With Hydrogen Patents (Class 208/89)
  • Publication number: 20150129461
    Abstract: Embodiments of apparatuses and methods for hydrotreating coker kerosene or other thermally or catalytically cracked hydrocarbon stream are provided. In one example, a method comprises splitting a feed comprising coker kerosene into first and second feed streams. The first feed stream is heated to form a heated first feed stream. The second feed stream is partially heated to form a partially heated second feed stream. The heated first feed stream is contacted with a first hydrotreating catalyst to form a first hydrotreated intermediate stream. The first hydrotreated intermediate stream is combined with the partially heated second feed stream to form a partially quenched first hydrotreated intermediate combined stream. The partially quenched first hydrotreated intermediate combined stream is contacted with a second hydrotreating catalyst to further hydrotreat the partially quenched first hydrotreated intermediate combined stream.
    Type: Application
    Filed: November 14, 2013
    Publication date: May 14, 2015
    Applicant: UOP LLC
    Inventor: Soumendra Mohan Banerjee
  • Patent number: 9005429
    Abstract: The present invention relates to hydrocarbons and particularly to the manufacture of hydrocarbon components suitable as aviation fuels or jet fuels and as blending stocks for aviation fuels. The process comprises the stages, wherein in the first stage an oil feed of biological origin and hydrogen gas are subjected to conditions sufficient to effect hydrodeoxygenation in the presence of a hydrodeoxygenation catalyst to yield n-paraffins; in the second stage the n-paraffins and hydrogen gas are subjected to conditions sufficient to effect isomerization in the presence of an isomerization catalyst to yield isoparaffins and separating fractions; and recycling the fraction boiling at a temperature above 200° C. under atmospheric pressure obtained from the second stage to reisomerization, where isomerization is effected in the presence of an isomerization catalyst.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: April 14, 2015
    Assignee: Neste Oil Oyj
    Inventors: Varpu Markkanen, Petri Lindqvist, Elina Harlin, Pekka Aalto, Jukka Myllyoja, Ville Alopaeus
  • Publication number: 20150090634
    Abstract: Disclosed are processes for producing a transportation fuel from a high quality oil sands-derived crude oil. The oil sands-derived crude oil is provided as a feed source for a catalytic conversion reaction, which produces the product useful as the transportation fuel. The oil sands-derived crude oil has an ASTM D7169 5% distillation point of from 400° F. to 700° F. Transportation fuel is produced from the provided oil sands-derived crude oil by treating the oil sands-derived crude oil through at least one catalytic cracking process and mild hydrotreating process.
    Type: Application
    Filed: September 26, 2014
    Publication date: April 2, 2015
    Applicant: EPIC OIL EXTRACTORS, LLC
    Inventors: Richard H. SCHLOSBERG, Richard D. JORDAN
  • Patent number: 8992764
    Abstract: An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur and/or nitrogen conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants. The integrated process includes an initial dewaxing of a feed under sour conditions, optional hydrocracking of the dewaxed feed, and a separation to form a first diesel product and a bottoms fraction. The bottoms fraction is then exposed to additional hydrocracking and dewaxing to form a second diesel product and optionally a lubricant base oil product. Alternatively, a feedstock can be hydrotreated, fractionated, dewaxed, and then hydrocracked to form a diesel fuel and a dewaxed, hydrocracked bottoms fraction that is optionally suitable for use as a lubricant base oil.
    Type: Grant
    Filed: June 27, 2011
    Date of Patent: March 31, 2015
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Krista Marie Prentice, Michel Daage, Ajit Bhaskar Dandekar, Christopher Gordon Oliveri, Rohit Vijay, Stephen J. McCarthy, Wenyih F. Lai, Bradley R. Fingland
  • Publication number: 20150083643
    Abstract: A process for the hydroprocessing of a gas oil (GO) hydrocarbon feed to provide high yield of a diesel fraction. The process comprises a liquid-full hydrotreating reaction zone followed by a liquid-full hydrocracking reaction zone. A refining zone may be integrated with the hydrocracking reaction zone. Ammonia and other gases formed during the hydrotreatment are removed in a separation step prior to hydrocracking.
    Type: Application
    Filed: September 10, 2014
    Publication date: March 26, 2015
    Inventors: HASAN DINDI, THANH GIA TA, VINCENT ADAM KUPERAVAGE, JR., ALAN HOWARD PULLEY, SCOTT LOUIS WEBSTER
  • Patent number: 8980081
    Abstract: A process of upgrading a highly aromatic hydrocarbon feedstream comprising (a) contacting a highly aromatic hydrocarbon feedstream, wherein, a major portion of the feedstream has a boiling range of from about 300° F. to about 800° F., under catalytic conditions with a catalyst system, containing a hydrotreating catalyst and a hydrogenation/hydrocracking catalyst in a single stage reactor system, wherein the active metals in the hydrogenation/hydrocracking catalyst comprises from about 5%-30% by weight of nickel and from about 5%-30% by weight tungsten; and (b) wherein at least a portion of the highly aromatic hydrocarbon feedstream is converted to a product stream having a boiling range within jet or diesel boiling ranges.
