Abstract: This invention relates to a process for the preparation of aluminum alloys having a high reducing capacity for use in reductions in organic chemistry. According to this method a discontinuous heterodisperse superficial alloy is formed by subjecting an aluminum alloy prepared by a metallurgical process to superficial activation and/or treating aluminum with a salt of a metal having a greater normal electrode potential than that of aluminum; whereby the solution of said metal in a protic solvent is reacted with granular aluminum and/or an aluminum alloy. The catalyst prepared according to the invention is especially suitable for the reduction of a nitro or nitroso group into an amino group. The aluminum alloys having a high reducing capacity are also within the scope of the invention.

Abstract: A method of inhibiting the fatigue of aluminum comprising the steps of immersing aluminum in an aqueous solution of a water soluble cyanide compound at room temperature and continuously maintaining the aluminum in contact with the aqueous solution. The aqueous solution is substantially free of chromium.

Abstract: The thickness of a hydrous oxide layer on aluminum capacitor foil is controlled by producing the oxide in a hot, dilute borate solution with a pH of about 6, prior to anodization of the foil.

Abstract: A method for plating very thin films of aluminum for subsequent electrical contact. The method is particularly suitable for preparation of the thin films of aluminum used in semiconductor integrated circuits for subsequent plating operations or lead bonding processes. The method comprises a removal of surface oxides in a way that does not substantially attack the very thin films of aluminum followed by immersion plating with a metal selected from the group comprising zinc, tin, nickel, silver and copper.

Abstract: The solution for sealing anodic oxidized aluminum or aluminum alloys comprises basically an aqueous solution containing an addition of 0.1 to 2.5 g/l, made up of Agar-Agar and gelatine. the optimum pH value for the solution lies between 5.5 and 6.0.The sealing is carried out at a temperature between 90.degree. C. and the boiling point of the solution.

Abstract: Improved color, brightness and corrosion resistance are imparted to metal surfaces such as zinc plated surfaces, by treatment with a non-toxic solution comprised of sulfuric acid, hydrogen peroxide, a silicate and at least one cationic triarylmethane dye. Certain organophosphorus compound additives further enhance the corrosion resistance.

Abstract: Improved brightness and corrosion resistance are imparted to metal surfaces such as zinc plated surfaces, by treatment with a non-toxic solution comprised of sulfuric acid, hydrogen peroxide, a silicate, certain primary organophosphorus compound promoters and at least one secondary promoter selected from ascorbic acid, boric acid, gluconic acid, glycolic acid, tartaric acid and salts of said acids.

Abstract: Improved brightness and corrosion resistance are imparted to metal surfaces such as zinc plated surfaces, by treatment with a non-toxic solution comprised of sulfuric acid, hydrogen peroxide and a silicate. Certain organophosphorus and organonitrogen compound additives further enhance the corrosion resistance.

Abstract: A process for the production of a laminate which comprises laminating a boehmite- or pseudoboehmite-treated aluminum foil with an oxidation-treated polyolefin film with the treated surface of the foil facing to the treated surface of the film under heat and pressure without the use of binders for lamination. In one embodiment, the laminate so produced may be laminated with the same laminate with the treated surface of the foil of the former facing to the treated surface of the film of the latter, under heat and pressure, or it may be laminated on the aluminum foil side with a resin film, such as a polyester or polyamide film, with the use of a binder between the aluminum foil and the resin film.

Abstract: A process for the preparation of an improved base for offset printing plates comprising superimposing together two prerolled aluminum ribbons with an individual thickness of 0.12 to 0.5 mm, rolling the said superimposed ribbons to an individual ribbon thickness of 0.08 to 0.22 mm whereby the mutual contact surfaces have an uniform surface roughness, separating the two ribbons and forming a stable aluminum oxide layer on the uniformly roughened surfaces which have improved properties when used as a base for offset printing plates.

