Abstract: Techniques for separating a fuel on-board a vehicle include mixing an input fuel stream and a fluid solvent; separating the mixture into a first liquid fuel stream and a second liquid fuel stream, the first liquid fuel stream including a first portion of the input fuel stream defined by a first auto-ignition characteristic value and the fluid solvent, the second liquid fuel stream including a second portion of the input fuel stream defined by a second auto-ignition characteristic value that is different than the first auto-ignition characteristic value; separating the first liquid fuel stream into the fluid solvent and the first portion of the input fuel stream; directing the first portion of the input fuel stream to a first fuel tank on the vehicle; and directing the second portion of the input fuel stream to a second fuel tank on the vehicle.

Abstract: Methods are provided for producing lubricant base oils from petrolatum. After solvent dewaxing of a brightstock raffinate to form a brightstock base oil, petrolatum is generated as a side product. The petrolatum can be hydroprocessed to form base oils in high yield. The base oils formed from hydroprocessing of petrolatum have an unexpected pour point relationship. For a typical lubricant oil feedstock, the pour point of the base oils generated from the feedstock increases with the viscosity of the base oil. By contrast, lubricant base oils formed from hydroprocessing of petrolatum have a relatively flat pour point relationship, and some of the higher viscosity base oils unexpectedly have lower pour points than lower viscosity base oils generated from the same petrolatum feed. The base oils from petrolatum are also unusual in yielding both high viscosity and high viscosity index and can be generated while maintaining a high yield.

Abstract: A method and system for handling viscous liquid crude hydrocarbons is disclosed. The method involves (a) solvent deasphalting at least a portion of an asphaltene-containing liquid crude hydrocarbon feedstock to form an asphaltene fraction and a deasphalted oil (DAO) fraction essentially free of asphaltenes; (b) adjusting the density of the asphaltene fraction to substantially the same density of a carrier for the asphaltene fraction; (c) forming coated asphaltene particles from the asphaltene fraction of step (b); (d) slurrying the coated asphaltene particles with the carrier; and (e) transporting the slurry to a treatment facility or a transportation carrier.

Abstract: The present invention provides a process to prepare a residual base oil, which process at least comprises the following steps: (a) providing a mineral bright stock waxy raffinate; (b) combining the mineral bright stock waxy raffinate provided in step (a) with a catalytically dewaxed residual Fischer-Tropsch derived base oil to obtain a mixture; and (c) solvent dewaxing the mixture obtained in (b) to obtain a residual base oil, wherein the weight ratio of the mineral bright stock waxy raffinate to the catalytically dewaxed residual Fischer-Tropsch derived base oil in step (b) is in the range of from 75:25 to 35:65. In another aspect the present invention provides a residual base oil obtainable by the process.

Abstract: In a hydrocarbon upgrading process, a hydrocarbon feed is treated in at least one of a steam cracker, catalytic cracker, coker, hydrocracker, and reformer under suitable conditions to produce a first stream comprising olefinic and aromatic hydrocarbons. A second stream composed mainly of C4 to C12+ olefinic and aromatic hydrocarbons is recovered from the first stream and blended said second stream with a residual fraction from a steam cracker or an atmospheric or vacuum distillation unit to produce a third stream. The third stream is then catalytically pyrolyzed in a reactor under conditions effective to produce a fourth stream having an increased benzene and/or toluene content compared with said second stream and a C3-olefin by-product. The C3-olefin by-product is recovered and benzene and/or toluene are recovered from the fourth stream.

Abstract: Deasphalted residual oil (DAO) and the aromatics-rich extract that is derived from DAO have low polycyclic aromatics contents, relatively low aniline points, and high flash points. They form blending stocks that improve properties of mixed feedstocks to consistently produce environmentally qualified rubber processing oil (RPO) by extraction under low solvent-to-oil ratios and moderate extraction temperatures. Distilling a petroleum crude oil under atmospheric pressure generates a bottom residual oil which is then subject to vacuum distillation to yield a bottom residual oil. DAO is produced by removing the asphalt from the vacuum bottom residual oil through extraction with light paraffinic solvent. The extract of DAO is a co-product in the production of the bright stock of the lubricating oil through extraction. The feedstock is mixed with the extract from a petroleum fraction boiling in lube oil range.

