Synthetic Resin Patents (Class 174/110SR)
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Patent number: 4780576Abstract: An insulated electrical cable is disclosed, comprising an electrical conductor coated with an insulating layer comprising an ethylene/.alpha.-olefin copolymer having a density of from 0.89 to 0.91 and an ethylene/vinyl acetate copolymer.Type: GrantFiled: March 6, 1987Date of Patent: October 25, 1988Assignee: Sumitomo Electric Industries, Ltd.Inventor: Mineya Kuno
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Patent number: 4769287Abstract: An electric cable having at least one conductor and at least one covering therefor obtained from the polymerization of a silanic monomer of a compound comprising a non-cross-linked base-polymer and a polymerizable silanic monomer present prior to polymerization in a quantity not less than 5 parts by weight with respect to 100 parts by weight of the base-polymer. Thepolymerization of the silanic monomer units forms a polymeric mesh which is closely interconnected and thoroughly compenetrated into the non-cross-linked base-polymer. In one embodiment the polymeric mesh may be grafted onto the base-polymer through the addition of an organic peroxide. Thus, there is provided an electric cable for use as building wires wherein the conductor covering is not cross-linked but is heat resistant to temperatures above the deformation temperature of the base-polymer.Type: GrantFiled: December 18, 1986Date of Patent: September 6, 1988Assignee: Societa' Cavi Pirelli S.p.A.Inventors: Antonio Zaopo, Flavio Casiraghi, Alessandro Secco
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Patent number: 4748209Abstract: The present invention provides a method for improving impulse destructive strength of an electrical insulating material which is characterized by employing, as the electrical insulating material, a random copolymer of a styrene series monomer and ethylene or a combination of ethylene and another ethylenic unsaturated monomer, or a composition in which the copolymer is blended with an ethylene series polymer, the copolymer being prepared by introducing, into a reaction system, the styrene series monomer selected from the group of styrene and single-ring substituted styrenes, ethylene or the combination of ethylene and the ethylenic unsaturated monomer and a polymerization initiator, the latter being introduced thereinto separately from at least the styrene series monomer, and subjecting these monomers to a high-pressure radical copolymerization under a polymerization pressure of 500 to 4,000 kg/cm.sup.2 at a polymerization temperature of 50.degree. to 400.degree. C.Type: GrantFiled: June 8, 1987Date of Patent: May 31, 1988Assignee: Nippon Petrochemicals Co., Ltd.Inventors: Yuichi Orikasa, Shinji Kojima, Takashi Inoue, Kaoru Yamamoto, Atsushi Sato, Shigenobu Kawakami
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Patent number: 4743644Abstract: A water stabilizer polymeric composition incorporating a hydrated alumina filler, which is characterized by the presence of an effective amount of an antimony V compound. The compositions have a reduced tendency to absorb water and specific compositions find applicaiton as electrical insulation and in the production of dimensionally recoverable article.Type: GrantFiled: March 23, 1987Date of Patent: May 10, 1988Assignee: Raychem LimitedInventors: Richard S. Skipper, Richard J. Penneck
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Patent number: 4734545Abstract: An insulated conductor for a wire harness comprising a conductor and an insulation with which the conductor is covered, the insulation being formed of thermoplastic polyurethane having shore D hardness of more than 50, thickness of less than 0.2 mm, and an adherence of the insulation to the conductor less than 2 Kg/10 mm, being measured as the required force to pull 10 mm of the insulation off the conductor.Type: GrantFiled: November 26, 1986Date of Patent: March 29, 1988Assignee: The Furukawa Electric Co., Ltd.Inventors: Isao Susuki, Tomomi Hizikata
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Patent number: 4726993Abstract: A low-voltage cable with insulation having good fire self-extinguishing and life cycle properties and with improved heat resisting and low toxic gas generation properties. The cable is formed by extruding a mixture of a polymer which is substantially non-cross-linkable by irradiation, a monomer cross-linkable by irradiation and optionally, a fluidizing polymeric material which is cross-linkable by irradiation around a conductor and subjecting the so-formed cable to irradiation to cross-link the materials cross-linkable by irradiation.Type: GrantFiled: December 2, 1985Date of Patent: February 23, 1988Assignee: Societa' Cavi Pirelli S.p.A.Inventor: Antonio Zaopo