Abstract: The invention is for a process for providing a protective, color receptive coating over aluminum using chemical means without a requirement for the use of an electric current as in electrical anodizing. Absent conventional steps such as water rinses, the process comprises cleaning, including desmutting of the surface of an aluminum part as necessary, and treatment with an aqueous alkaline solution of ferric citrate for a time sufficient to provide the coating over the part. The treated aluminum part has enhanced corrosion resistance and the coating over the part acts as a base for other coatings such as paint, and is readily dyed.

Abstract: A method is disclosed for the painting of aluminum surfaces that provides a highly superior coating than prior methods. The method comprises a controlled oxidation of the aluminum surface, the application to the oxidized surface of an epoxy functional silanol, and coating of the aluminum surface with paint by conventional methods such as brushing, spraying and the like. The useful epoxy functional silanols have the general formula of: ##STR1## wherein: n is a whole number integer of 1 through 3; andm is a whole number integer of 1 through 5.These silanols can be applied to the oxidized aluminum surface by dissolving them, or their corresponding trialkoxysilanes, in an aqueous solution which is applied to the surfaces and permitted to dry or can be incorporated in the coating composition.

Abstract: A fastener and method of manufacturing fasteners is disclosed including coating the fastener with a cured, oil-free polyester coating, the cured polyester coating comprising the reaction product of one or more polyols selected from the group consisting of pentaerythritol, trimethylolpropane, glycerol, ethylene glycol, triethylene glycol, neopentyl glycol, trimethylolethane, 1,2 hexanediol, 1,3 butenediol, and mixtures thereof; one or more dibasic organic acids selected from the group consisting of phthalic acid, isophthalic acid, maleic acid, adipic acid, succinic acid, sebacic acid, fumaric acid, and mixtures thereof; and an aminoplast cross-linking agent selected from the group consisting of melamine-formaldehyde, urea-formaldehyde, hexahydroxymethyl melamine, and mixtures thereof.

Abstract: Aluminum electrolytic capacitor foil is treated prior to anodization in a two-step process in which a hydrous oxide film is first formed on the foil and the hydrous oxide is then modified. In the first step the foil is immersed in boiling water to form an appropriate thickness of hydrous oxide and in the second step it is immersed in a boiling aqueous solution containing phosphate, silicate, or tartrate ions, or combinations thereof. This treatment results in a decreased power consumption during anodization and produces a film having higher film capacitance.

Abstract: The surfaces of articles made of aluminum, such as annodized aluminum and bare aluminum, are treated with N-alkyl-fluoroaliphaticsulfonamidophosphonic acids or salts thereof to impart corrosion resistance to said surfaces.

Abstract: This invention relates to a method and compositions for coating aluminum in order to improve both corrosion resistance and paint adhesion. By using a coating composition consisting essentially of (a) polyacrylic acid or esters thereof and (b) at least one acid selected from the group consisting of H.sub.2 ZrF.sub.6, H.sub.2 TiF.sub.6, and H.sub.2 SiF.sub.6, the characteristics of the treated aluminum surfaces are improved, while process waste disposal problems associated with conventional chrome/phosphate coating are avoided.

Abstract: The transfer elements of a heat and humidity exchanger are made by forming the transfer elements in the desired configuration and of a non-hygroscopic metal such as aluminum, and treating the surfaces to produce an integral hygroscopic layer thereof. This is done by oxidizing the surface of the metal to form an oxide layer, which itself is hygroscopic, and preferably enhancing the hygroscopic properties by subsequent impregnation of the oxide with a hygroscopic material such as lithium chloride. According to one form of the method, the oxidizing layer is produced by immersing the transfer elements, in a bath such as a warm aqueous solution of sodium hydroxide, or sodium carbonate, followed by heating in humid air; in a second form of the method, the oxide layer is produced by heating in humid air, or in a water, without preliminary alkaline treatment; in a third form of the method, the oxide layer is formed in a water bath containing an oxidizing agent such as trietanolamin or hydrogen peroxide.

Abstract: A surface processing solution for an aluminum or aluminum alloy substrate comprises 0.1 to 10 g/liter of one or more compounds selected from the group consisting of inositol di-.about.hexaphosphates and water soluble salts thereof and 0.1 to 10 g/liter as Ti of a titanium fluoride.A surface of an aluminum or aluminum alloy substrate is treated with said surface processing solution.

