Sweetening Patents (Class 208/189)
-
Patent number: 11866656Abstract: The present application relates to a method for treating a petrol containing sulphur compounds, olefins and diolefins, the method comprising the following steps: a) a step of hydrodesulphurisation in the presence of a catalyst comprising an oxide support and an active phase comprising a group VIB metal and a group VIII metal from, b) a step of hydrodesulphurising at least one portion of the effluent from step a) at a higher hydrogen flow rate/feed ratio and a temperature higher than those of step a) without removing the H2S formed in the presence of a catalyst comprising an oxide support and an active phase consisting of at least one group VIII metal, c) a step of separating the H2S formed in the effluent from step b).Type: GrantFiled: July 6, 2020Date of Patent: January 9, 2024Assignee: IFP ENERGIES NOUVLLESInventors: Clementina Lopez-Garcia, Philibert Leflaive
-
Patent number: 11518947Abstract: The present disclosure generally relates to dispersions useful for scavenging hydrogen sulfide. The dispersions may be anhydrous and contain a solvent and a hydrogen sulfide scavenging compound. The hydrogen sulfide scavenging compound may be hexamine, for example. The solvent may be a C2-8 polyol, such as glycerin.Type: GrantFiled: March 26, 2018Date of Patent: December 6, 2022Assignee: ECOLAB USA Inc.Inventor: Kim R. Solomon
-
Patent number: 10731090Abstract: Processes and apparatuses are disclosed for treating a naphtha stream from a FCC unit comprising passing the naphtha stream to a naphtha splitter column to provide a light naphtha stream and a heavy naphtha stream. The light naphtha stream is reacted in a mercaptan oxidation reactor to provide a demercaptanized naphtha stream. The demercaptanized naphtha stream is stripped in a light stripper column to provide a treated light naphtha stream and a bottoms stream.Type: GrantFiled: July 25, 2018Date of Patent: August 4, 2020Assignee: UOP LLCInventors: Piyush Pahwa, Amit Munjal
-
Patent number: 10633602Abstract: The present disclosure generally relates to scavenging hydrogen sulfide. The disclosure pertains to non-aqueous and non-volatile compositions that include a monolignol alcohol and hydrogen sulfide scavenging compound. The hydrogen sulfide scavenging compound may be hexamine in some aspects. The compositions may also include a C2-8 polyol. The compositions disclosed are stable and can be used, for example, in removing hydrogen sulfide from hot asphalt.Type: GrantFiled: March 26, 2018Date of Patent: April 28, 2020Assignee: ECOLAB USA INC.Inventor: Kim R. Solomon
-
Patent number: 10633599Abstract: An improved contactor/separator process is presented where one or more stages of contact and separation is achieved by providing one or more shroud and disengagement device combinations within a vessel, where the disengagement device is connected to the top of the shroud that contains vertically hanging fibers. A liquid admixture of immiscible fluids is directed co-currently upward through the shroud at flooding velocity or greater, where all of the admixture exits the disengagement device through a coalescing material. Tray supports are used to stack additional shroud and disengagement combinations vertically within the vessel. Each tray allows less dense liquids exiting one disengagement device from a lower shroud and disengagement device combination to enter the bottom of a shroud of a shroud and disengagement device combination position vertically above the lower shroud and disengagement device combination.Type: GrantFiled: January 12, 2018Date of Patent: April 28, 2020Assignee: MERICHEM COMPANYInventors: James F. McGehee, Jeffrey B. Gomach, Baisheng Zou
-
Patent number: 10544282Abstract: Scavenging compounds and compositions useful in reducing sulfide emissions from polymer treated asphalt, such as polyphosphoric acid, are disclosed. The scavengers include hexamethyl-enetetramine, water-free triazine, and water-free 1,3,5-triazine derivatives of formula I. Methods of using the compositions to reduce hydrogen sulfide emissions from asphalt are also disclosed.Type: GrantFiled: November 29, 2017Date of Patent: January 28, 2020Assignee: ECOLAB USA INC.Inventors: Xiaowei Tong, Jennifer L. Sorrells, Prakasa Rao Anantaneni
-
Patent number: 10414651Abstract: Methods, kits, cartridges, and compounds related to generating chlorine dioxide by exposing ClO2? to at least one of an iron porphyrin catalyst or an iron porphyrazine catalyst are described.Type: GrantFiled: August 4, 2016Date of Patent: September 17, 2019Assignee: The Trustees of Princeton UniversityInventors: John T. Groves, Roy Xiao
-
Patent number: 9969660Abstract: The present disclosure provides natural gas and petrochemical processing systems including oxidative coupling of methane reactor systems that integrate process inputs and outputs to cooperatively utilize different inputs and outputs of the various systems in the production of higher hydrocarbons from natural gas and other hydrocarbon feedstocks.Type: GrantFiled: July 8, 2013Date of Patent: May 15, 2018Assignee: SILURIA TECHNOLOGIES, INC.Inventors: Rahul Iyer, Alex Tkachenko, Sam Weinberger, Erik Scher, Guido Radaelli, Hatem Harraz
