Passing Through Membrane In Vapor Phase Patents (Class 210/640)
  • Patent number: 8485366
    Abstract: There are disclosed a ceramic porous membrane formed with less membrane formation times and having less defects, a small and uniform thickness and a high flux, and a ceramic filter. A silica membrane is formed on a titania UF membrane as an ultrafiltration membrane (a UF membrane) formed on a porous base member which is a microfiltration membrane (also referred to as an MF membrane) and having an average pore diameter smaller than that of the porous base member, and the silica membrane has an average pore diameter smaller than that of the titania UF membrane, and does not substantially permeates the titania UF membrane.
    Type: Grant
    Filed: April 15, 2010
    Date of Patent: July 16, 2013
    Assignee: NGK Insulators, Ltd.
    Inventors: Manabu Isomura, Tatsuya Hishiki, Ichiro Wada
  • Publication number: 20130175218
    Abstract: Membranes are provided for energy efficient purification of alcohol by pervaporation. Such membranes include a nanofibrous scaffold in combination with a barrier layer. The membranes also include zeolites in the barrier layer. The membranes may, in embodiments, also include a substrate.
    Type: Application
    Filed: December 13, 2012
    Publication date: July 11, 2013
    Applicant: The Research Foundation of State University of New York
    Inventor: The Research Foundation of State University of New York
  • Patent number: 8480905
    Abstract: A method and system for recycling and treating dyeing wastewater are provided. To begin with, the dyeing wastewater is added with an adsorbent for assisted decolorization and filtration. Then, the wastewater is filtered with a first filtration device having hydrophilic membranes. The liquid having passed through the hydrophilic membranes undergoes an RO membrane-base filtration process to produce recycled water and concentrated wastewater. The concentrated wastewater is delivered into a second filtration device having hydrophobic membranes, before a micro-bubbling process is performed on the concentrated wastewater in the second filtration device to turn the concentrated wastewater into a creamy-white nebulized working liquid of high gas content. The steam in the working liquid can readily pass through the hydrophobic membranes to produce an effluent that meets effluent standards.
    Type: Grant
    Filed: March 3, 2011
    Date of Patent: July 9, 2013
    Inventor: Jr-Jung Iang
  • Patent number: 8470179
    Abstract: A water distillation system includes a membrane distillation unit which produces desalinated water from feed water comprising salt water. The system also includes a primary water heater which raises a temperature of the feed water upstream of the feed water entering the membrane distillation unit. The system additionally includes an evaporative cooler which lowers a temperature of a coolant upstream of the coolant entering the membrane distillation unit.
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: June 25, 2013
    Assignee: King Abdulaziz City for Science and Technology
    Inventors: Ibrahim A. Al-Arifi, Hisham Taha Abdulla El-Dessouky
  • Publication number: 20130153498
    Abstract: [Problem] To provide a membrane separation apparatus and a membrane separation method capable of reducing energy consumption, [Solution] A membrane separation apparatus (10) includes: a membrane separator (20) supplied with a fluid (X) containing a component (A) and a component (R) and separating the fluid (X) into a fluid (Y) having a higher concentration of the component (A) than the fluid (X) and a fluid (Z) having a lower concentration, of the component (A) than the fluid (X) by using a separation membrane; a first compressor (21) adiabatically compressing the fluid (Y); a first heat exchanger (11) to which the fluid (Y) adiabatically compressed by the first compressor (21) is introduced as a heat source; and a second heat exchanger (12) to which the fluid (Z) is introduced as a heat source.
    Type: Application
    Filed: July 29, 2011
    Publication date: June 20, 2013
    Inventors: Takafumi Kiuchi, Ryohta Hidaka, Yoichi Ishibashi, Yasuki Kansha, Atsushi Tsutsumi
  • Publication number: 20130153497
    Abstract: A VMD system and method uses an aspirator to generate a vacuum pressure for drawing permeate from a membrane module. The aspirator generates the vacuum pressure by receiving and passing a circulating liquid and combines the permeate with the circulating liquid such that the permeate condensates in the circulating liquid. Using an aspirator (e.g., instead of a vacuum pump) allows a more efficient and cost-effective operation of the VMD system and method, particularly in a desalination application. A VMD system and method using an aspirator may be used in desalination and other applications including, without limitation, environmental cleanup (e.g., removal of volatile organic chemicals from water) and food and medical applications.
    Type: Application
    Filed: December 17, 2012
    Publication date: June 20, 2013
    Applicant: MASDAR INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventor: Masdar Institute of Science and Technology
  • Patent number: 8465648
    Abstract: A ceramic pervaporation membrane and a ceramic vapor-permeable membrane where the total aperture length of discharge channels parallel to the channel direction of water collection cells is at least 10% of the length of filtration cells and where the ratio m/n of the number m of rows of filtration cells to the number n of rows of water collection cells is between 1 and 4 have a high water permeation rate and a high separation coefficient.
    Type: Grant
    Filed: November 4, 2011
    Date of Patent: June 18, 2013
    Assignee: NGK Insulators, Ltd.
