Abstract: Methods for using rapid setting plugging compositions comprising oil, clay, magnesium chloride, and magnesium oxide powder to seal permeable zones in subterranean formations are provided. The permeable zones may be sealed by passing the plugging composition and water to the subterranean formation. While being exposed to downhole temperatures in a range of from about 0° F. to about 500° F., the plugging composition quickly thickens to form a sealing mass that is substantially impermeable to fluid in less than about 1 minute after contacting the water. It then usually develops an effective amount of compressive strength to prevent it from being washed away within a period ranging from about 5 minutes to about 2 hours at temperatures ranging from about 0° F. to about 500° F.

Abstract: A solid body contains a surfactant and crushed walnut hulls. The solid body is shaped to predetermined dimensions that permit passage through the central interior opening of drill pipe. The solid body dissolves in drilling mud for delivery of a pill to the annulus through the drill bit nozzles. The pill is an effective treatment against bit balling.

Abstract: A sealant composition and methods for using the same are disclosed. In an embodiment, a method of servicing a wellbore in contact with a subterranean formation is disclosed. The method comprises placing a sealing agent and a nonaqueous carrier fluid in the wellbore. The method further comprises placing a nonaqueous activating fluid in the wellbore. In addition, the method comprises contacting the sealing agent with the nonaqueous activating fluid to form a sealant composition.

Abstract: The present invention relates to methods and compositions for use in subterranean operations. More particularly, the present invention relates to additives comprising one or more silicates used to treat tar resident in a well bore, and methods of use. In one embodiment, the present invention provides a method of treating tar resident in a well bore comprising providing a tar-treating additive comprising one or more silicates introducing the tar-treating additive into the well bore; and allowing the tar-treating additive to react with the tar resident in the well bore so as to at least partially reduce the adhesiveness of the tar.

Abstract: A method of increasing shale formation stability with a water based drilling fluid, the method including: delivering to the shale formation a drilling fluid formulated to include an aqueous fluid; a first reactant which is a soluble monomer, oligomer, or polymer with exposed ketone, aldehyde, or aldol groups or with groups which can be shifted to ketone or aldehyde functionality; and, a second reactant which is a primary amine, diamine, or polyamine which by condensation reaction forms a semi-soluble or precipitated filming product with the first reactant.

Abstract: An assembly and methods for constructing a MONOWELL includes a monodiameter casing disposed in a monodiameter wellbore having diametric efficiency with a monobore production delivery system disposed within the monodiameter casing. An assembly for constructing a monodiameter wellbore includes a bottomhole assembly having a overgauge hole drilling member, a directional steering assembly, a measurement while drilling tool, and a logging while drilling tool; a work string attached to the bottomhole assembly and extending to the surface; drilling fluids flowing through the work string and bottomhole assembly; chemical casing casing the borehole; expandable casing disposed in the wellbore; and a sealing composition disposed between the expandable casing and the wellbore.

Abstract: Settable drilling fluids comprising an aqueous-based drilling fluid and cement kiln dust. Methods of cementing in a subterranean formation comprising: providing a settable drilling fluid comprising an aqueous-based drilling fluid and cement kiln dust, introducing the settable drilling fluid into a subterranean formation, and allowing the settable drilling fluid to set in the subterranean formation. Methods of converting an aqueous-based drilling fluid to a settable drilling fluid comprising: providing the aqueous-based drilling fluid, and adding cement kiln dust to the aqueous-based drilling fluid to form the settable drilling fluid. Methods of drilling a well bore and cementing a well bore comprising: drilling a well bore, circulating an aqueous-based drilling fluid in the well bore during the step of drilling the well bore, adding cement kiln dust to the aqueous-based drilling fluid to form a settable drilling fluid, and allowing the settable drilling fluid to set in the well bore.

Abstract: A method of controlling and delaying the inversion of a drilling fluid and the wettability of a filtercake by using a delayed phase changing agent. The filtercake is preferably formed while drilling a subterranean formation using a drilling fluid includes: an oleaginous fluid; a non-oleaginous fluid; an amine surfactant having the structure: wherein R is a C12–C22 aliphatic hydrocarbon; R? is an independently selectable from hydrogen or C1 to C3 alkyl; A is NH or O, and 1?x+y?3. In the method, the filter cake is exposed to a delayed phase changing agent selected from the group consisting of aliphatic amine acids, salts of aliphatic amine acids and combinations thereof. In one preferred illustrative embodiment, the delayed phase changing agent is delivered in the form of a pill, the pill including a carrier fluid, a viscosifier and the delayed phase changing agent.

