Abstract: Debondable adhesive compositions are provided. This disclosure also provides articles of footwear and components for articles of footwear including a debondable adhesive matrix. The debondable adhesive matrix can allow for the bonding and debonding of two substrates in the article of footwear or component thereof. This disclosure also provides methods of making the debondable adhesive compositions and methods of using said compositions for bonding and debonding the substrates, e.g. for bonding and debonding of an upper and an outsole in an article of footwear.

Abstract: An infiltrant comprising from 90 to 99.9 wt.-% of at least one polymerizable monomer, oligomer or prepolymer and from 0.05 to 10 wt.-% of a polymerization initiator, the infiltrant having a dynamic viscosity of 0.3 to 100 mPa·s (23° C.); for use in a method for strengthening a fixed ceramic dental prosthesis in the oral cavity.

Abstract: The invention is a bonding process using a composition comprising a) one or more organotitanates or zirconates having four ligands wherein the ligands are hydrocarbyl, optionally containing one or more functional groups having one or more heteroatoms selected from the group comprising oxygen, nitrogen, phosphorus and sulfur wherein two or more of the ligands may form a cyclic structure with the proviso that one of the ligands has an acidic moiety; one or more strong organic acids or a mixture thereof; b) one or more alkoxysilanes; c) optionally one or more high molecular weight resins; and d) a solvent which dissolves the components of the composition. This composition is referred to as a clear primer hereinafter. Preferably, the composition comprises both an organotitanate or zirconate and a strong acid.

Abstract: Methods of bonding glass and silicon-containing articles are disclosed. Bonding is achieved without use of adhesives or high temperature fusion. A wide variety of glass and silicon-containing articles may be bonded by the methods of the invention.

Abstract: Methods of bonding glass and silicon-containing articles are disclosed. Bonding is achieved without use of adhesives or high temperature fusion. A wide variety of glass and silicon-containing articles may be bonded by the methods of the invention.

Abstract: A method of gluing pieces of substrate together, by using an expandable gluing system comprising a resin component and a hardener component, wherein the hardener component is acidic, and the resin component comprises one or more gas generating substances capable of forming a gas when contacted with the hardener component, whereby the resin and the hardener components are separately applied onto the substrate. The invention also relates to a device suitable for carrying out the method.

Abstract: A method of preparing particles of a lignocellulosic material for the manufacture of a finished product, such as a particle board, includes the steps of chemically modifying the lignocellulosic material by impregnating the lignocellulosic material with a suitable anhydride in a non-aqueous solvent; applying to the particles of lignocellulosic material an adhesion promoter to promote the adherence of a thermoplastic resin to the surfaces of the particles of lignocellulosic material; and applying to the particles a thermoplastic resin in dry powder form, so that after the application of the adhesion promoter, the thermoplastic resin adheres to the surfaces of the particles of lignocellulosic material, the thermoplastic resin having been surfaced modified by irradiation or by fluorination; and removing any solvent present.

Abstract: A method of forming a bond between a resilient rubber member with a chlorinated surface and a bracket, especially in a vehicle mount assembly, includes forming a cured epoxy coating on the bracket member and heating the bracket member and the chlorinated surface of the rubber body to a bonding temperature while pressing them together to form a bond between them.

Abstract: A process is described which is useful in treating metal surfaces to increase the adhesion of polymeric materials thereto. The process involves treating the metal surface with a pre-dip which comprises an aqueous solution with pH of from 5 to 12 and then further treating the metal surface with an adhesion-promoting composition comprising an acid, an oxidizer and a corrosion inhibitor.

Abstract: A hemming machine for simultaneously bending a flange on a first panel into engagement with an edge portion of a second panel to form a hem, and at least partially curing an adhesive located in the hem. The flange bending members and/or the top surface of the panel support nest of the present invention are heated using electric cartridge heaters, hot oil, or electric heating cables, for example. During the hemming operation the nested panels are in constant direct contact with the panel support nest, and the heated flange bending members are in direct contact with the hem for approximately 3 to 6 seconds (dwell time is dependent on whether the die blocks are heated or if the die blocks are heating in conjunction with the top surface of the panel support nest), which is generally sufficient to at least partially cure the adhesive located in the hem, thereby reducing the incidence of panel shift during subsequent transfer through the manufacturing process using conveyors, racks etc.

Abstract: Pretreatment of elastomer substrate surfaces with aqueous solutions of monopersulfate compound (MPS) and the improved adhesive bonds obtained between such pretreated substrate surfaces and other substrates.

Abstract: An agent is characterized by containing a polymerizable monomer having a thiophosphoric acid dichloride group. By applying this agent to the surfaces of noble metals, much more durable and increased bond strength is obtained.