Abstract: A process for treating bitumen froth with paraffinic solvent is provided which uses three stages of separation. Froth and a first solvent are directed to a first stage at a solvent/bitumen ratio for precipitating few or substantially no asphaltenes. A first stage underflow is directed to a second stage and a first stage overflow is directed to a third stage. A second stage underflow is directed to waste tailings and the second stage overflow joins the first stage overflow. A third stage underflow is recovered as an asphaltene by-product and a third stage overflow is recovered as a diluted bitumen product. At least a second solvent is added to one or both of the second or third stages for controlling a fraction of asphaltenes in the third stage underflow. Asphaltene loss to waste tailings is minimized and asphaltenes are now recovered as asphaltene by-product.

Abstract: A method for cross connecting the lean solvent supply lines between the liquid liquid extraction (LLE) and the extractive distillation (ED) processes thereby using the LLE column as the outlet for removing accumulated heavy hydrocarbons (HCs) and polymeric materials from the solvent loop of both processes to maintain their solvent performance. The unique capabilities of the LLE column in rejecting heavy HCs from the solvent into a raffinate product stream that leaves the system enable the removal of the accumulated heavy HCs and polymeric materials from the closed solvent loop of the ED process when their lean solvent loop are cross connected. Cross connection requires minimum equipment change. In the revamped system, the solvent recovery column (SRC) in LLE process supplies lean solvent for the extractive distillation column while the SRC of the ED process supplies lean solvent for LLE column.

Abstract: A method for recovering base oil from waste lubricating oil by separating base oil range constituents from a waste lubricating oil mixture, thereafter separating higher quality base oil constituents and lower quality base oil constituents from the base oil recovered from the waste lubricating oil mixture and thereafter treating the lower quality base oil constituents to produce marketable base oil. The total base oil produced from a waste lubricating oil mixture by this process is greater than the quantity producible by previous processes using only base oil separation from the waste lubricating oil mixture or processes which use only treatment of the base oil recovered from the waste lubricating oil mixture to produce the product base oil.

Abstract: Deasphalted residual oil (DAO) and the aromatics-rich extract that is derived from DAO have low polycyclic aromatics contents, relatively low aniline points, and high flash points. They form blending stocks that improve properties of mixed feedstocks to consistently produce environmentally qualified rubber processing oil (RPO) by extraction under low solvent-to-oil ratios and moderate extraction temperatures. Distilling a petroleum crude oil under atmospheric pressure generates a bottom residual oil which is then subject to vacuum distillation to yield a bottom residual oil. DAO is produced by removing the asphalt from the vacuum bottom residual oil through extraction with light paraffinic solvent. The extract of DAO is a co-product in the production of the bright stock of the lubricating oil through extraction. The feedstock is mixed with the extract from a petroleum fraction boiling in lube oil range.

Abstract: A dewatered ethanol residue regenerable and non-regenerable sorbent for the removal of acid gas from hydrocarbon production gas streams and the process for the removal of acid gas from hydrocarbon gas. The process includes the steps of obtaining residue from the distillation of ethanol; de-watering the residue; mixing the de-watered residue with an amine; and, contacting the hydrocarbon gas with the dewatered residue/amine mixture.

Abstract: An energy efficient, high throughput process for aromatics recovery can be readily implemented by revamping existing sulfolane solvent extraction facilities, or constructing new ones, so as to incorporate unique process operations involving liquid-liquid extraction and extractive distillation. Current industrial sulfolane solvent based liquid-liquid extraction processes employ a liquid-liquid extraction column, an extractive stripping column, a solvent recovery column, a raffinate wash column, and a solvent regenerator. The improved process for aromatic hydrocarbon recovery from a mixture of aromatic and non-aromatic hydrocarbons requires transformation of the extractive stripping column into a modified extractive distillation column. The revamping incorporates the unique advantages of liquid-liquid extraction and extractive distillation into one process to significantly reduce energy consumption and increase process throughput.

Abstract: A fuel composition useful for operating a jet engine or a diesel engine containing a petroleum derived kerosene fuel and a Fischer-Tropsch derived kerosene fuel is provided. The Fischer-Tropsch derived kerosene fuel contains normal and iso-paraffins in a weight ratio of greater than 1:1 and/or the freeze point of the composition is lower than the freeze points of both of the petroleum derived kerosene fuel and the Fischer-Tropsch derived kerosene fuel.

