Plural Treating Agents (sequential Or Simultaneous) Patents (Class 208/181)
  • Patent number: 11655422
    Abstract: A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material includes more than 1 ppm silicon as silicon compounds. Exemplary steps include (a) providing the recycled or renewable organic material; (b) heat treating the recycled or renewable organic material to form a heat treated recycled or renewable organic material, wherein the at least part of silicon compounds present in the recycled or renewable organic material are converted to volatile silicon compounds, and (c) evaporating volatile silicon compounds from the heat treated recycled or renewable organic material to obtain recycled or renewable organic material fraction containing less silicon than the recycled or renewable organic material provided in step (a).
    Type: Grant
    Filed: July 19, 2019
    Date of Patent: May 23, 2023
    Assignee: NESTE OYJ
    Inventors: Jouni Touronen, Meri Hovi, Antti Pasanen, Salla Likander, Sami Toppinen, Pekka Aalto, Kari Jansson, Marina Lindblad, Mats Käldström, Kaisa Lamminpää, Andrea Perez Nebreda
  • Patent number: 9550936
    Abstract: A process for increasing mobility of heavy oil includes: disposing a solvating composition comprising a paraffinic solvent and a multifunctional solvent in a heavy oil environment including a heavy oil, the heavy oil comprising asphaltene; contacting the heavy oil with the solvating composition; and stabilizing asphaltene in the heavy oil with the solvating composition to increase mobility of the heavy oil and to form a stabilized heavy oil which includes the heavy oil and solvating composition. A method for making stabilized heavy oil includes separating resin from an oil; combining the resin and a paraffinic solvent to form a solvating composition; disposing the solvating composition in a heavy oil environment which includes heavy oil comprising asphaltene; and contacting the asphaltene with the solvating composition to make stabilized heavy oil, wherein the stabilized heavy oil comprises the solvating composition and heavy oil.
    Type: Grant
    Filed: August 8, 2012
    Date of Patent: January 24, 2017
    Assignee: BAKER HUGHES INCORPORATED
    Inventors: Oleg A. Mazyar, Michael H. Johnson
  • Patent number: 9006504
    Abstract: Methods for converting petroleum based oil into fuel generally include forming a conversion mixture of an alcohol and a base, and adding the conversion mixture to petroleum based oil, such as used motor oil, to form a reaction mixture. The methods can also include adding a high nitrate compound and an amino acid to the reaction mixture and ozonizing the reaction mixture. The result of the methods can include a three phase system in which the bottom phase is asphalt oil, the middle phase is diesel fuel or jet fuel, and the top phase is sulfuric acid. The three phases can be separated to obtain the final diesel fuel or jet fuel product.
    Type: Grant
    Filed: July 10, 2013
    Date of Patent: April 14, 2015
    Assignee: OTG Research, LLC
    Inventor: Philip Allen Boe
  • Publication number: 20150048005
    Abstract: A continuous, hot vapor stripping, process and apparatus to recover base oil from used lubricating oils (IMO) containing lubricating oil boiling range material, with further refining using solvent extraction to produce a high quality base oil.
    Type: Application
    Filed: August 13, 2014
    Publication date: February 19, 2015
    Applicant: Solvex Process Technologies LLC
    Inventors: Christopher Joseph Lobue, Gary Lynn Hensley
  • Patent number: 8859833
    Abstract: Methods and system for obtaining long chain carbons that generally include forming a conversion mixture of an alcohol and a base, adding the conversion mixture to oil (such as petroleum based oil, crude oil, used oil, used motor oil, and new motor oil) to form a reaction mixture, adding a high nitrate compound the reaction mixture, and separating out the long chain carbons for use as an input by other processing such as pharmaceutical and/or additional petro-chemical processing. Additional cooling and/or filtering processes may be utilized to complete and/or optimize oil conversion.
    Type: Grant
    Filed: April 12, 2013
    Date of Patent: October 14, 2014
    Inventor: Philip Allen Boe
  • Patent number: 8758597
    Abstract: A saturated elastomeric mixture is disclosed having a cured or vulcanized elastomer crumb rubber and atmospheric distillations bottoms residue is disclosed.
