Refining Patents (Class 196/46)
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Publication number: 20100155296Abstract: A method of manufacturing a purified renewable diesel product from a biofeedstock includes filtering the biofeedstock, heating the biofeedstock to about 520° F., introducing hydrogen into the biofeedstock, and treating the biofeedstock in a reactor to generate a renewable diesel product. Additionally, the method includes cooling the renewable diesel product wherein the renewable diesel product comprises a liquid, separating vapors from the liquid, and distilling the liquid in a distillation column to generate the purified renewable diesel product. In at least one embodiment the biofeedstock comprises at least one of waste grease, tallow, algae, algal oil, vegetable oil, and soybean oil.Type: ApplicationFiled: December 16, 2009Publication date: June 24, 2010Applicant: CETANE ENERGY, LLCInventors: Richard AVES, Jason SMITH
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Publication number: 20100147647Abstract: A crude oil feedstream is treated to remove or reduce the content of known undesired heteroatomic and polynuclear aromatic compounds containing nitrogen and sulfur by contacting the feedstream with one or more solid adsorbent materials selected from attapulgus clay, alumina, silica gel and activated carbon in a mixing vessel for a time that is sufficient to optimize the adsorption of the undesired compounds from the crude oil, subjecting the mixture to atmospheric flash distillation and then to vacuum flash distillation to recover presorbed boiling ranges of products having a lowered content of the undesired compounds, and preferably regenerating at least a portion of the solid adsorbent material for reuse in the process.Type: ApplicationFiled: February 9, 2010Publication date: June 17, 2010Inventors: Omer Refa Koseoglu, Adnan Al-Haji, Hendrik Muller
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Publication number: 20100147739Abstract: High molecular weight naphthenic tetra-acids are added to a base crude oil to prevent and/or reduce fouling of crude oil refinery equipment. The method includes adding an effective amount of a high molecular weight naphthenic tetra-acid to the base crude oil to form a crude oil mixture and feeding the crude oil mixture to a crude oil refinery component. Particularly, the high molecular weight naphthenic tetra-acids include ARN acids.Type: ApplicationFiled: December 4, 2009Publication date: June 17, 2010Applicant: ExxonMobil Research and Engineering CompanyInventors: Steven W. LEVINE, Glen B. Brons, George A. Lutz, Daniel P. Leta, Clifford C. Walters
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Patent number: 7736469Abstract: A process for converting animal fats and/or other feedstocks into gas oil fuel including the steps of introducing material including the animal fats into a still pot in the form of liquor, extracting a volume of material from the still pot, heating the extracted material to a cracking temperature, reintroducing the extracted material back into the still pot, separating the lighter molecular weight compounds from the cracked material into a small fraction of volatile light ends and a second mixture of gas oil fuel in a distillation column collecting the second mixture of gas oil fuel by means of a condenser.Type: GrantFiled: November 19, 2004Date of Patent: June 15, 2010Inventor: John Taylor
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Publication number: 20100122937Abstract: A method is provided for purifying a hydrocarbon oil comprising a quantity of impurities. A Lewis acid solution comprising a Lewis acid and an aprotic solvent is added to the hydrocarbon oil having the plurality of impurities, e.g. sulfur, vanadium, and nickel impurities, to form a mixture. Complexes are formed between the Lewis acid of the Lewis acid solution and a respective one of the impurities in the mixture. The mixture is separated into a first layer that comprises a purified fraction of the hydrocarbon oil and a second layer comprising the complexes dissolved in the aprotic solvent.Type: ApplicationFiled: November 20, 2008Publication date: May 20, 2010Inventors: John Aibangbee Osaheni, Thomas Joseph Fyvie
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Publication number: 20100116714Abstract: One exemplary embodiment can be a process for facilitating adding a promoter metal to at least one catalyst particle in situ in a catalytic naphtha reforming unit. The process can include introducing a compound comprising the promoter metal to the catalyst naphtha reforming unit and adding an effective amount of the promoter metal from the compound comprising the promoter metal to the catalyst particle under conditions to effect such addition and improve a conversion of a hydrocarbon feed.Type: ApplicationFiled: November 12, 2008Publication date: May 13, 2010Inventors: Mark P. Lapinski, Richard R. Rosin, Marc R. Schreier
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Publication number: 20100115839Abstract: The present disclosure relates generally to contaminant removal from gas streams. In certain embodiments, the present disclosure relates to a process for removing one or more contaminants from a gas stream via contact with a regenerable sorbent at high temperature and pressure, utilizing a unique arrangement of reactors operating in parallel.Type: ApplicationFiled: August 31, 2009Publication date: May 13, 2010Applicant: CONOCOPHILLIPS COMPANYInventors: Ronald E. BROWN, Daniel T. Fernald
