Portland Type Cement Per Se (e.g., Clinker Preparation, Etc.) Patents (Class 106/739)
  • Patent number: 7972419
    Abstract: Disclosed is a method for reducing emissions from exhaust gas generated during the grinding and drying of cement raw meal as part of a cement manufacturing process. The invention comprises circuiting the exhaust gas between a raw mill and a clinker cooler. In the clinker cooler at least a portion of said emissions are delivered to a cement kiln in which said emissions are removed by being combusted and/or absorbed.
    Type: Grant
    Filed: August 7, 2008
    Date of Patent: July 5, 2011
    Assignee: FLSmidth A/S
    Inventors: Ove L. Jepsen, Steven Miller, Anthony Shave
  • Patent number: 7922779
    Abstract: The invention herein provides for an improved dye material composed of a concentrated dye element for mixture with an aqueous element prior to application.
    Type: Grant
    Filed: June 11, 2007
    Date of Patent: April 12, 2011
    Assignee: American Decorative Concrete Supply Company, Inc.
    Inventor: Clint Howle
  • Publication number: 20110067600
    Abstract: Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.
    Type: Application
    Filed: August 16, 2010
    Publication date: March 24, 2011
    Inventors: Brent R. Constantz, Kasra Farsad, Chris Camire, Irvin Chen
  • Publication number: 20110067605
    Abstract: Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.
    Type: Application
    Filed: August 16, 2010
    Publication date: March 24, 2011
    Inventors: Brent R. Constantz, Kasra Farsad, Chris Camire, Joshua Patterson, Matthew Ginder-Vogel, Karin Yaccato, John Stagnaro, Martin Devenney
  • Publication number: 20110067603
    Abstract: Provided herein are compositions and methods including hydraulic cement, supplementary cementitious material, and/or self-cementing material. Methods for making the compositions and using the compositions are provided.
    Type: Application
    Filed: August 16, 2010
    Publication date: March 24, 2011
    Inventors: Brent R. Constantz, Kasra Farsad, Chris Camire, Joshua Patterson, Miguel Fernandez, Karin Yaccato, Ryan Thatcher, John Stagnaro, Irvin Chen, Sidney Omelon, Keith Hodson, Laurence Clodic, Katharine Geramita, Terence C. Holland
  • Publication number: 20110061569
    Abstract: A method for manufacturing a cement clinker includes a rotary furnace, a cyclone preheater receiving the fumes from said rotary furnace, an air blowing clinker cooler, and at least one heat exchanger, referred to as a first heat exchanger. The raw materials are preheated and decarbonated in said cyclone preheater. The clinker is cooled in said clinker cooler. A first portion of the hot air generated by said clinker cooler, or so-called secondary air, is directed to the rotary furnace to be used as combustion air. A second portion of the hot air generated, or so-called tertiary air, is directed and carried separately from the first portion to a place in the facility where fuel is burned. A third portion of hot air generated in said clinker cooler, or so-called excess air, is carried into at least said first heat exchanger for the purpose of recovering power to produce electricity.
    Type: Application
    Filed: June 2, 2009
    Publication date: March 17, 2011
    Applicant: Fives FCB
    Inventors: Sébastien Devroe, Simon Metivier
  • Patent number: 7906028
    Abstract: Hydraulic cement compositions that include a carbonate compound composition, e.g., a salt-water derived carbonate compound composition containing crystalline and/or amorphous carbonate compounds, are provided. Also provided are methods of making and using the hydraulic cements, as well as settable compositions, such as concretes and mortars, prepared therefrom. The cements and compositions produced therefrom find use in a variety of applications, including use in a variety of building materials and building applications.
    Type: Grant
    Filed: February 4, 2010
    Date of Patent: March 15, 2011
    Assignee: Calera Corporation
    Inventors: Brent R Constantz, Cecily Ryan, Laurence Clodic
  • Patent number: 7896963
    Abstract: Self-reducing, cold-bonded pellets and a method for their production for smelting a great variety of steels, including blast furnace iron-making, non-blast furnace iron-making, and all sorts of steelmaking in steel smelting furnaces, etc. The self-reducing, cold-bonded pellets comprise iron ore concentrate, carbonaceous reducing agent, and finely divided Portland cement clinker with special requirements as binder. The components are combined together to form a mixture. Pellets are produced when the mixture is placed into a balling disc or rotating drum and water is added. Pellets with predetermined size normally ranging from about 8-16 mm are obtained by using roller screens. The pellets are then continuously placed into a curing device. Inside the curing device, the pellets will then be hydrated and carbonated by using hot gases containing carbon dioxide with a temperature range of about 100-300° C. Thereafter, after drying, the dried pellets are discharged from the curing device and will be ready for use.
