With Feeding And/or Withdrawal Means Patents (Class 204/269)
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Patent number: 6132572Abstract: An apparatus and method of producing water for deodorization and cleaning applications is disclosed. In the apparatus or an electrolyzer, anode and cathode units are alternately arranged and are separated from each other by ion exchange membranes, and individually form a unit cell. Two end plates are attached to both ends of the electrolyzer. The inlet end plate has two water inlets, while the outlet end plate has two water outlets. In an electroanalysis of water in the apparatus, the current for the apparatus is set to a level of not higher than 100 A, while the voltage for the apparatus is set to a level of not higher than 100 V. In addition, the finally processed water of this invention has an acidity (pH) ranged from 2.0 to 12 and an oxidation/reduction electric potential ranged from -900 to +1180.Type: GrantFiled: September 17, 1998Date of Patent: October 17, 2000Assignee: Kyungwon Enterprise Co., Ltd.Inventor: Hee Jeong Kim
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Patent number: 6113779Abstract: An apparatus for water treatment, and in particular for electrical water purification in combination with a filtering apparatus for providing purified water for drinking and other application common in the home, farm or business. Metal, hydrogen and oxygen ions are introduced into water to be treated by using plasma fused iridium coated titanium electrodes and copper alloy electrodes. After ionizing the water to be purified, the water is then filtered in a filter tank which contains layers of various filtration media, including granular activated carbon.Type: GrantFiled: February 13, 1998Date of Patent: September 5, 2000Assignee: Des Moines Five, Inc.Inventor: Thomas M. Snee
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Patent number: 6110332Abstract: A three-dimensional (3-D) T-load for planar microchannel arrays for electrophoresis, for example, which enables sample injection directly onto a plane perpendicular to the microchannels' axis, at their ends. This is accomplished by forming input wells that extend beyond the ends of the microchannel thereby eliminating the right angle connection from the input well into the end of the microchannel. In addition, the T-load input well eases the placement of electrode in or adjacent the well and thus enables very efficient reproducible electrokinetic (ek) injection. The T-load input well eliminates the prior input well/microchannel alignment concerns, since the input well can be drilled after the top and bottom microchannel plates are bonded together. The T-load input well may extend partially or entirely through the bottom microchannel plate which enables more efficient gel and solution flushing, and also enables placement of multiple electrodes to assist in the ek sample injection.Type: GrantFiled: October 26, 1998Date of Patent: August 29, 2000Assignee: The Regents of the University of CaliforniaInventor: Stefan P. Swierkowski
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Patent number: 6099703Abstract: Water cleaning device with at least one reactor device (4) for electrolytic cleaning of polluted water, assembled of one or more anodes (1a) and cathodes (2a), one flotation device (14, 15) and one device for handling sludge (23, 24, 18). The water flow inside and just outside (downstream) of the electrochemical reactor (4) is turbulent. The turbulence is created by one or more mechanical devices which affect the flow pattern.Type: GrantFiled: September 11, 1998Date of Patent: August 8, 2000Assignee: Cleaner Technology ASInventors: Ulf Syversen, Jan Sundell, Ingunn Saur, Synnove Rubach, Gudolf Kjaerheim
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Patent number: 6083376Abstract: An electrochemical reaction assembly and methods of inducing electrochemical reactions, such as for deposition of materials on semiconductor substrates. The assembly and method achieve a highly uniform thickness and composition of deposition material or uniform etching or polishing on the semiconductor substrates by retaining the semiconductor substrates on a cathode immersed in an appropriate reaction solution wherein a wire mesh anode rotates about the continuous moving cathode during electrochemical reaction.Type: GrantFiled: July 28, 1999Date of Patent: July 4, 2000Assignee: Micron Technology, Inc.Inventors: Salman Akram, David R. Hembree
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Patent number: 6080290Abstract: The present invention relates to electrochemical cells and electrochemical systems using a one piece or unitary electrode plate hereinafter also referred to as a double electrode plate (DEP) which serves to electrically connect two adjacent cell compartments and wherein the current flow in the electrodes is parallel to the working face of the electrode. In the cell designs disclosed herein the cells are assembled as a contiguous stack of cells (cell stack) appearing similar to a filter press where the electrical connections between adjacent cells are made using the double electrode plate. In one aspect of the invention there is provided a mono-polar multiple stack electrolyser (MSE) using double electrode plates wherein the planar double electrode plates connect cells in adjacent cell stacks. The mono-polar characteristics of the cell are maintained by the presence of an air gap isolating each adjacent stack of cells connected by each double electrode plate.Type: GrantFiled: December 31, 1997Date of Patent: June 27, 2000Assignee: Stuart Energy Systems CorporationInventors: Andrew T. B. Stuart, Raynald G. LaChance, Chris T. Bowen
