Abstract: The present invention relates to a current composition for cementing oil or gas wells. The composition comprises calcium aluminate cement in which the proportion of HC203 is at least 50% by weight, dispersant, microsilica, mineral particles, water and optionally a retarder.

Abstract: A process for treating fly ash to activate the fly ash so that it may be used as a substitute for Portland cement, with the process including the use of a specialized rotary mill having variably sized and shaped media to increase the surface area of one fly ash component by grinding, avoiding milling a second fly ash component, while roughing up the surface of the second component to increase its surface area.

Abstract: A method of servicing a wellbore comprising preparing a composition comprising a calcium aluminate cement, water, and a fluid loss additive wherein the fluid loss additive comprises an acid gelling polymer, placing the composition in the wellbore, and allowing the composition to set. A method of servicing a wellbore comprising placing into a wellbore having a bottom hole static temperature of greater than about 50° F. and/or a pH of from about 3 to about 9 a cement slurry comprising a calcium aluminate cement having an aluminum oxide content of greater than about 60 wt. % based on the total weight of the calcium aluminate cement and an acid-gelling polymer wherein the cement slurry has a fluid loss at 10 cc/10 min. to about 600 cc/30 min.

Abstract: The disclosure relates generally to mold compositions comprising calcium aluminate and calcium titanate. The disclosure also relates to methods of molding and the articles so molded using the mold compositions. More specifically, the disclosure relates to calcium aluminate/calcium titanate mold compositions and methods for casting titanium-containing articles, and the titanium-containing articles so molded.

Abstract: Well cement compositions comprise water, an inorganic cement and one or more fillers having a thermal expansion coefficient (CTE) that is lower than about 3×10?6/° C. The presence of low-CTE fillers may reduce cement-sheath shrinkage when the well temperature falls during stimulation treatments, cyclic steam injection or when the well temperature reaches equilibrium at the top of a long casing string.

Abstract: A cement mix for preparation of a magnesium silico-phosphate cement (MSPC) with an altered hardening rate is provided. The cement mix comprises on the order of 1% of an [MF6]n? salt or acid. Upon addition of water, the mix produces a final set cement that has similar physical properties to those of a cement prepared from a mix lacking the additive, but with a significantly altered setting time. In some embodiments of the invention, the additive is provided in the form of a coating for the MgO component of the mix. In preferred embodiments, H2TiF6, Na2TiF6 and/or K2TiF6 are used as retarders, while K3AlF6 is used as an accelerant. Other embodiments use M?nMF6 compounds wherein M? is an alkali metal, an alkaline earth metal, or H, and M is chosen from inter alia Ti (n=2), Zr (n=2), P (n=1), Al (n=3), and Sb (n=1).

Abstract: Methods and compositions that protect cement compositions from corrosion, particularly from wet carbon dioxide, are provided. A soluble salt additive is provided to react with reaction products generated during the reactions that occur when cement is exposed to wet carbon dioxide. The soluble salt reacts to form an insoluble salt that forms a protective layer on the surface of the cement that protects it from further corrosion from exposure to wet carbon dioxide.

Abstract: Methods and compositions are provided that relate to weighted elastomers. The weighted elastomers may comprise an elastomer and a weighting agent attached to an outer surface of the elastomer. An embodiment includes a method of cementing that comprises providing a cement composition containing cement, water, and a weighted elastomer. In addition, the cement composition may be introduced into a subterranean formation and allowed to set therein.

Abstract: The use of a binder system comprising compounds containing aluminium oxide and silicon oxide for producing a hydrophilic building product, characterized in that the sum of the oxides calculated as Al2O3 and SiO2 in the binder system is ?40% by weight, based on the water-free binder system, and the contact angle of an oil drop placed on the surface of the cured building product is ?90°, where the contact angle determination is carried out under water, is proposed. The said hydrophilicity makes the building product easy to clean, with simple rinsing with water often being sufficient.

Abstract: The invention relates to a sulfo-aluminous clinker with optimal setting time and short term compressive strengths, comprising a mixture of the following phases: —calcium sulfoaluminate, or C4A3$, in amounts higher than 50% by weight of the mixture, —belite, or C25, in amounts between 2 and 23%, —3C25 3C$ CaX2, X being fluorine or chlorine, between 3 and 15% —C11A7CaX2, X being fluorine or chlorine, between 2 and 12%, both fluorine and chlorine being altogether present in the mixture, and phase C5S2$ being absent. The invention also relates to a method for preparing this sulfo-aluminous clinker, and hydraulic binders comprising this clinker.

