Austenitic Phase Structure Patents (Class 148/611)
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Publication number: 20140041766Abstract: The invention relates to a method for manufacturing a ferritic-austenitic stainless steel having good formability, good weldability and high elongation. The stainless steel containing the sum of carbon and nitrogen C+N in the range 0.17-0.295 in weight % in which sum C+N a lower carbon content to avoid sensitisation during welding is compensated by an increased nitrogen content to maintain formability is heat treated so that the microstructure of the stainless steel contains 45-75% austenite in the heat treated condition, the remaining microstructure being ferrite, and the measured Md30 temperature of the stainless steel is adjusted between 0 and 50° C. in order to utilize the transformation induced plasticity (TRIP) for improving the formability of the stainless steel.Type: ApplicationFiled: April 18, 2012Publication date: February 13, 2014Applicant: OUTOKUMPU OYJInventors: James Oliver, Jan Y. Jonsson, Juho Talonen, Rachel Petersson, Jan-Olof Andersson
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Patent number: 8506729Abstract: An austenitic stainless steel hot-rolled steel material can be provided which has sea-water resistance and strength superior to conventional steel. Low-temperature toughness can be maintained, which is preferable in a structural member of speedy craft. The steel material can include an austenitic stainless steel hot-rolled steel material which excels in the properties of corrosion resistance, proof stress, and low-temperature toughness. In such austenitic stainless steel hot-rolling steel material, e.g., PI [=Cr+3.3(Mo+0.5W)+16N] ranges from 35 to 40, ? cal [=2.9 (Cr+0.3Si+Mo+0.5W)?2.6 (Ni+0.3Mn+0.25Cu+35C+20N)?18] ranges from ?6 to +2, and a 0.2% proof stress at room temperature is not less than 550 MPa, Charpy impact value measured using a V-notch test piece at ?40° C. is not less than 100 J/cm2, and the pitting potential measured in a deaerated aqueous solution of 10% NaCl at 50° C. (Vc?100) is not less than 500 mV (as it relates to saturated Ag/AgCl).Type: GrantFiled: January 13, 2012Date of Patent: August 13, 2013Assignee: Nippon Steel & Sumikin Stainless Steel CorporationInventors: Yuusuke Oikawa, Shinji Tsuge, Shigeo Fukumoto, Kazuhiro Suetsugu, Ryo Matsuhashi, Hiroshige Inoue
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Patent number: 8317944Abstract: One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650° C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 ?m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.Type: GrantFiled: October 26, 2011Date of Patent: November 27, 2012Assignee: U.S. Department of EnergyInventors: Paul D. Jablonski, David Alman, Omer Dogan, Gordon Holcomb, Christopher Cowen
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Patent number: 8268101Abstract: The invention relates to an austenitic stainless steel strip having an elastic limit Rp0.2 which is greater than or equal to 600 MPa, a breaking load Rm which is greater than or equal to 800 MPa, an elongation A80 which is greater than or equal to 40% and a bright surface finish of the bright annealed type. The invention also relates to a method for the continuous production of said austenitic stainless steel strip.Type: GrantFiled: April 6, 2006Date of Patent: September 18, 2012Assignee: Aperam Stainless FranceInventors: Francois Conrad, Christian Proudhon, Patrick Borgna
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Patent number: 8246767Abstract: The invention relates to a composition and heat treatment for a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650° C. The novel combination of composition and heat treatment produces a heat treated material containing both large primary titanium carbides and small secondary titanium carbides. The primary titanium carbides contribute to creep strength while the secondary titanium carbides act to maintain a higher level of chromium in the finished steel for increased oxidation resistance, and strengthen the steel by impeding the movement of dislocations through the crystal structure. The heat treated material provides improved performance at comparable cost to commonly used high-temperature steels such as ASTM P91 and ASTM P92, and requires heat treatment consisting solely of austenization, rapid cooling, tempering, and final cooling, avoiding the need for any hot-working in the austenite temperature range.Type: GrantFiled: September 12, 2008Date of Patent: August 21, 2012Assignee: The United States of America, as represented by the United States Department of EnergyInventors: Paul D. Jablonski, David Alman, Omer Dogan, Gordon Holcomb, Christopher Cowen