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Patent number: 6077411Abstract: An apparatus for forming a zinc oxide film on a sheet substrate including a tank containing an aqueous electrolytic solution containing at least nitrate ions and zinc ions, conveyer means for continuously feeding and conveying an elongated electroconductive sheet substrate having two major surfaces in a direction while dipping a lengthwise portion of the sheet substrate in the electrolytic solution, a counter electrode immersed in the electrolytic solution so as to be opposite to the lengthwise portion of the sheet substrate, and a power supply disposed so as to pass a current between the sheet substrate and the counter electrode, wherein the conveyer means include a plurality of rollers and an endless belt wound about the rollers so as to have a conveyer surface contacting and covering one of the major surfaces of the lengthwise portion of the sheet substrate dipped in the electrolytic solution while moving together with the sheet substrate.Type: GrantFiled: January 16, 1998Date of Patent: June 20, 2000Assignee: Canon Kabushiki KaishaInventor: Tetsuro Nakamura
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Patent number: 6059942Abstract: Disclosed is an improved electrolytic cell 10 for the generation of low cost halogen biocidally active agent from an aqueous solution having a low halogen salt content for the use in the treatment of swimming pools and spas or other liquid effluents, especially those the fresh water swimming pools or spas. The electrolytic cell is used in line with pumps generally associated with the distribution of waters for swimming pools, spas or other facilities. The electrolytic cell has electrodes 11 made of a noble metal that are not directly in the path of the flow of the liquid.Type: GrantFiled: April 8, 1998Date of Patent: May 9, 2000Inventors: Ferman Richard Barnes, Deborah Barnes
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Patent number: 6045686Abstract: A process for the delacquering and detinning of a metal substrate is presented comprising the fully electrochemical removal of both an outer polymeric coating and an inner tin coating from a metal substrate. The disclosed method provides a clean metal substrate, and results in wastes which are easily disposed of with minimal cost and minimal environmental impact. In one embodiment, the present invention comprises a one-stage process for removing an outer polymeric coating and an inner tin coating from a metal substrate in a single electrolyte bath through electrolytic removal of both the polymeric and tin layers from the metal substrate. An electrically conductive container having the electrolyte bath therein acts as an anode in the process, and the removed tin is plated out on the cathode. In another embodiment, the present invention comprises a two-stage process for removing an outer polymeric coating and an inner tin coating from a metal substrate.Type: GrantFiled: December 15, 1997Date of Patent: April 4, 2000Assignee: The University of ConnecticutInventors: James M. Fenton, John E. Dresty, Jr., Richard Bodensteiner, Chunzhi He, Ramakrishnan Venkataraman, Jung-Chou Lin, Antonio J. Aldykiewicz, Jr.
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Patent number: 6033548Abstract: An electrochemical reaction assembly and methods of inducing electrochemical reactions, such as for deposition of materials on semiconductor substrates. The assembly and method achieve a highly uniform thickness and composition of deposition material or uniform etching or polishing on the semiconductor substrates by retaining the semiconductor substrates on a cathode immersed in an appropriate reaction solution wherein a wire mesh anode rotates about the continuous moving cathode during electrochemical reaction.Type: GrantFiled: July 28, 1997Date of Patent: March 7, 2000Assignee: Micron Technology, Inc.Inventors: Salman Akram, David R. Hembree
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Patent number: 6017461Abstract: An ion supply unit for a water system which is to have its contents purified includes a tank fed from a main water supply and an electrolytic ion generator including silver alloy electrodes. A pump circulates water from the tank through the ion generator and back into the tank at a rate of at least 1 L/s to gradually ionize the contents of the tank and generate a concentrate of silver-ion-laden water. An injector feeds the concentrate into the water system as required.Type: GrantFiled: February 23, 1998Date of Patent: January 25, 2000Inventors: Ernest Sydney Garvey, Randolph Euan Irvine Reid
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Patent number: 5980704Abstract: A system and method for accomplishing a plurality of combinatorial processes in parallel comprising a microelectronic and fluidic array (device array) having micron-sized reservoirs, connecting microchannels and reaction cells etched into a substrate. The device array is supported by a station which serves to interface and perform electro-optic measurements of material in the reaction cells of the device array. The device array incorporates a modular configuration with three distinct layers or plates. The device array comprises a top feedthru plate, a center distribution plate and a bottom cell plate. The three plates are stacked vertically and coupled together to form a liquid-tight seal. Reservoirs, microchannels and reactions cells are controllably etched onto the plates using traditional semiconductor fabrication techniques. The top feedthru plate serves as a cover for the device array and contains apertures selectively positioned above the reservoirs located in the center distribution plate.Type: GrantFiled: October 7, 1996Date of Patent: November 9, 1999Assignee: David Sarnoff Research Center Inc.Inventors: Satyam Choudary Cherukuri, Robert Richard Demers, Zhong Hui Hugh Fan, Aaron W. Levine, Sterling Edward McBride, Peter John Zanzucchi
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Patent number: 5976332Abstract: A turbine power system that includes a compressor for compressing a first medium, and an electrochemical converter in communication with the compressor and adapted to receive the first medium and a second medium. The converter is configured to allow an electrochemical reaction between the first and second mediums, thereby generating electricity and producing exhaust having a selected elevated temperature. The power system further includes a turbine in fluid communication with the electrochemical converter and adapted to receive the converter exhaust, such that the turbine converts the electrochemical converter exhaust into rotary energy and electricity. The system can further include a steam generator and a steam turbine that produces electricity. The electrochemical converter is utilized herein as an electrochemical combustor-replacement (ECCR) or as a fuel cell for combustor-replacement (FCCR).Type: GrantFiled: November 26, 1997Date of Patent: November 2, 1999Assignee: Ztek CorporationInventors: Michael S. Hsu, Ethan D. Hoag
