Environmental air sterilization system

- BOC, Inc.

The present invention is a high volume, wall-mountable air sanitation apparatus for disinfecting and removing VOCs from air with high energy UV light and ozone. The apparatus has a powerful fan and an elongated UV light source and target for use with the movement of a large volume of air. The target includes a mesh and a secondary target both comprising a target compound which creates hydro-peroxides, super oxide ions and hydroxyl radicals in the presence of water also for removing pollutants in the air.

Skip to: Description  ·  Claims  ·  References Cited  · Patent History  ·  Patent History
Description
BACKGROUND OF INVENTION Field of Invention

This invention relates to an air treatment apparatus, and more particularly to a wall-mountable, high volume air treatment apparatus for the removal of contaminants such as pollutants, organisms and odors from air.

Airborne pollutants, organisms and odors are all major concerns in indoor air quality assessment. Solid pollutants such as dust or other particulates may be removed by a filtering mechanism. However, organic compounds and organisms in the atmosphere are more difficult to remove by filter, and need a very fine filter or other specialized equipment. Chemicals and bactericidal agents are known in the prior art to combat airborne organisms. Deodorants are known in the art to mask odors that may be found in the indoor air, but they do nothing to actually eliminate those odors. Unfortunately, chemicals and bactericidal agents must be replaced regularly and are not always effective in the elimination of the pollutants and organisms. In fact, the misuse of bactericidal agents may actually cause the mutation of the bacteria into strain resistant to that agent.

The use of ozone is commonly known in the prior art for freshening air and removing odors. Ozone is generated by a variety of methods. One known method is to subject air to high intensity UV light, such as that at approximately 185 nm. The flow of oxygen over the UV light, and the dimensions of the light, and the intensity of the light are known to be important factors in generating ozone, because it is commonly known that high concentrations of ozone are undesirable for humans. In fact, most literature teaches away from the use of high intensity UV light to treat air because of the danger to humans. Systems known in the art which use ozone to freshen air and remove odors do not effectively remove organic pollutants and organisms. Moreover, these systems are incapable of handling large volumes of air.

Hydro peroxides, super-oxide ions and hydroxyl radicals are known to oxidize volatile organic compounds (VOCs). These radicals and ions also kill and decompose airborne bacteria and other airborne organisms. This process is known as heterogeneous photocatalysis or photocatalytic oxidation (PCO). PCO is particularly desirable for treating VOCs because these materials are oxidized and are therefore eliminated rather than merely captured or removed from the airstream. Thus PCO is preferable to a filter mechanism, because filters must be replaced or cleaned regularly. PCO reactors also have low power consumption, long service life and low maintenance requirements. Also, a filtration system would be expensive and impractical for the cleansing of large volumes of air. Moreover, using several small units for freshening air would be overly expensive and still would not efficiently cleanse a large volume of air.

Thus, there is no viable apparatus for effectively freshening air and removing odors from a large volume of air.

There is also no wall-mounted apparatus that could effectively freshen air and remove odors.

There is no effective means for freshening a large volume of air that safely and efficiently uses ozone, hydro peroxides, super oxide ions and hydroxyl radicals.

It is, therefore, to the effective resolution of the aforementioned problems and shortcomings of the prior art that the present invention is directed.

However, in view of the prior art at the time the present invention was made, it was not obvious to those of ordinary skill in the pertinent art how the identified needs could be fulfilled.

SUMMARY OF INVENTION

The present invention comprises A high volume, wall-mountable air sanitation apparatus for disinfecting and removing VOCs from air with an elongated high energy UV light source and ozone, comprising a casing, a means for moving air, the air moving across at least one elongated target comprising a target compound, said target compound comprising at least one selected from the group consisting of titanium dioxide, copper and silver; and a high energy UV light source adapted to direct UV light toward the air and the target whereby the UV striking the air and the target will generate at least one selected from the group of hydro-peroxides, super-oxide ions and hydroxyl radicals. It is preferred that the target compound further comprises approximately 0-30% titanium dioxide, 0-30% silver, and 0-30% copper, by weight. It is also preferred that the target compound further comprises a hydration compound of silica gel.

