Abstract: Embodiments of the present techniques provide electrolyzers made using thermoformed electrode assemblies and diaphragm assemblies. Each electrode assembly is made from two plastic rings and an electrode plate using a twin sheet thermoforming technique. A first plastic ring is laid in a mold having the appropriate shape to form the electrode assembly. The electrode plate is laid on top of the first plastic ring and is generally centered on the ring. The second plastic ring is laid over the electrode plate, and is generally centered over the electrode plate. The plastic is heated to soften the plastic, and a vacuum is pulled on the mold to pull the softened plastic into the shape of the mold. The mold is closed over the assembly to seal the two plastic rings together. After cooling, the molded part may be removed, resulting in a hollow plastic rim surrounding an electrode plate.

Abstract: A high-pressure hydrogen producing apparatus includes a first cell device and a second cell device. The first cell device includes an electrolyte membrane, an anode electrode catalyst layer and an anode current collector provided on a first surface of the electrolyte membrane, and a cathode electrode catalyst layer and a cathode current collector provided on a second surface of the electrolyte membrane. The second cell device includes an electrolyte membrane, an anode current collector provided on a first surface of the electrolyte membrane of the second cell device, and a cathode current collector provided on a second surface of the electrolyte membrane of the second cell device.

Abstract: An apparatus to produce high purity hydrogen and electricity is disclosed in one embodiment of the invention as including a fuel cell configured to convert the chemical energy of a fuel to electricity and heat. An electrolyzer cell is placed in electrical and thermal communication with the fuel cell and is configured to electrolyze an oxygen-containing compound, such as steam or carbon dioxide, using the electricity and heat generated by the fuel cell. In selected embodiments, the fuel cell and electrolyzer cell are physically integrated into a single electrochemical cell stack.

Abstract: A carbon dioxide negative method of manufacturing renewable hydrogen and trapping carbon dioxide from the air or gas streams is described. Direct current renewable electricity is provided to a water electrolysis apparatus with sufficient voltage to generate hydrogen and hydroxide ions at the cathode, and protons and oxygen at the anode. These products are separated and sequestered and the base is used to trap carbon dioxide from the air or gas streams as bicarbonate or carbonate salts. These carbonate salts, hydrogen, and trapped carbon dioxide in turn can be combined in a variety of chemical and electrochemical processes to create valuable carbon-based materials made from atmospheric carbon dioxide. The net effect of all processes is the generation of renewable hydrogen from water and a reduction of carbon dioxide in the atmosphere or in gas destined to enter the atmosphere.

Abstract: Electrochemical cell comprises, in one embodiment, a proton exchange membrane (PEM), an anode positioned along one face of the PEM, and a cathode positioned along the other face of the PEM. An electrically-conductive, compressible, spring-like, porous pad for defining a fluid cavity is placed in contact with the outer face of the cathode or the outer face of the anode. The porous pad comprises a particulate or mat of one or more doped- or reduced-valve metal oxides, which are bound together with one or more thermoplastic resins.

Abstract: An electrolyzed water production apparatus and method safely and simply produce electrolyzed water having a sterilizing action, having a physiologically neutral pH value, and, in addition, simultaneously with strong acidic electrolyzed water and strong alkaline electrolyzed water depending upon the structure. The electrolyzed water production apparatus has an electrolyzer tank with an end that receives or stores raw water, and a power supply. The interior portion of the electrolyzer tank is partitioned by a plurality of diaphragms into a plurality of regions. An anode and a cathode (constituting an electrode pair) are positioned on either side of the diaphragm. In a certain region of the electrolyzer tank, an anode and a cathode are arranged so as to face each other without a diaphragm sandwiched between them. When raw water for electrolysis is electrolyzed, electrolyzed water having a desired pH of a neutral range is produced during electrolysis.