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Publication number: 20100116715Abstract: A system and method are outlined for controlling and optimizing chemical injection into a process unit to control fouling. The method uses an optical device to measure the fouling propensity of the process fluid at various points within the process unit. The measurements are compared with one another and prediction methods are used to evaluate the fouling potential within the unit, and determine the proper chemical dosage. Antifoulant chemical is then introduced into the unit to control the rate of fouling. The method and application continue on a frequent basis to maintain optimal fouling control within the unit.Type: ApplicationFiled: December 3, 2009Publication date: May 13, 2010Applicant: General Electric CompanyInventors: Collin Wade Cross, Andre Vanhove, David Owen
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Publication number: 20100096297Abstract: A process for treating bitumen froth with paraffinic solvent is provided which uses three stages of separation. Froth and a first solvent are directed to a first stage at a solvent/bitumen ratio for precipitating few or substantially no asphaltenes. A first stage underflow is directed to a second stage and a first stage overflow is directed to a third stage. A second stage underflow is directed to waste tailings and the second stage overflow joins the first stage overflow. A third stage underflow is recovered as an asphaltene by-product and a third stage overflow is recovered as a diluted bitumen product. At least a second solvent is added to one or both of the second or third stages for controlling a fraction of asphaltenes in the third stage underflow. Asphaltene loss to waste tailings is minimized and asphaltenes are now recovered as asphaltene by-product.Type: ApplicationFiled: October 20, 2009Publication date: April 22, 2010Applicant: TOTAL E&P CANADA LTD.Inventors: Geoff STEVENS, Ray REIPAS
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Publication number: 20100084314Abstract: A method and a device for separation of a fluid in the liquid state comprising two liquids that are not mutually miscible, with different densities, wherein a first liquid is to be cleansed from a second liquid, whereby the fluid in the liquid state is conducted through a rotor where centrifugal separation of the second liquid from the first liquid takes place, and is then conducted into a tank, with the proportion of the second liquid being reduced to less than 5%, and by conducting the fluid, after centrifugal separation, through a restriction, whereby the pressure of the fluid in the liquid state is reduced, which causes portions of the fluid in the liquid state to evaporate so that further portions of the second liquid escape in the form of a gas which is conducted away, thereby further reducing the proportion of the second liquid in the outgoing fluid in the liquid state.Type: ApplicationFiled: November 1, 2007Publication date: April 8, 2010Applicant: ALFA LAVAL CORPORATE ABInventors: Claes-Goran Carlsson, Leonard Borgstrom, Carl Haggmark, Hans Moberg, Jan Skoog
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Publication number: 20100038290Abstract: The present application provides a method for reducing fouling, including particulate-induced fouling, in a hydrocarbon refining process including the steps of providing a crude hydrocarbon for a refining process; adding a polyalkyl succinic acid derivative additive. The additive can be complexed with a boronating agent, such as boric acid, to yield a boron-containing polyalkyl succinic acid derivative.Type: ApplicationFiled: July 31, 2009Publication date: February 18, 2010Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Frank C WANG, Chris A WRIGHT, Glen B BRONS, Steven W LEVINE, L. Oscar FARNG
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Publication number: 20100038284Abstract: The invention relates to a method for the catalytic hydrotreatment of a load based on a diesel fuel oil and a biological load based on plant oils and/or animal fats in a hydrotreatment unit. The invention is characterised in that the hydrotreatment unit comprises at least one hydrotreatment reactor operating on a countercurrent. The invention also relates to a hydrotreatment unit for implementing said method, and a corresponding hydrorefining unit.Type: ApplicationFiled: February 12, 2008Publication date: February 18, 2010Applicant: TOTAL RAFFINAGE MARKETINGInventor: Cesar Vergel
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Publication number: 20100038289Abstract: The present application provides a method for reducing fouling, including particulate-induced fouling, in a hydrocarbon refining process including the steps of providing a crude hydrocarbon for a refining process; adding an additive selected from: wherein R1, R2, R3, and R4 are independently selected from a branched or straight-chained C5-C80 alkyl group, and M1, M2, and M3 are independently selected from Ca, Mg and Na.Type: ApplicationFiled: July 31, 2009Publication date: February 18, 2010Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Frank C. WANG, Chris A. WRIGHT, Glen B. BRONS, Steven W. LEVINE, L. Oscar FARNG