    Type: Grant
    Filed: August 20, 2009
    Date of Patent: June 24, 2014
    Inventor: John D. Osborn
  • Patent number: 8535517
    Abstract: The present invention relates to a method for treating various waste petroleum into eco-friendly solid so that leaching of oil would not occur. The method of the present invention can treat radioactive waste petroleum as well as various waste petroleum, thereby stabilizing waste petroleum chemically and physically, wherein the method comprises mixing waste petroleum with a sulfuric acid and a nitric acid; adding sodium hydroxide, thereby carrying out a polymerization reaction to produce solid particles; colloidizing a mixture obtained by uniformly stirring the solid particles; adding a diisocyanate compound in reactor, thereby carrying out a subsequent polymerization reaction to obtain a new compound in the form of powder; discharging a generated gas into the atmosphere; and filling the powder into a resin as a filling material and compression molding and reclaiming the filled powder.
    Type: Grant
    Filed: September 30, 2009
    Date of Patent: September 17, 2013
    Inventor: Hong Yoon Choi
  • Patent number: 8492601
    Abstract: Methods for converting used oil into fuel generally include forming a conversion mixture of an alcohol and a base, and adding the conversion mixture to used oil, such as used motor oil, to form a reaction mixture. The methods can also include adding a high nitrate compound and an amino acid to the reaction mixture and ozonizing the reaction mixture. The result of the methods can include a three phase system in which the bottom phase is asphalt oil, the middle phase is diesel fuel or jet fuel, and the top phase is sulfuric acid. The three phases can be separated to obtain the final diesel fuel or jet fuel product.
    Type: Grant
    Filed: April 12, 2012
    Date of Patent: July 23, 2013
    Assignee: OTG Research, LLC
    Inventor: Philip Allen Boe
  • Patent number: 8398847
    Abstract: One or more computer implemented methods for continuously processing used oils are provided. The method can include a feedstock tank containing feedstock. The feedstock tank can have a sparger and a level sensor. The feedstock tank can be in fluid communication with a first pump, a first filter, a heater, a second filter, first flow meter, a primary nozzle, a secondary nozzle, a motionless inline static mixer, and a first reactor.
    Type: Grant
    Filed: July 28, 2010
    Date of Patent: March 19, 2013
    Assignee: Vertex Energy, LP
    Inventors: Gregory Odell Wallace, John G. Schulz, Benjamin P. Cowart
  • Publication number: 20110100878
    Abstract: The present invention relates to a process for the treatment of oil residues coming from the oil industry which comprises the recovery of the oil fraction of residues by extraction with solvents having a low environmental impact (ethyl acetate/toluene) and subsequent finishing for the downgrading of the residual material.
    Type: Application
    Filed: March 26, 2009
    Publication date: May 5, 2011
    Inventors: Felicia Massetti, Michelangelo D'abbieri, Alessandro Nardella
  • Patent number: 7799213
    Abstract: Reactive phosphorus species can be removed or transferred from a hydrocarbon phase to a water phase in an emulsion breaking process by using a composition that contains water-soluble hydroxyacids. Suitable water-soluble hydroxyacids include, but are not necessarily limited to glycolic acid, gluconic acid, C2-C4 alpha-hydroxy acids, poly-hydroxy carboxylic acids, thioglycolic acid, chloroacetic acid, polymeric forms of the above hydroxyacids, poly-glycolic esters, glycolate ethers, and ammonium salt and alkali metal salts of these hydroxyacids, and mixtures thereof. The composition may optionally include a mineral acid to reduce the pH of the desalter wash water. A solvent may be optionally included in the composition. The invention permits transfer of reactive phosphorus species into the aqueous phase with little or no hydrocarbon phase undercarry into the aqueous phase. The composition is particularly useful in treating crude oil emulsions, and in removing calcium and other metals therefrom.
    Type: Grant
    Filed: July 8, 2005
    Date of Patent: September 21, 2010
    Assignee: Baker Hughes Incorporated
    Inventors: Lawrence N. Kremer, Tran M. Nguyen, Jerry J. Weers
  • Patent number: 7662274
    Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.