Abstract: A method for concentrating dilute sulfuric acid involves feeding dilute sulfuric acid through at least two electrolytic cells depolarized by sulfur dioxide, and through a cation conductive membrane separating the cathode and anode sides in the electrolytic cell. Also provided is an apparatus for concentrating sulfuric acid, wherein at least a first electrolytic cell is in fluid communication with a second electrolytic cell, and wherein a cation conductive membrane separates the cathode and anode sides in the electrolytic cells.

Abstract: An electrochemical reactor comprises at least one electrolytic cell, each cell is divided by a membrane (12) into two electrode chambers (7, 8), each one is crossed by flows of liquid and each having at least a corresponding electrode (13, 14). Both the electrodes (13, 14) have one own face directly in contact with the membrane (12) and have a plurality of openings (21) for the passage of the liquid. Each electrode (13, 14) is provided with one or more contact means (15) for the power supply.

Abstract: A unitized electrolyzer apparatus for generating hydrogen gas at high pressure. According to one embodiment, the apparatus includes a pressure-containment vessel, a water electrolyzer stack, and a water supply. The water electrolyzer stack is mounted on or in the vessel and is used to generate hydrogen gas for containment in the vessel at high pressure. The water supply is contained within the vessel, the water supply being fluidly coupled to the water electrolyzer stack to provide a cathode feeding of water to the water electrolyzer stack.

Abstract: An electrolyzing system for electrolyzing a brine solution of water and an alkali salt to produce acidic electrolyzed water and alkaline electrolyzed water is provided. The system includes an internal chamber for receiving the brine solution and two electrolyzer cells immersed in a brine bath. Each electrolyzer cell includes an electrode, at least one ion permeable membrane supported relative to the electrode to define a space communicating between a fresh water supply and a chemical outlet into which brine enters only through the membrane. One of the electrodes is coupled to a positive charging electrical supply and the other to a negative charging electrical supply.

Abstract: A PEM based water electrolysis stack consists of a number of cells connected in series by using interconnects. Water and electrical power (power supply) are the external inputs to the stack. Water supplied to the oxygen electrodes through flow fields in interconnects is dissociated into oxygen and protons. The protons are transported through the polymer membrane to the hydrogen electrodes, where they combine with electrons to form hydrogen gas. If the electrolysis stack is required to be used exclusively as an oxygen generator, the hydrogen gas generated would have to be disposed off safely. The disposal of hydrogen would lead to a number of system and safety related issues, resulting in the limited application of the device as an oxygen generator. Hydrogen can be combusted to produce heat or better disposed off in a separate fuel cell unit which will supply electricity generated, to the electrolysis stack to reduce power input requirements.

Abstract: A water electrolysis apparatus is formed by stacking a plurality of unit cells. Each unit cell includes a membrane electrode assembly, and an anode separator and a cathode separator which sandwich the membrane electrode assembly therebetween. The anode separator has a plurality of inlet joint channels in fluid communication with a water supply passage, and a plurality of outlet joint channels in fluid communication with a discharge passage. The water supply passage has an inner wall surface at which the inlet joint channels are open, and an outer wall surface which faces the inner wall surface, the inner wall surface and the outer wall surface jointly forming an opening of an oblong cross-sectional shape.

Abstract: Method and apparatus for controlling two phase flow in electrolytic cells. The present invention is directed to any electrolytic cell, including but not limited to upflow electrolytic cells that comprise parallel electrodes in a vertical orientation. Fluid control strips are preferably added between the anode and cathode electrodes to control flow of fluid and gas bubbles generated between the electrodes in order to avoid the detrimental effects of gas bubbles on the conductivity of the fluid solution, and thereby increase production and operational efficiency of the electrolytic cell.

Abstract: Electrolysis cell in the constructive form of single elements, intended for instance for the production of chlorine, hydrogen and/or caustic soda and designed in such a way that the portion of inactive membrane surface is minimised thanks to an optimised flange type so that the ratio between the flange surface of a semi-shell and the active membrane surface can be set to less than 0.045, neither the semi-shells nor the membrane being provided with bores or recesses for accommodating the clamping members.

