Abstract: The invention provides a carbon dioxide-resistant hydraulic cement composition. The inventive composition comprises a Portland cement, Class C fly ash and water. The Class C fly ash is present in the composition in an amount in the range of from about 5% to less than about 30% by weight based on the total weight of the cementitious components in the composition. In another aspect, the invention provides a method of cementing in a carbon dioxide environment. In yet another aspect, the invention provides a method of enhancing the recovery of a hydrocarbon fluid from a subterranean formation.

Abstract: To protect an underground aquifer from pollution due to the extraction of subsurface products from a recovery well or other subsurface mining operation, a plurality of barrier injection wells are formed around the recovery well/subsurface operation, each barrier injection well terminating in a groundwater layer to be protected. A polymer matrix material is then into the injection wells such that the material exiting each injection well expands and overlaps with material exiting from adjacent wells prior to solidification, thereby forming an isolation barrier within the groundwater layer. In the preferred embodiment, the polymer matrix material is a cellulose polymer hydrogel matrix material which is injected in gel form. Following recovery of the hydrocarbonaceous products from the recovery well(s), the injected polymer matrix material may be reheated and subsequently liquefied allowing full groundwater flow to occur.

Abstract: Methods for controlling lost circulation in subterranean wells, and in particular, fluid compositions and methods for operations during which the fluid compositions are pumped into a wellbore, enter voids in the subterranean-well formation through which wellbore fluids escape, and form a seal that limits further egress of wellbore fluid from the wellbore. The methods include preparing a carrier fluid containing compressed expandable foam that may be encapsulated. The carrier fluid is then placed into a lost-circulation zone, whereupon the foam expands to form a barrier that minimizes or blocks further ingress of carrier fluid. Lost-circulation control may be supplemented by introducing additional lost-circulation materials, pumping a cement slurry behind the foam-containing carrier fluid or both.

Abstract: The disclosure relates to a system (10) for improving zonal isolation in a well in a subterranean formation, comprising: a tubular (1) having a outer surface (11); and a swellable coating (2) coating the outer surface (11) of said tubular (1), said swellable coating (2) having an external surface (21); and/or a composition (20) provided in an annular space outside said tubular (1). The swellable coating (2) is made of a first swellable material (3) able to swell in contact with a first fluid (6) on said external surface (21) and/or the composition (20) is made of a second swellable material (4) able to swell in contact with a second fluid (7), and wherein said first (3) and/or said second (4) swellable materials include an elastomer compounded with an aqueous inverse emulsion of particles of a polymer comprising a betaine group, said elastomer being able to swell in contact with hydrocarbon and saline aqueous fluids.

Abstract: Mixtures of fibers and solid particles are effective for curing fluid losses and lost circulation in a subterranean well. Stiff fibers are more effective than flexible ones; however, mixtures of stiff and flexible fibers have a synergistic effect. The quantity and particle-size distribution of the solids are optimized according to the stiffness, dimensions and concentrations of fibers.

Abstract: A method of servicing a wellbore in a subterranean formation, comprising preparing a cement composition comprising water and a cementitious material, wherein the cementitious material further comprises blast furnace slag, vitrified shale, calcium sulfate hemi-hydrate or combinations thereof, and placing the cement composition in the wellbore. A cement composition comprising water and a cementitious material, wherein the cementitious material further comprises blast furnace slag, vitrified shale, calcium sulfate hemi-hydrate or combinations thereof. A cement composition comprising water and a cementitious material, wherein the cementitious material further comprises blast furnace slag.

Abstract: Methods and compositions are provided that relate to sealant compositions comprising cement kiln dust, tire-rubber particles, and water. An embodiment discloses a method comprising: providing a sealant composition comprising cement kiln dust, tire-rubber particles, and water; and allowing the sealant composition to set to form a hardened mass.

Abstract: An embodiment of the present invention comprises a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising unexpanded perlite, cement kiln dust, and water; and allowing the settable composition to set. Another embodiment of the present invention comprises a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising ground unexpanded perlite, Portland cement interground with pumicite, and water; and allowing the settable composition to set. Yet another embodiment of the present invention comprises a settable composition comprising: ground unexpanded perlite; cement kiln dust; and water.

