Reflective Patents (Class 204/192.27)
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Patent number: 7622161Abstract: A method of making a coated article (e.g., window unit), and corresponding coated article are provided. A layer of or including diamond-like carbon (DLC) is formed on a glass substrate. Then, a protective layer is formed on the substrate over the DLC inclusive layer. During heat treatment (HT), the protective layer prevents the DLC inclusive layer from significantly burning off. Thereafter, the resulting coated glass substrate may be used as desired, it having been HT and including the protective DLC inclusive layer.Type: GrantFiled: July 15, 2004Date of Patent: November 24, 2009Assignee: Guardian Industries Corp.Inventor: Vijayen S. Veerasamy
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Patent number: 7585396Abstract: A coated article is provided that may be used as a vehicle windshield, insulating glass (IG) window unit, or the like. Ion beam treatment is performed on a layer(s) of the coating. For example, an overcoat layer (e.g., of silicon nitride) of a low-E coating may be ion beam treated in a manner so as to cause the ion beam treated layer to include (a) nitrogen-doped Si3N4, and/or (b) nitrogen graded silicon nitride. It has been found that this permits durability of the coated article to be improved.Type: GrantFiled: June 25, 2004Date of Patent: September 8, 2009Assignee: Guardian Industries Corp.Inventor: Vijayen S. Veerasamy
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Patent number: 7575661Abstract: In a reactive sputtering apparatus, an inert-gas supplying hole is provided in a movable target unit whose one end is open and whose conductance is controlled, and a reactive gas containing at least fluorine or oxygen can be supplied to a space between the target and a substrate. The apparatus is constructed so as to emit the reactive gas toward the substrate. A reactive-gas emitting location is in the space between the target and the substrate such that a concentration of the reactive gas on the substrate surface can be maintained at a higher level. When the target is moved, a reactive-gas emitting port is moved or the reactive-gas emitting location is changed. The concentration of the reactive gas on the substrate surface can be effectively kept constant, and a high-quality optical thin film can be formed.Type: GrantFiled: July 27, 2004Date of Patent: August 18, 2009Assignee: Canon Kabushiki KaishaInventors: Yasuyuki Suzuki, Koji Teranishi
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Publication number: 20090195865Abstract: The invention relates to an infrared radiation reflecting layer system for panes of glass and similar, the properties of said layer system being maintained even after heat treatment, for example, for bending or hardening the panes of glass. Silver is used as the infrared radiation reflecting layer. A combination of NiCrOx and Zn(Al)Ox is used as a lower-layer blocker for the silver. Also, a stoichiometric layer is also used as a pre-blocker layer. A specific work point is selected for a first dielectric layer of TiOxNy. Harmonisation of the thickness of the layers and the degrees of oxidation of NiCrOx and ZnAlOx as double lower-layer blockers and the work point of the TiOxNy-base layer are important for the temperability of the coating.Type: ApplicationFiled: February 15, 2007Publication date: August 6, 2009Applicant: APPLIED MATERIALS GMBH & CO. KGInventors: Gerd Kleideiter, Michael Geisler, Udo Schreiber, Sven Schramm
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Publication number: 20090188786Abstract: Methods and apparatus for use with a micromirror element includes a micromirror a micromirror having a substantially flat outer surface disposed outwardly from a support structure that is operable to at least partially support the micromirror. The support structure includes at least one layer overlying at least two discrete planes that are both substantially parallel to the outer surface of the micromirror. In one particular embodiment, the support structure includes annular-shaped sidewalls that encapsulate a photoresist plug.Type: ApplicationFiled: April 6, 2009Publication date: July 30, 2009Applicant: Texas Instruments IncorporatedInventor: David A. Rothenbury
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Patent number: 7563347Abstract: A coated article is provided that may be used as a vehicle windshield, insulating glass (IG) window unit, or the like. An ion beam is used to treat an infrared (IR) reflecting layer(s) of such a coated article. Advantageously, this has been found to improve sheet resistance (Rs) properties, emittance, solar control properties, and/or durability of the coated article. In certain example embodiments, an ion source(s) and a sputtering target(s) used in forming the IR reflecting layer, or any other suitable layer, may be located in a common deposition chamber of an apparatus used in forming at least part of the coating.Type: GrantFiled: November 17, 2004Date of Patent: July 21, 2009Assignees: Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.), Guardian Industries Corp.Inventors: Uwe Kriltz, Jochen Butz, Gerald Jänicke, Vijayen S. Veerasamy
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Publication number: 20090176086Abstract: The invention relates to a substrate (10), especially a transparent glass substrate, provided with a thin-film multilayer coating comprising an alternation of n functional layers (40) having reflection properties in the infrared and/or in solar radiation, especially metallic functional layers based on silver or on metal alloy containing silver, and (n+1) dielectric films (20, 60), where n>1, said films being composed of a layer or a plurality of layers (22, 24, 62, 64), at least one of which is made of a dielectric material, so that each functional layer (40) is placed between at least two dielectric films (20, 60) , characterized in that at least one functional layer (40) includes a blocker film (30, 50) consisting of at least one interface layer (32, 52) immediately in contact with said functional layer, this interface layer being based on titanium oxide TiOx.Type: ApplicationFiled: November 8, 2006Publication date: July 9, 2009Applicant: SAINT-GOBAIN GLASS FRANCEInventors: Estelle Martin, Eric Mattmann, Pascal Reutler, Eric Petitjean, Jonathan Schneider
