Passing Through Membrane In Vapor Phase Patents (Class 210/640)
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Patent number: 8485366Abstract: There are disclosed a ceramic porous membrane formed with less membrane formation times and having less defects, a small and uniform thickness and a high flux, and a ceramic filter. A silica membrane is formed on a titania UF membrane as an ultrafiltration membrane (a UF membrane) formed on a porous base member which is a microfiltration membrane (also referred to as an MF membrane) and having an average pore diameter smaller than that of the porous base member, and the silica membrane has an average pore diameter smaller than that of the titania UF membrane, and does not substantially permeates the titania UF membrane.Type: GrantFiled: April 15, 2010Date of Patent: July 16, 2013Assignee: NGK Insulators, Ltd.Inventors: Manabu Isomura, Tatsuya Hishiki, Ichiro Wada
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Publication number: 20130175218Abstract: Membranes are provided for energy efficient purification of alcohol by pervaporation. Such membranes include a nanofibrous scaffold in combination with a barrier layer. The membranes also include zeolites in the barrier layer. The membranes may, in embodiments, also include a substrate.Type: ApplicationFiled: December 13, 2012Publication date: July 11, 2013Applicant: The Research Foundation of State University of New YorkInventor: The Research Foundation of State University of New York
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Patent number: 8480905Abstract: A method and system for recycling and treating dyeing wastewater are provided. To begin with, the dyeing wastewater is added with an adsorbent for assisted decolorization and filtration. Then, the wastewater is filtered with a first filtration device having hydrophilic membranes. The liquid having passed through the hydrophilic membranes undergoes an RO membrane-base filtration process to produce recycled water and concentrated wastewater. The concentrated wastewater is delivered into a second filtration device having hydrophobic membranes, before a micro-bubbling process is performed on the concentrated wastewater in the second filtration device to turn the concentrated wastewater into a creamy-white nebulized working liquid of high gas content. The steam in the working liquid can readily pass through the hydrophobic membranes to produce an effluent that meets effluent standards.Type: GrantFiled: March 3, 2011Date of Patent: July 9, 2013Inventor: Jr-Jung Iang
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Patent number: 8470179Abstract: A water distillation system includes a membrane distillation unit which produces desalinated water from feed water comprising salt water. The system also includes a primary water heater which raises a temperature of the feed water upstream of the feed water entering the membrane distillation unit. The system additionally includes an evaporative cooler which lowers a temperature of a coolant upstream of the coolant entering the membrane distillation unit.Type: GrantFiled: September 12, 2012Date of Patent: June 25, 2013Assignee: King Abdulaziz City for Science and TechnologyInventors: Ibrahim A. Al-Arifi, Hisham Taha Abdulla El-Dessouky
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Publication number: 20130153498Abstract: [Problem] To provide a membrane separation apparatus and a membrane separation method capable of reducing energy consumption, [Solution] A membrane separation apparatus (10) includes: a membrane separator (20) supplied with a fluid (X) containing a component (A) and a component (R) and separating the fluid (X) into a fluid (Y) having a higher concentration of the component (A) than the fluid (X) and a fluid (Z) having a lower concentration, of the component (A) than the fluid (X) by using a separation membrane; a first compressor (21) adiabatically compressing the fluid (Y); a first heat exchanger (11) to which the fluid (Y) adiabatically compressed by the first compressor (21) is introduced as a heat source; and a second heat exchanger (12) to which the fluid (Z) is introduced as a heat source.Type: ApplicationFiled: July 29, 2011Publication date: June 20, 2013Inventors: Takafumi Kiuchi, Ryohta Hidaka, Yoichi Ishibashi, Yasuki Kansha, Atsushi Tsutsumi
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Publication number: 20130153497Abstract: A VMD system and method uses an aspirator to generate a vacuum pressure for drawing permeate from a membrane module. The aspirator generates the vacuum pressure by receiving and passing a circulating liquid and combines the permeate with the circulating liquid such that the permeate condensates in the circulating liquid. Using an aspirator (e.g., instead of a vacuum pump) allows a more efficient and cost-effective operation of the VMD system and method, particularly in a desalination application. A VMD system and method using an aspirator may be used in desalination and other applications including, without limitation, environmental cleanup (e.g., removal of volatile organic chemicals from water) and food and medical applications.Type: ApplicationFiled: December 17, 2012Publication date: June 20, 2013Applicant: MASDAR INSTITUTE OF SCIENCE AND TECHNOLOGYInventor: Masdar Institute of Science and Technology