Abstract: An energy efficient, high throughput process for aromatics recovery can be readily implemented by revamping existing sulfolane solvent extraction facilities, or constructing new ones, so as to incorporate unique process operations involving liquid-liquid extraction and extractive distillation. Current industrial sulfolane solvent based liquid-liquid extraction processes employ a liquid-liquid extraction column, an extractive stripping column, a solvent recovery column, a raffinate wash column, and a solvent regenerator. The improved process for aromatic hydrocarbon recovery from a mixture of aromatic and non-aromatic hydrocarbons requires transformation of the extractive stripping column into a modified extractive distillation column. The revamping incorporates the unique advantages of liquid-liquid extraction and extractive distillation into one process to significantly reduce energy consumption and increase process throughput.

Abstract: The present invention is a separation method and system in which granulation of coupled post-extraction asphalt residue is used to achieve deep separation of heavy oil. A dispersion solvent is introduced into the asphalt phase after separation by solvent extraction and the asphalt phase undergoes rapid phase change in a gas-solid separator and is dispersed into solid particles while the solvent vaporizes, resulting in low temperature separation of asphalt and solvent with adjustable size of the asphalt particles. The separation method of this invention also includes a three-stage separation of heavy oil feedstock, in which the deasphalted oil phase separated from heavy oil is treated with supercritical solvent and results in the further separation of the resin portion of the deasphalted oil, maximizing the yield and quality of the deasphalted oil.

Abstract: The invention relates to a process, including removal of resins, for the treatment of a hydrocarbon charge, at least 80% of the compounds of which have a boiling point which is above or equal to 340° C., in which process: the charge is sent to a fractionation stage during which the recovery takes place of at least one heavy fraction and at least one light fraction, at least some of the heavy fraction is sent to an extraction stage during which resins contained in said heavy fraction are extracted, and a purified fraction is recovered, a mixture is made which comprises at least part of the purified fraction which was obtained in the extraction stage and at least one light fraction which was obtained in the fractionation stage, and the mixture thus obtained is sent to a cracking stage.

Abstract: In an atmospheric fractionator, the number of theoretical stages are increased in the upper light distillate flash zone and in the middle heavy distillate flash zone. The middle distillate pumparound circuit has been eliminated. The reflux to distillate ratio for the light distillate as well as the effluent feed temperature have been substantially increased. As a result, increased yields for middle distillate (e.g. kerosene) and heavy distillate (eg diesel) have been achieved which more than offset the increased energy consumption used for the higher feed temperature In the example of hydrocracking technology, the improved fractionation has benefits in the hydrocracking unit outside of the fractionation unit Increased fractionation efficiency reduces the severity in the hydrocracking unit reactor catalyst and less hydrogen is consumed. The invention can be applied to several other refining technologies besides hydrocracking.

Abstract: In a process for deacidifying a fluid hydrocarbon stream which comprises carbon dioxide (CO2) and/or other acid gases as impurities, the fluid stream is brought into intimate contact with an absorption liquid in an absorption or extraction zone (12), the substantially purified fluid stream and the absorption liquid which is loaded with CO2 and/or other acid gases are separated from one another, and the absorption liquid is subsequently regenerated and then again fed to the absorption extraction zone (12). To regenerate the absorption liquid, the loaded absorption liquid is first expanded in a first low-pressure expansion stage (22) to a pressure of from 1 to 2 bar (absolute). The partially regenerated absorption liquid is then heated in a heat exchanger (20) and then, in a second low-pressure expansion stage (29), again expanded to a pressure of from 1 to 2 bar (absolute).

Abstract: A method for producing a process oil is provided in which a napthenic rich feed is enriched with an aromatic extract oil. The enriched feed is then subjected to a solvent extraction thereby providing a process oil.

Abstract: In a solvent refining process a naphthenic lubricating oil feedstock is solvent extracted to yield a primary aromatics-lean raffinate and a primary aromatics-rich extract. Polynuclear aromatic content of primary raffinate is controlled by manipulating extraction temperature and solvent dosage. Primary extract is separated (settled) to form a secondary raffinate and a secondary extract. Secondary raffinate is recycled to solvent extraction. The refractive index of secondary raffinate is controlled by manipulating settling temperature and antisolvent dosage. The refractive index of secondary raffinate is maintained at or below the refractive index of feedstock. An improved yield of primary raffinate of a specified polynuclear aromatic content is achieved.