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Publication number: 20100025184Abstract: A mercury removal apparatus for a liquid hydrocarbon of the present invention includes a conversion device 2 which converts a mercury component in a raw liquid hydrocarbon into elemental mercury to obtain a first liquid hydrocarbon containing the elemental mercury; and a first stripping device 4 which brings the first liquid hydrocarbon into counter-current contact with a first stripping gas, thereby transferring the elemental mercury in the first liquid hydrocarbon to the first stripping gas to obtain a second liquid hydrocarbon in which the amount of the elemental mercury decreases and a first gaseous hydrocarbon containing the elemental mercury.Type: ApplicationFiled: February 10, 2006Publication date: February 4, 2010Applicants: JGC CORPORATION, SEKIYUSHIGEN KAIHATSU KABUSHIKI KAISHAInventors: Hiromitsu Shibuya, Kazuo Sato, Yoshiyuki Yamaguchi, Senichiro Kaku
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Publication number: 20100018899Abstract: One exemplary embodiment can be a process for producing a reformate by combining a stream having an effective amount of isopentane and a stream having an effective amount of naphtha for reforming. Generally, the naphtha has not less than about 95%, by weight, of one or more compounds having a boiling point of about 38—about 260° C. as determined by ASTM D86-07. The process may include introducing the combined stream to a reforming reaction zone. The combined stream can have an isopentane:naphtha mass ratio of about 0.10:1.00—about 1.00:1.00.Type: ApplicationFiled: July 24, 2008Publication date: January 28, 2010Inventors: Steven L. Krupa, Mark P. Lapinski, Clayton C. Sadler
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Publication number: 20100018900Abstract: One exemplary embodiment can be a process for producing a reformate by combining a stream having an effective amount of n-butane and a stream having an effective amount of naphtha for reforming. Generally, the naphtha has not less than about 95%, by weight, of one or more compounds having a boiling point of about 38—about 260° C. as determined by ASTM D86-07. The process can include introducing the combined stream to a reforming reaction zone. Typically, the combined stream has an n-butane:naphtha mass ratio of about 0.10:1.00—about 1.00:1.00.Type: ApplicationFiled: July 24, 2008Publication date: January 28, 2010Inventors: Steven L. Krupa, Mark P. Lapinski, Clayton C. Sadler
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Publication number: 20100018906Abstract: One exemplary embodiment can be a process for lowering an amount of carbon monoxide in a stream rich in hydrogen. The process can include passing the stream rich in hydrogen through a carbon monoxide removal zone to produce a product stream having no more than about 10 vppm carbon monoxide and communicating the product stream to a reduction zone receiving a catalyst comprising unreduced metal species.Type: ApplicationFiled: July 22, 2008Publication date: January 28, 2010Inventors: Mark P. Lapinski, Richard R. Rosin
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Publication number: 20100006476Abstract: A fluid is mixed into a mixture that has been separated from an oil well stream and comprises water, oil, and gas. The mixture comprising the fluid is led into a separator (3) and allowed to separate into a water phase and an oil/fluid phase. The cleaned water phase is removed from said separator (3) via an outlet for water. The oil/fluid phase is subjected to a separation step separating the oil/fluid phase into an oil phase and a gaseous phase from which gaseous phase the fluid is recovered by a condensation step and recycled for injection into the mixture. The separator is a liquid-liquid/gas separator (3) in which the pressure is in the range of 0.5 bar to 25 bar while the mixture comprising said fluid is separated into said water phase and an oil/gas phase.Type: ApplicationFiled: November 3, 2006Publication date: January 14, 2010Inventor: Jorn Folkvang
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Publication number: 20100000909Abstract: The suppression of coke adherence in a reaction vessel and cracked gas pipelines at the outlet of the reaction vessel and the prevention of plugging are designed by improving the dispersion of superheated steam inside the reaction vessel to preferable conditions, and pitch having more uniform and higher quality can be produced. A cracking process in which superheated steam is directly contacted with the heavy petroleum oil by blowing the superheated steam into the reaction vessel to be thermally cracked to oil fractions and pitch, wherein the superheated steam is blown into the reaction vessel from the bottom portion thereof so that the superheated steam generates rotational flow around the central axis of the shell of the reaction vessel.Type: ApplicationFiled: September 27, 2007Publication date: January 7, 2010Applicants: CHIYODA CORPORATION, FUJI OIL CO., LTD.Inventors: Makoto Nomura, Kenichi Mimura, Munenori Maekawa, Naoko Suzuki, Katsunori Yagi
