Separation Of Paraffin From Oil (e.g., Dewaxing) Patents (Class 208/28)
  • Patent number: 4911821
    Abstract: Lubricants of improved characteristics are produced by carrying out a solvent extraction to remove aromatic components after solvent or catalytic dewaxing. Aromatic extraction solvents such as phenol, furfural or N-methyl pyrrolidone may be used. The process is particularly useful with wax-derived lubricants produced by the hydroisomerization of a petroleum wax which has then been dewaxed.
    Type: Grant
    Filed: February 8, 1989
    Date of Patent: March 27, 1990
    Assignee: Mobil Oil Corporation
    Inventors: James R. Katzer, Quang N. Le, Stephen S. Wong
  • Patent number: 4906350
    Abstract: A process is disclosed for the preparation of a lubricating base oil with a high viscosity index and a low pour point by catalytic dewaxing, which process comprises contacting at dewaxing conditions a feedstock containing at least part of the hydrocrackate of a wax-containing mineral oil fraction, which feedstock has a kinematic viscosity at 100.degree. C. of, at most, 10 mm.sup.2 /s, with a dewaxing catalyst. The invention further provides a lubricating mineral base oil comprising hydrocarbons with a boiling point of at least 250.degree. C., and having a viscosity index of at least 125 and a pour point of at most -25.degree. C.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: March 6, 1990
    Assignee: Shell Oil Company
    Inventors: Jacques Lucien, Gilbert Dutot
  • Patent number: 4867861
    Abstract: The pour point and/or cloud point of the lube fractions comprising a waxy hydrocarbon feedstock containing straight and branched chain paraffins is reduced by contacting the feedstock in a dewaxing zone, preferably in the presence of added hydrogen, with a dewaxing catalyst comprising (1) an intermediate pore crystalline molecular sieve having a pore size between about 5.0 Angstroms and about 7.0 Angstroms and (2) a large pore crystalline molecular sieve having a pore size above about 7.0 Angstroms and typically selected from the group consisting of silicoaluminophosphates, ferrosilicates, aluminophosphates and Y zeolites. A hydrocarbon fraction of reduced paraffin content is recovered from the effluent of the dewaxing zone. Preferred intermediate pore crystalline molecular sieves are silicalite and a ZSM-5 type zeolite. Preferred large power crystalline molecular sieves are silicoaluminophosphates such as SAPO-5 and ammonium exchanged and steamed Y zeolites.
    Type: Grant
    Filed: July 21, 1988
    Date of Patent: September 19, 1989
    Assignee: Union Oil Company of California
    Inventors: Suheil F. Abdo, Eric L. Moorhead, John W. Ward
  • Patent number: 4846959
    Abstract: A process is provided wherein premium fuels are manufactured from a high sulfur, low pour point feed and a low sulfur, high pour point feed. The feeds are treated individually (blocked operation) in a catalytic reactor that desulfurizes or dewaxes the feed, depending on temperature, and the effluents are combined. Since cut point limitations due to sulfur or pour point are removed by the process, yield of a fuel (e.g. jet fuel) is materially enhanced.
    Type: Grant
    Filed: August 18, 1987
    Date of Patent: July 11, 1989
    Assignee: Mobil Oil Corporation
    Inventors: Clinton R. Kennedy, Stuart S. Shih
  • Patent number: 4842717
    Abstract: A process is disclosed for eliminating waxy paraffins from hydrocarbon feedstocks having an initial boiling temperature above about 180.degree. C. and containing sulphur, by selective cracking of the straight chain paraffinic hydrocarbons, said process comprising passing said feedstock over a crystalline silica polymorph of the silicalite type under suitable operating conditions for cracking the straight chain paraffins.
    Type: Grant
    Filed: January 28, 1987
    Date of Patent: June 27, 1989
    Assignee: Labofina, S.A.
    Inventors: Jacques F. Grootjans, Pierre J. Bredael
  • Patent number: 4820400
    Abstract: For removing haze from dewaxed hydrocarbon oil mixture boiling in the lubricating oil range which is hazy, the hazy oil mixture is filtered in the filtration stage (201) of a dewaxing plant which is concurrently filtering undewaxed hydrocarbon oil mixture boiling in the lubricating oil range. Prior to filtering, the hazy dewaxed oil mixture is subjected to pretreatment (in pretreatment stage 204) such as to promote removal of haze from the dewaxed oil mixture during filtering. This pretreatment is carried out independently of the undewaxed oil mixture and can involve dilution/chilling with an oil solvent (e.g. liquid propane) and/or introduction of free excess electric charge, for example by charge injection. As an alternative to the pretreatment, the temperature conditions under which filtration takes place may be low enough to promote wax crystallization.