    Inventors: Makoto Teranishi, Hideyuki Suzuki, Satoshi Sakashita, Manabu Isomura
  • Patent number: 8465465
    Abstract: A dynamic, reduced-pressure treatment system generates reduced pressure and a wave experienced at a tissue site where the wave may have a frequency in the range of from 0.5 Hertz to 20 Hertz. The system includes a manifold for delivering reduced pressure to the tissue site, a sealing member forming a fluid seal over the tissue site, a reduced-pressure source for providing reduced pressure, a reduced-pressure delivery member for delivering reduced pressure from the reduced-pressure source to the manifold, and a wave generator associated with the reduced-pressure delivery member for imparting a wave to the reduced pressure developed by the reduced-pressure source. A reduced-pressure delivery member with liquid-impermeable-and-gas-permeable element may be applied to help reduce blockages and to facilitate ease of treatment. Other systems, apparatuses, and methods are disclosed.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: June 18, 2013
    Assignee: KCI Licensing, Inc.
    Inventor: Jonathan Scott Olson
  • Patent number: 8460551
    Abstract: A water distillation system includes a membrane distillation unit which produces desalinated water from feed water comprising salt water. The system also includes a primary water heater which raises a temperature of the feed water upstream of the feed water entering the membrane distillation unit. The system additionally includes an evaporative cooler which lowers a temperature of a coolant upstream of the coolant entering the membrane distillation unit.
    Type: Grant
    Filed: May 26, 2010
    Date of Patent: June 11, 2013
    Assignee: King Abdulaziz City for Science and Technology
    Inventors: Ibrahim A. Al-Arifi, Hisham Taha Abdulla El-Dessouky
  • Patent number: 8454832
    Abstract: A system and process for treating a hydrocarbon feed mixture containing aromatic compounds is provided to separate the at least one aromatic compound from the hydrocarbon feed stream is provided. A supported ionic liquid membrane, which is a microporous polymeric support containing ionic liquid in its pores, is used to selectively extract aromatics. The hydrocarbon feed mixture is directed to a retentate side of the supported ionic liquid membrane. A permeate stream is drawn from the permeate, side of the supported ionic liquid membrane, which is an aromatic-rich hydrocarbon stream. An aromatic-lean hydrocarbon stream, which is the retentate portion of the original hydrocarbon feed, remains on the retentate side of the supported ionic liquid membrane.
    Type: Grant
    Filed: November 29, 2010
    Date of Patent: June 4, 2013
    Assignee: Saudi Arabian Oil Company
    Inventors: Esam Zaki Hamad, Ahmad Abdullah Bahamdan
  • Publication number: 20130126432
    Abstract: Selective retaining a relatively hydrophilic molecule from a mixture of a relatively hydrophobic molecule and the relatively hydrophilic molecule can be achieved using a hydrophobic, microporous hybrid membrane based on silica, wherein at least 25% of the silicon atoms is bound to a bridging C1-C12-hyrdocarbylene group. The average number of carbon atoms of the bridging groups and any additional monovalent organic groups, taken together, is at least 3.5. The membrane can be part of a production facility for separating alcohol/water mixtures.
    Type: Application
    Filed: May 16, 2011
    Publication date: May 23, 2013
    Applicant: Stichting Energieonderzoek Centrum Nederland
    Inventors: Robert Kreiter, Goulven Gildas Paradis, Jaap Ferdinand Vente, Hessel Lennart Castricum, Johan Evert Ten Elshof
  • Patent number: 8440003
    Abstract: A liquid degassing apparatus is arranged to limit pervaporation through a membrane by attenuating pressure oscillations developed by a vacuum pump. The attenuation is obtained through a combination of one or more flow restrictors and added volume chambers fluidly interposed between the degassing chamber and the vacuum pump. The pressure oscillation attenuation may further inhibit cross-contamination of pervaporated solvents among a plurality of distinct degassing chambers.
    Type: Grant
    Filed: June 29, 2011
    Date of Patent: May 14, 2013
    Assignee: IDEX Health & Science, LLC
    Inventors: Yuri Gerner, Quan Liu, Carl W. Sims
  • Patent number: 8435751
    Abstract: A membrane which can be used for cultivating cells, in particular adherent cells. The membrane permits the adhesion and proliferation of the cells based on its specific composition comprising polyurethane. The resulting surface characteristics further permit the membrane to be used without any pre-treatment with surface modifying substances. A method for preparing a membrane which can be used for cultivating cells, in particular adherent cells. Methods of using the membrane for cultivating cells, in particular adherent cells.
    Type: Grant
    Filed: September 23, 2009
    Date of Patent: May 7, 2013
    Assignee: Gambro Lundia AB
    Inventors: Carina Zweigart, Bernd Krause, Markus Neubauer, Doris Deppisch
  • Patent number: 8430949
    Abstract: A liquid degassing apparatus is arranged to limit pervaporation through a membrane by establishing a pervaporation control space at a permeate side of the membrane. The pervaporation control space is defined in a vacuum chamber between the membrane and a shield member. The shield member may be substantially gas and liquid impermeable to maintain an environment in contact with the permeate side of the membrane that is relatively rich in solvent vapor concentration, thereby limiting further liquid pervaporation across the membrane.