The preferred shape of the target is a mesh at least partially located between the UV light source and the air. The UV light source emits UV light at a wavelength of approximately 185 nm. In the preferred embodiment, the UV light source emits UV light at between 185 nm and 254 nm. In an alternative embodiment, the target further comprises a secondary element located a predetermined distance from the wire mesh, whereby at least a portion of the UV light coming through the mesh strikes the secondary element. It is also preferred that the secondary element is made of a target compound comprising approximately 0-30% titanium dioxide, 0-30% silver, and 0-30% copper, by weight.

It is preferred that the apparatus includes a fan located in the interior of the casing. Also, a particulate filter may be included for removing particulates from the air before the air is moved over the target compound. When in use, reflected and refracted UV light is visible from the exterior of the casing through the blades of the fan.

The UV light source comprises one or more UV lights. The UV lights are preferably mercury vapor UV light sources capable of emitting between approximately 185 nm UV light and approximately 254 nm UV light. Preferably, at least one separate mesh target surrounds each UV light. However, a single mesh target may be affected by more than one UV light source.

The invention is also an apparatus for efficiently disinfecting and removing VOCs from air with high energy UV light, comprising a high energy UV light source capable of generating ozone from oxygen in air, a mesh target located at least partway between the high energy UV light source and the air, the target including a target compound comprising at least one selected from the group consisting of titanium dioxide, copper and silver, whereby the UV light and the target compound generate in the presence of water at least one selected from the group of hydro-peroxides, super-oxide ions and hydroxyl radicals; and a secondary target element located a predetermined distance from the mesh target, the secondary target element including the target compound, whereby at least a portion of the UV light that passes through the mesh target strikes the secondary target element, thereby generating additional hydro-peroxides, super-oxide ions and hydroxyl radicals to that generated by the mesh target. It is also preferred in this embodiment that the air generally flows between the mesh target and the secondary target. Also, it is preferred that the secondary target acts as a conduit for the moving air.

The preferred target compound includes a hydration compound of silica gel. The preferred UV light source is one or more mercury vapor UV lights of a predetermined geometry.

The invention is also a wall-mountable method for treating a large volume of air, comprising: directing the large volume of air toward a target comprising a target, said target comprising a compound consisting of titanium dioxide, silver and copper; and directing UV light toward the target, said the UV light being at a wavelength sufficient to generate ozone from oxygen in the air and being sufficient to generate at least one selected from the group consisting of hydro-peroxides, super-oxide ions and hydroxyl radicals from interaction with the compound in the presence of water.

In this method, the target may be solely a mesh located generally between the air and the UV light. Alternatively, the target may include a secondary element located a predetermined distance from the mesh whereby the air generally passes between the mesh and the secondary element and UV light passing through the mesh strikes the secondary target element, thereby generating additional hydro-peroxides, super-oxide ions and hydroxyl radicals to that generated by the mesh target.

It is therefore an object of the present invention to provide a viable apparatus for effectively freshening air and removing odors from a large volume of air.

It is another object of the present invention to provide a wall-mounted apparatus that could effectively freshen air and remove odors.

It is another object of the present invention to provide an apparatus and a method for freshening a large volume of air that safely and efficiently uses ozone, hydro-peroxides, super oxide ions, hydroxyl radicals and UV radiation.

It is to be understood that both the foregoing general description and the following detailed description are explanatory and are not restrictive of the invention as claimed. The accompanying drawings, which are incorporated in and constitute part of the specification, illustrate embodiments of the present invention and together with the general description, serve to explain principles of the present invention.

These and other important objects, advantages, and features of the invention will become clear as this description proceeds.

The invention accordingly comprises the features of construction, combination of elements, and arrangement of parts that will be exemplified in the description set forth hereinafter and the scope of the invention will be indicated in the claims.

BRIEF DESCRIPTION OF DRAWINGS

For a fuller understanding of the nature and objects of the invention, reference should be made to the following detailed description, taken in connection with the accompanying drawings, in which:

FIG. 1 is a top perspective view of the preferred embodiment of the invention.

