Abstract: A method and apparatus for manufacturing ceramic microspheres from industrial slag. The microspheres have a particle size of about 38 microns to about 150 microns. The microspheres are used to create a cement slurry having a density of at least about 11 lbs/g. The resultant cement slurry may then be used to treat subterranean wells.

Abstract: The invention relates to providing controlled delivery of subterranean fluid additives to a well bore treatment fluid and/or a surrounding subterranean environment using intelligent materials that respond to a magnetic stimulus to release subterranean fluid additives downhole in a subterranean environment. Methods disclosed include a method of releasing a subterranean fluid additive in a subterranean formation comprising: providing a magnetically-sensitive component that comprises a subterranean fluid additive; providing a magnetic source; and releasing the subterranean fluid additive in the subterranean formation from the magnetically-sensitive component using a magnetic force generated from the magnetic source.

Abstract: Methods suitable for use in a subterranean formation utilizing particulates coated with both a tackifier and a resin.

Abstract: Methods and apparatuses for releasing a chemical in a well bore are disclosed. One apparatus includes a curved member configured for coupling to a casing, and a hollow member is connected to the curved member. A chemical container is disposed, at least in part, within the hollow space, and the hollow member extends at least partially around a hollow space.

Abstract: A method of servicing a wellbore in contact with a subterranean formation, comprising: placing a wellbore servicing fluid comprising a crosslinkable polymer system and a filler into a lost circulation zone within the wellbore. A method of blocking the flow of fluid through a lost circulation zone in a subterranean formation comprising placing a first composition comprising a packing agent into the lost circulation zone, placing a second composition comprising a crosslinkable polymer system and a filler into the lost circulation zone, and allowing the compositions to set into place.

Abstract: Rapid swelling and un-swelling materials provide for rapid actuation of well tools. A well tool can include a swellable material, with the swellable material comprising a swellable glass material. A method of actuating a well tool in a subterranean well can include contacting a swellable material of the well tool with an activating fluid in the well, thereby causing the swellable material to swell. The well tool rapidly actuates in response to contacting the swellable material with the activating fluid.

Abstract: Methods including the steps of providing an injection well having unconsolidated particulates in one or more formation intervals along the wellbore that accept injection fluid; providing a consolidating treatment fluid comprising a base fluid and a consolidating agent; introducing the consolidating treatment fluid through the injection well, while the well is under injection, such that the consolidating treatment fluid enters into a portion of a formation interval along the wellbore that accepts injection fluid; and, allowing the consolidating fluid to consolidate formation particulates therein. The methods may be performed such that the percentage of consolidating agent varies over the course of the treatment or the rate of injection varies over the course of the treatment.

Abstract: A well cement composition for plugging a bore at the location for initiating sidetracking to bore a lateral well is formulated as a slurry of hydraulic cement that contains at least two, but preferably all three of the following additives: (1) a source of silicon dioxide, (2) fracturing proppants and (3) an expansion compound selected from the group consisting of 1%-5% crystalline silica and 60%-99% MgO or CaO, and their mixtures.

Abstract: Stimulation operations can be conducted by isolating portions of a subterranean formation adjacent to a highly deviated well bore. The planned settled height of a sand plug in a well bore adjacent a first zone of the subterranean formation is determined. The first zone is then perforated using a hydrajetting tool which is oriented so as to form perforations below the planned settled height of the sand plug.

Abstract: Set retarders of copolymers of at least one polymerizable ethylenically unsaturated monomer and at least one alkoxylated sulfate, phosphate or ketonic salt are capable of delaying the hardening of a cementitious slurry when introduced into a subterranean formation until a downhole temperature greater than or equal to 500° F. is obtained, even in the absence of an intensifier.

Abstract: A composition for use in plugging a well includes a mud having a plurality of plugging members therein, wherein the plugging member has a density more than about eight times that of water. A method of providing the composition into the well is also provided.

Abstract: Organic compounds containing at least one nitrogen atom are particularly suitable as retarders for geopolymeric systems employed as well cements. Preferred compounds include aminated polymers, amine phosphonates, quaternary ammonium compounds and tertiary amines. The geopolymeric compositions are suitable for primary cementing and remedial cementing operations. The preferred temperature range within which the retarders operate is between about 20° C. and 120° C.