    Type: Grant
    Filed: September 10, 2007
    Date of Patent: February 16, 2010
    Assignee: Miami University
    Inventors: Jeffrey H. Sherman, Richard T. Taylor
  • Publication number: 20090184030
    Abstract: A process for removing impurities from used oil. Impurities such as water, solid particles, and the like are removed from used oil by processing the oil with a mixture of polar and non-polar solvents. The process operates at room temperatures and pressures, simplifying the equipment and energy requirement for the process.
    Type: Application
    Filed: January 17, 2008
    Publication date: July 23, 2009
    Inventors: Teh Fu Yen, William Tsung-Chieh Fan
  • Patent number: 7497943
    Abstract: It has been discovered that metals and/or amines can be removed or transferred from a hydrocarbon phase to a water phase in an emulsion breaking process by using a composition that contains water-soluble hydroxyacids. Suitable water-soluble hydroxyacids include, but are not necessarily limited to glycolic acid, gluconic acid, C2-C4 alpha-hydroxy acids, poly-hydroxy carboxylic acids, thioglycolic acid, chloroacetic acid, polymeric forms of the above hydroxyacids, poly-glycolic esters, glycolate ethers, and ammonium salt and alkali metal salts of these hydroxyacids, and mixtures thereof. The composition may also include at least one mineral acid to reduce the pH of the desalter wash water. A solvent may be optionally included in the composition. The invention permits transfer of metals and/or amines into the aqueous phase with little or no hydrocarbon phase undercarry into the aqueous phase.
    Type: Grant
    Filed: August 27, 2003
    Date of Patent: March 3, 2009
    Assignee: Baker Hughes Incorporated
    Inventors: Tran M. Nguyen, Lawrence N. Kremer, Jerry J. Weers
  • Patent number: 7226533
    Abstract: A process to re-refine used petroleum oils by extraction with aliphatic solvents, wherein after eliminating the extract solvent, the process consists of the following treatments, (a) flash, continuous vaporization, at atmospheric pressure or near atmospheric pressure, to separate the light fractions, in the presence of small amounts of a basic compound or a reducing agent or a combination of both and (b) continuous distillation, in a fractionating column, of the bottom liquid obtained in stage (a), under vacuum and moderate temperatures, in the presence of a basic compound or a reducing compound or a combination of both, with recirculation from the bottom of the column to its feed; separating, as lateral extractions, the vacuum gas-oil or spindle oil and the lubricant bases and, as bottom product, a fuel-oil or asphaltic component.
    Type: Grant
    Filed: October 10, 2002
    Date of Patent: June 5, 2007
    Assignee: Sener Grupo De Ingenieria, S.A.
    Inventor: Jerónimo Angulo Aramburu
  • Patent number: 7223331
    Abstract: Disclosed is a method for settling suspended finely divided inorganic solid particles from a hydrocarbon slurry using an additive. The additive comprises (a) a hydroxy-terminated polyoxyalkylate chain(s) containing polymer having at least one oxygen atom and at least one nitrogen atom and, optionally, (b) other components such as a solvent, an acid or mixtures thereof.
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: May 29, 2007
    Assignee: Baker Hughes Incorporated
    Inventors: Joseph L. Stark, Robert S. Lauer, Lawrence N. Kremer
  • Patent number: 7208079
    Abstract: A process for the treatment of waste oil comprises the steps of (a) supplying a stream of the waste oil to a dehydrator to dehydrate the waste oil and obtain a stream of dehydrated waste oil; (b) supplying the stream of dehydrated waste oil to a fractionated distillation column having a lower tray, an upper tray and a middle tray therebetween, wherein the lower tray is operated at a temperature of 370 to 390° C. under a sub-atmospheric pressure of 50 to 100 mmHg, the middle tray is operated at a temperature of 265 to 280° C. under a sub-atmospheric pressure of 35 to 45 mmHg and the upper tray is operated at a temperature of 100 to 110° C. under a sub-atmospheric pressure of 30 to 40 mmHg; (c) withdrawing from the distillation column a bottom product comprising a bituminous material; (d) withdrawing a first side stream from the distillation column between the first and second trays, the first side stream comprising a heavy oil having a viscosity of 130 to 180 cSt at 40° C.