    Type: Grant
    Filed: March 25, 2011
    Date of Patent: April 30, 2013
    Assignee: IDEX Health & Science LLC
    Inventors: Yuri Gerner, Quan Liu, Carl W. Sims
  • Patent number: 8419961
    Abstract: An oil gas separation membrane combines a gas permeable yet oil and temperature resistant bulk polymer membrane such as poly(tetrafluoroethylene) and poly(tetrafluoroethylene-co-hexafluoropropylene); a porous metal support such as sintered metal frit disk made with stainless steel, bronze or nickel; and an highly gas permeable adhesive that bonds firmly the bulk polymer membrane and the metal frit surface together. The adhesive is either a homogenous polymer that has desirable gas permeability, or a coalescent porous polymer particulates network. A gas sensor employing the oil gas separation membrane for detecting and monitoring fault gases of oil filled electrical equipment requires no mechanical wearing or moving part such as pump and valve and the gas sensor is operated normally under various temperature and pressure conditions.
    Type: Grant
    Filed: May 28, 2009
    Date of Patent: April 16, 2013
    Assignee: Asensou Technologies Co., Ltd.
    Inventor: Ren Yan Qin
  • Patent number: 8414686
    Abstract: The present invention is directed to degassing devices for dialysate circuits. One embodiment has a first housing and a second housing positioned within the first housing in an annular relationship. A second embodiment comprises a dialysate regeneration system with urease, a dialyzer, and a housing with an external wall, where the external wall is exposed to atmosphere and comprises a material that passes gas but does not pass liquid and where the housing is positioned between the urease and dialyzer.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: April 9, 2013
    Assignee: Fresenius Medical Care Holdings, Inc.
    Inventors: Victor Gura, Carlos Jacobo Ezon, Masoud Beizai
  • Patent number: 8414684
    Abstract: A degas assembly including a low pressure fluid channel for carrying a wash fluid at a first pressure, a pressurized channel for carrying eluent including a gas at a second pressure higher than the first pressure, and a degas separator defining a fluid barrier between the low pressure fluid channel and pressurized fluid channel, the separator configured to retain liquid in the pressurized fluid channel and allow gas to flow through the separator to the low pressure fluid channel. The pressurized fluid channel may extend along an outer periphery of the low pressure fluid channel. The eluent may be received from an eluent generator at a pressure of at least about 3300 psi, and in various embodiments up to about 5000 psi. A liquid chromatography system and method are also disclosed.
    Type: Grant
    Filed: June 1, 2010
    Date of Patent: April 9, 2013
    Assignee: Dionex Corporation
    Inventors: Yan Liu, Christopher A. Pohl, Michael McAdams, Hamish Small, Zhongqing Lu, Milton Liu, Khosro Moshfegh
  • Publication number: 20130075333
    Abstract: The invention relates to a system for use in the treatment of produced water, e.g., water treatment in connection with hydrocarbon production operations. Silica in produced water produces undesirable scaling in processing equipment, which causes excess energy usage and maintenance problems. Electrocoagulation (EC) at relatively high water temperature, followed by any of membrane distillation (MD) or forward osmosis (FO), may be combined with a process of ceramic ultra-filtration (UF filtration) to treat water. Water to be treated may be produced water that has been pumped from a subterranean reservoir. The treated water may be employed to generate steam. The system comprises a plurality of units (e.g., EC, forward osmosis, membrane distillation unit, UF filtration, etc) which can be configured as an on-site installation or a mobile unit for on-site or off-site water treatment.
    Type: Application
    Filed: September 21, 2012
    Publication date: March 28, 2013
    Inventors: Randall B. Pruet, De Quang Vu, Prakhar Prakash
  • Publication number: 20130075334
    Abstract: The invention relates to the treatment of water, including for example treatment in connection with hydrocarbon production operations. Silica in water produces undesirable scaling in processing equipment, which causes excess energy usage and maintenance problems. Electrocoagulation (EC) at relatively high water temperature may be combined with a process of ceramic ultra-filtration (UF filtration) employed to treat water, and optionally followed by any of membrane distillation or forward osmosis (FO). Water to be treated may be produced water that has been pumped from a subterranean reservoir. The treated water may be employed to generate steam. The treatment units (e.g., EC, forward osmosis, UF filtration, etc) can be configured into one system as an on-site installation or a mobile unit for on-site or off-site water treatment.
    Type: Application
    Filed: September 21, 2012
    Publication date: March 28, 2013
    Inventors: Prakhar Prakash, James Craig Pauley, De Vu
  • Publication number: 20130075335
    Abstract: The invention relates to the treatment of water, including for example treatment in connection with hydrocarbon production operations. Silica in water produces undesirable scaling in processing equipment, which causes excess energy usage and maintenance problems. Electrocoagulation (EC) at relatively high water temperature followed by ultra-filtration (UF filtration) may be combined with forward osmosis (FO) to treat water. Water to be treated may be produced water that has been pumped from a subterranean reservoir. The treated water may be employed to generate steam. The treatment units (e.g., EC, forward osmosis, UF filtration, etc) can be configured into one system as an on-site installation or a mobile unit for on-site or off-site water treatment.