Abstract: Methods and compositions for wellbore treating fluids, especially settable spotting fluids, that include zeolite and at least one carrier fluid.

Abstract: Methods and compositions for wellbore treating fluids, especially drilling fluids, that comprise zeolite and a carrier fluid.

Abstract: Methods and compositions for wellbore treating fluids, especially remedial compositions such as pills, that include zeolite and at least one carrier fluid.

Abstract: Single phase microemulsions improve the removal of filter cakes formed during drilling with invert emulsions. The single phase microemulsion removes oil and solids from the deposited filter cake. Optionally, an acid capable of solubilizing the filter cake bridging particles may also be used with the microemulsion. In one non-limiting embodiment the acid may be a polyamino carboxylic acid. Skin damage removal from internal and external filter cake deposition can be reduced.

Abstract: A method of increasing shale formation stability with a water based drilling fluid, the method including: delivering to the shale formation a drilling fluid formulated to include an aqueous fluid; a first reactant which is a soluble monomer, oligomer, or polymer with exposed ketone, aldehyde, or aldol groups or with groups which can be shifted to ketone or aldehyde functionality; and, a second reactant which is a primary amine, diamine, or polyamine which by condensation reaction forms a semi-soluble or precipitated filming product with the first reactant.

Abstract: The process for environmental pacification of drill cuttings which contain drilling fluid residue is characterized by mixing said cuttings with dehydrated limestone coke ash in the presence of water. Upon mixing the drilling fluid residue becomes entrapped into a non-leaching solid. Following treatment of drill cuttings with dehydrated limestone coke ash the resulting product has particular use as a road or work area base in connection with a topping which includes calcium sulfate hemihydrates.

Abstract: A well drilling method comprises removing the drilling cuttings using an aqueous drilling fluid such as a foam including a foaming agent which includes at least one mono-(aliphatic hydrocarbyl) phosphate ester. More specifically, the drilling fluid takes the form of a potassium and/or alkanolamine and/or alkylalkanolamine salt, the foam also comprising a foam stabiliser.

Abstract: Zeolite compositions having enhanced compressive strength and methods therefor are provided. In particular, methods and compositions for wellbore treating fluids, especially settable spotting fluids having enhanced compressive strength are provided.

Abstract: Methods and compositions relating to fluid loss control operations are provided. Examples of compositions may comprise ceramic particulate bridging agents and improved fluid loss control additives, and methods of using those compositions to provide fluid loss control. An embodiment of a method of providing fluid loss control from a first location to a second location may comprise the steps of: providing a treatment fluid comprising ceramic particulate bridging agents, a modified starch composition, and a base fluid; introducing the treatment fluid to the first location; and allowing the treatment fluid to form a filter cake to prevent fluid loss from the first location to the second location.

Abstract: A method and materials for stabilizing a wellbore against excess fluid pressure is described. It comprises forming or placing a flexible and essentially impermeable lining on or in the wellbore wall. The flexibility of the lining ensures that it remains in compression as the pressure in the wellbore is increased above the fluid pressure in the surrounding rock and it therefore does not need high tensile strength. The lining may be a preformed elastomer sleeve or formed in situ by the use of a reactive drilling fluid. Appropriate reactive formulations are described for the situation where the rock contains significant quantities of clay.

Abstract: A method is disclosed that affords improved stability to wellbores during drilling in argillaceous formations with water-based drilling fluids. The method comprises adding to the drilling fluid a compound of the invention having the capacity in water to generate a highly efficient membrane on argillaceous materials. The compound is soluble in the drilling fluid at least at the pH at which the compound is added to the drilling fluid or exists in the drilling fluid, but is insoluble in the water in the pores of the argillaceous formations, or at least at the pH of the water in such pores.

Abstract: A method and apparatus for delivering a well treatment fluid to a productive zone of a subterranean formation at the same time that a well bore is being drilled is provided. The method includes the steps of delivering a drill-in fluid to a drill bit drilling a well bore in, or adjacent to, the productive zone; removing drill cuttings from the well bore; and simultaneous with these steps injecting the treatment fluid into the productive zone. The apparatus includes at least three nested tubes, which form one internal flow path and two annuluses. The drill-in fluid and drill cuttings are delivered to, and removed from, the drill bit, respectively, through the internal flow path and one of the two annuluses. The treatment fluid is delivered to the subterranean formation through the remaining annulus and an expandable bladder mounted to the intermediate and outer tubes.