FIG. 2a is a top view of a cover plate of the invention.

FIG. 2b is a side view of a cover plate of the invention.

FIG. 2c is an end view of the lip of the cover plate.

FIG. 3a is a top view of a top panel of the invention.

FIG. 3b is a side view of a top panel of the invention.

FIG. 3c is an end view of a top panel of the invention.

FIG. 4a is a top view of a bottom panel of the invention.

FIG. 4b is a side view of a bottom panel of the invention.

FIG. 4c is an end view of a bottom panel of the invention.

FIG. 5a is a top view of a chassis of the invention.

FIG. 5b is a side view of a chassis of the invention.

FIG. 5c is an end view of a chassis of the invention.

FIG. 6a is a side view of a mesh target of the invention.

FIG. 6b is an end view of a mesh target of the invention.

FIG. 7a is a top view of a lamp support tray of the invention.

FIG. 7b is a side view of a lamp support tray of the invention.

FIG. 7c is an end view of a lamp support tray of the invention.

FIG. 8a is a top plan partially cut away view of the invention.

FIG. 8b is an end plan view of the invention.

FIG. 9 is a front plan partially cut away view of the invention.

FIG. 10 is a bottom plan partially cut away view of the invention.

FIG. 11 is a perspective partially cut away view of an alternative embodiment of the invention.

DETAILED DESCRIPTION

FIG. 1 shows the present invention: a high volume, wall-mountable air sanitation apparatus for disinfecting and removing VOCs from air with high energy UV light and ozone, shown generally as 10. The invention has a casing 12 mountable onto a wall. It is preferred that the casing 12 comprise a chassis 14, a top panel 16 a front panel 18, and a bottom panel 20, shown in detail in FIGS. 2-5. Other geometries for the casing 12 may alternatively be used. In addition, the casing 12 preferably comprises an air intake grill panel 24 on one side and an air exhaust grill panel 26 on the other side. However, the air intake grill panel 24 and the air exhaust grill panel 26, as well as the air intake and exhaust functions described herein, may be reversed. As shown, each of the panels to the casing 12 and the chassis 14 has points 22 for attachment, so the casing may be assembled. The panels and chassis may be attached by screws, bolts, friction or other means known in the art. The chassis 14 and panels are preferably made from a rigid material to withstand the stresses of the movement of a high volume of air, such as stainless steel. In addition, the chassis 14 and the panels are preferably assembled so that the interior of the apparatus 10 may be accessed while the apparatus 10 is attached to a wall. Other means for forming a casing 12, such as a removable one-piece cover over the chassis 14 may be preferable.

FIGS. 8a and 8b, a removable filter 32 may be placed within the casing 12 inside the air intake grill panel 24. For added sanitization of the air moving through the casing 12, a second removable filter 34 may also be placed within the casing 12 in front of the air exhaust grill panel 26. The second removable filter 34 also aids in shielding any UV light that may otherwise be emanating from the apparatus 10. However, in an alternative embodiment, some reflected or refracted UV light may be observable from outside the apparatus 10. A high-pressure fan 28 is placed within the casing 12 to move air through the apparatus 10. The fan 28 is mounted into the casing 12 by a mounting bracket 30 as shown in FIGS. 8-10. Preferably, the fan 28 moves sufficient air so that the apparatus 10 is capable of sanitizing the air in a room of approximately 200,000 square feet, or more.

As FIG. 8a, attached to the bottom panel 20 is a lamp support tray 36. The preferred geometry of the lamp support tray 36 is provided in FIGS. 7a-7c. However, depending upon the geometry of the casing 12 and of the light source used, other geometries may be used and may be preferred. It is preferred that the lamp support tray 36 is made of a rigid material like a metal such as stainless steel. Alternatively, lamp brackets may be mounted within the apparatus to house the elongated UV light sources 40. The lamp support tray 36 or lamp brackets may be attached by being bolted, welded or screwed to the bottom panel 20, or other means known in the art.