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Patent number: 5954937Abstract: An electrically regeneratable electrochemical cell (30) for capacitive deionization and electrochemical purification and regeneration of electrodes includes two end plates (31, 32), one at each end of the cell (30). Two end electrodes (35, 36) are arranged one at each end of the cell (30), adjacent to the end plates (31, 32). An insulator layer (33) is interposed between each end plate (31, 32) and the adjacent end electrode (35, 36). Each end electrode (35, 36) includes a single sheet (44) of conductive material having a high specific surface area and sorption capacity. In one embodiment, the sheet (44) of conductive material is formed of carbon aerogel composite. The cell (30) further includes a plurality of generally identical double-sided intermediate electrodes (37-43) that are equidistally separated from each other, between the two end electrodes (35, 36).Type: GrantFiled: November 15, 1996Date of Patent: September 21, 1999Assignee: The Regents of the University of CaliforniaInventor: Joseph C. Farmer
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Patent number: 5928493Abstract: A process for the treatment of industrial waste water using electrocoagulation to effect separation of contaminants, which may include heavy metals, dyes, oils, fats, solvents, and salts. The process comprises passing waste water containing contaminants susceptible to electrocoagulation between pairs of electrodes within a reactor cell, energizing the electrodes with direct current, thereby breaking down and chemically altering contaminants in the electrolyzed water to form a sedimentable flocculate therein; and separating the flocculate from cleaned water. The invention also anticipates an apparatus for treating waste water which comprises: an electrocoagulation reactor cell having spaced-apart electrodes energized by direct current, a pump for passing industrial waste water through the reactor and between the electrodes, a de-foam tank, a mechanical clarifier, and a recessed-plate filter press.Type: GrantFiled: November 24, 1997Date of Patent: July 27, 1999Assignee: Kaspar Electroplating CorporationInventors: Paul E. Morkovsky, Douglas D. Kaspar, Jonathan M. Petru
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Patent number: 5901997Abstract: A transport device for conveying vertically oriented plate-like articles for chemical or electrolytic surface treatment, the device having clamping elements maintained in the manner of tongs, which can be actuated by means of a sliding body and a linkage mechanism for grasping a plate-like article. The linkage mechanism consists of two crank arms which are associated with each other and guided in such a way that the course of their movement consists of two sections, namely a spreading or clamping movement extending essentially horizontally for grasping and releasing the plate-like article to be held, and an essentially vertically extending lifting and lowering movement for dipping and removing the transport device in the respective treatment liquid for the plate-like article.Type: GrantFiled: June 26, 1997Date of Patent: May 11, 1999Assignee: Lea Ronal GmbHInventor: Reinhold Bayer
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Patent number: 5882502Abstract: An electrochemical apparatus and system for extracting and recovering metals from their compounds using electrochemical cells where the anolyte 10 is connected electrically to the catholyte 11 through an independent set of electrodes 13, 14 immersed in each electrolyte and connected to each other by a conductor 16. The specification details the application of this principle to commercial size cells and systems to extract metals from solutions, from ores in-situ, from ores in heaps and fixed beds, from fine metal concentrates dissolved either at the anode cell or in a separate leaching vessel. Alkaline electrolytes are also given for the extraction and recovery of nickel and copper from their oxide ores. A method for extracting gold from ores or residues is also included.Type: GrantFiled: September 25, 1996Date of Patent: March 16, 1999Assignee: RMG Services Pty Ltd.Inventor: Rodolfo Gomez
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Patent number: 5879632Abstract: The invention provides an apportioning system comprising a first apportioning chamber having a first outlet and fillable with liquid to a first defined level such that if liquid is added to fill the first apportioning chamber above the first defined level, then the extra fluid drains through the first outlet, an inlet channel that distributes liquid to the first apportioning chamber, and a first electrode-based pump for moving liquid in the first apportioning chamber out the first outlet.Type: GrantFiled: April 9, 1996Date of Patent: March 9, 1999Assignee: Sarnoff CorporationInventor: Robert Richard Demers
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Controlled and regulated conveying of flowable media with a gas evolution cell and a flow multiplier
Patent number: 5871632Abstract: Process and apparatus for conveying flowing substances with the aid of an electrochemical gas evolution cell whose cell current generates primarily a gas volume flow which secondarily causes the volume flow of a decomposer liquid into a catalytic decomposer and which thereby initiates a quantity flow of the decomposer gas which transports the flowable conveyed medium to the intended location.Type: GrantFiled: May 14, 1997Date of Patent: February 16, 1999Inventor: August Winsel -