-
Patent number: 9815720Abstract: A method and system treat contaminated water. In one embodiment, the method comprises treating contaminated water by introducing a methylmorpholine-N-oxide solution to a vessel. The vessel contains the contaminated water and iron oxide. The contaminated water comprises contaminants. In addition, the methylmorpholine-N-oxide solution comprises methylmorpholine-N-oxide and water. The method further comprises contacting the methylmorpholine-N-oxide solution with the contaminated water. In addition, the method comprises treating the contaminated water by allowing the methylmorpholine-N-oxide to react with the contaminants in the presence of the iron oxide.Type: GrantFiled: October 13, 2014Date of Patent: November 14, 2017Assignee: United Laboratories International, LLCInventors: Stephen D. Matza, Jack G. Frost
-
Patent number: 9580367Abstract: The present disclosure provides natural gas and petrochemical processing systems including oxidative coupling of methane reactor systems that integrate process inputs and outputs to cooperatively utilize different inputs and outputs of the various systems in the production of higher hydrocarbons from natural gas and other hydrocarbon feedstocks.Type: GrantFiled: July 8, 2013Date of Patent: February 28, 2017Assignee: SILURIA TECHNOLOGIES, INC.Inventors: Rahul Iyer, Alex Tkachenko, Sam Weinberger, Erik Scher, Guido Radaelli, Hatem Harraz, Fabio R. Zurcher, Joel Gamoras, Dmitry Karshtedt, Greg Nyce
-
Patent number: 9505686Abstract: The present application relates to a process for the selective hydrogenation of a gasoline which contains polyunsaturated compounds and sulphurous light compounds, the process allowing conjointly the hydrogenation of polyunsaturated compounds into mono-unsaturated compounds, increasing weight of the sulphurous light compounds by reaction with the unsaturated compounds, and maximization of the isomerization of the monounsaturated compounds comprising an external C?C double bond into their internal C?C double bond isomer, said process implementing a catalyst containing at least one group VIb metal and at least one group VIII metal deposited on a porous support.Type: GrantFiled: March 27, 2013Date of Patent: November 29, 2016Assignee: IFP Energies nouvellesInventors: Antoine Daudin, Elodie Devers, Julien Gornay, Philibert Leflaive
-
Patent number: 9458392Abstract: In a catalytic treatment process, mercaptans in sour hydrocarbon are oxidized to disulfide oils using an aqueous treatment solution containing a chelated polyvalent metal catalyst, alkali metal hydroxide, and the alkali metal salt of at least one alcohol in a non-dispersive mixing apparatus wherein an upgraded hydrocarbon containing the disulfide oils is produced.Type: GrantFiled: November 3, 2014Date of Patent: October 4, 2016Assignee: MERICHEM COMPANYInventors: Tiejun Zhang, K. Michael Hardy, V. Keith Turner, Ignacio C. Bincaz, Tom Varadi
-
Patent number: 9138658Abstract: The invention concerns the control of solvent systems in processes and apparatus for the separation of aromatic hydrocarbons from non-aromatic hydrocarbons in liquid-liquid extraction, extractive distillation, and the combination thereof.Type: GrantFiled: May 22, 2013Date of Patent: September 22, 2015Assignee: ExxonMobil Chemical Patents Inc.Inventors: John Joseph Monson, Arnold Hee-Sur Choi, Dana Lynn Pilliod
-
Patent number: 9120834Abstract: A membrane separation process using a highly fluorinated polymer membrane that selectively permeates water of an aqueous ionic liquid solution to provide dry ionic liquid. Preferably the polymer is a polymer that includes polymerized perfluoro-2,2-dimethyl-1,3-dioxole (PDD). The process is also capable of removing small molecular compounds such as organic solvents that can be present in the solution. This membrane separation process is suitable for drying the aqueous ionic liquid byproduct from precipitating solutions of biomass dissolved in ionic liquid, and is thus instrumental to providing usable lignocellulosic products for energy consumption and other industrial uses in an environmentally benign manner.Type: GrantFiled: October 29, 2014Date of Patent: September 1, 2015Assignee: CMS TECHNOLOGIES HOLDINGS, INC.Inventors: Daniel Campos, Andrew Edward Feiring, Sudipto Majumdar, Stuart Nemser
-
Publication number: 20150001132Abstract: Disclosed herein are scavenging compounds and compositions useful in applications relating to the production, transportation, storage, and separation of crude oil and natural gas. Also disclosed herein are methods of using the compounds and compositions as scavengers, particularly in applications relating to the production, transportation, storage, and separation of crude oil and natural gas.Type: ApplicationFiled: June 25, 2014Publication date: January 1, 2015Inventors: Jennifer L. Sorrells, Nestor U. Soriano, JR.