Abstract: Sealant compositions comprising a colloidally stabilized latex and methods of using the same to service a wellbore are provided. The sealant compositions may include: an aliphatic conjugated diene monomer; an additional monomer comprising a non-aromatic unsaturated mono- or di- carboxylic ester monomer, an aromatic unsaturated monomer, a nitrogen-containing monomer, or combinations thereof; and a protective colloid. The foregoing sealant composition may be displaced into the wellbore to isolate the subterranean formation from a portion of the wellbore, to support a conduit in the wellbore, to plug a void or crack in the conduit, to plug a void or crack in a cement sheath disposed in an annulus of the wellbore, to plug an opening between the cement sheath and the conduit, or combinations thereof. The colloidally stabilized latex remains substantially stable when exposed to salt, which may be present in the wellbore and/or in the sealant composition itself.

Abstract: A barrier plug assembly for incorporation into a lower portion of a plumbing installation for supporting a column of test water during inspection of the installation includes a tubular plumbing segment for sealingly securing between and in fluid communication with opposing and spaced apart portions of a plumbing installation, the tubular plumbing segment being formed of plumbing segment material and having a plumbing segment interior and a substantially smooth and continuous plumbing segment interior surface; and a barrier plug having a plug upper surface and a plug lower surface, and having a plug circumferential surface adhering to the plumbing segment interior surface and extending diametrically across and sealing the plumbing segment interior until dislodged by a plug dislodgement triggering means; so that upon plug dislodgement the test water drains and the plumbing installation is operational.

Abstract: A slurry for treating a wellbore that includes a base fluid; at least one fibrous structure; and a plurality of calcium silicate particles is disclosed. Methods of reducing loss of wellbore fluid in a wellbore to a formation using an LCM pill having calcium silicate particles therein is also disclosed.

Abstract: The present invention includes methods and compositions relating to the setting of fluids or slurries in a wellbore. In one embodiment, a method of isolating a portion a wellbore includes preparing a sealant composition having a fluid component, a polymeric additive constituent, and a set modifier component. The sealant composition is placed into a wellbore and subjected to ionizing radiation. The ionizing radiation can cause bonding between polymeric additive constituents and create a polymer matrix within the sealant composition that increases the mechanical strength of the sealant composition. The ionizing radiation also alters the set modifier component, triggering the thickening of the sealant composition.

Abstract: The present invention relates to methods useful for isolating a portion of a wellbore. In one embodiment, a method includes preparing a sealant composition containing a set modifier component. The sealant composition is placed into the wellbore and is subjected to ionizing radiation that alters the set modifier component, triggering the thickening of the sealant composition.

Abstract: The present invention includes methods relating to the setting of fluids or slurries in a wellbore. In one embodiment, a method of isolating a portion a wellbore by preparing a sealant composition comprising a fluid component and a polymeric additive component, placing the sealant composition into a wellbore and subjecting the sealant composition to ionizing radiation. The ionizing radiation can cause bonding between polymeric additive components and create a polymer matrix within the sealant composition that increases the mechanical strength of the sealant composition.

Abstract: The present disclosure is directed to a system and method for sonically activating cement slurries. In some implementations, a method of treating a subterranean formation includes positioning a settable composition including a capsule in a wellbore. The capsule is used to increase a setting rate in response to at least sonic signals. A sonic signal is transmitted to at least a portion of the settable composition to release an activator from the capsule.

Abstract: A fluid loss control method uses a fluid loss control pill in a well in advance of a completion operation. An embodiment of the fluid loss control pill comprises polyester solids that are hydrolysable and can exhibit plastic deformation at formation conditions. An embodiment of the method comprises spotting the fluid loss control pill in the well adjacent to a formation to form a filtercake to inhibit fluid entry from the well into the formation, performing a completion operation comprising contacting the filtercake with overbalanced wellbore fluid, and degrading the filtercake wherein the polyester particles are hydrolyzed to remove formation damage.

Abstract: A system and method for cavitating a producible formation is disclosed to improve hydrocarbon production and to increase a production rate without an concurrent co-production of formation particulate. The method and system include conglomerating the producible formation using a conglomerating composition. Once the producible formation is conglomerated, the conglomerated, producible formation is produced above its critical draw down pressure to form a cavity surrounding the wellborn in the conglomerated, producible formation and placing the cavitated, conglomerated, producible formation on production below a higher maximum sand free rate (MSFR).

