Plasticizer Or Adhesive Coating Patents (Class 131/343)
  • Patent number: 5012828
    Abstract: A tobacco smoke filter comprising a rod of tobacco smoke filtering material incorporating particulate additive, wherein at least some of the particulate additive is concentrated on one or a restricted number of threads and/or strips incorporated within the remaining body of filtering material, the additive adhering to said thread(s) and/or strip(s).
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: May 7, 1991
    Inventors: Ernest B. Hayes, Paul F. Clarke
  • Patent number: 5000198
    Abstract: An agent for removing noxious tobacco components is disclosed, which is attached to or sprinkled over sliced tobacco leaves when producing a cigarette. The agent is produced by mixing menthol in the form of crystalline menthol microcapsules, disodium glycrrhizinate, confree particles, perleloxyantoxyn, stearic acid B in the form of particles, maltol, glove-aniline, lecithin, ammonium benzoate, vanillin, calcium carbonate, corn starch and beans in the form of particles.
    Type: Grant
    Filed: June 13, 1989
    Date of Patent: March 19, 1991
    Inventor: Mituo Nakajima
  • Patent number: 4924887
    Abstract: Tobacco containing cigarette filter plugs comprise strands of tobacco material which are bound with an activated binding agent. The filter plugs exhibit good firmnless and integrity, and provide cigarettes exhibiting a unique tobacco taste. Filter plugs are prepared by forming an intimate admixture of tobacco material and binding agent, forming rods and activating the binding agent.
    Type: Grant
    Filed: February 3, 1986
    Date of Patent: May 15, 1990
    Assignee: R. J. Reynolds Tobacco Company
    Inventors: Mark L. Raker, Andrew J. Sensabaugh, Jr., Stephen W. Jakob
  • Patent number: 4907609
    Abstract: Filter element and method for increasing the hardness thereof by contacting filter plug material with effective amounts of (a) a water soluble resin (or copolymer) having available chelate bond-forming chemical groups and (b) a water soluble nontoxic salt, the metal cation of the nontoxic salt forming a chelate bond with the chelate bond-forming chemical groups of said water soluble resin.
    Type: Grant
    Filed: August 24, 1988
    Date of Patent: March 13, 1990
    Assignee: Hercules Incorporated
    Inventors: Richmond R. Cohen, Jimmie D. McCarty
  • Patent number: 4896683
    Abstract: A method for controlling nicotine delivery through a cigarette filter relative to total particulate pass-through concentration, and the corresponding filter utilizing, as a filter modifier component, at least one water-soluble metal salt of a weak acid, the choice and amount of salt within the filter favoring an alkaline pH exceeding about pH 8, the amount of alkalinity being correlated to the desired amount of nicotine pass-through while corresponding nicotine filter retention properties are keyed to the presence and concentration of a water soluble salt of a strong acid within the filter.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: January 30, 1990
    Assignee: Hercules Incorporated
    Inventors: Richmond R. Cohen, David J. Gibboni
  • Patent number: 4821750
    Abstract: Skinless shaped articles having increased specific surface area and based on cellulose esters, including both solid and hollow fibers, can be produced with at least one surface having a striated or fibrous appearance and a cellular interior structure by extruding a spinning solution comprising a cellulose ester and a solvent therefor directly into an aqueous bath, wherein the residual content of solvent in the bath is maintained at a concentration below a critical level, preferably less than about 10 weight percent.
    Type: Grant
    Filed: November 16, 1987
    Date of Patent: April 18, 1989
    Assignee: Celanese Corporation
    Inventor: Colin L. Browne
  • Patent number: 4770193
    Abstract: A smoke filter and a method for manufacturing the filter from a continuous multifilament filter tow are described in which a portion of the filter tow is treated with a dye to impart color to a discrete elongated zone of dye-treated filaments that is in substantial alignment with the longitudinal axis of the smoke filter.