-
Publication number: 20140374315Abstract: The present application concerns a process for the treatment of a gasoline containing sulphur-containing compounds and olefins, with the following steps: a) a step for hydrodesulphurization of said gasoline in order to produce an effluent which is depleted in sulphur by passing the gasoline mixed with hydrogen over at least one hydrodesulphurization catalyst; b) a step for separating the partially desulphurized gasoline from the hydrogen introduced in excess as well as the H2S formed during step a); c) a catalytic step for sweetening desulphurized gasoline obtained from step b), which converts residual mercaptans into thioethers via an addition reaction with the olefins.Type: ApplicationFiled: June 17, 2014Publication date: December 25, 2014Applicant: IFP ENERGIES NOUVELLESInventors: Julien GORNAY, Philibert LEFLAIVE, Annick PUCCI, Olivier TOUZALIN
-
Patent number: 8900446Abstract: In a catalytic treatment process, mercaptans in sour hydrocarbon are oxidized to disulfide oils using an aqueous treatment solution containing a chelated polyvalent metal catalyst, alkali metal hydroxide, and the alkali metal salt of at least one alcohol in a non-dispersive mixing apparatus wherein an upgraded hydrocarbon containing the disulfide oils is produced.Type: GrantFiled: January 31, 2011Date of Patent: December 2, 2014Assignee: Merichem CompanyInventors: Tiejun Zhang, K. Michael Hardy, V. Keith Turner, Ignacio C. Bincaz, Tom Varadi
-
Patent number: 8845885Abstract: A method of removing sulfur from sour oil by subjecting sour oil having a first sulfur content to high shear in the presence of at least one desulfurizing agent to produce a high shear treated stream, wherein the at least one desulfurizing agent is selected from the group consisting of bases and inorganic salts, and separating both a sulfur-rich product and a sweetened oil product from the high shear-treated stream, wherein the sulfur-rich product comprises elemental sulfur and wherein the sweetened oil product has a second sulfur content that is less than the first sulfur content. A system for reducing the sulfur content of sour oil via at least one high shear device comprising at least one rotor and at least one complementarily-shaped stator, and at least one separation device configured to separate a sulfur-rich product and sweetened oil from the high shear-treated stream.Type: GrantFiled: August 2, 2011Date of Patent: September 30, 2014Assignee: H R D CorporationInventors: Abbas Hassan, Aziz Hassan, Rayford G. Anthony, Gregory G. Borsinger
-
Patent number: 8815083Abstract: In a process to treat gaseous components obtained from an in situ recovery of liquid hydrocarbons from a hydrocarbonaceous deposit the mercaptans and hydrogen sulfide are separated from each other using lean oil and the hydrogen sulfide further processed to obtain a sulfur-free fuel gas product. The rich oil obtained after treating the gaseous components can be used as a diluent with the liquid hydrocarbons or processed to remove and convert the mercaptans to disulfide oils.Type: GrantFiled: November 29, 2012Date of Patent: August 26, 2014Assignee: Merichem CompanyInventor: John Watson
-
Publication number: 20140197073Abstract: This invention relates to a process for treatment of a gasoline comprising diolefins, olefins, and sulfur-containing compounds including mercaptans, in which: Gasoline is injected into a distillation column comprising at least one reaction zone to produce a desulfurized light gasoline; with the process also comprising the following stages: An intermediate gasoline fraction is drawn off at a level located above the reaction zone; A heavy gasoline comprising the majority of the sulfur-containing compounds is drawn off at the bottom of the column; In a demercaptization reactor, said intermediate gasoline fraction is brought into contact with a second catalyst to produce an effluent that contains sulfides; The effluent that is obtained from the demercaptization reactor is recycled in the distillation column (3).Type: ApplicationFiled: January 9, 2014Publication date: July 17, 2014Applicant: IFP Energies nouvellesInventors: Olivier TOUZALIN, Philibert LEFLAIVE
-
Publication number: 20140174982Abstract: Processes are provided herein for producing naphtha boiling range products with a desired sulfur content by reducing the mercaptan content of the naphtha boiling range products after the products exit a hydroprocessing stage. Due to mercaptan reversion, naphtha boiling range products that contain even small amounts of olefins can have a higher than expected sulfur content after hydroprocessing. In order to reduce or mitigate the effects of mercaptan reversion, microchannel reactors (or microreactors) can be placed in a processing system downstream of a reactor that produces a low sulfur naphtha product. The microreactors can include a coating of metals that have activity for hydrodesulfurization. By passing at least a portion of the naphtha product through the downstream microreactors, the mercaptans formed by reversion reactions can be reduced or eliminated, resulting in a naphtha product with possessing a very low sulfur content.Type: ApplicationFiled: December 3, 2013Publication date: June 26, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Benjamin S. Umansky, Charles R. Bolz, Anjaneya S. Kovvali, Carlos N. Lopez, Rathna P. Davuluri