Abstract: A wellbore fluid comprising a base fluid and a particulate bridging agent comprised of a sparingly water-soluble material selected from the group consisting of melamine (2,4,5-triamino-1,3,5-triazine), lithium carbonate, lithium phosphate (Li3PO4), and magnesium sulfite.

Abstract: Embodiments of the present invention generally relate to a sealant for forming durable plugs in wells and method for completing or abandoning wells. In one embodiment, a method of plugging a wellbore includes mixing sealant; mixing cement; pumping the cement and sealant into the wellbore. The cement is above the sealant and the sealant cures to become viscoelastic or semisolid.

Abstract: A process for preparing a binder which comprises a heterocondensate of silicon compounds and metal and/or boron compounds. The process comprises mixing a silicon component which comprises (A), at least one hydrolyzable silicon compound having a non-hydrolyzable polymerizable group, with water to form a hydrolysis product, and 15 s to 15 min after mixing (A) with water, the addition of (B), at least one compound of boron or a metal selected from Al, Ga, In, Tl, Ge, Ga, Sn, Pb, Ti, Zr, Hf, Sc, Y and La.

Abstract: The use of silicate as a retarder enhancer at appropriate levels to enhance the retarding effect of retarders at high temperatures encountered downhole while accelerating the set of cement at lower temperatures encountered near to the surface.

Abstract: A cement includes a cement mixture and a permeable, micro-cluster silica material present in an amount from about 10 percent to about 30 percent by weight of the cement mixture. The cement blend may be used in casing a borehole when appropriate fluid loss agents are included in the cement blend. Additionally, a cement additive is added to a cement mixture to provide the cement blend. This cement additive can be formulated in a kit form.

Abstract: Among many things, in some embodiments, improved viscoelastic surfactant gels that comprise non-aqueous tackifying agents, and their associated methods of use, are provided. In one embodiment, the methods comprise: providing a treatment fluid that comprises an aqueous base fluid, a non-aqueous tackifying agent, and a viscoelastic surfactant; and introducing the treatment fluid into a subterranean formation.

Abstract: A cement mix for cementing the well casing within a wellbore which contains a synergistic blend of an alkali metasilicate and/or alkali silicate, aluminum silicate and either silica fume or micro silica quartz along with a Portland cement. The cement mix, when combined with mix water, may render a cementitious slurry having a density less than or equal to 11.5 pounds per gallon (ppg); the amount of mix water in the cementitious slurry being between from about 200 to about 560 percent by weight of cement (BWOC). The compressive strength of such cementitious slurries, when cured, is in excess of 100 psi, more typically in excess of 200 psi, after 72 hours at 130° F.

Abstract: A self-adaptive cement system includes cement, water and at least one additive that reacts or/and expands in contact with oil and gas. Several chemical products have been identified including rubber alkylstyrene, polynorbornene, resins such precrosslinked substituted vinyl acrylate copolymers and diatomaceous earth. These additives have the effect of making the cement self-healing in the event of physical failure or damage such as micro-annuli. The self healing property is produced by the contact with subterranean hydrocarbon fluids, the potential repair mechanism is thus activated if and when needed in case of start of loss of zonal isolation. In another embodiment, the expansion is deliberately induced by pumping a hydrocarbon fluid in the vicinity of the set cement.

Abstract: Compositions and methods of reducing a flow of aqueous liquids through a subterranean formation are provided. The compositions and methods are used for water control. The compositions include a water control additive that is prepared by reacting a soluble sodium silicate and a hydrolysable organosilane compound to produce silanol that reacts and forms a bond with the formation thereby producing a binding polysiloxane.

Abstract: A process may include providing heat from one or more heaters to at least a portion of a subsurface formation. Heat may transfer from one or more heaters to a part of a formation. In some embodiments, heat from the one or more heat sources may pyrolyze at least some hydrocarbons in a part of a subsurface formation. Hydrocarbons and/or other products may be produced from a subsurface formation. Certain embodiments describe apparatus, methods, and/or processes used in treating a subsurface or hydrocarbon containing formation.