Abstract: An ion exchange membrane electrolyzer is provided, which is characterized in that a current is passed through at least one electrode in contact with a plate spring member formed at a portion of an electrode retainer member parallel with a flat plate form of electrode chamber partition, wherein said electrode retainer member is joined at a belt junction to the flat plate form of electrode chamber partition with a space between them, said electrode is provided with a floating mount means at a portion thereof other than a portion of contact with the plate spring member, and said floating mount means is provided with an engaging portion that is engaged with a fixed engaging member to enable said electrode to move in a perpendicular direction to an electrode surface and in a range of displacement of said plate spring member.

Abstract: The invention relates to chemical engineering, in particular to devices for electrolyzing aqueous solutions of alkali or alkali-earth metal chlorides and for obtaining gaseous electrolytic products such as chlorine and oxygen. It can be used for water purifying and disinfecting processes and for electrochemically producing some chemical products. The inventive device includes at least one electrochemical reactor (1) comprising from 2 to 16 electrochemical cells. Lines for supplying and discharging cathode and anode chambers are embodied in the form of pipelines having an inner diameter equal to or less than 0.5 of the interelectrode distance and lengths which are equal to or greater than 2 Ld, wherein the interelectrode distance is an anode-to-cathode distance and Ld is the cathode length.

Abstract: A water treatment system is disclosed having electrolytic cell for liberating hydrogen from a base solution. The base solution may be a solution of brine for generating sodium hypochlorite, or potable water to be oxidized. The cell has first and second opposing electrode endplates held apart from each other by a pair of supports such that the supports enclose opposing sides of the endplates to form a cell chamber. One or more inner electrode plates are spaced apart from each other in the cell chamber in between the first and second electrode plates. The supports are configured to electrically isolate the first and second electrode plates and the inner electrode plates from each other. The first and second electrode plates are configured to receive opposite polarity charges that passively charge the inner electrode plates via conduction from the base solution to form a chemical reaction in the base solution as the base solution passes through the cell chamber.

Abstract: A low energy method and system of removing H+ from a solution in an electrochemical cell wherein on applying a voltage across an anode in a first electrolyte and a cathode in second electrolyte, H+ are transferred to second electrolyte through a proton transfer member without forming a gas, e.g., oxygen or chlorine at the electrodes.

Abstract: An electrochemical cell stack and method are provided with use the generated hydrogen gas to pressurize a chamber. The electrochemical cell stack includes a plurality of cells mounted between a first static endplate and a dynamic endplate. A pressure chamber is formed between a second static endplate and the dynamic endplate. The chamber acts upon a dynamic endplate to increase the loading on a plurality of cells as the generated gas pressure increases.

Abstract: A low energy water treatment system and method is provided. The system has at least one electrodialysis device that produces partially treated water and a brine byproduct, a softener, and at least one electrodeionization device. The partially treated water stream can be softened by the softener to reduce the likelihood of scale formation and to reduce energy consumption in the electrodeionization device, which produces water having target properties. At least a portion of the energy used by the electrodeionization device can be generated by concentration differences between the brine and seawater streams introduced into compartments thereof. The brine stream can also be used to regenerate the softener.

Abstract: A distributing element for an electrolyte percolating-type electrochemical cell comprises an external feeding manifold and an assembly formed by a gas diffusion electrode, a percolator and optionally an on-exchange membrane. The element is particularly suitable for chlor-alkali electrolysis cells and alkaline fuel cells. It is also disclosed a method for retrofitting membrane electrochemical cells by inserting the distributing element of the invention therein.