    Type: Grant
    Filed: February 17, 1987
    Date of Patent: September 13, 1988
    Assignee: R. J. Reynolds Tobacco Company
    Inventor: James W. Pryor
  • Patent number: 4763674
    Abstract: Method for reducing normal concentrations of hydrogen cyanide and/or nitrogen oxide by-products in cigarette smoke, by using, as garniture feed for a cigarette filter rod-making apparatus, one or more substrates, one or more surfaces thereof being treated by applying thereto an effective amount of at least one of(A) a solution, emulsion or dispersion of at least one of sodium bicarbonate, sodium carbonate, potassium permanganate, manganese dioxide in a nonionic spin solution;(B) glycerol triacetate;and corresponding filter element and cigarette utilizing a filter formed of such substrate(s).
    Type: Grant
    Filed: April 16, 1986
    Date of Patent: August 16, 1988
    Assignee: Hercules Incorporated
    Inventor: Michael D. Lelah
  • Patent number: 4752348
    Abstract: A continuous rod of a product such as a cigarette filter material is coated with a treating liquid by being passed axially through a cylindrical applicator zone comprising a permeable cylindrical wall, the cylindrical wall being concentrically enclosed within a reservoir and manifold zone connected to a source of liquid. The feed supply for the liquid additive can be pressurized and/or heated, so that application of the additive can be in either liquid or vapor form. The process and apparatus of this invention may be used alone or in conjunction with prior art homogeneous applicators and processes.When used to apply a plasticizer to a rod of continuous filament tow, e.g. for use in producing cigarette filters, annular regions of varying concentrations of the plasticizer are produced in the rod. A relatively dense region of plasticized fiber can be produced on the outside of the filter. Filter rods having wrapping paper uniformly adhered about the periphery of the rod can be produced.
    Type: Grant
    Filed: November 12, 1986
    Date of Patent: June 21, 1988
    Assignee: Celanese Corporation
    Inventors: Ronald O. Bryant, William L. Millen, Robert E. Swander
  • Patent number: 4729390
    Abstract: Disclosed are tobacco smoke filtering materials for selectively removing deleterious material from tobacco smoke without at the same time removing desirable smoke vapors which contribute to aroma and taste. The filtering materials comprise a fibrous article, the fibers of which have a coating on the surfaces thereof comprising a compound of the formula ##STR1## wherein R.sub.1 is the residue of a straight chain fatty acid having 8-22 carbon atoms and R.sub.2 is OH or ##STR2## wherein Ac is an acetyl group.
    Type: Grant
    Filed: July 31, 1985
    Date of Patent: March 8, 1988
    Assignee: Eastman Kodak Company
    Inventor: Robert C. Mumpower, II
  • Patent number: 4655230
    Abstract: A continuous rod of a product such as cigarette filter material is coated with a treating liquid by being passed axially through a cylindrical applicator zone comprising a permeable cylindrical wall, the cylindrical wall being concentrically enclosed within a reservoir and manifold zone connected to a source of liquid. The feed supply for the liquid additive can be pressurized and/or heated, so that application of the additive can be in either liquid or vapor form. The process and apparatus of this invention may be used alone or in conjunction with prior art homogeneous applicators and processes.When used to apply a plasticizer to a rod of continuous filament tow, e.g. for use in producing cigarette filters, annular regions of varying concentrations of the plasticizer are produced in the rod. A relatively dense region of plasticized fiber can be produced on the outside of the filter. Filter rods having wrapping paper uniformly adhered about the periphery of the rod can be produced.
    Type: Grant
    Filed: March 29, 1985
    Date of Patent: April 7, 1987
    Assignee: Celanese Corporation
    Inventors: Ronald O. Bryant, William L. Millen, Robert E. Swander
  • Patent number: 4614199
    Abstract: A tobacco smoke filter includes a smoke pervious rod of plastic material about which a smoke impervious plastic overwrap film is extruded. In the preferred embodiment, the overwrap and the rod are made of the same material, e.g., cellulose acetate. By using the same material, waste from the normal filter-making processes can be formed into granules or pellets and rendered molten for re-cycling as the raw material for the overwrap film. The resulting filter can be used with or without a tipping paper cover and can be perforated or not, as desired, to ventilate the filter rod.