-
Patent number: 8721872Abstract: A method for thermally cracking an organic acid containing hydrocarbonaceous feed wherein the feed is first processed in a vaporization step, followed by thermal cracking.Type: GrantFiled: March 31, 2009Date of Patent: May 13, 2014Assignee: Equistar Chemicals, LPInventors: Donald H. Powers, Robert S. Bridges, Kenneth M. Webber
-
Patent number: 8703084Abstract: A method and apparatus for eliminating COS and/or CS2 from a hydrocarbon-containing feed stream, and further eliminating H2S from such feed stream or converting all sulfur species in such feed stream to H2S and SO2 to allow for easy subsequent conversion of such H2S and SO2 to elemental sulfur in a Claus reaction. The method comprises: (i) injecting water so that the feed stream contains greater than 10 vol % (water equivalent); (ii) passing the feed stream through catalyst means which hydrogenates COS and/or CS2 to H2S; (iii) injecting O2 so that the stoichiometric ratio of O2 to H2S is at least 0.5:1.0; (iv) passing the stream though a reaction zone having oxidation catalyst means which oxidizes H2S to elemental sulfur or SO2 (depending on the amount of oxygen and water added); where the temperature of the reaction zone is above the elemental sulfur dew point.Type: GrantFiled: February 17, 2012Date of Patent: April 22, 2014Assignee: Archon Technologies Ltd.Inventors: Conrad Ayasse, Ahmed M. Shahin, Alan Ayasse
-
Patent number: 8679203Abstract: Hydrogen sulfide and mercaptans in hydrocarbons, gas mixtures of hydrocarbons and the like may be scavenged therefrom by being brought into intimate contact with a mercaptan scavenger formulation of quaternary ammonium alkoxide or hydroxide in the presence of a high oxidative state metal such as cobalt, iron, chromium and/or nickel. The high oxidative state metal, being an oxidizer, acts as a catalyst when combined with the quaternary ethoxide or hydroxide for improved mercaptan scavenging performance.Type: GrantFiled: November 22, 2010Date of Patent: March 25, 2014Assignee: Baker Hughes IncorporatedInventors: Timothy J. O'Brien, Jerry J. Weers
-
Publication number: 20140034321Abstract: A process comprising receiving a hydrocarbon feed stream comprising carbon dioxide, separating the hydrocarbon feed stream into a light hydrocarbon stream and a heavy hydrocarbon stream, separating the light hydrocarbon stream into a carbon dioxide-rich stream and a carbon dioxide-lean stream, and feeding the carbon dioxide-lean stream into a hydrocarbon sweetening process, thereby increasing the processing capacity of the hydrocarbon sweetening process compared to the processing capacity of the hydrocarbon sweetening process when fed the hydrocarbon feed stream.Type: ApplicationFiled: October 9, 2013Publication date: February 6, 2014Applicant: Pilot Energy Solutions, LLCInventor: Eric Prim
-
Patent number: 8518357Abstract: Methods, systems, and apparatus for managing sulfur are disclosed. In some embodiments, the method comprise the following: obtaining material containing sulfur; refining the material to develop a high sulfur content heavy fraction fuel oil and a low sulfur content light fraction fuel oil; burning the low sulfur content light fraction fuel oil in apparatus that emit to the atmosphere; burning the high sulfur content heavy fraction fuel oil to produce energy thereby generating flue gas containing sulfur oxide; and removing and disposing of sulfur in the flue gas using a sulfur sequestration system that includes utilizing sulfur removed from the flue gas to form a brine material.Type: GrantFiled: May 5, 2009Date of Patent: August 27, 2013Assignee: The Trustees of Columbia University in the City of New YorkInventors: Klaus S. Lackner, Tim A. Rappold
-
Publication number: 20130081325Abstract: The present invention relates to a method of improving a heavy hydrocarbon, such as bitumen, to a lighter more fluid product and, more specifically, to a final hydrocarbon product that is refinery-ready and meets pipeline transport criteria without the addition of diluent. A solid asphaltene by-product is created for easy handling and further processing. The invention is targeted to enhance Canadian bitumen, but has general application in improving any heavy hydrocarbon.Type: ApplicationFiled: September 30, 2011Publication date: April 4, 2013Applicant: MEG ENERGY CORPORATIONInventors: TOM CORSCADDEN, GERALD BRUCE, GREG DIDUCH, DAMIEN HOCKING, DARIUS REMESAT
-
