Solvent Extraction Patents (Class 208/45)
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Patent number: 7981277Abstract: A method for dewatering and deasphalting a hydrocarbon feed is provided. A hydrocarbon feed containing one or more hydrocarbons, asphaltenes and water can be mixed or otherwise combined with one or more solvents. The addition of the solvent sufficiently decreases the density of the hydrocarbon feed to enable gravity settling of the water phase, providing an oil phase containing one or more hydrocarbons, asphaltenes and solvents. The asphaltenes can be separated from the oil phase to provide an asphaltene mixture containing asphaltenes and a portion of the solvents and a deasphalted oil containing one or more hydrocarbons and the balance of the solvents. The solvents can be separated from the asphaltenes and deasphalted oil, and recycled to the initial mixing step wherein the solvent is mixed or otherwise combined with one or more solvents.Type: GrantFiled: December 27, 2007Date of Patent: July 19, 2011Assignee: Kellogg Brown & Root LLCInventors: Anand Subramanian, Raymond Floyd
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Patent number: 7964090Abstract: Systems and methods for processing hydrocarbons are provided. A hydrocarbon containing one or more asphaltenes and one or more non-asphaltenes can be mixed with a solvent. The ratio of the solvent to the hydrocarbon can be about 2:1 to about 10:1. The asphaltenes can be selectively separated from the non-asphaltenes. A portion of the asphaltenes can be vaporized in the presence of gasified hydrocarbons and combustion gas. A portion of the asphaltenes can be cracked at a temperature sufficient to provide a cracked gas. Liquid asphaltenes, solid asphaltenes, or both can be deposited onto one or more solids to provide one or more hydrocarbon containing solids. The cracked gas can be selectively separated from the hydrocarbon containing solids. A portion of the hydrocarbon containing solids can be combusted to provide the combustion gas. The hydrocarbon containing solids can be gasified to provide the gasified hydrocarbons and to regenerate the solids.Type: GrantFiled: May 28, 2008Date of Patent: June 21, 2011Assignee: Kellogg Brown & Root LLCInventor: Rashid Iqbal
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Patent number: 7909989Abstract: A method and a system for obtaining bitumen from tar sand are disclosed. The disclosed method can include two extraction steps, such as a first extraction step using a light aromatic solvent and a second extraction step using a volatile hydrocarbon solvent. The light aromatic solvent and the volatile hydrocarbon solvent both can be recycled and used in multiple extractions. Each extraction and recycling step can include a separation. The disclosed system can include separators configured to perform these separations. Some of these separators also can function as mixers. Using the disclosed method and system, it is possible to achieve a high degree of bitumen recovery while minimizing undesirable complications, such as swelling of clays in the tar sand and/or precipitation of asphaltenes.Type: GrantFiled: October 12, 2005Date of Patent: March 22, 2011Assignee: Marathon Oil Canada CorporationInventors: Willem P. C. Duyvesteyn, Raymond L. Morley, James S. Hanson
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Publication number: 20110011769Abstract: A method of delivering feed, for example a paraffinic solvent treated bitumen froth, to a separation vessel, for example a froth separation unit (FSU). The feed is delivered from one or more side inlets that may be substantially normal to, and flush with, the wall of the vessel. In contrast to certain conventional feed systems used in gravity separators which use a distributor plate to widely distribute the feed with a vessel, the feed is delivered such that it flows down the inside wall of the vessel. This feed delivery is characterized by a Richardson number of greater than 1.0. Such feed delivery is particularly useful where the feed has particles with a bi-modal size distribution to be separated from an overflow stream. The gentle flow serves to mitigate the upward flux of the smaller particles, for example mineral solids, by being trapped below the larger particles, for example precipitated asphaltene aggregates.Type: ApplicationFiled: May 14, 2010Publication date: January 20, 2011Inventors: Clay R. Sutton, Ken N. Sury, Darwin Edward Kiel, John Khai-Quang Diep
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Publication number: 20100326883Abstract: Solvent deasphalting (SDA) is used to prepare a heavy hydrocarbon feed for further upgrading. An overhead deasphalted oil (DAO) stream is prepared for catalytic upgrading and an asphaltene stream is prepared for slurry hydrocracking (SHC). SHC product can be further deasphalted and the DAO can be separated from solvent in an upstream extraction column.Type: ApplicationFiled: June 30, 2009Publication date: December 30, 2010Inventors: Mark Van Wees, Robert S. Haizmann, Daniel B. Gillis
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Patent number: 7854836Abstract: A process for upgrading a heavy hydrocarbon includes the steps of obtaining a heavy hydrocarbon; contacting the heavy hydrocarbon with a solvent at upgrading conditions so as to produce a first product comprising a mixture of upgraded hydrocarbon and solvent and a second product comprising asphaltene waste, water and solvent; and feeding the first product to a separator to separate the upgraded hydrocarbon from the solvent. A system is also provided.Type: GrantFiled: November 21, 2006Date of Patent: December 21, 2010Assignee: INTEVEP, S.A.Inventors: Manuel Chirinos, Felix Silva, Gerson Siachoque, Miguel Marquina, Miguel A. Paraco, Galanda Morfes, Carlos Conde