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Publication number: 20090314687Abstract: The invention relates to a device and method for regenerating oil (17) containing a contamination in the form of a liquid. The oil (17) is brought in contact with a point source (3) consisting of at least one point source (3), where the point source (3) is brought to a predetermined temperature that at an interface between the point source (3) and the oil (17) corresponds to a maximum allowed oil temperature.Type: ApplicationFiled: March 23, 2006Publication date: December 24, 2009Inventor: Roni Söderlund
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Patent number: 7625466Abstract: A process and apparatus to remove asphaltenic contaminants from bitumen, heavy oil or residue to produce lower viscosity petroleum products and high purity asphaltenes.Type: GrantFiled: May 16, 2006Date of Patent: December 1, 2009Assignee: Value Creation Inc.Inventor: Columba K. Yeung
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Publication number: 20090288985Abstract: A process for producing light olefins and aromatics, which comprises reacting a feedstock with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone. The spent catalyst is separated from the reaction product vapor, regenerated and then returned to the reactor. The reaction product vapor is separated to obtain the desired products, light olefins and aromatics. This process efficiently produces light olefins such as propylene, ethylene, etc. from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc. at the same time.Type: ApplicationFiled: March 8, 2005Publication date: November 26, 2009Inventors: Jun Long, Zhijian Da, Dadong Li, Xieqing Wang, Xingtian Shu, Jiushun Zhang, Hong Nie, Chaogang Xie, Zhigang Zhang, Wei Wang
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Publication number: 20090178954Abstract: A processing scheme and arrangement for enhanced olefin production involves cooling or treating an olefin cracking reactor effluent stream by contacting the olefin cracking reactor effluent stream with a quench oil stream in a single contact cooler contact zone to produce a cooled vapor stream and to form a heated quench oil stream. A pressure differential across the single contact cooler is less than about 3.5 kPa. The heated quench oil stream can be subsequently cooled and returned to the single contact cooler.Type: ApplicationFiled: March 16, 2009Publication date: July 16, 2009Inventor: Adam J. Kanyuh
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Publication number: 20090173667Abstract: Methods, systems, and devices are described for using high-power microwave radiation to process (e.g., refine) recovered oil. In certain embodiments, relatively low-power microwave radiation is propagated into a recovered oil emulsion to process the emulsion into a more useful product. For example, the radiation may be used to refine the oil emulsion into a light crude oil.Type: ApplicationFiled: September 22, 2008Publication date: July 9, 2009Applicant: Colorado SeminaryInventor: Ravi Varma
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Publication number: 20090139902Abstract: A continuous process for upgrading sour crude oil by treating the sour crude oil in a two step process that includes a hydro-demetallization section and a hydro-desulfurization section, both of which are constructed in a permutable fashion so as to optimize the operating conditions and catalyst lifespan to produce a high value crude oil having low sulfur and low organometallic impurities.Type: ApplicationFiled: November 26, 2008Publication date: June 4, 2009Applicant: Saudi Arabian Oil CompanyInventors: Stephane Cyrille Kressmann, Raheel Shafi, Esam Z. Hamad, Bashir Osama Dabbousi
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Patent number: 7520743Abstract: With the disclosed device, some or all of the available oil tank vent gas in a production system can be utilized to augment the primary fuel gas needed by a heater treater unit to separate the gas, oil, and water fractions from raw natural gas extracted at the wellhead. Augmenting the primary fuel gas with vent gas reduces the demand for primary fuel gas, which thereby increases the amount of gas traversing a meter. The disclosed device also provides for an auxiliary burner unit that can directly address any available oil tank vent gas that is not utilized to augment fuel gas as waste gas. A method and apparatus for reducing the venting of raw natural gas emissions from an oil storage tank is described.Type: GrantFiled: January 2, 2007Date of Patent: April 21, 2009Assignee: Chemical Applications and Engineering, Inc.Inventor: Leslie Clifford Roberts
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Publication number: 20090012649Abstract: A control system for an oil sand processing apparatus and a method for controlling the apparatus. The apparatus includes a rotatable drum, an oil sand feed mechanism, a drive mechanism for rotating the drum, a first drum support and a second drum support. The control system includes a first drum load sensor associated with the first drum support for sensing a first drum load, a second drum load sensor associated with the second drum support for sensing a second drum load and an oil sand feedrate sensor associated with the oil sand feed mechanism for sensing a feedrate of the oil sand feed mechanism. A controller is provided for controlling a rotation speed of the drum and a feedrate of the oil sand feed mechanism in response to input data from the first drum load sensor, the second drum load sensor and the oil sand feedrate sensor.Type: ApplicationFiled: September 17, 2008Publication date: January 8, 2009Applicant: BITMIN RESOURCES INC.Inventor: William L. STRAND