Abstract: Hydraulic cements, such as Portland cements and other cements that include substantial quantities of tricalcium silicate (C3S), dicalcium silicate (C2S), tricalcium aluminate (C3A), and/or tetracalcalcium alumino-ferrite (C4AF), are particle size optimized to have increased reactivity compared to cements of similar chemistry and/or decreased water demand compared to cements of similar fineness. Increasing hydraulic cement reactivity increases early strength development and release of reactive calcium hydroxide, both of which enhance SCM replacement and 1-28 day strengths compared to blends of conventional Portland cement and one or more SCMs, such as coal ash, slag or natural pozzolan. Decreasing the water demand can improve strength by decreasing the water-to-cement ratio for a given workability. The narrow PSD cements are well suited for making blended cements, including binary, ternary and quaternary blends.

Abstract: Provided herein are systems, methods, and compositions related to mixtures of calcium aluminate cements with compositions comprising carbonate. The compositions comprising carbonates may be formed by sequestering carbon dioxide.

Abstract: The invention relates to a sulfo-aluminous clinker with optimal setting time and short term compressive strengths, comprising a mixture of the following phases: calcium sulfoaluminate, or C4A3$, in amounts higher than 50% by weight of the mixture, belite, or C2S, in amounts between 2 and 23%, 3C2S 3C$ CaX2, X being fluorine or chlorine, between 3 and 15% C11A7CaX2, X being fluorine or chlorine, between 2 and 12%, both fluorine and chlorine being altogether present in the mixture, and phase C5S2$ being absent. The invention also relates to a method for preparing this sulfo-aluminous clinker, and hydraulic binders comprising this clinker.

Abstract: A process for producing a geopolymer includes combusting at least one of oil shale and mineral residues originating from a production of oil using the oil shale so as to produce a combustion product. The combustion product is ground. An alkaline activator is added to the combustion product to form a geopolymer mixture. Water is added to the geopolymer mixture. The geopolymer mixture is adjusted so as to obtain a mol ratio of Si:Al of 2 to 5, a mol ratio of K:Al of 0.6 to 0.7, a mol ratio of Si:K of 3 to 10, a mol ratio of Ca:Al of 0.1 to 0.4, and a mol ratio of Si:CA of 4.9 to 41. The geopolymer mixture is hardened.

Abstract: Microparticles having crystalline needle or rod-shaped structures of, for example, an ettringite mineral grown and attached radially from their surface. A method including nucleating and growing crystalline needles/rods from the surface of a particle in the presence of a solution of calcium, sulfur, and aluminum such as calcium sulfoaluminate, lime and calcium sulfate is described. One example is the radial growth of ettringite needles on the surface of fly ash particles in calcium sulfoaluminate-based cement paste and concrete.

Abstract: Hydraulic cements, such as Portland cements and other cements that include substantial quantities of tricalcium silicate (C3S), dicalcium silicate (C2S), tricalcium aluminate (C3A), and/or tetracalcalcium alumino-ferrite (C4AF), are particle size optimized to have increased reactivity compared to cements of similar chemistry and/or decreased water demand compared to cements of similar fineness. Increasing hydraulic cement reactivity increases early strength development and release of reactive calcium hydroxide, both of which enhance SCM replacement and 1-28 day strengths compared to blends of conventional Portland cement and one or more SCMs, such as coal ash, slag or natural pozzolan. Decreasing the water demand can improve strength by decreasing the water-to-cement ratio for a given workability. The narrow PSD cements are well suited for making blended cements, including binary, ternary and quaternary blends.

Abstract: Methods and compositions that comprise sub-micron alumina for accelerating setting of a cement composition. An embodiment includes a method of cementing in a subterranean formation. The method may comprise introducing a cement composition into the subterranean formation, wherein the cement composition comprises hydraulic cement, sub-micron alumina, and water. The method further may comprise allowing the cement composition to set in the subterranean formation. Another embodiment includes a cement composition that may comprise hydraulic cement, sub-micron alumina, and water.