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Patent number: 7811444Abstract: A method for processing asphaltenes is disclosed. The method can include separating asphaltenes from an asphaltene-containing composition and oxidizing the separated asphaltenes to form oxidation products. Alternatively, the method can include oxidizing asphaltenes within an asphaltene-containing composition without first separating the asphaltenes. Once formed, the oxidation products can be combined with other hydrocarbons. The amount of oxidation can be limited to an amount sufficient to produce a mixture suitable for the desired application. This method can be used to upgrade asphaltenes from a variety of sources, including oil sands. The oxidation step can be performed, for example, by introducing an oxidizing agent and, in some cases, a catalyst into the asphaltenes. A solvent or miscibility agent also can be introduced to improve mixing between the oxidizing agent and the asphaltenes.Type: GrantFiled: June 8, 2006Date of Patent: October 12, 2010Assignee: Marathon Oil Canada CorporationInventors: Willem P. C. Duyvesteyn, Raymond L. Morley
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Publication number: 20100243518Abstract: Integrated slurry hydrocracking (SHC) and solvent deasphalting (SDA) methods for making slurry hydrocracking (SHC) distillates are disclosed. Representative methods involve passing a slurry comprising a vacuum column resid, a recycled, deasphalted oil obtained from SDA, and a solid particulate through an SHC reaction zone in the presence of hydrogen to obtain the SHC distillate. Fractionation or distillation in the SHC product recovery section yields a combined SHC gas oil/SHC pitch stream that is sent to SDA. In a representative embodiment, vacuum distillation in the SHC product recovery is avoided, thereby eliminating equipment that is often most susceptible to fouling.Type: ApplicationFiled: March 25, 2009Publication date: September 30, 2010Inventors: Paul R. ZIMMERMAN, Mark VAN WEES, Robert S. HAIZMANN, Milan SKRIPEK
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Patent number: 7749378Abstract: Disclosed is a process for the upgrading of heavy oils and bitumens, where the total feed to the process can include heavy oil or bitumen, water, and diluent. The process can include the steps of solvent deasphalting 110 the total feed 105 to recover an asphaltene fraction 116, a deasphalted oil fraction 118 essentially free of asphaltenes, a water fraction 112, and a solvent fraction 114. The process allows removal of salts from the heavy oils and bitumens either into the aqueous products or with the asphaltene product.Type: GrantFiled: June 21, 2005Date of Patent: July 6, 2010Assignee: Kellogg Brown & Root LLCInventors: Rashid Iqbal, Anshumali, Raymond H. Floyd
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Patent number: 7744743Abstract: A feedstream comprising tar is fed to a solvent deasphalter wherein it is contacted with a deasphalting solvent or fluid to produce a composition comprising a mixture or slurry of solvent containing a soluble portion of the tar, and a heavy tar fraction comprising the insoluble portion of the tar. These fractions may be separated in the deasphalter apparatus, such as by gravity settling wherein the heavy tar fraction is taken off as bottoms, and the solvent-soluble fraction taken as overflow or overheads with the solvent. The overflow or overheads is sent to a solvent recovery unit, such as a distillation apparatus, wherein solvent is recovered as overheads and a deasphalted tar fraction is taken off as a sidestream or bottoms. The solvent or a portion thereof, recovered as overheads, may be then be recycled to the solvent deasphalter, or in a preferred embodiment, at least a portion of the solvent is steam cracked to produce a product comprising light olefins.Type: GrantFiled: October 30, 2006Date of Patent: June 29, 2010Assignee: Exxonmobil Chemical Patents Inc.Inventors: James N. McCoy, Paul F. Keusenkothen, Alok Srivastava
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Patent number: 7736493Abstract: The present invention relates to a process for improving a deasphalting unit process by producing an improved feedstream for the deasphalting process via ultrafiltration of a vacuum resid-containing feedstream. In particular, the present invention produces an improved quality feedstream to a solvent deasphalting process which results in improved deasphalted oil (DAO) production rates and/or higher quality deasphalted oils. The present invention can be particularly beneficial when used in conjunction with an existing deasphalting equipment to result in improved deasphalted oil (DAO) production rates and/or higher quality deasphalted oils from the existing deasphalting equipment without the need for significant equipment modifications to the existing deasphalting unit.Type: GrantFiled: October 30, 2007Date of Patent: June 15, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Daniel P. Leta, Lisa M. Rogers, Merryl J. Miranda, Keith K. Aldous, Stephen M. Cundy, MaryKathryn Lee, Edward W. Corcoran
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Publication number: 20100096297Abstract: A process for treating bitumen froth with paraffinic solvent is provided which uses three stages of separation. Froth and a first solvent are directed to a first stage at a solvent/bitumen ratio for precipitating few or substantially no asphaltenes. A first stage underflow is directed to a second stage and a first stage overflow is directed to a third stage. A second stage underflow is directed to waste tailings and the second stage overflow joins the first stage overflow. A third stage underflow is recovered as an asphaltene by-product and a third stage overflow is recovered as a diluted bitumen product. At least a second solvent is added to one or both of the second or third stages for controlling a fraction of asphaltenes in the third stage underflow. Asphaltene loss to waste tailings is minimized and asphaltenes are now recovered as asphaltene by-product.Type: ApplicationFiled: October 20, 2009Publication date: April 22, 2010Applicant: TOTAL E&P CANADA LTD.Inventors: Geoff STEVENS, Ray REIPAS