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Patent number: 8465648Abstract: A ceramic pervaporation membrane and a ceramic vapor-permeable membrane where the total aperture length of discharge channels parallel to the channel direction of water collection cells is at least 10% of the length of filtration cells and where the ratio m/n of the number m of rows of filtration cells to the number n of rows of water collection cells is between 1 and 4 have a high water permeation rate and a high separation coefficient.Type: GrantFiled: November 4, 2011Date of Patent: June 18, 2013Assignee: NGK Insulators, Ltd.Inventors: Makoto Teranishi, Hideyuki Suzuki, Satoshi Sakashita, Manabu Isomura
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Patent number: 8465465Abstract: A dynamic, reduced-pressure treatment system generates reduced pressure and a wave experienced at a tissue site where the wave may have a frequency in the range of from 0.5 Hertz to 20 Hertz. The system includes a manifold for delivering reduced pressure to the tissue site, a sealing member forming a fluid seal over the tissue site, a reduced-pressure source for providing reduced pressure, a reduced-pressure delivery member for delivering reduced pressure from the reduced-pressure source to the manifold, and a wave generator associated with the reduced-pressure delivery member for imparting a wave to the reduced pressure developed by the reduced-pressure source. A reduced-pressure delivery member with liquid-impermeable-and-gas-permeable element may be applied to help reduce blockages and to facilitate ease of treatment. Other systems, apparatuses, and methods are disclosed.Type: GrantFiled: November 18, 2009Date of Patent: June 18, 2013Assignee: KCI Licensing, Inc.Inventor: Jonathan Scott Olson
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Patent number: 8460551Abstract: A water distillation system includes a membrane distillation unit which produces desalinated water from feed water comprising salt water. The system also includes a primary water heater which raises a temperature of the feed water upstream of the feed water entering the membrane distillation unit. The system additionally includes an evaporative cooler which lowers a temperature of a coolant upstream of the coolant entering the membrane distillation unit.Type: GrantFiled: May 26, 2010Date of Patent: June 11, 2013Assignee: King Abdulaziz City for Science and TechnologyInventors: Ibrahim A. Al-Arifi, Hisham Taha Abdulla El-Dessouky
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Patent number: 8454832Abstract: A system and process for treating a hydrocarbon feed mixture containing aromatic compounds is provided to separate the at least one aromatic compound from the hydrocarbon feed stream is provided. A supported ionic liquid membrane, which is a microporous polymeric support containing ionic liquid in its pores, is used to selectively extract aromatics. The hydrocarbon feed mixture is directed to a retentate side of the supported ionic liquid membrane. A permeate stream is drawn from the permeate, side of the supported ionic liquid membrane, which is an aromatic-rich hydrocarbon stream. An aromatic-lean hydrocarbon stream, which is the retentate portion of the original hydrocarbon feed, remains on the retentate side of the supported ionic liquid membrane.Type: GrantFiled: November 29, 2010Date of Patent: June 4, 2013Assignee: Saudi Arabian Oil CompanyInventors: Esam Zaki Hamad, Ahmad Abdullah Bahamdan
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Publication number: 20130126432Abstract: Selective retaining a relatively hydrophilic molecule from a mixture of a relatively hydrophobic molecule and the relatively hydrophilic molecule can be achieved using a hydrophobic, microporous hybrid membrane based on silica, wherein at least 25% of the silicon atoms is bound to a bridging C1-C12-hyrdocarbylene group. The average number of carbon atoms of the bridging groups and any additional monovalent organic groups, taken together, is at least 3.5. The membrane can be part of a production facility for separating alcohol/water mixtures.Type: ApplicationFiled: May 16, 2011Publication date: May 23, 2013Applicant: Stichting Energieonderzoek Centrum NederlandInventors: Robert Kreiter, Goulven Gildas Paradis, Jaap Ferdinand Vente, Hessel Lennart Castricum, Johan Evert Ten Elshof
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Patent number: 8440003Abstract: A liquid degassing apparatus is arranged to limit pervaporation through a membrane by attenuating pressure oscillations developed by a vacuum pump. The attenuation is obtained through a combination of one or more flow restrictors and added volume chambers fluidly interposed between the degassing chamber and the vacuum pump. The pressure oscillation attenuation may further inhibit cross-contamination of pervaporated solvents among a plurality of distinct degassing chambers.Type: GrantFiled: June 29, 2011Date of Patent: May 14, 2013Assignee: IDEX Health & Science, LLCInventors: Yuri Gerner, Quan Liu, Carl W. Sims