    Type: Application
    Filed: September 21, 2012
    Publication date: March 28, 2013
    Inventors: Prakhar Prakash, James Craig Pauley, Randall B. Pruet
  • Publication number: 20130075332
    Abstract: The invention relates to the treatment of water, including for example treatment in connection with hydrocarbon production operations. Silica in water produces undesirable scaling in processing equipment, which causes excess energy usage and maintenance problems. Electrocoagulation (EC) at relatively high water temperature, followed by any of membrane distillation or forward osmosis (FO), may be combined with a subsequent process of ceramic ultra-filtration (UF filtration) employed to treat water. Water to be treated may be produced water that has been pumped from a subterranean reservoir. The treated water may be employed to generate steam. The treatment units (e.g., EC, forward osmosis, UF filtration, etc) can be configured into one system as an on-site installation or a mobile unit for on-site or off-site water treatment.
    Type: Application
    Filed: September 21, 2012
    Publication date: March 28, 2013
    Inventors: Prakhar Prakash, James Craig Pauley, Randall B. Pruet
  • Publication number: 20130068689
    Abstract: The present invention provides a system for liquid distillation which includes a vapor permeable-liquid impermeable microporous membrane having structures defining a plurality of pores, an oleophobic material that is applied to the structures of the membrane so as to leave the plurality of pores open, a means for supplying non-distilled liquid to the first side of the membrane, and a means for collecting distilled liquid from a second side of the membrane. In a further example, the present invention provides a method for the distillation of liquids.
    Type: Application
    Filed: September 15, 2011
    Publication date: March 21, 2013
    Applicant: BHA Group, Inc.
    Inventors: Vishal Bansal, Christopher Keller
  • Publication number: 20130071793
    Abstract: A method for fractionating a fuel includes heating the fuel and flowing it through hollow superhydrophobic membranes in a membrane module. Vapor from the fuel permeates the hydrophobic membranes and enters a distillate collection chamber, producing distilled fuel and residual fuel. The residual fuel is removed from the module and cooled. The cooled residual fuel is flowed through hollow tubes in the module and the distilled fuel is removed from the distillate collection chamber. Burning the distilled fuel reduces engine emissions. A fuel fractionation system includes a distillate collection chamber, hollow superhydrophobic membranes, hollow tubes and a distillate outlet. The hollow superhydrophobic membranes receive heated fuel and allow vapor from the heated fuel to permeate the membranes and enter the distillate collection chamber. The hollow tubes receive cooled residual fuel and are positioned to allow vapor in the distillate collection chamber to condense on outer surfaces of the hollow tubes.
    Type: Application
    Filed: September 15, 2011
    Publication date: March 21, 2013
    Applicant: UNITED TECHNOLOGIES CORPORATION
    Inventors: Zidu Ma, Joseph J. Sangiovanni, Zissis A. Dardas, Meredith B. Colket, III
  • Patent number: 8394176
    Abstract: Disclosed are a gas separation membrane and a gas separation method in which at least one species of organic vapor is separated and recovered from an organic vapor mixture using the gas separation membrane. The gas separation membrane is made of an aromatic polyimide composed of a tetracarboxylic acid component consisting of an aromatic ring-containing tetracarboxylic acid and a diamine component comprising 10 to 90 mol % of a combination of (B1) 3,4?-diaminodiphenyl ether and (B2) 4,4?-diaminodiphenyl ether at a B1 to B2 molar ratio, B1/B2, ranging from 10/1 to 1/10, and 10 to 90 mol % of other aromatic diamine.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: March 12, 2013
    Assignee: Ube Industries, Ltd.
    Inventors: Tomonori Kanougi, Harutoshi Hoshino, Toshimune Yoshinaga, Yoji Kase, Kenji Fukunaga
  • Patent number: 8382988
    Abstract: The invention is directed to a process for the production of ultra pure water, comprising feeding water containing ions and optionally other impurities to one side of a membrane based on hydroxy sodalite (H-SOD), and recovering ultra pure water from the other side of the membrane.
    Type: Grant
    Filed: November 30, 2009
    Date of Patent: February 26, 2013
    Assignee: Techische Universiteit Delft
    Inventors: Sheida Khajavi, Frederik Kapteijn, Jacobus Cornelis Jansen
  • Patent number: 8376148
    Abstract: An object of the present invention is to provide a zeolite membrane composite satisfying both the treating amount and the separation performance at a practically sufficient level, which can be applied even in the presence of an organic material and can separate/concentrate an organic material-containing gas or liquid mixture and which is economic without requiring a high energy cost and is not limited in its application range; a production method thereof; and a separation or concentration method using the same. The present invention is an inorganic porous support-zeolite membrane composite, wherein the inorganic porous support contains a ceramic sintered body and the inorganic porous support-zeolite membrane composite has, as a zeolite membrane, a CHA-type zeolite crystal layer on the inorganic porous support surface.