Abstract: Adhesives for ceramics obtained as first adhesives for ceramics according to the invention are excellent in bond properties as well as in water resistance because they contain first acidic compounds such as organic carboxylic acids in addition to silane coupling agents, polymerizable monomers and polymerization catalysts. Further, adhesives for ceramics obtained as second adhesives for ceramics according to the invention are excellent in bond properties as well as in dependability and water resistance because they contain metal salts in addition to silane coupling agents, polymerizable monomers and polymerization catalysts. Furthermore, adhesives for ceramics obtained as third adhesives for ceramics according to the invention are excellent in bond properties as well as dependability and water resistance because they contain second acidic compounds selected from among metal salts and organic carboxylic acid anhydrides in addition to silane coupling agents, polymerizable monomers and polymerization catalysts.

Abstract: A method for manufacturing vibration proof rubber by compounding rubber elastic bodies between an inner metal fitting and outer shell metal fitting including the steps of forming a rubber layer by curing adhesion of the rubber elastic bodies to the respective metal fittings, applying a halogen compound solution to the bonding surfaces of the respective rubber layers and then press-fitting the inner metal fitting to the outer shell metal fitting using a lubricant or a lubricating adhesive. The above manufacturing method prevents the defects found in conventional types of vibration proof rubber, particularly disadvantages such as poor durability in a corrosive environment and further the severe requirements which have recently been imposed on vibration proof rubber can sufficiently satisfied.

Abstract: A metal-working lubricant comprises an aqueous emulsion of (a) a long-chain aliphatic ester, amide, alcohol or acid, and (b) as a fugitive emulsifier an ammonium or volatile amine salt of a long-chain aliphatic acid. On application to sheet, e.g. of aluminum metal with a chromate or anodic oxide protective surface layer, the water and ammonia or volatile amine evaporate to leave a storage-stable hydrophobic lubricant. The sheet can be formed or made into adhesively bonded structures of shaped components.

Abstract: A method of pretreating wood veneers with a wetting agent which reduces the amount of adhesive required to bond the veneers together in plywood manufacturing. The wetting agent can be water or a liquid solution containing an elastomer or plasticizer which leaves a thin film of solids on the veneer surface after it evaporates. The wetting agent is in part absorbed by the veneer to inhibit absorption of liquid from the adhesive. Also, the solid film left on the veneer flows on the glue line and wets the adhesive when the veneer is hot pressed. This promotes flow and spreading of the adhesive, even if it is partially dry, and thus results in more effective use of the adhesive so that the adhesive usage is reduced.

Abstract: A method of preparing a composite of polyurethane bonded to the surface of a cured rubber substrate and the resulting composite. The method requires the rubber substrate to contain an hydroxyl terminated polybutadiene polyol. The method is practiced by first applying to a cleaned, cured rubber surface containing the polybutadiene polyol a coating of cyanuric acid followed by an additional coating of a phenol formaldehyde resin and then applying a liquid polyurethane reaction mixture which is cured to form the resultant composite. The invention is particularly directed to the preparation of a tire comprised of a polyurethane carcass applied to a cured rubber tread and to a tire comprised of a polyurethane tread applied to a cured rubber carcass.

Abstract: A method is disclosed for laminating plastics resin films to aluminum. The aluminum surface to be bonded is treated with a coating composition consisting essentially of an aqueous solution of polyacrylic acid or esters thereof and at least one acid selected from the group consisting of H.sub.2 ZrF.sub.6, H.sub.2 TiF.sub.6 and H.sub.2 SiF.sub.6. After this coating has dried, the plastics resin film is bonded to the aluminum, using dry laminating adhesives.

Abstract: A process and chemical composition for laminating a photograph or lithograph onto canvas are disclosed whereby the resulting product appears similar to an oil painting, as well as providing improved depth. The process involves stripping a photograph or lithograph from a substantial portion of its backing, followed by application of the chemical composition to the photograph. The chemical composition includes a surfactant and an optical brightener such as a fluorescent whitening agent, and can include a sensitizer and stabilizer. The treated photograph or lithograph is then bonded to a textured backing at elevated temperature and pressure.

Abstract: A protective material for use in articles of apparel such as golves, leggings, sleeves, aprons and the like. The protective material comprises a base layer composed of textile material, an intermediate layer composed of a cut-resistant material having intermeshing strands defining pores therebetween and an outer layer composed of solid, elastomeric material which retards penetration by liquid. The elastomeric material covers and is bonded to the base layer which prevents passage entirely therethrough by liquid, elastomeric material but permits partial penetration. The solid, elastomeric material extends through the pores of the intermediate layer and encapsulates the strands thereof. A method for producing the protective material comprises dipping an article composed of base layer and intermediate layer into a bath of liquid, elastomeric material preferably after absorbing into the base layer a coagulant for the liquid elastomeric material.

Abstract: The present invention is directed to a method for improving the adhesion of epoxy resins to steel substrates which comprises first removing the oxide surface layer, preferably by chemical means, and then pretreating the substrate with a solution of at least one coupling agent selected from the group consisting of .beta.-diketones and mercaptoesters. The invention also provides a method for improving the adhesion of epoxy resins to steel substrates by pretreating with citric acid or a salt thereof.