    Type: Grant
    Filed: October 22, 2007
    Date of Patent: March 17, 2015
    Assignee: Chevron U.S.A. Inc.
    Inventors: Jaime Lopez, Janine Lichtenberger
  • Publication number: 20150060331
    Abstract: Methods for processing a hydrocarbonaceous feedstock flows are provided. In one embodiment, the method includes providing two or more hydroprocessing stages disposed in sequence, each hydroprocessing stage having a hydroprocessing reaction zone with a hydrogen requirement and each stage in fluid communication with the preceding stage. The hydrocarbonaceous feedstock flow may be separated into portions of fresh feed for each hydroprocessing stage, and the first portion of fresh feed to the first hydroprocessing stage is heated. The heated first portion of fresh feed may be supplied with hydrogen from the hydrogen source in an amount satisfying substantially all of the hydrogen requirements of the hydroprocessing stages to a first hydroprocessing zone. The unheated second portion of fresh feed is injected counter current to the process flow as quench at one or more locations in one or more of the reaction zones.
    Type: Application
    Filed: November 10, 2014
    Publication date: March 5, 2015
    Inventors: Paul A. Sechrist, Robert L. Bunting, Nicholas W. Bridge, RIchard K. Hoehn
  • Patent number: 8969242
    Abstract: A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks, the catalyst comprising a metal from Group 6, a metal from Group 8, and optionally phosphorous, wherein the carrier or support, comprises porous alumina comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (A); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 to less than about 1000 A; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 A.
    Type: Grant
    Filed: August 3, 2012
    Date of Patent: March 3, 2015
    Assignee: Advanced Refining Technologies LLC
    Inventors: Darryl P. Klein, Nan Chen, Matthew P. Woods, Bruno Nesci
  • Patent number: 8968552
    Abstract: An intermediate hydrogen separation and purification system is integrated with a hydrotreating and an aromatic saturation process for the production of relatively lower molecular weight products from a relatively heavy feedstock including sulfur-containing and aromatic-containing hydrocarbon compounds. The integrated process allows the processing of heavy hydrocarbon feedstock having high aromatic and high sulfur contents in a single-stage configuration and the using of noble metal catalyst in the aromatic saturation zone. The integrated process increases the overall catalytic activity and hydrogenation capability to produce superior distillate products.
    Type: Grant
    Filed: November 2, 2012
    Date of Patent: March 3, 2015
    Assignee: Saudi Arabian Oil Company
    Inventors: Vinod Ramaseshan, Ali Hasan Al-Abdulal, Yuv Raj Mehra
  • Patent number: 8945372
    Abstract: The present invention provides a process for hydroprocessing comprising treating a hydrocarbon feed in a first two-phase hydroprocessing zone having a liquid recycle, producing product effluent, which is contacted with a catalyst and hydrogen in a downstream three-phase hydroprocessing zone, wherein at least a portion of the hydrogen supplied to the three-phase zone is a hydrogen-rich recycle gas stream. Optionally, the product effluent from the first two-phase hydroprocessing zone is fed to a second two-phase hydroprocessing zone containing a single-liquid-pass reactor. The two-phase hydroprocessing zones comprise two or more catalyst beds disposed in liquid-full reactors. The three-phase hydroprocessing zone comprises one or more single-liquid-pass catalyst beds disposed in a trickle bed reactor.
    Type: Grant
    Filed: September 15, 2011
    Date of Patent: February 3, 2015
    Assignee: E I du Pont de Nemours and Company
    Inventors: Hasan Dindi, Luis Eduardo Murillo, Thanh Gia Ta
  • Patent number: 8945373
    Abstract: According to the present invention, organic material is converted to biogas through anaerobic digestion and the biogas is purified to yield a combustible fluid feedstock comprising methane. A fuel production facility utilizes or arranges to utilize combustible fluid feedstock to generate renewable hydrogen that is used to hydrogenate crude oil derived hydrocarbons in a process to make liquid transportation or heating fuel. The renewable hydrogen is added to a reactor operated so as to simultaneously desulfurize and hydrogenate crude oil derived hydrocarbons.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: February 3, 2015
    Assignee: Iogen Corporation
    Inventor: Brian Foody
  • Patent number: 8936714
    Abstract: A process is disclosed for hydrocracking a primary hydrocarbon feed and a diesel co-feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The diesel stream fed through the hydrocracking unit is pretreated to reduce sulfur and ammonia and can be upgraded with noble metal catalyst.