    Type: Grant
    Filed: June 6, 1988
    Date of Patent: April 11, 1989
    Assignee: Exxon Research and Engineering Company
    Inventors: Douglas G. Ryan, Donald B. Trust, Rudolph R. Savory
  • Patent number: 4808300
    Abstract: Waxy oil distillates, preferably waxy petroleum oil distillates, most preferably waxy lube refrigerator, turbine, transformer or other speciality oil distillates which contain appreciable amounts of aromatics and polar molecule contaminants can have wax and aromatics/polars simultaneously and continuously removed from said oil using an adsorbent/desorbent system. The adsorbent system employs a combination of large pore polar adsorbent/hydrophobic molecular sieves. The desorbent system utilizes a combination small diameter polar solvent/large diameter non-polar solvent to regenerate the loaded adsorbent.
    Type: Grant
    Filed: February 13, 1987
    Date of Patent: February 28, 1989
    Assignee: Exxon Research and Engineering Company
    Inventor: Keith C. Yao
  • Patent number: 4752378
    Abstract: A process is provided for converting feedstock comprising hydrocarbon compounds to product comprising hydrocarbon compounds of lower molecular weight than feedstock hydrocarbon compounds over a catalyst comprising porous crystalline material having the structure of ZSM-58. In particular embodiments, the conversion is selective cracking for waxes and the process is useful for reducing the pour point of fuel oils and lubricants.
    Type: Grant
    Filed: March 12, 1987
    Date of Patent: June 21, 1988
    Assignee: Mobil Oil Corporation
    Inventor: Ernest W. Valyocsik
  • Patent number: 4724066
    Abstract: There is provided a catalyst comprising a zeolite component and a microcrystalline, microporous aluminum phosphate component. Examples of the zeolite component are ZSM-5 and zeolite Beta, and an example of an aluminum phosphate component is AlPO.sub.4 -5. The aluminum phosphate component provides increased catalyst activity and lifetime. Also provided for in this disclosure are a method for making the zeolite/aluminum phosphate composite and a process for using this composite in the preparation or conversion of hydrocarbons, e.g., in a dewaxing process.
    Type: Grant
    Filed: December 12, 1985
    Date of Patent: February 9, 1988
    Assignee: Mobil Oil Corporation
    Inventors: Garry W. Kirker, Michael E. Landis, Jeffrey H. Yen
  • Patent number: 4702817
    Abstract: Haze in lube oil is firstly precipitated as wax and ice crystals to form a slurry which is introduced, through inlet (18), into a separation vessel (15) containing a bed of packed aggregate (20) which preferably comprises wax balls, or asphalt or ice chunks. The slurry is indirectly charged with free excess charge which is net unipolar by means of a charge injector 11. The injected charge causes the wax and ice crystals to be electrically driven to and deposited on the aggregate. Periodically, the wax and ice-soiled aggregate is replaced by fresh aggregate and the soiled aggregate can be supplied as feed to a conversion process, which can for example be a catalytic cracking process.
    Type: Grant
    Filed: October 21, 1985
    Date of Patent: October 27, 1987
    Assignee: Exxon Research and Engineering Company
    Inventors: Douglas G. Ryan, Steven Ackerman
  • Patent number: 4560670
    Abstract: A method for the regeneration of end-of-cycle catalysts is provided wherein nitrogen and other deleterious poisons are removed prior to hydrogen treatment by passing over the catalyst bed a stripping mixture consisting of an alkyl amine whose basicity is much greater than that of the indigenous nitrogen compounds found in the catalyst.