    Type: Grant
    Filed: September 23, 2003
    Date of Patent: March 1, 2011
    Inventor: Hanqing Liu
  • Publication number: 20110041737
    Abstract: The invention relates to a monophase amorphous hydraulic binder containing silicon, calcium and oxygen atoms in an arrangement comprising silicate building units having an average connectedness of at least Q1, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or no more than 45 atomic percent of the silicon atoms being substituted for by a metal atom M[4]y+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2)·(M[6]x+Ox/2)]:[SiO2+M[4]y+Oy/2] having a value of 0.2 to 1.5, and the binder having less than 3.5% by weight of water, as well as a mixture containing this binder.
    Type: Application
    Filed: July 16, 2008
    Publication date: February 24, 2011
    Inventors: Guenter Beuchle, Peter Stemmermann, Uwe Schweike, Krassimir Garbev
  • Publication number: 20100282132
    Abstract: A cement composition is made from a heat activated chemical salt selected from the group consisting of magnesium oxide, potassium oxide, sodium oxide, and calcium oxide and mixtures thereof. This activated salt is the mixed with hydraulic cement in an amount of 2½ to 3½ parts activated salt to one part hydraulic cement and the resulting mixture of hydraulic cement and activated salt is mixed with water and aggregate.
    Type: Application
    Filed: May 11, 2009
    Publication date: November 11, 2010
    Inventor: Abdullah A. Al-Yateem
  • Publication number: 20100212551
    Abstract: A lightweight structural concrete includes a hydraulic binder; effective water; a superplasticizer; and aggregates; the concrete having a density in the fresh state varying from 1.40 to a Dmax value calculated according to formula (I) Dmax=1.58+(a×AM) in which “a” represents a coefficient for which the value is equal to 1; “AM” represents the mass percentage of the amorphous materials contained in 1 m3 of fresh concrete; the concrete having a maximum fresh state density Dmax less than or equal to 1.85; the concrete having a Weffective/L ratio varying from 0.19 to 0.
    Type: Application
    Filed: October 10, 2008
    Publication date: August 26, 2010
    Applicant: LAFARGE
    Inventors: Sylvain Meille, Emmanuel Bonnet, Gilles Chanvillard, Arnaud Schwartzentruber
  • Publication number: 20100193982
    Abstract: The invention relates to a process for producing a hyper-fine cement, in which cement is wet milled in a nonaqueous solvent, if appropriate in the presence of a grinding aid, as a result of which a hyper-fine cement having a particle size D50 of <1 ?m is obtained. The hyper-fine cement is suitable for sealing or strengthening porous moulded articles, rock or porous formations, in particular for the gastight sealing of natural gas reservoirs and also for making polymer materials or components composed of pressed textiles or natural fibres fire resistant.
    Type: Application
    Filed: September 5, 2008
    Publication date: August 5, 2010
    Applicant: EPG (ENGINEERED NANOPRODUCTS GERMANY) AG
    Inventors: Luis Genolet, Helmut Schmidt
  • Publication number: 20100170420
    Abstract: A method for reducing hexavalent chromium in cement comprising the addition, to said cement, of antimony (III) compounds as reducing agents.
    Type: Application
    Filed: October 26, 2007
    Publication date: July 8, 2010
    Inventors: Matteo Magistri, Potito D'Arcancgelo
  • Patent number: 7735274
    Abstract: Hydraulic cement compositions that include a carbonate compound composition, e.g., a salt-water derived carbonate compound composition containing crystalline and/or amorphous carbonate compounds, are provided. Also provided are methods of making and using the hydraulic cements, as well as settable compositions, such as concretes and mortars, prepared therefrom. The cements and compositions produced therefrom find use in a variety of applications, including use in a variety of building materials and building applications.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: June 15, 2010
    Assignee: Calera Corporation
    Inventors: Brent R. Constantz, Cecily Ryan, Laurence Clodic
  • Publication number: 20100139527
    Abstract: The process is described for the dry mixing of fibers of different types and sizes with materials formulated with cementants or agglutinant components, granular aggregates and able to include or otherwise other additional ingredients. The principal characteristics of the process are to ensure a correct incorporation of the fibers with the rest of the materials, increase the mechanical fastening of same with the rest of the components and facilitate the use of formulas with high fiber content (over-fibration).
    Type: Application
    Filed: November 21, 2006
    Publication date: June 10, 2010
    Inventor: Carlos Javier Fernandez-Garcia
  • Publication number: 20100132591
    Abstract: Hydraulic cement compositions that include a carbonate compound composition, e.g., a salt-water derived carbonate compound composition containing crystalline and/or amorphous carbonate compounds, are provided. Also provided are methods of making and using the hydraulic cements, as well as settable compositions, such as concretes and mortars, prepared therefrom. The cements and compositions produced therefrom find use in a variety of applications, including use in a variety of building materials and building applications.