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Patent number: 8226780Abstract: This ferrite-austenite stainless steel sheet includes: in terms of mass %, C: 0.1% or less; Cr: 17 to 25%; Si: 1% or less; Mn: 3.7% or less; Ni: 0.6 to 3%; Cu: 0.1 to 3%; and N: 0.06% or more and less than 0.15%, with the remainder being Fe and inevitable impurities, wherein the steel sheet has a two-phase structure consisting of a ferrite phase and an austenite phase, a volume fraction of the austenite phase is in a range of 15 to 70%, and in a sheet plane (ND) of a center of a sheet thickness, grains of the ferrite phase having a crystal orientation satisfying ND//{111}±10° and grains of the ferrite phase having a crystal orientation satisfying ND//{101}±10° are present in a total content of 10% by area or more.Type: GrantFiled: January 30, 2009Date of Patent: July 24, 2012Assignees: Nippon Steel, Sumikin Stainless Steel CorporationInventors: Masaharu Hatano, Akihiko Takahashi, Eiichiro Ishimaru, Ken Kimura
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Patent number: 8172959Abstract: There are provided an austenitic stainless steel having high stress corrosion crack resistance, characterized by containing, in percent by weight, 0.030% or less C, 0.1% or less Si, 2.0% or less Mn, 0.03% or less P, 0.002% or less S, 11 to 26% Ni, 17 to 30% Cr, 3% or less Mo, and 0.01% or less N, the balance substantially being Fe and unavoidable impurities; a manufacturing method for an austenitic stainless steel, characterized in that a billet consisting of the said austenitic stainless steel is subjected to solution heat treatment at a temperature of 1000 to 1150° C.; and a pipe and a in-furnace structure for a nuclear reactor to which the said austenitic stainless steel is applied.Type: GrantFiled: January 13, 2005Date of Patent: May 8, 2012Assignees: Mitsubishi Heavy Industries, Ltd., The Tokyo Electric Power Company, Inc.Inventors: Yasuhiro Sakaguchi, Toshihiko Iwamura, Hiroshi Kanasaki, Hidehito Mimaki, Masaki Taneike, Shunichi Suzuki, Kenrou Takamori, Suguru Ooki, Naoki Anahara, Naoki Hiranuma, Toshio Yonezawa
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Publication number: 20120080124Abstract: The invention provides an alloy steel having the following composition: Ni 5-14 wt %; Cr 4-16 wt %; Co 7-14 wt %; Mo 1-5 wt %; W 0-5 wt %; Ti 0-0.8 wt %; Al 0.1-3 wt %; the balance being Fe save for incidental impurities. This provides an ultra-high strength corrosion resistant steel with good toughness, which does not significantly creep at temperatures up to 450° C. The high quantity of alloying to elements, particularly chromium, also gives the alloy good corrosion resistance. The alloy is particularly suitable for main shafts of gas turbine engines.Type: ApplicationFiled: September 14, 2011Publication date: April 5, 2012Applicant: ROLLS-ROYCE PLCInventors: Andrew T.W. BARROW, Harshad K.D.H. BHADESHIA, Martin J. RAWSON, Paul O. HILL
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Publication number: 20120000580Abstract: A corrosion-resistant austenitic steel is claimed which, in each case relative to 100 mass percent, contains 20 to 32% manganese, 10 to 15% chromium, a total of 0.5 to 1.3% carbon and nitrogen, wherein the ratio of carbon to nitrogen is 0.5 to 1.5, the remainder being iron and melt-related impurities. The claimed steel can be produced and processed at normal pressure and has TWIP properties. It is in particular suited for producing structural components in constructs, such as in the automotive industry.Type: ApplicationFiled: March 3, 2010Publication date: January 5, 2012Applicant: MAX-PLANCK-INSTITUT FUER EISENFORSCHUNG GMBHInventors: Sebastian Weber, Lais Mujica Roncery
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Publication number: 20120000579Abstract: An ultra-high strength stainless steel alloy with enhanced toughness includes in % by weight: 0 to 0.06% carbon (C); 12.0 to 18% chromium (Cr); 16.5 to 31.0% cobalt (Co); 0 to 8% molybdenum (Mo); 0.5 to 5.0% nickel (Ni); 0 to 0.5% titanium (Ti); 0 to 1.0% niobium (Nb); 0 to 0.5% vanadium (V); 0 to 16% tungsten (W); balance iron (Fe) and incidental deoxidizers and impurities. The heat treating method includes the steps of austenitizing at least once followed by quenching, tempering and sub-zero cooling to obtain no more than about 6-8% retained austenite in the finished alloy.Type: ApplicationFiled: September 7, 2011Publication date: January 5, 2012Applicant: CARNEGIE MELLON UNIVERSITYInventor: Warren M. Garrison, JR.