Patent number: 5858199Abstract: An apparatus and method for separating and removing ionizable components dissolved in fluids, such as for example, water, by separating said ionizable substances into fractions by the action of electric current and of Coriolis force. Liquid containing ionizable components is continuously fed in and the purified solvent and the solute in a concentrated solution are continuously removed while the liquid is rotated. Compound centrifugal force or Coriolis force causes the concentrated solution to move to a location where it can be effectively and continuously removed as well as causes the depleted liquid to move to a separate location where it also can be effectively and continuously removed. The invention can operate in several modes, the modes being electrolytic and electrostatic. The invention allows for almost universal application to removal of ionizable components and provides a cost effective and energy efficient continuous process to do so.Type: GrantFiled: July 12, 1996Date of Patent: January 12, 1999Assignee: Apogee CorporationInventor: Joseph J. Hanak
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Patent number: 5855756Abstract: An electrorefining cell permits increased electrolyte flow rates while maintaining the slime layer at the bottom of the cell and on the anode faces substantially intact. The cell includes an inlet manifold located near the bottom of the cell and having a plurality of discharge orifices for the electrolyte solution. An inlet baffle shrouds the discharge orifices to regulate and direct the flow of electrolyte solution within the cell. The inlet baffle and the cell wall form an elongated slot that resides beneath the surface of the electrolyte solution. An analogous configuration is employed for electrolyte discharge to enable relatively high electrolyte flow into and out of the cell. The specific shape, size, and location of the inlet baffle and an outlet baffle may be selected to optimize the electrolyte flow characteristics of the cell.Type: GrantFiled: November 20, 1996Date of Patent: January 5, 1999Assignee: BHP Copper Inc.Inventor: Gerald C. Anzalone, III
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Patent number: 5843290Abstract: A contactless electrolytic polishing apparatus for manufacturing a lead frame having a smooth polished surface includes a polishing tank containing polishing solution and divided by partitions into a first cathode-containing vessel, a first solution-discharge vessel, a first anode-containing vessel, a second solution-discharge vessel, a second anode-containing vessel, a third solution-discharge vessel and a second cathode-containing vessel. A direct current is applied with ripples having a frequency of 40 to 120 Hz alternately to the anode and cathode in the electrolytic polishing tank filled with an electrolytic polishing solution so that the time for which the blank positioned between both electrodes functions as the anode may be at least 3.3 times longer than that for which it functions as the cathode. The blank is then plated with a metal by employing a customary method.Type: GrantFiled: January 31, 1997Date of Patent: December 1, 1998Assignee: Sumitomo Metal Mining Co., LimitedInventors: Yoshimaro Tezuka, Katsuhisa Tokunaga, Mitsuyuki Kakimoto, Shigeki Ogawa, Miyuki Tani, Satoshi Kobayashi, Kiyotaka Sasaki, Motoyuki Tomizawa
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Patent number: 5837109Abstract: The present invention relates to an apparatus for treating a strip such as a steel strip. The first object is to provide an electrode opening and closing mechanism having a simple construction. The second object is to uniform the flow of a solution around the electrode. The third object is to prevent causing irregularities in the treatment, caused by the variation of surface level of the solution between the electrodes. To attain the first object, one of the mutually facing electrodes is stationarily secured, and there is provided an opening and closing mechanism for moving the other electrode. To attain the second object, stabilizing members for solution flow are provided on the electrodes, a fluid-storing room is formed between the stabilizing member for solution flow and the electrode, and a slit-shaped hole for uniformly flowing the solution between the electrodes from the fluid-storing room, is formed at right angles to the travelling direction of the strip.Type: GrantFiled: January 31, 1997Date of Patent: November 17, 1998Assignee: Toyo Kohan Co., Ltd.Inventors: Tadashi Fujii, Eiichiro Sugioka
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Patent number: 5833816Abstract: The printed circuit boards (LP) are conducted through treatment baths (BB1 through BB3) in vertical attitude on at least two horizontal conveying paths (TW1 through TW4) proceeding next to one another, these treatment baths being accommodated in treatment cells (BZ10 through BZ13, BZ20 through BZ23, BZ30 through BZ33) that are arranged successively and next to one another. The end walls of the treatment cells are provided with vertical slots (S) and allocated seals (D) for the passage of the printed circuit boards. The bath liquid emerging from treatment cells arranged next to one another is collected in common collecting tanks (AW1 through AW3) and is returned into the treatment cells with the assistance of pumps (P). A common treatment cell for treatment zones lying next to one another can also be provided in a common collecting tank. The conveying of the printed circuit boards on the conveying paths lying next to one another preferably ensues with a common conveyor device.Type: GrantFiled: November 12, 1996Date of Patent: November 10, 1998Assignee: Siemens S.A.Inventors: Marcel Heermann, Daniel Hosten
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Patent number: 5811201Abstract: A system for generating electricity comprises a fuel cell, a heating stage, and an integral, power generator. The power generator comprises a compressor, an electricity generator and a turbine. Hot exhaust gas from the fuel cell is used for driving the turbine, which in turn drives the generator and the compressor. Both the fuel cell and the generator produce electricity. The compressor is used for compressing air for use in the fuel cell. A portion of the waste heat from the turbine drive gas is used for preheating the air utilized in the fuel cell.Type: GrantFiled: August 16, 1996Date of Patent: September 22, 1998Assignee: Southern California Edison CompanyInventor: Mark J. Skowronski