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Patent number: 4724248Abstract: Esters and urethanes of certain polydialkylsiloxanepolyoxyalkylene block and graft copolymers which impart high voltage stabilization to dielectric olefin polymers, the stabilized olefin polymer insulating materials resulting therefrom and electric wire or cable insulated therewith.Type: GrantFiled: July 2, 1986Date of Patent: February 9, 1988Assignee: Ciba-Geigy CorporationInventors: Martin Dexter, David H. Steinberg
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Patent number: 4716079Abstract: In an excellent windability magnet wire wherein an insulating layer of a synthetic resin film is formed on a conductor directly or with another insulation in between and a lubricant layer is formed on the insulating layer, the lubricant layer is made of an intimate mixture of natural wax as a major constituent and thermosetting and fluorocarbon resins compounded therewith.Type: GrantFiled: February 20, 1987Date of Patent: December 29, 1987Assignee: The Furukawa Electric Co. Ltd.Inventors: Fumikazu Sano, Masakazu Mezaki
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Patent number: 4701016Abstract: A grease composition comprising oil, colloidal particle filler, and, optionally, a bleed inhibitor is disclosed. The grease typically has a critical yield stress below 140 Pa at 20.degree. C., preferably below 70 or 35 Pa. The grease can advantageously be used as a cable filling material, especially for optical fiber cable. In the latter case it can result in cable having substantially no cabling loss. Preferred compositions comprise 77 to 95% b.w. of ASTM type 103, 104A, or 104B paraffinic or naphthenic oil, or polybutene oil; 2 to 15% b.w. of hydrophobic or hydrophilic fused silica; and optionally, up to 15% b.w. of styrene-rubber or styrene-rubber-styrene block copolymer, or semiliquid rubber.Type: GrantFiled: January 31, 1985Date of Patent: October 20, 1987Assignee: American Telephone and Telegraph Company, AT&T Bell LaboratoriesInventors: Charles H. Gartside, III, Alvin C. Levy, Bob J. Overton, Carl R. Taylor
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Patent number: 4693936Abstract: An improved thermally stable, lubricious magnet wire enamel is disclosed which is particularly suitable for use as an outermost insulating, lubricating layer on a magnet wire substrate. The enamel comprises the reaction product of a tri-basic acid anhydride, a diisocyanate and a polyfunctional organosiloxane. The coating has a coefficient of friction, after application to magnet wire, of less than 0.10. It is also substantially all polyfunctional organosiloxane reacted, i.e. substantially no polyfunctional organosiloxane is capable of being extracted from the cured coating with organic solvents.Type: GrantFiled: June 9, 1986Date of Patent: September 15, 1987Assignee: Essex Group, Inc.Inventors: Charles W. McGregor, Melody L. Sutto
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Patent number: 4628003Abstract: For use as a heat sealable, high temperature, insulative wrapping, a laminar structure of a polyimide inner layer and two fluoropolymer outer layers wherein the outer layers are pigmented for a combination of color, increased heat aged bond retention, and reduced heat seal energy requirements.Type: GrantFiled: March 20, 1985Date of Patent: December 9, 1986Inventor: Morton Katz
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Patent number: 4623755Abstract: The invention relates to an electrical insulation composition of a polyolefin, which can be used for medium and high voltage from about 10 kV and which resists effectively and permanently the formation of so-called water trees. The insulative polyolefin contains an inorganic oxide additive, in homogeneous distribution therewith, at a concentration of 0.05 to 10% by weight, relative to the total weight of the composition. The additive is absorption-active for heavy metal ions and/or binds heavy metal ions in an ion exchange, with a particle size of up to 50 um or an agglomerate size of up to 100 um. It can be silica, alumina, hydrated alumina or an aluminum silicate. The electrical insulation according to the invention is particularly well-suited for use in cables and wires.Type: GrantFiled: September 13, 1985Date of Patent: November 18, 1986Assignee: Siemens AktiengesellschaftInventors: Hans-Joachim Henkel, Norbert Muller
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Patent number: 4611021Abstract: There is provided a curable ether modified polyester resin composition comprising the reaction product of (a) at least one dicarboxylic acid, (b) at least one aliphatic polyol, and (c) at least one aromatic bis (ether dianhydride) or the corresponding tetracarboxylic acid.Type: GrantFiled: October 15, 1985Date of Patent: September 9, 1986Assignee: General Electric CompanyInventor: Otto S. Zamek