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Publication number: 20090176121Abstract: An electroconductive diffuse reflective film is made of an electroconductive metal, wherein the electroconductive diffuse reflective film has a porous structure in which crystal grains having an average grain diameter of 50 nm or more and 1,000 nm or less are separately arranged at intervals of 10 nm or more and 800 nm or less on average.Type: ApplicationFiled: December 1, 2008Publication date: July 9, 2009Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventor: Masao Mizuno
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Patent number: 7550067Abstract: A coated article is provided that may be used as a vehicle windshield, insulating glass (IG) window unit, or the like. Ion beam treatment is performed on a layer(s) of the coating. For example, a silicon nitride layer of a low-E coating may be ion beam treated. It has been found that ion beam treatment, for example, of a silicon nitride underlayer is advantageous in that sodium migration from the glass substrate toward the IR reflecting layer(s) can be reduced during heat treatment.Type: GrantFiled: June 25, 2004Date of Patent: June 23, 2009Assignee: Guardian Industries Corp.Inventor: Vijayen S. Veerasamy
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Patent number: 7537677Abstract: A ceramic target is used in sputter-depositing a contact layer adjacent an infrared (IR) reflecting layer in certain example embodiments. For example, a ZnOx ceramic target may be used in sputter-depositing a zinc oxide inclusive layer over and/or under a silver based IR reflecting layer in certain embodiments. In certain example embodiments, the ceramic target may be doped with a non-metal such as F and/or B.Type: GrantFiled: January 19, 2005Date of Patent: May 26, 2009Assignee: Guardian Industries Corp.Inventors: Yiwei Lu, Thomas A. Seder
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Patent number: 7431808Abstract: An electrically conductive titanium dioxide sputter target with an electrical resistivity of less than 5 ?-cm, which contains as an additive at least one doping agent or a mixture of doping agents in an amount of less than 5 mole %. The doping agent or agents are selected from the group including indium oxide, zinc oxide, bismuth oxide, aluminum oxide, gallium oxide, antimony oxide, and zirconium oxide. This treatment renders the titanium dioxide sputter target suitable for use in a direct-current sputtering process without any negative effects on the properties of the coating.Type: GrantFiled: August 19, 2002Date of Patent: October 7, 2008Assignee: W.C. Heraeus GmbH & Co., KGInventors: Markus Schultheis, Christoph Simons, Martin Weigert
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Patent number: 7323088Abstract: A method of manufacturing a glazing panel comprises the steps of: a) taking a glazing panel having on one of its surfaces (i) a substantially transparent coating layer having a transformable portion, and (ii) an enamel material associated with the transformable portion of the coating layer; and b) causing an interaction between the transformable portion of the coating layer and the enamel material associated therewith by healing the glazing panel to a temperature above about 300° C. This may render a portion of the coating layer less susceptible to corrosion and/or non-conductive to electricity.Type: GrantFiled: April 16, 2003Date of Patent: January 29, 2008Assignee: GlaverbelInventor: Etienne Degand
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Patent number: 7314688Abstract: A reflection mask blank and a method of producing a reflection mask blank by forming, on a substrate, at least a multilayer reflection film for reflecting exposure light and an absorber layer formed on the multilayer reflection film for absorbing the exposure light. In order to avoid change over lapsed time in properties of the multilayer reflection film, the substrate with the multilayer reflection film is subjected to heat treatment. The heat treatment is during deposition and/or after deposition of the multilayer reflection film. A reflection mask is made from the reflection mask blank according to a reflection mask production method and a semiconductor is made from the reflection mask according to a semiconductor production method.Type: GrantFiled: September 10, 2003Date of Patent: January 1, 2008Assignee: Hoya CorporationInventor: Tsutomu Shoki
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Patent number: 7303658Abstract: A glass coated with a heat reflecting colored film, which is excellent in the uniformity of the film thickness and composition, which is free from a unfavorable whitish coloration in ceramic color printing and which is excellent in a silver print coloration, is presented. A glass coated with a heat reflecting colored film, obtained by heat treatment of a glass having a first layer containing iron oxide, chromium oxide and nickel oxide and a second layer containing cobalt oxide, laminated sequentially by a sputtering method, on one side of a glass substrate.Type: GrantFiled: December 6, 2004Date of Patent: December 4, 2007Assignee: Asahi Glass Company, LimitedInventors: Takashi Sugiyama, Eiichi Ando