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Patent number: 5804043Abstract: A surface treating device for applying a surface treatment through the use of a fluid to the cylinder bores of a wide variety of types of cylinder blocks. The apparatus includes a cylinder block mounting arrangement that has flow paths formed in it that are adapted to accommodate a wide variety of types of cylinder blocks and cylinder blocks having different cylinder numbers and different cylinder bore diameters. Improved flushing and fluid recovery systems are also disclosed.Type: GrantFiled: January 30, 1996Date of Patent: September 8, 1998Assignee: Yamaha Hatsudoki Kabushiki KaishaInventor: Hirohiko Ikegaya
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Patent number: 5804055Abstract: An electrode, electrochemical cell, and electrochemical processes are disclosed. The electrode is a porous, multi-layered electrode which can have an element in flexible, strip form wound around a central, usually flat plate core, which core may serve as a current distributor. In any form, each layer can be represented by a very thin, highly flexible metal mesh. This can be a fine, as opposed to a coarse, mesh which has extremely thin strands and small voids. The electrode will have an active coating. For utilizing this electrode, the cell in one form will be a monopolar cell providing upward, parallel electrolyte flow through the porous, multi-layered electrode. A representative cell can have such electrode at least substantially filling an electrode chamber. The cells can be contained in a cell box that will provide the desired flow-through relationship for the electrolyte to the electrode.Type: GrantFiled: February 19, 1997Date of Patent: September 8, 1998Assignee: Eltech Systems CorporationInventors: Richard J. Coin, Lynne M. Ernes, Andy W. Getsy, Edward M. Halko, Kenneth L. Hardee, Marilyn J. Niksa
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Patent number: 5756874Abstract: An electrochemical cell (20) which is effectively leakproof and can be incorporated into an easily serviceable cell pack (80). Within the cell are a plurality of parallel electrode plates (44, 46, 56) which act as anode and cathode reaction surfaces for processing chemicals. The electrochemical cell housing (33) is preferably formed of durable plastic with all fluid inlets (36, 38) and outlets (40, 42) on its upper face (30). One or more input manifolds (48, 50) are provided to route process chemicals to the bottom of the cell and then distribute them upward across the electrode plates. The housing is formed as a one-piece, monolithic structure with an opening left on top for fitting the top face. At the end of cell assembly, the top face is attached to the remainder of the cell housing so as to form a sealed cell.Type: GrantFiled: October 10, 1995Date of Patent: May 26, 1998Assignee: Eosystems, Inc.Inventor: G. Anthony Steward
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Patent number: 5753098Abstract: An electrolyzer assembly has an outer, cylindrical dielectric electrolyzer housing member having a top, bottom, and cylindrical side wall. In one embodiment, the housing member has a sealed top, an open bottom for electrolyte entry, and apertures through the side wall near the sealed top permitting flow of electrolyte through the apertures. A cylindrical anode and cathode pair is situated inside the housing member. The cathode is positioned concentrically within the anode. Electrolyte flows in the space between anode and cathode. The anode is spaced apart from the side wall, providing an electrolyte flow path through the resulting cylindrically-shaped space. Electrical connections through the top of the housing member extend downwardly therein to electrical connection elements projecting upwardly from the electrode pair. The assembly provides for ease of cleaning, as well as ease of refurbishing, and operates efficiently and economically in both forced and unforced flow conditions.Type: GrantFiled: April 22, 1996Date of Patent: May 19, 1998Assignee: Excel Technologies International Corp.Inventors: James W. Bess, Jr., Charles W. Clements, Sr., John F. Newman, III
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Patent number: 5746904Abstract: A method for continuously treating a water body, comprising a step of using a substantially sealed processing tank, at a top and a bottom portions of which a water outlet and a water inlet are arranged respectively, and in an interior space of which three or more conductive plates substantially in parallel relation with the tank bottom and substantially in parallel relation with one another for upwardly forming a substantially closed S-shaped one-way flow path in said processing tank, wherein said conductive plates are made of a conductive material having a resistivity ranged from 1.59 .mu..OMEGA.to 1300 .mu..OMEGA.Type: GrantFiled: March 5, 1996Date of Patent: May 5, 1998Inventor: Ming Shing Lee
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Patent number: 5744028Abstract: A water dispenser including a water tank for storing water supplied from a water bottle; an electrolytic cell including an anode, a cathode, and a three-dimensional carbon electrode provided between the anode and the cathode, the electrolytic cell being provided downstream of the water tank; a water outlet valve provided downstream of the electrolytic cell; and a power supply for applying an electric current to the anode so as to polarize the electrode for sterilizing the water.Type: GrantFiled: November 21, 1996Date of Patent: April 28, 1998Assignee: Konica CorporationInventors: Nobutaka Goto, Peter S. Cartwright
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Patent number: 5728287Abstract: A method and apparatus for generating oxygenated water are shown and described. A plurality of electrolytic cells are coupled to each other and to a source of water. A volume of water is drawn from the source, and forced through at least one of the electrolytic cells at a user desired flow rate. If the demanded rate of flow at the outlet exceeds a threshold flow rate through the electrolytic cell, a valve is opened and an additional volume of water flows through the second electrolytic cell to the discharge, the rate of flow through each electrolytic cell not exceeding the selected value. Additional cells are added as needed. A varying demand of oxygenated water is therefore met, while ensuring that the dissolved oxygen content of the water at the outlet does not fall below a selected value.Type: GrantFiled: October 31, 1996Date of Patent: March 17, 1998Assignee: H.sub.2 O Technologies, Ltd.Inventors: Gary S. Hough, David V. Carlson
