Abstract: A shaped strip of highly reflective aluminum protected by an anodic oxide coating and a light-permeable fluoropolymer coating which is non-adhesively interstitially mechanically bonded to the microscopic irregularities of the anodic oxide surface. There is no adhesive used to obtain chain entanglement. The highly reflective strip may be substituted for polished stainless steel and/or bi-metal and used under comparably aggressive conditions for a prolonged period without deleteriously affecting the initial D/I (distinctness of reflected image) of the shaped strip. The strip of arbitrary length is shaped in rolling dies so that at least a portion of the strip has a radius of less than 10 mm without damaging or separating the fluoropolymer coating. The specific steps of the claimed process require starting with a clean strip which is brightened to a nearmirror-like finish, then treated to carry a thin porous aluminum oxide coating in a phosphoric acid bath under direct current (DC).
Type:
Grant
Filed:
January 31, 1992
Date of Patent:
March 1, 1994
Assignee:
Aluminum Company of America
Inventors:
Frank A. Mozelewski, Daniel L. Serafin, Robert E. Bombalski, Romeo C. Pascasio, Donald L. Nock
Abstract: A method for changing a metal body, especially an aluminum alloy body, and, in particular, a method for producing a uniform metal body surface for use in achieving desired light reflectance characteristics and/or other useful attributes. The method comprises (a) preparing a metal body in a first solution by producing a first coating on at least a desired portion thereof with the first coating providing a substantially continuous outer surface on the metal body and (b) treating the metal body to achieve substantial uniformity throughout the desired portion of the metal body. In the treating step, substantially all of the first coating is removed in a second solution. The metal body has a substantially uniform roughened surface after the treating step which is sufficient to substantially optimize diffusive reflectance and reduce spectral reflectance of the metal body surface. The preparing step is preferably accomplished by anodizing.
Abstract: A method for preparing a substrate for lithographic printing plates comprises the steps of forming a hydrated oxide layer on the surface of an aluminum plate and then anodizing the plate in a sulfuric acid electrolyte; a lithographic printing plate comprises the substrate; and the substrate per se prepared by the method is also disclosed herein.The presensitized plate for use in making lithographic printing plates which comprises the substrate has very high sensitivity which makes the presensitized plate applicable to new exposure methods and is capable of being developed with a developer of an aqueous solution system. The light-sensitive layer and the substrate of the presensitized plate are strongly adhered to one another and, therefore, the resulting lithographic printing plate has excellent printing durability and good printability.
Abstract: The invention relates to a method of producing aluminum capacitor foil adapted for use in high voltage AC motor start capacitors. Aluminum foil is electrolytically etched in a hot aqueous solution of sodium cloride and then immersed in a hot solution of nitric acid. The foil is immediately thereafter passivated in a dilute aqueous solution of phosphoric acid. The passivated foil is electrolytically treated at a first voltage of at least 150 but not greater than 250 volts in a solution of an ammonium salt of a phosphate, a silicate or a vanadinate to substantially reduce the leakage current, and further electrolytically treated at a second voltage of a magnitude about twice that of the first voltage in a solution of an ammonium salt of an aliphatic dicarboxylic acid of at least 9 carbon atoms and ammonium phosphate until an essentailly amorphous oxide is formed on the foil.
Abstract: A process is disclosed for treating the surface of a valve metal such as aluminum to form a two layer protective coating thereon using an anodizing bath consisting essentially of an aqueous solution having a concentration ranging from about 0.001 molar to a saturated solution of a phosphorus-containing compound selected from the class consisting of a phosphorus acid ester and salts thereof. A non-porous barrier valve metal oxide layer is formed on a surface of the valve metal, and a functionalized layer comprised of a phosphate ester is formed on the oxide layer.
Type:
Grant
Filed:
October 16, 1989
Date of Patent:
April 7, 1992
Assignee:
Aluminum Company of America
Inventors:
Larry F. Wieserman, Karl Wefers, Gary A. Nitowski
Abstract: A process for preparing an electrode foil for use in aluminum electrolytic capacitors is disclosed which comprises the steps of: subjecting an aluminum base foil to a first anodic treatment in an aqueous solution of oxalic acid or sulfuric acid; subjecting the base foil so treated to a second anodic treatment in an aqueous solution of boric acid or adipic acid; and immersing the base foil so treated into an aqueous solution containing phosphoric acid or a salt thereof. Also disclosed is an electrode foil prepared by this process, which comprises an aluminum base foil, an anodic oxide film disposed on the base foil, and a porous oxide film disposed on the anodic oxide film, wherein phosphate ions are adsorbed on the surface of the porous oxide film.
Type:
Grant
Filed:
November 21, 1990
Date of Patent:
January 7, 1992
Assignee:
Matsushita Electric Industrial Co., Ltd.
Abstract: A method for fabricating a solid electrolytic capacitor is described, in which a solid electrolyte is made of a conductive polymer layer and is formed on a conductive inorganic layer which is formed on a metallic foil through a dielectric film. For the formation of the conductive polymer layer, while an external electrode is not directly contacted with the conductive inorganic layer, the electrolytic polymerization reaction of a polymerizable monomer in an electrolytic solution is carried out. For this purpose, the external electrode may be covered with a conductive polymer film at the contact portion. Alternatively, the external electrode may be moved from one position to another or may be kept apart from the conductive inorganic layer during the electrolytic polymerization reaction. By this, the mechanical damages of the conductive inorganic layer with the external electrode are suppressed with good electric characteristics of the capacitor.
Type:
Grant
Filed:
September 6, 1990
Date of Patent:
December 10, 1991
Assignee:
Matsushita Electric Industrial Co., Ltd.