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Patent number: 7914630Abstract: The subject of the invention is a process for the continuous manufacture of an austenitic stainless steel strip having a dull surface appearance, consisting in subjecting an austenitic stainless steel strip to a heat treatment in a bright annealing furnace inside which an inert or reducing flushing gas circulates, which gas has a dew point above ?15° C., and then in pickling the strip using a suitable acid pickling solution.Type: GrantFiled: March 9, 2005Date of Patent: March 29, 2011Assignee: Ugine & Alz FranceInventors: Arnaud Dessis, Henri Giraud, Caroline Dhondt
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Publication number: 20100294402Abstract: This stainless steel sheet includes, in terms of mass %, C: 0.001 to 0.1%, N: 0.01 to 0.15%, Si: 0.01 to 2%, Mn: 0.1 to 10%, P: 0.05% or less, S: 0.01% or less, Ni: 0.5 to 5%, Cr: 10 to 25%, and Cu: 0.5 to 5%, with a remainder being Fe and unavoidable impurities, and contains a ferrite phase as a main phase and 10% or more of an austenite phase, wherein a work-hardening rate in a strain range of up to 30% is 1000 MPa or more which is measured by a static tensile testing and a difference between static and dynamic stresses which occur when 10% of deformation is caused is 150 MPa or more. This method for producing a stainless steel includes annealing a cold-rolled steel sheet under conditions where a holding temperature is set to be in a range of 950 to 1150° C. and a cooling rate until 400° C. is set to be in a range of 3° C./sec or higher.Type: ApplicationFiled: January 22, 2009Publication date: November 25, 2010Inventors: Junichi Hamada, Haruhiko Kajimura, Eiichiro Ishimaru
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Patent number: 7708841Abstract: An austenitic, substantially ferrite-free steel alloy and a process for producing components therefrom. This Abstract is not intended to define the invention disclosed in the specification, nor intended to limit the scope of the invention in any way.Type: GrantFiled: December 2, 2004Date of Patent: May 4, 2010Assignees: Boehler Edelstahl GmbH & Co KG, Schoeller-Bleckmann Oilfield Technology GmbHInventors: Gabriele Saller, Herbert Aigner, Josef Bernauer, Raimund Huber
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Publication number: 20100012232Abstract: Disclosed are corrosion resistant, non-magnetic austenitic stainless steels containing alloying elements molybdenum, nickel, and copper and further containing small quantities of an additional element selected from the group consisting of a rare-earth element, calcium, cobalt, iridium, osmium, rhenium, rhodium, ruthenium, silver, and a combination thereof.Type: ApplicationFiled: July 9, 2009Publication date: January 21, 2010Applicant: BAKER HUGHES INCORPORATEDInventor: Hendrik John
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Publication number: 20090081068Abstract: An ultra-high strength stainless steel alloy with enhanced toughness includes in % by weight: 0 to 0.06% carbon (C); 12.0 to 18% chromium (Cr); 16.5 to 31.0% cobalt (Co); 0 to 8% molybdenum (Mo); 0.5 to 5.0% nickel (Ni); 0 to 0.5% titanium (Ti); 0 to 1.0% niobium (Nb); 0 to 0.5% vanadium (V); 0 to 16% tungsten (W); balance iron (Fe) and incidental deoxidizers and impurities. The heat treating method includes the steps of austenitizing at least once followed by quenching, tempering and sub-zero cooling to obtain no more than about 6-8% retained austenite in the finished alloy.Type: ApplicationFiled: June 18, 2008Publication date: March 26, 2009Applicant: CARNEGIE MELLON UNIVERSITYInventor: Warren M. Garrison, JR.
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Publication number: 20090022617Abstract: A low-nickel austenitic stainless steel is provided which comprises by weight: ?0.08% C, 4.0˜5.0% Mn, 0.7˜1.0% Si, 3.5˜4.5% Ni, 16.0˜18.0% Cr, 3.0˜3.50% Cu, ?0.045% S, ?0.030% P, impurity elements in the total amount of ?0.2%, and Fe as the balance. This low-nickel austenitic stainless steel has decreased nickel content, but retains excellent mechanical properties and corrosion resistance property. Therefore, the cost for producing the stainless steel can be reduced remarkably. The method for producing the low-nickel austenitic stainless steel is also provided.Type: ApplicationFiled: October 5, 2007Publication date: January 22, 2009Inventor: Hyunku Kim
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Patent number: 6893727Abstract: This invention relates to a stainless steel gasket having markedly improved strength and fatigue properties due to precipitation strengthening. Its composition comprises C: at most 0.03%, Si: at most 1.0%, Mn: at most 2%, Cr: 16.0%-18.0%, Ni: 6.0%-8.0%, N: at most 0.25%, if necessary Nb: at most 0.30%, and a remainder of Fe and unavoidable impurities. After cold rolling, final annealing is carried out, and after a structure is formed of recrystallized grains with an average grain diameter of at most 5 ?m having an area ratio of 50-100% and an unrecrystallized portion having an area ratio of 0-50%, a metal gasket is formed by steps including temper rolling with a reduction of at least 30% to make the area ratio of a strain induced martensite phase at least 40%, and forming and heat treatment at 200-350° C.Type: GrantFiled: October 24, 2003Date of Patent: May 17, 2005Assignees: Sumitomo Metal Industries, Ltd., Honda Giken Kogyo Kabushiki KaishaInventors: Kazuhiko Adachi, Seishi Ishiyama, Kenichi Goshokubo, Takashi Katsurai
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Patent number: 6475310Abstract: A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800° C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800° C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700° C.Type: GrantFiled: October 10, 2000Date of Patent: November 5, 2002Assignee: The United States of America as represented by the United States Department of EnergyInventors: John S. Dunning, David E. Alman