    Type: Grant
    Filed: November 28, 2012
    Date of Patent: January 20, 2015
    Assignee: UOP LLC
    Inventors: Peter Kokayeff, Paul R. Zimmerman
  • Publication number: 20150008158
    Abstract: Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by hydrotreating the feed under mild conditions, and separating the hydrotreated effluent into an aromatic-rich fraction which contains a substantial amount of the aromatic refractory and sterically hindered sulfur-containing compounds, and an aromatic-lean fraction. The aromatic-rich fraction is contacted with isomerization catalyst, and the isomerized aromatic-rich fraction is recycled to the mild hydrotreating process.
    Type: Application
    Filed: July 15, 2014
    Publication date: January 8, 2015
    Inventor: Omer Refa Koseoglu
  • Publication number: 20150001129
    Abstract: A process and apparatus is disclosed for pretreating a hydrocarbon stream in a hydrotreating reactor and separating the diesel materials from the pretreated effluent before the heavier liquid materials are fed to a hydrocracking unit. Thus diesel materials are preserved but recovered along with the hydrocracked effluent. A recovered diesel stream can be sent to a hydrotreating unit to improve its cetane rating.
    Type: Application
    Filed: June 28, 2013
    Publication date: January 1, 2015
    Inventors: Peter Kokayeff, Clayton C. Sadler, Vasant P. Thakkar
  • Publication number: 20140374311
    Abstract: A process and apparatus are disclosed for hydrotreating a hydrocarbon feed in a hydrotreating unit and hydrocracking a liquid hydrotreating effluent stream in a hydrocracking unit. A hot separator separates the diesel in a liquid hot hydrotreating effluent stream that serves as feed to the hydrocracking unit. Low sulfur diesel product can be saturated to further upgrade its cetane rating.
    Type: Application
    Filed: June 20, 2013
    Publication date: December 25, 2014
    Inventors: Paul R. Zimmerman, Peter Kokayeff, Michael R. Smith
  • Patent number: 8906224
    Abstract: Sweet and sour lubricant feeds are block and continuous processed to produce lubricant basestocks. Total liquid product yields at a desired pour point are maintained for catalytic dewaxing of both sweet and sour conditions. The desired pour point is achieved for both the sweet and sour feeds by varying the catalytic dewaxing reaction temperature as a function of sulfur content entering the reactor.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: December 9, 2014
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Krista Marie Prentice, Michel Daage, Gary Paul Schleicher, Christine Nicole Elia, Stephen J. McCarthy, Wenyih F. Lai, Shifang L. Luo, Robert Andrew Migliorini
  • Publication number: 20140339133
    Abstract: A process that provides for the improvement of the properties of a distillate feedstock that has significant concentrations of nitrogen and polyaromatic compounds. The process includes a first reaction zone that uses a base metal catalyst and is operated under high pressure conditions to provide for the hydrodenitrogenation of organic nitrogen and saturation of polyaromatic compounds contained in the distillate feedstock. The first reaction zone treated effluent is separated into a heavy fraction and a lighter fraction with the heavy fraction being charged to a second reaction zone that also uses a base metal catalyst and is operated under high pressure conditions to provide for the saturation of monaromatic compounds that are contained in the heavy fraction. The inventive process provides for a high quality, low-sulfur and low-nitrogen diesel product that has a significantly lower aromatics content than the distillate feedstock and having a high value for its high Cetane Index.
    Type: Application
    Filed: May 19, 2014
    Publication date: November 20, 2014
    Applicant: SHELL OIL COMPANY
    Inventors: John Anthony SMEGAL, Aristides MACRIS
  • Patent number: 8877014
    Abstract: Split-shell fractionation columns and associated processes for separating aromatic hydrocarbons. A split-shell fractionation column includes a housing shell having a first height and a partition having a second height and disposed within the housing shell. The partition includes first and second vertically oriented baffles separated by a gap region, a seal plate connecting top ends of the baffles, a first input port formed to extend through the partition for the introduction of a gas into the gap region, and a first output port formed to extend outwardly from a bottom of the gap region and through the housing shell. The partition defines a first distillation zone and a second distillation zone within the housing shell.
    Type: Grant
    Filed: December 14, 2012
    Date of Patent: November 4, 2014
    Assignee: UOP LLC
    Inventors: Jason T. Corradi, David William Ablin
  • Publication number: 20140299510
    Abstract: Methods relating to methods for producing a needle coke precursor from slurry oil having low levels of nitrogen and sulfur. Nitrogen-containing compounds are removed by chromatography, followed by hydrotreating at relatively mild conditions that focus on the more easily-removed sulfur-containing compounds while largely preserving aromatic content of the slurry oil. The resulting needle coke precursor can be converted to a premium needle coke in a delayed coking system.