    Type: Grant
    Filed: December 9, 1983
    Date of Patent: December 24, 1985
    Assignee: Mobil Oil Corporation
    Inventor: Bruce P. Pelrine
  • Patent number: 4548755
    Abstract: Process for the extractive production of valuable, natural waxes from fossil and/or freshly grown vegetable and/or animal starting material by extraction of the starting material in an extraction stage with a physiologically unobjectionable gas at supercritical pressure and temperature conditions, separation of the extract-containing gas in a separator part by pressure reduction and/or temperature change, periodical or continuous withdrawal of the extract and return of the separated gas to the extraction stage.
    Type: Grant
    Filed: February 24, 1983
    Date of Patent: October 22, 1985
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventors: Egon Stahl, Karl-Werner Quirin
  • Patent number: 4441991
    Abstract: Straight-chain hydrocarbons and slightly branched chain hydrocarbons are selectively converted utilizing highly siliceous porous crystalline materials of the zeolite type having SiO.sub.2 /Al.sub.2 O.sub.3 ratio of greater than 200, unique molecular sieving properties and superior resistance to ammonia deactivation. The catalyst preferably contains acidic cations and can also contain a component having a hydrogenation/dehydrogenation function. The process of this invention is particularly useful for the dewaxing of hydrocarbon oils, including removal of high freezing point paraffins from jet fuel to lower freezing point, as well as improving the octane rating of naphtha fractions.
    Type: Grant
    Filed: October 20, 1982
    Date of Patent: April 10, 1984
    Assignee: Mobil Oil Corporation
    Inventors: Francis G. Dwyer, William E. Garwood
  • Patent number: 4434046
    Abstract: Crude oil, when mildly dewaxed in the absence or presence of added hydrogen, separates into two phases with different pour points. A filtration step, which removes less than 5 percent of the product as solids, prevents this phase separation.
    Type: Grant
    Filed: April 30, 1981
    Date of Patent: February 28, 1984
    Assignee: Mobil Oil Corporation
    Inventors: Costandi A. Audeh, David S. Shihabi
  • Patent number: 4234409
    Abstract: In the production of lubricating oil blend stocks obtained by the distillation, extraction, dewaxing and clay contacting of atmospheric crude distillation column residue, the improvement comprising using a hydrogenated gas oil to supplement the atmospheric crude distillation column residue feedstock.
    Type: Grant
    Filed: February 28, 1979
    Date of Patent: November 18, 1980
    Assignee: Standard Oil Company
    Inventors: Richard D. Schieman, John H. Steffens
  • Patent number: 3975242
    Abstract: A method for electroplating a metal strip to be plated includes continuously running the metal strip through the interior of a plating vessel of a cylindrical form having a rectangular cross section, the upper and lower walls of such vessel being constructed of an insoluble anode material which is to function as an anode, and compulsively circulating a plating solution in a direction counter to the running direction of the metal strip within the plating vessel and an apparatus for carrying out the same, whereby a high speed plating is performed and the replacement of the anodes can be minimized.
    Type: Grant
    Filed: December 16, 1974
    Date of Patent: August 17, 1976
    Assignee: Nippon Steel Corporation
    Inventors: Shozo Matsuda, Tadashi Tanaka, Joji Oka, Saburo Ayusawa, Kiyotoshi Iwasaki, Toshiyuki Teramachi, Toshitake Miyazono
  • Patent number: 3965004
    Abstract: In a system for removing oil from oily water which employs an oil droplet coalescer, a ceramic dewaxer is inserted before the coalescer to remove waxes, asphalts, and similar materials which would otherwise quickly clog the fine holes of the coalescer. The "dirty" ceramic elements of the dewaxer may be easily and efficiently regenerated.
    Type: Grant
    Filed: January 30, 1975
    Date of Patent: June 22, 1976
    Assignee: Sun Shipbuilding & Drydock Company
    Inventor: Daniel C. Garber
  • Patent number: 3960705
    Abstract: Foots oil, the by-product left when high quality wax is recovered by a solvent dewaxing process, is usually used as cracker feed stock. There is disclosed a method of converting it to higher quality lubricant base stock by subjecting such to catalytic hydroprocessing utilizing a ZSM-5 or similarly behaving zeolite catalyst under hydrogen pressure followed by distillation of the product to remove light products such as naphtha, LPG and No. 2 fuel oil therefrom.
    Type: Grant
    Filed: June 17, 1975
    Date of Patent: June 1, 1976
    Assignee: Mobil Oil Corporation
    Inventors: William E. Garwood, John J. Wise