Abstract: An example method of cementing in a subterranean formation includes determining a settable composition for use in the subterranean formation; calculating a total carbon footprint of the settable composition; determining at least one additive for use in the settable composition, wherein the additive replaces at least a portion of the settable composition and reduces the total carbon footprint of the settable composition; preparing the settable composition comprising the additive; placing the settable composition comprising the additive in the subterranean formation; and allowing the settable composition comprising the additive to set in the subterranean formation. Additional embodiments of the present invention include determining an amount of reduction in the carbon footprint of the settable composition; and/or communicating the amount of reduction in the carbon footprint of the settable composition to a customer or end user.

Abstract: Methods comprising mixing particulates with a consolidating agent emulsion to form a slurry; creating a foamed slurry by adding a foaming agent and a gas to the slurry; placing the foamed slurry into a portion of a subterranean formation so as to create a particulate pack; and flushing the particulate pack with a postflush fluid. In some embodiments, the consolidating agent emulsion composition comprises a resin composition.

Abstract: The invention provides a cementing composition for use in oilfield application, wherein a significant amount of cement is left intentionally un-hydrated when the cement is set; such that said amount of un-hydrated cement becomes hydrated when the set cement is damaged.

Abstract: Embodiments disclose method and compositions that comprise cement kiln dust and rice husk ash. An embodiment comprises a method of cementing comprising: placing a settable composition into a subterranean formation, the settable composition comprising cement kiln dust, rice husk ash, and water; and allowing the settable composition to set.

Abstract: Compositions and methods according to the invention are directed to a cement composition for use in a subterranean formation. The cement composition comprises: (A) cement; (B) water; and (C) a polymer, wherein the polymer: (i) comprises a monomer or monomers selected from the group consisting of epoxysuccinic acid, a substituted epoxysuccinic acid, and an alkali metal salt, alkaline earth metal salt, or ammonium salt of any of the foregoing, and any combination of any of the foregoing; (ii) has the following characteristics: (a) is water soluble; and (b) is biodegradable; and (iii) is capable of providing: (a) a thickening time of at least 2 hours for a test composition at a temperature of 190° F. and a pressure of 5,160 psi; and (b) an initial setting time of less than 24 hours for the test composition at a temperature of 217° F. and a pressure of 3,000 psi, wherein the test composition consists of 860 grams of Class-H Portland cement, 325 grams of deionized water, and 0.

Abstract: Spacer compositions and products may include a biopolymer component, a plant fiber component, and a weighting agent component, and in further non-limiting embodiments may include xanthan gum, a blend of plant fibers, and a weighting agent component. These spacer compositions and spacer products may be utilized in well fluid operations, including well cementing operations and well completion operations.

Abstract: According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a Lewis acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition.

Abstract: According to an embodiment, a method for thermally insulating a portion of a tubular located inside an enclosed conduit comprises the steps of: (A) introducing a grouting composition into an annulus between the tubular and the enclosed conduit, the grouting composition comprising: (i) an oil-swellable binding material; and (ii) a hydrocarbon liquid, wherein the hydrocarbon liquid is the continuous phase of the grouting composition; and (iii) an insulating material comprising a hollow microsphere; and (B) allowing or causing the grouting composition to set after the step of introducing, wherein after setting the grouting composition has a thermal conductivity of less than 0.3 BTU/hr·ft·° F.

Abstract: A product, system and method for controlling fluid loss in oil wells, including lost circulation while drilling wells. A load of fluid control pods is pumped down the drill string into the target formation using water, drilling mud or another suitable delivery fluid. Each pod comprises a discrete mass of swelling agent with a frictional surface. Preferably, the pod comprises superabsorbent granules inside a fabric sack that is deformable and elastic and provides the frictional surface. After the pods have time to swell and become compressed against each other in the voids, drilling or other procedures may be continued. The size and frictional surface of the pods facilitates stable positioning of the pods in the voids of the formation, minimizes the total amount of swelling agent required, and reduces the tendency of the pods to become dislodged.

Abstract: The present invention is directed to plug-and-abandon operations that use plugging compositions comprising cement kiln dust, pumicite, and/or lime. An embodiment includes a method of plugging a well bore for abandonment comprising: placing a plugging composition in the well bore, the plugging composition comprising: cement kiln dust in an amount of about 5% to about 100% by weight of cementitious components, pumicite in an amount of about 5% to about 100% by weight of cementitious components, 0% to about 24% of Portland cement by weight of cementitious components, and water; and allowing the plugging composition to set and form a plug.