    Type: Application
    Filed: February 4, 2010
    Publication date: June 3, 2010
    Inventors: Brent R. Constantz, Cecily Ryan, Laurence Clodic
  • Patent number: 7708825
    Abstract: The technical field of the invention belongs to concrete and cement. The invention relates to a sialite binary wet cement and its package, transportation, storage and application. The sialite binary wet cement is composed of a “female body” as a primary component and a “male body” as a secondary component both of which are produced, stored, and transported separately, and are mixed together when they are used, wherein the “female body” and the “male body” each have a specific surface area of 2800-7500 cm2/g, the “female body” is mainly composed of inorganic cementitious materials and water, and it is in slurry, paste or wet powder form during the whole period of its production, storage, transportation and usage; the “male body” is mainly composed of inorganic cementitious materials, and it can be a wet form or a dry powder form. When they are used, the “female body” and the “male body” are mixed together with a small amount of regulating agents.
    Type: Grant
    Filed: December 24, 2003
    Date of Patent: May 4, 2010
    Assignee: Tsinghua University
    Inventors: Henghu Sun, Weirui Xu, Guangju Gai, Shuqin Li
  • Publication number: 20100071598
    Abstract: The carbon monoxide and hydrocarbon content of flue gas in a cement clinker production apparatus is lowered by feeding a high velocity stream of hot oxygen into the flue gas. Methods and apparatus for producing the hot oxygen stream are disclosed.
    Type: Application
    Filed: September 25, 2008
    Publication date: March 25, 2010
    Inventors: Stefan Ernst Friedrich Laux, Lee Jonathan Rosen
  • Patent number: 7682447
    Abstract: The carbon monoxide and hydrocarbon content of flue gas in a cement clinker production apparatus is lowered by feeding a high velocity stream of hot oxygen into the flue gas. Methods and apparatus for producing the hot oxygen stream are disclosed.
    Type: Grant
    Filed: September 25, 2008
    Date of Patent: March 23, 2010
    Assignee: Praxair Technology, Inc.
    Inventors: Stefan Ernst Friedrich Laux, Lee Jonathan Rosen
  • Publication number: 20100050906
    Abstract: To provide a cement clinker production line with a calcining stage which is connected upstream of the rotary tubular kiln and has an integrated calcining combustion chamber, with formation of a CO-containing reduction zone whose size and length and reduction potential can be adapted with simple means to different NOx contents contained in the rotary kiln exhaust gas and/or different types of material and pellet sizes of the secondary fuels used in the calcining combustion chamber, the calcining combustion chamber may have an upper, raw-meal-free reducing zone with a feed for secondary fuels arranged at the upper side of the combustion chamber, and first tertiary partial airstream with sub-stoichiometric fuel combustion for the purpose of gasifying the secondary fuels, and the combustion chamber may have a lower zone, the inflow for at least one raw meal partial stream and one second tertiary partial airstream being arranged in the junction region of the upper raw-meal-free, reducing zone and the lower zone, t
    Type: Application
    Filed: November 29, 2006
    Publication date: March 4, 2010
    Inventors: Heiko Schürmann, Carsten Eckert
  • Publication number: 20090194005
    Abstract: A cementitious composition capable of forming high early strength cement when admixed with water may comprise, for each 100% by weight, no more than about 60% by weight C3S, at least about 4% by weight C2S, and between about 7% and about 11% by weight SO3, wherein the cementitious composition has a particle size distribution such that substantially all of its particles are of a size of about 10 microns or smaller. A cementitious composition may have a ratio of weight % SO3 to weight % Al2O3 of at least about 1.5 and a particle size distribution such that substantially all of its particles are of a size of about 10 microns or smaller. An apparatus and method for making such a cementitious composition are also described.
    Type: Application
    Filed: February 4, 2008
    Publication date: August 6, 2009
    Inventors: Louis U. Spellman, Jose Garcia
  • Patent number: 7553155
    Abstract: Apparatus and method for the production of cement clinker, wherein raw meal is preheated in a heat exchanger and is burnt in a kiln to form cement clinker and the exhaust gases from the kiln flow in succession through the heat exchanger and a catalytic converter, wherein the exhaust gases are analysed before and/or after the catalytic converter arid the preheated raw meal is precalcined in a calciner. Moreover, for the subsequent catalytic exhaust gas purification the provision of a calciner has the advantage that higher exhaust gas temperatures are produced so that a throughput is produced. As a result the required volume of the catalytic converter is reduced and the investment costs are lowered.