    Type: Application
    Filed: June 19, 2014
    Publication date: October 9, 2014
    Applicant: PHILLIPS 66 COMPANY
    Inventors: Ayyappan SUBBIAH, Tushar V. CHOUDHARY
  • Patent number: 8852426
    Abstract: Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by hydrotreating the feed under mild conditions, and separating the hydrotreated effluent into an aromatic-rich fraction which contains a substantial amount of the aromatic refractory and sterically hindered sulfur-containing compounds, and an aromatic-lean fraction. The aromatic-rich fraction is contacted with isomerization catalyst, and the isomerized aromatic-rich fraction is recycled to the mild hydrotreating process.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: October 7, 2014
    Assignee: Saudi Arabian Oil Company
    Inventor: Omer Refa Koseoglu
  • Publication number: 20140291200
    Abstract: The invention relates to a process for the production of diesel fuel bases comprising a sulfur content that is less than 100 ppm, starting from a feedstock that is obtained from a renewable source, comprising the following stages: a) A stage for bringing the feedstock into contact with a fixed-bed hydrotreatment catalyst for producing an effluent that comprises a gaseous fraction comprising hydrogen and a hydrocarbon-based liquid fraction, d) A stage for bringing into contact at least one portion of the hydrocarbon-based liquid fraction in the presence of a selective hydroisomerization catalyst in a fixed bed, e) A stage for separating the effluent that is obtained from stage d) into a gaseous fraction that comprises hydrogen and at least one diesel-fuel-based fraction.
    Type: Application
    Filed: December 16, 2013
    Publication date: October 2, 2014
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Wilfried WEISS, Thierry CHAPUS
  • Publication number: 20140291201
    Abstract: One exemplary embodiment can be a process for hydroprocessing. The process can include providing a hydroprocessing zone having at least two beds, and quenching downstream of a first bed of the at least two beds with a first vacuum gas oil that may be lighter than another vacuum gas oil fed to the first bed.
    Type: Application
    Filed: March 26, 2013
    Publication date: October 2, 2014
    Applicant: UOP, LLC
    Inventors: Soumendra Mohan Banerjee, Mani Krishna, Avnish Kumar
  • Publication number: 20140262945
    Abstract: Novel liquid-full process for improving cold flow properties and increasing yield of middle distillate fuel feedstock by hydrotreating and dewaxing the feedstock in liquid-full reactors.
    Type: Application
    Filed: March 13, 2014
    Publication date: September 18, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: HASAN DINDI, SANDEEP PALIT, ALAN HOWARD PULLEY, LUIS EDUARDO MURILLO, THANH GIA TA, BRIAN BOEGER
  • Publication number: 20140262940
    Abstract: A process for upgrading residuum hydrocarbons is disclosed. The process may include: contacting a residuum hydrocarbon fraction and hydrogen with a first hydroconversion catalyst in a first ebullated bed hydroconversion reactor system; recovering a first effluent from the first ebullated bed hydroconversion reactor system; solvent deasphalting a vacuum residuum fraction to produce a deasphalted oil fraction and an asphalt fraction; contacting the deasphalted oil fraction and hydrogen with a second hydroconversion catalyst in a second hydroconversion reactor system; recovering a second effluent from the second hydroconversion reactor system; and fractionating the first effluent from the first ebullated bed hydroconversion reactor system and the second effluent from the second hydroconversion reactor system to recover one or more hydrocarbon fractions and the vacuum residuum fraction in a common fractionation system.
    Type: Application
    Filed: March 5, 2014
    Publication date: September 18, 2014
    Applicant: LUMMUS TECHNOLOGY INC.
    Inventors: Mario C. Baldassari, Ujjal K. Mukherjee, Ann-Marie Olsen, Marvin I. Greene
  • Publication number: 20140221709
    Abstract: A process for upgrading residuum hydrocarbons is disclosed. The process may include: contacting a residuum hydrocarbon fraction and hydrogen with a first hydroconversion catalyst in a first ebullated bed hydroconversion reactor system; recovering a first effluent from the first ebullated bed hydroconversion reactor system; solvent deasphalting a vacuum residuum fraction to produce a deasphalted oil fraction and an asphalt fraction; contacting the deasphalted oil fraction and hydrogen with a second hydroconversion catalyst in a second hydroconversion reactor system; recovering a second effluent from the second hydroconversion reactor system; and fractionating the first effluent from the first ebullated bed hydroconversion reactor system and the second effluent from the second hydroconversion reactor system to recover one or more hydrocarbon fractions and the vacuum residuum fraction in a common fractionation system.