    Type: Grant
    Filed: March 3, 2003
    Date of Patent: April 24, 2007
    Inventor: Nouredine Fakhri
  • Patent number: 7202391
    Abstract: According to the present invention, there is provided a process for inhibiting the polymerization of an aromatic vinyl compound which is capable of efficiently inhibiting the polymerization of an aromatic vinyl compound not only in an initial stage but also over a long term in the stage of producing, purifying, storing or transporting the aromatic vinyl compound, and which is excellent in handling. The present invention relates to a process for inhibiting the polymerization of an aromatic vinyl compound which requires the step of adding a 2-nitrophenol compound in combination with a sulfonic acid compound to the aromatic vinyl monomer during the stage of producing, purifying, storing or transporting the aromatic vinyl compound.
    Type: Grant
    Filed: April 18, 2002
    Date of Patent: April 10, 2007
    Assignee: Hakuto Co., Ltd.
    Inventors: Seiji Tanizaki, Junichi Nakajima
  • Patent number: 6929737
    Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is also distilled to remove any remaining solvent therefrom, with the recovered solvent being reused.
    Type: Grant
    Filed: January 2, 2001
    Date of Patent: August 16, 2005
    Assignee: Miami University
    Inventors: Jeffrey H. Sherman, Richard T. Taylor, Amanda L. Hofacker, James W. Hershberger, Garrett M. Conn, William A. Gorman
  • Patent number: 6712954
    Abstract: The invention relates to a method for reprocessing waste oils and producing high-grade base oils, whereby waste oil is treated by means of distillation, thin-film evaporation in a high vacuum, optional fractionation for separation into layers of different viscosities and subsequent extraction with N-methyl-2-pyrrolidone and/or N-formylmorpholine. The invention also relates to base oils that can be obtained by said method and to the use thereof. The inventive method is characterized in that approximately any waste oil can be used, including waste oils with polychlorinated biphenylene (PCB) or PCB substitutes with contents of up to 250 mg/kg. Furthermore, waste oils containing up to 5% vegetable oil can be present in the waste oil that is to be reprocessed without impairing the quality of the base oil. The undesirable constituents, especially polycyclic aromatic hydrocarbons and polychlorinated biphenylenes (PCB) or the substitutes thereof are removed in an almost quantitative manner.
    Type: Grant
    Filed: August 13, 2001
    Date of Patent: March 30, 2004
    Assignee: Mineralöl-Raffinerie Dollbergen GmbH
    Inventors: Joachim Pöhler, Michael Mödler, Detlev Bruhnke, Holger Hindenberg
  • Patent number: 6398948
    Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: June 4, 2002
    Assignee: Miami University
    Inventors: Jeffrey H. Sherman, Richard T. Taylor
  • Patent number: 6395166
    Abstract: A method of reclaiming used motor oil for further use is disclosed comprising (a) admixing used impurity laden motor oil with an effective amount of acetone as a flocculating agent and an effective amount of a second ketone as a wetting agent thereby forming an oil impurity flocculent mixture; (b) subjecting said mixture to a force such that a heavy phase and a light phase are formed, wherein said light phase is comprised of lean motor oil, acetone, and a second ketone, and wherein said heavy phase is comprised of flocculated impurities, any remaining acetone, and any remaining second ketone; and (c) separating said light phase containing said lean motor oil from said heavy phase containing said flocculated impurities. Preferably the second ketone is diisopropyl ketone, though other second ketones are also functional.
    Type: Grant
    Filed: August 30, 2000
    Date of Patent: May 28, 2002
    Inventor: Frederick J. Haydock
  • Patent number: 6372122
    Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is coalesced to remove any remaining solvent therefrom, with the recovered solvent being reused.
    Type: Grant
    Filed: August 1, 2000
    Date of Patent: April 16, 2002
    Assignee: Avista Resources, Inc.
    Inventor: William A. Gorman
  • Patent number: 6319394
    Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is also distilled to remove any remaining solvent therefrom, with the recovered solvent being reused.
    Type: Grant
    Filed: January 4, 2001
    Date of Patent: November 20, 2001
    Assignee: Miami University
    Inventors: Jeffrey H. Sherman, Richard T. Taylor, Amanda L. Hofacker, James W. Hershberger, Garrett M. Conn, William A. Gorman
  • Patent number: 6316685
    Abstract: Disclosed is a method for separating finely divided solids from a hydrocarbon slurry by using an additive that comprises a polymer and, optionally, an alkylbenzene sulfonic acid; and a composition of the additive thereof. The polymer is a polymer having (a) a polymeric backbone comprising polyol units and at least one unsaturated polycarboxylic unit, (b) acrylate units coordinated via unsaturated polycarboxylic units, and (c) oxyalkylated alkyl phenol units.
