CREEP-RESISTANT MAGNESIUM ALLOY
The present invention relates to a magnesium aluminum alloy with enhanced creep resistance. The alloy contains barium and calcium in low proportions, and possesses a higher creep resistance in comparison to alloys containing rare earth elements. The alloy may additionally include zinc, tin, lithium, manganese, yttrium, neodymium, cerium and/or praseodymium in proportions of up to 7% by weight, respectively.
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The present invention relates to a creep-resistant magnesium alloy.
BACKGROUND AND PRIOR ARTMetal alloys containing magnesium are used extensively in the automotive industry, electronic industry, aerospace industry and several other technical areas. Those alloys are especially advantageous, which are high temperature creep-resistant and therefore usable in a high temperature environment.
Several different magnesium alloys have been developed and standardized, such as the magnesium alloys JIS H 5203 (MC1-MC10) and JIS H 5303 (MDC1A, MDC1B). Alloy A having the composition Mg-4% Al-2% RE (RE=rare earth elements), which has been developed by the company Dow Chemical, is also well known for high temperature use.
However, such heat-resistant magnesium alloys are quite inapplicable in casting, wherein the metal object must be cooled rapidly after shaping.
DE 44 46 898 A1 discloses creep-resistant magnesium alloys, containing: 1.5 to 10% by weight of aluminum (Al), less than 2% by weight of rare earth elements (RE), 0.25 to 5.5% by weight of calcium (Ca), the balance being magnesium. In addition, the alloy may contain 0.2 to 2.5% by weight of copper and/or zinc.
The rare earth elements contained in such alloys, however, increase the costs of the alloy.
DE 22 01 460 A1 also discloses creep-resistant magnesium alloys containing aluminum and optionally an additional element selected from calcium, zirconium, titanium, silicon, strontium, yttrium, cerium or barium. Barium and calcium in combination are not disclosed as additional elements.
SUMMARYIt is therefore the object of the present invention to provide a magnesium alloy, which is able to overcome the above mentioned disadvantages of the state of the art and, moreover, has a higher creep resistance.
The object is solved by a metal alloy containing magnesium or magnesium alloy, containing 1 to 9% by weight of aluminum (Al), 0.5 to 5% by weight of barium (Ba), 0.5 to 5% by weight of calcium (Ca), the balance being magnesium (Mg) and inevitable production-related impurities, based on the total weight of the alloy. Preferably, the inevitable production-related impurities amount in total to no more than 2% by weight, based on the total weight of the alloy. The proportion of aluminum is preferably 2 to 7% by weight, more preferably 3 to 6% by weight. The proportion of barium is preferably 1 to 4% by weight, more preferably 1.5 to 3% by weight. The proportion of calcium is preferably 1 to 4% by weight, more preferably 1.5 to 3% by weight.
The magnesium alloy of the invention may additionally include zinc, tin, lithium, manganese, yttrium, neodymium, cerium and/or praseodymium in proportions of up to 7% by weight, respectively.
The magnesium alloy of the invention may be used in a multiplicity of application areas; preferably it is used in the production of components for automotives, vessels and/or aeroplanes, more preferably in the production of power trains and components thereof.
The drawing is a graph showing creep deformation as a function of time for two magnesium alloys of the invention.
The invention is further illustrated with reference to the attached FIGURE. In
The inventive alloys have a considerably lower creep deformation than the respective comparison alloys. This leads to the conclusion that, with constant strain, the temperature may be increased even further, or that a component may be strained for considerably prolonged times.
Claims
1. Magnesium alloy, containing the following ingredients, based on total weight of the alloy:
- 1 to 9% by weight of aluminium
- 0.5 to 5% by weight of barium
- 0.5 to 5% by weight of calcium and
- the balance being magnesium.
2. The magnesium alloy according to claim 1, characterized in that it additionally includes zinc, tin, lithium, manganese, yttrium, neodymium, cerium and/or praseodymium in proportions of up to 7% by weight, respectively.
3. The magnesium alloy according to claim 1, characterized in that the proportion of aluminum is 2 to 7% by weight.
4. The magnesium alloy according to claim 1, characterized in that the proportion of barium is 1 to 4% by weight.
5. The magnesium alloy according to claim 1, characterized in that the proportion of calcium is 1 to 4% by weight.
6. A method for the production of components of automotives, vessels and/or airplanes, comprising making the components from the magnesium alloy of claim 1.
7. A method for the production of power trains or components thereof, comprising making the components from the magnesium alloy of claim 1.
8. The magnesium alloy according to claim 1, characterized in that the proportion of aluminum is 3 to 6% by weight.
9. The magnesium alloy according to claim 1, characterized in that the proportion of barium is 1.5 to 3% by weight.
10. The magnesium alloy according to claim 2, characterized in that the proportion of barium is 1.5 to 3% by weight.
11. The magnesium alloy according to claim 1, characterized in that the proportion of calcium is 1.5 to 3% by weight.
12. The magnesium alloy according to claim 2, characterized in that the proportion of calcium is 1.5 to 3% by weight.
13. The magnesium alloy according to claim 3, characterized in that the proportion of calcium is 1.5 to 3% by weight.
14. A method for the production of components of automotives, vessels and/or airplanes, comprising making the components from the magnesium alloy of claim 2.
15. A method for the production of components of automotives, vessels and/or airplanes, comprising making the components from the magnesium alloy of claim 3.
16. A method for the production of components of automotives, vessels and/or airplanes, comprising making the components from the magnesium alloy of claim 4.
17. A method for the production of components of automotives, vessels and/or airplanes, comprising making the components from the magnesium alloy of claim 5.
18. A method for the production of power trains or components thereof, comprising making the components from the magnesium alloy of claim 2.
19. A method for the production of power trains or components thereof, comprising making the components from the magnesium alloy of claim 3.
20. A method for the production of power trains or components thereof, comprising making the components from the magnesium alloy of claim 4.
Type: Application
Filed: Aug 13, 2009
Publication Date: Mar 4, 2010
Applicant: Gkss-Forschungszentrum Geesthacht GmbH (Geesthacht)
Inventors: HAJO DIERINGA (Sudergellersen), Norbert Hort (Luneburg), Karl U. Kainer (Hohnstorf)
Application Number: 12/540,581
International Classification: C22C 23/02 (20060101); C22C 30/00 (20060101); C22C 30/04 (20060101);