Abstract: The invention relates to a single-component or multiple-component polyelectrolyte cement containing at least two reaction partners: (a) at least one metal-cation-releasing compound and (b) one or more polyelectrolytes capable of being converted into a solid state, wherein at least one of the polyelectrolytes is at least partially water soluble, and wherein at least a part of the reaction partner (a) and/or (b) is coated with an organic surface-coating agent. In one preferred embodiment, at least one part of the formulation constituents of the cement is present in granulated form, wherein at least a part of the reaction partner (b) serves as an essential granulation agent. The polyelectrolyte cement is particularly stable in storage and can be easily mixed.

Abstract: The invention relates to the use of a mixture of bioactive glass and dental glass for producing an agent for a permanent dental filling. The bioactive glass is preferably contained in a binding agent for binding a dental filling to a tooth, in a glass-ionomer cement, in a glass-plastic composite, in a composite-reinforced glass-ionomer cement and/or in an agent for treating the tooth root, the neck of the tooth and/or the tooth crown and preferably contains fluoride ions.

Abstract: A porous ceramics body for in vivo or in vitro 1use in which a number of pores are closely distributed in three dimensional directions, adjoining pores thereof being partitioned by wall portions with respective communication ports to bring said adjoining pores into communication with each other such that a series of connected spherical pores are formed therewithin, said porous ceramics body being made of a sintered calcium phosphate body, characterized in that, within said sintered calcium phosphate body, pores each having a diameter of 5 microns (&mgr;m) or more account for 80% or more of all the pores in terms of volume whereas pores having a diameter of less than 5 microns (&mgr;m) account for less than 20% of all the pores in terms of volume as subjected to a mercury porosimeter measurement.

Abstract: Cement materials useful in dental and medical fields with improved mechanical properties is described. The cement material includes fluoroaluminosilicate powder and poly(acrylic acid) liquid. Biocompatible oxide powders are further included resulting in improved mechanical properties of maximum strength, rigidity and toughness. Variations of the cement material resulting in improved mechanical properties include the concentration of poly(acrylic acid) liquid, and combining the fluoroaluminosilicate powder with different biocompatible oxide powders. Useful oxide powders include hydroxyapatite powders, titanium oxide, zirconium oxide, aluminum oxide, and silica-containing e-glass powder. Preferably, about 10 vol. % of total amount of oxide powders is used to obtain optimum improvements. The total amount can be based on incorporation of a single or a combination of selected oxide powders.

Abstract: A pressable glass ceramic which contains lithium silicate glass and leucite is disclosed. Also, disclosed is the combination of leucite and a lithium silicate glass to stably increase the coefficients of thermal expansion of the resulting glass composition, and the preparation of leucite suitable for addition to the glass composition. Also disclosed are methods for fabricating glass ceramic and dental products from the pressable glass ceramic.

Abstract: I provide a multi-part aqueous gypsum dental casting composition having gypsum and water and wherein (a) one or more of a first compound is mixed in the gypsum and/or water; or (b) one or more of the first compound and one or more of a second compound are mixed in the gypsum and/or water; or (c) one or more of the first compound and one or more of an acid are mixed in the gypsum and/or water; or (d) one or more of the first compound and one or more of the second compound and one or more of the acid are mixed in the gypsum and/or water; or (e) two or more of the acids and optionally one or more of the second compound are mixed in the gypsum and/or water; and (f) the gypsum and water are maintained separately and mixed when the casting is to be prepared. Also provided are the dosage sized containers for the above, along with the dosage size containers having gypsum enhancers.

Abstract: A calcium phosphate cement suitable for use in dental and bone prosthesis is disclosed, which include calcium phosphate particles having a diameter of 0.05 to 100 microns, wherein said calcium phosphate particles on their surfaces have whiskers or fine crystals having a width ranging from 1 to 100 nm and a length ranging from 1 to 1000 nm.

Abstract: This invention relates to a cement, which consists in its main phase of microcrystalline magnesium ammonium phosphate and nanoapatite after hardening and thus at the same time has considerable strength. The material is biologically degradable and is suitable for application in tooth cements, as bone replacement, as bone filler, as bone cement or as bone adhesive.

Abstract: The invention concerns microgranules produced from calcium phosphate materials. The invention also concerns a method for producing said microgranules. The inventive microgranules are characterized by a very narrow particle size distribution.