Abstract: A method and a system for minimizing circulating fluid return losses during drilling of a well bore are disclosed. Circulating fluid, or mud, is heated above conventional temperatures for circulating fluids. The heated circulating fluid then contacts a region of a formation, in which a well bore is to be drilled, maintaining the formation at a relative higher temperature than if no special sources of heat were used to add heat to the circulating fluid. The region, at the relatively higher temperature, has a tendency to expand and to be placed in a relatively higher compressive state as compared to a formation at a lower temperature. Consequently, the use of the heated circulating fluid minimizes fracture initiation and growth and circulation fluid losses into the formation.

Abstract: A method and composition is provided for sealing a subterranean zone penetrated by a well bore and restoring lost circulation, wherein the composition basically comprises a mixture of latex, melamine-formaldehyde resin, and a catalyst.

Abstract: A water-base drilling fluid for use in drilling wells through a formation containing a shale which swells in the presence of water. The drilling fluid preferably includes: an aqueous based continuous phase, a weight material, and a shale hydration inhibition agent having the formula: H2N—R—{OR?}x—Y.[H+B?]d in which R and R? are alkylene groups having 1 to 6 carbon atom and x is a value from about 1 to about 25. The Y group should be an amine or alkoxy group, preferably a primary amine or a methoxy group. The acid H+B? is a protic acid selected from the group consisting of inorganic acids and organic acids, illustrative examples of which include: hydrochloric, hydrobromic, sulfuric, phosphoric, nitric, boric, perchloric, formic, acetic, halogenated acetic, propionic, butyric, maleic, fumeric, glycolic, lactic, citric and combinations of these. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale.

Abstract: A nutrient source for marine organisms comprising: drilling fluids containing organic contaminants; a solidification agent; a cell transport agent; and a cellulosic additive.

Abstract: Methods of forming chemical casings include drilling a well bore with a drilling fluid having a pH in the range of from about 6 to 10 and comprising water, a water soluble or water dispersible polymer which is capable of being cross-linked by a thermoset resin and causing the resin to be hard and tough when cured, a particulate curable solid thermoset resin, a water soluble or dispersible thermoset resin, and a delayed dispersible acid-catalyst for curing the solid thermoset resin and the water soluble thermoset resin, whereby the drilling fluid forms a filter cake on the walls of the wellbore that cures into a hard and tough cross-linked chemical casing thereon.

Abstract: Methods of consolidating formations include drilling a well bore with a drilling fluid that comprises water, a polymeric cationic catalyst which is adsorbed on minerals and rocks in weak unconsolidated zones or formations and then further contacting the unconsolidated formation with a treating fluid comprising a water soluble or dispersible polymer which is cross-linked by a thermoset resin and causes the resin to be hard and tough when cured, and a water soluble or dispersible thermoset resin which cross-links the polymer, is catalyzed and cured by the catalyst and consolidates the weak zone or formation so that sloughing is prevented.

Abstract: A method to significantly reduce mounding on the seafloor near oil drilling operations comprising the steps of: mixing drilling fluids with organic contaminates in a high shear mixer; adding a solidification agent which expands when hydrated and electrolytically attracts said organic contaminates to its surface; adding a cellulosic additive in an amount between 1 and 50 wt % based on the amount of said organic contaminate in the drilling fluid forming a mixture; adding a cell transport agent in an amount between 0.5 wt % and 10 wt % based on the amount of said organic contaminate in the drilling fluid, wherein said cell transport agent is capable of transporting large organic molecules through cell walls and neutralizing said mixture to a pH of between 7 and 8 to said mixture; and mixing at a high shear rate until said mixture forms a fine powder, dispersing said fine powder into the sea.

Abstract: A water-base fluid for use in drilling wells and other drilling operation includes a shale clay which swells in the presence of water. The fluid preferably includes: an aqueous based continuous phase, and a shale hydration inhibition agent having the formula: wherein R and R′ are independently selectable alkylene groups having 2 to 4 carbon atoms, and wherein x and y have independently selected values such that the sum of x and y is at least 1. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale clay. The fluid may be used for formulating drilling fluids such as water-base drilling muds or clear brine drilling fluids. The fluid may also be used in the slurrification and disposal of drill cuttings that contain water swellable clays or shale clays.