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Patent number: 7691256Abstract: Heavy hydrocarbon charges are converted in a deasphalting section in the presence of solvents and obtaining two streams, one consisting of deasphalted oil and the other one containing asphaltenes, mixing the deasphalted oil stream with a hydrogenation catalyst and passing the thus obtained mixture to a hydroprocessing section containing hydrogen or hydrogen/H2S, mixing the stream consisting of asphaltenes discharged from the deasphalting section with an appropriate hydrogenation catalyst and passing the obtained mixture to a second hydroprocessing section where it is reacted with hydrogen or a mixture of hydrogen and H2S, passing both the stream containing the reaction product with dispersed catalyst from the hydroprocessing section and the stream containing the reaction product with dispersed catalyst from the second hydroprocessing section, to one or more distillation or flash stages, whereby the more volatile fractions are separated from the distillation residue (tar) or from the liquid discharged from theType: GrantFiled: December 20, 2005Date of Patent: April 6, 2010Assignees: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.Inventors: Romolo Montanari, Mario Marchionna, Sergio Rosi, Nicoletta Panariti, Alberto Delbianco
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Patent number: 7662275Abstract: The present disclosure relates to a system and method of providing water management and utilization during the process of dewatering and retorting of oil shale. More specifically, the process described relates to co-producing potable and non-potable water, for various uses, during the extraction of petroleum from shale oil deposits. Generally, the process allows the production of multiple streams of waters or varying salinity and pressures at least one of which is of high enough pressure for reinsertion into geological formations or reservoirs, and another which may supply a potable water source. In one embodiment, the high pressure required for reinserting the non-potable water into geological formation or reservoirs may be utilized for producing the potable water supply. In another embodiment, the non-potable water supply may also be used for entraining and sequestering undesired emissions, such as CO2.Type: GrantFiled: May 21, 2007Date of Patent: February 16, 2010Assignee: Colorado School of MinesInventor: John R. Dorgan
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Patent number: 7625479Abstract: A binder pitch material includes a petroleum pitch and asphalt fraction obtained from petroleum crude oil and has a significantly lower polycyclic aromatic hydrocarbon composition than a coal tar pitch having a like softening point. The pitch material is useful as a binder material for various applications such as clay pigeons.Type: GrantFiled: June 12, 2008Date of Patent: December 1, 2009Assignee: Marathon Ashland Petroleum LLCInventors: Melvin D. Kiser, David C. Boyer
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Patent number: 7622035Abstract: A method of deresinating a crude oil comprises contacting the crude oil with a carbon dioxide containing fluid, the crude oil having an initial API gravity and comprising an oil phase, resins, and asphaltenes, and wherein the carbon dioxide containing fluid enters the oil phase of the crude oil in a manner such that the resins and asphaltenes precipitate out of the crude oil such that the final API gravity of the crude oil is higher than the initial API gravity of the crude oil.Type: GrantFiled: September 13, 2001Date of Patent: November 24, 2009Assignee: North Carolina State UniversityInventors: Nael Naguib Zaki, Peter Kelley Kilpatrick, Ruben Guillermo Carbonell
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Patent number: 7597794Abstract: The present invention is a separation method and system in which granulation of coupled post-extraction asphalt residue is used to achieve deep separation of heavy oil. A dispersion solvent is introduced into the asphalt phase after separation by solvent extraction and the asphalt phase undergoes rapid phase change in a gas-solid separator and is dispersed into solid particles while the solvent vaporizes, resulting in low temperature separation of asphalt and solvent with adjustable size of the asphalt particles. The separation method of this invention also includes a three-stage separation of heavy oil feedstock, in which the deasphalted oil phase separated from heavy oil is treated with supercritical solvent and results in the further separation of the resin portion of the deasphalted oil, maximizing the yield and quality of the deasphalted oil.Type: GrantFiled: November 1, 2005Date of Patent: October 6, 2009Inventors: Suoqi Zhao, Chunming Xu, Ren′an Wang, Zhiming Xu, Xuewen Sun, Keng H. Chung
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Patent number: 7579303Abstract: A method for reducing the viscosity and toluene equivalence of an oil containing asphaltenes comprises the steps of: a) mixing with the oil, a polar solvent, and an asphaltene dispersant additive wherein the weight ratio of oil:polar solvent is in the range of 10:0.1 to 10:5, the asphaltene dispersant additive is at a treat rate in the range of 0.025 to 5 weight percent based on the weight of the oil, and then, b) removing at least 90 wt % of the polar solvent from the mixture of oil, polar solvent and the asphaltene dispersant additive to provide upgraded oil with reduced viscosity and toluene equivalence.Type: GrantFiled: July 1, 2005Date of Patent: August 25, 2009Assignee: Exxonmobil Research and Engineering CompanyInventors: Ramesh Varadaraj, Cornelius Hendrick Brons