Patent number: 8394261Abstract: Catalysts amenable to oxidizing sulfur compounds and systems and methods of using these catalysts to effect the removal of sulfur from crude oil and crude oil distillates are disclosed. The catalyst is disposed with a titanyl moiety which serves to selectively coordinate sulfur compounds and affect their oxidation. The titanyl may be bound within a polymer or on the surface of a polymer or on the surface or in the pores of an inorganic support. The resulting oxidized sulfur compounds are readily separated from the initial crude oil or crude oil distillate streams by traditional separation techniques arrayed as described in the systems and methods disclosed.Type: GrantFiled: October 31, 2008Date of Patent: March 12, 2013Assignee: Auterra, Inc.Inventors: Kyle E. Litz, Tracey M. Jordan, Mark N. Rossetti, Anthony J. Loughran, Jennifer L. Vreeland
-
Publication number: 20130056391Abstract: A process for selective removal of mercaptan from aviation turbine fuel feed includes mixing aviation turbine fuel feed with hydrogen, at a pressure in a range from 3 bar to 20 bar to obtain a reaction mixture. The reaction mixture is heated at a temperature range of 150° C. to 350° C. to obtain a heated mixture. The heated mixture is reacted with a hydrotreating catalyst in a rector to obtain a reactor effluent, and H2S gas is stripped from the reactor effluent to obtain a stripper bottom product. Moisture is removed from the stripper bottom product to obtain aviation turbine fuel product having less than 10 ppm mercaptan. The aviation fuel product has improved properties such as color and acidity. Embodiments also relate to an aviation turbine fuel product having less than 10 ppm mercaptan prepared by the described process of the present invention.Type: ApplicationFiled: March 16, 2011Publication date: March 7, 2013Applicant: INDIAN OIL CORPORATION LIMITEDInventors: Rajesh Muralidhar Badhe, Alok Sharma, Brijesh Kumar, Santanam Rajagopal, Ravinder Kumar Malhotra, Anand Kumar
-
Patent number: 8357306Abstract: A process for removing a sulfur species from a stream selected from the group consisting of a hydrocarbon stream, an aqueous stream, and mixtures thereof is disclosed herein, which may include introducing a treating mixture into the stream. The treating mixture may include a compound of the general formula selected from the group consisting of: or combinations of compound (I) or compound (II). R1 may be a C1-C30 hydrocarbyl group that is saturated, unsaturated, cyclic or branched, or may contain a heteroatom. ‘A’ may be an oxygen atom or a methylene group. R2 may be a C1-C30 hydrocarbyl group that may be saturated, unsaturated, cyclic or branched, or may contain a heteroatom(s) other than C and H. The treating mixture may reduce the reactive sulfur species in the stream. The sulfur species reduced from the stream may be hydrogen sulfide, mercaptans, polysulfides, or combinations thereof.Type: GrantFiled: December 20, 2010Date of Patent: January 22, 2013Assignee: Baker Hughes IncorporatedInventors: Jianzhong Yang, Matthew T. Barnes, Joseph L. Stark
-
Patent number: 8283507Abstract: A process and apparatus are presented for the removal of carbon monoxide from ethylene streams. The removal of carbon monoxide before selective hydrogenation protects the catalyst in the selective hydrogenation reactor. Carbon monoxide levels are controlled with the water gas shift process to convert the carbon monoxide to carbon dioxide, with the carbon dioxide removed in an acid gas removal process.Type: GrantFiled: November 2, 2010Date of Patent: October 9, 2012Assignee: UOP LLCInventors: David A. Wegerer, Kurt M. Vanden Bussche
-
Patent number: 8277639Abstract: The invention is directed to a process comprising feeding high TAN feedstreams to a steam cracker, whereby naphthenic acids in the feedstreams are substantially converted to CO, CO2, and low amounts of smaller acids (e.g., formic, acetic, propionic, and butyric acids). The feedstream is preferably a high TAN feedstream comprising crude or high TAN feedstream which has previously been subjected to a refinery process to remove resid.Type: GrantFiled: September 20, 2005Date of Patent: October 2, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: John Scott Buchanan, Paul F. Keusenkothen, Stephen Harold Brown, Julian A. Wolfenbarger, James Earl Graham, James N. McCoy
-
Patent number: 8197674Abstract: This invention relates to thioetherification processes for the removal of mercaptans in charge gas streams. In particular, the invention relates to thioetherification processes for the removal of mercaptans using a catalyst comprising palladium and silver.Type: GrantFiled: September 9, 2008Date of Patent: June 12, 2012Assignee: Lummus Technology Inc.Inventors: Thomas Skourlis, Robert J. Gartside, Robert E. Trubac
-