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Patent number: 8435751Abstract: A membrane which can be used for cultivating cells, in particular adherent cells. The membrane permits the adhesion and proliferation of the cells based on its specific composition comprising polyurethane. The resulting surface characteristics further permit the membrane to be used without any pre-treatment with surface modifying substances. A method for preparing a membrane which can be used for cultivating cells, in particular adherent cells. Methods of using the membrane for cultivating cells, in particular adherent cells.Type: GrantFiled: September 23, 2009Date of Patent: May 7, 2013Assignee: Gambro Lundia ABInventors: Carina Zweigart, Bernd Krause, Markus Neubauer, Doris Deppisch
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Patent number: 8430949Abstract: A liquid degassing apparatus is arranged to limit pervaporation through a membrane by establishing a pervaporation control space at a permeate side of the membrane. The pervaporation control space is defined in a vacuum chamber between the membrane and a shield member. The shield member may be substantially gas and liquid impermeable to maintain an environment in contact with the permeate side of the membrane that is relatively rich in solvent vapor concentration, thereby limiting further liquid pervaporation across the membrane.Type: GrantFiled: March 25, 2011Date of Patent: April 30, 2013Assignee: IDEX Health & Science LLCInventors: Yuri Gerner, Quan Liu, Carl W. Sims
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Patent number: 8419961Abstract: An oil gas separation membrane combines a gas permeable yet oil and temperature resistant bulk polymer membrane such as poly(tetrafluoroethylene) and poly(tetrafluoroethylene-co-hexafluoropropylene); a porous metal support such as sintered metal frit disk made with stainless steel, bronze or nickel; and an highly gas permeable adhesive that bonds firmly the bulk polymer membrane and the metal frit surface together. The adhesive is either a homogenous polymer that has desirable gas permeability, or a coalescent porous polymer particulates network. A gas sensor employing the oil gas separation membrane for detecting and monitoring fault gases of oil filled electrical equipment requires no mechanical wearing or moving part such as pump and valve and the gas sensor is operated normally under various temperature and pressure conditions.Type: GrantFiled: May 28, 2009Date of Patent: April 16, 2013Assignee: Asensou Technologies Co., Ltd.Inventor: Ren Yan Qin
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Patent number: 8414686Abstract: The present invention is directed to degassing devices for dialysate circuits. One embodiment has a first housing and a second housing positioned within the first housing in an annular relationship. A second embodiment comprises a dialysate regeneration system with urease, a dialyzer, and a housing with an external wall, where the external wall is exposed to atmosphere and comprises a material that passes gas but does not pass liquid and where the housing is positioned between the urease and dialyzer.Type: GrantFiled: September 21, 2011Date of Patent: April 9, 2013Assignee: Fresenius Medical Care Holdings, Inc.Inventors: Victor Gura, Carlos Jacobo Ezon, Masoud Beizai
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Patent number: 8414684Abstract: A degas assembly including a low pressure fluid channel for carrying a wash fluid at a first pressure, a pressurized channel for carrying eluent including a gas at a second pressure higher than the first pressure, and a degas separator defining a fluid barrier between the low pressure fluid channel and pressurized fluid channel, the separator configured to retain liquid in the pressurized fluid channel and allow gas to flow through the separator to the low pressure fluid channel. The pressurized fluid channel may extend along an outer periphery of the low pressure fluid channel. The eluent may be received from an eluent generator at a pressure of at least about 3300 psi, and in various embodiments up to about 5000 psi. A liquid chromatography system and method are also disclosed.Type: GrantFiled: June 1, 2010Date of Patent: April 9, 2013Assignee: Dionex CorporationInventors: Yan Liu, Christopher A. Pohl, Michael McAdams, Hamish Small, Zhongqing Lu, Milton Liu, Khosro Moshfegh
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Publication number: 20130075333Abstract: The invention relates to a system for use in the treatment of produced water, e.g., water treatment in connection with hydrocarbon production operations. Silica in produced water produces undesirable scaling in processing equipment, which causes excess energy usage and maintenance problems. Electrocoagulation (EC) at relatively high water temperature, followed by any of membrane distillation (MD) or forward osmosis (FO), may be combined with a process of ceramic ultra-filtration (UF filtration) to treat water. Water to be treated may be produced water that has been pumped from a subterranean reservoir. The treated water may be employed to generate steam. The system comprises a plurality of units (e.g., EC, forward osmosis, membrane distillation unit, UF filtration, etc) which can be configured as an on-site installation or a mobile unit for on-site or off-site water treatment.Type: ApplicationFiled: September 21, 2012Publication date: March 28, 2013Inventors: Randall B. Pruet, De Quang Vu, Prakhar Prakash