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Patent number: 4610505Abstract: A sheath for light waveguides. The sheath consists of a tube loosely surrounding one or more light waveguides. In a neutral bending plane, longitudinal elements are provided for absorbing tensile and compressive forces. The coefficient of expansion of the longitudinal elements corresponds to that of the light waveguides. The longitudinal elements are form-coupled and force-coupled to the tube.Type: GrantFiled: May 6, 1985Date of Patent: September 9, 1986Assignee: U.S. Philips CorporationInventors: Johann A. Becker, Helmut Wirth, Werner Zell
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Patent number: 4609702Abstract: Ether modified polyesterimide resins are prepared by reacting under esterimide forming conditions substantially free of inert solvents a mixture consisting essentially of:(i) a diamine,(ii) a carboxylic acid anhydride containing at least one additional carboxylic group,(iii) an aromatic bis (ether anhydride) or the corresponding acid thereof,(iv) terephthalic acid and/or isophthalic acid,(v) a polyhydric alcohol having at least two hydroxyl groups, and(vi) optionally, a monoether of diethylene glycol or a monoether of triethylene glycol.Type: GrantFiled: October 22, 1985Date of Patent: September 2, 1986Assignee: General Electric CompanyInventor: Otto S. Zamek
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Patent number: 4581290Abstract: The invention relates to electrical insulation material of a polyolefin composition with a phosphate additive which prevents the formation of so-called water trees. The phosphate additive may be a water-soluble alkali or earth-alkali phosphate and/or a hydrolysable phosphoric acid ester (RO).sub.3 PO, wherein at least one of the substituents R is an aliphatic radical and the remaining substituents may be hydrogen or an aliphatic radical. The electrical insulation according to the invention is suited particularly for use in cables and wires.Type: GrantFiled: December 12, 1984Date of Patent: April 8, 1986Assignee: Siemens AktiengesellschaftInventors: Hans-Joachim Henkel, Norbert Muller
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Patent number: 4577664Abstract: A conduit tube of an electrode device for electrically heating underground hydrocarbon resources, which comprises: a metal conduit tube and an electrically insulative covering adhered on and around the outer peripheral surface of said metal conduit tube, said electrically insulative covering being formed by adhering polyether/ether/ketone resin in powder form having particle size of a range of from 10 to 100 .mu.m on and around said metal conduit tube which has been preheated to a temperature range of from 350.degree. C. to 450.degree. C. by the electrostatic coating method, and fusion-bonding the electrically insulative covering material thereon at said temperature range of the preheating.Type: GrantFiled: April 17, 1984Date of Patent: March 25, 1986Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Ichiro Takahashi, Goro Okamoto, Kazuo Okahashi
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Patent number: 4578312Abstract: This invention relates to a composition comprising (1) a phenoxy resin and (2) at least two compositions selected from (a) phenolic resins, (b) melamine resins and (c) polyisocyanates; to the cured products thereof; and to an electrical conductor coated with said cured products.Type: GrantFiled: March 27, 1985Date of Patent: March 25, 1986Assignees: The P. D. George Co., Industrie Vernici Italiane S.p.A.Inventors: Luciano Biorcio, Carlo Mensi
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Patent number: 4576857Abstract: Melt-fusible polyimides based on pyromellitic dianhydride and at least one defined aromatic diamine are useful in making low-void composites and thermoplastic tapes, which can be fabricated into articles such as, for example, aircraft and autobody panels, printed circuit boards, etc. Some of these polyimides are melt-processible and can be fabricated by conventional procedures such as extrusion and injection molding.Type: GrantFiled: September 21, 1983Date of Patent: March 18, 1986Assignee: E. I. Du Pont de Nemours and CompanyInventors: Thomas P. Gannett, Hugh H. Gibbs
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Patent number: 4575184Abstract: An optical composite cable having an outer sheath comprising a radiation cured copolymer of ethylene and vinyl acetate containing 50-85% by weight of vinyl acetate having intimately admixed therewith a flame retarding and smoke suppressing amount of a finely divided filler mixture consisting essentially of a first filler selected from hydroxides and carbonates of di- and tri-valent metals and a second filler which is zinc borate.Type: GrantFiled: December 22, 1983Date of Patent: March 11, 1986Assignee: Sumitomo Electric Industries, Ltd.Inventors: Keiji Ueno, Akinori Mori