Abstract: A method of preparing nitrile elastomer surfaces for bonding by epoxy adhves is presented. A treating solution comprising a dilute concentration of a mineral acid such as HCl in a carrier comprising water and either alcohol or ketones is prepared. The treating solution is applied to the elastomer surface with the surface being hydrolyzed in a mild manner thereby providing an improved adherable surface for covalent bonding by epoxy adhesives. A surfactant can be added to the treating solution for cleaning the surface to enhance the surface treatment.

Abstract: A process and chemical composition for laminating a photograph or lithograph onto canvas are disclosed whereby the resulting product appears similar to an oil painting, as well as providing improved depth. The process involves stripping a photograph or lithograph from a substantial portion of its backing, followed by application of the chemical composition to the photograph. The chemical composition includes a surfactant and an optical brightener such as a fluorescent whitening agent, and can include a sensitizer and stabilizer. The treated photograph or lithograph is then bonded to a textured backing at elevated temperature and pressure.

Abstract: In producing an article having a structurally primary part obtained by press-forming of a metal sheet to which a lubricant is applied beforehand and a secondary part stuck to the primary part with an adhesive, troublesome procedures for removal of the lubricant from the press-formed metal part precedent to adhesion-bonding of the secondary part can entirely be omitted without sacrificing the strength of adhesion between the primary and secondary parts by using an adhesive that has high chemical affinity with the lubricant remaining on the surface of the press-formed metal part. Preferably use is made of a solid lubricant containing organic polymeric substance as its principal component. In many cases the secondary part is made of a nonmetallic material, either an organic material or an inorganic material.

Abstract: At least a substantial amount of the corrosion products on the surface(s) of brass plated steel cord are removed by treatment in an aqueous solution containing a minor amount of an NH.sub.4, Na, K, Li, Ca, Mg, Sr, Ba and Zn salt of a saturated aliphatic carboxylic acid of from 1 to 5 carbon atoms.

Abstract: A method of bonding a cation exchange membrane which comprises melt-bonding a part of the cation exchange membrane of a fluorinated copolymer in the form having ion-exchange groups of --COOY wherein Y represents hydrogen atom or a C.sub.1 -C.sub.20 alkyl group, when the cation exchange membrane is used in the form having ion-exchange groups of--(COO).sub.m Xwherein X represents an alkali metal, an alkaline earth metal or --NHR.sub.1 R.sub.2 R.sub.3 and R.sub.1 to R.sub.3 respectively represent hydrogen atom or a lower alkyl group and m is a valence of X.

Abstract: The adhesion of brass plated steel cord to rubber is improved in many cases by treatment of the cord with a dilute aqueous solution of certain amino carboxylic acids and their corresponding ammonium, lithium, sodium and/or potassium salts and salt hydrates. After dipping in the treating solution, the cords may be rinsed with water, dried, combined with a vulcanizable rubber compound and vulcanized.

Abstract: This invention relates to the treating of wood surfaces with a solution of selected boron compounds in order to preserve bondability during drying or storing. Effective compounds are borax and boric acid which are applied in an aqueous solution to the wood surface prior to drying or storing.

Abstract: A two part adhesive composition characterized by rapid curing and long shelf life is disclosed. The adhesive composition comprises a first component of an acrylic monomer and copper saccharinate or saccharin and a soluble copper salt and a second component comprising an alpha-hydroxy sulfone or an alpha-amino sulfone or mixtures thereof which functions as an activator therefor.

Abstract: A two part adhesive composition characterized by rapid curing and long shelf life is disclosed. The adhesive composition comprises a first component of an acrylic monomer and saccharin or copper saccharinate and a second component comprising a p-toluenesulfinic acid salt which functions as an activator therefor.

Abstract: The instant invention comprises providing copper or a copper alloy which has on its surface a uniform glassy like and substantially pore free coating of copper phosphate, rinsing the coated material for at least 2 seconds in water at a pH of from 4.9 to 6.3, at a temperature of 90.degree.C to the boiling point and drying.

Abstract: The instant invention comprises providing copper or a copper alloy which has on its surface a uniform glassy like and substantially pore free coating of copper phosphate, rinsing the coated material for at least two seconds in water at a pH of at least 8.0, at a temperature of 90.degree.C to the boiling point and drying.

Abstract: The instant invention comprises providing copper or a copper alloy which has on its surface a uniform glassy like and substantially pore free coating of copper phosphate, rinsing the coated material for at least two seconds in water at a pH of from 4.9 to 6.3, at a temperature of 90.degree.C to the boiling point and drying.

Abstract: The instant invention comprises providing copper or a copper alloy which has on its surface a uniform glassy like and substantially pore free coating of copper phosphate, rinsing the coated material for at least two seconds in water at a pH of at least 8.0, at a temperature of 90.degree.C to the boiling point and drying.