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Patent number: 7267748Abstract: A coated article is provided, where a coating is supported by a substrate. The coating may include at least one infrared (IR) reflecting layer of or including Ag, Au or the like. The IR reflecting layer(s) may be sandwiched between first and second dielectric layers in certain example embodiments of this invention. It has been found that properties of the IR reflecting layer can be improved by reducing the distance between the substrate and the sputtering target(s) used in forming the IR reflecting layer(s).Type: GrantFiled: November 5, 2004Date of Patent: September 11, 2007Assignee: Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A.Inventors: Jochen Butz, Anton Dietrich
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Patent number: 7238262Abstract: A system and method of coating curved substrates and assembling devices having coated elements. The system and method are of particular utility in the manufacture of lamps having a coating formed on the hermetically sealed light emitting chamber of the lamp. The system and method includes, inter alia, an improved uniform coating process and apparatus, improved throughput in the coating process, a reduction in bad coating losses, improved baking processes, and an improved method and apparatus for aligning the filament of a halogen lamp achieved by performing the step of coating of the light emitting chamber prior to the step of sealing the chamber.Type: GrantFiled: March 29, 2000Date of Patent: July 3, 2007Assignee: Deposition Sciences, Inc.Inventors: Leroy A. Bartolomei, H. Robert Gray
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Patent number: 7229533Abstract: A coated article is provided that may be used as a vehicle windshield, insulating glass (IG) window unit, or the like. An ion beam is used during at least part of forming an infrared (IR) reflecting layer(s) of such a coated article. Advantageously, this has been found to improve sheet resistance (Rs) properties, solar control properties, and/or durability of the coated article. Other layers may also be ion beam treated in certain example embodiments.Type: GrantFiled: June 25, 2004Date of Patent: June 12, 2007Assignee: Guardian Industries Corp.Inventor: Vijayen S. Veerasamy
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Patent number: 7226528Abstract: A sputter coated article is provided with improved mechanical durability (e.g., pre-HT scratch resistance) and/or thermal stability by sputtering at least one Ag inclusive layer in an atmosphere including at least O2 gas. For instance, in certain example embodiments an Ag inclusive target may be sputtered in an atmosphere including a combination of Ar and O2 gas. In certain embodiments, this enables the resulting AgOx infrared (IR) reflecting layer to better adhere to adjacent contact layer(s).Type: GrantFiled: March 18, 2004Date of Patent: June 5, 2007Assignees: Guardian Industries Corp., Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.)Inventors: Ronald E. Laird, George Neuman, Philip J. Lingle, Jean-Marc Lemmer, Keith H. Schillinger
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Patent number: 7198700Abstract: An alloy material, a thin film and an optical recording medium to achieve various tasks such as maintenance of a high reflectivity, improved corrosion resistance, simplified production of the alloy, and realization of stability and simplicity/easiness of a sputtering process when being used as a sputtering target. An AgPd alloy including Ag as a main component and Pd in the range of 0.5 to 4.9 atomic % is used as a thin film formation use sputtering target material, with the target material a thin film, that is a reflecting film, constituting an optical recording medium is formed and the optical recording medium containing the reflecting film as a constituent is produced.Type: GrantFiled: February 4, 2005Date of Patent: April 3, 2007Assignees: Sony Corporation, Furuyametals Co., Ltd.Inventors: Katsuhisa Aratani, Takashi Ueno
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Patent number: 7198699Abstract: A coating apparatus deposits a first coating (single or multi-layered) onto a first side of a substrate (e.g., glass substrate) passing through the apparatus, and a second coating (single or multi-layered) onto the other or second side of the substrate. In certain example embodiments, the first coating may be deposited via sputtering while the second coating is deposited via ion beam deposition. In such a manner, it is possible to coat both sides of the substrate in a single apparatus in an efficient manner. In other embodiments, the coating apparatus may sputter a coating onto a first side of the substrate and ion beam mill at least one surface of the substrate as the substrate passes through the coating apparatus. In other embodiments of this invention, a dual mode chamber may be provided that is adapted to receive a removable ion beam module on one side of a substrate and a removable sputtering module on the other side of the substrate.Type: GrantFiled: May 6, 2003Date of Patent: April 3, 2007Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Hugh A. Walton
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Patent number: 7052585Abstract: A coated article is provided which includes a layer including titanium oxycarbide. In order to form the coated article, a layer of titanium oxide is deposited on a substrate by sputtering or the like. After sputtering of the layer including titanium oxide, an ion beam source(s) is used to implant at least carbon ions into the titanium oxide. When implanting, the carbon ions have sufficient ion energy so as to knock off oxygen (O) from TiOx molecules so as to enable a substantially continuous layer comprising titanium oxycarbide to form near a surface of the previously sputtered layer.Type: GrantFiled: March 11, 2003Date of Patent: May 30, 2006Assignee: Guardian Industries Corp.Inventors: Vijayen S. Veerasamy, Scott V. Thomsen, Rudolph Hugo Petrmichl