    Type: Grant
    Filed: August 26, 2011
    Date of Patent: February 19, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Miki Sugita, Takahiko Takewaki, Kazunori Oshima, Naoko Fujita
  • Patent number: 8361197
    Abstract: There is provided a zeolite separation membrane-provided article having gaps or pores larger than pores inherent to zeolite crystals and controlled within an appropriate range and being capable of achieving both high permeability and high separability for components with small difference in adsorption properties or a component having a smaller molecular diameter than the diameter of the pores, a method for producing the same, a method for separating mixed fluids, and a device for separating mixed fluids. The zeolite separation membrane-provided article is provided with a zeolite membrane having an N2 gas permeation speed at room temperature of 1.0×10?6 mol·m?2·s?1·Pa?1 or more and a permeation speed ratio of 1,3,5-trimethylbenzene/N2 at room temperature of 0.17 or more and being free from dyeing caused by the impregnation with Rhodamine B.
    Type: Grant
    Filed: September 13, 2011
    Date of Patent: January 29, 2013
    Assignee: NGK Insulators, Ltd.
    Inventors: Masaaki Kawai, Toshihiro Tomita, Nobuhiko Mori, Aya Satoh
  • Publication number: 20130015133
    Abstract: The system and method reduces volatile organic compound concentration in a water distribution system using pressurized diffused aeration. The system and method is used in-line in a water distribution system. The system and method can be used at the ends of the distribution system where volatile organic compounds, including trihalomethanes, are more likely to persist. The system and method of pressurized, diffused aeration reduces volatile organic compounds from groundwater remediation systems as well.
    Type: Application
    Filed: February 16, 2012
    Publication date: January 17, 2013
    Inventors: Ethan Brooke, Michael Robin Collins, John Michael Zwerneman
  • Publication number: 20130015134
    Abstract: There is provided a carbon membrane formed by carbonizing a phenol resin having at least one kind of atomic groups selected from the group consisting of a methylene bond, a dimethylene ether bond, and a methylol group, wherein the total mole content rate of the atomic groups is 100 to 180% with respect to the phenolic nuclei.
    Type: Application
    Filed: September 17, 2012
    Publication date: January 17, 2013
    Applicant: NGK INSULATORS, LTD.
    Inventor: NGK Insulators, Ltd.
  • Publication number: 20130001164
    Abstract: A water distillation system includes a membrane distillation unit which produces desalinated water from feed water comprising salt water. The system also includes a primary water heater which raises a temperature of the feed water upstream of the feed water entering the membrane distillation unit. The system additionally includes an evaporative cooler which lowers a temperature of a coolant upstream of the coolant entering the membrane distillation unit.
    Type: Application
    Filed: September 12, 2012
    Publication date: January 3, 2013
    Applicant: KING ABDULAZIZ CITY FOR SCIENCE AND TECHNOLOGY
    Inventors: Ibrahim A. AL-ARIFI, Hisham Taha Abdulla EL-DESSOUKY
  • Patent number: 8343348
    Abstract: A method for producing a carbon membrane of the present invention is a production method where a carbon membrane obtained by subjecting a carbon-containing layer to thermal decomposition in an oxygen inert atmosphere while sending a gas mixture containing an oxidizing gas thereinto is thermally heated. The carbon membrane is subjected to a heating oxidation treatment with controlling the ratio of the flow rate of the gas mixture to the areas of the carbon membrane to 0.5 cm/min. or more to control (temperature ° C.)2×time (h)/10000, which is the relation between the temperature of the gas mixture and the flow time, to 9 to 32. This enables to obtain a carbon film which selectively separates alcohols having 2 or less carbon atoms from a liquid mixture of the alcohols having 2 or less carbon atoms and organic compounds having 5 to 9 carbon atoms.
    Type: Grant
    Filed: December 28, 2011
    Date of Patent: January 1, 2013
    Assignee: NGK Insulators, Ltd.
    Inventors: Aya Satoh, Nobuhiko Mori
  • Patent number: 8328906
    Abstract: The present disclosure relates to a high molecular weight, monoesterified polyimide polymer. Such high molecular weight, monoesterified polyimide polymers are useful in forming crosslinked polymer membranes for the separation of fluid mixtures. According to its broadest aspect, the method of making a crosslinked membrane comprises the following steps: (a) preparing a polyimide polymer comprising carboxylic acid functional groups from a reaction solution comprising monomers and at least one solvent; (b) treating the polyimide polymer with a diol at esterification conditions in the presence of dehydrating conditions to form a monoesterified polyimide polymer; and (c) subjecting the monoesterified fiber to transesterification conditions to form a crosslinked fiber membrane, wherein the dehydrating conditions at least partially remove water produced during step (b). The crosslinked membranes can be used to separate at least one component from a feed stream including more than one component.