    Type: Grant
    Filed: November 30, 2000
    Date of Patent: November 13, 2001
    Assignee: Baker Hughes Incorporated
    Inventors: Robert S. Lauer, Lawrence N. Kremer, Joseph L. Stark, Andrew McCallum
  • Publication number: 20010025807
    Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is also distilled to remove any remaining solvent therefrom, with the recovered solvent being reused.
    Type: Application
    Filed: January 2, 2001
    Publication date: October 4, 2001
    Inventors: Jeffrey H. Sherman, Richard T. Taylor, Amanda L. Hofacker, James W. Hershberger, Garrett M. Conn, William A. Gorman
  • Patent number: 6270678
    Abstract: The present invention relates to a method of treating alkaline waste water originating from washing spent oil which has undergone an alkaline treatment with water and which contains organic material. This method can produce water which can be discharged into conventional industrial water treatment facilities or which can be used directly as a base for preparing fertilizers or for preparing an agent for preventing ice formation on road surfaces.
    Type: Grant
    Filed: March 21, 2000
    Date of Patent: August 7, 2001
    Inventor: Bernard Chavet
  • Patent number: 6270657
    Abstract: An asphalt blend composition containing an asphalt component and a bottoms fraction from a used motor vaporization process of the above process, and a pavement composition comprising aggregate and the asphalt blend composition. The process comprises directly contacting used lubricating oil with a heated vapor, e.g., steam, under conditions which at least partially decompose the organo-metallic component and provide a desired volume of pumpable bottoms containing organo-metallic compound decomposition products and an overhead comprising gases and distillatable hydrocarbons, with no substantial carryover of metals into the overhead. The process may be carried out under conditions which minimize decomposition of high molecular weight additives such as VI improvers.
    Type: Grant
    Filed: April 11, 2000
    Date of Patent: August 7, 2001
    Assignee: Marathon Ashland Petroleum LLC
    Inventors: Howard F Moore, Donald P Malone, Patricia K Doolin, David J Zalewski
  • Patent number: 6238551
    Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is also distilled to remove any remaining solvent therefrom, with the recovered solvent being reused.
    Type: Grant
    Filed: December 17, 1999
    Date of Patent: May 29, 2001
    Assignee: Miami University
    Inventors: Jeffrey H. Sherman, Richard T. Taylor, Amanda L. Hofacker, James W. Hershberger, Garrett M. Conn, William A. Gorman
  • Publication number: 20010001198
    Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is also distilled to remove any remaining solvent therefrom, with the recovered solvent being reused.
    Type: Application
    Filed: January 4, 2001
    Publication date: May 17, 2001
    Applicant: Miami University
    Inventors: Jeffrey H. Sherman, Richard T. Taylor, Amanda L. Hofacker, James W. Hershberger, Garrett M. Conn, William A. Gorman
  • Patent number: 6179999
    Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.
    Type: Grant
    Filed: October 15, 1999
    Date of Patent: January 30, 2001
    Assignee: Miami University
    Inventors: Jeffrey H. Sherman, Richard T. Taylor
  • Patent number: 6174431
    Abstract: A method for pretreating and re-refining used oil that requires only moderate heat and only one re-refining step. The pretreatment involves mixing the used oil with a basic solution and optionally a phase transfer catalyst. The phase transfer catalyst aids the chemical reaction which allows removal of impurities in used oil. The basic solution preferably includes more than one base. The used oil, basic solution and phase transfer catalyst are mixed under low heat. The pretreated oil is then mixed with liquid propane in a non-turbulent manner, such as by use of a globe valve or orbit valve. The mixture of used oil and liquid propane are then placed into an extraction vessel and impurities are allowed to settle out of the oil and propane mixture. Heavy fraction may be removed from the extraction vessel. Preferably, a second vessel called a settling vessel will be used to cause further settling of impurities out of the used oil. Light fraction is produced which may be re-refined to produce base oil.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: January 16, 2001
    Assignee: Interline Hydrocarbon, Inc.