Abstract: Blocks of material are prepared in a variety of shapes and sizes to be used in the fabrication of models for dental restorations. The material comprises a partially sintered ceramic material. The blocks are used to manufacture molds using CAD/CAM methods and equipment. The molds are useful in the manufacture of dental restorations using ceramics, metals, alloys, or powders thereof, and composite materials. The models milled from the blanks may be used to manufacture a variety of dental restorations including, but not limited to, crowns, bridges, space maintainers, tooth replacement appliances, orthodontic retainers, dentures, posts, jackets, inlays, onlays, facings, veneers, facets, implants, abutments, splints, partial crowns, teeth, cylinders, pins, and connectors.

Abstract: A dental composition for the treatment of dentinal hypersensitivity and in particular for the desensitization of exposed dentin, the desensitizing treatment of deep cavities, the desensitizing treatment when replacing dental layers, the stumps desensitizing treatment before placing dental prosthesis. The composition can be used as a solution or as a gel. In the first case two distinct liquid solutions for use successively on the exposed dentin are provided for. In the second case two distinct gel compounds spread successively on the exposed dentin are provided for. The first solution or the first gel compound comprises preferably three soluble potassium salts, whereas the second solution or the second gel compound comprises a calcium salt and a soluble strontium salt.

Abstract: A bioactive biphasic ceramic composition combining apatite and wollastonite is disclosed, in order to solve the defect of apatite ceramic that has poor bioactivity though it is excellent in biocompatibility, which has improved bioactivity, as compared to monophasic ceramics of apatite or wollastonite. The ceramic composition is produced by steps of: providing a composition including powders of apatite of formula Ca10(PO4)6X, in which X is any one of O, (OH)2, CO3, F2 and Cl2, and wollastonite (CaSiO3) in a weight ratio of 5:95 to 90:10, forming the composition into a desired body by press or forming the composition into a porous body, and sintering the formed body.

Abstract: The invention proposes to produce a mixture that is shrink-resistant, or has a freely selectable degree of shrinkage, and can be used as a molding compound, and a method for producing a corresponding oxide-ceramic sintered body. The molding compound comprises an intermetallic compound and a wax. In the method for producing an oxide-ceramic sintered body, a green body is molded from a molding compound of this type, dewaxed and sintered in an oxidizing atmosphere to form a ceramic sintered body. The molding compound is suited for producing dentures and dental fillings.

Abstract: A biodegradable ceramic for medical use is disclosed, which comprises calcium hydrogenphosphate (CaHPO4) modified by organic molecules. The organic molecule mentioned above is hexamethylene diisocyanate (HMDI), which is grafted to the calcium hydrogenphosphate through covalent bond. The present invention also relates to a method for preparing the biodegradable ceramics. In addition, the biodegradable ceramic can be used for repair of bone defects. Therefore, the present invention further relates to a method and a device for repair of bone defects, and to a delivery system for the medicine of repair of bone defects.

Abstract: A tetracalcium phosphate (TTCP) particle for use in preparing a fast-setting, bioresorbable calcium phosphate cement is disclosed. The TTCP particle has a basic calcium phosphate whiskers or fine crystals on a surface thereof; the basic calcium phosphate whiskers or fine crystals having a Ca/P molar ratio greater than 1.33, and having a length up to about 5000 nm and a width up to about 500 nm.

Abstract: Novel unsaturated esters for use in dentistry as bonding agents are produced by a stepwise reaction of a cyclic dianhydride with a) unsaturated alcohols, b) unsaturated glycidyl ethers, and c) unsaturated isocyanates. The products used as bonding agents have the formula: wherein R2 is H or CH3.

Abstract: A kit and a method for making a porous cement which self sets to hydroxyapatite and has an interconnected porosity is produced by mixing a calcium source and a phosphate source with a carbonate source and mixing this powdered component with a liquid component having an acid component. The liquid component comprises water or an aqueous solution containing an acid. The acid and the carbonate react to form carbon dioxide thereby producing an interconnected porosity in the normally solid self-hardening bone cement. The method requires only a relatively low weight percent of the acid and base to be mixed with the liquid and powder cement components.

Abstract: Dental compositions containing adjuvants are provided that have the capability of undergoing an increase in viscosity in response to an increase in temperature. In a preferred embodiment, the compositions also have the ability to reverse their viscosity in response to a decrease in temperature.

Abstract: Refractory investment material for forming a positive replication of a tooth structure on which a high-alumina based porcelain tooth restoration is to be formed, the material being formed from a refractory powder which includes alumina mixed with a liquid carrier comprising an aqueous dispersion of silicon dioxide.

Abstract: A porcelain composition for dental restorations comprising a leucite crystallite phase and a glass matrix phase, wherein the leucite crystallites possess diameters not exceeding about 10 micron. Preferably, the porcelain composition has a maturing temperature from about 750° to about 1050° C. and a coefficient of thermal expansion from about 12×10−6/° C. to about 17.5×10−6/° C., and comprises: Component Amount (wt. %) SiO2 57-66 Al2O3  7-15 K2O  7-15 Na2O  7-12 Li2O 0.5-3.