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Patent number: 4574111Abstract: The invention relates to electric insulation of polyolefin suitable for medium and high voltage from about 10 kV which resists the formation of so-called water trees. For this purpose, the insulation contains as an additive at least one alcoholate of magnesium, calcium or aluminum. The electric insulation according to the invention is particularly suitable for use in cables and wires.Type: GrantFiled: June 28, 1985Date of Patent: March 4, 1986Assignee: Siemens AktiengesellschaftInventors: Hans-Joachim Henkel, Norbert Muller
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Patent number: 4572853Abstract: There is presented a highly reliable resin encapsulation type semiconductor device excellent in humidity resistance as well as high temperature electrical characteristics. The specific feature consists in the epoxy resin composition employed for encapsulation. This composition comprises an epoxy resin, a novolac resin as curing agent and an organic tertiary phosphine compound as curing accelerator. The resin encapsulation type semiconductor device is markedly small in leak current under hot and humid conditions and has a prolonged life due to difficult deterioration through corrosion of electrodes and aluminum wiring, as compared with those of prior art.Type: GrantFiled: February 21, 1984Date of Patent: February 25, 1986Assignee: Tokyo Shibaura Denki Kabushiki KaishaInventors: Hirotoshi Ikeya, Shuichi Suzuki, Takayuki Oguni, Kazutaka Matsumoto, Akiko Hatanaka
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Patent number: 4552818Abstract: An encapsulant for an electronic device comprises a silicone resin having a highly colored porphyrin compound doped therein.Type: GrantFiled: May 10, 1984Date of Patent: November 12, 1985Assignee: AT&T Technologies, Inc.Inventor: Ching-Ping Wong
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Patent number: 4546041Abstract: A corona-resistant wire enamel composition is described comprising a polyetherimide resin and from about 1% to about 35% by weight of dispersed alumina particles of a finite size less than about 0.1 micron, the alumina particles being dispersed therein by high shear mixing. A method of providing corona resistant insulations for an electrical conductor employing the above composition and an electrical conductor insulated with a coating of the wire enamel composition are also disclosed.Type: GrantFiled: July 25, 1983Date of Patent: October 8, 1985Assignee: General Electric CompanyInventors: John J. Keane, Denis R. Pauze
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Patent number: 4543381Abstract: An unfilled polymeric composition having improved electrical treeing and water treeing properties comprising a polymeric component and effective amounts of a silane and a fatty acid. The compositions are particularly useful as insulation for high voltage transmission and distribution cables.Type: GrantFiled: June 24, 1983Date of Patent: September 24, 1985Assignee: National Distillers and Chemical CorporationInventors: Anthony Barlow, Melvin F. Marginger
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Patent number: 4538881Abstract: There is disclosed an undersea communications cable containing optical fibers. The cable is fabricated so that fiber optical loss characteristics vary only slightly with changes in tensile strain in the cable.Type: GrantFiled: February 24, 1983Date of Patent: September 3, 1985Assignee: AT&T Bell LaboratoriesInventors: Stephen N. Anctil, Robert F. Gleason, Don A. Hadfield, John S. B. Logan, Jr., Alfred G. Richardson
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Patent number: 4536530Abstract: Organophosphorus compounds having the general formula ##STR1## useful as water tree resistant additives for polymeric compositions.Type: GrantFiled: February 1, 1984Date of Patent: August 20, 1985Assignee: National Distillers and Chemical CorporationInventors: Anthony Barlow, Melvin F. Maringer
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Patent number: 4530975Abstract: A polyamide-imide resin composition comprising (A) a polyamide-imide resin modified with a polyisocyanate containing one or more isocyanurate rings and a lactam and (B) at least one member selected from the group consisting of (i) an alkoxy modified amino resin, (ii) a polyisocyanate containing one or more isocyanurate rings, (iii) a phenol-formaldehyde resin, (iv) an epoxy resin, (v) a polyester resin having one or more hydroxyl groups obtained by using terephthalic acid and/or isophthalic acid as an acid component, and (vi) a metal salt of Sn, Mn, Co or Zn, can give fast curing properties to the resin composition without lowering heat resistance, flexibility, abrasion resistance and also giving good surface appearance to the coating.Type: GrantFiled: September 30, 1982Date of Patent: July 23, 1985Assignee: Hitachi Chemical Company, Ltd.Inventors: Yoshiyuki Mukoyama, Touichi Sakata, Yuichi Osada