Abstract: Systems are described for the “on-site” production of substantial amounts of carbon dioxide and hydrogen. The systems include a stack of multiple electrochemical cells, which decompose organic carboxylated compounds into CO2 and H2 without leaving any residue. From a bench-top small generator, producing about 1 lb of CO2 per day to a large-scale generator producing 1 ton of CO2 per day, the process is essentially identical. Oxalic acid, either anhydrous or in its dihydrate form, is used to efficiently generate the gases. The energy required is less than 0.3 Kilowatt-hours per lb of CO2 generated. Individual cells operate at less than 1.2 volts at current densities in excess of 0.75 amps/cm2. CO2 production rates can be controlled either through voltage or current regulation. Metering is not required since the current sets the gas production rate. These systems can competitively replace conventional compressed CO2 gas cylinders.

Abstract: An electrolyser including a stack of a plurality of elementary electrolysis cells, each cell including a cathode, an anode, and an electrolyte provided between the cathode and the anode. An interconnection plate is interposed between each anode of an elementary cell and a cathode of a following elementary cell, the interconnection plate being in electric contact with the anode and the cathode. A pneumatic fluid is to be brought into contact with the cathodes, and the electrolyser further includes a mechanism ensuring circulation of the pneumatic fluid in the electrolyser for heating it up before contacting the same with the cathodes.

Abstract: There is provided an ion exchange membrane electrolyzer, wherein at least one electrode is energized by coming into contact with plate spring bodies formed on the electrode side of an electrode holding member forming a space with an electrode chamber partition bonded to a plate-like electrode chamber partition by a strip-like bonded portion, the electrode has a connected portion extending from a plane parallel to the ion exchange membrane toward the electrode holding member side in a direction perpendicular to the electrode plane, the connected portion is provided with an engaging opening extending in a direction perpendicular to the electrode plane, and the engaging opening engages with an engaging member, permitting the electrode to move in a direction perpendicular to the electrode plane within the displacement range of the plate spring bodies.

Abstract: Methods, apparatus, and applications for the on-site production of hydrogen peroxide are described. An embodiment of the apparatus comprises at least one anolyte chamber coupled to at least one anode, at least one catholyte chamber, wherein the at least one catholyte chamber is coupled to at least one cathode, at least one anode membrane and at least one cathode membrane, wherein the anode membrane is adjacent to the at least one anode, wherein the cathode membrane is adjacent to the at least one cathode, at least one central chamber disposed between the at least one anolyte chamber and the at least one catholyte chamber. Hydrogen peroxide is produced by reduction of an oxygen-containing gas at the cathode.

Abstract: A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.

Abstract: A fuel stabilization device reduces the amount of dissolved oxygen within a fuel stream utilizing the combination of an electrochemical device to produce hydrogen gas and water and a catalyst that promotes the formation of water utilizing dissolved oxygen within the fuel and hydrogen gas generated by the electrochemical device.

Abstract: Cells can include variable volumes defined between a flexible structure, such as a polymer layer, and a support surface, with the flexible structure and support surface being attached in a first region that surrounds a second region in which they are unattached. Various adhesion structures can attach the flexible structure and the support surface. When unstretched, the flexible structure can lie in a flat position on the support surface. In response to a stretching force away from the support surface, the flexible structure can move out of the flat position, providing the variable volume. Electrodes, such as on the flexible structure, on the support surface, and over the flexible structure, can have charge levels that couple with each other and with the variable volume. A support structure can include a device layer with signal circuitry that provides a signal path between an electrode and external circuitry. One or more ducts can provide fluid communication with each cell's variable volume.

Abstract: Electrolysis cell comprises, in one embodiment, a proton exchange membrane (PEM), an anode positioned along one face of the PEM, and a cathode positioned along the other face of the PEM. An electrically-conductive, compressible, spring-like, porous pad for defining a fluid cavity is placed in contact with the outer face of the cathode. The porous pad comprises a mat of carbon fibers bound together with one or more, preferably thermoplastic, resins, the mat having a density of about 0.2-1.5 g/cm3. Cell frames are placed in peripheral contact with the metal screen and the compression pad for peripherally containing fluids present therewithin. Electrically-conductive separators are placed in contact with the metal screen and the compression pad for axially containing fluids present therewithin. A plurality of the cells may be arranged in series in a bipolar configuration without requiring a separate compression pad between cells (for gas pressure differentials up to about 400 psi or greater).