As in FIGS. 8 and 9, attached to the lamp support tray 36 are one or more ballast circuits 38 in electronic communication with one or more elongated UV light sources 40. Preferably, the UV light source 40 is a low-pressure mercury vapor lamp. However, medium pressure mercury lamps and other equivalent UV light sources are known in the art. The UV light source 40 preferably emits at least some UV light of approximately 185 nm. In the preferred embodiment, the UV light source 40 is a combination UV light source capable of emitting between approximately 185 nm and approximately 254 nm UV light. Also, as shown in FIG. 10, in the preferred embodiment the bottom panel includes a power switch 56 and an hour meter 58 to show the duration that the apparatus 10 has been active. The hour meter 58 thus helps the user to determine a schedule for maintenance.

The preferred UV light source 40 is shown generally in FIG. 11. The preferred UV light source 40, as shown, has a portion 50, which emits mostly approximately 185 nm UV light, and a portion 52, which emits mostly approximately 254 nm UV light. For the UV light source 40 shown, it is preferred that the portion of the UV light source 40 capable of emitting 185 nm UV light 50 is mounted toward the air intake grill panel 24. Thus, the concentration of ozone created by the 185 nm UV light source 40 will have at least partially dissipated when the air passes through the exhaust grill panel 26.

The elongated UV light source 40 is preferably attached to the lamp support tray 36 by means such as a 4-pin connector 42 and a lamp clip 44 that is attached to the light support tray by means such as riveting. Also as shown in FIG. 8a, attached to the bottom panel 20 is a support 60 for the fan mounting bracket 30. This support 60 allows the apparatus 10 to have a powerful fan within it for rapidly moving a large volume of air. As shown in FIGS. 8-10, the UV light sources 40 may be arranged in a rectangular geometry. However, other geometries may be preferred, such as triangular, hexagonal or circular, depending upon the number and size of UV light sources used.

Around each UV light source 40 is preferably a mesh target 46. The preferred geometry of the mesh target 46 is illustrated in FIGS. 6a and 6b; however, other geometries may be used, depending upon the size, shape and intensity of the UV light source used the amount of interaction with the UV light desired by the user. The mesh target 46 allows part of the UV light reaching the mesh target 46 to pass through it. The mesh target 46 preferably comprises a target compound. However, it may also comprise a UV transparent material. The target compound is preferably comprised of a combination of titanium dioxide, copper and silver formed in a hydration compound of silica gel. It is preferred that the target compound is approximately 0-30% titanium dioxide, 0-30% silver, and 0-30% copper by weight. Air that is pushed by the fan passes over the UV light source 40 and the mesh target 46. The UV light interacts with the oxygen in the air to form ozone, which destroys biological pollutants in the air. In addition, in the presence of water, the UV light interacts with the target compound to form hydro-peroxides, super oxide ions and hydroxyl radicals, which combine with VOCs in the air passing through the apparatus 10, thereby reducing the VOCs where the apparatus is used. In addition, the UV light itself destroys biological pollutants in the air.

The ambient humidity may provide the apparatus with enough water to form the hydro-oxides, super oxide ions and hydroxyl radicals. However, in an alternative embodiment, the emitted UV light also interacts with the target compound in the mesh target 46 in the presence of a mist of water supplied by a mister to form the hydro peroxides ions, super oxide ions and hydroxide radicals that act to neutralize VOCs and other organic pollutants in the air passing through the apparatus 10. In an alternative embodiment, illustrated in FIG. 11, a mister 54 is attached to the apparatus 10. The creation of the hydro peroxides ions, super oxide ions and hydroxide radicals is optimized where the mist from the mister 54 is introduced into the apparatus 10 approximately after the intake fan 28 and approximately before the 185 nm emitting portion of the UV light source 50. It is preferred that the mister 54 uses high purity water to prevent contamination of the apparatus 10 or the addition of pollutants into the air. In addition, it is preferred that the mist is formed by ultrasonically agitating a reservoir of ultra pure water. In the preferred embodiment the mister 54 also includes a baffle to prevent large droplets or splashing of the water in the reservoir from entering the apparatus 10. In addition, a manually or mechanically controlled flow controller for the mister 54 to control the amount of mist entering the apparatus 10 is preferred.