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Publication number: 20090000988Abstract: This disclosure relates to a process of manufacturing para-xylene, comprising (a) contacting a pygas feedstock and methylating agent with a catalyst under reaction conditions to produce a product having para-xylene, wherein the product has higher para-xylene content than the para-xylene content of the pygas feedstock; and (b) separating the para-xylene from the product of the step (a), wherein the catalyst comprises a molecular sieve having a Diffusion Parameter for 2,2-dimethylbutane of about 0.1-15 sec?1 when measured at a temperature of 120° C. and a 2,2-dimethylbutane pressure of 8 kPa-a and the pygas comprises from about 1 to about 65 wt % benzene and from about 5 to 35 wt % toluene.Type: ApplicationFiled: June 28, 2007Publication date: January 1, 2009Inventors: Stephen Harold Brown, John Scott Buchanan
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Publication number: 20080308460Abstract: The present invention relates to an enclosure (10) comprising at least one packed bed (12) and supply means (20) for delivering at the bottom of the enclosure a mixture of a liquid with a gas. According to the invention, the enclosure comprises a system (22) for separating the liquid phase and the gas phase of said mixture, said system being arranged between bed (12) and said mixture supply means, and this system comprises a housing (24) comprising flow means (32) for the degassed liquid and discharge means (42, 44, 46, 48; 142, 144, 146, 148) for the disengaged gas.Type: ApplicationFiled: June 6, 2008Publication date: December 18, 2008Inventors: Frederic Augier, Robert Beaumont, Christophe Boyer, Denis Darmancier
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Publication number: 20080237090Abstract: Olefins can impose deleterious effect on hydrocarbon reforming processes used to generate hydrogen-enriched gas, and thus are converted into saturated compounds. Since the hydrogenation process to convert the olefins into saturated compound, difficulties arise in attempting to regulate the temperature of the hydrogenation. To facilitate temperature regulation, the hydrogenation reaction is carried out in a shell-tube reactor, containing catalyst-filled tubes, which is operated under isothermal or essentially isothermal conditions. Preferably, the heat exchange medium introduced into the shell side of the reactor to regulate the hydrogenation temperature is boiling water.Type: ApplicationFiled: March 30, 2007Publication date: October 2, 2008Inventors: Nicholas Musich, Raju S. Natarajan, Harald Klein
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Publication number: 20080190818Abstract: A method of recovering hydrocarbons from hydrocarbonaceous materials can include forming a constructed permeability control infrastructure. This constructed infrastructure defines a substantially encapsulated volume. A comminuted hydrocarbonaceous material can be introduced into the control infrastructure to form a permeable body of hydrocarbonaceous material. The permeable body can be heated sufficient to remove hydrocarbons therefrom. During heating the hydrocarbonaceous material is substantially stationary as the constructed infrastructure is a fixed structure. Removed hydrocarbons can be collected for further processing, use in the process, and/or use as recovered.Type: ApplicationFiled: February 8, 2008Publication date: August 14, 2008Inventors: Todd Dana, James W. Patten
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Patent number: 7407571Abstract: A novel apparatus for producing sweet synthetic crude from a heavy hydrocarbon feed includes: an upgrader for receiving the heavy hydrocarbon feed and producing a distillate fraction including sour products, and high-carbon content by-products; a gasifier for receiving the high-carbon content by-products and producing synthetic fuel gas and sour by-products; a hydroprocessing unit for receiving the sour by-products and hydrogen gas, thereby producing gas and sweet crude; and a hydrogen recovery unit for receiving the synthetic fuel gas and producing further hydrogen gas and hydrogen-depleted synthetic fuel gas, the further hydrogen gas being supplied to the hydroprocessing unit.Type: GrantFiled: December 24, 2002Date of Patent: August 5, 2008Assignee: Ormat Industries Ltd.Inventors: Philip Rettger, Randall Goldstein, Jim Arnold, Yoram Bronicki, J. Robert Friday
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Patent number: 7381309Abstract: Disclosed is an apparatus for extracting sulfur compounds from a hydrocarbon stream. A prewash section for converting hydrogen sulfide to sodium sulfide by reaction with an alkali such as caustic prepares the hydrocarbon stream for extraction. Spent alkali is continuously withdrawn and regenerated alkali is continuously added to the prewash section.Type: GrantFiled: December 17, 2003Date of Patent: June 3, 2008Assignee: UOP LLCInventors: Luigi Laricchia, Jonathan A. Tertel