    Type: Grant
    Filed: November 28, 2011
    Date of Patent: December 11, 2012
    Assignees: Chevron U.S.A. Inc., Georgia Tech Research Corporation
    Inventors: Stephen J. Miller, Imona C. Omole, William J. Kronos
  • Publication number: 20120305484
    Abstract: Synthesis and use of a new class of polymeric materials with favorable separation characteristics for the dehydration of ethanol and other organic solvents is described herein. The thermally rearranged (TR) polybenzoxazole (PBO), polybenzimidazole (PBI) and polybenzothiazole (PBT) membranes of the present invention can be used for the dehydration of ethanol during processing to fuel grade biodiesel by either pervaporation or vapor permeation. The unique microstructure of the membranes provides excellent separation characteristics, and this, coupled with their inherent thermal and chemical stability, enables their usage in other separations, such as the dehydration of other organic solvents.
    Type: Application
    Filed: June 3, 2011
    Publication date: December 6, 2012
    Applicant: Board of Regents, The University of Texas System
    Inventors: Benny D. Freeman, Donald R. Paul, Katrina Czenkusch, Claudio P. Ribeiro, JR., Chaoyi Ba
  • Patent number: 8323379
    Abstract: A method of improving the blood compatibility of a blood-contacting surface includes immobilizing carbonic anhydrase on the surface, wherein the surface exhibits carbonic anhydrase activity of at least 20% of maximum theoretical activity of the surface based on monolayer surface coverage of carbonic anhydrase.
    Type: Grant
    Filed: October 24, 2011
    Date of Patent: December 4, 2012
    Assignee: University of Pittsburgh—of the Commonwealth System of Higher Education
    Inventors: William J. Federspiel, Alan J. Russell, Heung-Il Oh, Joel Kaar
  • Patent number: 8318013
    Abstract: The present invention involves the use of a multi-stage membrane system for gas, vapor, and liquid separations. In this multi-stage membrane system, high selectivity and high permeance or at least high selectivity polybenzoxazole membranes or cross-linked polybenzoxazole membranes are applied for a pre-membrane or both the pre-membrane and the secondary membrane. A primary membrane can be from conventional glassy polymers. This multi-stage membrane system can reduce inter-stage compression cost, increase product recovery and product purity for gas, vapor, and liquid separations. It can also save the cost compared to the system using all the high cost polybenzoxazole membranes or cross-linked polybenzoxazole membranes.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: November 27, 2012
    Assignee: UOP LLC
    Inventors: Lubo Zhou, Chunqing Liu, Carlos A. Cabrera, Peter K. Coughlin
  • Patent number: 8318023
    Abstract: Contaminating water and/or fuel material may be removed from a stream of internal combustion engine lubricating oil being circulated over parts of an operating engine. A suitable membrane material is supported in a suitable housing. At least a portion of the oil stream is flowed over one side of the membrane and water and/or fuel material diffuses through the membrane to its other side where they are gathered and removed from the housing. The water and fuel material may be recovered separately using different membranes or different regions of a membrane. They may be swept from the membranes and housings using streams of flowing air heated to a pre-selected temperatures using waste engine heat for disposition outside the housing. Application of this practice to other membrane-separable mixtures is described.
    Type: Grant
    Filed: September 28, 2009
    Date of Patent: November 27, 2012
    Assignee: GM Global Technology Operations LLC
    Inventors: Gregory Mordukhovich, Andrew M. Mance
  • Publication number: 20120285889
    Abstract: The present invention relates to a membrane separation method and a relevant equipment, in particular to a method and an equipment for membrane separation utilizing concentration polarization during membrane filtration process, especially, to a concentration process and equipment and a drawer special for drawing a concentration polarization layer. The direct removal of the concentration polarization layer from membrane surface not only decreases the adverse influence of concentration polarization on membrane separation but also obtains concentrated retention components, thereby significantly improving the ability to maintain membrane flux, solving the twinborn problems concerning concentration polarization and membrane fouling during the membrane separation process, and achieving a high-efficiency concentration for retention components.
    Type: Application
    Filed: July 23, 2012
    Publication date: November 15, 2012
    Applicant: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY OF SCIENCES
    Inventors: Yinhua Wan, Xiangrong Chen, Zhiguo Su, Guanghui Ma, Xiaoguang Jiao, Fei Shen, Zhanfeng Cui
  • Publication number: 20120283489
    Abstract: A method of removing water from fluid mixtures of the water with other compounds uses selective vapor permeation or pervaporation of the water, as the case may be, from the mixture through a membrane having an amorphous perfluoropolymer selectively permeable layer. The novel process can be applied in such exemplary embodiments as (a) removing water from mixtures of compounds that have relative volatility of about 1-1.1 or that form azeotropic mixtures with water, (b) the dehydration of hydrocarbon oil such as hydraulic fluid to concentrations of water less than about 50 ppm, (c) removing water byproduct of reversible chemical equilibrium reactions to favor high conversion of reactants to desirable products, (d) drying ethanol to less than 0.5 wt. % water as can be used in fuel for internal combustion engines, and (e) controlling the water content to optimum concentration in enzyme-catalyzed chemical reactions carried out in organic media.
    Type: Application
    Filed: July 19, 2012
    Publication date: November 8, 2012
    Applicant: CMS TECHNOLOGIES HOLDINGS INC.