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Patent number: 7566394Abstract: A solvent deasphalting of crude oil or petroleum heavy fractions and residues is carried out in the presence of a solid adsorbent, such as clay, silica, alumina and activated carbon, which adsorbs the contaminants and permits the solvent and oil fraction to be removed as a separate stream from which the solvent is recovered for recycling; the adsorbent with contaminants and the asphalt bottoms is mixed with aromatic and/or polar solvents to desorb the contaminants and washed as necessary, e.g., with benzene, toluene, xylenes and tetrahydrofuran, to clean adsorbant which is recovered and recycled; the solvent-asphalt mixture is sent to a fractionator for recovery and recycling of the aromatic or polar solvent. The bottoms from the fractionator include the concentrated PNA and contaminants and are further processes as appropriate.Type: GrantFiled: October 20, 2006Date of Patent: July 28, 2009Assignee: Saudi Arabian Oil CompanyInventor: Omer Refa Koseoglu
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Publication number: 20090159491Abstract: A process for converting fine catalyst slurried in heavy oil into a coke-like material from which catalytic metals can be recovered comprises mixing fine catalyst slurried in heavy oil with solvent, which causes asphaltenes in the heavy oil to precipitate from the heavy oil; separating fine catalyst and precipitated asphaltenes from the heavy oil and solvent; and converting precipitated asphaltenes to a coke-like material by pyrolizing fine catalyst and precipitated asphaltenes separated from the heavy oil.Type: ApplicationFiled: December 20, 2007Publication date: June 25, 2009Applicant: Chevron U.S.A. Inc.Inventors: Jose Guitian Lopez, Christopher A. Powers, Donald H. Mohr
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Patent number: 7540951Abstract: A process for preparation of synthetic crude from a deposit of heavy crude, comprises: (a) the extraction of heavy crude by technology using steam; (b) the separation of crude extract and water; (c) the separation of crude into at least one light fraction and one heavy fraction; (d) the conversion of the heavy fraction of separation into a lighter product, said converted product, and a residue; (e) optionally, the partial or total hydrotreatment of the converted product and/or the light fraction (or fractions) obtained during the separation c), (f) the combustion and/or gasification of the conversion residue; the converted product and the light fraction (or fractions) for separation, optionally having been subjected to a hydrotreatment e), constituting the synthetic crude; said combustion allowing the generation of steam and/or electricity and said gasification allowing the generation of hydrogen; the steam and/or electricity thus generated being used for the extraction a) and/or the electricity and/or hydrogType: GrantFiled: August 23, 2006Date of Patent: June 2, 2009Assignee: Institut Francais du PetroleInventors: Arnault Selmen, Thierry Gauthier, Mathieu Pinault, Eric Benazzi
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Publication number: 20090057192Abstract: The present invention relates to a process for improving a deasphalting unit process by producing an improved feedstream for the deasphalting process via ultrafiltration of a vacuum resid-containing feedstream. In particular, the present invention produces an improved quality feedstream to a solvent deasphalting process which results in improved deasphalted oil (DAO) production rates and/or higher quality deasphalted oils. The present invention can be particularly beneficial when used in conjunction with an existing deasphalting equipment to result in improved deasphalted oil (DAO) production rates and/or higher quality deasphalted oils from the existing deasphalting equipment without the need for significant equipment modifications to the existing deasphalting unit.Type: ApplicationFiled: October 30, 2007Publication date: March 5, 2009Inventors: Daniel P. Leta, Lisa M. Rogers, Merryl J. Miranda, Keith K. Aldous, Stephen M. Cundy, MaryKathryn Lee, Edward W. Corcoran
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Publication number: 20090020453Abstract: The present invention is related to a process oil using as a raw material a deasphalted oil obtained by deasphalting a vacuum residual oil of a crude oil and a manufacturing method of the process oil, the process oil having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (b) a viscosity (100° C.) of 40 to 70 mm2/s; (c) an aniline point of 85 to 100° C.; (d) a flash point of 250° C. or higher; (e) an aromatic hydrocarbon content of 40 to 55 mass %; and (f) a polar substance content of 10 to 15 mass %. The present invention is also related to a process oil and a manufacturing method of the process oil, the process oil obtained by mixing: an extract obtained by deasphalting and solvent-extracting a vacuum residual oil of a crude oil; and a lubricant base oil having a polycyclic aromatics (PCA) content of less than 3 mass %, and having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (i) a viscosity (100° C.Type: ApplicationFiled: May 29, 2006Publication date: January 22, 2009Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Meishi Tanaka, Masashi Nakamura, Kazuhiro Teshima, Akihito Abe, Masami Takasaki
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Patent number: 7438797Abstract: A method of reducing the aggregation and deposition of asphaltene from a fluid containing asphaltene, such as crude oil, which method comprises the addition to the fluid of a compound of formula (1): wherein A is an optionally substituted ring system containing 6 to 14 carbon atoms; n is at least 1 and may equal the number of positions available for substitution in A; each X is independently a linker group; and each R is independently a hydrocarbyl group containing 10 to 25 carbon atoms.Type: GrantFiled: July 26, 2002Date of Patent: October 21, 2008Assignee: iC16 LimitedInventors: Rodney John Gochin, Alec Smith