    Inventors: Michael R. Williams, Jan Krzykawski
  • Patent number: 6007701
    Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.
    Type: Grant
    Filed: February 16, 1999
    Date of Patent: December 28, 1999
    Assignee: Miami University
    Inventors: Jeffrey H. Sherman, Richard T. Taylor
  • Patent number: 5948242
    Abstract: A process for upgrading heavy crude oil production is described which involves adding a diluent, or solvent, which is a light hydrocarbon to reduce the viscosity and specific gravity of the crude oil being processed. After dilution, the emulsions in the crude are broken and the separation of the crude into the components follows, aided by a second injection of diluent. This upgrades the crude and enhances the amount recovered for processing at a refinery. A high asphalt content of a heavy crude can also be tolerated in the practice of this invention resulting in environmentally-benign solids and water exiting a process which due to the modularization of equipment can be practiced at the well-head itself.
    Type: Grant
    Filed: October 15, 1997
    Date of Patent: September 7, 1999
    Assignee: UniPure Corporation
    Inventors: Ernest O. Ohsol, John W. Pinkerton, Thomas E. Gillespie, Thomas H. Laity
  • Patent number: 5882506
    Abstract: An invention is disclosed whereby refinery waste emulsion streams such as API slop oils, desalter rag layer emulsions, mud pit sludges and the like having high viscosities and specific gravity approaching that of water can be treated for the recovery of processable oil values which had previously been unavailable by adding a sufficient amount of a light hydrocarbon diluent to the emulsion to lower its overall viscosity and to reduce the specific gravity of the oil phase to less than about 0.92. The diluted emulsions are subjected to flashing at emulsion-breaking conditions after which the oil is recovered from the various streams created in the flashing steps.
    Type: Grant
    Filed: November 19, 1997
    Date of Patent: March 16, 1999
    Inventors: Ernest O. Ohsol, John W. Pinkerton, Thomas E. Gillespie
  • Patent number: 5875406
    Abstract: A method for reducing radioactive waste, particularly oils and solvents in nuclear power stations and military research centers, and a device therefor. The method comprises feeding the waste into a tank (1) in which it is continuously stirred, preheating the waste, performing a chemical precipitation treatment, feeding the mixture into a centrifuge (2), performing an electrostatic or conventional filtration step, and testing the level of radioactivity. The treatment is continuously repeated until the desired level of decontamination is reached.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: February 23, 1999
    Assignee: Bernatom S.A.R.L.
    Inventor: Adolphe Weber
  • Patent number: 5639383
    Abstract: This procedure includes detecting and rejecting the used mineral motor oils containing polychlorinated biphenyls (PCB's) and/or polychlorinated triphenyls (PCT's) before filtering; before the decantation and/or distillation step, if necessary, submitting the used mineral motor oil to thermal shock treatment. In the recycling process, stabilizing the used mineral motor oils that normally contain heavy metals by adding to bitumen, using 0 to 15 percent of used mineral motor oil and a minimum of 85 percent bitumen for bituminous pavements and 1 to 20 percent of used mineral motor oils and a minimum of 80 percent bitumen for bitumen emulsions and paints. Also in the recycling process the used mineral motor oils are mixed with bitumen and paraffinic elastomers, stabilizing the heavy metals contained in the used mineral motor oils, getting usual bituminous pavements, self-draining bituminous pavements, sport pavements, etc. EPM EPDM or butyl rubber are used as paraffinic elastomers.
    Type: Grant
    Filed: April 21, 1994
    Date of Patent: June 17, 1997
    Assignee: Ralfer, S.L.
    Inventors: Carlos Gajas Fuertes, Miguel Balada Subirats
  • Patent number: 5573656
    Abstract: A process for significantly decreasing the acid sludge settling time in waste oil recovery processes comprising the steps of heating used oil to a high temperature above 725 degrees Fahrenheit, cooling the heated oil, adding an oxidizing agent to the oil, allowing the acid sludge to settle within a period of approximately 24 to 72 hours, separating the acid-sludge-free oil from the acid sludge which settles out of solution as a result of addition of the oxidizing agent, and adding a polishing agent and separating the re-refined oil from the spent polishing agent. The spent polishing agent is recycled, and the acid sludge which settles out after oxidation is converted to either hard, oxidized asphalt or soft asphalt or asphalt products such as emulsions etc. The process produces a high quality re-refined oil rapidly and economically with no acid sludge disposal problem.