    Type: Application
    Filed: February 4, 2013
    Publication date: August 7, 2014
    Applicant: LUMMUS TECHNOLOGY INC.
    Inventors: Mario C. Baldassari, Ujjal K. Mukherjee, Ann-Marie Olsen, Marvin I. Greene
  • Patent number: 8790507
    Abstract: Processes and catalyst systems are provided for dewaxing a hydrocarbon feedstock to form a lubricant base oil. A layered catalyst system of the present invention may comprise a first hydroisomerization dewaxing catalyst disposed upstream from a second hydroisomerization dewaxing catalyst. Each of the first and second hydroisomerization dewaxing catalysts may be selective for the isomerization of n-paraffins. The first hydroisomerization catalyst may have a higher level of selectivity for the isomerization of n-paraffins than the second hydroisomerization dewaxing catalyst. At least one of the first and second hydroisomerization dewaxing catalysts comprises small crystallite zeolite SSZ-32x.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: July 29, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: Kamala Krishna, Guan-Dao Lei
  • Publication number: 20140197071
    Abstract: Systems and methods are provided for using field enhanced separations to produce multiple fractions from a petroleum input. A liquid thermal diffusion and/or electric field separation is used to produce the fractions. The fractions can then be used to form multiple outputs that share a first feature while being different with regard to a second feature. For example, a first fraction from the plurality of fractions can have a desired value for a first property such as viscosity index. Two or more additional fractions from the plurality of fractions can then be blended together to make a blended fraction or output. The blended fraction can have a value for the first property that is substantially similar to the value for the first fraction. However, for a second property, the first fraction and the blended fraction can have distinct values. As a result, multiple output fractions can be formed that share a first feature but differ in a second feature.
    Type: Application
    Filed: December 18, 2013
    Publication date: July 17, 2014
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Krista M. Prentice, Jason M. McMullan, Michel Daage, Gregory J. DeMartin, John Stephen Szobota, Ronald M. Gould, Anastasios Ioannis Skoulidas, Ajit Bhaskar Dandekar, Patrick Loring Hanks, Charles Lambert Baker, JR., Lei Zhang, X B. Cox, III
  • Publication number: 20140174982
    Abstract: Processes are provided herein for producing naphtha boiling range products with a desired sulfur content by reducing the mercaptan content of the naphtha boiling range products after the products exit a hydroprocessing stage. Due to mercaptan reversion, naphtha boiling range products that contain even small amounts of olefins can have a higher than expected sulfur content after hydroprocessing. In order to reduce or mitigate the effects of mercaptan reversion, microchannel reactors (or microreactors) can be placed in a processing system downstream of a reactor that produces a low sulfur naphtha product. The microreactors can include a coating of metals that have activity for hydrodesulfurization. By passing at least a portion of the naphtha product through the downstream microreactors, the mercaptans formed by reversion reactions can be reduced or eliminated, resulting in a naphtha product with possessing a very low sulfur content.
    Type: Application
    Filed: December 3, 2013
    Publication date: June 26, 2014
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Benjamin S. Umansky, Charles R. Bolz, Anjaneya S. Kovvali, Carlos N. Lopez, Rathna P. Davuluri
  • Publication number: 20140174983
    Abstract: A supported catalyst useful in processes for chemically refining hydrocarbon feedstocks, the catalyst comprising a metal from Group 6, a metal from Group 8, and optionally phosphorous, wherein the carrier or support, comprises porous alumina comprising: (a) equal to or greater than about 78% to about 95% of TPV in pores having a diameter of less than about 200 Angstroms (A); (b) greater than about 2% to less than about 19% of the TPV in pores having a diameter of about 200 to less than about 1000 A; (c) equal to or greater than 3% to less than 12% of the TPV in pores having a diameter equal to or greater than about 1000 A.
    Type: Application
    Filed: August 3, 2012
    Publication date: June 26, 2014
    Applicant: ADVANCED REFINING TECHNOLOGIES LLC
    Inventors: Darryl P. Klein, Nan Chen, Matthew P. Woods, Bruno Nesci
  • Publication number: 20140148628
    Abstract: A process is disclosed for treating a hydrocarbon stream including flowing the hydrocarbon stream through a hydrocarbon treating vessel, heating a portion of the hydrocarbon treating vessel to a predetermined temperature and for a predetermined amount of time and controlling sensitization of the portion of the interior surface of the hydrocarbon treating vessel.
    Type: Application
    Filed: September 30, 2011
    Publication date: May 29, 2014
    Inventors: Steven A. Bradley, Benjamin L. Tiemens, Mark W. Mucek, Shixue Wen
  • Publication number: 20140144809
    Abstract: A process is disclosed for hydrocracking a primary hydrocarbon feed and a diesel co-feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The diesel stream fed through the hydrocracking unit is pretreated to reduce sulfur and ammonia and can be upgraded with noble metal catalyst.