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Patent number: 6972076Abstract: An alloy material, a thin film and an optical recording medium to achieve various tasks such as maintenance of a high reflectivity, improved corrosion resistance, simplified production of the alloy, and realization of stability and simplicity/easiness of a sputtering process when being used as a sputtering target. An AgPd alloy including Ag as a main component and Pd in the range of 0.5 to 4.9 atomic % is used as a thin film formation use sputtering target material, with the target material a thin film, that is a reflecting film, constituting an optical recording medium is formed and the optical recording medium containing the reflecting film as a constituent is produced.Type: GrantFiled: October 29, 1999Date of Patent: December 6, 2005Assignees: Sony Corporation, Furuyametals Co., Ltd.Inventors: Katsuhisa Aratani, Takashi Ueno
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Patent number: 6933013Abstract: In order to allow application of any coating under a vacuum over a volatile gelatinous layer, such as polymer dispersed liquid crystal (PDLC) on an optical glass substrate with a transparent electrode, such as indium tin oxide (ITO) on its surface, a layer of an intermediate stress absorbing polymeric material is first applied to cover the volatile gelatinous layer to prevent evaporation and escape of volatiles, thereafter the coating is applied under a very high vacuum using for example a technique called Physical Vapor Deposition (PVD) or sputtering.Type: GrantFiled: October 14, 2003Date of Patent: August 23, 2005Assignee: Photon Dynamics, Inc.Inventors: Rajiv Pethe, Pramod Gupta, Xianhai Chen, Alexander Nagy
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Patent number: 6921465Abstract: A method for making a dry plating built-up film comprises providing silicon carbide as a starting source and subjecting to dry plating while changing a concentration of a reactive gas continuously or intermittently to deposit and form, on a substrate, a thin film having different refractive indices along its thickness. A method for making a sputter built-up film is also described, which comprising providing silicon carbide as a target and subjecting to sputtering while changing making electric power against the target continuously or intermittently to deposit and form a thin film having different refractive indices along its thickness.Type: GrantFiled: August 26, 2003Date of Patent: July 26, 2005Assignee: Bridgestone CorporationInventors: Masato Yoshikawa, Shingo Ohno, Sho Kumagai
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Patent number: 6911125Abstract: When forming an optical thin film on a surface of a bulb of a light source such as an electric lamp or a discharge lamp, a thin film whose interface/surface is less rough is formed on a base having a spheroid shape. When forming a thin film on a base 2 with a spheroid shape, which is disposed in a vacuum chamber 4 of a film-forming device and spun on its rotation axis, an interface or a surface of the thin film is made less rough and the thickness distribution of the thin film is made smaller by setting a sputtering gas pressure to be in a range from 0.04 Pa to 5.Type: GrantFiled: September 4, 2001Date of Patent: June 28, 2005Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Naotaka Hashimoto, Yuuji Omata
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Patent number: 6860974Abstract: There are provided techniques of forming a back reflecting layer with constant characteristics throughout long-term film formation and forming a metal oxide film so as to be able to maintain a current of a bottom cell and thereby keep a short-circuit current Jsc of a solar cell constant over a long period of time. A sputtering method is a method of forming a stack of a metal film and a metal oxide film, comprising the step 1 of forming a metal layer on a substrate, the step 2 of bringing a surface of the metal layer into contact with active oxygen, and the step 3 of forming a metal oxide film thereon after the step 2, wherein in the step 2 an amount of active oxygen at a first substrate position is different from that at a second substrate position.Type: GrantFiled: June 28, 2002Date of Patent: March 1, 2005Assignee: Canon Kabushiki KaishaInventors: Hiroshi Echizen, Yasuyoshi Takai, Akiya Nakayama
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Patent number: 6808606Abstract: This invention relates to a method of making a window (e.g., vehicle windshield, architectural window, etc.), and the resulting window product. At least one glass substrate of the window is ion beam treated and/or milled prior to application of a coating (e.g., sputter coated coating) over the treated/milled substrate surface and/or prior to heat treatment. As a result, defects in the resulting window and/or haze may be reduced. The ion beam used in certain embodiments may be diffused. In certain embodiments, the ion beam treating and/or milling is carried out using a fluorine (F) inclusive gas(es) and/or argon/oxygen gas(es) at the ion source(s). In certain optional embodiments, F may be subimplanted into to treated/milled glass surface for the purpose of reducing Na migration to the glass surface during heat treatment or thereafter, thereby enabling corrosion and/or stains to be reduced for long periods of time.Type: GrantFiled: September 10, 2002Date of Patent: October 26, 2004Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Rudolph Hugo Petrmichl, Vijayen S. Veerasamy, Anthony V. Longobardo, Henry A. Luten, David R. Hall, Jr.