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Patent number: 6406570Abstract: An elastic component for a precision measuring instrument is made from an austenitic metal alloy containing less than two percent ferrite, less than two percent martensite, and more than eleven percent chromium. The crystalline texture has a nano-structure with blocked dislocations. The manufacturing process includes cold hardening followed by thermal aging between 200° C. and 700° C. The benefits are low anelasticity, freedom from creep and hysteresis, resistance to corrosion, and a low magnetic permeability. Examples are load cells used in analytical, motion-guiding mechanisms, coupling elements and pivoting elements.Type: GrantFiled: August 7, 2000Date of Patent: June 18, 2002Assignee: Mettler-Toledo, GmbHInventor: Jean-Maurice Tellenbach
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Patent number: 6338762Abstract: An austenitic stainless steel for use in engine gaskets having a high fatigue strength and resistance to settlement and method of manufacture thereof. The austenitic stainless steel is prepared by cold rolling at least 40%, annealing at a temperature of 700° C. to 900° C. followed by temper rolling with a reduction of at least 40%. The metal structure obtained by annealing is a recovered unrecrystallized structure or a mixed structure of a recovered unrecrystallized structure and a recrystallized structure. The austenitic stainless steel includes at most 0.03% C, at most 1.0% Si, at most 2.0% Mn, 16.0% to 18.0% Cr, 6.0% to 8.0% Ni and up to 0.20% N.Type: GrantFiled: May 3, 2000Date of Patent: January 15, 2002Assignee: Sumitomo Metal Industries, Ltd.Inventors: Naoto Sato, Kazuhiko Adachi, Kenichi Goshokubo, Takashi Katsurai, Shigeki Muroga
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Patent number: 6149744Abstract: Method of making a hot-rolled steel sheet having superior surface appearance, free of surface patterns and uneven glossiness from an austenitic stainless steel slab containing about 0.03 percent by weight or more of Cu, about 0.03 percent by weight or more of V, and about 0.01 percent by weight or more of Mo under any of the following conditions: (A) pickling in a nitric-hydrofluoric acid solution containing about 20 to 100 g/l of nitric acid and about 100 to 300 g/l of hydrofluoric acid; (B) controlling nitric-hydrofluoric acid content in response to the iron ion content in the solution; (C) a preliminary pickling step prior to finishing pickling; (D) grinding about 2 .mu.m or more of the surface after preliminary pickling and prior to finishing pickling; (E) causing counterflow with a relative flow rate of 0.5 to 5.Type: GrantFiled: October 23, 1998Date of Patent: November 21, 2000Assignee: Kawasaki Steel CorporationInventors: Kunio Fukuda, Takumi Ujiro, Masaaki Kohno, Susumu Satoh, Masahiro Yoshioka, Shinji Yamazaki
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Patent number: 6132525Abstract: Austenitic steel intended for use in radiation areas of nuclear reactors is largely resistant to irradiation-induced stress corrosion cracking if its silicon, phosphorus and sulfur contents are reduced in relation to standard commercial steel quantities and its grain structure has finely dispersed carbide precipitation, particularly of niobium carbide. The finely dispersed distribution can be induced in that larger niobium precipitation takes place at annealing temperatures between 1100 and 1150.degree. C., and carbide is precipitated through the corresponding annealing at temperatures of approximately 750.degree. C.Type: GrantFiled: March 7, 1997Date of Patent: October 17, 2000Assignee: Electric Power Research Institute, Inc.Inventors: Dietrich Alter, Peter Dewes, Friedrich Garzarolli, Roland Hahn, J. Lawrence Nelson
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Patent number: 6129795Abstract: A method is provided for improving the microstructure of nickel and iron-based precipitation strengthened superalloys used in high temperature applications by increasing the frequency of "special", low-.SIGMA. CSL grain boundaries to levels in excess of 50%. Processing entails applying specific thermomechanical processing sequences to precipitation hardenable alloys comprising a series of cold deformation and recrystallization-annealing steps performed within specific limits of deformation, temperature, and annealing time. Materials produced by this process exhibit significantly improved resistance to high temperature degradation (eg. creep, hot corrosion, etc.), enhanced weldability, and high cycle fatigue resistance.Type: GrantFiled: August 3, 1998Date of Patent: October 10, 2000Assignee: Integran Technologies Inc.Inventors: Edward M. Lehockey, Gino Palumbo, Peter Keng-Yu Lin, David L. Limoges
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Patent number: 6060180Abstract: The present invention provides a highly corrosion-resistant alloy used as a boiler tube in equipment the energy source of which is obtained by burning fossil fuel or waste, a steel tube for which the alloy is used, and a process for producing the steel tube. The alloy comprises up to 0.05% of C, 1.0 to 2.6% of Si, 0.02 to 1.0% of Mn, 20.0 to 28.0% of Cr, 18.0 to 30.0% of Ni, up to 4.0% of Mo, up to 0.05% of Al, 0.05 to 0.30% of N and the balance Fe and unavoidable impurities. Furthermore, the present invention also provides a multilayer steel tube having the alloy as a liner material and a standardized boiler tube as a base layer material, and a process for producing the multilayer steel tube.Type: GrantFiled: November 2, 1997Date of Patent: May 9, 2000Assignee: Nippon Steel CorporationInventors: Tetsuo Ishitsuka, Koichi Nose