    Type: Grant
    Filed: February 21, 2005
    Date of Patent: June 30, 2009
    Assignee: Polysius AG
    Inventors: Richard Erpelding, Guenter Driemeier
  • Publication number: 20090078161
    Abstract: A method of reducing plastic shrinkage cracking in concrete compositions that includes a) combining 3-40 volume percent cement, 5-50 volume percent fine aggregate, 5-50 volume percent coarse aggregate, and 10-22 volume percent water to form a concrete mixture; b) during or after (a), adding 1.5-40 volume percent of prepuff particles to the concrete mixture to form a concrete composition; c) placing the concrete composition in a form; and d) allowing the concrete to set and harden to form a hardened concrete article substantially free of plastic shrinkage cracking. The prepuff particles have an average particle diameter of from 0.2 mm to 8 mm, a bulk density of from 0.02 g/cc to 0.64 g/cc, an aspect ratio of from 1 to 3. The concrete composition has a density of from about 40 to about 135 lb./ft3.
    Type: Application
    Filed: September 17, 2008
    Publication date: March 26, 2009
    Applicant: NOVA CHEMICALS INC.
    Inventors: Daniel Woolfsmith, Larry Chappell, Luke Kimble
  • Publication number: 20090071374
    Abstract: A dry mix cement composition including an alkaline multi-phase aluminosilicate material, wherein the alkaline multi-phase aluminosilicate material provides a source of alkaline and soluble silicate to the cement composition.
    Type: Application
    Filed: September 26, 2008
    Publication date: March 19, 2009
    Applicant: ZEOBOND RESEARCH PTY LTD
    Inventors: Jan Stephanus Jakob Van Deventer, Dingwu Feng, Peter Duxson
  • Publication number: 20080282938
    Abstract: A method of making cement clinker in a wet rotary kiln that includes providing raw material at the front of the kiln and adding a second group of materials for processing at an intermediate location along the kiln. This second group may include materials that improve the clinker and requires less energy to produce. A kiln system that employs this method and a cement clinker made by the method.
    Type: Application
    Filed: August 1, 2008
    Publication date: November 20, 2008
    Inventors: Victor H. Cifuentes, Kenneth A. DeWitt, JR., Frederick P. Hommel, Anthony Santamaria, Barry A. Rowland
  • Patent number: 7445668
    Abstract: The invention relates to a hydraulic binder containing, in percentage by weight: from 1.1 to 9% of tricalcium aluminate from 1.5 to 13.5% of tetracalcium ferroaluminate from 0.5 to 1.5% of dodecacalcium heptaaluminate from 0.5 to 1.5% of tetracalcium trialuminate sulphate from 0 to 0.8% of dicalcium silicoaluminate from 5 to 70% of pozzolanic material(s) from 0 to 6% of calcium sulphate the remainder being composed of the non-aluminous constituents of at least one Portland-type clinker. It also relates to concretes or mortars prepared using a binder of this type.
    Type: Grant
    Filed: October 16, 2006
    Date of Patent: November 4, 2008
    Assignee: VICAT
    Inventor: Denis Sommain
  • Publication number: 20080245275
    Abstract: The invention relates to a device and a method for producing clinker from raw cement material. The raw cement material is preheated in a preheater, is precalcined in a calcining apparatus, is completely burned in a sintering furnace, and is final cooled in a cooler Tertiary air of the cooler is fed to the calcining apparatus while eliminated dust is thermally treated in a dust burning reactor with the aid of combustion air and fuel. At least some of the tertiary air is fed to the dust burning reactor as combustion air while the dust that is to be treated and the combustion air penetrate the dust burning reactor in the same direction of flow.
    Type: Application
    Filed: August 25, 2006
    Publication date: October 9, 2008
    Inventors: Markus Mohr, Christoph Beyer
  • Publication number: 20080223259
    Abstract: The invention relates generally to a cement or gypsum composition having improved properties, which is prepared by incorporating an enzyme into a cement material such as a cement, motar, or concrete, or into a gypsum product. The invention also relates to methods of manufacturing improved cement compositions and gypsum products, methods of improving the compressive strength of cement compositions and gypsum products, and methods of reducing the cost of such compositions by enabling the use of less expensive aggregates in the manufacturing process. More specifically, the invention relates to a cement composition or a gypsum composition, optionally including at least one aggregate and optionally including at least one pozzolan, comprising a cement material or gypsum optionally including aggregate(s) and pozzolan(s) having blended therein an enzyme.
    Type: Application
    Filed: August 29, 2006
    Publication date: September 18, 2008
    Inventor: Josef Atoon
  • Publication number: 20080190328
    Abstract: A cement clinker which necessitates no considerable change in the main chemical components and mineral components of cement, is free from preheater coating problems and adverse influences on cement properties, and is effective in reducing the heat quantity required for burning; and a process for producing the cement clinker. In the process for cement clinker production a substance having a melting point higher than the temperature of a liquid phase of the cement clinker and serving as crystal nuclei for C3S is incorporated include a fine powder of refractory brick, particles of an ordinary Portland cement clinker, a fine powder of a high-early-strength Portland cement clinker, a high-early-strength Portland cement, and a fine powder of quicklime. Due to this, alite generation is accelerated even at a low temperature. As a result, high-quality clinker can be produced through burning using a small unit heat quantity and no decrease in cement quality results.