    Type: Application
    Filed: November 28, 2012
    Publication date: May 29, 2014
    Applicant: UOP LLC
    Inventors: Peter Kokayeff, Paul R. Zimmerman
  • Patent number: 8734638
    Abstract: Processes are provided for producing a diesel fuel product having a sulfur content of 15 wppm or less (e.g., 10 wppm or less) from feed sources that include a biocomponent feedstock. The biocomponent feedstock can be initially co-processed with a mineral feed in a fluidized bed stage, such as an ebullating bed processing stage. Ebullating bed processing can mitigate the impact of the biocomponent feed on other hydrotreatment aspects of a diesel boiling range feed. Challenged biocomponent feeds can be handled by introducing the biocomponent feed into the ebullating bed reactor in a manner that reduces the fouling impact of the feed.
    Type: Grant
    Filed: May 27, 2010
    Date of Patent: May 27, 2014
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Patrick L. Hanks, Kathryn Younger Cole, William Ernest Lewis, Edward Stanley Ellis
  • Patent number: 8696888
    Abstract: The invention concerns integration of hydroprocessing and steam cracking. A feed comprising crude or resid-containing fraction thereof is severely hydrotreated and passed to a steam cracker to obtain an olefins product.
    Type: Grant
    Filed: October 17, 2006
    Date of Patent: April 15, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Paul F. Keusenkothen, Megan L. Renstrom, Julian A. Wolfenbarger, Stephen H. Brown, John S. Buchanan
  • Patent number: 8686204
    Abstract: Methods for co-processing a biorenewable feedstock and a petroleum distillate feedstock are provided. The petroleum distillate feedstock containing sulfur is reacted with hydrogen gas in the presence of a hydrotreating catalyst thereby forming an effluent mixture comprising hydrogen sulfide. A combined feed comprising the effluent mixture, optionally a recycle liquid, and the biorenewable feedstock is contacted with hydrogen gas in a reaction zone with a deoxygenation catalyst under reaction conditions to provide a reaction product comprising a hydrocarbon fraction. The combined feed comprises greater than 50 weight percent biorenewable feedstock.
    Type: Grant
    Filed: November 8, 2010
    Date of Patent: April 1, 2014
    Assignee: UOP LLC
    Inventors: Andrea G. Bozzano, Donald Eizenga, Ralph Charles Norton
  • Patent number: 8652321
    Abstract: Production of gasolines with low sulfur contents from a starting gasoline containing sulfur-containing compounds comprising a stage a) for selective hydrogenation of non-aromatic polyunsaturated compounds present in the starting gasoline, a stage b) for increasing the molecular weight of the light sulfur-containing products that are initially present in the gasoline that enters this stage, a stage c) for alkylation of at least a portion of the sulfur-containing compounds present in the product that originates from stage b), a stage d) for fractionation of the gasoline that originates from stage c) into at least two fractions, one fraction virtually lacking in sulfur-containing compounds, whereby the other contains a larger proportion of sulfur-containing compounds (heavy gasoline), a stage e) for catalytic treatment of the heavy gasoline for transformation of sulfur-containing compounds under conditions for the at least partial decomposition of hydrogenation of these sulfur-containing compounds.
    Type: Grant
    Filed: June 1, 2010
    Date of Patent: February 18, 2014
    Assignee: IFP Energies nouvelles
    Inventors: Quentin Debuisschert, Denis Uzio, Jean-Luc Nocca, Florent Picard
  • Patent number: 8647500
    Abstract: A mineral feed can be hydrotreated in a trickle-bed reactor or other stage in a continuous gas-phase environment. The effluent from the hydrotreatment stage can be separated to remove gas-phase impurities. The remaining liquid effluent from the hydrotreating stage can then be introduced, in total or in part, into a second stage/reactor. A feed of biocomponent origin can also be introduced into the second stage/reactor. The second stage/reactor can be operated to perform deoxygenation of the mixture of biocomponent feed and hydrotreated liquid effluent in a continuous liquid phase environment.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: February 11, 2014
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Richard C. Dougherty, Michael A. Hayes, Benjamin S. Umansky, William E. Lewis
  • Publication number: 20140027346
    Abstract: An inorganic material is described, constituted by at least two elementary spherical particles, each of said spherical particles comprising metallic nanoparticles having at least one band with a wave number in the range 750 to 1050 cm?1 in Raman spectroscopy and containing one or more metals selected from vanadium, niobium, tantalum, molybdenum and tungsten, said metallic nanoparticles being trapped in a mesostructured matrix based on an oxide of an element Y selected from silicon, aluminium, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium. Said matrix has pores with a diameter in the range 1.5 to 50 nm and amorphous walls with a thickness in the range 1 to 30 nm. Said elementary spherical particles have a maximum diameter of 200 microns and said metallic nanoparticles have a maximum dimension strictly less than 1 nm.