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Patent number: 5980662Abstract: Methods are provided for annealing coils of austenitic stainless steels through the use of a batch annealing process. The preferred methods involved selecting compositions of austenitic stainless steel alloys having a sufficiently low weight percentage of carbon so that annealing of the austenitic stainless steel occurs without intergranular carbide precipitation at a temperature of less than about 1700.degree. F., which is well below the normal annealing temperature for austenitic stainless steels. The lower annealing temperatures allow for annealing in conventional batch annealing furnaces. The content of carbon in T-201L stainless steel was kept at less than 0.030 weight percent and the steel was successfully annealed at temperatures within a range of about 1650.degree. F. to about 1700.degree. F. The carbon content of T-304L stainless steel was kept at less than 0.015 weight percent and the steel was successfully annealed at temperatures within a range of about 1550.degree. F. to about 1700.degree. F.Type: GrantFiled: April 22, 1997Date of Patent: November 9, 1999Assignee: Allegheny Ludlum CorporationInventors: Yeong-U Kim, Lewis L. Kish, Nazmi Toker
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Patent number: 5976275Abstract: The present invention aims at providing structural materials having a resistance to degradation by neutron irradiation, causing no SCC in an environment of light-water reactors even after subjecting the materials to neutron irradiation of approximately at least 1.times.10.sup.22 n/cm.sup.2 (E>1 MeV), and having thermal expansion coefficients approximately similar to that of structural materials. The high nickel austenitic stainless steels of the present invention having a resistance to degradation by neutron irradiation can be produced by subjecting stainless steels having compositions (by weight %) of 0.005 to 0.08% of carbon, at most 0.3% of Mn, at most 0.2% of (Si+P+S), 25 to 40% of Ni, 25 to 40% of Cr, at most 3% of Mo or at most 5% of (Mo+W), at most 0.3% of Nb+Ta, at most 0.3% of Ti, at most 0.001% of B and the balance of Fe to a solution-annealing treatment at a temperature of 1000 to 1150.degree. C.Type: GrantFiled: June 5, 1997Date of Patent: November 2, 1999Assignee: Mitsubishi Jukogyo Kabushiki KaishaInventors: Toshio Yonezawa, Toshihiko Iwamura, Hiroshi Kanasaki, Koji Fujimoto, Shizuo Nakada, Kazuhide Ajiki, Mitsuhiro Nakamura
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Patent number: 5858135Abstract: A method for producing strip cast, austenitic stainless steel strip comprises providing a strip cast strip having an initial microstructure including a detrimental amount of delta ferrite and a detrimental amount of dendritic structure is provided. The strip may have a composition comprising the following ingredients: 0.4 wt. % max. carbon, 5-38 wt. % nickel, and 15-28 wt. % chromium. The strip is subjected to a cold rolling step prior to any annealing step. Upon subsequent annealing, (a) the amount of delta ferrite in the strip is reduced to substantially below the detrimental amount of delta ferrite that was in the strip prior to cold rolling and (b) the amount of dendritic structure in the strip is reduced to below the detrimental amount of dendritic structure that was in the strip prior to cold rolling. By employing the method of the present invention, an austenitic stainless steel strip having a high quality surface is produced.Type: GrantFiled: July 29, 1997Date of Patent: January 12, 1999Assignee: Inland Steel CompanyInventors: Zofia E. Niemczura, Kenneth E. Blazek
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Patent number: 5824264Abstract: A high-temperature austenitic stainless steel having improved weldability is disclosed. The steel consists essentially, by weight, of:C: 0.05%-0.15%, Si: less than 1.0%, Mn: 2.0% or less,P: 0.04% or less, S: 0.01% or less, Cr: 20%-30%,Ni: 10%-15%, N: 0.10%-0.30%,B: 0.0010%-0.01%,one or two of La and Ce: 0.01%-0.10% in total,Al: 0.01%-0.20%, anda balance of Fe and incidental impurities, wherein the contents of N and Al satisfy the following inequality:% N+2.times.% Al.ltoreq.0.500%and the value for Ni balance (Ni bal.) of the steel calculated by the following formula is in the range of from -1.0% to +3.0%:Ni bal. (%)=% Ni+0.5.times.% Mn+30.times.(% C+% N)-1.1.times.(% Cr+1.5.times.% Si)+8.2.Type: GrantFiled: July 25, 1996Date of Patent: October 20, 1998Assignee: Sumitomo Metal Industries, Ltd.Inventors: Hideki Uno, Yoshitaka Nishiyama, Yoshiatsu Sawaragi, Nobuo Otsuka, Kazuhiro Ogawa, Toshiro Anraku
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Patent number: 5817193Abstract: In the fabrication of components from a face centered cubic alloy, wherein the alloy is cold worked and annealed, the cold working is carried out in a number of separate steps, each step being followed by an annealing step. The resultant product has a grain size not exceeding 30 microns, a "special" grain boundary fraction not less than 60%, and major crystallographic texture intensities all being less than twice that of random values. The product has a greatly enhanced resistance to intergranular degradation and stress corrosion cracking, and possesses highly isotropic bulk properties.Type: GrantFiled: January 17, 1997Date of Patent: October 6, 1998Inventor: Gino Palumbo
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Patent number: 5284535Abstract: A method of manufacturing an austenitic stainless steel sheet having reduced minute surface concavities and convexties ropings and gloss unevenness and a manufacturing system for carrying out the same are provided. The method comprises (a) a casting process of casting a molten austenitic (.gamma.) stainless steel into a thin cast plate by a twin-roll thin plate casting method employing a pair of cooled rolls disposed opposite to each other, (b) a cooling process of cooling the cast thin plate in a single phase state of the .gamma. phase, (c) a cast plate in a dual phase state of the .delta. and .gamma. phase or a single phase state of the .delta. phase and then cooling the thin cast plate to restore the single phase state of the .gamma. phase, and (d) a cold-rolling process of cold-rolling the heat-treated thin cast plate.Type: GrantFiled: August 19, 1991Date of Patent: February 8, 1994Assignee: Nippon Steel CorporationInventors: Yoshiyuki Ueshima, Kenichi Miyazawa, Toshiaki Mizoguchi, Masayuki Abe