Abstract: Method of making abrasive compositions comprised of water-insoluble abrasive polishing agents suspended in an aqueous medium in combination using wet grinding, and products thereof. The abrasive compositions made by the method contain appropriately sized abrasive particles provided without the need for drying or dry milling, while also providing an abrasive composition which is theologically stable, settling-resistant, and re-agglomeration resistant, even during and after transport and/or storage before end-use, such as incorporation into dentifrice formulations or other oral cleaning compositions.

Abstract: A dental retrograde-filling material process, comprising the steps of: taking 3:1 mole ratio of a calcium oxide and a silicon dioxide mixes a 1˜5 w.t. % cobalt oxide at 1200˜1800 degree Celsius temperature to get a A-product including a tricalcium silicate, a dicalcium silicate and a containing cobalt composition; taking 3:1 mole ratio of a calcium oxide and an aluminum oxide at 1200˜1800 degree Celsius temperature reacts a B-product including a tricalcium aluminate; taking 4:1:1 mole ratio of a calcium oxide, an aluminum oxide and a ferric oxide at 1200˜1800 degree Celsius temperature reacts a C-product including a calcium alminoferrite; and mixing the A-product, B-product and C-product are the retrograde-filling material. The dental retrograde-filling material mixes of taking 8:1:1 mole ratio of said tricalcium silicate, dicalcium silicate and containing cobalt composition, tricalcium aluminate and calcium alminoferrite.

Abstract: Micaceous glass-ceramics are useful in the fabrication of single and multi-unit dental restorations including but not limited to orthodontic appliances, bridges, space maintainers, tooth replacement appliances, splints, crowns, partial crowns, dentures, posts, teeth, jackets, inlays, onlays, facing, veneers, facets, implants, abutments, cylinders, and connectors by machining the glass-ceramic using CAM/CAM devices. The micaceous glass-ceramics are provided in a plurality of shades and colors to adequately match the colors and shades of teeth found in 95% or more of the human population.

Abstract: The present invention is concerned with a process for the formation of dental restorations from glass-ceramic materials and the resulting dental restorations. A dental restoration is formed by pressing a lithium discilicate glass ceramic where the concentration of lithium discilicate crystals in the glass ceramic composition is at least 30% by weight. Crystal formation is effected with P2O5. The glass ceramic material may further contain coloring oxides, fluoresing agents, pigments, opacifiers and glass modifiers. The resulting dental restorations have superior optical, esthetic and strength properties.

Abstract: The invention relates to dental materials which contain filler and a polymerizable matrix and are characterized in that they additionally have a component which contracts during thermal treatment.

Abstract: The preferred embodiment of the present invention provides novel and unique fused fibrous compounds for addition to and manufacture of bone and dental cement systems and methods of making the same. The preferred embodiment of the fused fibrous compound material made therefrom comprises a rigid three-dimensional network of fibers fused together at their points of contact wherein said network is greater than 60% by volume void space, has mean pore diameters greater than 10 microns, or both. The fused fibrous compound is preferably manufactured from fibers and a fusion source and is added to the composition in particle form.

Abstract: The invention relates to mixtures comprising polymers containing hydrogen-siloxane groups and fluoride, in addition to the use of said mixtures as a dental scaling varnish and fluoridation varnish and as a desensitising agent, in addition to the use of said mixtures as a protective covering for glasionomer cement fillings.

Abstract: The invention relates to a dental ceramic comprising a sintered body that has a share of more than 90% by weight hydroxylapatite (HA; Ca5(PO4)3OH). The ceramic is easy to produce and highly stable, and in addition offers a natural-looking appearance if the sintered body is anisotropic.

Abstract: High strength ceramic components for use in dental applications are provided wherein one or more layers of ceramic material is disposed on a high strength ceramic component to provide a dental restoration. The ceramic material may be applied in the form of powder, putty, tape a pellet.

Abstract: Potassium-zinc-silicate glasses are described which because of their high chemical stability as well as their optical properties and favorable working properties are suitable in particular as coating or veneering materials for ceramic dental suprastructures and thus for the preparation of all-ceramic dental restorations, such as crowns or bridges.

Abstract: Described are methods of improving cure of polymerizable dental materials by preventing oxygen inhibition; preferred embodiments relate to methods wherein the dental compositions comprises a polymerizable sealant and the barrier material comprises an essential oil.