Abstract: A low-water-content castable composition produces cast products with an increased modulus of rupture, an increased cold crushing strength, and decreased porosity. The composition employs closed fractions of constituent particles with specified populations and specified gaps in the particle size distribution to produce these properties. The composition is suitable for refractory applications.

Abstract: The present invention provides for a refractory aggregate composition comprising an improved calcium aluminate clinker having the formula CnAx wherein C is calcium oxide and A is aluminum oxide, wherein n is an integer from about 1 to about 12, wherein x is an integer from about 1 to about 24, and wherein said clinker has from zero to less than about fifty weight percent C12A7, and including a source of barium that is substituted for calcium in said calcium aluminate clinker. Analogs, derivatives and hydrates of the improved calcium aluminate clinker are provided. A refractory composition and a sprayable refractory composition are disclosed comprising the improved calcium aluminate clinker. A method for improving the insulating character and/or penetration resistance of a liner in contact with molten aluminum in an aluminum manufacturing process or during aluminum transport is provided.

Abstract: Inorganic polymer compositions and methods for their preparation are described herein. The compositions include the reaction product of a reactive powder, an activator, and optionally a retardant. The reactive powder includes fly ash and a tricalcium aluminate additive. In some examples, the reactive powder comprises less than 5% by weight portland cement. The tricalcium aluminate is present in an amount of 0.5% or greater by weight of the reactive powder. Also described herein are building materials including the compositions.

Abstract: Methods and compositions are provided that relate to weighted elastomers. The weighted elastomers may comprise an elastomer and a weighting agent attached to an outer surface of the elastomer. An embodiment includes a method of cementing that comprises providing a cement composition containing cement, water, and a weighted elastomer. In addition, the cement composition may be introduced into a subterranean formation and allowed to set therein.

Abstract: A dry mortar mixture based on at least one hydraulic and/or latently hydraulic binder which in the made-up and not yet cured state has firm properties is claimed. The novel dry mortar mixture is characterized in that it contains at least one representative of a dispersant and at least one compound having superabsorbent properties. This mixture makes it possible to carry over the advantages of known tile adhesives for horizontal application to vertical application possibilities.

Abstract: It is the object of the invention to provide a cement admixture, and a cement composition that can impart good enough rustproofness to reinforcing bars in hardened cement concrete, and can have resistance to penetration of chloride ions entering from the outside, prevent the hardened cement concrete from getting porous due to reduced leaching of Ca ions and have a self-recovery capability. The invention provides a cement admixture characterized by containing a calcium ferroaluminate compound comprising a CaO—Al2O3—Fe2O3 system, and having a Fe2O3 content of 0.5 to 15% by mass and a CaO.2Al2O3 structure with a CaO/Al2O3 molar ratio ranging from 0.15 to 0.7.

Abstract: A method of making Portland cement, white cement, calcium aluminates, calcium aluminum silicates and similar oxides using solid state combustion synthesis is described. The method uses less energy and produces lower CO2 emissions than conventional processes. The method uses green fuels like biomass and lignin and eliminates most of the coal used in traditional cement production. A batch reactor and a semi-continuous reactor that can be used for the combustion synthesis are also described.

Abstract: Hydraulic cements, such as Portland cements and other cements that include substantial quantities of tricalcium silicate (C3S), dicalcium silicate (C2S), tricalcium aluminate (C3A), and/or tetracalcalcium alumino-ferrite (C4AF), are particle size optimized to have increased reactivity compared to cements of similar chemistry and/or decreased water demand compared to cements of similar fineness. Increasing hydraulic cement reactivity increases early strength development and release of reactive calcium hydroxide, both of which enhance SCM replacement and 1-28 day strengths compared to blends of conventional Portland cement and one or more SCMs, such as coal ash, slag or natural pozzolan. Decreasing the water demand can improve strength by decreasing the water-to-cement ratio for a given workability. The narrow PSD cements are well suited for making blended cements, including binary, ternary and quaternary blends.