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Patent number: 7393449Abstract: A binder pitch material includes a petroleum pitch and asphalt fraction obtained from petroleum crude oil and has a significantly lower polycyclic aromatic hydrocarbon composition than a coal tar pitch having a like softening point. The pitch material is useful as a binder material for various applications such as clay pigeons.Type: GrantFiled: May 31, 2006Date of Patent: July 1, 2008Assignee: Marathon Ashland Petroleum LLCInventors: Melvin D. Kiser, David C. Boyer
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Patent number: 7381320Abstract: Disclosed is a process for the upgrading and demetallizing of heavy oils and bitumens. A crude heavy oil and/or bitumen feed is supplied to a solvent extraction process 104 wherein DAO and asphaltenes are separated. The DAO is supplied to an FCC unit 106 having a low conversion activity catalyst for the removal of metals contained therein. The demetallized distillate fraction is supplied to a hydrotreater 110 for upgrading and collected as a synthetic crude product stream. The asphaltene fraction can be supplied to a gasifier 108 for the recovery of power, steam and hydrogen, which can be supplied to the hydrotreater 110 or otherwise within the process or exported. An optional coker 234 can be used to convert excess asphaltenes and/or decant oil to naphtha, distillate and gas oil, which can be supplied to the hydrotreater 220.Type: GrantFiled: August 30, 2004Date of Patent: June 3, 2008Assignee: Kellogg Brown & Root LLCInventors: Rashid Iqbal, Anshumali, Odette Eng, Phillip Niccum
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Publication number: 20080099371Abstract: A feedstream comprising tar is feed to a solvent deasphalter wherein it is contacted with a deasphalting solvent or fluid to produce a composition comprising a mixture or slurry of solvent containing a soluble portion of the tar, and a heavy tar fraction comprising the insoluble portion of the tar. These fractions may be separated in the deasphalter apparatus, such as by gravity settling wherein the heavy tar fraction is taken off as bottoms, and the solvent-soluble fraction taken as overflow or overheads with the solvent. The overflow or overheads is sent to a solvent recovery unit, such as a distillation apparatus, wherein solvent is recovered as overheads and a deasphalted tar fraction is taken off as a sidestream or bottoms. The solvent or a portion thereof, recovered as overheads, may be then be recycled to the solvent deasphalter, or in a preferred embodiment, at least a portion of the solvent is steam cracked to produce a product comprising light olefins.Type: ApplicationFiled: October 30, 2006Publication date: May 1, 2008Inventors: James N. McCoy, Paul F. Keusenkothen, Alok Srivastava
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Publication number: 20080093260Abstract: A solvent deasphalting of crude oil or petroleum heavy fractions and residues is carried out in the presence of a solid adsorbent, such as clay, silica, alumina and activated carbon, which adsorbs the contaminants and permits the solvent and oil fraction to be removed as a separate stream from which the solvent is recovered for recycling; the adsorbent with contaminants and the asphalt bottoms is mixed with aromatic and/or polar solvents to desorb the contaminants and washed as necessary, e.g., with benzene, toluene, xylenes and tetrahydrofuran, to clean adsorbant which is recovered and recycled; the solvent-asphalt mixture is sent to a fractionator for recovery and recycling of the aromatic or polar solvent. The bottoms from the fractionator include the concentrated PNA and contaminants and are further processes as appropriate.Type: ApplicationFiled: October 20, 2006Publication date: April 24, 2008Inventor: Omer Refa Koseoglu
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Publication number: 20080047871Abstract: HSP crude oil is used as process stream in crude oil storage tanks to address sludge levels both by cleaning sludge accumulations and preventing any significant sludge build up when used on a regular basis. HSP crude oil is also used to optimize cleaning routines. Making HSP oil easily accessible by providing a designated HSP source will make tank maintenance more efficient and allow refineries to use the advantages of the HSP oil to the maximum extent.Type: ApplicationFiled: August 23, 2006Publication date: February 28, 2008Applicant: ExxonMobil Research and Engineering CompanyInventors: Glen B. Brons, Douglas S. Meyer, Mohsen N. Harandi, Randolph Perry, John W. Anthony, John S. Jackson
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Publication number: 20080006561Abstract: This invention relates to a dearomatized asphalt. More particularly, an asphalt is extracted with a aromatic extraction solvent to produce an asphalt-rich phase and a solvent rich phase. The asphalt rich phase is stripped of solvent to produce dearomatized asphalt that has superior properties for paving and roofing applications.Type: ApplicationFiled: July 5, 2006Publication date: January 10, 2008Inventors: Lyle E. Moran, Larry W. Windsor
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Patent number: 6878263Abstract: Disclosed is a rubber process oil in which the content of polycyclic aromatics (PCAs) as determined by the IP 346 method is less than 3% by mass and which is rich in aromatic hydrocarbons, and a method for producing the same. The aniline point of the rubber process oil is 80° C. or less, and the % CA value as determined by ring analysis according to the Kurtz method is from 20 to 50%. The rubber process oil is produced by using extraction of lube oil fraction with a solvent having a selective affinity for aromatics. The extraction conditions are determined so that the extraction yield is regulated to a predetermined requirement defined by the PCAs content of the lube oil fraction. Alternatively, the extract is cooled to further separate into the extract and the raffinate, and the second raffinate is used for the rubber process oil.Type: GrantFiled: April 27, 2001Date of Patent: April 12, 2005Assignee: Japan Energy CorporationInventors: Takashi Kaimai, Kazumitsu Fujihara, Yoshiyuki Morishima