    Type: Application
    Filed: December 15, 2011
    Publication date: January 30, 2014
    Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, IFP ENERGIES NOUVELLES, UNIVERSITE PIERRE ET MARIE CURIE
    Inventors: Alexandra Chaumonnot, Clement Sanchez, Cedric Boissiere, Frederic Colbeau-Justin, Audrey Bonduelle
  • Patent number: 8632673
    Abstract: A continuous process for upgrading sour crude oil by treating the sour crude oil in a two step process that includes a hydro-demetallization section and a hydro-desulfurization section, both of which are constructed in a permutable fashion so as to optimize the operating conditions and catalyst lifespan to produce a high value crude oil having low sulfur and low organometallic impurities.
    Type: Grant
    Filed: November 26, 2008
    Date of Patent: January 21, 2014
    Assignee: Saudi Arabian Oil Company
    Inventors: Stephane Cyrille Kressmann, Raheel Shafi, Esam Z. Hamad, Bashir Osama Dabbousi
  • Patent number: 8632675
    Abstract: Processes are provided for producing a diesel fuel product having a sulfur content of 10 ppm by weight or less from feed sources that include up to 50% by weight of a biocomponent feedstock. The biocomponent feedstock is co-processed with a heavy oil feed in a severe hydrotreating stage. The product from the severe hydrotreatment stage is fractionated to separate out a diesel boiling range fraction, which is then separately hydrotreated.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: January 21, 2014
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Kathryn Y. Cole, William E. Lewis
  • Publication number: 20140001089
    Abstract: Process for hydrotreating a heavy hydrocarbon fraction using a system of switchable fixed bed guard zones each containing at least two catalyst beds and in which whenever the catalyst bed that is brought initially into contact with the feed is deactivated and/or clogged during the steps in which the feed passes successively through all the guard zones, the point of introduction of the feed is shifted downstream. The present invention also relates to an installation for implementing this process.
    Type: Application
    Filed: December 20, 2011
    Publication date: January 2, 2014
    Applicant: IFP Energies nouvelles
    Inventors: Frederic Bazer-Bachi, Christophe Boyer, Isabelle Guibard, Nicolas Marchal, Cecile Plain
  • Publication number: 20140001090
    Abstract: The present invention relates to a catalyst combination for hydrotreating raw oils and a process for hydrotreating raw oils with the catalyst combination. The catalyst combination comprises one or both of at least one hydrogenation protection catalyst I and at least one hydrogenation demetalling catalyst I; at least one hydrogenation demetalling catalyst II; and at least one hydrogenation treatment catalyst III.
    Type: Application
    Filed: March 29, 2013
    Publication date: January 2, 2014
    Applicants: RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Qinghe YANG, Dawei Hu, Shuling Sun, Jia Liu, Hong Nie, Xinqiang Zhao, Xuefen Liu, Dadong Li, Lishun Dai, Zhicai Shao, Tao Liu
  • Publication number: 20130334099
    Abstract: A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HhXxMmOy)q?, said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.
    Type: Application
    Filed: December 15, 2011
    Publication date: December 19, 2013
    Applicants: IFP ENERGIES NOUVELLES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Karin Marchand, Alexandra Chaumonnot, Audrey Bonduelle, Veronique Dufaud, Frederic Lefebvre, Manuela Bader, Susana Lopes Silva
  • Patent number: 8597502
    Abstract: Disclosed is a method of manufacturing a diesel fuel base stock improved in low-temperature flowability, including: fractionating in a first fractionator a synthetic oil obtained by Fisher-Tropsch synthesis into at least two fractions of a first middle fraction containing a component having a boiling range corresponding to diesel fuel oil, and a wax fraction containing a wax component heavier than the first middle fraction; hydroisomerizing the first middle fraction by bringing the first middle fraction into contact with a hydroisomerizing catalyst to produce a hydroisomerized middle fraction; hydrocracking the wax fraction by bringing the wax fraction into contact with a hydrocracking catalyst to produce a wax-decomposition component; and fractionating in a second fractionator a mixture of the produced hydroisomerized middle fraction and the produced wax-decomposition component, wherein rectification conditions in the first fractionator and/or rectification conditions in the second fractionator are adjusted
    Type: Grant
    Filed: September 25, 2008
    Date of Patent: December 3, 2013
    Assignees: Japan Oil, Gas and Metals National Corporation, Inpex Corporation, Nippon Oil Corporation, Japan Petroleum Exploration Co., Ltd., Cosmo Oil Co., Ltd., Nippon Steel Engineering Co., Ltd.