Abstract: The present disclosure relates to a titanium-containing article casting mold composition comprising calcium aluminate and an X-ray or Neutron-ray detectable element. Furthermore, present embodiments teach a method for detecting sub-surface ceramic inclusions in a titanium or titanium alloy casting by combining calcium aluminate, an element more radiographically dense than the calcium aluminate, and a liquid to form a slurry; forming a mold having the calcium aluminate and the radiographically dense element from the slurry; introducing a titanium aluminide-containing metal to the radiographically dense element-bearing mold; solidifying said titanium aluminide-containing metal to form an article in the mold; removing the solidified titanium aluminide-containing metal article from said mold; subjecting the solidified titanium aluminide-containing article to radiographic inspection to provide a radiograph; and examining said radiograph for the presence of the radiographically dense element on or in the article.

Abstract: Cement compositions and methods for making cement compositions are provided. The cement compositions can comprise at least one oxide having a particle size of less than about 600 nm. The methods for making cement may include: providing a mixture of compounds containing the required calcium, silicon, aluminum, and iron to provide at least one of tricalcium silicate, dicalcium silicate, tricalcium aluminate, tetracalcium aluminoferrite, other calcium silicates, aluminates, ferrites, and silicates or combinations thereof; adding a fuel source and an oxidizer to the mixture of compounds; and heating the mixture of compounds, the fuel source, and the oxidizer such that the mixture of compounds, the fuel source, and the oxidizer ignite to form the at least one tricalcium silicate, dicalcium silicate, tricalcium aluminate, and tetracalcium aluminoferrite, or combinations thereof.

Abstract: Resilient graphitic carbon may be an effective lost-circulation control agent for well-cementing compositions. During primary or remedial cementing, the carbon particles may hinder or prevent the egress of the well-cementing composition from the wellbore into subterranean formations via formation fissures or cracks. The carbon particles may also be added to spacer fluids, chemical washes or both.

Abstract: Hydraulic cements, such as Portland cements and other cements that include substantial quantities of tricalcium silicate (C3S), dicalcium silicate (C2S), tricalcium aluminate (C3A), and/or tetracalcalcium alumino-ferrite (C4AF), are particle size optimized to have increased reactivity compared to cements of similar chemistry and/or decreased water demand compared to cements of similar fineness. Increasing hydraulic cement reactivity increases early strength development and release of reactive calcium hydroxide, both of which enhance SCM replacement and 1-28 day strengths compared to blends of conventional Portland cement and one or more SCMs, such as coal ash, slag or natural pozzolan. Decreasing the water demand can improve strength by decreasing the water-to-cement ratio for a given workability. The narrow PSD cements are well suited for making blended cements, including binary, ternary and quaternary blends.

Abstract: A wearing compound slurry comprising an inorganic binder, ceramic particles, ceramic powder, diluent and optionally filler and discontinuous fibers. The slurry is applied to a wearable surface and exposed to heat to remove diluent and cure the wearing compound into a hard layer. The cured wearing compound layer remains intact after exposure to extremely high temperatures.

Abstract: A composition includes at least, in % expressed by mass relative to the total mass of the composition, from 0.01 to 3% of polycarboxylic acid or salts thereof, the polycarboxylic acid including 2 to 4 carboxyl groups per molecule; and from 97 to 99.99% of a Belite-Calcium-Sulphoaluminate-Ferrite clinker (BCSAF clinker).

Abstract: A binder for monolithic refractories characterized by containing ingredients comprised of a chemical composition of at least one of CaxSr1-xAl2O4, and CaySr1-yAl4O7 or these plus 12(CaO)z(SrO)1-z.7Al2O3 (where, 0<x<1, 0<y<1, and 0<z<1) and a binder for monolithic refractories and monolithic refractories superior in erosion resistance to slag or molten iron by monolithic refractories comprised of this binder and refractory aggregates are provided.

Abstract: The present invention relates to the production of geopolymers from oil shale and/or mineral residues, which originate from the production of oil by means of oil shale. To use the residues left in the combustion of oil shale for the production of geopolymers, the oil shale and/or also mineral residues, which originate from the production of oil by means of shale are burnt and subsequently ground, before they are mixed with an alkaline activator and water and cured.