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Patent number: 5269856Abstract: A high strength steel belt having an excellent flatness and a duplex structure of austenite and martensite has been prepared by a process which comprises providing a cold rolled or cold rolled and annealed strip of a martensitic structure from low carbon martensitic stainless steel containing from 10 to 17% by weight of Cr and having a carbon content of not exceeding 0.15% by weight, connecting ends of the strip or ends of a plate cut from said strip to provide an endless belt, causing the endless belt to circularly move between rolls under tension and to pass through a heating furnace where the belt is heated to a temperature within a range from (As point of the steel+30.degree. C.) to Af point of the steel and not higher than 900.degree. C. so that a part of the martensitic phase may be changed to a reversed austenitic phase and a desired surface flatness may be obtained after cooling.Type: GrantFiled: November 13, 1992Date of Patent: December 14, 1993Assignee: Nisshin Steel Co., Ltd.Inventors: Takashi Igawa, Yoshihiro Uematsu, Toshihiko Takemoto
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Patent number: 5252149Abstract: An erosion and corrosion resistant ferrochromium alloy comprising the following composition, in wt. %, 34-50 chromium, 1.5-2.5 carbon, up to 5 manganese, up to 5 silicon, up to 5 molybdenum, up to 10 nickel, up to 5 copper, up to 1% of each of one or more micro-alloying elements selected from the group consisting of titanium, zirconium, niobium, boron, vanadium and tungsten, and balance, iron and incidental impurities.The alloy has a microstructure comprising eutectic chromium carbides in a matrix comprising one or more of ferrite, retained austenite and martensite, as herein defined. Optionally, the microstructure further comprises one of primary chromium carbides, primary ferrite or primary austenite in the matrix.Type: GrantFiled: February 10, 1993Date of Patent: October 12, 1993Assignee: Warman International Ltd.Inventor: Kevin F. Dolman
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Patent number: 5180450Abstract: A high strength, low alloy, low to medium carbon structural steel is provided of the Fe/Cr/C type, said steel characterized by the presence of a small but effective amount of each of Cu and Ni sufficient to enhance the mechanical stability of retained austenite formed following quenching of said steel from its austentizing temperature. Preferably the steel also includes small but effective amounts a Al, Ti and Nb suficient to provide a fine grained microstructure.Type: GrantFiled: June 5, 1990Date of Patent: January 19, 1993Assignee: Ferrous Wheel Group Inc.Inventor: Banagaru V. N. Rao
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Patent number: 5171384Abstract: A high strength steel strip excellent in shape having a duplex structure of austenite and martensite has been prepared by a process which comprises providing a cold rolled or cold rolled and annealed strip of a martensitic structure from low carbon martensitic stainless steel containing from 10 to 17% by weight of Cr and having a carbon content of not exceeding 0.15% by weight, causing the strip to continuously pass through a continuous heat treatment furnace under tension where the strip is heated to temperatures within the range from (the As point of the steel+30.degree. C.) to the Af point of the steel and not higher than 900.degree. C.Type: GrantFiled: October 9, 1991Date of Patent: December 15, 1992Assignee: Nisshin Steel Co., Ltd.Inventors: Takashi Igawa, Yoshihiro Uematsu, Toshihiko Takemoto
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Patent number: 4804445Abstract: A surface layer which is composed of the carbonitride of molybdenum is formed on an article made of iron or an iron alloy by heating the article in the presence of a material containing molybdenum and a treating agent. The treating agent may be composed of at least one of the cyandides and cyanates of alkali metals and alkaline earth metals. The layer adhering closely to the article can be formed efficiently at a temperature which is so low that virtually no thermal strain may develop in the article.Type: GrantFiled: November 20, 1987Date of Patent: February 14, 1989Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Yukio Ohta, Shigeo Moriyama, Akira Sato, Tohru Arai, Hironori Fujita, Yoshihiko Sugimoto
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Patent number: 4671824Abstract: Process for producing zirconium oxide blue-black coatings on zirconium alloy substrates by treating said alloys with molten salts containing small amounts of oxidizing compounds. The molten salts are sodium cyanide and combinations of sodium chloride and potassium chloride.Type: GrantFiled: December 18, 1985Date of Patent: June 9, 1987Assignee: Teledyne Industries, Inc.Inventor: John C. Haygarth
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Patent number: 4655852Abstract: A steel article which is made of carbon or low alloy steel, with a prescribed chemical composition, is heat treated so that its yield strength is increased to a minimum of 60,000 psi and is subsequently dipped or spray covered with aluminum and then heated to interdiffuse aluminum metal and the iron in the steel matrix, thereby forming a new intermetallic layer which is an integral part of the steel article and which is essentially an aluminum-iron alloy, all in a manner which does not lower the yield strength of the steel below 60,000 psi. In the preferred form of the invention, a steel article is austenitized above its critical temperature for about 15 minutes or more and is subsequently rapidly cooled to below 600.degree. F. to transform the austenite structure to a much stronger martensitic structure and is then reheated to below 1341.degree. F. to temper the martensite.Type: GrantFiled: August 16, 1985Date of Patent: April 7, 1987Inventor: Anthony T. Rallis