Abstract: The invention relates to glass ionomer for enhancing mineralization of hard tissue of mammals. The glass ionomer comprises, a inert biocompatible ceramic and a bioactive ceramic. The invention also relates to a method for enhancing mineralization of hard tissue of mammals with the aid of said glass ionomer. The invention further relates to the use of said glass ionomer for the preparation of products intended for treatment of defects of soft and hard tissue as well as the use of said glass ionomer for the preparation of a variety of products wherein the ability to enhance mineralization is advantageous.

Abstract: The invention relates to dental materials which contain hydrolysis-resistant phosphonic acids with ethylenically unsaturated double bonds and which are especially suitable for use as adhesion promoters.

Abstract: A process for preparing a paste from calcium phosphate cement includes a) mixing an aqueous acidic solution and powder containing at least one of tricalcium phosphate and tetracalcium phosphate; and b) mixing the resulting mixture from step a) and an aqueous basic solution to form a paste. The calcium phosphate cement paste is useful in dental and bone prosthesis.

Abstract: The present invention relates to a denture adhesive composition comprising mixed salts of an alkyl vinyl ether-maleic acid or anhydride copolymer and/or terpolymer with isobutylene wherein the mixed salt contains a cationic salt function comprising at least about 22.5% calcium cations, from about 15% to about 25% of zinc cations, of the total initial carboxyl groups reacted, the mixed salt containing from about 36% to about 50% free acid component. In addition the present invention relates to denture adhesive compositions comprising the above composition and at least one non-adhesive self-supporting layer. The present invention further relates to a method of increasing the adhesion of dentures to the oral cavity by applying the above compositions to dentures, directly to the oral cavity, palate or ridge of the oral cavity, or applying it to both, and thereafter securing the denture to the ridge or palate of the oral cavity.

Abstract: A white, substantially non-iron containing dental material formed from Portland cement. The material may be a dental cement, dental restorative or the like.

Abstract: The invention provides ink which is best suited for inkjet printing of a printed substrate. The ink is a photo polymerizing type water-base ink including at least a colorant, a photo polymerization resin, a photo initiator, and a water-base solvent. The photo polymerization resin includes oligomer particles in an emulsion state and monomers which reside in the oligomer particles. The water-base ink contains, with content ratio in terms of the percentage weight, 5% of ethyleneglycol, and between 0.1% to 10% of 2-pyrrolidone and N-acryloyl morpholine combined.

Abstract: A paste type dental glass ionomer cement composition in paste type using no polymerizable monomer, that is good in operationality with excellent inherent characteristics of glass ionomer cement maintained, is constituted with a first paste and a second paste, in which the first paste contains 30 to 70% by weight of a polymer of an &agr;-&bgr; unsaturated carboxylic acid and 30 to 70% by weight of water, and the second paste contains 50 to 85% by weight of fluoroaluminosilicate glass, 0.005 to 1% by weight of a water soluble thickening agent and the remaining percentage by weight of water, the mixing amount of the water soluble thickening agent being preferably 0.01 to 0.4% by weight.

Abstract: The present invention provides a method of utilizing a non-metallic composition to repair or seal hard dental tissue, wherein the non-metallic compositions harden in the mouth to form substantially permanent fixtures. The compositions comprise an amount of an essential oil effective to alter the sensor properties, i.e., the taste or smell, of the composition, and that desirably imparts a pleasant taste and/or odor. The essential oil further advantageously provides the composition, once hardened in the mouth, with a surface more hydrophobic than a corresponding composition, thereby inhibiting the deposition or formation of bacterial plaque.

Abstract: Raw compact (3) comprising a binding phase of one or more powdered binding agents, which raw compact has the capacity, following saturation with a liquid reacting with binding agents, to form a chemically bound ceramic material, and which raw compact preferably has a degree of compactness of 55-67 percent by volume solid phase. According to the invention, the raw compact (3) also comprises one or more expansion-compensating additives adapted to give the material dimensionally stable long-term properties. The invention also relates to a method of manufacture of the ceramic material, and a compaction device and a compaction body for compacting the saturated raw compacts.

Abstract: Laminated paste for a dental crown and preparation method thereof are disclosed. Ceramic powders for dental crown added by aqueous additives are mixed with each other and are laminated as paste state in appropriate of the order of dental crown forming layers.

Abstract: A polycrystalline translucent aluminum oxide ceramic material having an average grain size of no greater than 1.0 micron and a Contrast Ratio value of less than about 0.7. The material can be in the form of a dental mill blank, dental prosthesis or other dental article or non-dental article.