Abstract: A refractory self-flow filler mortar, includes in mass % with relation to the basic refractory material, at least 1% and at most 10% of non-granulated spherical particles with median size greater than 0.1 ?m and less than or equal to 2 mm and further includes in mass % with relation to the total dry mass of the mortar, less than 4.5% of silica (SiO2) and between 1% and 8% water, the standard deviation of the non-granulated spherical particle size being less than 100%.

Abstract: The invention relates to a novel sulfoaluminous clinker, to a method for preparing said clinker, and to the use of said clinker for preparing a hydraulic binder and subsequently grout, concrete, or mortar.

Abstract: Methods for preventing, reducing, or eliminating construction heave, expansion, distresses, and damage primarily caused by the formation of ettringite are disclosed including introducing fluoride ion releasing agent/salt(s), such as sodium fluoride, calcium fluoride, and potassium fluoride, to expansive soil layers or concrete structural elements and allowing the fluoride ion releasing agent/salt(s) at ambient temperature to react with formed ettringite and to prevent the formation of ettringite of the expansive soil layers or concrete structural elements. Other embodiments are described and claimed.

Abstract: A wellbore servicing method comprises converting a water into an electrochemically activated water, preparing a wellbore servicing composition comprising the electrochemically activated water, and placing the wellbore servicing composition in a wellbore. Also, cement composition comprises a cement and an electrochemically activated water.

Abstract: The self-leveling fluid screed cement composition with limited shrinkage, formed by a mixture of a cement binder, a fluidizing adjuvant, granulates and water, is characterized in that the binder includes 70% to 85% by weight of Portland cement, 7% to 18% by weight of sulfo-aluminous clinker, and 6% to 14% by weight of calcium sulfate, with a calcium sulfate C$/calcium sulfo-aluminate C4A3$ molar ratio of between 5 and 7 and a water/binder ratio by weight of between 0.60 and 0.90. The self-leveling fluid screed that is thus produced has a mechanical resistance to its compression at 24 hours that is at least equal to 1 MPa, shrinkage at 7 days, measured under a relative hygrometry of 50%, less than 500 ?m/m, and an endogenic expansion value that is measured at 7 days, less than 1,000 ?m/m, as well as a very slight lifting of edges.

Abstract: Cement compositions containing biowaste ash and methods of cementing in subterranean formations using such cement compositions. Examples of suitable biowaste ash include agricultural waste ash, municipal waste ash, waste-water treatment waste ash, animal waste ash, non-human-non-animal industrial waste ash, and combinations thereof.

Abstract: A low-calcium-cementitious material having a calcium oxide content less than or equal to 10 wt % which is processed at room temperature into a low calcium cement mainly composed of mullite and a method manufacturing of the low calcium cement are provided. The low-calcium-cementitious material includes low calcium fly ash, an alkaline agent, and a congealing agent, wherein the calcium oxide content of the low-calcium-cementitious material is less than or equal to 10 wt %. The low calcium fly ash has a calcium oxide content less than or equal to 10 wt %. The low calcium cement manufacturing method includes providing a low calcium fly ash having a calcium oxide content less than or equal to 10 wt %; providing an alkaline agent; providing a congealing agent; and mixing the low-calcium-content fly ash, the alkaline agent, and the congealing agent and standing the mixture at room temperature to form a low calcium cement.

Abstract: The present invention relates to a composition including at least a Portland clinker and a Belite-Calcium-Sulphoaluminate-Ferrite clinker (BCSAF).

Abstract: Hydraulic cements, such as Portland cements and other cements that include substantial quantities of tricalcium silicate (C3S), dicalcium silicate (C2S), tricalcium aluminate (C3A), and/or tetracalcalcium alumino-ferrite (C4AF), are particle size optimized to have increased reactivity compared to cements of similar chemistry and/or decreased water demand compared to cements of similar fineness. Increasing hydraulic cement reactivity increases early strength development and release of reactive calcium hydroxide, both of which enhance SCM replacement and 1-28 day strengths compared to blends of conventional Portland cement and one or more SCMs, such as coal ash, slag or natural pozzolan. Decreasing the water demand can improve strength by decreasing the water-to-cement ratio for a given workability. The narrow PSD cements are well suited for making blended cements, including binary, ternary and quaternary blends.