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Patent number: 4529652Abstract: The invention relates to a polymer composition based on a polyphenylene ether which is suitable for wire insulation extrusion. The polymer composition comprises a polyphenylene ether, optionally a polystyrene, a hydrogenated block copolymer, an aromatic phosphate compound, a mineral oil and optionally typical additives. The invention also relates to an electrically conductive wire comprising an insulation built up from the above-mentioned polymer composition and provided around the electrically conductive wire by wire insulation extrusion.Type: GrantFiled: March 15, 1984Date of Patent: July 16, 1985Assignee: General Electric CompanyInventors: Jan Bussink, Johannes W. J. de Munck
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Patent number: 4514535Abstract: Organophosphorous phosphites having the formula ##STR1## useful as water tree and electrical tree retardant additives for polymeric compositions.Type: GrantFiled: February 1, 1984Date of Patent: April 30, 1985Assignee: National Distillers and Chemical CorporationInventors: Harry Braus, Anthony Barlow, Melvin F. Maringer
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Patent number: 4514539Abstract: The present invention comprises a stain resistant flame retardant insulating composition that is stain resistant under conditions of natural aging, heat aging, or exposure to gases such as hydrogen sulfide or methane. The inventive insulating composition remains substantially white in color under elevated heating and combustion temperature conditions. The stain resistant electrical insulating composition of the present invention is also flame retardant and has a polymer system comprising ethylene-vinyl acetate copolymer and polyethylene. The composition also utilizes a vinyl silane component as a coupling agent, peroxide cross-linking agents, fillers, and a three part stabilizing system.Type: GrantFiled: May 5, 1983Date of Patent: April 30, 1985Assignee: Reichhold Chemicals, Inc.Inventors: George A. Hattrich, Stephen J. Byron
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Patent number: 4511624Abstract: An enameled wire which can be safely used for electric machinery such as an electric motor and transformer without causing smoking or fire accidents comprising a conductive wire coated with a thermoplastic straight chain polyurethane having therein the following repeating unit ##STR1## wherein R and R' each represents a divalent group having at least 2 carbon atoms.Type: GrantFiled: July 18, 1983Date of Patent: April 16, 1985Assignee: Sumitomo Electric Industries, Ltd.Inventors: Munetaka Kawaguchi, Hirohiko Nakabayashi, Masayoshi Miyake
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Patent number: 4503124Abstract: A corona-resistant wire enamel composition is described comprising a polyimide, polyamide, polyester, polyamideimide, polyesterimide, or polyetherimide resin and from about 1% to about 35% by weight of dispersed alumina particles of a finite size less than about 0.1 micron, the alumina particles being dispersed therein by high shear mixing. A method of providing corona resistant one and two-stage insulations for an electrical conductor employing the above compositions and an electrical conductor insulated with a one or two-stage coating of the wire enamel compositions are also disclosed.Type: GrantFiled: March 30, 1983Date of Patent: March 5, 1985Assignee: General Electric CompanyInventors: John J. Keane, Denis R. Pauze
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Patent number: 4497922Abstract: A composition of materials comprising a polyamide acid-silicone intermediate obtained by reacting (a) a diaminoamide compound of the formula: ##STR1## wherein Ar and Y are as defined in the specification, (b) a diaminosiloxane, (c) a diamine, and (d) an aromatic tetracarboxylic acid dianhydride can form a protective film used in a semiconductor device excellent in adhesive properties, heat resistance and preventing soft errors due to .alpha.-rays.Type: GrantFiled: June 6, 1983Date of Patent: February 5, 1985Assignee: Hitachi Chemical Company, Ltd.Inventors: Hidetaka Sato, Shunichiro Uchimura, Isao Uchigasaki, Daisuke Makino
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Patent number: 4485127Abstract: Improved enamels and insulated electrical articles produced therefrom are described. The enamels are composed of solutions of curable resin which have been modified to contain nylon polymer. This polymer facilitates application of the enamel to a metallic conductor so as to produce an especially smooth and desirable insulation coating.Type: GrantFiled: May 21, 1982Date of Patent: November 27, 1984Assignee: General Electric CompanyInventor: Denis R. Pauze