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Patent number: 6806030Abstract: In an optical disk for high density recording, for preventing the deformation of recording tracks caused by stress which may develop between the substrate and the recording stacked film formed thereon, a stress-compensation layer having a metal element such as Ti or Cr as a main component is provided. The stress-compensation layer undergoes contraction (tensile stress) to compensate for compression stress which develops in the stacked film during cooling after the thermal expansion of the substrate surface that occurs at the end of film formation. The stress-compensation layer has a pillar-like structure which, starting from the lower face, reaches the upper face of the film.Type: GrantFiled: March 19, 2001Date of Patent: October 19, 2004Assignees: Hitachi, Ltd., Hitachi Maxell, Ltd.Inventors: Motoyasu Terao, Makoto Miyamoto, Yasushi Miyauchi, Keikichi Ando, Yumiko Anzai, Junko Ushiyama, Reiji Tamura, Yoshihiro Ikari, Tamotsu Fuchioka
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Patent number: 6800179Abstract: A heat treatable coated article includes an oxidation graded layer designed so as to include an at least partially oxided anti-migration or barrier layer(s) portion provided between a solar management layer portion (e.g., NiCr layer portion) and a dielectric layer (e.g., silicon nitride). In certain example embodiments, the anti-migration or barrier layer(s) portion may include a metal oxide, and function(s) to prevent element(s) from migrating between the solar management layer and the dielectric layer upon heat treatment (HT) of the coated article. As a result, the coated article has improved color stability (and thus a lower &Dgr;E* value) upon HT. In certain example embodiments, a single target may be used to sputter the graded layer including the anti-migration layer portions and the more metallic central portion. Coated articles herein may be used in the context of insulating glass (IG) window units, other architectural windows, vehicle windows, or the like.Type: GrantFiled: October 8, 2003Date of Patent: October 5, 2004Assignee: Guardian Industries Corp.Inventor: Hong Wang
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Publication number: 20040180214Abstract: A sputter coated article is provided with improved mechanical durability (e.g., pre-HT scratch resistance) and/or thermal stability by sputtering at least one Ag inclusive layer in an atmosphere including at least O2 gas. For instance, in certain example embodiments an Ag inclusive target may be sputtered in an atmosphere including a combination of Ar and O2 gas. In certain embodiments, this enables the resulting AgOx infrared (IR) reflecting layer to better adhere to adjacent contact layer(s).Type: ApplicationFiled: March 18, 2004Publication date: September 16, 2004Applicants: Guardian Industries Corp., Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C)Inventors: Ronald E. Laird, George Neuman, Philip J. Lingle, Jean-Marc Lemmer, Keith H. Schillinger
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Patent number: 6787005Abstract: A sputter coated article is provided with improved mechanical durability (e.g., pre-HT scratch resistance) and/or thermal stability by sputtering at least one Ag inclusive layer in an atmosphere including at least O2 gas. For instance, in certain example embodiments an Ag inclusive target may be sputtered in an atmosphere including a combination of Ar and O2 gas. In certain embodiments, this enables the resulting AgOx infrared (IR) reflecting layer to better adhere to adjacent contact layer(s).Type: GrantFiled: September 16, 2002Date of Patent: September 7, 2004Assignees: Guardian Industries Corp., Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.)Inventors: Ronald E. Laird, George Neuman, Philip J. Lingle, Jean-Marc Lemmer, Keith H. Schillinger
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Patent number: 6764579Abstract: A substrate is coated with a solar management coating system including at least one infrared (IR) reflective layer. A diamond-like carbon (DLC) inclusive protective coating system (e.g., including at least one highly tetrahedral amorphous carbon (ta-C) inclusive layer having sp3 carbon—carbon bonds) is provided on the substrate over at least the IR reflective layer in order to make the coating system scratch resistant, abrasion resistant, and generally mechanically durable. The DLC inclusive protective coating system may be hydrophobic, hydrophillic, or neutral in different embodiments of the invention. Optionally, at least one fluoro-alkyl silane (FAS) compound inclusive layer may be provided on the substrate over at least one of the DLC inclusive layer(s) in hydrophobic embodiments in order to increase contact angle &thgr; of the coated article.Type: GrantFiled: September 13, 2002Date of Patent: July 20, 2004Assignee: Guardian Industries Corp.Inventors: Vijayen S. Veerasamy, Rudolph Hugo Petrmichl, Scott V. Thomsen