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Publication number: 20080047871Abstract: HSP crude oil is used as process stream in crude oil storage tanks to address sludge levels both by cleaning sludge accumulations and preventing any significant sludge build up when used on a regular basis. HSP crude oil is also used to optimize cleaning routines. Making HSP oil easily accessible by providing a designated HSP source will make tank maintenance more efficient and allow refineries to use the advantages of the HSP oil to the maximum extent.Type: ApplicationFiled: August 23, 2006Publication date: February 28, 2008Applicant: ExxonMobil Research and Engineering CompanyInventors: Glen B. Brons, Douglas S. Meyer, Mohsen N. Harandi, Randolph Perry, John W. Anthony, John S. Jackson
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Patent number: 7204928Abstract: A process for the fractional distillation of crude oil, which comprises the steps of: feeding a continuous current of crude oil at 310–400° C. into a turbomixer comprising a tubular cylindrical body (1) provided with a rotor (9) formed with helically oriented paddles (10) and rotatably supported inside the body, along with a continuous current of steam; subjecting both currents to the mechanical action of the paddled rotor (9), so as to create a thin tubular dynamic turbulent layer, which is discharged and fed continuously into a fractioning column, at a predetermined height level in the column, to produce an upward-flowing vapor current and a downward-flowing liquid current therein; and optionally discharging the downward-flowing liquid current continuously from the column bottom, and feeding it continuously into the turbomixer in the same direction as the crude oil current.Type: GrantFiled: September 24, 2001Date of Patent: April 17, 2007Assignee: Vomm Chemipharma S.r.l.Inventor: Giuseppina Cerea
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Patent number: 6881303Abstract: A plastic as a material to be treated and an additive such as unsaturated fatty acid oil are mixed, and the mixture is heated in a pyrolysis tank at a temperature of 300° C. to 450° C. by a heating member to thereby thermally decompose the mixture. A gas component produced during the heating process is then removed and a pyrolysate is thus produced.Type: GrantFiled: February 28, 2001Date of Patent: April 19, 2005Assignee: Tokyo Ertec Co., Ltd.Inventors: Yoji Inoue, Satoru Aikawa, Norihiro Inagaki, Shigeru Tasaka
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Publication number: 20040118745Abstract: A novel apparatus for producing sweet synthetic crude from a heavy hydrocarbon feed comprising: an upgrader for receiving said heavy hydrocarbon feed and producing a distillate fraction including sour products, and high-carbon content by-products; a gasifier for receiving the high-carbon content by-products and producing synthetic fuel gas and sour by-products; a hydroprocessing unit for receiving the sour by-products and hydrogen gas, thereby producing gas and sweet crude; and a hydrogen recovery unit for receiving said synthetic fuel gas and producing further hydrogen gas and hydrogen-depleted synthetic fuel gas, said further hydrogen gas being supplied to said hydroprocessing unit.Type: ApplicationFiled: February 4, 2004Publication date: June 24, 2004Inventors: Philip Rettger, Randall Goldstein, Jim Arnold, Yoram Bronicki, J Robert Friday
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Patent number: 6702936Abstract: A novel apparatus for producing sweet synthetic crude from a heavy hydrocarbon feed comprising: an upgrader for receiving said heavy hydrocarbon feed and producing a distillate fraction including sour products, and high-carbon content by-products; a gasifier for receiving the high-carbon content by-products and producing synthetic fuel gas and sour by-products; a hydroprocessing unit for receiving the sour by-products and hydrogen gas, thereby producing gas and sweet crude; and a hydrogen recovery unit for receiving said synthetic fuel gas and producing further hydrogen gas and hydrogen-depleted synthetic fuel gas, said further hydrogen gas being supplied to said hydroprocessing unit.Type: GrantFiled: December 26, 2001Date of Patent: March 9, 2004Assignee: Ormat Industries Ltd.Inventors: Philip Rettger, Randall Goldstein, Jim Arnold
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Publication number: 20040011707Abstract: A process for the fractional distillation of crude oil, which comprises the steps of: feeding a continuous current of crude oil at 310-400° C. into a turbomixer comprising a tubular cylindrical body (1) provided with a rotor (9) formed with helically oriented paddles (10) and rotatably supported inside the body, along with a continuous current of steam; subjecting both currents to the mechanical action of the paddled rotor (9), so as to create a thin tubular dynamic turbulent layer, which is discharged and fed continuously into a fractioning column, at a predetermined height level in the column, to produce an upward-flowing vapor current and a downward-flowing liquid current therein; and optionally discharging the downward-flowing liquid current continuously from the column bottom, and feeding it continuously into the turbomixer in the same direction as the crude oil current.Type: ApplicationFiled: July 15, 2003Publication date: January 22, 2004Inventor: Giuseppina Cerea