    Type: Application
    Filed: December 2, 2005
    Publication date: August 14, 2008
    Applicant: MITSUBISHI MATERIALS CORPORATION
    Inventors: Etsuro Asakura, Kenichi Shimosaka, Makio Yamashita, Ryuichi Komatsu
  • Patent number: 7410537
    Abstract: Accordingly, the present invention provides an improved process for the production of Portland slag cement using granulated blast furnace slag, which comprises: (viii) forming of cement clinker by known process, (ix) ball-milling of cement clinker for a period ranging between 30-60 minutes in dry condition, (x) reducing size of granulated blast furnace slag by any process to obtain the size in the range between 210 to 100 ?m for using as feed for attrition mill, (xi) wet milling of granulated blast furnace slag for a period ranging between 5-15 minutes in an attrition mill using granulated blast furnace slag to water ratio in the range of 1:1 to 1:2 and granulated blast furnace slag to grinding bail ratio in the range of 1:5 to 1:15, (xii) removing water from the slurry obtained after attrition milling by known process, (xiii) drying of the obtained slurry by known process, (xiv) mixing intimately of: attrition milled slag obtain in step (vi) in the range of: 50 to 95% by weight ball-milled clinker obtain
    Type: Grant
    Filed: July 25, 2006
    Date of Patent: August 12, 2008
    Assignee: Council of Scientific & Industrial Research
    Inventors: Rakesh Kumar, Sanjay Kumar, Amitava Bandopadhaya, Surya Pratap Mehrotra
  • Publication number: 20080156225
    Abstract: A cementitious composition including cement, water, and a rheology modifying additive (RMA) is provided. The inclusion of the RMA improves the cementitiuous composition's response to vibration, and dampens out differences due to minor fluctuations in initial slump of the composition. The RMA may include a dispersant for cementitiuous compositions. The cementitious composition may optionally include other admixtures or additives known in the industry. A method for making the cementitious composition is also provided.
    Type: Application
    Filed: December 5, 2007
    Publication date: July 3, 2008
    Inventor: Jeffrey R. Bury
  • Patent number: 7390357
    Abstract: Described is a method for manufacturing cement clinker by which method cement raw meal is preheated and burned in a plant comprising a cyclone preheater (1) and a kiln (5). The method is peculiar in that that at least a portion of the raw meal is extracted from the cyclone preheater (1), that this raw meal is introduced into a separate unit (21) in which it is given a retention time under oxidating conditions provided by means of a gas stream for forming SO2 and for expelling organic carbon, that the formed SO2 and the expelled organic carbon are subsequently discharged from the separate unit (21) entrained in the gas stream for further treatment in a subsequent process stage, and that the raw meal is reintroduced into the cyclone preheater (1). Hereby is obtained an effective reduction of the VOC, CO as well as the SO2 emission without necessitating utilization of additional energy for heating.
    Type: Grant
    Filed: July 11, 2003
    Date of Patent: June 24, 2008
    Assignee: F.L.Smidth A/S
    Inventors: Lars Skaarup Jensen, Jens Peter Hansen
  • Patent number: 7384475
    Abstract: Described is a method as well as a plant for preheating particulate or pulverulent material such as cement raw meal or similar material in a cyclone preheater (1), comprising at least two cyclone stages, each comprising a riser duct (2a, 2b, 2c, 2d) and a cyclone (1a, 1b, 1c, 1d). The method is peculiar in that a portion of the material which is fed to at least one cyclone stage is introduced to the first part of the riser duct, viewed in the direction of travel of the exhaust gases, and is heated from a temperature of maximum 450° C. to a temperature of at least 550° C., and in that the remaining material which is fed to the same cyclone stage is introduced into the last part of the said riser duct. As a result, there will be a reduction in the amount of SO2 which is discharged from the cement plant preheater as emission, without a simultaneous increase in energy consumption.
    Type: Grant
    Filed: August 30, 2004
    Date of Patent: June 10, 2008
    Assignee: F. L. Smidth A/S
    Inventors: Lars Skaarup Jensen, Jens Peter Hansen
  • Publication number: 20080127863
    Abstract: The invention concerns the addition of ammonia to cement, thereby increasing the cement's tensile strength and flexibility. More flexible cement, whether used by itself or in conjunction with other materials in cementitious compositions, is useful in a wide range of applications.