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Publication number: 20040137235Abstract: The use of a layer comprising a suboxidic indium oxide as an embedding layer above and/or below a light transmitting silver layer provides a coated glass substrate which can be toughened and/or bent. The preferred suboxidic oxide is indium tin oxide. The coating may comprise one or more silver layers. The bent or toughened coated glass are suitable for use e.g. in vehicle glazings and architectural glazings.Type: ApplicationFiled: February 25, 2004Publication date: July 15, 2004Inventors: Thomas Paul, Axel Noethe, Dieter Mueller, Michael Rissmann, Heinz Hoelscher
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Publication number: 20040137237Abstract: A heat treatable coated article including an infrared (IR) reflecting layer (e.g., of or including Ag), the coated article being able to attain a &Dgr;E* (glass side) no greater than about 3.0, more preferably no greater than 2.5, and even more preferably no greater than 2.0, following or due to heat treatment (e.g., thermal tempering). Accordingly, low-E (i.e., low emissivity) coated articles of certain embodiments of this invention appear from the glass side thereof visually similar to the naked eye both before and after heat treatment. Coated articles herein may be used in the context of insulating glass (IG) window units, vehicle windshields, or any other suitable applications. In certain embodiments of this invention, an exemplary layer stack includes: glass/Si3N4/NiCr/Ag/NiCr/Si3N4. Other materials may instead be used without departing from the scope and/or spirit of the instant invention which is a low-E matchable product.Type: ApplicationFiled: December 24, 2003Publication date: July 15, 2004Applicant: Guardian Industries Corp.Inventor: Grzegorz Stachowiak
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Patent number: 6740211Abstract: This invention relates to a method of making a laminated window such as a vehicle windshield. At least one of the two glass substrates of the window is ion beam milled prior to heat treatment and lamination. As a result, defects in the resulting window and/or haze may be reduced.Type: GrantFiled: February 14, 2002Date of Patent: May 25, 2004Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Rudolph Hugo Petrmichl, Anthony V. Longobardo, Vijayen S. Veerasamy, David R. Hall, Jr., Henry Luten
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Patent number: 6726814Abstract: A process for producing an optical article includes laminating a first optically transparent thin layer and a second optically transparent thin layer having a higher refractive index than that of the first optically transparent thin layer on a surface of a substrate. At least one of the first and second optically transparent thin layers is deposited by sputtering using a sputtering gas comprising atoms of at least one selected from the group consisting of krypton, xenon and radon.Type: GrantFiled: January 28, 2002Date of Patent: April 27, 2004Inventors: Tadahiro Ohmi, Kazuyuki Harada, Nobuyoshi Tanaka
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Patent number: 6723211Abstract: A heat treatable coated article (e.g., vehicle windshield, IG unit, etc.) is provided with a dual-silver low-E coating. Before and/or after heat treatment (HT); the coating and/or coated article has a visible transmittance of at least 70%, more preferably at least 75%. Moreover, the coating and/or coated article is designed so as to have approximately the same color when viewed over a wide range of viewing angles. In certain embodiments, at least one contact layer (e.g., of or including NiCrOx) that contacts an infrared (IR) reflecting layer (e.g., Ag) is oxidation graded so that it progressively becomes less oxidized through its thickness as it nears the IR reflecting layer. In still other embodiments, a Si-rich silicon nitride layer(s) may be utilized to reduce haze.Type: GrantFiled: January 7, 2003Date of Patent: April 20, 2004Assignees: Guardian Industries Corp, Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.)Inventors: Philip J. Lingle, Anton Dietrich, Ronald E. Laird, Jean-Marc Lemmer
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Publication number: 20040069616Abstract: A heat treatable coated article includes an oxidation graded layer designed so as to include an at least partially oxided anti-migration or barrier layer(s) portion provided between a solar management layer portion (e.g., NiCr layer portion) and a dielectric layer (e.g., silicon nitride). In certain example embodiments, the anti-migration or barrier layer(s) portion may include a metal oxide, and function(s) to prevent element(s) from migrating between the solar management layer and the dielectric layer upon heat treatment (HT) of the coated article. As a result, the coated article has improved color stability (and thus a lower &Dgr;E* value) upon HT. In certain example embodiments, a single target may be used to sputter the graded layer including the anti-migration layer portions and the more metallic central portion. Coated articles herein may be used in the context of insulating glass (IG) window units, other architectural windows, vehicle windows, or the like.Type: ApplicationFiled: October 8, 2003Publication date: April 15, 2004Applicant: Guardian Industries Corp.Inventor: Hong Wang