Abstract: The invention relates to an electrode assembly for the electrochemical treatment of liquids with a low conductivity. Said assembly comprises electrodes (1, 2), between which a polymer solid electrolyte (3) is situated. The electrodes are pressed against one another by means of a compression device (9, 10; 91) and are configured in such a way that the assembly can be traversed by the liquid. To produce said assembly simply and to ensure that it is flexible and easy to use, the compression device (9, 10; 91) is supported on the electrodes (1, 2).

Abstract: A cooking appliance comprising an electrolyzer which produces a combustible fuel, a burner downstream from the electrolyzer, and, an electrically heatable cooking surface on which food is receivable for cooking, the electrically heatable cooking surface being operable simultaneously with the electrolyzer.

Abstract: A pressure electrolyzer having an electrolytic cell block that contains a number of electrolytic cells combined to form a stack, each electrolytic cell having an anode and a cathode. The electrolytic cell block has a sealed housing formed by a number of stacked cell frames of the electrolytic cells, the cell frames being composed at least partially of a material that is elastic at least in a longitudinal direction of the electrolytic cell block and seals adjacent cell frames from each other. End plates are provided so as to hold the electrolytic cell block in place between the end plates under compression of the elastic material. Each of the cell frames has a rigid element that runs in a circumferential direction of the frame so as to mechanically stabilize the cell frame.

Abstract: An electrolytic cell 1 comprises electrolysis chambers 5 and 6 arranged opposite to each other through a diaphragm 11, raw water feed means 8 and 7, electrodes 12a and 12b arranged in the electrolysis chambers 5 and 6 in a manner sandwiching the diaphragm 11, and electrolyzed water take-out means 9 and 10 for taking out electrolyzed water obtained by electrolyzing raw water. The electrolytic cell 1 comprises a membrane-electrode assembly 2 formed so as to cause the electrodes 12a and 12b to respectively adhere to both surfaces of the diaphragm 11, mesh current collectors 13 and 14 respectively arranged opposite to the electrodes 12a and 12b, and a plurality of protrusions 15 and 16.

Abstract: It is herein described an electrowinning cell with a spouted bed electrode of growing metallic beads, separated by a semi-permeable diaphragm and suitable for being assembled in a stack in a modular arrangement.

Abstract: Embodiments of the invention generally provide a fluid delivery system for an electrochemical plating platform. The fluid delivery system is configured to supply multiple chemistries to multiple plating cells with minimal bubble formation in the fluid delivery system. The system includes a solution mixing system, a fluid distribution manifold in communication with the solution mixing system, a plurality of fluid conduits in fluid communication with the fluid distribution manifold, and a plurality of fluid tanks, each of the plurality of fluid tanks being in fluid communication with at least one of the plurality of fluid conduits.

Abstract: An electrochemical cell having an inner electrode mounted coaxially within an outer, electrode, with a tube mounted coaxially between them to define annular passageways for liquid flow in separate streams of the cell between respective pairs of inlet/outlet ports. A cup-shaped fitting having a stepped-down internal diameter is fastened to the inner electrode at the end of the cell with the outer electrode at the mouth of the fitting.

Abstract: A gas evolving bipolar electrolysis system is provided which includes multiple cells. Each cell further includes a cathode, an anode, at least one inlet and at least one outlet for flow of electrolyte and the cathode and the anode are configured to maintain a variable interelectrode gap between the cathode and the anode. In some embodiments, the cell includes a membrane disposed between the electrodes and in some other embodiments the electrodes are coated with electrocatalysts configured to provide uniform current density on the electrode surface.