Publication number: 20120111769Abstract: A method of removing sulfur from sour oil by subjecting sour oil having a first sulfur content to high shear in the presence of at least one desulfurizing agent to produce a high shear treated stream, wherein the at least one desulfurizing agent is selected from the group consisting of bases and inorganic salts, and separating both a sulfur-rich product and a sweetened oil product from the high shear-treated stream, wherein the sulfur-rich product comprises elemental sulfur and wherein the sweetened oil product has a second sulfur content that is less than the first sulfur content. A system for reducing the sulfur content of sour oil via at least one high shear device comprising at least one rotor and at least one complementarily-shaped stator, and at least one separation device configured to separate a sulfur-rich product and sweetened oil from the high shear-treated stream.Type: ApplicationFiled: August 2, 2011Publication date: May 10, 2012Applicant: H R D CorporationInventors: Abbas HASSAN, Aziz Hassan, Rayford G. Anthony, Gregory G. Borsinger
-
Publication number: 20120103871Abstract: A method for reducing mercaptan concentration in a liquid hydrocarbon, comprising: contacting a mercaptan-rich liquid hydrocarbon having a first concentration of mercaptan sulfur with a composition comprising an oxidizing agent and water wherein the molar ratio of the oxidizing agent to mercaptan sulfur in the mercaptan-rich liquid hydrocarbon is from 3:1 to 10:1; and separating the water from the liquid hydrocarbon to yield a mercaptan-depleted liquid hydrocarbon having a second concentration of mercaptan sulfur, the second concentration being less than the first concentration; wherein a major amount of mercaptan compounds in the mercaptan-rich liquid hydrocarbon are converted to at least one sulfur oxoacid or salt thereof, having the formula: [RSOx]nY wherein R is a hydrocarbyl group; x is an integer from 1 to 3; n is 1 or 2; and Y is hydrogen, an alkaline metal, or alkaline earth metal.Type: ApplicationFiled: October 28, 2010Publication date: May 3, 2012Inventors: Zunqing He, Zhen Zhou, Lin Li
-
Publication number: 20120043259Abstract: Processes for the extractive removal of mercaptan compounds from hydrocarbon feeds, in which the contact between oxidation catalyst with oxygen and mercaptan in the feed is reduced or eliminated, are described. Oxidation of mercaptan compounds to disulfides in the extraction zone is prevented, thereby overcoming separation inefficiencies associated with the inability to extract disulfides in this zone. The invention advantageously relies on the use of a fixed bed of catalyst in the oxidation or regeneration zone, which is coupled to the extraction zone.Type: ApplicationFiled: August 18, 2010Publication date: February 23, 2012Applicant: UOP LLCInventor: Ralph C. NORTON
-
Patent number: 7758745Abstract: A diesel desulfurization method has various steps including: implementing a modified oxidative desulfurization (UAOD) process. The UAOD has the steps of: mixing diesel fuel with room temperature ionic liquid, oxidant, phase transfer catalyst, and acid catalyst in a tank in a mix; recycling the ionic liquid and recycling the acid catalyst in aqueous phase. A step is to move the sulfur from the diesel fuel in a fluidized bed reactor (FBR) having bed reactor material. The process can be improved with ultrasound during mixing, or a high shear mixer. The bed reactor is preferably acidic alumina for adsorbing oxidized sulfur. The oxidant is preferably hydrogen peroxide (H2O2). The acid catalyst is preferably a mixture of Acetic acid and Tri-fluoro acetic acid.Type: GrantFiled: March 20, 2008Date of Patent: July 20, 2010Inventor: Shun-Sheng Cheng
-
Publication number: 20100084315Abstract: A process for treating a stream of elemental sulphur comprising an organic polysulphide and/or a thiol for smell improvement, the process comprising the following steps: (a) providing a molten stream of elemental sulphur comprising an organic polysulphide and/or a thiol at a temperature in the range of from 120 to 160° C.; (b) admixing a liquid unsaturated compound with the stream of molten elemental sulphur in an amount in the range of from 0.01 to 10.0 wt % based on the weight of sulphur to allow the organic polysulphide and/or thiol to react with the unsaturated compound.Type: ApplicationFiled: October 3, 2007Publication date: April 8, 2010Inventors: Carolus Matthias Anna Maria Mesters, Ronald Jan Schoonebeek, Rob Aloysius Maria Van Trier, Guy Lode Magda Maria Verbist
-
Publication number: 20100059413Abstract: This invention relates to thioetherification processes for the removal of mercaptans in charge gas streams. In particular, the invention relates to thioetherification processes for the removal of mercaptans using a catalyst comprising palladium and silver.Type: ApplicationFiled: September 9, 2008Publication date: March 11, 2010Inventors: Thomas Skourlis, Robert J. Gartside, Robert E. Trubac
-