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Publication number: 20130075334Abstract: The invention relates to the treatment of water, including for example treatment in connection with hydrocarbon production operations. Silica in water produces undesirable scaling in processing equipment, which causes excess energy usage and maintenance problems. Electrocoagulation (EC) at relatively high water temperature may be combined with a process of ceramic ultra-filtration (UF filtration) employed to treat water, and optionally followed by any of membrane distillation or forward osmosis (FO). Water to be treated may be produced water that has been pumped from a subterranean reservoir. The treated water may be employed to generate steam. The treatment units (e.g., EC, forward osmosis, UF filtration, etc) can be configured into one system as an on-site installation or a mobile unit for on-site or off-site water treatment.Type: ApplicationFiled: September 21, 2012Publication date: March 28, 2013Inventors: Prakhar Prakash, James Craig Pauley, De Vu
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Publication number: 20130075335Abstract: The invention relates to the treatment of water, including for example treatment in connection with hydrocarbon production operations. Silica in water produces undesirable scaling in processing equipment, which causes excess energy usage and maintenance problems. Electrocoagulation (EC) at relatively high water temperature followed by ultra-filtration (UF filtration) may be combined with forward osmosis (FO) to treat water. Water to be treated may be produced water that has been pumped from a subterranean reservoir. The treated water may be employed to generate steam. The treatment units (e.g., EC, forward osmosis, UF filtration, etc) can be configured into one system as an on-site installation or a mobile unit for on-site or off-site water treatment.Type: ApplicationFiled: September 21, 2012Publication date: March 28, 2013Inventors: Prakhar Prakash, James Craig Pauley, Randall B. Pruet
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Publication number: 20130075332Abstract: The invention relates to the treatment of water, including for example treatment in connection with hydrocarbon production operations. Silica in water produces undesirable scaling in processing equipment, which causes excess energy usage and maintenance problems. Electrocoagulation (EC) at relatively high water temperature, followed by any of membrane distillation or forward osmosis (FO), may be combined with a subsequent process of ceramic ultra-filtration (UF filtration) employed to treat water. Water to be treated may be produced water that has been pumped from a subterranean reservoir. The treated water may be employed to generate steam. The treatment units (e.g., EC, forward osmosis, UF filtration, etc) can be configured into one system as an on-site installation or a mobile unit for on-site or off-site water treatment.Type: ApplicationFiled: September 21, 2012Publication date: March 28, 2013Inventors: Prakhar Prakash, James Craig Pauley, Randall B. Pruet
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MEMBRANE DISTILLATION MODULES USING OLEOPHOBICALLY AND ANTIMICROBIALLY TREATED MICROPOROUS MEMBRANES
Publication number: 20130068689Abstract: The present invention provides a system for liquid distillation which includes a vapor permeable-liquid impermeable microporous membrane having structures defining a plurality of pores, an oleophobic material that is applied to the structures of the membrane so as to leave the plurality of pores open, a means for supplying non-distilled liquid to the first side of the membrane, and a means for collecting distilled liquid from a second side of the membrane. In a further example, the present invention provides a method for the distillation of liquids.Type: ApplicationFiled: September 15, 2011Publication date: March 21, 2013Applicant: BHA Group, Inc.Inventors: Vishal Bansal, Christopher Keller -
Publication number: 20130071793Abstract: A method for fractionating a fuel includes heating the fuel and flowing it through hollow superhydrophobic membranes in a membrane module. Vapor from the fuel permeates the hydrophobic membranes and enters a distillate collection chamber, producing distilled fuel and residual fuel. The residual fuel is removed from the module and cooled. The cooled residual fuel is flowed through hollow tubes in the module and the distilled fuel is removed from the distillate collection chamber. Burning the distilled fuel reduces engine emissions. A fuel fractionation system includes a distillate collection chamber, hollow superhydrophobic membranes, hollow tubes and a distillate outlet. The hollow superhydrophobic membranes receive heated fuel and allow vapor from the heated fuel to permeate the membranes and enter the distillate collection chamber. The hollow tubes receive cooled residual fuel and are positioned to allow vapor in the distillate collection chamber to condense on outer surfaces of the hollow tubes.Type: ApplicationFiled: September 15, 2011Publication date: March 21, 2013Applicant: UNITED TECHNOLOGIES CORPORATIONInventors: Zidu Ma, Joseph J. Sangiovanni, Zissis A. Dardas, Meredith B. Colket, III