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Publication number: 20040058253Abstract: A mirror for use in an exposure system of this invention includes a reflection layer for reflecting EUV formed on a mirror substrate and an absorption layer formed on the reflection layer and made from a compound for absorbing infrared light.Type: ApplicationFiled: August 15, 2003Publication date: March 25, 2004Applicant: MATSUSHITA ELECTRIC INDUSTRIAL CO., LTDInventors: Masayuki Endo, Masaru Sasago
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Publication number: 20040053080Abstract: A carbon hydrogen raw material gas and a SF6 raw material gas are introduced into a chamber, and a high frequency electric power is introduced into the chamber to discharge the raw material gas to be made plasma. At the same time, a metallic plate on a main surface of one of parallel plate electrodes is sputtered to form a compound film made of carbon, sulfide and metallic elements which are dispersed in the film matrix made of carbon and sulfide and does not consititute clusters through aggregation.Type: ApplicationFiled: February 19, 2003Publication date: March 18, 2004Applicant: NAGOYA UNIVERSITYInventors: Shinzo Morita, Masaki Matsushita
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Publication number: 20040048193Abstract: An optical data recording and storage medium includes a reflective layer formed from a silver alloy that contains, in addition to silver, about 0.1 to about 4.0 wt. %, based on the total weight of alloy, of samarium (Sm).Type: ApplicationFiled: June 26, 2003Publication date: March 11, 2004Inventors: Heiner Lichtenberger, Derrick L. Brown, Scott Haluska
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Publication number: 20040048074Abstract: A glass coated with a heat reflecting colored film, which is excellent in the uniformity of the film thickness and composition, which is free from a unfavorable whitish coloration in ceramic color printing and which is excellent in a silver print coloration, is presented. A glass coated with a heat reflecting colored film, obtained by heat treatment of a glass having a first layer containing iron oxide, chromium oxide and nickel oxide and a second layer containing cobalt oxide, laminated sequentially by a sputtering method, on one side of a glass substrate.Type: ApplicationFiled: August 28, 2003Publication date: March 11, 2004Applicant: Asahi Glass Company, LimitedInventors: Takashi Sugiyama, Eiichi Ando
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Publication number: 20040043226Abstract: A sputter coated article is provided with improved mechanical durability (e.g., pre-HT scratch resistance) and/or thermal stability by sputtering at least one Ag inclusive layer in an atmosphere including at least O2 gas. For instance, in certain example embodiments an Ag inclusive target may be sputtered in an atmosphere including a combination of Ar and O2 gas. In certain embodiments, this enables the resulting AgOx infrared (IR) reflecting layer to better adhere to adjacent contact layer(s).Type: ApplicationFiled: September 16, 2002Publication date: March 4, 2004Inventors: Ronald E. Laird, George Neuman, Philip J. Lingle, Jean-Marc Lemmer, Keith H. Schillinger
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Publication number: 20040005467Abstract: A coated article is provided so as to have a fairly high visible transmission (TY or Tvis) to sheet resistance (Rs) ratio (i.e., a ratio Tvis/Rs). The higher this ratio, the better the coated article's combined functionality of providing for both good solar performance (e.g., ability to reflect and/or absorb IR radiation) and high visible transmission. In certain example embodiments, coated articles herein may be heat treatable. Coated articles herein may be used in the context of insulating glass (IG) window units, architectural or residential monolithic window units, vehicle window units, and/or the like.Type: ApplicationFiled: March 27, 2003Publication date: January 8, 2004Applicant: Guardian Industries Corp.Inventors: George Neuman, Philip J. Lingle, Ronald E. Laird, Thomas A. Seder, Grzegorz Stachowiak
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Patent number: 6666958Abstract: A method for making a dry plating built-up film comprises providing silicon carbide as a starting source and subjecting to dry plating while changing a concentration of a reactive gas continuously or intermittently to deposit and form, on a substrate, a thin film having different refractive indices along its thickness. A method for making a sputter built-up film is also described, which comprising providing silicon carbide as a target and subjecting to sputtering while changing making electric power against the target continuously or intermittently to deposit and form a thin film having different refractive indices along its thickness.Type: GrantFiled: September 28, 1999Date of Patent: December 23, 2003Assignee: Bridgestone CorporationInventors: Masato Yoshikawa, Shingo Ohno, Sho Kumagai