Abstract: Disclosed is a single-application non-electrolytic method for the treatment of bare metal surfaces to form a corrosion-resistant coating. The clean metal surfaces are treated with an aqueous composition containing a melamine-formaldehyde resin and a vegetable tannin. The resulting dried coating exhibits superior qualities for a single-application coating process when used as a paint base and the process does not require the use of environmentally objectionable chromium compounds. Application to ferrous, zinc or aluminum surfaces may be by any known technique designed to provide a deposited layer of desired uniformity.

Abstract: A chromium-free treatment for aluminum imparts corrosion resistance and paint receptivity to the surface. The process is sequential and includes a first contact with an aqueous alkaline solution (pH above 10) containing complexed iron ion, water rinsing, and then contact with an aqueous acidic organic tannin-containing composition.

Abstract: Steel, aluminum and aluminum alloys, zinc and zinc alloys are treated to improve corrosion resistance with an aqueous solution of a fluorophosphate salt to passivate the metal surface, before or after phosphatizing and prior to painting.

Abstract: There are disclosed herein lithographic plates having an aluminum base the surface of which has been made porous and hardened first by an alternating current anodization in a hydrochloric acid electrolyte and then by a direct current anodization in a sulfuric acid electrolyte.

Abstract: A process for providing a priming layer of aluminum hydroxyoxide on aluminum and aluminum alloy surfaces comprising treating the surface with a chemical reagent having a solvent action for the naturally-occurring oxides which form on such surfaces until said oxides are dissolved, and contacting said surfaces with steam while a film of the reagent is still present on the metal surface. The priming layer provides for excellent adhesion of subsequent organic coatings to the metal surface.BACKGROUND OF THE INVENTIONThe present invention relates to the formation of priming films on aluminum and aluminum alloy surfaces so as to render such surfaces permanently receptive to subsequent organic coatings.Because of the weight of aluminum and its corrosion characteristics, aluminum and alloys therewith are being increasingly utilized in commercial, industrial and consumer areas in conjunction with organic coatings, e.g., aluminum siding for dwellings, containers for food and beverages, automobile parts, etc.

Abstract: An acidic aqueous coating solution for forming on an aluminum surface a coating which is corrosion resistant and to which overlying coatings adhere excellently is disclosed. The coating solution contains compounds of zirconium and/or titanium, fluoride and phosphate in dissolved form, and optionally, polyhydroxy compounds having 6 or fewer carbon atoms. The coating solution is capable of forming on an aluminum surface a uniformly colorless and clear coating so that the coated surface has the appearance of the underlying metal surface, that is, the coating can be formed without changing the appearance of the metal surface.

Abstract: A composition, and method for using the composition in applying a conversion coating on aluminum and aluminum alloy surfaces, is disclosed. In the method of this invention an aluminum containing metal surface is contacted with a ferricyanide free aqueous acidic solution containing zinc, hexavalent chromium, fluoride, and molybdate ions. The coated metal surface shows inhanced resistance to corrosion and improved paint adhesion. The absence of ferricyanide in the composition promotes easier disposal of the spent solutions.

Abstract: To provide a substrate of aluminum with a dark surface layer of high absorption/emission ratio for luminous energy, the degreased and pickled substrate is immersed in a hot chromating bath until an oxide coating of not more than 2.5.mu. thickness is formed thereon. This coating is then colored black in a hot, acidic dyeing solution (pH between about 0.5 and 5) of potassium permanganate and a nitrate of cobalt or copper.

Abstract: A process for producing solar collectors of aluminum or aluminum alloys having a selective absorptive coating. Aluminum or its alloy is dipped in a hot aqueous solution containing a silicate. Aluminum alloys can be also used which contain alloying elements such as iron, copper, titanium, nickel, silver and gold.

Abstract: A process for producing a strong and water-resistant bond between aluminum or an aluminum-based alloy and a polysulphide material by means of a primer which is applied to the metal, characterized in that the primer is a solution of a strongly basic alkali metal compound such as alkali metal hydroxides, phosphates and carbonates. The present invention also includes articles treated by the aforementioned process.