Abstract: Methods of consolidating unconsolidated weak zones or formations and forming chemical casings include drilling a well bore with a drilling fluid having a pH in the range of from about 6 to 10 and that comprises water, a polymeric cationic catalyst which is adsorbed on the mineral surfaces in the weak zone, a particulate curable solid thermoset resin and a delay acid catalyst for curing the solid resin, and forming a filter cake on the walls of the well bore. The filter cake is then contacted with a treating fluid comprising a water soluble or water dispersible polymer which is capable of being cross-linked by a thermoset resin and causing the resin to be hard and tough when cured, and a water soluble or dispersible thermoset resin, whereby the treating fluid components deposit on the filter cake and the thermoset resin cures into a hard and tough cross-linked chemical casing thereon.

Abstract: A composition for oil and gas drilling fluids containing organic contaminants comprising: a solidification agent; cell transport agent; a cellulosic additive; and wherein said composition comprises enough solidification agent to enable the solidification agent to electrolytically attract the organic contaminates to the surface of the solidification agent when hydrated.

Abstract: Methods and compositions for wellbore treating fluids, especially settable spotting fluids, that include zeolite and at least one carrier fluid.

Abstract: Zeolite compositions having enhanced compressive strength and methods therefor are provided. In particular, methods and compositions for wellbore treating fluids, especially settable spotting fluids having enhanced compressive strength are provided.

Abstract: A composition and method for treating oil and gas drilling fluids containing organic contaminants comprising: a solidification agent and a cellulosic additive; and wherein the composition comprises enough solidification agent to enable the solidification agent to electrolytically attract the organic contaminates to the surface of the solidification agent when hydrated.

Abstract: A composition and method for treating oil and gas drilling fluids containing organic contaminants comprising: a solidification agent, and a cell transport agent; wherein the composition comprises enough solidification agent to enable the solidification agent to electrolytically attract the organic contaminates to the surface of the solidification agent when hydrated.

Abstract: Methods and materials for chemically enhanced drilling of oil/gas wells are disclosed. The use of drilling fluids containing chemicals that dissolve formation constituents results in the creation of boreholes. Fluids containing acids such as hydrochloric acid, formic acid, acetic acid, or combinations thereof have been found to be especially useful in chemical drilling of formations containing basic minerals such as calcium carbonate. The use of acid has the further advantage of simultaneously stimulating the borehole.

Abstract: A method is provided for reducing loss of drilling fluid and for stabilizing a wellbore during drilling through depleted sands in a subterranean formation comprising depleted sands. The method comprises introducing into said wellbore and into said depleted sands an aqueous fluid comprising silicate or siliconate and resilient graphitic carbon in an amount effective at substantially plugging pores in said depleted sands.

Abstract: Methods of consolidating formations or forming chemical casing or both while drilling are provided. One method of the invention comprises drilling a well bore with a drilling fluid comprised of water, a polymeric cationic catalyst which is adsorbed on weak zones or formations formed of unconsolidated clays, shale, sand stone and the like, a water soluble or dispersible polymer which is cross-linked by a thermoset resin and causes the resin to be hard and tough when cured, a particulate curable solid thermoset resin, a water soluble thermoset resin, and a delayed dispersible acid catalyst for curing the solid and water soluble resins. The drilling fluid forms a filter cake on the walls of the well bore that cures and consolidates the unconsolidated weak zones and formations penetrated by the well bore so that sloughing is prevented and forms a hard and tough cross-linked chemical casing on the walls of the well bore.

Abstract: A method for removing filter cake from a subterranean borehole comprising drilling the borehole with a drilling fluid that includes additives to form a filter cake having an oxidation-degradable component, preferably a polysaccharide. The filter cake is contacted with a clear brine containing a mixture of a persulfate salt in a variable density brine to degrade the polymers within the filter cake. The persulfate mixture breaks down the filter cake in well bores having temperatures ranging from about 65° F. to 165° F. Concentration of the persulfate sets the pace of the reaction.

Abstract: Methods of consolidating formations or forming chemical casing or both while drilling are provided. One method of the invention comprises drilling a well bore with a drilling fluid comprised of water, a polymeric cationic catalyst which is adsorbed on weak zones or formations formed of unconsolidated clays, shale, sand stone and the like, a water soluble or dispersible polymer which is cross-linked by a thermoset resin and causes the resin to be hard and tough when cured, a particulate curable solid thermoset resin, a water soluble thermoset resin, and a delayed dispersible acid catalyst for curing the solid and water soluble resins. The drilling fluid forms a filter cake on the walls of the well bore that cures and consolidates the unconsolidated weak zones and formations penetrated by the well bore so that sloughing is prevented and forms a hard and tough cross-linked chemical casing on the walls of the well bore.