    Type: Application
    Filed: October 24, 2007
    Publication date: June 5, 2008
    Inventors: Mark A. Webb, Stephen M. Hubbard
  • Patent number: 7335253
    Abstract: The invention provides a process for preparing a sulphur cement product comprising the following steps: (a) selectively oxidising hydrogen sulphide to elemental sulphur by contacting, in a reaction zone, a hydrogen sulphide containing feed gas and a molecular-oxygen containing gas with a particulate oxidation catalyst under selective oxidation conditions; (b) discharging a stream comprising liquid and/or solid elemental sulphur and particulate oxidation catalyst from the reaction zone; (c) admixing the stream comprising elemental sulphur and particulate oxidation catalyst with at least any one of elemental sulphur, a sulphur cement filler, a sulphur cement modifier, or aggregate at a temperature at which sulphur is molten; (d) solidifying the mixture obtained in step (c) by cooling it to a temperature below the melting temperature of sulphur to obtain the sulphur cement product.
    Type: Grant
    Filed: March 29, 2006
    Date of Patent: February 26, 2008
    Assignee: Shell Oil Company
    Inventors: Carolus Matthias Anna Maria Mesters, Marinus Johannes Reynhout, Guy Lode Magda Maria Verbist
  • Publication number: 20080022903
    Abstract: Accordingly, the present invention provides an improved process for the production of Portland slag cement using granulated blast furnace slag, which comprises: (viii) forming of cement clinker by known process, (ix) ball-milling of cement clinker for a period ranging between 30-60 minutes in dry condition, (x) reducing size of granulated blast furnace slag by any process to obtain the size in the range between 210 to 100 ?m for using as feed for attrition mill, (xi) wet milling of granulated blast furnace slag for a period ranging between 5-15 minutes in an attrition mill using granulated blast furnace slag to water ratio in the range of 1:1 to 1:2 and granulated blast furnace slag to grinding bail ratio in the range of 1:5 to 1:15, (xii) removing water from the slurry obtained after attrition milling by known process, (xiii) drying of the obtained slurry by known process, (xiv) mixing intimately of: attrition milled slag obtain in step (vi) in the range of: 50 to 95% by weight ball-milled clinker obtain
    Type: Application
    Filed: July 25, 2006
    Publication date: January 31, 2008
    Inventors: Rakesh Kumar, Sanjay Kumar, Amitava Bandopadhaya, Surya Pratap Mehrotra
  • Patent number: 7160384
    Abstract: An exemplary method of the invention comprises introducing into a grinding mill, wherein cement clinker is ground to provide cement powder, a diamine such as tetrahydroxylethylethylene diamine, and an alkanolamine such as triethanolamine or triisopropanolamine. The combination of the diamine and alkanolamine provides superior grinding efficiency compared to diamine or alkanolamine added separately.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: January 9, 2007
    Assignee: W.R. Grace & Co.-Conn.
    Inventor: Leslie A. Jardine
  • Patent number: 7037368
    Abstract: A method for the production of cement clinker comprises the introduction of non-traditional materials into the kiln, preferably at a mid-kiln locations. The non-traditional materials are materials that are difficult, expensive or environmentally challenging for disposal. In one embodiment, weathered clinker is introduced into the kiln to admix with the raw material mix to augment clinker production. In another embodiment, bird, animal or human manure is added to the kiln so that gaseous reducing agents can be released by the manure and combine with certain noxious gases generated during the clinker production, to thereby reduce the noxious gas output. In other embodiments, other non-traditional waste-derived fuels are added to the kiln during clinker production, including railroad ties coated with creosote, industrial, commercial and consumer rubber components, such as rubber hoses, unshredded plastics, and organic materials, such as bird and animal meal.
    Type: Grant
    Filed: April 29, 2004
    Date of Patent: May 2, 2006
    Assignee: Buzzi Unicem USA, Inc.