Abstract: The present invention provides an apparatus for preparing and treating a heavy oil extraction solvent. A solvent fraction is separated from a crude oil and combined with a slip stream of rerun solvent taken from an extraction process solvent recycle system. The solvent fraction and rerun solvent are fractionated to provide a purified extraction solvent. The purified extraction solvent is then utilized in the heavy oil extraction process.

Abstract: The present invention provides a method and apparatus for preparing and treating a heavy oil extraction solvent. A solvent fraction is separated from a crude oil and combined with a slip stream of rerun solvent taken from an extraction process solvent recycle system. The solvent fraction and rerun solvent are fractionated to provide a purified extraction solvent. The purified extraction solvent is then utilized in the heavy oil extraction process.

Abstract: A process for the removal of basic heterocyclic nitrogen compounds from petroleum oils which comprises:(a) contacting said petroleum oils containing basic heterocyclic nitrogen compounds with an aqueous solution of a first solvent comprising concentrated acid at extraction conditions in a first extract zone,(b) separating the product of step (a) into a raffinate product stream comprising hydrocarbons having a lean content of basic heterocyclic nitrogen compounds and residual acid levels, and a first extract phase comprising hydrocarbons, water and acid having a substantial content of basic heterocyclic nitrogen compounds,(c) flashing said first extract phase to remove bulk first solvent.

Abstract: The process for production of an aromate concentrate for use as a blending component for gasification fuel includes subjecting another feed hydrocarbon mixture to an extractive distillation using N-substituted morpholines as selective solvent in a extractive distillation column. Low-boiling non-aromates with a boiling range up to about 105.degree. C. practically completely and higher-boiling non-aromates with a boiling range between about 105.degree. and 160.degree. C. to a substantial extent are discharged as a raffinate from the top of the extractive distillation column. The extract bottoms from the extractive distillation are fed to a solvent stripping column where the solvent is at least partially recovered from other hydrocarbons. To eliminate condensation and polymerization products due to components with a boiling point over 170.degree. C.

Abstract: A coal liquefaction system is disclosed with a novel preasphaltene recycle from a supercritical extraction unit to the slurry mix tank wherein the recycle stream contains at least 90% preasphaltenes (benzene insoluble, pyridine soluble organics) with other residual materials such as unconverted coal and ash. This subject process results in the production of asphaltene materials which can be subjected to hydrotreating to acquire a substitute for No. 6 fuel oil. The preasphaltene-predominant recycle reduces the hydrogen consumption for a process where asphaltene material is being sought.

Abstract: This invention relates to an improved process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal.The claimed improved process includes the hydrocracking of the light SRC mixed with a suitable hydrocracker solvent. The recycle of the resulting hydrocracked product, after separation and distillation, is used to produce a solvent for the hydrocracking of the light solvent refined coal.

Abstract: An improved SRC-I two-stage coal liquefaction process which improves the product slate is provided. Substantially all of the net yield of 650.degree.-850.degree. F. heavy distillate from the LC-Finer is combined with the SRC process solvent, substantially all of the net 400.degree.-650.degree. F. middle distillate from the SRC section is combined with the hydrocracker solvent in the LC-Finer, and the initial boiling point of the SRC process solvent is increased sufficiently high to produce a net yield of 650.degree.-850.degree. F. heavy distillate of zero for the two-stage liquefaction process.

Abstract: The recovery of hydrocarbon values from high metals content feeds can be carried out more efficiently via supercritical extraction with recycle of a portion of the asphalt product and proper control of the use of countercurrent solvent flow to said extraction.

Abstract: A solvent refining process utilizing N-methyl-2-pyrrolidone as solvent in which primary extract from the extraction zone is cooled to form a secondary raffinate and secondary extract and the secondary and primary raffinates are blended to produce an increased yield of product of desired quality. In a preferred embodiment of the process, the lubricating oil feedstock to the process is first contacted with a stripping medium previously used in the process for the recovery of solvent from at least one of the product streams whereby solvent contained in said stripping medium is recovered therefrom.

Abstract: The invention concerns improvements in the process of U.S. Pat. No. 3,870,625 for treating polluted lubricating oil. Previous to said treatment, the used lubricating oil is injected, preferably at a plurality of levels, into at least one reservoir containing liquid propane, where it is left for a time necessary for its dissolution and for its primary separation from the insoluble impurities.

Abstract: Residual oils are upgraded to lube oil base stocks by a combination process involving deasphalting, solvent extraction and hydrocracking arranged to particularly promote the efficient production of lube oil products.