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Patent number: 6821413Abstract: A method for the continuous process of fluids is based on mixing the fluid with a supercritical fluid. The mixing of the two fluids may be accomplished using either a co-flow or counter-flow process. The process focuses on the difference in the solubilities of the desired and the undesired components into supercritical fluid and de-emphasizes the influence of the contaminating components of the fluid to be processed. The process of the present invention is particularly advantageous to the recycling of industrial waste fluids, such as used oil, wherein the process is carried out by jet spray micro-orifices atomization of waste material with a supercritical fluid to dissolve oil from the waste material. Additional mixing devices such as a magneto driven impeller shaft and ultrasonic gun may be employed. Thereafter, un-dissolved components are separated, first and the dissolved fluid is then separated from the supercritical fluid. Various apparatus for carrying out the method are also disclosed.Type: GrantFiled: August 31, 2000Date of Patent: November 23, 2004Assignee: FluidPhase Technologies, Inc.Inventor: Abdulhaq E. Alkhalidl
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Patent number: 6717021Abstract: A solvating component for a solvated mesophase pitch. The solvated component includes a mixture of aromatic hydrocarbons having boiling points in the atmospheric equivalent boiling point range of about 285° to about 500° C. (about 550° F.-932° F.). At least 80% of the carbon atoms of the hydrocarbons are aromatic as characterized by carbon 13 NMR. The aromatic hydrocarbons are selected from a group consisting of aromatic compounds having 2 to 5 aromatic rings, substituted aromatic compounds having 2 to 5 aromatic rings wherein said substituents are alkyl groups having 1 to 3 carbons, hydroaromatic compounds having 2 to 5 rings, substituted aromatic compounds having 2 to 5 rings wherein said substituents are alkyl groups having 1 to 3 carbons, and mixtures thereof.Type: GrantFiled: June 4, 2001Date of Patent: April 6, 2004Assignee: ConocoPhillips CompanyInventors: H. Ernest Romine, John A. Rodgers, W. Mark Southard, Edward J. Nanni
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Patent number: 6673234Abstract: A combined process of low degree solvent deasphalting and delayed coking, which comprises feeding a deasphalting stock and a solvent into an extractor and making the yield of the deasphalted oil 70 wt %-95 wt %, and introducing a part or all of the deasphalted oil and optionally a conventional coking stock into a delayed coker. This process increases the yield of liquid products, removes the heavy asphaltene which is prone to coke, extends the run length of the delayed coker, and at the same time, lowers the content of impurities in coke, enlarges the sources of the stocks for producing the needle coke.Type: GrantFiled: September 25, 2001Date of Patent: January 6, 2004Assignees: China Petroleum and Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Rui Li, Zijun Wang, Jun Long
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Patent number: 6641716Abstract: An embodiment of the present invention is a method for isolating conducting polymer precursors by contacting a non-basic heterocyclic nitrogen containing hydrocarbon stream having a boiling point of from 232° C. (450° F.) to 566° C. (1050° F.) with an effective amount of a treating agent selected from monohydroxyl alcohols having a density at 25° C. of less than 0.90 g/cm3 and mixtures thereof, at conditions effective to maintain the reactants in a liquid phase to produce a first stream enriched in non-basic heterocyclic nitrogen containing hydrocarbon compounds and a second treated stream having a decreased non-basic heterocyclic nitrogen content. Optionally, an effective amount of mineral acid may be added to the hydrocarbon stream to enhance the process.Type: GrantFiled: April 18, 2000Date of Patent: November 4, 2003Assignee: ExxonMobil Research and Engineering CompanyInventors: Mark Alan Greaney, John N. Begasse
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Publication number: 20030134018Abstract: A process for the selective extraction of desired compounds from solid materials, and more particularly, a process for oil extraction from oil-bearing materials with a hydrocarbon solvent composition is provided. The method includes contacting the oil-containing solids with a particular type of hydrocarbon solvent to form an extraction mixture.Type: ApplicationFiled: December 31, 2001Publication date: July 17, 2003Applicant: Cargill, Inc.Inventors: Matthew S. Turner, Leroy Venne
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Patent number: 6566410Abstract: A method of demulsifying a water-in-oil emulsion comprising an oil phase comprising asphaltenes and an aqueous phase is disclosed. The method comprises contacting a carbon dioxide containing fluid with the emulsion such that the carbon dioxide containing fluid enters the oil phase of the emulsion. The asphaltenes precipitate out of the emulsion and the emulsion destabilizes.Type: GrantFiled: June 21, 2000Date of Patent: May 20, 2003Assignee: North Carolina State UniversityInventors: Nael Naguib Zaki, Peter Kelley Kilpatrick, Ruben Guillermo Carbonell