Abstract: A method of plugging wells wherein cementitious materials (like Portland cement) are formed into pellets that can be dumped or dropped into a well that is filled with an aqueous solution. The pellets will fall quickly to the bottom of the well or mechanically placed barrier, and over time, the pellets will loose their structure and release dry cementitious material into aqueous well fluid. The cementitious material will wet in the aqueous well fluid and then set to form an impermeable plug in the well.

Abstract: A composition for reducing lost circulation in a well, while drilling the well with a drilling mud, which is composed of a base fluid, a mixture of particles, and a blend of fibers. The composition is used by stopping drilling with the mud, injecting a spacer, injecting the water-based composition, injecting a spacer, and resuming drilling with the oil-based mud.

Abstract: A method of cementing a wellbore in a subterranean formation, comprising formulating a cement composition that may be suitable for long-term zonal isolation of the subterranean formation by evaluating a subterranean formation, preparing a base cement composition, determining the compressive strength of the base cement composition, determining the tensile strength of the base cement composition, and adjusting the ratio of compressive strength to tensile strength as need to within a first optimizing range to form a first optimized cement composition, and placing the optimized cement composition in the wellbore.

Abstract: Equipment for servicing subterranean wells, and in some cases, an apparatus and method for remotely launching cementing plugs during the primary cementation of a subterranean well. The top plug and bottom plug are launched by different mechanisms, thereby preventing premature release of the top plug during a cementing operation.

Abstract: A method of servicing a wellbore in contact with a subterranean formation comprising placing a wellbore servicing fluid comprising a polyuronide polymer within the wellbore, contacting the wellbore servicing fluid with a divalent ion source, and allowing the wellbore servicing fluid to form a gel within the wellbore wherein the divalent ion source is located within the wellbore. A method of servicing a wellbore in contact with a subterranean formation comprising (a) placing a wellbore servicing fluid comprising a polyuronide polymer into the wellbore wherein the wellbore servicing fluid contacts a calcium ion source, (b) shutting the wellbore and allowing the servicing fluid to set into place for a period of time, and (c) repeating steps (a) and (b) until the permeability of a structure within the wellbore is reduced by about 50%.

Abstract: The present invention relates to methods useful for isolating a portion of a wellbore. In one embodiment, a method includes preparing a sealant composition containing a set modifier component. The sealant composition is placed into the wellbore and is subjected to ionizing radiation that alters the set modifier component, triggering the thickening of the sealant composition.

Abstract: A synthetic glass family in the quaternary phase field of CaO—SiO2—Al2O3—MgO (CSAM) with hydraulic and pozzolanic properties for use in differing applications in the gas and oil well cementing area. A method of making a mud-to-cement (MTC) slurry and a method for treating oil and gas wells with the MTC slurry containing a homogenous amorphous synthetic glass made from a mixture of inorganic materials selected from the group consisting of CSAM, wherein the cementing glasses with the mixture of inorganic materials are in a 100% amorphous phase with a degree of crystallization of zero.

Abstract: The present invention includes methods relating to the setting of fluids or slurries in a wellbore. In one embodiment, a method of isolating a portion a wellbore by preparing a sealant composition comprising a fluid component and a polymeric additive component, placing the sealant composition into a wellbore and subjecting the sealant composition to ionizing radiation. The ionizing radiation can cause bonding between polymeric additive components and create a polymer matrix within the sealant composition that increases the mechanical strength of the sealant composition.

Abstract: A transient overbalance condition is created in a wellbore interval such that a pressure of the wellbore interval is greater than a reservoir pressure in surrounding formation. Creating the transient overbalance condition causes a near-wellbore region of the formation to increase in pressure. The pressure in the wellbore interval is reduced at a rate that produces a relative underbalance condition in which the pressure in the wellbore interval is less than the pressure of the near-wellbore region of the formation, but the pressure in the wellbore interval is greater than the reservoir pressure.

Abstract: A cement composition, comprises a mixture of a blend of materials including cement and/or micro cement, calcium carbonate, organic fibres, and inorganic fibres; and water; wherein the composition forms a cement that is at least partially soluble in acid and/or water. A method of treating a well, comprises pumping the composition into the well, allowing the cement to set, and treating the set cement so that it is partially to completely dissolved. In case of partial dissolution the residue in time is degradable. The inorganic fiber can be used in the traditional cementing in all stages of the well construction to defeat partial losses and improve the set properties of the final set cement.