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Publication number: 20030168381Abstract: The reforming of heavy oil with supercritical water or subcritical water is accomplished by mixing together supercritical water, heavy oil, and oxidizing agent, thereby oxidizing vanadium in heavy oil with the oxidizing agent at the time of treatment with supercritical water and separate vanadium oxide. The separated vanadium oxide is removed by the scavenger after treatment with supercritical water. In this way it is possible to solve the long-standing problem with corrosion of turbine blades by vanadium which arises when heavy oil is used as gas turbine fuel.Type: ApplicationFiled: September 18, 2002Publication date: September 11, 2003Inventors: Nobuyuki Hokari, Tomohiko Miyamoto, Hirokazu Takahashi, Hiromi Koizumi
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Publication number: 20030116470Abstract: A novel apparatus for producing sweet synthetic crude from a heavy hydrocarbon feed comprising: an upgrader for receiving said heavy hydrocarbon feed and producing a distillate fraction including sour products, and high-carbon content by-products; a gasifier for receiving the high-carbon content by-products and producing synthetic fuel gas and sour by-products; a hydroprocessing unit for receiving the sour by-products and hydrogen gas, thereby producing gas and sweet crude; and a hydrogen recovery unit for receiving said synthetic fuel gas and producing further hydrogen gas and hydrogen-depleted synthetic fuel gas, said further hydrogen gas being supplied to said hydroprocessing unit.Type: ApplicationFiled: December 26, 2001Publication date: June 26, 2003Inventors: Philip Rettger, Randall Goldstein, Jim Arnold
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Publication number: 20020036158Abstract: A method for separating used oil in a simple batch process into usable fractions. A pretreatment step involves forming a mixture of the used oil and specified pretreatment chemicals. A reduced pressure is maintained throughout the process along with mixing of the formed mixture. Heat is applied at a predetermined rate corresponding to vaporization and recovery of usable fractions of aqueous, light hydrocarbons, base oil, and a pumpable residual. Each distillate fraction is removed as a vapor, condensed and collected. Undesirable cracking is avoided by maintaining a reduced pressure and avoiding rapid or localized heating within the mixture by mixing during the distillation process. The resulting aqueous and light fractions can be reused in the process or otherwise used. The pumpable residual can also be sold as a high quality asphalt extender. The recovered base oil fraction may be sold as a diesel fuel extender, lubricant, catalytic cracker feed stock, or #4 fuel oil for stationary power generators.Type: ApplicationFiled: August 6, 2001Publication date: March 28, 2002Inventor: Douglas P. Austin
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Publication number: 20010032960Abstract: Unsaturated C3 and C4 perfluorocarbons are used to extinguish fires. These compounds have been found to extinguish fires as effectively as Halons with similar volatility, residue levels, materials compatibility and safety but with enhanced environmental acceptability.Type: ApplicationFiled: February 9, 2000Publication date: October 25, 2001Inventors: Lawrence Robert Grzyll, Dwight Douglas Back, Charlie Ramos, Nidal Abdul Samad
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Patent number: 6287455Abstract: The present invention provides a means of removing water, antifreeze and fuel from lubricating or hydraulic oil by evaporating these impurities and venting them out of the purifier. The oil is heated by heat of an exposed horizontal heating wand within the evaporator. The oil then passes over the upper lip of the evaporator and cascades downward over the evaporator's ridged outer surface, thereby impeding the flow of oil and increasing the rate of evaporation of the impurities. The evaporated impurities then rise upward along the interior of the domed cover and are vented out of the purifier.Type: GrantFiled: May 15, 1998Date of Patent: September 11, 2001Inventor: C. Barclay Whitmore
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Patent number: 6036473Abstract: A heavy oil emulsified fuel combustion apparatus is provided in which steam bubbles generated in the pressure reduction operation for dewatering a heavy oil emulsified fuel before combustion are prevented from mixing into a dewatered heavy oil side resulting in lowering of a dewatering efficiency.In a heavy oil emulsified fuel combustion boiler, a heavy oil emulsified fuel 101 is heated by a heater 110 and dewatered by a flusher 120 and then introduced into a boiler 10 for combustion, and water 152 obtained by the dewatering is sent to a water utilizing system of the boiler. The heavy oil emulsified fuel 102 is heated in a high pressure and then introduced into a pressure reducing device 200 to be applied by a pressure reduction by multi-stage orifices 201 for dewatering. The pressure reduction is done with a pressure reduction per stage of 1 to 3 ata.Type: GrantFiled: March 31, 1998Date of Patent: March 14, 2000Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Toshimitsu Ichinose, Hirokazu Hino, Akira Yamada, Hiroshi Kikuchi, Katsuyuki Ueda