Also in an alternative embodiment, several layers of mesh target 46 are used so that air flows between the layers of mesh targets 46. This configuration increases the efficiency of the use of the target compound with the UV light.

In yet another embodiment, a secondary target 48 comprising target compound is placed a predetermined distance from the mesh target 46 so that UV light passing through the mesh target 46 strike the secondary target 48. Thus, increased ozone and hydro peroxide and super oxide ions are produced in the air stream passing generally between the mesh target 46 and the secondary target 48.

The secondary target 48 may be target compound formed on the inside surface of the casing 12. In an alternative embodiment, as illustrated in FIG. 11, the UV light source 40 may be surrounded by the mesh target 46. The secondary target 48 is located a predetermined distance from the mesh target 46. Consideration of the UV light intensity, the length of the path of the air over the UV light and mesh target, and the speed and volume and components of the air passing over the mesh is made in determining the distance of the secondary target 48 from the mesh target 46. It is preferred that the secondary target, as well as the mesh, surrounds the UV light source 40 completely for optimum efficiency. Moreover, to ensure optimum efficiency, it is preferred that the secondary target 48 itself acts as a conduit for the moving air. However, the mesh target 46 and the secondary target 48 may alternatively only partly surround the UV light source. While it is shown in FIG. 11 that the mister introduces the mist between the mesh target 46 and the secondary target 48, other configurations for the introduction of the mist are contemplated.

It will be seen that the objects set forth above, and those made apparent from the forgoing description, are efficiently attained and since certain changes may be made in the above construction without departing from the scope of the invention, it is intended that all matters contained in the foregoing description or shown in the accompanying drawings shall be interpreted as illustrative and not in a limiting sense.

It is also to be understood that the following claims are intended to cover all of the generic and specific features of the invention herein described, and all statements of the scope of the invention, which, as a matter of language, might be said to fall therebetween. Now that the invention has been described,

Claims

1. A high volume, wall-mountable air sanitation apparatus for removing contaminants such as pollutants, organisms and odors from air with high energy UV light and ozone, comprising:

a casing with an interior, a first side and a second side;
means for moving air located at the first side of the casing, the air moving across at least one target comprising a target compound, said target compound comprised of titanium dioxide, in combination with at least one selected from the group consisting of up to about 30% by weight copper and up to about 30% by weight silver; and
an elongated high energy UV light source adapted to direct UV light toward the air and the target, whereby the UV light striking the air and the target in the presence of water will generate at least one oxidant selected from the group consisting of hydro-peroxides, super-oxide ions and hydroxyl radicals.

2. The apparatus of claim 1, wherein the target compound is up to about 30% by weight titanium dioxide, and further comprises a hydration compound of silica gel.

3. The apparatus of claim 1, wherein the target comprises a mesh at least partially located between the UV light source and the air.

4. The apparatus of claim 3, wherein the target further comprises a secondary element located a predetermined distance from the mesh, whereby at least a portion of the UV light coming through the mesh strikes the secondary element.

5. The apparatus of claim 4, wherein the secondary element comprises a secondary target compound comprised of titanium dioxide, in combination with at least one selected from the group consisting of up to about 30% by weight copper and up to about 30% by weight silver.

6. The apparatus of claim 1, wherein the elongated high energy UV light source emits UV light at a wavelength of approximately 185 nm to 254 nm.

7. The apparatus of claim 1, wherein the means for moving air comprises a fan located in the interior of the casing.

8. The apparatus of claim 7, wherein UV light may be visible from an exterior of the casing, whereby a person may observe whether the UV light source within the apparatus is operating.

9. The apparatus of claim 1, further comprising at least a first particulate filter operatively associated with the casing for removing particulates from the air before the air is moved over the target compound.

10. The apparatus of claim 1, wherein the UV light source comprises at least one low-pressure mercury UV light.

11. The apparatus of claim 10, comprising at least one mesh target disposed to surround each low-pressure mercury UV light.

12. The apparatus of claim 11, wherein each of the at least one mesh target may be affected by more than one UV light source.