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Patent number: 4471021Abstract: Improved polyetherimide compositions and processes for their production are described. Various polyetherimide derivatives including water-soluble and tri-functional isocyanate cross-linked resins are described. They permit production of water-based enamels and coatable particulates which may be employed in, for example, formulation of insulated electrical conductors.Type: GrantFiled: July 1, 1982Date of Patent: September 11, 1984Assignee: General Electric CompanyInventors: Denis R. Pauz/e/, Raymond B. Hughes
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Patent number: 4454278Abstract: A polyester, a polyester/polyamide or a polyester/polyamide/polyimide polymers are prepared from (a) a diaryl terephthalate or diaryl isophthalate, and (b) an aromatic polyol or of (a) and a mixture of (b), and an aromatic diamine, or of (a), (b), (c), and (d) a triaryl mellitate, or a copolycarbonate of any of the foregoing including units derived from (e) a diaryl carbonate. The resulting polyester, polyamide, polyester/polyamide or polyester/polyamide/polyimide polymers are adapted for use as an insulating coating on an electrical conductor.Type: GrantFiled: June 24, 1981Date of Patent: June 12, 1984Assignee: General Electric CompanyInventors: Daniel W. Fox, John J. Keane
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Patent number: 4452937Abstract: The disclosure of this application is directed to a composition, devoid of added mineral filler, comprising an ethylene polymer and an organo titanium chelate as a water treeing inhibitor. The compositions can be extruded about electrical conductors providing insulation thereon which is resistant to deterioration in the presence of moisture and/or an electrical field.Type: GrantFiled: November 5, 1982Date of Patent: June 5, 1984Assignee: Union Carbide CorporationInventor: Michael J. Keogh
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Patent number: 4448844Abstract: A heat resistant resin produced by reacting (A) a polyamideimide resin with (B) an alcohol component and (C) an acid component with heating is soluble in a cresol type solvent and gives coatings excellent in heat resistance, thermal shock resistance, wear resistance, resistance to hydrolysis, etc., suitable for enamelled wire.Type: GrantFiled: July 28, 1983Date of Patent: May 15, 1984Assignee: Hitachi Chemical Co., Ltd.Inventors: Yuichi Osada, Shozo Kasai, Yasunori Okada, Isao Uchigasaki, Toyoji Oshima, Yoshiyuki Mukoyama, Hiroshi Nishizawa
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Patent number: 4447472Abstract: A method of improving the physical and electrical properties of polymer insulation coated electrical conductors is described. A non-ionic surfactant added to an organic solvent solution of insulation polymer followed by coating the solution on the wire, drying and curing, has been found to produce a coated magnet wire with improved concentricity and smoothness, therefore resulting in improvement in other wire properties as well.Type: GrantFiled: September 23, 1982Date of Patent: May 8, 1984Assignee: Essex Group, Inc.Inventors: Michael G. Minnick, James J. Connell, Charles W. McGregor
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Patent number: 4433131Abstract: Disclosed is a coating solution including an aromatic bis(ether anhydride) component, an organic diamine component, an organic triamine component, and a solvent system, and optionally water which may be coated on a substrate and polymerized to form high quality polyetherimide coatings.Type: GrantFiled: July 30, 1981Date of Patent: February 21, 1984Assignee: General Electric CompanyInventors: Donald A. Bolon, Thomas B. Gorczyca
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Patent number: 4430470Abstract: Flame retardant additive comprising alumina trihydrate and a methyl hydrogen polysiloxane which when added to ethylene polymers provide compositions which have improved flame retardant properties, have reduced gas evolution, do not drip or give off noxious gases on burning and are particularly useful as jacketing material about wire and cables.Type: GrantFiled: June 30, 1982Date of Patent: February 7, 1984Assignee: Nippon Unicar Company Ltd.Inventors: Seiho Taniguchi, Yuichiro Sakuma, Tadashi Yoshii
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Patent number: 4430385Abstract: An elongated metallic conductor is insulated with an inner layer of a plasticized polyvinyl chloride composition and an outer layer of a plasticized, irradiation cross-linked polyvinyl chloride composition. The outer layer has a low coefficient of friction to facilitate pulling in central office racks, has mechanical properties which are required for installation and use and, in a preferred embodiment, has a thickness which is substantially less than that of the inner layer. The layers are extruded in the same extruder crosshead that seemingly causes the outer layer to bond to the inner layer to facilitate stripping of the composite insulation from the conductor.Type: GrantFiled: February 18, 1982Date of Patent: February 7, 1984Assignee: Western Electric Company, Inc.Inventors: Harry M. Dillow, Anthony E. Sansone, Raymond K. Swartz