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Patent number: 5718814Abstract: A separating plant for separating metals from an electrolyte which contains metal, particularly for coating steel strip, includes successively arranged vertical coating cells in which the strip to be coated is guided from an upper deflection roller and/or current-carrying roller to a lower deflection roller and from there to another upper deflection roller and/or current-carrying roller. The upwardly or downwardly travelling strip portion passes through a gap between vertically arranged anodes and an electrolyte flow which is circulated by means of pumps is fed into the gap, preferably in a direction opposite the strip travel direction. Two oppositely arranged walls of each coating cell are constructed as anode plates and adjacent anode plates of successive coating cells form a separating chamber.Type: GrantFiled: March 22, 1996Date of Patent: February 17, 1998Assignee: SMS Schloemann-Siemag AktiengesellschaftInventor: Werner Schimion
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Patent number: 5705048Abstract: The present invention relates to an apparatus and a process for regenerating a used etchant solution, which solution contains a metal in divalent form. The apparatus includes a tank which is originally supplied with the etchant solution; a first electrolytic cell for converting solution from the tank to a solution containing a high fraction of a monovalent form of the metal; and a second electrolytic tank for plating metal from the solution containing a high fraction of the monovalent form of the metal. The details of the process of the present invention are set forth in the disclosure.Type: GrantFiled: March 27, 1996Date of Patent: January 6, 1998Assignee: Oxley Research, Inc.Inventors: James E. Oxley, Raymond J. Smialek, Ronald A. Putt
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Patent number: 5693201Abstract: A turbine power system that includes a compressor for compressing a first medium, and an electrochemical converter in communication with the compressor and adapted to receive the first medium and a second medium. The converter is configured to allow an electrochemical reaction between the first and second mediums, thereby generating electricity and producing exhaust having a selected elevated temperature. The power system further includes a turbine in fluid communication with the electrochemical converter and adapted to receive the converter exhaust, such that the turbine converts the electrochemical converter exhaust into rotary energy and electricity. The system can further include a steam generator and a steam turbine that produces electricity. The electrochemical converter is utilized herein as an electrochemical combustor-replacement (ECCR) or as a fuel cell for combustor-replacement (FCCR).Type: GrantFiled: October 19, 1994Date of Patent: December 2, 1997Assignee: Ztek CorporationInventors: Michael S. Hsu, Ethan D. Hoag
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Patent number: 5690806Abstract: An electrochemical cell is provided for removal of metals such as copper, lead, silver, tellurium, platinum, palladium or nickel from dilute solutions of the metal. The cell comprises a porous tubular support (18) which is provided with a cathode comprising a porous carbon fiber material (19), a current feeder (15) for the cathode, a tubular anode (12) spaced from said cathode, a current feeder (16) for the anode, the anode and the cathode being enclosed by a non-porous outer casing (11). In use the dilute solution from which the metal is to be removed is introduced into the cell through an inlet (13) and flows through the porous carbon fiber cathode to an outlet (14). The cell is useful for removing harmful metals from wastes so that they are environmentally acceptable for disposal and for recovery of valuable metals.Type: GrantFiled: March 7, 1996Date of Patent: November 25, 1997Assignee: EA Technology Ltd.Inventors: John Garry Sunderland, Ian McCrady Dalrymple
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Patent number: 5679240Abstract: The anode comprises a substantially horizontal carrying bar, which is disposed outside the electrolyte and serves to supply electric current. Two substantially parallel metal surfaces (anode grids) are electrically conductively connected to the carrying bar and with at least one-half of their surface extending into the electrolyte. The carrying bar comprises a copper conductor, to which at least one vertical copper rod is joined. There is a direct electrically conducting connection between the copper conductor and the copper rod. The copper rod is surrounded by a titanium sheath and is an interference fit in that sheath. The copper rod provided with the titanium sheath is disposed between the two anode grids and is electrically conductively connected to said grids.Type: GrantFiled: July 11, 1996Date of Patent: October 21, 1997Assignee: Metallgesellschaft AktiengesellschaftInventors: Nikola Anastasijevic, Gerhard Jedlicka, Karl Lohrberg
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Patent number: 5607563Abstract: An electrolytic cell and system for electrolysizing and/or heating a liquid electrolyte containing water having a conductive salt in solution flowing through the cell. The electrolytic cell includes a non-conductive housing having an inlet and an outlet and spaced apart first and second conductive foraminous grids connected within the housing. A plurality of spaced beds of closely packed conductive microspheres are positioned end to end within the housing in electrical contact with the first grid adjacent the inlet. The individual microsphere beds are electrically isolated from one another in the absence of the liquid electrolyte. The microspheres are generally uniform in size and density and include a plated layer formed of metallic hydride which is readily combineable with hydrogen or an isotope of hydrogen with hydrazine to form a conductive, preferably flash coated metal layer.Type: GrantFiled: December 4, 1995Date of Patent: March 4, 1997Inventors: James A. Patterson, Dennis Cravens