13. A wall mountable method for treating air, comprising:

directing the air toward a target comprising a target compound, said target compound comprised of titanium dioxide, in combination with at least one selected from the group consisting of up to about 30% by weight silver and up to about 30% by weight copper;
directing UV light toward the target, said UV light being at a wavelength sufficient to generate ozone from oxygen in air and to generate at least one oxidant selected from the group consisting of hydro-peroxides, super-oxide ions and hydroxyl radicals from interaction with the compound in the presence of water.

14. An apparatus for efficiently removing contaminants such as pollutants, organisms and odors from air with high energy UV light, comprising:

a high energy UV light source capable of generating ozone from oxygen in air;
a mesh target located between the high energy UV light source and the air to be treated, the mesh target including a target compound, said target compound comprised of titanium dioxide, in combination with at least one selected from the group consisting of up to about 30% by weight copper and up to about 30% by weight silver, wherein UV light and the target compound generate in the presence of water at least one oxidant selected from the group consisting of hydro-peroxides, super-oxide ions and hydroxyl radicals; and
a secondary target element located a predetermined distance from the mesh target, the secondary target element including a secondary target compound, said secondary target compound comprised of titanium dioxide, in combination with at least one selected from the group consisting of up to about 30% by weight copper and up to about 30% by weight silver, wherein at least a portion of the UV light that passes through the mesh target strikes the secondary target element, thereby generating an additional oxidant selected from the group consisting of hydro-peroxides, super-oxide ions and hydroxyl radicals.

15. The apparatus of claim 14, wherein the air generally flows between the mesh target and the secondary target element.

16. The apparatus of claim 15, wherein the target compound further comprises a hydration compound of silica gel.

17. The apparatus of claim 14, wherein the secondary target element acts as a conduit for the air.

18. The apparatus of claim 14, wherein the high energy UV light source comprises at least one low-pressure mercury UV light.

19. A wall mountable method for treating a large volume of air, comprising:

directing the large volume of air toward a target, said target comprising a target compound, said target compound comprised of titanium dioxide, in combination with at least one selected from the group consisting of copper and silver; and
directing UV light toward the target, said UV light being at a wavelength sufficient to generate ozone from oxygen in the air and being sufficient to generate at least one oxidant selected from the group consisting of hydro-peroxides, super-oxide ions and hydroxyl radicals from interaction with the compound in the presence of water.

20. The method of claim 19, wherein the target comprises a mesh located generally between the air and the UV light.

21. The method of claim 20, wherein the target further comprises a secondary element located a predetermined distance from the mesh, whereby the air generally passes between the mesh and the secondary element and UV light passing through the mesh strikes the secondary element in the presence of water, thereby generating an additional oxidant selected from the group consisting of hydro-peroxides, super-oxide ions and hydroxyl radicals.