    Type: Grant
    Filed: February 16, 1994
    Date of Patent: November 12, 1996
    Inventor: Benjamin Santos
  • Patent number: 5556548
    Abstract: A novel process and related apparatus for removing common contaminants from used motor oil. Propane, butane or similar solvent is mixed with the contaminated oil to form a solution. This solution is agitated and then given time to settle thus allowing gravitational separation of asphaltic pollutants. The solution is then percolated through a columned filter to remove heavy metallic contaminants and the solvent recovered by heating the solution.
    Type: Grant
    Filed: February 15, 1994
    Date of Patent: September 17, 1996
    Assignee: Interline Hydrocarbon Inc.
    Inventor: Craig R. Mellen
  • Patent number: 5514272
    Abstract: A process for significantly decreasing the acid sludge settling time in waste oil recovery processes comprising the steps of heating used oil to a high temperature above 700 degrees Fahrenheit, cooling the heated oil, adding an oxidizing agent to the oil, allowing the acid sludge to settle within a period of approximately 24 to 72 hours, separating the acid-sludge-free oil from the acid sludge which settles out of solution as a result of addition of the oxidizing agent, and adding a polishing agent and separating the re-refined oil from the spent polishing agent. The process produces a high quality re-refined oil rapidly and economically.
    Type: Grant
    Filed: June 4, 1993
    Date of Patent: May 7, 1996
    Inventor: Benjamin S. Santos
  • Patent number: 5286380
    Abstract: A novel process and related apparatus for removing common contaminants from used motor oil. Propane, butane or a similar solvent is mixed with the contaminated oil to form a solution. This solution is agitated and then given time to settle thus allowing gravitational separation of asphaltic pollutants. The solution is then percolated through a columned filter to remove heavy metallic contaminants and the solvent recovered by heating the solution.
    Type: Grant
    Filed: May 14, 1990
    Date of Patent: February 15, 1994
    Assignee: Petroleum Technology Corporation
    Inventor: Craig R. Mellen
  • Patent number: 5209839
    Abstract: NaOH can be used to remove hydroperoxides from a lubricating oil provided the oil contains a metal thiophosphate. This extends the useful life of the oil and the equipment being lubricated. In a preferred embodiment, the NaOH is immobilized within the lubrication system of an internal combustion engine.
    Type: Grant
    Filed: March 5, 1992
    Date of Patent: May 11, 1993
    Assignee: Exxon Research and Engineering Co.
    Inventors: Harold Shaub, Darrell W. Brownawell, Arthur DiBenedetto
  • Patent number: 5141628
    Abstract: Used oils, especially used lube oils, after rough filtering are mixed with an aqueous solution of water glass and an aqueous solution of polyalkylene glycol while stirring at elevated temperature, the obtained mixture is allowed to settle, the settlings are separated, and water and light ends are removed from the oil phase by distillation. The thus obtained dry oil phase may be subjected to adsorptive filtering either direct or through a per se known treatment with dispersed sodium and may finally be fractionated by distillation.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: August 25, 1992
    Assignee: RWE-Entsorgung Aktiengesellschaft
    Inventors: Erich-Klaus Martin, Adekunle Onabajo
  • Patent number: 5057207
    Abstract: The present invention provides a method for reprocessing, particularly the dehalogenation, of oil products which involves a) treating the oil product at temperatures up to about 150.degree. C. with an effective amount of an aqueous solution of at least one compound selected from the group consisting of a strong acid, a salt of a weak base and a strong acid and precursors thereof; b) treating the oil product of step (a) at increased temperatures with at least one halogen binding agent; and c) separating water and/or the solids from the treated oil product of step (b).