Abstract: A method of converting a completed well into a dual completed well that includes selectively pumping a water-based fluid into a first production zone of the completed well, wherein the water-based fluid has a pH of greater than about 5; allowing the water-based fluid to form a continuous, non-flowing water-based gel in the first production zone of the completed well, wherein the water-based gel has a pH of greater than about 5; disposing a layer of cement into the completed well above the water- based gel; perforating a second production zone of the completed well in a location above the layer of cement; drilling through the layer of cement; and breaking the water-based gel located in the first production zone of the completed well, wherein the breaking comprises: exposing the water-based gel to a breaker fluid, wherein the breaker fluid has a pH of greater than about 5 is disclosed.

Abstract: The present invention relates to acid-soluble cement compositions that comprise cement kiln dust (“CKD”) and/or a natural pozzolan and associated methods of use. An embodiment includes a method of cementing comprising: placing an acid-soluble cement composition in a subterranean formation, wherein the acid-soluble cement composition comprises a hydraulic cement, a component selected from the group consisting of CKD, pumicite, and a combination thereof, and water; allowing the acid-soluble cement composition to set; and contacting the set acid-soluble cement composition with an acid to dissolve the set acid-soluble cement composition.

Abstract: Disclosed are spacer fluids comprising cement kiln dust (“CKD”) and methods of use in subterranean formations. An embodiment discloses a method comprising: providing a foamed spacer fluid comprising CKD, a foaming agent, a gas, and water; and introducing the foamed spacer fluid into a well bore to displace at least a portion of a first fluid present in the well bore. Another embodiment discloses a method comprising: providing a foamed spacer fluid comprising a partially calcined kiln feed removed from a gas stream, a foaming agent, a gas, and water, wherein the partially calcined kiln feed comprises SiO2, Al2O3, Fe2O3, CaO, MgO, SO3, Na2O, and K2O; and introducing the foamed spacer fluid into a well bore to displace at least a portion of a first fluid present in the well bore.

Abstract: Apparatus and methods comprising a plurality of particles which are magnetically attracted to one another in response to exposure to an magnetic field, and which maintain attraction to one another after removal of the magnetic field, the attraction being disabled when the particles are demagnetized, whereby the particles operate to alter the rheological properties of a fluid in which the particles are mixed when the attraction is enabled or disabled is disclosed.

Abstract: Methods and compositions are disclosed that comprise cement kiln dust having a mean particle size that has been altered. An embodiment discloses a subterranean treatment method comprising: introducing a treatment fluid into a subterranean formation, wherein the treatment fluid comprises cement kiln dust having a mean particle size that has been altered from its original size by grinding, separating, or a combination thereof. Another embodiment discloses a subterranean treatment method comprising: introducing a treatment fluid into a subterranean formation, wherein the treatment fluid comprises cement kiln dust having a mean particle size that has been reduced from its original size.

Abstract: Of the many methods and compositions provided herein, one method includes a method comprising introducing a sealant composition into a well bore that penetrates a subterranean formation, wherein the sealant composition comprises a base fluid, a binder material, and a filler material; and allowing the sealant composition to form a cohesive sealant. One composition provided herein includes a sealant composition comprising a base fluid, a binder material, and a filler material, wherein the sealant composition will form a cohesive sealant.

Abstract: The present invention relates to a process for binding non-consolidated oxidic inorganic materials with curable formulations which comprise etherified amino resins, and to cured compositions obtainable by the process. A preferred embodiment of the invention comprises a process for stabilizing underground formations composed of oxidic inorganic materials, wherein the curable composition is injected into the underground formation and cured at the temperatures which exist in the formation.

Abstract: Methods for treating an interval of a subterranean formation having a permeability that varies include identifying the interval to be treated; introducing a relative-permeability modifier into the interval, wherein the relative-permeability modifier modifies the interval to have a more uniform effective permeability to water, and wherein the relative-permeability modifier comprises a water-soluble polymer; and introducing a sealant into the interval, wherein the more uniform effective permeability of the interval allows for a more uniform treatment of the interval by the sealant than would be allowed without treatment of the interval with the relative-permeability modifier.

Abstract: Methods comprising providing a dry, solid particulate material comprising a cementitious material, a non-cementitious material, or a combination thereof and having a flow enhancing additive absorbed thereon. The flow enhancing additive comprises a flow inducing chemical, ethylene glycol, and water. The coated, dry, solid material is then mixed with a sufficient amount of water to form a pumpable slurry and then the slurry may be placed in a subterranean formation. In some cases the dry, solid particulate material comprising a cementitious material, a non-cementitious material, or a combination thereof and having a flow enhancing additive absorbed thereon may be stored for a period of time before the slurry is formed.