    Type: Grant
    Filed: November 23, 1982
    Date of Patent: September 30, 1986
    Assignee: American Filtrona Corporation
    Inventor: Richard M. Berger
  • Patent number: 4579130
    Abstract: A process is provided for producing cigarette filters which exhibit desired adhesion properties between the filter fibers, and which may be subjected to a substantially broader operating range during a temperature melt fusion step. A crystalline propylene polymer and a second crystalline polymer are mixed together, and the blend is extruded into fibers which are then heated to a temperature above the original melting point of the second crystalline polymer and below the original melting point of the crystalline propylene polymer. The fibers are twisted and/or crimped to effectuate desired adhesion between the fibers and are subsequently formed into filter rods which display greatly increased cohesiveness.
    Type: Grant
    Filed: December 22, 1983
    Date of Patent: April 1, 1986
    Assignee: Shell Oil Company
    Inventor: Paul M. Coffman
  • Patent number: 4521493
    Abstract: A resin-modified fiber filter formulation, fiber filter element, and method for improving dimensional stability, firmness and resiliency of a polyolefin fiber filter element comprised of crimped polyolefin fiber tow, by contacting filaments thereof with a formulation comprising a blend of resin and base polymer emulsions as precursors forming the active formulation "in situ", at a convenient station by removing water, the solid resin component of which must have a low molecular weight and approved softening temperature range to obtain the desired characteristics.Typical resins are polyterpenes and hydrogenated rosin esters; typical base polymers are polyvinyl acetate and copolymers thereof with, e.g., ethylene or acrylates.
    Type: Grant
    Filed: January 12, 1984
    Date of Patent: June 4, 1985
    Assignee: Hercules Incorporated
    Inventor: Jay B. Class
  • Patent number: 4498485
    Abstract: Methods and compositions are provided for preparing stabilized interferons and for combining stabilized interferon with cigarettes. Special domains of the interferon molecule are recognized by methods which are described. A means for constructing these domains by recombinant DNA technology is detailed. A method for stabilizing natural interferons is also described. A process for combining the stabilized interferon with cigarettes is presented.The combination of interferons and cigarettes is synergistic, especially because interferon effects are magnified at elevated temperatures and because interferon has a preferential effect on tumor cells, but for other reasons as well. The process is not obvious and will be beneficial to a large segment of mankind; those who use tobacco products.
    Type: Grant
    Filed: August 5, 1982
    Date of Patent: February 12, 1985
    Assignee: Hem-Sub, Inc.
    Inventor: William A. Carter
  • Patent number: 4476807
    Abstract: A filter tow blooming jet device for applying an additive to a continuous, multifilament filter tow is disclosed wherein the jet device is provided with orifice means transversely positioned in an elongated passageway through which the advancing filter tow passes and the additive is applied by nozzle means concentrically positioned with respect to the advancing filter tow at a point downstream of the orifice means. The additive may also be applied to the filter tow by nozzle means positioned adjacent to the wall surface of the elongated passageway or by injecting the additive into a stream of gaseous fluid introduced into the jet device for blooming the filter tow.
    Type: Grant
    Filed: February 18, 1983
    Date of Patent: October 16, 1984
    Assignee: R. J. Reynolds Tobacco Company
    Inventor: James W. Pryor
  • Patent number: 4466451
    Abstract: A highly-porous silica gel charged with 10% by weight of anethole and 20% by weight of deactivating agent is used in the tip of a cigarette in order to aromatize the smoke drawn from the cigarette in a simple way with anethole even after prolonged storage of the cigarette.