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Patent number: 5603351Abstract: A system and method for accomplishing a plurality of combinatorial processes in parallel comprising a microelectronic and fluidic array (device array) having micron-sized reservoirs, connecting microchannels and reaction cells etched into a substrate. The device array is supported by a station which serves to interface and perform electro-optic measurements of material in the reaction cells of the device array. The device array incorporates a modular configuration with three distinct layers or plates. The device array comprises a top feedthru plate, a center distribution plate and a bottom cell plate. The three plates are stacked vertically and coupled together to form a liquid-tight seal. Reservoirs, microchannels and reactions cells are controllably etched onto the plates using traditional semiconductor fabrication techniques. The top feedthru plate serves as a cover for the device array and contains apertures selectively positioned above the reservoirs located in the center distribution plate.Type: GrantFiled: June 7, 1995Date of Patent: February 18, 1997Assignee: David Sarnoff Research Center, Inc.Inventors: Satyam C. Cherukuri, Robert R. Demers, Zhong H. Fan, Aaron W. Levine, Sterling E. McBride, Peter J. Zanzucchi
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Patent number: 5587057Abstract: Electrolytic treaters for treating highly conductive liquid media include a conductive housing structure which is fluidically sealed and has inlet and outlet fluid connections, a conductive electrode structure positioned within the housing structure, and a DC power supply connected to components of the housing and electrode structure in such a manner that the output voltage of the power supply is applied across a substantial portion of the liquid media to be treated to control the current flow from the power supply. In a preferred embodiment, the electrode structure is formed by a center electrode rod with a plurality of ring electrodes positioned coaxially between the center electrode rod and the housing. Each ring electrode is formed by a plurality of circumferentially spaced rod elements extending parallel to the center electrode. The rod elements in a given ring electrode are held in place by a plurality of annular spacer baffles which additionally affect the flow of liquid media through the treater.Type: GrantFiled: December 7, 1993Date of Patent: December 24, 1996Assignee: David M. A. MetzlerInventors: David M. A. Metzler, Albert L. Mauk
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Patent number: 5584984Abstract: A process and apparatus for electrolytically treating a surface, as for pickling, cleaning and/or degreasing a high-speed continuous metal strip. The strip to be treated is passed through a container holding an electrolyte and including strip electrodes disposed in confrontingly-spaced relation above and below the movement path of the strip. The electrodes are arranged along the movement path in serial adjacency so that each electrode is disposed immediately adjacent to an opposite polarity electrode along the path. Electrolyte is applied to the strip by a number of nozzle pairs, each pair being associated with and arranged on opposite sides of a respective electrode and acting on a region of the strip confrontingly opposite that electrode so as to prevent the electrolyte from entering gap regions defined between adjacent electrodes. This arrangement avoids short circuits through the electrolyte between adjacent, opposite charge electrodes.Type: GrantFiled: July 7, 1995Date of Patent: December 17, 1996Assignee: Mannesmann AktiengesellschaftInventors: Franz G. Pempera, Michael Haentjes
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Patent number: 5582708Abstract: Electroplating cell comprising an electrolysis tank (2) containing a plating solution (S), at least one immersed anode (3), means for making a strip run through the solution (S) in front of said anode (3), from one of its edges (3A) to the opposite edge (3B), and electrically insulating masks (4A, 4B) arranged along said edges (3A, 3B).Said masks overhang said edges by an amount at least equal to the distance separating said anode (3) from said strip and overlap them by an amount less than the same distance.Application to coating with an alloy, especially a zinc-based alloy, especially in installations having several successive cells.The quality of the coating is improved, something which facilitates the subsequent forming and painting of the coated sheet.Type: GrantFiled: September 28, 1995Date of Patent: December 10, 1996Assignee: SollacInventors: Franco Delfrate, Claude Arnoux
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Patent number: 5580438Abstract: A water purifier comprising an electrolytic cell housed in an enclosure and an attaching apparatus. The enclosure attaches over an outlet fitting of a water circulation line in a swimming pool by the attaching apparatus. The attaching apparatus and the enclosure define apertures and outlet openings, respectively, having increasing areas in the direction of the water flow. This configuration increases flow rates through the apertures and outlet openings; the increased flow rates break off scale formations extending into the center of the apertures and outlet openings and thereby prevent scale from clogging the purifier. The attaching apparatus also can be coupled directly to the water circulation line and can be adjusted to accommodate fittings and circulation lines of various sizes.Type: GrantFiled: March 27, 1995Date of Patent: December 3, 1996Inventor: Michael A. Silveri
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Patent number: 5556522Abstract: A filter assembly for an electrostatic filter for removing solid contaminants in parts-washing solvents and other fluids is disclosed. The filter assembly provides a back flushable filter pack for continual use. When the flow of cleaned fluid slows, a simple procedure of back flushing will give user full flow and complete filtration again. This provides continual use by cleaning clogged porous filter media without the expense of a new filter pack each time it clogs with contaminant. The filter pack provides a stacked array of alternatingly charged electrode plates sandwiched between porous filter media. Appropriate electrical connections are disclosed and an electric monitoring circuit for monitoring the condition of the electrostatic filter is also disclosed.Type: GrantFiled: September 2, 1994Date of Patent: September 17, 1996Inventors: Rex K. Ingalls, Harold H. Casey, Rodger T. Moloney