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Patent number: 4654237Abstract: A process for chemical and thermal treatment of steel workpieces accompanied by the formation thereon of a coating includes diffusive precipitation onto the base metal of the workpiece of an intermetallic compound from a melt of a low-melting-point metal, such as sodium or lithium, at a temperature of from 720.degree. to 820.degree. C. for a duration of time necessary for obtaining a coating layer of required thickness.Type: GrantFiled: September 6, 1985Date of Patent: March 31, 1987Assignees: Fiziko Mekhanichesky Institut Imeni Karpenko, Institut Metallurgii Imeni Baikova Akademii Nauk SSRInventors: Evgeny M. Savitsky, Mikhail S. Goikhman, Petr M. Khudyk, Valery V. Chepkasov, Valentin V. Sulyagin, Viktoria P. Polyakova, Viktor F. Shatinsky, Nelli B. Gorina, Evgeny M. Rudkovsky
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Patent number: 4624895Abstract: A low-titanium alloy steel foil having a cold rolled metallic aluminum hot-dip coated surface which is adapted for growing a thick surface coating of spine-like whiskers of aluminum oxide suitable for retaining a coating of a metallic catalyst, which is formable at room temperature without annealing, and which exhibits good resistance to oxidation at temperatures up to 1149.degree. C. (2100.degree. F.).Type: GrantFiled: June 4, 1984Date of Patent: November 25, 1986Assignee: Inland Steel CompanyInventor: Richard A. Nickola
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Patent number: 4608092Abstract: A process for improving the corrosion resistance of ferrous metal parts also subject to heat and chemical treatment following nitriding in association or not with carburizing and/or sulfurizing essentially comprises immersing the parts in a known bath of molten salts to which is added a sufficient quantity of a halogenophosphate having formula:M.sub.2 (PO.sub.3 X).sub.min which X and is fluorine and M is a metal of subgroup Ia, IIa or IIb of the periodic table of elements, having the valency m. The preferred halogenophosphate is sodium, potassium, calcium or zinc monofluorophosphate. The molten salt bath may be of the oxidizing type, comprising for example, 65% by weight KOH, 25% NaNO.sub.3, 10% Na.sub.2 CO.sub.3, or of the neutral type, for example a eutectic mixture of 50% BaCl.sub.2, 30% CaCl.sub.2, 20% NaCl. The halogenophosphate may be added in proportions of 0.1 to 20 g per kilogram of salt bath.Type: GrantFiled: March 19, 1985Date of Patent: August 26, 1986Assignee: Centre Stephanois de Recherches Mecaniques Hydromecanique et FrottementInventors: Yves Tremoureux, Jean-Luc Reynaud
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Patent number: 4536224Abstract: There is described a salt bath based on an alkali and/or alkaline earth metal halide with which there can be produced without the use of current adherent and wear resistant boride coatings on metallic workpieces. This bath contains gaseous boron monofluoride or a compound from which there is formed intermediately boron monofluoride. Advantageous there is used a salt bath containing 30-60% BaCl.sub.2, 10-25% NaCl, 1-20% boron oxide or borate, 10-30% NaF, and 1-15% B.sub.4 C.Type: GrantFiled: July 12, 1984Date of Patent: August 20, 1985Assignee: Degussa AktiengesellschaftInventors: Hans-Hermann Beyer, Ulrich Baudis, Peter Biberbach, Wolfgang Weber
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Patent number: 4534794Abstract: A salt system having a reduced rate of corrosion comprises a salt selected from the group consisting of KNO.sub.3,NaNO.sub.3 and mixtures thereof, and a minor amount of a corrosion inhibitor selected from the group consisting of Li.sub.2 O, Na.sub.2 O, CuO, Mgo, NiO, CaO, Al.sub.2 O.sub.3, Cr.sub.2 O.sub.3, SiO.sub.2, Mn.sub.3 O.sub.4, Ti.sub.2 O.sub.3, Y.sub.2 O.sub.3, Na.sub.2 CrO.sub.4, Na.sub.2 Cr.sub.2 O.sub.7, K.sub.2 CrO.sub.4, K.sub.2 Cr.sub.2 O.sub.7, and mixtures thereof.Type: GrantFiled: May 14, 1981Date of Patent: August 13, 1985Assignee: Rockwell International CorporationInventors: Robert J. Walter, Bernard J. Gerik
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Patent number: 4453987Abstract: A method for producing an edged tool which has an excellent cutting ability and durability, which comprises immersing an edged-tool material in a molten-salt bath containing a carbide-forming element, such as a Va Group element, titanium, chromium or manganese, to form a carbide layer on the surface of the edged-tool material; heating the edged-tool material to a temperature not lower than the austenite-transformation temperature of the material in a non-oxidizing gas atmosphere for a predetermined period of time; and rapidly cooling the heated material to harden it. According to the improved method of the present invention, the edged tool (having an excellent cutting ability and durability) is produced without grinding the formed carbide layer on the surface thereof.Type: GrantFiled: April 6, 1982Date of Patent: June 12, 1984Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Tohru Arai, Yoshihiko Sugimoto