Abstract: Steel, aluminum and aluminum alloys, zinc and zinc alloys are treated to improve corrosion resistance with an aqueous solution of a fluorophosphate salt to passivate the metal surface, before or after phosphatizing and prior to painting.

Abstract: This invention relates to a composition and method for coating aluminum in order to improve both corrosion resistance and paint adhesion. By using very low concentrations of hexavalent chromium ions, phosphate ions and fluoride ions in the coating composition, the characteristics of the treated aluminum surfaces are improved, while process waste disposal problems are minimized.

Abstract: This invention is concerned with a process for bonding a durable low surface energy polymeric coating to a metal or oxide surface. The metal or oxide surface is first treated with an alkali, thereby maximizing the hydroxide ion concentration on the surface, and then in a rigorously dry state with a rigorously dry fluorinated material to form the polymeric coating. The fluorinated material has the formulaRf -- O -- (CH.sub.2).sub.n -- SiX.sub.3wherein Rf is a fluorinated lower alkyl group, n is an integer from 2 to 10, and X is a halogen, cyanide or alkoxy group.

Abstract: A method of producing a support for a printing plate comprising treating an aluminum plate, which has been oxidized by anodizing and then etched, with hot water or with water vapor.

Abstract: Shaped aluminum bars fresh from an extruder machine are coated with a specific organopolysiloxane composition while remaining uncooled and staying at temperatures not lower than about 250.degree. C, or at a temperature between about 550.degree. and 250.degree. C. The thus coated aluminum bars are then, preferably, subjected to annealing. The coatings formed on the surfaces of the aluminum materials have a superior resistance to attack by chemicals, weather, stains and heat as well as excellent adhesion and mechanical properties.

Abstract: This invention relates to a method of forming an oxide coating on an aluminum surface having a controlled surface resistance and if sufficiently thick have an integral color by treating the aluminum surface with a neutral or slightly basic aqueous solution containing at least 0.001 gm/liter of a difficultly soluble magnesium compound expressed as MgCO.sub.3. The temperature of the bath should exceed 65.degree. C and the pH should range from about 7 to 9.

Abstract: Disclosed is a process for cleaning and treating an aluminum surface to improve the corrosion resistance and paint receptivity of the surface. The treating composition is an aqueous vegetable tannin composition, and the cleaning composition is an aqueous acidic fluoride containing cleaner.

Abstract: A method of protecting an aluminum braking surface is disclosed. A brake lining associated with the surface is formed of a brake lining material which includes as a part of the composition an additive of sodium fluoride or cryolite. When a brake system composed of the braking surface and the brake lining are subjected to repeated braking actions, the additive of the brake lining reacts with a surface layer of the aluminum braking surface to form a tenacious, wear resistant layer thereon. The additive, upon further braking actions serves to maintain the wear resistant layer as fresh aluminum is exposed during normal wear of the braking surface over its useful life.

Abstract: A method of forming a low temperature, smudge-free seal on anodized aluminum comprises exposing anodized aluminum to a source of ammonia vapors.

Abstract: This invention is directed to a process for forming a hydrophobic and highly oleophilic coating on an aluminum surface which comprises treating the aluminum surface under aqueous alkaline conditions with a long chain aliphatic carboxylic acid (or an equivalent carboxylate compound), such as isostearic acid, which has one or more short secondary alkyl groups on or near the nonpolar end of the carboxylate compound. The coating can be formed by treating the surface with an aqueous alkaline solution which contains the carboxylic acid or the coating can be formed by mechanically deforming or upsetting the aluminum surface to expose a fresh aluminum surface to a carboxylic acid (or its equivalent) and a compound which generates alkaline conditions on the aluminum surface. In the latter instance, the carboxylic acid and alkaline compound is preferably incorporated into a metal-working lubricant used to facilitate deformation.