Abstract: The present invention provides a ceramic porous body for in-vitro and in-vivo use comprising a composition comprising a calcium aluminate (CA) containing phase and optionally at least one of an accelerator, a retarder, a surfactant, a foaming agent, a reactive alumina, water, a fiber, and a biologically active material, and combinations thereof. Ceramic compositions are provides as well as method of using the ceramic compositions and methods of manufacturing a ceramic porous body. The ceramic porous bodies of this invention may be used as artificial bones, joints, in-vitro support structures, and in-vivo support structures for cells, tissues, organs, and nerve growth and regeneration.

Abstract: A method of treating marine or river dredging sediments, especially harbour zone sediments, whose free water content is between 40% and 80% by weight, for the purpose of obtaining a solid material which is easy to handle, includes the following successive steps: mixing the sediments with a treatment composition including a sulphoaluminate binder and at least one other component selected from a sulphate source and a catalyst of the hydration reactions of the sulphoaluminate binder; a step of setting of the mixture, leading to a compact mixture having a free water content of less than 20% by weight; then fractionating the compact mixture. The sediment thus treated may be incorporated into concrete or mortar formulas, which then have leachable fractions of less than 1% by weight.

Abstract: The present invention provides for a refractory aggregate composition comprising an improved calcium aluminate clinker having the formula CnAx wherein C is calcium oxide and A is aluminum oxide, wherein n is an integer from about 1 to about 12, wherein x is an integer from about 1 to about 24, and wherein said clinker has from zero to less than about fifty weight percent C12A7. Analogs, derivatives and hydrates of the improved calcium aluminate clinker are provided. A refractory composition and a sprayable refractory composition are disclosed comprising the improved calcium aluminate clinker. A method for improving the insulating character and/or penetration resistance of a liner in contact with molten aluminum in an aluminum manufacturing process or during aluminum transport is provided.

Abstract: It is an object of the invention to provide a cement admixture that can form concrete having a sufficient self-healing capability and satisfactorily maintaining its self-healing capability for prolonged periods. The cement admixture of the invention contains an expanding material and an alumina-silicate with swelling properties. The cement admixture is combined with cement to form a cement composition. The cement composition is mixed with water and an aggregate to provide concrete with an excellent self-healing capability.

Abstract: Compositions for fabricating architectural works wherein the compositions utilize one or more cement materials, additives, fibers and recycled glass. Exemplary cement materials include Portland cement, calcium aluminate, fly ash and/or E glass. Exemplary additives include boric acid, citric acid, lithium, plasticizer and/or methylcellulose ethers. Exemplary fibers include polyvinyl alcohol (PVA) and/or micro-fibers. Crushed recycled glass is used as an aggregate or non-reactive material. Other ingredients may be used including: sodium hydroxide, potassium hydroxide and hydrated lime to alter the PH; ferrous sulfate, mono-potassium phosphate, or manganese carbonate and magnesium sulfate as color enhancements; and/or pozzolans (Vcas) to neutralize the ASR efflorescence.

Abstract: The invention relates to a novel sulfoaluminous clinker, to a method for preparing said clinker, and to the use of said clinker for preparing a hydraulic binder and subsequently grout, concrete, or mortar.

Abstract: A calcium sulfoaluminate-based concrete with a permeability of less than 1000 Coulombs. Rapid-setting low chloride-ion permeability calcium sulfoaluminate (CSA) cements and concretes include CSA and a suitable polymer such as a sol-gel derived, organic-inorganic, silica based hybrid coating solutions of polystyrene-butylacrylate polymers containing active silanol groups protected by hydroxyl groups containing polyalcohol, or other polymers. Such polymers may be added as powders or as liquid in the finish mill. Other rapid-setting low chloride-ion permeability (CSA) cements and concretes include CSA with selected particle size distributions, and do not require use of any polymer. These CSA cements and concretes have low chloride-ion permeability, high early strength, fast setting times, low-shrinkage, and high freeze-thaw resistance.

Abstract: Disclosed are compositions and methods for providing fluid-loss control in subterranean wells. Well-completion fluids contain fine particulate additives whose glass-transition temperatures are below the anticipated bottomhole temperature. The particles soften upon injection into the well, whereupon they soften and become deformable. The particles then migrate to the borehole wall and form a seal that reduces further fluid flow from the borehole into the formation. The additive may be supplied as a powder or in the form of a liquid suspension.