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Patent number: 8394176Abstract: Disclosed are a gas separation membrane and a gas separation method in which at least one species of organic vapor is separated and recovered from an organic vapor mixture using the gas separation membrane. The gas separation membrane is made of an aromatic polyimide composed of a tetracarboxylic acid component consisting of an aromatic ring-containing tetracarboxylic acid and a diamine component comprising 10 to 90 mol % of a combination of (B1) 3,4?-diaminodiphenyl ether and (B2) 4,4?-diaminodiphenyl ether at a B1 to B2 molar ratio, B1/B2, ranging from 10/1 to 1/10, and 10 to 90 mol % of other aromatic diamine.Type: GrantFiled: February 4, 2009Date of Patent: March 12, 2013Assignee: Ube Industries, Ltd.Inventors: Tomonori Kanougi, Harutoshi Hoshino, Toshimune Yoshinaga, Yoji Kase, Kenji Fukunaga
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Patent number: 8382988Abstract: The invention is directed to a process for the production of ultra pure water, comprising feeding water containing ions and optionally other impurities to one side of a membrane based on hydroxy sodalite (H-SOD), and recovering ultra pure water from the other side of the membrane.Type: GrantFiled: November 30, 2009Date of Patent: February 26, 2013Assignee: Techische Universiteit DelftInventors: Sheida Khajavi, Frederik Kapteijn, Jacobus Cornelis Jansen
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Patent number: 8376148Abstract: An object of the present invention is to provide a zeolite membrane composite satisfying both the treating amount and the separation performance at a practically sufficient level, which can be applied even in the presence of an organic material and can separate/concentrate an organic material-containing gas or liquid mixture and which is economic without requiring a high energy cost and is not limited in its application range; a production method thereof; and a separation or concentration method using the same. The present invention is an inorganic porous support-zeolite membrane composite, wherein the inorganic porous support contains a ceramic sintered body and the inorganic porous support-zeolite membrane composite has, as a zeolite membrane, a CHA-type zeolite crystal layer on the inorganic porous support surface.Type: GrantFiled: August 26, 2011Date of Patent: February 19, 2013Assignee: Mitsubishi Chemical CorporationInventors: Miki Sugita, Takahiko Takewaki, Kazunori Oshima, Naoko Fujita
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Patent number: 8361197Abstract: There is provided a zeolite separation membrane-provided article having gaps or pores larger than pores inherent to zeolite crystals and controlled within an appropriate range and being capable of achieving both high permeability and high separability for components with small difference in adsorption properties or a component having a smaller molecular diameter than the diameter of the pores, a method for producing the same, a method for separating mixed fluids, and a device for separating mixed fluids. The zeolite separation membrane-provided article is provided with a zeolite membrane having an N2 gas permeation speed at room temperature of 1.0×10?6 mol·m?2·s?1·Pa?1 or more and a permeation speed ratio of 1,3,5-trimethylbenzene/N2 at room temperature of 0.17 or more and being free from dyeing caused by the impregnation with Rhodamine B.Type: GrantFiled: September 13, 2011Date of Patent: January 29, 2013Assignee: NGK Insulators, Ltd.Inventors: Masaaki Kawai, Toshihiro Tomita, Nobuhiko Mori, Aya Satoh
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Publication number: 20130015133Abstract: The system and method reduces volatile organic compound concentration in a water distribution system using pressurized diffused aeration. The system and method is used in-line in a water distribution system. The system and method can be used at the ends of the distribution system where volatile organic compounds, including trihalomethanes, are more likely to persist. The system and method of pressurized, diffused aeration reduces volatile organic compounds from groundwater remediation systems as well.Type: ApplicationFiled: February 16, 2012Publication date: January 17, 2013Inventors: Ethan Brooke, Michael Robin Collins, John Michael Zwerneman
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Publication number: 20130015134Abstract: There is provided a carbon membrane formed by carbonizing a phenol resin having at least one kind of atomic groups selected from the group consisting of a methylene bond, a dimethylene ether bond, and a methylol group, wherein the total mole content rate of the atomic groups is 100 to 180% with respect to the phenolic nuclei.Type: ApplicationFiled: September 17, 2012Publication date: January 17, 2013Applicant: NGK INSULATORS, LTD.Inventor: NGK Insulators, Ltd.