Abstract: It is described a bipolar plate consisting of a single wall and a perimetrical sealing frame obtained by folding and provided with a planar abutment surface for the frame-to-wall welding. The wall is further provided with projections on one face thereof preferably obtained by moulding, and with supports on the other face consisting of sheet strips housed in the recesses formed by the concave part of the projections. The projections substantially extend along the entire length of the bipolar plate. The projections and supports are connected to electrodes or current distributors. The projections, the supports, the single wall and the perimetrical frame are made of the same metal or alloy. The electrode or current distributor supported by the projections, the same projections and the supports are welded together by a single pass of arc-welding or preferably laser-welding.

Abstract: A gasket having the form of a frame is provided with a curved portion at an inner or outer periphery thereof. When used in combination with a similarly configured gasket, the two gaskets may together, upon compression, form a pinch seal. The curved portion may be provided with a chemically resistant material.

Abstract: The invention relates to a diaphragm electrolytic cell, for the production of chlorine and caustic soda having superimposed modules, and a method for increasing the electrodic surface of a diaphragm electrolytic cell constituted by a module of interdigitated anodes and cathodes which foresees an additional cell module having the same geometry as that of the original cell. The additional module is hydraulically connected in series and electrically connected in parallel to the existing module.

Abstract: Water electrolysis device determining stable isotopic composition of water and a water electrolysis method for stable isotopic composition of water capable of analyzing many samples easily, safely and at low cost in very short time, and rapidly analyzing 17O are provided. The water electrolysis device performing mass spectrometry of hydrogen or oxygen stable isotopic composition includes a proton exchange membrane of fluorocarbon polymer plated non-electrolytically with platinum, iridium, rhodium or iridium-rhodium alloy, and a cathode and an anode of porous titanium plated with platinum and sandwiching the proton exchange membrane, wherein water electrolyzes by introduction into the anode side chamber and supplying DC current between the anode and the cathode, and oxygen gas generated at the anode and hydrogen gas generated at the cathode respectively flows into an isotope ratio mass spectrometer.

Abstract: The invention relates to an electrolysis device for halogen gas production from an aqueous alkali halide solution in several plate-type electrolysis cells stacked and arranged side by side, with electrical contacts, each of the cells with a housing consisting of two half-shells made of electrically conductive material, said housing being equipped with devices for feeding electrolytic current and the electrolysis plant reactants and devices for discharging electrolytic current and discharging the electrolysis products, with anodic electrode, cathodic electrode and a membrane arranged therebetween, built-in components being fitted in at least one of the two half-shells and permitting a defined increase in the liquid level and thus minimizing the remaining gas volume accordingly.

Abstract: A modular electrochemical cell having two interchangeable assemblies each with a support structure defining a cylindrical recess and having a fitting for connecting a pipe to the assembly. A disc-shaped electrode is arranged inside each recess and the assemblies are arranged relative to each other so that their respective electrodes face each other. A modular insert is inserted between the assemblies to define an open space between the electrodes and to distribute fluid to a plurality of openings spaced from each other along an edge of this open space. Securing members secure together the two assemblies and the modular insert, and passages in the support structures convey fluid between the fittings and the modular insert.

Abstract: A structural component for electrolytic cells of an electrochemical reactor of the filter-press type, comprising a frame (6) supporting its corresponding functional element (7, 7a), a bipolar sheet or a diaphragm, respectively.

Abstract: The present invention provides a bonded membrane-electrode assembly for electrolysis of water, which enables the generation of hydrogen capable of being used as a fuel for a fuel cell by electrolyzing water, and a water electrolyzer constructed using the bonded membrane-electrode assembly, so that hydrogen can be produced safely. The bonded membrane-electrode assembly includes a solid polymer electrolyte membrane, an oxygen electrode bonded to one of sides of the solid polymer electrolyte membrane, a hydrogen electrode bonded to the other side of the solid polymer electrolyte membrane. The oxygen electrode includes a porous sheet-shaped carbon element plated with iridium and coated with a mixture containing carbon and a resin for a solid polymer membrane.