Abstract: This invention relates to the formation of a hydrophobic and usually oleophilic coating on an aluminum surface by mechanically deforming or upsetting the aluminum surface to disrupt the natural oxide coating in the presence of alkaline agents and a long chain aliphatic carboxylic acid or other equivalent long chain aliphatic carboxylate compounds. Preferably, the carboxylic acid and alkaline agent are incorporated into a metal-working lubricant which is maintained on the aluminum surface during fabrication, such as rolling, so that the hydrophobic coating is formed simultaneously with fabrication and thereby avoid the necessity of a separate coating operation.

Abstract: This invention relates to a method of pretreating an aluminum surface for the resistance welding thereof wherein an oxide coating is formed on the aluminum surface having a controlled electrical resistance and then the oxidized surface is stabilized by treatment with a hot aqueous alkaline solution containing long chain carboxylic acids.

Abstract: An aluminum container has an inner surface treated to suppress foaming of carbonated liquids subsequently placed therein by first chemically cleaning the aluminum surface, forming a conversion coating on the surface using a solution containing ions of phosphate, hexavalent chromium and fluoride; and treating the coated aluminum surface with an aqueous solution containing glycerol.

Abstract: An improved photographic element having high photosensitivity, which element comprises an anodized aluminum plate as a support having silver halide adsorbed in the pores of the oxide layer on the surface of said plate. The improvement comprises adding aqueous ammonia to a solution of silver nitrate used in forming said silver halide, the amount of aqueous ammonia being sufficient to raise the photosensitivity of the element.

Abstract: An aluminum layer such as an intraconnect on an integrated circuit semiconductive device is passivated by oxidizing the aluminum layer to form a thin layer of amorphous alumina thereon. The alumina layer is coated with a surface active agent to form a hydrophobic surface on the aluminum oxide to inhibit the creation and growth of ALOOH on the oxide layer. The hydrophobic surface is coated with a conventional passivating material such as silicon dioxide, epoxy or the like.

Abstract: A method for preparing aluminum based lithographic printing plates which comprises coating at least one surface of an aluminum base sheet with a potassium zirconium fluoride solution, thereafter treating the coated, aluminum plate with a stratum of a sodium silicate solution and then applying to said surface a lithographically suitable light sensitive composition to yield the desired photosensitive lithographic printing plate of improved characteristics.

Abstract: A process for improving the continuity of overlayers above an aluminum metallization stripe on a semiconductor device which includes the step of forming a conversion coating on the surface of the aluminium metallization. The conversion coating has a higher etch rate than the aluminum per se, and hence after selective masking, a tapered or sloped edge is produced on the aluminum stripe which is more easily continuously overlayed by the further necessary layers.

Abstract: A corrosive solution, designed to accelerate the rupture of workpieces of aluminum and its alloys in stress-corrosion-cracking tests, contains sodium chloride, hydrogen peroxide and sodium acetate dissolved in water, with maintenance of an acidic pH.

Abstract: Disclosed are an improved composition and process for the treatment of aluminum surfaces for the purpose of imparting corrosion resistance and improved receptivity of an organic finish. A lithium compound is added to an aqueous tannin composition to obtain this effect.

Abstract: A solar energy receiver comprising an aluminum panel and a coating which comprises a black metal sulfide film having a high solar absorptance but a low thermal emissivity and a method for the production of such a receiver by wet chemical deposition onto an aluminum panel of a metal sulfide film from an alkaline aqueous solution of a salt of a metal, a complexing agent for the metal ions, and a sulfur compound capable of reacting with the metal ions in the presence of aluminum to form a metal sulfide are disclosed.

Abstract: The hard rock-like scale formed on zinc phosphating equipment is rendered soft and dispersible by adding a scale-reducing amount of dialkyl triamine pentakis methylene phosphonic acid or its alkaline salt in the zinc phosphating solution.

Abstract: Disclosed are a composition and process useful for the treatment of an aluminum surface comprising contacting the surface with an aqueous solution containing at least 0.000025 weight percent of a vegetable tannin, which solution exhibits a pH of at least 3. Best results can be obtained via a two-stage tanin treatment in which the treating solution of the first stage also contains titanium and fluoride in dissolved form.