Abstract: Of the methods provided herein, is a method comprising: providing a clean-up fluid comprising a peroxide-generating compound and an aqueous base fluid; placing the clean-up fluid in a subterranean formation; removing contaminants from at least a portion of the subterranean formation to form a cleaned portion of the formation; providing a consolidation agent; placing the consolidation agent on at least a portion of the cleaned portion of the formation; and allowing the consolidation agent to adhere to at least a plurality of unconsolidated particulates in the cleaned portion of the formation.

Abstract: Methods are provided that include a method comprising: providing an emulsified treatment fluid comprising an oleaginous phase, an aqueous phase, a consolidating agent, and an emulsifying agent that comprises at least one convertible surfactant described by a one of the disclosed formulae, and placing the subterranean treatment fluid in a subterranean formation.

Abstract: A wellbore servicing method comprises converting a water into an electrochemically activated water, preparing a wellbore servicing composition comprising the electrochemically activated water, and placing the wellbore servicing composition in a wellbore. Also, a cement composition comprises a cement and an electrochemically activated water.

Abstract: Methods and compositions for consolidating particulate matter in a subterranean formation are provided. In one embodiment, a method of treating a subterranean formation includes coating a curable adhesive composition comprising a silane coupling agent and a polymer having a reactive silicon end group onto proppant material; suspending the coated proppant material in a carrier fluid to form a proppant slurry; introducing the proppant slurry into a subterranean formation; and allowing the curable adhesive composition to at least partially consolidate the proppant material in the subterranean formation.

Abstract: The present invention provides settable compositions and methods of using settable compositions that comprise a hydraulic cement; a partially calcined kiln feed comprising SiO2, Al2O3, Fe2O3, CaO, MgO, SO3, Na2O, and K2O; metakaolin; and water. The location to be cemented may be above ground or in a subterranean formation.

Abstract: A method of controlling pressure in a wellbore can include placing a barrier substance in the wellbore while a fluid is present in the wellbore, and flowing another fluid into the wellbore while the first fluid and the barrier substance are in the wellbore. The first and second fluids may have different densities. Another method can include circulating a fluid through a tubular string and an annulus formed between the tubular string and the wellbore, then partially withdrawing the tubular string from the wellbore, then placing a barrier substance in the wellbore, then partially withdrawing the tubular string from the wellbore and then flowing another fluid into the wellbore. A well system can include at least two fluids in a wellbore, the fluids having different densities, and a barrier substance separating the fluids.

Abstract: Spent Claus catalyst having a high alumina content is used as an ingredient in the manufacture of Portland cements in place of all or a portion of a conventional source of alumina. The spent Claus catalyst is preferably of a small particle size and can be ground to the desired fineness before mixing with the other ingredients that are heated in a conventional kiln to produce the cement composition. Finely ground spent Claus catalyst can also be used as an additive at levels of 0.1% to 2% by weight to increase the thickening time of shallow casing cement slurries.

Abstract: A self-adaptive cement formulation includes cement, water, block copolymer and asphaltite-mineral particles. The set cement demonstrates self-healing properties when exposed to methane, and is particularly suited for well-cementing applications. After placement and curing, the self-healing properties help maintain zonal isolation should bonding be disrupted between the set cement and the formation or a casing string, should cracks or defects appear in the set-cement matrix, or both.

Abstract: Compositions having shear-gelling and shear-thickening properties are based on an amphiphilic polymer combined with hydrophilic particles and polyethyleneoxide. The hydrophilic particles preferably consist of a hydrous sodium lithium magnesium silicate. The amphiphilic polymer may be a synthetic polymer, a hydrophobically modified biopolymer, or both. The compositions may be employed in enhanced oil recovery operations.

Abstract: A method of cementing involves introducing a pipe string into a well bore such that an annulus is defined between the pipe string and a wall of the well bore, and introducing a cement composition into the annulus. The cement composition includes cement, water, and an auto-sealing component. An annular structure, coupled to the pipe string, comprises an expandable material.