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Patent number: 4418170Abstract: A method for stabilizing organic polymers against copper-catalyzed oxidative decomposition by means of N,N-bis-salicyloyl hydrazine as a metal deactivator is described wherein dust development of the metal deactivator is precluded with certainty and negative property changes of the stabilized organic polymers are avoided. For this purpose, it is provided that a paste which contains finely-crystalline N,N'-bis-salicyloyl hydrazine in fine distribution in a liquid to wax-like aliphatic hydrocarbon of low volatility is worked into the polymer. The method is particularly well suited for stabilizing polyolefins for cable and wire insulation.Type: GrantFiled: July 19, 1982Date of Patent: November 29, 1983Assignee: Siemens AktiengesellschaftInventors: Wolfgang von Gentzkow, Manfred Schmiedel
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Patent number: 4407992Abstract: The disclosure of this application is directed to flame retardant compositions comprising an alkylene-alkyl acrylate copolymer, a halogenated flame retardant additive, an oxide, hydroxide, carbonate or sulfate of calcium or magnesium and antimony oxide as a second flame retardant additive. The compositions, as described, can be extruded about electrical conductors to provide insulation thereon and also extruded as jacketing about telephone wires and cables.Type: GrantFiled: August 30, 1982Date of Patent: October 4, 1983Assignee: Union Carbide CorporationInventor: Michael J. Keogh
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Patent number: 4405687Abstract: A polyborosiloxane composition to be used for the formation of an insulating layer on an electric conductor comprises (A) a polyborosiloxane produced by the reaction of boric acid, a boric acid derivative, or a halogenated boron with a silane compound and a silicone oil, (B) a silicone resin or a synthetic resin having a nitrogen-containing heterocyclic ring in the molecule, (C) an inorganic filler, and (D) a common solvent for (A) and (B). An insulated electric wire excellent in thermal resistance is obtained by applying the composition to an electric conductor and baking the applied layer of the composition.Type: GrantFiled: April 9, 1982Date of Patent: September 20, 1983Assignee: Showa Electric Wire & Cable Co., Ltd.Inventors: Minoru Morita, Etsuo Hosokawa, Kohzoh Arahara
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Patent number: 4404331Abstract: Improved enamels and insulated electrical articles produced therefrom are described. The enamels are composed of solutions of curable resin which have been modified to contain nylon polymer. This polymer facilitates application of the enamel to a metallic conductor so as to produce an especially smooth and desirable insulation coating.Type: GrantFiled: May 21, 1982Date of Patent: September 13, 1983Assignee: General Electric CompanyInventor: Denis R. Pauze
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Patent number: 4399064Abstract: Tracking is reduced in insulators comprising one or more polymers and an anti-tracking filler system comprising (a) a hydrate of alumina having a specific surface area of at least 2 m.sup.2 /g measured by the BET method, and (b) a compound selected from the group consisting of oxides, mixed oxides and mixtures of oxides wherein said compound contains at least one element selected from the group consisting of transition series elements, lanthanide series elements and nontransuranic actinide series elements.Type: GrantFiled: January 3, 1980Date of Patent: August 16, 1983Assignee: Raychem CorporationInventor: Richard J. Penneck
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Patent number: 4394471Abstract: The disclosure of this application is directed to compositions having improved flame retardant properties containing an alkylene-alkyl acrylate copolymer, a halogenated flame retardant additive and an oxide, carbonate, hydroxide or sulfate of magnesium or calcium in an amount more than 20 and up to about 30 percent by weight. The compositions disclosed are useful as jacketing material and as insulation about wire and cable.Type: GrantFiled: February 11, 1981Date of Patent: July 19, 1983Assignee: Union Carbide CorporationInventor: Michael J. Keogh
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Patent number: 4376180Abstract: Compositions, devoid of fillers, comprising an ethylene polymer and an N-phenyl substituted amino silane, which can be extruded about electrical conductors to provide insulation thereon which is resistant to the formation of water trees.Type: GrantFiled: September 30, 1981Date of Patent: March 8, 1983Assignee: Union Carbide CorporationInventors: Robert J. Turbett, Arnold C. Ashcraft, Herbert E. Petty