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Patent number: 6555728Abstract: A two step process for destruction of polyhalogenated aromatic compounds contained in pitch from ballasts of fluorescent lamps comprises: (a) contacting the pitch with a sufficient amount of an organic solvent such that the pitch and the solvent together form a liquid phase in which the polyhalogenated aromatic compounds are dissolved; and (b) chemically destroying the polyhalogenated aromatic compounds in the liquid phase. In preferred embodiments of the process, the solvent comprises mineral oil and the polyhalogenated aromatic compounds comprise polychlorinated biphenyls. Chemical destruction of the polyhalogenated aromatic compounds preferably comprises treatment with an alkali metal dispersion, preferably sodium metal in mineral oil.Type: GrantFiled: August 8, 2001Date of Patent: April 29, 2003Assignee: Kinectrics Inc.Inventors: Luciano A. Gonzalez, Blair F. Sim, Henry E. Kowalyk, James D. Harcus
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Patent number: 6549817Abstract: A process for regulating a centrifuge used for solid/liquid separation of sewage sludge commences by measuring the input variables of the operating point ot the centrifuge, the variables including 1) suspended matter content of the centrate; 2) the flow rate of sludge; 3) the flow rate of reagent; and 4) the value of torque of the motor of a conventional centrifuge. Operating zones are established, each of which is two dimensional relative to the input variables. Fuzzy logic rules are established, qualifying the operation of the centrifuge, the rules respectively corresponding to the zones. The rules are implemented in response to the input variable measurements, where actions on the sludge flow rate and reagent flow rate make it possible to bring the operating point into a particular zone of optimal and stable centrifuge operation.Type: GrantFiled: July 19, 2000Date of Patent: April 15, 2003Assignee: DegremontInventor: Jacques Audibert
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Patent number: 6533925Abstract: This invention involves heat integration of a solvent deasphalting process with a gasification process and an improved process for separating a resin phase from a solvent solution comprising a solvent, deasphalted oil (DAO) and resin. This improved process comprises heating the solvent solution so as to precipitate the resin from the solvent solution, and then separating the resin and some solvent from the solvent solution. This will produce a resin product and a mixture comprising the DAO and the remaining solvent. The DAO/solvent mixture is then boiled so as to vaporize a fraction of the solvent, with waste heat from a gasification unit providing the heat source for the boiling. The vaporized solvent is removed from the DAO/solvent mixture leaving a resin-free DAO product that contains any unvaporized solvent. The vaporized solvent is used for heating the aforementioned solvent solution and preheating the resin-free DAO/solvent mixture.Type: GrantFiled: August 22, 2000Date of Patent: March 18, 2003Assignee: Texaco Development CorporationInventors: Paul S. Wallace, Kay A. Johnson, Clint F. Penrose, Jacqueline G. Niccum
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Publication number: 20030024857Abstract: A method of refining a petroleum product to remove aromatics and to separate paraffinic oils and waxes is provided. The method involves the utilization of phase equilibria wherein crystallized or solidified waxes, normally present in the petroleum product, are used to remove oils from a liquid solvent phase containing dissolved aromatics present in the unrefined petroleum product. The wax containing the oils is separated from the aromatic-containing solvent and is further processed to separate the waxes and oils. For petroleum products containing little, if any, wax, additional wax may be added and recycled back for further use in removing oils from the petroleum product. The method has particular application in preparing lubricating oils having a high viscosity index, where the presence of aromatics and wax can be detrimental.Type: ApplicationFiled: September 30, 2002Publication date: February 6, 2003Inventors: Michael D. Ackerson, Michael Steven Byars
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Patent number: 6464856Abstract: An improved process for the total separation and recovery of four constituents, namely, 1) insoluble pitches and tars also known as asphaltenes, 2) a kerosene based oil fraction, 3) clays and silts of less than 80 &mgr;m mesh and 4) sands of greater than 80 &mgr;m mesh. Recombination of the hydrocarbon fractions is the bitumen portion of tar sands. A further process for the extraction and separation of plant resins from cellulose and kerogen from oil shale that on thermal depolymerization become a source for aromatic and kerosene based oil fractions respectively.Type: GrantFiled: August 22, 2000Date of Patent: October 15, 2002Assignee: Deinking/ Solvent Extraction TechnologiesInventor: Venanzio Di Tullio
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Patent number: 6464859Abstract: This invention relates to a process for deacidifying a crude oil system, said process comprising the steps of: a) contacting the crude oil system with a polar solvent, such that at least part of the organic acid present in the oil is extracted into the solvent as an extract phase, and b) separating said extract phase from the treated crude oil system of step a).Type: GrantFiled: August 29, 2000Date of Patent: October 15, 2002Assignee: BP Exploration Operating Company, Ltd.Inventors: Simon Neil Duncum, Christopher George Osborne
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Patent number: 6383365Abstract: A 40 petroleum pitch is disclosed. A high melting point petroleum pitch is blended with a high boiling normally liquid petroleum derived hydrocarbon stream to form a mixture having a softening point of 35-45 C. as a partial or complete replacement for coal tar pitch used in driveway sealer and other sealer applications. Driveway sealer (an emulsion of clay, water and binder) made with A 40 has excellent durability and can have a greatly reduced amount of, or be essentially free of, coal tar pitch, greatly reducing the toxicity and odor of the sealer.Type: GrantFiled: November 16, 1999Date of Patent: May 7, 2002Assignee: Marathon Ashland Petroleum LLCInventors: D. Chris Boyer, Patricia K. Doolin