Patent number: 7645376Abstract: A process for jointly carrying out selective hydrogenation of polyunsaturated compounds into mono unsaturated compounds contained in gasolines, and for transforming light sulphur-containing compounds into heavier compounds by reaction with unsaturated compounds, said process employing a supported catalyst comprising at least one metal from group VIB and at least one non-noble metal from group VIII used in the sulphurized form deposited on a support and having a specific composition and comprising bringing the feed into contact with the catalyst at a temperature in the range of 80° C. to 220° C. at a liquid hourly space velocity in the range of 1 h?1 to 10 h?1 and at a pressure in the range of 0.5 to 5 MPa.Type: GrantFiled: December 21, 2006Date of Patent: January 12, 2010Assignee: Institute Francais du PetroleInventors: Christophe Bouchy, Florent Picard, Nathalie Marchal
-
Patent number: 7470829Abstract: The natural gas arriving through pipe 1 is deacidified by being brought into contact with a solvent in column C2. The solvent charged with acid compounds is regenerated in zone R. The purified gas evacuated by pipe 9 includes some of the solvent. The method enables the solvent contained in the purified gas to be extracted. In zone ZA, the purified gas is brought into contact with a non-aqueous ionic liquid whose general formula is Q+ A?, where Q+ designates an ammonium, phosphonium, and/or sulfonium cation, and A? designates an anion able to form a liquid salt. The solvent-impoverished purified gas is evacuated through pipe 17. The ionic liquid charged with solvent is regenerated by heating in an evaporator DE. The solvents separated from the ionic liquid in evaporator DE are recycled.Type: GrantFiled: February 14, 2005Date of Patent: December 30, 2008Assignee: Institut Francais du PetroleInventors: Renaud Cadours, Fabrice Lecomte, Lionel Magna, Cécile Barrere-Tricca
-
Publication number: 20080073249Abstract: A method of and system for reducing engine environmental atmospheric pollution emissions from a vehicle having a combustion engine utilizing hydrocarbon fuel for at least one of propulsion and auxiliary electrical power is disclosed. The method basically includes providing an unprocessed bulk fuel storage container and a clean processed fuel tank on the vehicle, supplying the engine for propulsion with fuel from the unprocessed fuel storage container when the vehicle is beyond a predetermined distance from an area having environmental restrictions passing a portion of unprocessed fuel through a desulphurization process to fill a clean fuel storage container while the vehicle is in motion and supplying the combustion engine for one of propulsion and auxiliary electrical power from clean fuel in the processed fuel storage container when the vehicle is within an area having environmental restrictions.Type: ApplicationFiled: April 10, 2007Publication date: March 27, 2008Applicant: INTELLIGENT ENERGY, INC.Inventors: Kandswamy Duraiswamy, Anand Chellappa
-
Patent number: 7291258Abstract: A process for concurrently fractionating and hydrotreating a full range naphtha stream.Type: GrantFiled: November 12, 2005Date of Patent: November 6, 2007Assignee: Catalytic Distillation TechnologiesInventors: Gary G. Podrebarac, Mario J. Maraschino, Montri Vichailak
-
Patent number: 7247234Abstract: The essence of the method is that diesel fuel is heated in the process of periodical circulation in a closed circuit including a heat exchanger and a rotor-disc apparatus of open type in centrifugal force field of which processes of mechanical destruction and dispersion run in environment of sucked air with oxygen saturation, simultaneously with processes of separation and homogenization fine filtration is carried out at a filtering porous partition of hydrophobic material with purification fineness 3÷8 micron as well as filtration at a multilayer filter-reactor at temperature 25÷45° C. which comprises granules of multifunctional catalyst alkylating aromatic compounds and a layer of fill of powder of transitional metals or their oxides. Then the treated fuel is stabilized by adding additives on the basis of surface-active substances.Type: GrantFiled: June 20, 2000Date of Patent: July 24, 2007Inventors: Oleg N. Zege, Jury N. Zharchenkov, Tamara N. Mitusova, Alexandr I. Mishin, Andrei S. Popov, Alexandr V. Tsivulin
-
Patent number: 7192565Abstract: The gaseous feed flowing in through line 1 is contacted in contacting zone ZA with a liquid solvent flowing in through line 2. The solvent comprises between 0.001% and 100% by weight of a liquid olefin. Contacting in zone ZA is carried out in the presence of an acid catalyst. The purified gaseous feed is discharged from zone ZA through line 3. The sulfide-laden solvent is discharged through line 4, then regenerated in unit RE. The regenerated solvent is recycled through lines 7 and 2 to zone ZA.Type: GrantFiled: August 2, 2005Date of Patent: March 20, 2007Assignee: Institut Francais du PetroleInventors: Patrick Briot, Renaud Cadours, Sophie Drozdz, Fabrice Lecomte
-
Patent number: 7045038Abstract: There is disclosed a burnable used oil fuel product by the process comprising: (a) obtaining a used oil sample having at least 1% (by weight) aqueous substances; (b) heating the used oil sample to a temperature of from about 20° C. to about 60° C.; and (c) extracting a volume of water from the heated used oil by adding super critical CO2.Type: GrantFiled: September 22, 2000Date of Patent: May 16, 2006Assignee: Industrial Microwave Technologies, Inc.Inventor: Frederick Anthony Schaefer