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Patent number: 5951868Abstract: The present invention relates to a system and a method for separating a hydrocarbon containing material such as crude oil from water. The system of the present invention includes a treatment tank, a layer of a fluid having a chemical affinity for the hydrocarbon contain material being separated within the tank for separating the hydrocarbon containing material from said water without any mixing and with a minimum level of turbulence, and a distribution system for introducing the water with the hydrocarbon containing material into the layer of chemical affinity fluid. The method of the present invention broadly comprises the steps of providing a treatment tank having a layer of a fluid having a chemical affinity for the hydrocarbon containing material and separating the hydrocarbon containing material from the water without any mixing and with a minimum of turbulence by introducing the water with the hydrocarbon containing material into the layer of chemical affinity fluid.Type: GrantFiled: September 19, 1997Date of Patent: September 14, 1999Assignee: Intevep, S.A.Inventor: Aaron Padron
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Patent number: 5904836Abstract: High-vacuum oil refinery systems and process are disclosed in this invention. The systems and process enables to carry out vaporization and distillation of oils under the condition of 1-10.sup.-4 Torr of high vacuum and at the temperature of not higher than 360.degree. C. and thereby removing possibility of thermal cracking while heating to be vaporized and easily produces high quality oil. The vaporized gases are centrifugally separated and liquefied by specific gravity using high-vacuum gas specific gravity centrifugal separators and thereby producing high purity oil of uniform quality. The process also carries out vaporization and distillation of the oil at the temperature of not higher than 360.degree. C. so that the process prevents vaporization of sulfur components of the oil, but simply drains the sulfur components along with the concentrated sludge oil and thereby distilling and desulfurizing the crude or heavy oil at the same time without using expensive conventional desulfurizing process.Type: GrantFiled: February 1, 1996Date of Patent: May 18, 1999Assignee: Dae Sung LeeInventors: Dae Sung Lee, Ho Keun Shin
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Patent number: 5871618Abstract: Disclosed is an apparatus and a process for reclaiming fuel oil from waste oil. The apparatus comprises a thermal cracking unit for cracking the high boiling hydrocarbon material into lighter, lower boiling, material so as to separate hydrocarbon vapor products from viscous materials; a condenser/heat exchanger for condensing the hydrocarbon vapor products to the liquid state; a fuel stabilization unit for chemically treating the condensates so as to give a oil product and solid sediment; and a polishing unit for forming a high quality fuel oil by physically removing solid contaminants. According to the present invention, high quality fuel oil can be obtained together with an environmentally innocuous solid ash cake, through a simple and efficient process.Type: GrantFiled: January 16, 1997Date of Patent: February 16, 1999Inventors: Sung Rae Lee, Henry Kong, Roy B. Jeffries, Norman L. Arrison, Wlodzimierz P. Rzazewski
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Patent number: 5707510Abstract: The treating apparatus and method of the present invention improve the efficiency and reliability of flash treating crude oil by including a recycled oil pumping loop that takes crude oil from a flashing section of a vessel and feeds it to either the inlet of a treater section or through a heater into a connecting pipe between the treater section and the flashing section, thereby eliminating the need of a fired heater in the flashing section.Type: GrantFiled: June 20, 1996Date of Patent: January 13, 1998Assignee: Kvaerner Process Systems, Inc.Inventor: J. Patrick Berry
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Patent number: 5645692Abstract: A method and apparatus for stabilizing crude oil at the outlet of a well, including at least one separation step wherein the crude oil is pressure distilled in at least one distillation column into at least two cuts, i.e., a C.sub.1-5 hydrocarbon gas cut recovered at the top of the column and a stabilized crude oil cut recovered below the point where the original crude oil was injected into the column. The method advantageously includes at least one decompression step before the separation step.Type: GrantFiled: June 26, 1995Date of Patent: July 8, 1997Assignee: Elf Aquitaine ProductionInventors: Jean-Paul Gourlia, Jacques Tournier Lasserve, Georges Bihn-Cirlot, Jean Vandermeersch