    Type: Grant
    Filed: June 4, 1982
    Date of Patent: August 21, 1984
    Assignee: Baumgartner Papiers S.A.
    Inventors: Jacques Bonnet, Pierre Jaccard, Serge Veluz
  • Patent number: 4433697
    Abstract: A wrapper is provided for smoking articles such as cigarettes, cigars and the like having incorporated therein at least 1% by weight of certain ceramic fibers in the paper furnish in combination magnesium oxide and/or magnesium hydroxide fillers, whereby the combination acts to significantly reduce visible sidestream smoke emanating from the smoking article during static burning, and improves ashing. Wrappers made according to this invention may be made by incorporating the magnesium hydroxide, magnesium oxide and the other fillers in the wrapper pulp furnish containing the ceramic fibers or either or both of the fillers may be applied to the improved wrapper as a coating for the papers. In the case of cigarette papers, the ceramic fibers may be added to an ordinary paper furnish such as pulped wood or flax fibers. The furnish of fiber pulp and ceramic fibers and fillers are used to make a paper sheet on conventional papermaking machines.
    Type: Grant
    Filed: April 7, 1982
    Date of Patent: February 28, 1984
    Assignee: Olin Corporation
    Inventors: Warren K. Cline, William F. Owens
  • Patent number: 4407863
    Abstract: A granule coated with a tannic acid metal chelate compound is produced by granulating granular cores by adding a tannic acid metal chelate compound under spraying a solution of a binder by a centrifugal fluidized granulating machine.
    Type: Grant
    Filed: December 31, 1981
    Date of Patent: October 4, 1983
    Assignees: Denki Kagaku Kogyo Kabushiki Kaisha, Toshiba Pharmaceutical Co., Ltd.
    Inventors: Tohru Yui, Hachiro Hirai, Ken Takamaru
  • Patent number: 4397321
    Abstract: This invention provides tobacco and non-tobacco smoking compositions which deliver smoke of reduced tar and nicotine content, and with a substantially reduced carbon monoxide content.In one of its embodiments this invention provides smoking preparations which contain a combustible filler, and uniformly dispersed therein a catalyst composition consisting of (a) fine ash, and (b) a transition metal compound.
    Type: Grant
    Filed: August 24, 1981
    Date of Patent: August 9, 1983
    Assignee: Celanese Corporation
    Inventor: Dagobert E. Stuetz
  • Patent number: 4396026
    Abstract: A filter for tobacco smoke comprises a porous substrate which has a deposit thereon of particles which are crystalline, positively charged at the pH of tobacco smoke, water-insoluble, hydrophobic, and oleophilic to provide a coalescing agent which acts to attract and neutralize the negatively charged particles which are dispersed in tobacco smoke. To increase the effectiveness of the filter, the tobacco has mixed therewith and deposited thereon particles of a water-insoluble, hydrophobic, moisture-laden, negative charge-imparting substance. Cigarettes made with tobacco thus treated furnish a number of advantages without being associated with the filter of the invention.
    Type: Grant
    Filed: November 21, 1980
    Date of Patent: August 2, 1983
    Assignee: Montclair Research Corporation
    Inventor: Harold Grossman
  • Patent number: 4390031
    Abstract: Self-sustaining, dimensionally stable, axially elongated fibrous bodies of suitable cross-sectional size and shape for use as cigarette filters are produced from a bondable continuous filamentary tow of substantially continuous thermoplastic fibers. The fibers within the filter body are oriented in an adjacent and overlapping relation to one another in generally successive layers extending generally transverse to the longitudinal axis of the filter. During fabrication the filter is passed through a cooling station of reduced cross-section so that the radially peripheral edges of the fibers are bent backward and overlap to form a smooth peripheral surface to which tip-wrap material can readily adhere without the need for a plug wrap or for coating the filter.