Abstract: The invention discloses a pressure electrolyzer comprising a pressure vessel (2) and an electrolytic-cell block (3) arranged in the pressure vessel (2) and containing a plurality of electrolytic cells (4) combined in the form of a stack. The electrolytic cells (4) in each case contain anodes (11) and cathodes (12), and an electrolyte-circuit system is provided for supplying an anolyte to the anodes (11) and for supplying a catholyte to the cathodes (12), and wherein the electrolytic-cell block (3) comprises a housing (5) which is sealed relative to the interior of the pressure vessel (2). The invention provides that the housing (5) of the electrolytic-cell block (3), together with the pressure vessel (2), forms at least two chambers (7, 8) separated from each other, which constitute a part of the electrolyte-circuit system and which are defined relative to the electrolytic cells (4) by the housing (5) and relative to the atmosphere by the pressure vessel (2).

Abstract: A pressure electrolyzer having a pressure reservoir, an electrolytic cell block containing a number of electrolytic cells and positioned in the pressure reservoir, the electrolytic cells each containing anodes and cathodes, and an electrolyte circulatory system for supplying electrolyte to the anodes and cathodes. The circulatory system includes an oxygen separator operative to separate gaseous oxygen formed during operation of the pressure electrolyzer and a hydrogen separator operative to separate gaseous hydrogen formed during operation of the pressure electrolyzer, and a store of an inert gas, to inert the pressure electrolyzer when it is switched off. The store of inert gas is supplied to the oxygen separator. The electrolyte circulatory system further includes a connecting line arranged so that a part of the electrolyte can be pushed out of the hydrogen separator when the inert gas is applied to the oxygen separator so as to displace the gaseous hydrogen.

Abstract: A composite proton exchange membrane and method of manufacturing the same. The composite proton exchange membrane comprises a proton exchange membrane which has been modified by replacing membrane protons in desired areas of the membrane with a cationic polymer. The cationic polymer is preferably formed by introducing a quaternary salt monomer into the membrane and then effecting the polymerization of the monomer. The modified areas of the proton exchange membrane exhibit increased strength, reduced water and gas permeability, reduced proton conductivity and reduced acidity. Accordingly, by modifying the periphery of the membrane, one can obtain an integral sealing edge for the membrane, and by modifying certain interior regions of the membrane, one can divide the membrane into a plurality of sealed segments.

Abstract: Electrolysis cell comprises, in one embodiment, a proton exchange membrane (PEM), an anode positioned along one face of the PEM, and a cathode positioned along the other face of the PEM. A multi-layer metal screen for defining a first fluid cavity is placed in contact with the outer face of the anode, and an electrically-conductive, compressible, spring-like, porous pad for defining a second fluid cavity is placed in contact with the outer face of the cathode. The porous pad comprises a mat of carbon fibers bound together with one or more, preferably thermoplastic, resins, the mat having a density of about 0.2–1.5 g/cm3. Cell frames are placed in peripheral contact with the metal screen and the compression pad for peripherally containing fluids present therewithin. Electrically-conductive separators are placed in contact with the metal screen and the compression pad for axially containing fluids present therewithin.

Abstract: An improved apparatus for treating plate-like workpieces with a designated chemical solution, including printed circuit boards, includes: (1) a tray for holding the chemical solution, with the tray having an open top which is configured to receive a horizontally-oriented workpiece, with the tray having a top edge with a portion of the edge forming a dam over which the solution may flow and an opening in its lower portion where the solution can enter the tray, (2) a reservoir tank situated below the tray, (3) a feed line connecting the reservoir tank and tray opening, (4) a drain that returns the solution that overflows the tray top edge to the reservoir tank, and (5) a pump that circulates the solution from the tank to the tray and over the horizontally situated workpiece.