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Patent number: 6357526Abstract: A process and system which integrates on-site heavy oil or bitumen upgrading and energy recovery for steam production with steam-assisted gravity drainage (SAGD) production of the heavy oil or bitumen. The heavy oil or bitumen produced by SAGD is flashed to remove the gas oil fraction, and the residue is solvent deasphalted to obtain deasphalted oil, which is mixed with the gas oil fraction to form a pumpable synthetic crude. The synthetic crude has an improvement of 4-5 degrees of API and lower in sulfur, nitrogen and metal compounds. The synthetic crude is not only more valuable than the heavy oil or bitumen, but also has substantial economic advantage of reducing the diluent requirement since it has lower viscosity than the heavy oil or bitumen. The asphaltenes, following an optional pelletizing and/or slurrying step, are used as a fuel for combustion in boilers near the steam injection wells for injection into the heavy oil or bitumen reservoir.Type: GrantFiled: March 16, 2000Date of Patent: March 19, 2002Assignee: Kellogg Brown & Root, Inc.Inventors: Tayseer Abdel-Halim, Murugesan Subramanian
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Publication number: 20020011427Abstract: A solvating component for a solvated mesophase pitch. The solvated component includes a mixture of aromatic hydrocarbons having boiling points in the atmospheric equivalent boiling point range of about 285° to about 460° C. (about 550° F.-932° F.). At least 80% of the carbon atoms of the hydrocarbons are aromatic as characterized by carbon 13 NMR. The aromatic hydrocarbons are selected from a group consisting of aromatic compounds having 2 to 5 aromatic rings, substituted aromatic compounds having 2 to 5 aromatic rings wherein said substituents are alkyl groups having 1 to 3 carbons, hydroaromatic compounds having 2 to 5 rings, substituted aromatic compounds having 2 to 5 rings wherein said substituents are alkyl groups having 1 to 3 carbons, and mixtures thereof.Type: ApplicationFiled: June 4, 2001Publication date: January 31, 2002Inventors: H. Ernest Romine, John A. Rodgers, W. Mark Southard, Edward J. Nanni
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Publication number: 20010045377Abstract: A novel process for the production of an extract useful as a process oil and a raffinate useful as a high-viscosity base oil by solvent refining is provided, characterized in that reduced pressure distillation is effected under the condition that the end point of distillate is 580° C. or higher as calculated in terms of atmospheric pressure or the initial boiling point of the residue is 450° C. or higher as calculated in terms of atmospheric pressure, the resulting residual oil is deasphalted under the condition that the carbon residue content in the deasphalted oil reached 1.6% or less, and the resulting deasphalted oil is subjected to solvent refining under the condition that the yield of extract is from 35% to 60%. It is a novel and economically excellent process for the preparation of a rubber process oil having a high safety, a high penetrating power with respect to rubber polymer and the content of PCA extract of less than 3%.Type: ApplicationFiled: April 19, 2001Publication date: November 29, 2001Inventors: Yoshiyuki Morishima, Kenji Fujino
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Patent number: 6274030Abstract: The invention is a process of removing solids, particularly catalyst fines, from an asphaltene-containing hydrocarbon liquid. The process comprises contacting an asphaltene-containing hydrocarbon liquid with a solvent to create a mixture. The solvent is typically an alkane such as, propane to pentanes. Then, solids are removed from the mixture by any known process. Finally, additional solvent may be added, and the mixture heated until asphaltenes precipitate into a separate phase. The asphaltenes are removed from the mixture. The mixture is then further heated to recover the solvent from the deasphalted hydrocarbon liquid. The asphaltenes are advantageously gasified.Type: GrantFiled: December 22, 1999Date of Patent: August 14, 2001Assignee: Texaco Inc.Inventors: Paul S. Wallace, Kay Anderson Johnson
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Patent number: 6270652Abstract: An improved process is disclosed for producing a unique metals-containing anisotropic pitch suitable for carbon fiber manufacture. Soluble, aromatic-organometallic compounds are added to a carbonaceous feedstock which is substantially free of mesophase pitch and the resulting composition is heat soaked to produce an isotropic pitch product containing mesogens and soluble, aromatic-organometallic compounds. Next, the pitch product is solvent fractionated to separate mesogens which contain metals from the organometallic compounds. The metals-containing mesogens are heated to a temperature sufficient to cause fusion to produce a metals-containing mesophase pitch. In another method, the carbonaceous feedstock is heat soaked to produce an isotropic pitch product containing mesogens and high molecular weight, soluble, aromatic-organometallic compounds are added to the mesogen containing isotropic pitch product prior to solvent fractionation.Type: GrantFiled: April 16, 1999Date of Patent: August 7, 2001Assignee: Conoco Inc.Inventors: H. Ernest Romine, James R. McConaghy, Jr., John A. Rodgers
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Patent number: 6270653Abstract: A method of controlling asphaltene precipitation in a fluid comprising the addition of a precipitation inhibitor to the fluid containing the asphaltene.Type: GrantFiled: September 29, 1999Date of Patent: August 7, 2001Assignee: Imperial College of Science, Technology & MedicineInventors: Rodney J. Gochin, Alec Smith