    Type: Grant
    Filed: August 25, 1981
    Date of Patent: June 28, 1983
    Assignee: American Filtrona Corporation
    Inventor: Richard M. Berger
  • Patent number: 4379465
    Abstract: Process for producing a filtering structure, in particular for cigarette filters from a fibrous mass comprising a homogeneous mixture of fibres of different types. Some of the fibres are necessarily thermofusible synthetic fibres having a low melting point and adhesive properties in the molten state, and the others are absorbent with respect to harmful products of tobacco smoke and stable at the melting temperature of the thermofusible fibres. The fibrous mixture is shaped into a cylindrical rod which is in state which is not yet coherent but homogeneous and comprises fibrous networks which are closely imbricated relative to each other.
    Type: Grant
    Filed: July 23, 1980
    Date of Patent: April 12, 1983
    Assignee: Job, anciens Ets Bardou Job & Pauilac
    Inventor: Francois Coq
  • Patent number: 4366826
    Abstract: A smoke-filter rod comprises a body of rod form consisting or having as at least major constituent a thermoplastics cellulose acetate or polypropylene smoke-filtration material, preferably of a fibrous or filamentary nature, and wrapped in a plugwrap comprising at least 50%, suitably at least 90%, by weight of fibres or filaments of, respectively, cellulose acetate or polypropylene material of substantially the same chemical identity as said major constituent of the filtration material, said plugwrap being bonded to said body and having a permeability for air of not less than 10,000 Coresta units. The bonding is by an agent which is a bonding agent for the material of said plugwrap and said filtration material, suitably triacetin in the case of cellulose acetate. Portions of such filter rod can be subjected to a hot-shaping process.
    Type: Grant
    Filed: August 18, 1980
    Date of Patent: January 4, 1983
    Assignee: British-American Tobacco Company Limited
    Inventor: Henry G. Horsewell
  • Patent number: 4364403
    Abstract: A rod-form body of smoke filtration material, preferably fibrous or filamentary, is wrapped in a fibrous or filamentary plugwrap comprising at least 50% by weight of fibres or filaments of thermoplastics material. The plugwrap may have premeability for air of not less than 10,000 Coresta units. The majority, suitably at least 80% by weight, of the material of the rod-form body is a material other than the said themoplastics material of the plugwrap. Thus the smoke-filtration material may comprise crimped polypropylene tow and the plugwrap be composed substantially wholly of fibrous cellulose acetate or conversely. Portions of such filter rod may be subjected to a hot-shaping process to provide grooved filter elements.
    Type: Grant
    Filed: August 18, 1980
    Date of Patent: December 21, 1982
    Assignee: British-American Tobacco Company Limited
    Inventors: Henry G. Horsewell, John A. Luke
  • Patent number: 4357188
    Abstract: A method for manufacturing cigarette filters which have a well-stabilized shape in which acetate fibrous tows impregnated with carboxylic acid ester of polyol are formed into a predetermined shape, uniformly impregnated with water, and irradiated with microwave energy. Water is used during the application of microwave energy to enhance the absorption of microwave energy and hence heating of the filter. This causes the carboxylic acid ester of polyol to very rapidly disperse causing it to permeate into the acetate fiber to rapidly complete the stabilization and solidification of the filter.
    Type: Grant
    Filed: October 17, 1980
    Date of Patent: November 2, 1982
    Assignees: Mitsubishi Rayon Co., Ltd., Mitsubishi Acetate Co., Ltd.
    Inventors: Naoki Mochida, Kazuhiko Morifuji, Takashi Sakai
  • Patent number: 4331166
    Abstract: The sensory effect of cigarette smoke is improved by using a disc (24) to shape the flow of smoke (32) leaving smoking article (10) into a divergent pattern, thus increasing the perceived flavor of the cigarette. The effect is most useful with cigarettes having relatively low delivery of particulate matter.
    Type: Grant
    Filed: May 2, 1980
    Date of Patent: May 25, 1982
    Assignee: Philip Morris, Incorporated
    Inventor: Robert W. Hale