Abstract: Methods of characterizing the self-healing properties of a set cement based material in contact with hydrocarbons in an oil- and/or gas-well are described. The methods comprise: providing a test cell (10); providing said test cell (10) with a sample (31, 40) of the set cement based material; damaging the sample to simulate a loss of zonal isolation resulting from damages made to the set cement based material in the oil- or gas-well; injecting a hydrocarbon fluid in the test cell; allowing the cement based material to heal by itself; measuring the differential pressure (?P) across the sample (31, 40); and characterizing the self-healing properties of the cement based material from the measure of said differential pressure (?P).

Abstract: A cement slurry comprising a mixture of a cement blend and water, wherein the cement blend comprises at least about 70% by volume of blend of cementitious particulate material and water is present in the mixture in an amount of not more than 50% by volume of the slurry.

Abstract: A system for automating service operations at a well includes a service rig having at least one input device, an engine connected to an engine electronic control unit having a engine controller area network, a plurality of crown sheeves, a cable, an output device, a communication infrastructure, and at least one of a computer and an operator station; at least one remote server in electronic communication with the communication infrastructure; and a web portal in electronic communication with the at least one remote server.

Abstract: The present invention is related in general to fluid compositions and methods for servicing subterranean wells. Particularly, the invention relates to the use of a fiber-laden fluid to separate two wellbore-service fluids as they travel through a tubular body, preventing their commingling. The invention obviates the need for mechanical devices such as wiper plugs, or special adjustment of the wellbore-service fluids' rheological properties.

Abstract: Viscoelastic compositions are disclosed herein containing an effective amount of one or more random or structurally defined polycationic quaternary ammonium compounds for controlling the viscoelasticity of the composition. In one aspect, the present technology provides polycationic quaternary ammonium compounds that comprise bis-quaternary compound. The bis-quaternary compounds of the present technology can be symmetric or dissymmetric. In another aspect, the present technology provides viscoelastic well bore treatment fluids comprising water, and at least one polycationic quaternary ammonium compound that comprises a bis-quaternary compound. In another aspect, the present technology provides polycationic carboxylates. Preferred viscoelastic compositions of the present technology maintain viscoelasticity at a temperature greater than about 80° C., preferably greater than about 100° C. or 110° C.

Abstract: The invention discloses a method of creating a polymerized composition in a well bore: providing a polymerizable composition made of a polymerization initiator and a monomer polymerizable by frontal polymerization; introducing the polymerizable composition into the wellbore; exposing the polymerizable composition to a trigger to activate the frontal polymerization; and creating the polymerized composition.

Abstract: Plug-inducing matter includes junk shot comprising members and swellable material substantially covering the members which are configured to swell upon exposure to wellbore fluids.

Abstract: A method of well construction or treatment comprising the introduction of a settable cement that contains pulverulent aplite down a borehole is provided, together with a cement composition comprising at least 30% by weight of cement pulverulent aplite on a dry solid basis.

Abstract: A cement retarder composition, method, kit and system are herein disclosed. Seeds are added to cement to delay the setting of cement. Cement retarders are added to cement to delay the setting of the cement until it is pumped to the desired position.

Abstract: A method of controlling pressure in a wellbore can include placing a barrier substance in the wellbore while a fluid is present in the wellbore, and flowing another fluid into the wellbore while the first fluid and the barrier substance are in the wellbore. The first and second fluids may have different densities. Another method can include circulating a fluid through a tubular string and an annulus formed between the tubular string and the wellbore, then partially withdrawing the tubular string from the wellbore, then placing a barrier substance in the wellbore, then partially withdrawing the tubular string from the wellbore and then flowing another fluid into the wellbore. A well system can include at least two fluids in a wellbore, the fluids having different densities, and a barrier substance separating the fluids.

Abstract: This invention relates to the use of degradable fibers, and more particularly, to self-degrading fibers and their associated methods of use and manufacture. In one embodiment, the present invention provides a self degrading fiber comprising: an outer shell, and a core liquid.

Abstract: The present disclosure is directed to a system and method for managing cement in a subterranean zone. In some implementations, a method of cementing in a subterranean formation includes positioning a cement slurry including a plurality of activation devices in a wellbore. The activation devices configured to release an activator that increases a setting rate of the cement slurry. A signal is transmitted to at least a portion of the cement slurry to activate the activation devices. The activation device releases the activator in response to at least the signal.

Abstract: Methods and compositions are provided that relate to cementing operations. Methods and compositions that include a latex strength enhancer for enhancing the compressive strength of slag compositions.