer having a surface roughness Ra greater than or equal 50 nm to provide a textured surface. Also disclosed is an article a substrate a coating disposed on the first major surface, wherein the coating has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set, a gauge hardness greater than or equal to 4H according to a pencil test, and a scratch hardness greater than or equal to 3H according to a pencil test set.

Abstract: Methods of etching an inorganic layer on a glass substrate are described, the methods comprising contacting the glass substrate including an inorganic layer with an etching solution comprising a polar organic solvent and an etchant, wherein the inorganic layer is removed at an inorganic layer etching rate and the glass substrate is etched as a glass etching rate.

Abstract: A method is described herein of making a textured glass article where the method includes: providing a glass substrate having an initial primary surface and an opposing primary surface; disposing a protective coating on at least one of the initial primary surface or the opposing primary surface; and etching the glass substrate with a hydrofluoric acid-free etchant having a pH of about 7 or less to form a leached layer in the glass substrate.

Abstract: Methods of manufacturing a glass-based article comprise: after mechanical polishing of a glass-based substrate, treating at least one surface of the glass-based substrate for protection of the at least one surface from contamination and/or for removal of contaminants from the at least one surface by a treatment other than ultrasonic cleaning; and exposing the glass-based substrate to an ion exchange treatment after the treating step to form the glass-based article. The treating step includes: exposing the at least one surface to a high pH soaking for removal of contaminants; deionizing the at least one surface for removal of contaminants; and/or applying a temporary coating to the at least one surface for protection of the at least one surface from contamination, and removing the temporary coating prior to the ion exchange treatment step. The ion exchange treatment may comprise a molten salt bath having an increased pH and temperature.

Abstract: A glass article is provided that includes: a glass substrate comprising a thickness and a primary surface; and a textured region defined by the primary surface. The textured region comprises a plurality of sub-surface hillocks, each hillock having a top surface and a base, the base located below the primary surface of the substrate. The plurality of hillocks comprises an average lateral feature size from 0.1 ?m to 3 ?m and an average height from 5 nm to 200 nm. Further, the primary surface of the substrate is substantially planar.

Abstract: A method of etching a substrate comprises: contacting a substrate having a thickness with an etchant disposed in a vessel for a period of time until the thickness has reduced by at least 2 ?m and at an average rate of 1 ?m per minute to 6.7 ?m per minute, the etchant having a temperature of 170° C. to 300° C. and comprising a molten mixture of two or more alkali hydroxides; and ceasing contacting the substrate with the etchant. The etchant in some instances comprises a molten mixture of NaOH and KOH. For example, the etchant in some instances includes a molten mixture of 24 wt. % to 72 wt. % NaOH, and 76 wt. % to 28 wt. % KOH. In some instances, the method alters the weight percentage of Na+, K+ and Li+ in the composition of the surface of the substrate by less than 1%.

Abstract: Methods for regenerating poisoned salt bath comprising providing a salt bath comprising at least one of KNO3 and NaNO3, providing an ion-exchangeable substrate comprising lithium cations, contacting at least a portion of the ion-exchangeable substrate with the salt bath, whereby lithium cations in the salt bath diffuse from the ion-exchangeable substrate and are dissolved in the salt bath, and selectively precipitating dissolved lithium cations from the salt bath using phosphate salt. The methods further include preventing or reducing the formation of surface defects in the ion-exchangeable substrate by preventing or reducing the formation of crystals on the surface of the ion-exchangeable substrate upon removal from the salt bath.