    Inventors: Yuichi Tanaka, Kazuhito Sato
  • Publication number: 20130313161
    Abstract: A process of hydroprocessing a hydrocarbon in a down flow reactor comprising one or more hydroprocessing-catalyst beds. The hydrocarbon feed is mixed with hydrogen and optionally diluent to form a liquid feed mixture wherein hydrogen is dissolved in the mixture, and the liquid feed mixture is introduced into the down flow reactor under hydroprocessing conditions. The hydroprocessing-catalyst bed(s) are liquid-full and the feed reacts by contact with the catalyst. Hydrogen gas is injected into at least one of the hydroprocessing-catalyst beds such that at least part of the hydrogen consumed in that bed is replenished and the liquid-full condition is maintained. In a multi-bed reactor, hydrogen gas may be injected into more than one or all of the hydroprocessing-catalyst beds.
    Type: Application
    Filed: May 25, 2012
    Publication date: November 28, 2013
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: Hasan Dindi
  • Publication number: 20130306517
    Abstract: A hydroconversion catalyst comprising a Group VIB metal component, a Group VIII metal component and a carrier material is disclosed wherein said catalyst has a total surface area of 240 to 360 m2/g; a total pore volume of 0.5 to 0.9 cc/g; and a pore volume distribution such that greater than 60% of pore volume are in pores present as micropores of diameter between 55 and 115 ?, less than 0.12 cc/g of pore volume are in pores present at pores of diameter greater than 160 ? and less than 10% of pore volume are in pores present as macropores of diameters greater than 250 ?.
    Type: Application
    Filed: May 20, 2013
    Publication date: November 21, 2013
    Inventors: John George KESTER, David Andrew KOMAR, David Edward SHERWOOD
  • Patent number: 8551327
    Abstract: Processes are provided for producing a diesel fuel product having a sulfur content of 10 ppm by weight or less from feed sources that include up to 20% by weight of a biocomponent feedstock. The mineral hydrocarbon portions of the feed sources can be distillate or heavier feed sources.
    Type: Grant
    Filed: December 16, 2008
    Date of Patent: October 8, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ernie Lewis, Tahmid Mizan, Zhiguo Hou
  • Patent number: 8545694
    Abstract: An improved aromatics saturation process for use with lube oil boiling range feedstreams utilizing a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof on a mesoporous support having aluminum incorporated into its framework and an average pore diameter of about 15 to less than about 40 ?.
    Type: Grant
    Filed: August 17, 2005
    Date of Patent: October 1, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Stephen J. McCarthy, Wenyih F. Lai, Sylvain S. Hantzer, Ian A. Cody
  • Patent number: 8541636
    Abstract: The invention relates to a method for the catalytic hydrotreatment of a load based on a diesel fuel oil and a biological load based on plant oils and/or animal fats in a hydrotreatment unit. The invention is characterized in that the hydrotreatment unit comprises at least one hydrotreatment reactor operating on a countercurrent. The invention also relates to a hydrotreatment unit for implementing said method, and a corresponding hydrorefining unit.
    Type: Grant
    Filed: February 12, 2008
    Date of Patent: September 24, 2013
    Assignee: Total Raffinage Marketing
    Inventor: César Vergel
  • Publication number: 20130233767
    Abstract: A process is provided that is directed to a steam pyrolysis zone integrated with a hydroprocessing zone including residual bypass to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics.
    Type: Application
    Filed: April 17, 2013
    Publication date: September 12, 2013
    Applicant: SAUDI ARABIAN OIL COMPANY
    Inventors: Raheel SHAFI, Abdennour BOURANE, Ibrahim A. ABBA, Abdul Rahman Zafer AKHRAS
  • Publication number: 20130233765
    Abstract: A hydrocracking system is upgraded by modifying an existing ebullated bed initially utilizing a supported ebullated bed catalyst to thereafter utilize a dual catalyst system that includes metal sulfide catalyst particles and supported ebullated bed catalyst. The upgraded hydrocracking system achieves at least one of: (1) hydroprocess lower quality heavy oil; (2) increase conversion of higher boiling hydrocarbons that boil at 524° C. (975° F.) or higher; (3) reduce the concentration of supported ebullated bed catalyst required to operate an ebullated bed reactor at a given conversion level; and/or (4) proportionally convert the asphaltene fraction in heavy oil at the same conversion level as the heavy oil as a whole. The metal sulfide catalyst may include colloidal or molecular catalyst particles less than 1 micron in size and formed in situ within the heavy oil using a catalyst precursor well-mixed within the heavy oil and decomposed to form catalyst particles.
    Type: Application
    Filed: April 18, 2013
    Publication date: September 12, 2013
    Inventors: Roger K. Lott, Lap Keung Lee