    Inventor: Lawrence L. Hoffis
  • Patent number: 7017755
    Abstract: Rear ends of pushing rods 40 are axially connected to a support base 50, which is movably engaged with guide rails 60. A drive unit 70 is disposed to rotatably move wire belts 74 between wheels 73 and 71 at longitudinal front and rear ends of the guide rails 60, and the support base 50 is connected to the wire belts 74. The drive unit 70 is activated to guide the pushing rods 40 by the guide rails 60 so to make pushing and pulling operation of the pushing rods 40. A door 33 which is disposed at the back wall of a static grate 31 in a clinker cooler 30 is opened to fit the pushing rods 40 into a seal material 34 on the opening to push a large lump of coating C2 retained on the static grate 31. The pushing rods 40 have a double tube structure and are cooled by injecting cooling water from supply pipes 45.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: March 28, 2006
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Masura Nakamura, Tsuyoshi Yamamoto, Asaaki Nishioka, Shigetoshi Toyooka, Yasufumi Matsuo, Shunichi Nagasaki
  • Patent number: 7001454
    Abstract: The present invention relates to a family of white clinker compositions with a high capacity to fix sulfur derived from a high sulfur content pet-coke used as fuel in the manufacture thereof, which further exhibits low fuel composition and fast setting, achieved by being comprised of the following amounts of clinker phases in percentage by weight: 3CaO.SiO2 (C3S): 40 to 75, 2CaO.SiO2 (C2S): 10 to 35, 3CaO.Al2O3 (C3A): 0 to 15, CaO.SO3 (CS): 0 to 10, 4CaO.3Al2O3.SO3 (C4A3{hacek over (S)}): 2 to 15, 11CaO.7Al2O3.CaF2 (C11A7.CaF2): 0 to 5, total % CaF2: 0.3 to 1.5 measured as CaF2, % Fe2O3: 0 to 0.5 and a SO3 content between 1.5 to 5% by weight obtained through the calcination of a raw meal containing CaO, SiO2, Al2O3, and CaF2, using as fuel, pet-coke with a sulfur content higher than 5% and at temperatures between 2192 and 2462° F., without the addition of essentially additive containing SO3 in the raw meal.
    Type: Grant
    Filed: December 10, 2003
    Date of Patent: February 21, 2006
    Assignee: Cemex Trademarks Worldwide, Ltd.
    Inventors: Waltter Lopez-Gonzales, Carlos Enrique Castillo-Linton, Graciela Eguia-Marquez
  • Patent number: 6936098
    Abstract: A process for producing blended cement in which the cement contains Portland Cement mixed thoroughly with a microfiller, and possibly a water reducing agent, to provide a dry cement mixture, and fine supplementary cementitious materials selected from the materials blast furnace slag, fly ash, quartz, silica, amorphous silicon dioxide, limestone, and recycled concrete. The supplementary materials are first subjected to a grinding step in a dry state to a specific surface of at least 1000 cm2/g (Blaine). In a second step the ground supplementary materials are subjected to a grinding step together with at least 20% by weight of the total grinding mass of a highly reactive cement mixture in a dry state, to achieve a specific surface of at least 3000 cm2/g (Blaine).
    Type: Grant
    Filed: April 30, 2003
    Date of Patent: August 30, 2005
    Assignee: Procedo Enterprises Etablissement
    Inventor: Vladimir Ronin
  • Patent number: 6908507
    Abstract: A process is disclosed for producing cement clinker, comprising the steps of: a) providing a mixture of ground calcareous materials and ground argillaceous materials; b) heating the mixture of step a) to a temperature sufficient to calcine and fuse the ground materials to form the cement clinker, and thereby producing an exhaust gas containing CO2; c) catalysing the hydration of at least a portion of the CO2 contained in the exhaust gas and producing a solution containing bicarbonate ions and hydrogen ions; and d) adding to the solution obtained in step c) metal ions, and adjusting the pH of the solution to precipitate a carbonate or said metal. Preferably, the metal ions are Ca++ obtained from the dissolution of a material selected from the group consisting of CaCl2, cement kiln dust and sea salts and the carbonate is CaCO3 which is advantageously recycled into the process by adding the CaCO3 to the mixture of step a). A cement plant for performing this process is also disclosed.
    Type: Grant
    Filed: April 12, 2002
    Date of Patent: June 21, 2005
    Assignee: CO2 Solution Inc.
    Inventors: Jean-Marie Lalande, Anne Tremblay
  • Patent number: 6875267
    Abstract: In order to make sure, for cement clinker production lines with blown injection of dispersible solid fuels such as, for example, coal dust, into the calcinator which is provided with fuel, that an open flame does not occur at the fuel injection point, it is proposed according to the invention that the fuel is fed into a meal intake box that has a sloping raw meal chute and deflector slide and is arranged on the outside of the calcinator and connected to it through a wall opening and the fuel is pre-mixed with the pre-heated raw meal there, and then introduced via the deflector slide into the reaction section of the calcinator in order to form a gas-raw meal-solid fuel-suspension that is uniformly distributed.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: April 5, 2005
    Assignee: KHD Humboldt Wedag AG
    Inventors: Claus-Jürgen Steffler, Wolfgang Müller, Stefan Köllen
  • Patent number: 6863837
    Abstract: The present invention provides a sulfonated coal tar distillate salt polymer that is a condensation product of an aldehyde, preferably formaldehyde, and a sulfonated middle fraction obtained during coal tar distillation. The middle fraction includes from about 40% to about 95% by weight naphthalene and from about 5% to about 60% by weight of a plurality of compounds selected from the group consisting of quinoline, indene, biphenyl, indane, acenaphthene, anthracene, phenanthrene, methyl naphthalene, cresol, phenol, xylenol, and tetralin. The present invention also provides a method of forming a sulfonated coal tar distillate salt polymer.