    Type: Grant
    Filed: November 3, 1989
    Date of Patent: October 15, 1991
    Assignee: Geut AG
    Inventor: Fritz Basler
  • Patent number: 5045179
    Abstract: The present invention provides a hydrogenation process for reprocessing used oil into secondary raffinates in the form of lubricating oils. In this process according to some embodiments of the invention, ecologically undesirable byproducts or waste materials are eliminated, without requiring expensive and time-consuming separation stages or reaction conditions, or the use of expensive catalysts. In particular, even severely contaminated oils, i.e. those which contain organo-chlorine compounds, in particular PCB, chlorinated dioxins and dibenzofurane in concentrations above certain limits, can also be reused as secondary raffinates, in particular as lubricating oils. No longer need these substances be destroyed in a high temperature combustion process, for example. As a first step, the coarse solid substances are removed from the used oil. Thereafter, with the addition of hydrogen, a hydrogenation step is conducted in a sump phase at predetermined pressures and temperatures.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: September 3, 1991
    Assignee: Ruhrkohle AG
    Inventors: Josef Langhoff, Alfons Jankowski, Harald Weber
  • Patent number: 4941967
    Abstract: Process for re-refining spent lubeoils, wherein a lubeoil freed from water and sludge forming impurities is subjected to a pre-destillation at reduced pressure and with a short residence time of the oil in the distillation column and is subsequently subjected to film evaporation under vacuum, in one or more wiped-film evaporators wherein the overhead product obtained with the film evaporator is subjected to an after-treatment after condensation and the heavy bottom product (residue product) of at least one film evaporator is at least partially recycled to the entrance of said film evaporator.
    Type: Grant
    Filed: January 27, 1987
    Date of Patent: July 17, 1990
    Assignee: Kinetics Technology International B.V.
    Inventors: Leonardus M. M. Mannetje, Ashok S. Laghate
  • Patent number: 4931161
    Abstract: A process is disclosed for removing hydrocarbons from oily wastes. According to the process, the oily wastes are mixed with solids and a binder and then granulated. The granules thus formed are contacted with solvent to extract hydrocarbons from the granules. Preferred solids include limestone and preferred binders include portland cement calcium sulfate and/or calcium sulfate hydrate such as plaster of Paris.
    Type: Grant
    Filed: July 12, 1989
    Date of Patent: June 5, 1990
    Assignee: Chevron Research Company
    Inventor: Parameshwaran S. Sundar
  • Patent number: 4925597
    Abstract: In a process for decontaminating radioactively polluted lubricant oil, (a) the lubricant oil to be decontaminated is mechanically filtered, (b) an acid solution of the salts of the elements, the radionuclides of which are to be removed, is added, and (c) a dose of a precipitating agent that cooperates with the elements, the radionuclides of which are to be removed, producing a salt of low solubility, is added, (d) the acid salt solution is intimately mixed with the lubricant oil after step (b), (e) the depositing aqueous phase is discharged after step (b), before step (c), (f) additional intimate mixing is carried out after the dosed admixture of step (c), and (g) finally the precipitation products are separated by centrifugation from the lubricant oil.
    Type: Grant
    Filed: October 12, 1988
    Date of Patent: May 15, 1990
    Inventor: Martin Ganter
  • Patent number: 4842715
    Abstract: A process is disclosed for separating an organic material from a composition comprising said organic material intermixed with particulate solids, the process comprising advancing a light hydrocarbon fluid through said particulate solids at an effective rate to drive at least some of said organic material from said particulate solids, adding water to said composition containing particulate solids and residual organic material to produce a second composition, and adding an oxidizing agent to said second composition in an amount sufficient to remove substantially all of the residual organic material.
    Type: Grant
    Filed: December 14, 1987
    Date of Patent: June 27, 1989
    Assignee: The Standard Oil Company
    Inventors: Stephen C. Paspek, Jr., Jeffrey B. Hauser, Christopher P. Eppig, Richard B. Stalzer
  • Patent number: 4808299
    Abstract: A process for removing copper and/or iron impurities from a liquid hydrocarbon-containing feed comprises contacting the feed with an aqueous treating agent comprising water-soluble alkali metal silicate (in particular sodium silicate) and/or a surfactant, in particular an anionic surfactant.
    Type: Grant
    Filed: April 14, 1988
    Date of Patent: February 28, 1989
    Assignee: Phillips Petroleum Company
    Inventors: Edward G. Latimer, Richard W. Jones