Referenced Cited
U.S. Patent Documents
4028246 June 7, 1977 Lund et al.
4094237 June 13, 1978 Riordan
4323437 April 6, 1982 Mucenieks
4400270 August 23, 1983 Hillman
4427636 January 24, 1984 Obenshain
4469951 September 4, 1984 Coco et al.
4482809 November 13, 1984 Maarschalkerweerd
4534282 August 13, 1985 Marinoza
4536332 August 20, 1985 Davis et al.
4547197 October 15, 1985 Winkler
4621195 November 4, 1986 Larsson
4661264 April 28, 1987 Goudy, Jr.
4694179 September 15, 1987 Lew et al.
4766321 August 23, 1988 Lew et al.
4798702 January 17, 1989 Tucker
4872980 October 10, 1989 Maarschalkerweerd
4899056 February 6, 1990 Ellner
4899057 February 6, 1990 Koji
4922114 May 1, 1990 Boehme
4968489 November 6, 1990 Peterson
4968891 November 6, 1990 Jhawar et al.
4971687 November 20, 1990 Anderson
5006244 April 9, 1991 Maarschalkerweerd
5035784 July 30, 1991 Anderson et al.
5037618 August 6, 1991 Hager
5114670 May 19, 1992 Duffey
5141636 August 25, 1992 Flanagan et al.
5144146 September 1, 1992 Wekhof
5145515 September 8, 1992 Gallup et al.
5150705 September 29, 1992 Stinson
5166527 November 24, 1992 Solymar
5186907 February 16, 1993 Yanagi et al.
5200156 April 6, 1993 Wedekamp
5207921 May 4, 1993 Vincent
5208461 May 4, 1993 Tipton
5230792 July 27, 1993 Sauska et al.
5266215 November 30, 1993 Engelhard
5288461 February 22, 1994 Gray
5290439 March 1, 1994 Buchwald
5308505 May 3, 1994 Titus et al.
5320749 June 14, 1994 Mullen
5352359 October 4, 1994 Nagai et al.
5366705 November 22, 1994 Reidy
5368826 November 29, 1994 Weltz et al.
5393419 February 28, 1995 Tiede et al.
5401394 March 28, 1995 Markham
5413768 May 9, 1995 Stanley, Jr.
5418370 May 23, 1995 Maarschalkerweerd
5422487 June 6, 1995 Sauska et al.
5440131 August 8, 1995 Hutchison et al.
5471063 November 28, 1995 Hayes et al.
5504335 April 2, 1996 Maarschalkerweerd
5505904 April 9, 1996 Haidinger et al.
5529689 June 25, 1996 Korin
5532549 July 2, 1996 Duzyk et al.
5539209 July 23, 1996 Maarschalkerweerd
5540848 July 30, 1996 Engelhard
5547635 August 20, 1996 Duthie, Jr.
5560958 October 1, 1996 Duzyk et al.
5573666 November 12, 1996 Korin
5580461 December 3, 1996 Cairns et al.
5589132 December 31, 1996 Zippel
5590390 December 31, 1996 Maarschalkerweerd
5597482 January 28, 1997 Melyon
5611918 March 18, 1997 Markham
5612001 March 18, 1997 Matschke
5614723 March 25, 1997 Oppenländer et al.
5624573 April 29, 1997 Wiesmann
5626768 May 6, 1997 Ressler et al.
5628895 May 13, 1997 Zucholl
5655483 August 12, 1997 Lewis et al.
5656242 August 12, 1997 Morrow et al.
5660719 August 26, 1997 Kurtz et al.
5675153 October 7, 1997 Snowball
5707594 January 13, 1998 Austin
5744094 April 28, 1998 Castberg et al.
5753106 May 19, 1998 Schenck
5779912 July 14, 1998 Gonzalez-Martin et al.
5780860 July 14, 1998 Gadgil et al.
5835840 November 10, 1998 Goswami
5846437 December 8, 1998 Whitby et al.
5874740 February 23, 1999 Ishiyama
5885449 March 23, 1999 Bergmann et al.
5911910 June 15, 1999 Becraft et al.
5925320 July 20, 1999 Jones
5933702 August 3, 1999 Goswami
5937266 August 10, 1999 Kadoya
5942110 August 24, 1999 Norris
5952663 September 14, 1999 Blatchley, III et al.
5958336 September 28, 1999 Duarte
5961920 October 5, 1999 Söremark
5997812 December 7, 1999 Burnham et al.
6013917 January 11, 2000 Ishiyama
6071473 June 6, 2000 Darwin
6083387 July 4, 2000 LeBlanc et al.
6090296 July 18, 2000 Oster
6120691 September 19, 2000 Mancil
RE36896 October 3, 2000 Maarschalkerweerd
6126841 October 3, 2000 Whitby et al.