Abstract: A new composition for a spotting fluid and a method of using such spotting fluid for freeing differential stuck pipe in a subterranean well drilling operation is disclosed. The composition comprises an invert water-in-oil emulsion comprising iso-butyl oleate as its external phase and glycerin as the internal phase. In an alternative embodiment, calcium chloride and water may be substituted for glycerin.

Abstract: Improved methods of generating gas in and foaming aqueous well fluids introduced into a subterranean zone are provided. A method of the invention includes the steps of combining with an alkaline aqueous well fluid one or more gas generating chemicals and a mixture of foaming and foaming stabilizing surfactants so that the gas generating chemical or chemicals react with the alkaline aqueous well fluid and gas and foam are formed in the well fluid while it is being pumped, and then pumping the well fluid into the subterranean zone.

Abstract: A product, system and method for treating a well bore using a concentrated treatment composition enclosed in a soluble container. The composition-filled container is deposited in the well, preferably through the drill string, followed by a solvent, such as drilling mud or water, to form a circulating solution characterized by the ability to circulate through the well. Most of the circulating solution is recovered at the surface using a mud tank, for example. In a well “sweeping” operation a partially hydrolyzed polyacrylamide powder in a soluble tube is dropped down the drill string. The well bore is then flushed with water or drilling mud to form the liquified polymer down hole. The well is flushed with more water or mud to sweep the cuttings and polymer solution from the well bore.

Abstract: A water-base fluid for use in drilling wells and other drilling operation includes a shale which swells in the presence of water. The fluid preferably includes: an aqueous based continuous phase, and a shale hydration inhibition agent having the formula: H2N—R—{OR′}x—Y in which R and R′ are alkylene groups having 1 to 6 carbon atoms and x is a value from about 1 to about 25. The Y group should be an amine or alkoxy group, preferably a primary amine or a methoxy group. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale. The fluid may be used for formulating drilling fluids such as invert emulsion drilling muds or clear brine drilling fluids. The fluid may also be used in the slurrification and disposal of drill cuttings that contain water swellable clays or shales.

Abstract: A water-base fluid for use in drilling wells and other drilling operation includes a shale clay which swells in the presence of water.

Abstract: A water-base drilling fluid for use in drilling wells through a formation containing a shale which swells in the presence of water.

Abstract: A method and composition is provided for sealing a subterranean zone penetrated by a well bore and restoring lost circulation, wherein the composition basically comprises a mixture of latex, melamine-formaldehyde resin, and a catalyst.

Abstract: A tool for use with a rotatable drill shaft and a source of pressurized fluidized solidifying agent. The tool member has upper and lower extremities. A coupler is coupled to the upper extremity of the tool member and is adapted to be secured to the drill shaft. A plurality of radially extending arms are secured to the tool member intermediate the upper and lower extremities of the tool member. A plurality of forwardly and downwardly extending teeth are secured to each of the radially extending arms and are spaced apart longitudinally of the arms. A plurality of nozzles are carried by the tool member and are spaced circumferentially of the tool member and are coupled to the source of pressurized fluidized solidifying agent.

Abstract: A water-base drilling fluid for use in drilling wells through a formation containing a shale which swells in the presence of water. The drilling fluid preferably includes: an aqueous based continuous phase, a weight material, and a shale hydration inhibition agent having the formula: H2N—R—{OR′}x—Y in which R and R′ are alkylene groups having 1 to 6 carbon atoms and x is a value from about 1 to about 25. The Y group should be an amine or alkoxy group, preferably a primary amine or a methoxy group. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale. Also inclusive of the present invention is a method of reducing the swelling of shale clay encountered during the drilling of a subterranean well, the method comprising circulating in the well a water-base drilling fluid formulated in accordance with the present invention.

Abstract: A new composition for a spotting fluid and a method of using such spotting fluid for freeing differential stuck pipe in a subterranean well drilling operation is disclosed. The composition comprises an invert water-in-oil emulsion comprising iso-butyl oleate as its external phase and glycerin as the internal phase. In an alternative embodiment, calcium chloride and water may be substituted for glycerin.

Abstract: A new composition for a spotting fluid and a method of using such spotting fluid for freeing differential stuck pipe in a subterranean well drilling operation is disclosed. The composition comprises an invert water-in-oil emulsion comprising iso-butyl oleate as its external phase and glycerin as the internal phase. In an alternative embodiment, calcium chloride and water may be substituted for glycerin.