    Inventors: Stuart M. Nemser, Sudipto Majumdar, Kenneth J. Pennisi
  • Patent number: 8293112
    Abstract: A method of removing water and/or methanol from fluid mixtures of the water or methanol with other compounds uses vapor permeation or pervaporation of the water or methanol, as the case may be, from the mixture through a membrane having an amorphous perfluoropolymer selectively permeable layer. The novel process can be applied in such exemplary embodiments as (a) removing water or methanol from mixtures of compounds that have relative volatility of about 1-1.1 or that form azeotropic mixtures with water or methanol, (b) the dehydration of hydrocarbon oil such as hydraulic fluid to concentrations of water less than about 50 ppm, (c) removing water and methanol byproducts of reversible chemical reactions thereby shifting equilibrium to favor high conversion of reactants to desirable products, (d) drying ethanol to less than 0.5 wt.
    Type: Grant
    Filed: October 26, 2007
    Date of Patent: October 23, 2012
    Assignee: CMS Technologies Holdings, Inc.
    Inventors: Stuart M. Nemser, Sudipto Majumdar, Kenneth J. Pennisi
  • Patent number: 8287735
    Abstract: The invention provides a method for the purification of a liquid by membrane distillation comprising: passing a heated vapourising stream of a liquid (retentate stream) through a retentate channel along a porous hydrophobic membrane (10), whereby vapour of the liquid flows via the pores of the membrane to the other side of said membrane, and condensing said vapour on the other side of said membrane to give a distillate stream in a distillate channel (5) which distillate is created by passing the heat of condensation (latent heat) towards a condenser surface (3), said condenser surface forming a non-porous separation between a feed stream of the liquid to be purified and said distillate stream, which feed stream is passed through a feed channel (2) in counter-current with the retentate stream, in which feed channel a space material (4) is arranged whereby at least part of the latent heat is transferred via the condenser surface to the feed stream, and whereby a positive liquid pressure difference is applied be
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: October 16, 2012
    Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO
    Inventors: Jan Hendrik Hanemaaijer, Albert Edward Jansen, Jolanda Van Medevoort, Hans De Jong, Eric Van Sonsbeek, Engelbert Peter Jurrie Jan Koele, Jan Willem Assink
  • Patent number: 8282708
    Abstract: Methods for the purification of steam, systems for purifying steam, methods for measuring and/or controlling steam flow rates, and uses for purified steam are provide. Also provided are substantially gas-impermeable membranes, such as perfluorinated ionomers (e.g., perfluoroethylene-sulfonic-acid/tetrafluoroethylene membranes), having a high ratio of water vapor permeation relative to gas permeation through the membrane. Also provided are methods of operation of such membranes at relatively high operating temperatures for the purification of steam and for operation of such membranes at relatively low temperature and sub-atmospheric pressures for the purification of steam. In a preferred embodiment, the system 400 for purifying steam comprises heater 404 for creating a source of a steam feed, and a purification device 416 for housing a substantially gas-impermeable membrane 424. In the operation of system 400, water, such as deionized water, is added to vessel 402 to provide a source of the steam feed.
    Type: Grant
    Filed: September 12, 2006
    Date of Patent: October 9, 2012
    Assignee: RASIRC
    Inventors: Jeffrey J. Spiegelman, Richard D. Blethen
  • Publication number: 20120234756
    Abstract: Disclosed is a method of controlling a real-time oxidation-reduction potential in a hot water system to inhibit corrosion in the hot water system. The method includes defining one or more operational protective zones in the hot water system. One or more of the operational protective zones includes an oxidation-reduction potential probe that is operable to measure a real-time oxidation-reduction potential in the hot water system at operating temperature and pressure. The probe transmits the measured real-time potential to the controller, which assesses and interprets the transmitted potential to determine whether it conforms to an oxidation-reduction potential setting. If the measured potential does not conform the oxidation-reduction potential setting, the controller is operable to feed or remove one or more active chemical species into or from the hot water system and further operable to change at least one system parameter.
    Type: Application
    Filed: April 9, 2012
    Publication date: September 20, 2012
    Inventors: Peter D. Hicks, David A. Grattan
  • Publication number: 20120228222
    Abstract: Separation processes using forward osmosis are disclosed generally involving the extraction of a solvent from a first solution to concentrate a solute therein by using a second concentrated solution to draw the solvent from the first solution across a semi-permeable membrane. One or both of the solute and solvent may be a desired product. By manipulating the equilibrium of the soluble and insoluble species of solute within the second solution, a saturated second solution can be used to generate osmotic pressure on the first solution. The various species of solute within the second solution can be recovered and recycled through the process to affect the changes in equilibrium and eliminate waste products. Enhanced efficiency may result from using low grade waste heat from industrial or commercial sources.