6129893 October 10, 2000 Bolton et al.
6149343 November 21, 2000 Lewis et al.
6150663 November 21, 2000 Rosenthal
6183652 February 6, 2001 Crevasse et al.
6193939 February 27, 2001 Kozlowski
6202384 March 20, 2001 Kurth et al.
6217834 April 17, 2001 Hosein et al.
6231820 May 15, 2001 Wedekamp
6248235 June 19, 2001 Scott
6261449 July 17, 2001 Scott
6264802 July 24, 2001 Kamrukov et al.
6264888 July 24, 2001 Palestro et al.
6265835 July 24, 2001 Parra
6274049 August 14, 2001 Scott
6280615 August 28, 2001 Phillips et al.
6299844 October 9, 2001 Toa et al.
6319809 November 20, 2001 Chang et al.
6328937 December 11, 2001 Glazman
6332981 December 25, 2001 Loyd
6358478 March 19, 2002 Söremark
6375833 April 23, 2002 Marston et al.
6398971 June 4, 2002 Butters et al.
6402964 June 11, 2002 Schmid
6403030 June 11, 2002 Horton, III
6404111 June 11, 2002 Kunkel
6419821 July 16, 2002 Gadgel et al.
6423763 July 23, 2002 Blasi
6436299 August 20, 2002 Baarman et al.
6447720 September 10, 2002 Horton, III et al.
6447721 September 10, 2002 Horton, III et al.
6454937 September 24, 2002 Horton et al.
6454952 September 24, 2002 Thorpe
6459087 October 1, 2002 Kaas
6461520 October 8, 2002 Engelhard et al.
6464884 October 15, 2002 Gadgil
6468419 October 22, 2002 Kunkel
6497840 December 24, 2002 Palestro et al.
6500312 December 31, 2002 Wedekamp
6500346 December 31, 2002 Taghipour et al.
6500387 December 31, 2002 Bigelow
6503401 January 7, 2003 Willis
6503447 January 7, 2003 Mondjian et al.
6534001 March 18, 2003 Michael et al.
6547963 April 15, 2003 Tsai
6565757 May 20, 2003 Wedkamp
6565803 May 20, 2003 Bolton et al.
6583422 June 24, 2003 Boehme
RE38173 July 8, 2003 Ishiyama
6589323 July 8, 2003 Korin
6589489 July 8, 2003 Morrow et al.
6589490 July 8, 2003 Parra
6599487 July 29, 2003 Luthra et al.
6602425 August 5, 2003 Drescher et al.
6605260 August 12, 2003 Busted
6610258 August 26, 2003 Strobbel et al.
20020033369 March 21, 2002 Bender
20020043504 April 18, 2002 Chen et al.
20020050479 May 2, 2002 Scott
20020070177 June 13, 2002 Kozlowski
20020081246 June 27, 2002 Tsukada et al.
20020094298 July 18, 2002 Monagan
20020098127 July 25, 2002 Bollini
20020144955 October 10, 2002 Barak et al.
20020170815 November 21, 2002 Fujii
20020172627 November 21, 2002 Aoyagi
20030010927 January 16, 2003 Wedekamp
20030019738 January 30, 2003 Reisfeld et al.
20030021721 January 30, 2003 Hall
20030035750 February 20, 2003 Neuberger
20030039576 February 27, 2003 Hall
20030049809 March 13, 2003 Kaiser et al.
20030064001 April 3, 2003 Fries et al.
20030089670 May 15, 2003 Saccomanno
20030099569 May 29, 2003 Lentz et al.
20030127603 July 10, 2003 Horowitz et al.
20030129105 July 10, 2003 Boehme
20030147770 August 7, 2003 Brown et al.
20030147783 August 7, 2003 Taylor
20030150708 August 14, 2003 Fink
20030155228 August 21, 2003 Mills et al.
20030155524 August 21, 2003 McDonald et al.
Other references
  • Copy of Webpage printed May 2, 2005 (http://www.predmaterials.com/ceramics/TitaniumDioxideC.html).
  • Copy of Webpage printed May 2, 2005 (http://www.travancoretitanium.com/products.htm).
Patent History
Patent number: 6955791
Type: Grant
Filed: Jun 14, 2002
Date of Patent: Oct 18, 2005
Patent Publication Number: 20030230477
Assignee: BOC, Inc. (Murray Hill, NJ)
Inventors: Ronald G. Fink (Jupiter, FL), Walter Ellis (Jupiter, FL), Charles Pearsall (Stuart, FL)
Primary Examiner: Steven Versteeg
Attorney: Joshua L. Cohen
Application Number: 10/064,154