Abstract: A method of limiting or preventing fluid flow through a portion of a subterranean formation comprises the steps of: (a) forming a treatment fluid comprising: (i) a water-swellable, water-insoluble elastomer in the form of discrete particles, wherein the particles of the water-swellable, water-insoluble elastomer have a characteristic of being capable of sticking together to form an agglomeration when exposed to water; and (ii) a carrier fluid for the water-swellable, water-insoluble elastomer; and (b) injecting the treatment fluid through a well into the subterranean formation to deposit the discrete particles of the water-swellable, water-insoluble elastomer in the subterranean formation.

Abstract: The present invention relates to a formulation of a high-performance foamed cement material, comprising: at least one hydraulic binder, microparticles whose grain size ranges between 0.1 and 30 ?m, whose proportion ranges between 15% and 50% by mass in relation to the mass of hydraulic binder, mineral particles whose grain size ranges between 1 and 500 ?m, whose proportion ranges between 10% and 35% by mass in relation to the mass of hydraulic binder, the proportion of particles being lower than the proportion of microparticles, a hydrosoluble polymer thinning agent whose proportion ranges between 0.1% and 8% by mass in relation to the mass of hydraulic binder, water whose proportion is at most 40% by mass in relation to the mass of hydraulic binder, a foaming agent whose proportion ranges between 0.1% and 10% by mass in relation to the mass of hydraulic binder.

Abstract: A method is provided for swelling water-swellable elements located in a portion of a well. The method comprises the steps of: (A) introducing an oil-in-water emulsion into the portion of the well, wherein the oil-in-water emulsion comprises: (i) an aqueous liquid, wherein the aqueous liquid is the external phase of the oil-in-water emulsion; (ii) a hydrocarbon liquid, wherein the hydrocarbon liquid is an internal phase of the oil-in-water emulsion, and wherein the hydrocarbon liquid is adjacent to the external phase of the oil-in-water emulsion; and (iii) a surfactant; and (B) allowing the oil-in-water emulsion to contact the water-swellable element for a sufficient length of time to cause the thickness of the water-swellable element to expand by a desired percentage, wherein the desired percentage is at least 5%.

Abstract: A two part encapsulated cementing system is mixed downhole in a method of remediation of an active well. Using this two part system, one of the components is first placed in the well at the desired remediation depth. Next, the other component is placed in the well above the first placed component. Densities of the components have been selected such that the density of the second placed component is sufficiently higher then the density of the first placed component to facilitate gravity mixing of the two components as the second placed component moves through the first placed component and in the process activation occurs.

Abstract: A spacer for use in an oil well cementing operation comprises an aqueous solution of a visco-elastic surfactant. A method of treating a well in a cementing operation, comprises pumping the spacer into a well ahead of a cement slurry for cementing the well.

Abstract: Disclosed is a method for controlling loss circulation and simultaneously strengthening a weakened formation when drilling for oil. This invention relates to the permeable subterranean formation and natural and induced fractured formations that encounter severe losses and their treatment with a composition composed of long rigid organic fibre with different type of fibres selected from a category of organic or inorganic fibres along with different particle sizes that orientation of fibres and packing of the solids shows a good blockage effect to resist the loss and later the final set material develop required compressive strength to cure those losses and strengthening the structure.

Abstract: A variety of methods and compositions, including, in one embodiment, a method of treating a subterranean formation comprising introducing a treatment fluid into a well bore, wherein the treatment fluid comprises a particulate elastomer having a specific gravity of at least about 1.6. Another method of treating a subterranean formation comprises introducing a treatment fluid into a well bore, wherein the treatment fluid comprises a particulate elastomer having a specific gravity of at least about 1.05, wherein the particulate elastomer comprises a halogenated thermoplastic.

Abstract: Disclosed are spacer fluids comprising cement kiln dust (“CKD”) and methods of use in subterranean formations.

Abstract: The invention provides a system for adapting an HVAC system in an existing building for utilizing geothermal energy, the system comprising an incoming flux of geothermal energy; a plurality of heat exchange surfaces adapted to receive the incoming flux of geothermal energy; and an interface between the HVAC system and the heat exchange surfaces, said interface adapted to transfer the geothermal energy to the system.