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Patent number: 4448611Abstract: To improve the corrosion resistance of ferrous metal parts containing free r combined sulphur on the surface, the parts are immersed in a bath of molten oxidizing salts at between 350.degree. C. and 450.degree. C., the bath typically having a composition by weight of 60% of potassium hydroxide, 30% of sodium nitrate and 10% of sodium carbonate. Between 0.5% and 15% of oxygen-containing salts, the normal oxidation-reduction potential of which is less than or equal to -1 volt, relative to the hydrogen electrode, such as alkali metal dichromates, permanganates, peroxycarbonates, iodates and periodates, are added to the bath, and an oxygen-containing gas is blown into the bath with an oxygen flow of between 1.5 and 7.5 liters/hour per 100 kg of bath. The molten salts of the bath are filtered continuously through an iron gauze filter cartridge in a furnace, the molten salts being transported into the filter cartridge by entrainment of the salts in a pipe by bubbles of air blown in through the pipe.Type: GrantFiled: April 25, 1983Date of Patent: May 15, 1984Assignee: Centre Stephanois de Recherches Mecaniques Hydromecanique et FrottementInventors: Bernard Grellet, Jean-Pierre Emmanuel, Bernard Sipp
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Patent number: 4440581Abstract: Vanadium carbide layers are produced on iron and iron alloys having a content of at least 0.1 weight % carbon by treating the workpiece at 800.degree. to 1100.degree. C. in a salt bath which contains 1-30 weight % of vanadium or ferrovanadium powder. The salt bath consists of alkaline earth and/or alkali metal halide.Type: GrantFiled: June 29, 1981Date of Patent: April 3, 1984Assignee: Degussa AktiengesellschaftInventors: Ulrich Baudis, Peter Biberbach, Wolfgang Weber
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Patent number: 4436560Abstract: A process for manufacturing a boride dispersed copper alloy by preparing a metallic material having a surface portion comprising at least one of Al, As, Cd, Co, Cr, Fe, Mg, Mo, Nb, Pt, Ta, W and Zr, and copper or an alloy thereof, and diffusing boron into the surface portion. The resulting material includes fine boride particles uniformly dispersed in the surface portion and is useful as a material for electrical contacts or sliding parts due to its high wear, adhesion and arc resistance and high electrical conductivity.Type: GrantFiled: June 11, 1982Date of Patent: March 13, 1984Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Kabushiki Kaisha Tokai Rika Denki SeisakushoInventors: Hironori Fujita, Tohru Arai, Jiro Mizuno
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Patent number: 4436559Abstract: A process for manufacturing a boride dispersion copper alloy by preparing a metallic material having a surface portion comprising at least one of beryllium, gallium, manganese, nickel, palladium, silicon and vanadium, and copper or an alloy thereof, and diffusing boron into the surface portion. The resulting material includes fine boride particles uniformly dispersed in the surface portion and is useful as a material for electrical contacts or sliding parts due to its high resistance to adhesion, wear and arc, and excellent electrical conductivity and sliding properties.Type: GrantFiled: June 11, 1982Date of Patent: March 13, 1984Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Hironori Fujita, Tohru Arai
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Patent number: 4419853Abstract: A composition and method for treating the surface of a metal structure adapted to be used for such purposes as a cornerbead and to have a cementitious material such as a joint compound applied to the surface thereto, the compound and composition and method resulting in the improvement of the adhesion between the surface of the metal structure and the cementitious compound applied thereto, which comprises preparing a composition such as that comprising a forming lubricant for processing the metal structure and a minor proportion of a polyfunctional aziridine incorporated therein. The presence of the aziridine enhances the adhesion properties between the surface of the metal and the cementitious compound even when less highly processed metals and less expensive compounds are utilized.Type: GrantFiled: September 24, 1981Date of Patent: December 13, 1983Assignee: United States Gypsum CompanyInventors: Friedrich Failmezger, Geronimo E. Lat
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Patent number: 4400222Abstract: A method for treating surfaces is provided, in which a material to be treated, such as iron, iron alloys or the like is immersed in a molten bath prepared by adding 5 to 50 weight % of a metal cementing agent consisting of one or more selected from the group consisting of a Group Va element, a substance containing the Group Va element, a Group VIa element and a substance containing the Group VIa element to a salt bath agent consisting of a neutral salt containing 5 to 30 mol % of a borate admixed therewith, to form the carbide of the Group Va element or Group VIa element or the composite carbide of these elements on the surfaces of the material. To the molten bath there may be optionally added 1 to 10 weight % of an adjuvant consisting of one or more selected from the group consisting of the oxysalts of the Groups IVa, Va and VIa elements and/or 1 to 10 weight % of a metal or an alloy thereof selected from the group consisting of a Group IVa metal and an alloy thereof.Type: GrantFiled: June 16, 1981Date of Patent: August 23, 1983Assignee: Hitachi Metals, Ltd.Inventor: Norimasa Uchida
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Patent number: 4400224Abstract: A method for forming a carbide layer on the surface of a carbon-containing ferrous alloy article or a cemented carbide article in a molten treating bath. The bath is prepared by introducing 5 to 20% by weight of alumina into molten boric acid or borate bath and a carbide-forming element dissolved therein. By employing the treating bath of this invention, the life of the bath can be remarkably improved, and no sintered substance of undissolved carbide-forming element is produced in the treating bath. Further, it is possible to reduce markedly the corrosion of the article and of the vessel holding the bath.Type: GrantFiled: April 2, 1982Date of Patent: August 23, 1983Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Tohru Arai, Hironori Fujita, Yasuo Takada