    Type: Grant
    Filed: August 5, 2002
    Date of Patent: March 8, 2005
    Assignee: GEO Specialty Chemicals, Inc.
    Inventors: Arpad Savoly, Dawn P. Elko, Bennie Veal, Michelle L. McMahon, David B. Heller, Jr.
  • Patent number: 6776839
    Abstract: A slag cement having an improved early strength and containing aluminosilicates, blast furnace slag, clinker and CaSO4, has a content of 70 to 95% by weight of blast furnace slag used in the ground form at >4,500 Blaine (cm2/g) with no more than half of this portion being substitutable by aluminosilicates such as fly ash, alumina, marl or the like, 0.1 to 2% by weight of clinker, sulfate in amounts of below 5% by weight, calculated as SO3, and 0.3 to 1% by weight of a superliquifier such as, e.g., naphthalene sulfonate.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: August 17, 2004
    Inventor: Suz-Chung Ko
  • Publication number: 20040129181
    Abstract: A process is disclosed for producing cement clinker, comprising the steps of: a) providing a mixture of ground calcareous materials and ground argillaceous materials; b) heating the mixture of step a) to a temperature sufficient to calcine and fuse the ground materials to form the cement clinker, and thereby producing an exhaust gas containing CO2; c) catalysing the hydration of at least a portion of the CO2 contained in the exhaust gas and producing a solution containing bicarbonate ions and hydrogen ions; and d) adding to the solution obtained in step c) metal ions, and adjusting the pH of the solution to precipitate a carbonate or said metal. Preferably, the metal ions are Ca++ obtained from the dissolution of a material selected from the group consisting of CaCl2, cement kiln dust and sea salts and the carbonate is CaCO3 which is advantageously recycled into the process by adding the CaCO3 to the mixture of step a). A cement plant for performing this process is also disclosed.
    Type: Application
    Filed: October 14, 2003
    Publication date: July 8, 2004
    Inventors: Jean-Marie Lalande, Anne Tremblay
  • Patent number: 6752865
    Abstract: The present invention describes a process for manufacture of high iron hydraulic cement clinker in production of cement and cementation binder for application in construction activity and in metallurgical industry for sintering of iron ore fines and making cold bonded briquettes and pellets. The process is cost effective and flexible for utilization of wide varieties of raw material consisting of lime and iron in production of high iron cements for different applications.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: June 22, 2004
    Assignee: Council of Scientific and Industrial Research
    Inventors: Bansidhar Nayak, Vibhuti Narayan Misra
  • Patent number: 6749681
    Abstract: In a method of producing cement clinker and electricity, cement raw mix and hydrocarbon are fed in a circulating fluidized bed boiler (1). Therein cement raw mix is calcined and steam is produced. Gas and solids out of the fluidized bed enter a cyclone (8), the solids being separated therein and returned to the bed. Part of those solids are first cooled down in a solids heat exchanger (9) producing steam. Fly ash consisting predominantly of lime and gas escaping the cyclone are passed through a heat exchanger (28, 33) and a filter (37). Hot bed material is discharged from the circulating fluidized bed and is ground with additives, then blended with lime being separated in the filter (37), then supplied to a rotary kiln (16), wherein the solids are clinkered. The produced steam is fed to a steam turbine island (42).
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: June 15, 2004
    Assignee: Alstom Technology LTD
    Inventors: Vassilios Burdis, Shin G. Kang, Srivats Srinivasachar, Majed Toqan
  • Patent number: 6740157
    Abstract: A method for the production of cement clinker comprises the introduction of vitrified slag into the feedstock stream prior to the clinkering zone. The addition of vitrified slag can increase the clinker output rates and/or reduce the energy requirements for maintaining the kiln temperatures. In one embodiment, the vitrified slag is a vitrified blast furnace slag.
    Type: Grant
    Filed: July 2, 2002
    Date of Patent: May 25, 2004
    Assignee: Lone Star Industries, Inc.
    Inventor: Ronald Piniecki
  • Patent number: 6709510
    Abstract: A process for forming cement clinker using mill scale that may have hydrocarbons associated therewith. Normal feedstock material is preheated and then transferred to a combustion area. The mill scale is also transferred to the combustion area where, during the process of burning a material, the unwanted hydrocarbons are volatilized and converted to harmless gaseous products (by combustion) that can be passed to the atmosphere. The combustion area may be a precalciner or may be the feed end of the rotary kiln if the rotary kiln has an adequate temperature profile. The remaining mill scale and feedstock material are thoroughly mixed and blended and the mill scale is diffused and combined with the feedstock material as the mill scale and the feedstock material move from the feed end toward the heat-source end of the rotary kiln to form cement clinker.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: March 23, 2004
    Assignee: Texas Industries, Inc.
    Inventors: Rom D. Young, David Norris