    Type: Application
    Filed: March 14, 2012
    Publication date: September 13, 2012
    Applicant: Yale University
    Inventors: Robert L. McGinnis, Menachem Elimelech
  • Publication number: 20120228225
    Abstract: The present invention relates to a method for contemporaneously recovering ammonia and carbon dioxide from an aqueous solution thereof, possibly comprising their condensates, in a synthesis process of urea, characterized in that it comprises a hydrophobic microporous membrane distillation phase of an aqueous solution comprising ammonia, carbon dioxide and their saline compounds or condensates, said distillation being carried out at a temperature ranging from 50 to 250° C. and a pressure ranging from 50 KPa to 20 MPa absolute, with the formation of a residual aqueous solution, possibly comprising urea, and a gaseous permeate stream, comprising ammonia, carbon dioxide and water. The present invention also relates to an apparatus for effecting the above method and a production process of urea which comprises the above method.
    Type: Application
    Filed: September 1, 2010
    Publication date: September 13, 2012
    Applicant: SAIPEM S.p.A.
    Inventors: Paolo Casara, Alessandro Gianazza
  • Patent number: 8262778
    Abstract: The invention relates to polymeric ultrafiltration or microfiltration membranes of, for instance, poly(ethylene chlorotrifluoroethylene) (HALAR®), PVDF or PP, incorporating PVME or vinyl methyl ether monomers. The PVME may be present as a coating on the membrane or dispersed throughout the membrane or both. The membranes are preferably hydrophilic with a highly asymmetric structure with a reduced pore size and/or absence of macrovoids as a result of the addition of PVME. The PVME maybe cross-linked. The invention also relates to methods of hydrophilising membranes and/or preparing hydrophilic membranes via thermal or diffusion induced phase separation processed.
    Type: Grant
    Filed: August 10, 2011
    Date of Patent: September 11, 2012
    Assignee: Siemens Industry, Inc.
    Inventors: Daniel Mullette, Joachim Muller, Neeta Patel
  • Patent number: 8262779
    Abstract: The present invention discloses microporous aluminophosphate (AlPO4) molecular sieve membranes and methods for making and using the same. The microporous AlPO4 molecular sieve membranes, particularly small pore microporous AlPO-14 and AlPO-18 molecular sieve membranes, are prepared by three different methods, including in-situ crystallization of a layer of AlPO4 molecular sieve crystals on a porous membrane support, coating a layer of polymer-bound AlPO4 molecular sieve crystals on a porous membrane support, and a seeding method by in-situ crystallization of a continuous second layer of AlPO4 molecular sieve crystals on a seed layer of AlPO4 molecular sieve crystals supported on a porous membrane support.
    Type: Grant
    Filed: August 16, 2010
    Date of Patent: September 11, 2012
    Assignee: UOP LLC
    Inventors: Chunqing Liu, Stephen T. Wilson, David A. Lesch
  • Patent number: 8256626
    Abstract: A composite membrane is provided for the separation of water with at least one separation layer of cross-linked polyvinyl alcohol, with the separation layer being subjected in a separate process step to a post-crosslinking operation with an acid or an acid-releasing compound and at least one dialdehyde.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: September 4, 2012
    Assignee: Souzer Chemtech GmbH
    Inventors: Andreas Hübner, Elena Gonzalez Diaz, Michael Frania
  • Publication number: 20120211421
    Abstract: Systems and methods for lowering levels of carbon dioxide and other atmospheric pollutants are provided. Economically viable systems and processes capable of removing vast quantities of carbon dioxide and other atmospheric pollutants from gaseous waste streams and sequestering them in storage-stable forms are also discussed.
    Type: Application
    Filed: March 1, 2012
    Publication date: August 23, 2012
    Inventors: KYLE SELF, Kasra Farsad, Robert W. Elliott, Brian Curtis, Srikanth Bellur, Miguel Fernandez, Philip Brian Tuet
  • Publication number: 20120210869
    Abstract: The present invention relates to a membrane, in particular to a hollow fiber membrane comprising a membrane, comprising at least two layers, wherein the at least two layers each comprise at least one layer forming material comprising at least one polymer and the at least two layers differ from each other with respect to the layer forming material, wherein the at least two layers are at least partly covalently and delamination free bonded to each other. The present invention relates furthermore to a method of production of the said membrane as well as to its use.
    Type: Application
    Filed: December 20, 2011
    Publication date: August 23, 2012
    Applicant: FRESENIUS MEDICAL CARE DEUTSCHLAND GMBH
    Inventors: Christian Finkler, Rainer Fislage, Torsten Keller, Igor Raiko, Roland Sander
  • Patent number: 8241501
    Abstract: The present invention discloses a new type of high performance polymer membranes prepared from aromatic polyimide membranes by thermal treating and crosslinking and methods for making and using these membranes. The polymer membranes were prepared from aromatic polyimide membranes by thermal treating under inert atmosphere followed by crosslinking preferably by using a UV radiation source. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The membranes showed significantly improved selectivity and permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The membranes can be fabricated into any convenient geometry and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used for other applications such as for catalysis and fuel cell applications.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: August 14, 2012
    Assignee: UOP LLC
    Inventors: Chunqing Liu, Peter K. Coughlin, Man-Wing Tang, Raisa Minkov, Lubo Zhou