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Patent number: 6663753Abstract: A substrate is coated with a low-E coating system including at least one infrared (IR) reflective layer. A diamond-like carbon (DLC) inclusive protective coating system (e.g., including at least one highly tetrahedral amorphous carbon (ta-C) inclusive layer having sp3 carbon—carbon bonds) is provided on the substrate over at least the IR reflective layer in order to make the low-E coating system scratch resistant, abrasion resistant, and generally mechanically durable. The DLC inclusive protective coating system may be hydrophobic, hydrophillic, or neutral in different embodiments of the invention. Optionally, at least one fluoro-alkyl silane (FAS) compound inclusive layer may be provided on the substrate over at least one of the DLC inclusive layer(s) in hydrophobic embodiments in order to increase contact angle &thgr; of the coated article.Type: GrantFiled: June 20, 2002Date of Patent: December 16, 2003Assignee: Guardian Industries Corp.Inventors: Vijayen S. Veerasamy, Rudolph Hugo Petrmichl, Scott V. Thomsen
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Publication number: 20030228472Abstract: The invention provides low solar reflectance, low-emissivity coatings. The invention provides a monolithic pane bearing a low solar reflectance, low-emissivity coating. Further, the invention provides an insulating glass unit bearing a low solar reflectance, low-emissivity coating. Finally, the invention provides methods of producing coated substrates by depositing low solar reflectance, low-emissivity coatings.Type: ApplicationFiled: April 25, 2003Publication date: December 11, 2003Inventors: Wayne L. Hoffman, Eric Eby
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Patent number: 6645352Abstract: A sputtering target made of AgxMayMbz or CuxMayMbz, where x>50 at % and Ag or Cu are a first metal, Ma is a second metal and Mb is a third metal is used in a method for manufacturing data storage disks. The method of manufacture includes providing a substrate, providing a spacer layer of a material transmitting light of a selected wavelength onto a surface of the substrate, applying a first layer of a first metal alloy between the substrate and spacer layer, providing a second layer of a second metal alloy on the spacer layer, and depositing the first and second metal alloys so that one of the first and second layers is semi-transparent with respect to the light. The first and second alloys have at least one common metal provided in particular fractions of the alloys.Type: GrantFiled: November 26, 2001Date of Patent: November 11, 2003Assignee: Unaxis Balzers AktiengesellschaftInventors: Helfried Weinzerl, Dubs Martin
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Publication number: 20030201164Abstract: The invention disclosed is a process for fabrication of IR-transparent electrically conductive metal oxide, such as copper aluminum oxide (CuAlxOy), by reactive magnetron co-sputtering from high purity metal targets, such as Cu and Al targets, in an argon/oxygen g as mixture. A preferred embodiment of the present invention is a process for making a metal oxide film having electrical conductivity and infrared transparency. Preferably, the substrate is placed in an environment having argon and oxygen. The process comprises applying between about 0.15 to 10.0% oxygen partial pressure to a substrate and DC-sputter depositing a first layer of conductive metal ions onto the substrate. The first layer has a physical thickness of from about 13 to 20 angstroms. Next, Co-sputter depositing a second layer of infrared transparent delafossite metal oxide onto the first layer with the second layer having a physical thickness of from about 1500 to 5000 angstroms, thereby forming a layer pair.Type: ApplicationFiled: April 29, 2002Publication date: October 30, 2003Inventors: Linda F. Johnson, Mark B. Moran
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Publication number: 20030201165Abstract: A method of film deposition is disclosed, which eliminates the conventional problem that a coating film having a component concentration gradient in the thickness direction and thus having a boundary with a compositional gradient or a coating film in which two or more components coexist as a mixture thereof cannot be stably obtained by sputtering. In the method, two planar cathodes are closely arranged as a pair, and a voltage is applied thereto while alternately inverting the polarities thereof so that when a target A bonded to one of the cathodes is used as a negative electrode, then a target B bonded to the other cathode and differing to the target A in component is used as a positive electrode. The targets A and B are simultaneously bombarded with positive ions while passing a substrate in front of the targets so as to cross the cathodes.Type: ApplicationFiled: April 2, 2003Publication date: October 30, 2003Applicant: NIPPON SHEET GLASS CO., LTD.Inventors: Toshiaki Anzaki, Etsuo Ogino, Takayuki Toyoshima