With Acids Patents (Class 208/98)
  • Patent number: 8163167
    Abstract: A process for the deep desulfurization of a heavy pyrolysis gasoline to very low levels of organic sulfur, e.g., 30 ppmv or less, with minimal octane number loss through aromatics saturation. The deep desulfurization is accomplished by contacting the heavy pyrolysis gasoline feedstock, partially in liquid and partially in gaseous phase, with a hydrogen treat gas containing a minimum H2S level in the presence of a hydrogenation catalyst in a one or two reactor system operated in trickle flow, using a low temperature, moderate pressure operating condition.
    Type: Grant
    Filed: September 11, 2008
    Date of Patent: April 24, 2012
    Assignee: Shell Oil Company
    Inventor: Paul Benjerman Himelfarb
  • Publication number: 20100288679
    Abstract: A process for the deep desulfurization of a heavy pyrolysis gasoline to very low levels of organic sulfur, e.g., 30 ppmv or less, with minimal octane number loss through aromatics saturation. The deep desulfurization is accomplished by contacting the heavy pyrolysis gasoline feedstock, partially in liquid and partially in gaseous phase, with a hydrogen treat gas containing a minimum H2S level in the presence of a hydrogenation catalyst in a one or two reactor system operated in trickle flow, using a low temperature, moderate pressure operating condition.
    Type: Application
    Filed: September 11, 2008
    Publication date: November 18, 2010
    Inventor: Paul Benjerman HIMELFARB
  • Patent number: 7731838
    Abstract: The instant invention relates to a process to produce low sulfur diesel products through the hydrodesulfurization of low nitrogen diesel boiling range feedstreams in the presence of solid acidic materials.
    Type: Grant
    Filed: September 11, 2007
    Date of Patent: June 8, 2010
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Jonathan M. McConnachie, Catalina L. Coker, Madhav Acharya
  • Patent number: 7678262
    Abstract: The invention concerns an improved hydrocracking process with a recycle having a step for eliminating polyaromatic compounds from at least a portion of the recycled fraction by adsorption on a particular adsorbent based on alumina-silica with a controlled macropore content.
    Type: Grant
    Filed: March 8, 2006
    Date of Patent: March 16, 2010
    Assignee: Institut Francais du Petrole
    Inventors: Karin Barthelet, Patrick Euzen, Hugues Dulot, Patrick Bourges
  • Patent number: 7588678
    Abstract: The invention concerns an improved hydrocracking process having a step for eliminating polyaromatic compounds from at least a portion of a recycled fraction by adsorption on a particular adsorbent based on alumina-silica with a limited macropore content.
    Type: Grant
    Filed: March 8, 2006
    Date of Patent: September 15, 2009
    Assignee: Institut Francais du Petrole
    Inventors: Karin Barthelet, Patrick Euzen, Hugues Dulot, Patrick Bourges
  • Patent number: 5464526
    Abstract: The buildup of heavy polynuclear aromatic compounds in a hydrocracking system is controlled by contacting at least a portion of the recycle oil to the hydrocracker with a porous solid that has been treated with an acid. The porous solid serves as a support for the acid, thereby presenting the recycle oil with a high surface area for contact with the acid, which extracts the heavy polynuclear aromatic compounds from the recycle oil. A preferred acid-treated support is an amorphous silica that has been impregnated with sulfuric acid.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: November 7, 1995
    Assignee: UOP
    Inventor: Dennis L. Saunders
  • Patent number: 5446233
    Abstract: A process for breaking the emulsion which commonly forms in the caustic system of olefin plants comprising mixing the emulsion with an effective amount of a Group II metal salt of an alkyl aryl sulfonic acid, wherein the alkyl contains 4-24 carbon atoms, most preferably 8-14 carbon atoms.
    Type: Grant
    Filed: April 11, 1994
    Date of Patent: August 29, 1995
    Assignee: Nalco Chemical Company
    Inventors: Vincent E. Lewis, Sherri L. Fisher
  • Patent number: 4795546
    Abstract: A process for improving the storage stability of hydrocracked neutral oil lubricating oil stocks comprising a dewaxing step utilizing a high silica zeolite catalyst to produce a dewaxer effluent and two stabilizing steps utilizing hydrofinishing and nonhydrogenative stabilization by an acidic catalyst.
    Type: Grant
    Filed: July 28, 1987
    Date of Patent: January 3, 1989
    Assignee: Chevron Research Company
    Inventor: Stephen J. Miller
  • Patent number: 4770763
    Abstract: A process for producing a lubricant base oil with low pour point and high aromaticity from a feedstock oil which is either a distillate fraction boiling at 250.degree. C. or above that is obtained from a paraffin base or mixed base crude or a deasphalted oil obtained from a vacuum distillation residual oil of said crude, and process comprising:(a) the step of bringing said feedstock oil into contact with a hydrofining catalyst in the presence of hydrogen and recovering a hydrofined oil;(b) the step of dewaxing said hydrofined oil and recovering the dewaxed oil;(c) the step of subjecting said dewaxed oil to extraction with a solvent having selective affinity for aromatic hydrocarbons so as to separate the feed into the raffinate portion and the extract portion, and removing the solvent from said extract portion to obtain an extract oil; and(d) the step of treating said extract oil by means of contact with a solid adsorbent or sulfuric acid.
    Type: Grant
    Filed: June 23, 1987
    Date of Patent: September 13, 1988
    Assignees: Nippon Mining Co., Ltd., Kyodo Oil Technical Research Center Co., Ltd.
    Inventors: Sampo Kusayanagi, Takashi Kaimai
  • Patent number: 4457830
    Abstract: A process for catalytic hydroconversion of heavy petroleum feedstocks containing preasphaltenes to produce lower-boiling hydrocarbon liquid products. In the process, an inorganic acid is added to the reactor effluent residual fraction boiling above about 950.degree. F. to produce substantial precipitation of the preasphaltene materials. The clarified overhead fraction is recycled to the reaction zone, and the precipitated preasphaltene material is passed to further processing, such as coking to recover additional light oils. The reactor can advantageously be an upflow ebullated catalytic bed type and may use fine size catalyst for increased hydroconversion.
    Type: Grant
    Filed: December 28, 1981
    Date of Patent: July 3, 1984
    Assignee: HRI, Inc.
    Inventor: Paul H. Kydd
  • Patent number: 4409092
    Abstract: A combination process for upgrading hydrocarbon fractions obtained from raw shale oil, oil products of coal processing and select fractions of crude oils comprising sulfur, nitrogen and metal contaminants to produce jet fuel product fractions such as JP4, JP5, JP8 and other turbine-type fuel materials provided. The combination of integrated processing steps involving hydrotreating, acid extraction of basic nitrogen compounds and hydrofining thereof to produce a feed composition suitable for catalytic reforming in the absence of significant hydrocracking whereby jet fuel boiling range material is produced significantly reduces by the combination the hydrogen requirements of the process.
    Type: Grant
    Filed: October 1, 1981
    Date of Patent: October 11, 1983
    Assignee: Ashland Oil, Inc.
    Inventors: Charles A. Johnson, Clifford Ward, Howard F. Moore, Jr. Hettinger