Abstract: A fast-setting, bioresorbable calcium phosphate cement is prepared by a process which can be carried out with a heat treatment up to 1000° C. on a mixture of a wetting solution and a calcium phosphate powder having a Ca to P molar ratio of 0.5-2.5. The wetting solution suitable for use in the process of the present invention includes water, an organic solvent, an acidic and basic solution. A setting solution for mixing with the heated powder to form the fast-setting, bioresorbable calcium phosphate cement may be water, an acidic or basic solution according to the process of the present invention.

Abstract: Opaque porcelains for use with metal cores in the manufacture of PFM restorations. The porcelains exhibit a coefficient of thermal expansion (CTE) substantially equal to or slightly above the CTE of the metal to which it is applied. The porcelains exhibit a CTE equal to or up to about 1.5×10−6/° C. higher than the dental alloys to which they are applied as the opaque. The porcelains are fabricated from a mixture of two frit compositions. A high expansion, leucite containing frit is combined with a low melting glass frit to provide a porcelain having an expansion in the range of 16.9 to about 18.5×10−6/° C. in the temperature range of 25°-600° C.

Abstract: The present invention is directed to a synthetic biomaterial compound based on stabilized calcium phosphates and more particularly to the molecular, structural and physical characterization of this compound. The compound comprises calcium, oxygen and phosphorous, wherein at least one of the elements is substituted with an element having an ionic radius of approximately 0.1 to 1.1 Å. The knowledge of the specific molecular and chemical properties of the compound allows for the development of several uses of the compound in various bone-related clinical conditions.

Abstract: The invention provides for a material comprising(a) a hardenable resin; and (b) a filler comprising (i) clusters of nano-sized particles, the clusters comprising non-beavy metal oxide particles and heavy metal oxides, and being not fully densified particles and (ii) non-agglomerated nano-sized particles selected from the group consisting of non-heavy metal oxide particles, heavy metal oxide particles, and combinations thereof. The material is suitable for use as dental materials.

Abstract: To provide a root canal filling material, which is high in strength, is hardly bent, is easy for root canal filling operation, is properly deformed during press contact, is high in adhesion and superior in sealing properties between root canal filling material each other or between a root canal filling material and a root canal wall, and is provided with proper radiopacity, the root canal filling material is constructed of (A) 1 to 50% by weight of one or two or more thermoplastic resins selected from trans-polyisoprene, polyethylene, polypropylene, and a copolymer of polyethylene and polypropylene; (B) 0.1 to 20% by weight of a styrene block copolymer; (C) 0.1 to 10% by weight of a paraffin wax; and (D) 30 to 95% by weight of one or two or more inorganic fillers selected from zinc oxide, barium sulfate, zirconium oxide, and titanium oxide.

Abstract: The present invention provides amorphous inorganic particles as a dental material comprising silica and inorganic oxide(s) other than silica and having high x-ray impermeability. The inorganic particles as a dental material comprise silica with the content in the range from 70 to 98 weight % and oxide(s) of one or more elements selected from the group consisting of Zr, Ti, La, Ba, Sr, Hf, Y, Zn, AL, and B, wherein 5 to 70 weight % of the silica is originated from an acidic silicic acid solution and 30 to 95 weight % of the silica is originated from a sol of silica. This inorganic particles as a dental material have average particle diameter in the range from 1 to 10 &mgr;m, specific surface area in the range from 50 to 350 m2/g, pore volume in the range from 0.05 to 0.5 ml/g, amorphous crystallinity as observed by x-ray diffraction, and the refractive index in the range from 1.47 to 1.60.

Abstract: Improved two component polymerizable polyorganosiloxane compositions are described, particularly for use in making dental impressions, having improved tear strength and wettability. Improved tear strength results from inclusion of a quadri-functional polysiloxane having a vinyl content of 0.16 to 0.24 m-mole/g. Working time is maintained by including sufficient amounts of a retarder composition that delays onset of the vinyl polymerization. Wettability is improved by including a surfactant resulting in a surface contact angle with water at three minutes of less than 50°. The surfactant chosen has an HLB of 8-11, such that the wetting contact angle is achieved within less than two minutes and remains wetting throughout the working time of the impression taking, substantially improving impression quality. A low viscosity impression material is provided and includes a base component and a catalyst component. Both components are siloxane-based materials.

Abstract: A dental porcelain composition comprises an amorphous glass phase with a maturing temperature less than about 850° C., wherein the amorphous glass phase, in one embodiment, comprises: Component Amount (wt. %) SiO2 55-75 B2O3 2.6-6   Al2O3   3-4.9 ZnO 0-3 CaO 0-3 MgO 0.5-3   ZrO2 0-3 BaO 0-2 Li2O 0.8-2   K2O   0-6.