-
Patent number: 6896795Abstract: The invention relates to a process for the production of gasoline with a low sulfur content that comprises at least the following stages: a1) at least a selective hydrogenation of diolefins, a2) optionally at least one stage that is aimed at increasing the molecular weight of the light sulfur-containing products that are present in the gasoline, b) at least one separation of the gasoline that is obtained in stage a1 or a2 into two fractions: light gasoline and heavy gasoline, c) at least one treatment with heavy gasoline that is separated in stage b on a catalyst that makes it possible to decompose or to hydrogenate at least partially the unsaturated sulfur-containing compounds, d) at least one treatment of the heavy gasoline that is obtained in stage c, without eliminating the H2S that is formed during this stage, on a catalyst that makes it possible to decompose the sulfur-containing compounds and more preferably the linear and/or cyclic saturated compounds.Type: GrantFiled: April 1, 2002Date of Patent: May 24, 2005Assignee: Institut Francais du PetroleInventors: Blaise Didillon, Denis Uzio, Nathalie Marchal
-
Patent number: 6881325Abstract: Economical processes are disclosed for the production of components for refinery blending of transportation fuels by selective oxidation of feedstocks comprising a mixture of hydrocarbons, sulfur-containing and nitrogen-containing organic compounds. Oxidation feedstock is contacted with a soluble quaternary ammonium salt containing halogen, sulfate, or bisulfate anion, and an immiscible aqueous phase comprising a source of hydrogen peroxide, and at least one member of the group consisting of phosphomolybdic acid and phosphotungstic acid, in a liquid reaction mixture under conditions suitable for reaction of one or more of the sulfur-containing and/or nitrogen-containing organic compounds. Blending components containing less sulfur and/or less nitrogen than the oxidation feedstock are recovered from the reaction mixture. Advantageously, at least a portion of the immiscible acid-containing phase is recycled to the oxidation.Type: GrantFiled: February 8, 2001Date of Patent: April 19, 2005Assignee: BP Corporation North America Inc.Inventors: George Ernest Morris, Andrew Richard Lucy, William H. Gong, Monica Cristina Regalbuto, George A. Huff, Jr.
-
Patent number: 6755964Abstract: A process for fixed bed sweetening of petroleum distillates using halogenating metal phthalocyanine as a catalyst comprising impregnating the catalyst on activated charcoal bed by circulating alcoholic alkaline solution of the catalyst through charcoal bed till colorless bed solution is obtained in the effluent, passing the petroleum distillate through the said catalyst loaded charcoal bed along with air or oxygen at a temperature and pressure with liquid hourly space velocity with continuous or intermittent injection of alkali solution such as sodium hydroxide of concentration to obtain the desired low mercaptan level petroleum distillates. The alkaline solution used is selected from methanolic and ethanolic solution of sodium hydroxide. The halogenated metal phthalocyanine catalyst used is selected from dichloro cobalt phthalocyanine and dibromo cobalt phthalocyanine. The petroleum fraction used is selected from diesel, kerosene and FCC gasoline.Type: GrantFiled: March 13, 2001Date of Patent: June 29, 2004Assignee: Council of Scientific & Industrial ResearchInventors: Brij Bahadur Agrawal, Som Nath Puri, Gautam Das, Bir Sain, Bhagwati Prasad Balodi, Sunil Kumar, Anil Kumar, Pushpa Gupta, Jai Prakash, Onkar Singh Tyagi, Turuga Sundara Rama Prasada Rao, Gur Pratap Rai
-
Patent number: 6709639Abstract: An apparatus for the purification of catalytic cracking gasolines containing dienic and/or acetylenic impurities, and mercaptans, said apparatus comprising at least one selective hydrogenation reactor 3 containing at least one fixed catalyst bed, and having at least one line 1 for introducing a feed, at least one effluent outlet line, and a line supplying hydrogen to the reactor, said reactor being followed by at least one stabilization drum 4 connected to said effluent outlet line, the drum having at least one gas outlet line 5 and at least one stabilized effluent outlet line, and said effluent passing into at least one sweetening reactor 8 comprising at least one effluent inlet line 6 and at least one effluent outlet line, said reactor having close thereto at least one oxidizing agent supply line, said apparatus also comprising at least one drum 9 for degassing the effluent from the sweetening reactor 8, said drum 9 having at least one gas outlet line and at least one outlet line 11 for dedienized, stabilizType: GrantFiled: March 9, 2000Date of Patent: March 23, 2004Assignee: Institut Francais du PetroleInventors: Thierry Chapus, Blaise Didillon, Christian Marcilly, Charles Cameron