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Patent number: 5549812Abstract: Electrolysis of water is effected while the water flow is pulsed utilizing pulse direct current in an electrolyzer having a medium flow between pairs of electrodes and a meandering flow from electrode pair to electrode pair, treating waste water and producing a flocculate which is removed in a stilling or settling tank cascade.Type: GrantFiled: March 20, 1995Date of Patent: August 27, 1996Assignee: WT Wassertechnologie GmbHInventor: Willi Witt a.k.a. Witte
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Patent number: 5543020Abstract: A cleaning system for electrolytic tanks consisting of a cell with a preferably rectangular layout, very long relative to its width, and which is provided with at least one conduit with perforated walls, and preferably two, which run over the bottom of the cell, along its length, and ascend alongside the shorter walls until they reach, approximately, the level of liquid of the tank, said cell being provided below with surfaces which are inclined towards the perforated conduits, said conduits having sufficient cross-sectional area to act as guides through which are inserted a suction head and pipe for sludge extraction.Type: GrantFiled: June 17, 1994Date of Patent: August 6, 1996Assignee: Asturiana De Zinc., S.A.Inventors: Francisco J. Sitges Menendez, Fernando Sitges Menendez, Francisco Alvarez Tamargo, Ives Lefevre
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Patent number: 5534120Abstract: A water electrolyzer for electrolyzing water to produce and recover acidic and/or alkaline water. The electrolyzer is of the membraneless laminar-flow type which is designed to electrolyze water without placing a membrane between the electrodes. To this end, the anode and cathode are arranged closely with one another with a very small spacing (generally less than 1 mm) to establish a laminar flow in a narrow flow path. The anode is provided with a slit-shaped aperture for separating a thin layer of acidic water flowing along the anode surface. This aperture is situated sufficiently upstream of the downstream end of the flow path to ensure that the layer of acidic water is separated away from the remainder of the laminar flow while the laminar flow is sustained in the flow path. Accordingly, formation of turbulence at a point of acidic water separation is minimized so that highly acidic water can be recovered.Type: GrantFiled: July 3, 1995Date of Patent: July 9, 1996Assignee: Toto Ltd.Inventors: Shigeru Ando, Hisato Haraga, Hidetaka Miyahara, Junji Tanaka, Hiroshi Takamatsu
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Patent number: 5531865Abstract: A method for removing contaminants from a flow of wastewater using an electrolytic oxidation vessel having a chamber and at least one elongate cathode electrode and a plurality of elongate sacrificial anode electrodes aligned parallel with the cathode electrode in the chamber. The flow of wastewater is directed through the chamber of the electrolytic oxidation vessel in a direction parallel with the cathode and anode electrodes so that the flow of wastewater engages the cathode and anode electrodes. A voltage is applied across the cathode electrode and the sacrificial anode electrodes to create a current having a density ranging from approximately 5-7 ma/sq. cm so as to release ions from the anode electrodes which oxidize and render insoluble contaminants in the flow of wastewater and create insoluble contaminants and substantially cleansed water. The insoluble contaminants are separated from the substantially cleansed water. An apparatus for use with the method is provided.Type: GrantFiled: February 28, 1995Date of Patent: July 2, 1996Inventor: Leland G. Cole
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Patent number: 5505847Abstract: The present invention is a bath which circulates and recycles a multiple mineral solution. The solution is released from the bathtub, filtered at the hair collector and the filtration device, sterilized at the electrolytic sterilizer, and returned to the tub. Non-metallic pipe is used along the circulation route. The electrolytic sterilizer employs several electrode panels which are placed perpendicular to the direction of flow of the solution. The filtration device features a rubber lining in the portions which come into contact with the solution, and has inside of it a dish onto which is lain filter sand. With the use of this invention, it becomes possible to repeatedly use and reuse a highly viscous solution containing multiple minerals as the recycling fluid, jams become infrequent, the filtration and reverse cleansing procedures become less time consuming, and the solution can be effectively sterilized.Type: GrantFiled: November 14, 1994Date of Patent: April 9, 1996Assignee: CAC CorporationInventors: Hajime Yamada, Akira Yamada
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Patent number: 5501781Abstract: An electrochemical converter assembly that significantly reduces the size of the dedicated thermal processing heat exchangers associated with the converter. This reduction is achieved by heating the input reactants of the electrochemical converter assembly inside the axial manifolds. This heating configuration thus relies upon an effective heat transfer mechanism located within the manifolds, and particularly within the manifold surfaces. In a preferred embodiment, the heating of the reactants occurs at the entrance region of the planar gap formed between the interconnector plates and the electrolyte plates. This heating is facilitated by the conduction of heat through the highly thermally conductive interconnector plate to an extended heating surface disposed within the manifold.Type: GrantFiled: August 8, 1994Date of Patent: March 26, 1996Assignee: Ztek CorporationInventors: Michael S. Hsu, Ethan D. Hoag