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Publication number: 20130001164Abstract: A water distillation system includes a membrane distillation unit which produces desalinated water from feed water comprising salt water. The system also includes a primary water heater which raises a temperature of the feed water upstream of the feed water entering the membrane distillation unit. The system additionally includes an evaporative cooler which lowers a temperature of a coolant upstream of the coolant entering the membrane distillation unit.Type: ApplicationFiled: September 12, 2012Publication date: January 3, 2013Applicant: KING ABDULAZIZ CITY FOR SCIENCE AND TECHNOLOGYInventors: Ibrahim A. AL-ARIFI, Hisham Taha Abdulla EL-DESSOUKY
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Patent number: 8343348Abstract: A method for producing a carbon membrane of the present invention is a production method where a carbon membrane obtained by subjecting a carbon-containing layer to thermal decomposition in an oxygen inert atmosphere while sending a gas mixture containing an oxidizing gas thereinto is thermally heated. The carbon membrane is subjected to a heating oxidation treatment with controlling the ratio of the flow rate of the gas mixture to the areas of the carbon membrane to 0.5 cm/min. or more to control (temperature ° C.)2×time (h)/10000, which is the relation between the temperature of the gas mixture and the flow time, to 9 to 32. This enables to obtain a carbon film which selectively separates alcohols having 2 or less carbon atoms from a liquid mixture of the alcohols having 2 or less carbon atoms and organic compounds having 5 to 9 carbon atoms.Type: GrantFiled: December 28, 2011Date of Patent: January 1, 2013Assignee: NGK Insulators, Ltd.Inventors: Aya Satoh, Nobuhiko Mori
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Patent number: 8328906Abstract: The present disclosure relates to a high molecular weight, monoesterified polyimide polymer. Such high molecular weight, monoesterified polyimide polymers are useful in forming crosslinked polymer membranes for the separation of fluid mixtures. According to its broadest aspect, the method of making a crosslinked membrane comprises the following steps: (a) preparing a polyimide polymer comprising carboxylic acid functional groups from a reaction solution comprising monomers and at least one solvent; (b) treating the polyimide polymer with a diol at esterification conditions in the presence of dehydrating conditions to form a monoesterified polyimide polymer; and (c) subjecting the monoesterified fiber to transesterification conditions to form a crosslinked fiber membrane, wherein the dehydrating conditions at least partially remove water produced during step (b). The crosslinked membranes can be used to separate at least one component from a feed stream including more than one component.Type: GrantFiled: November 28, 2011Date of Patent: December 11, 2012Assignees: Chevron U.S.A. Inc., Georgia Tech Research CorporationInventors: Stephen J. Miller, Imona C. Omole, William J. Kronos
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Publication number: 20120305484Abstract: Synthesis and use of a new class of polymeric materials with favorable separation characteristics for the dehydration of ethanol and other organic solvents is described herein. The thermally rearranged (TR) polybenzoxazole (PBO), polybenzimidazole (PBI) and polybenzothiazole (PBT) membranes of the present invention can be used for the dehydration of ethanol during processing to fuel grade biodiesel by either pervaporation or vapor permeation. The unique microstructure of the membranes provides excellent separation characteristics, and this, coupled with their inherent thermal and chemical stability, enables their usage in other separations, such as the dehydration of other organic solvents.Type: ApplicationFiled: June 3, 2011Publication date: December 6, 2012Applicant: Board of Regents, The University of Texas SystemInventors: Benny D. Freeman, Donald R. Paul, Katrina Czenkusch, Claudio P. Ribeiro, JR., Chaoyi Ba
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Patent number: 8323379Abstract: A method of improving the blood compatibility of a blood-contacting surface includes immobilizing carbonic anhydrase on the surface, wherein the surface exhibits carbonic anhydrase activity of at least 20% of maximum theoretical activity of the surface based on monolayer surface coverage of carbonic anhydrase.Type: GrantFiled: October 24, 2011Date of Patent: December 4, 2012Assignee: University of Pittsburgh—of the Commonwealth System of Higher EducationInventors: William J. Federspiel, Alan J. Russell, Heung-Il Oh, Joel Kaar
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Patent number: 8318013Abstract: The present invention involves the use of a multi-stage membrane system for gas, vapor, and liquid separations. In this multi-stage membrane system, high selectivity and high permeance or at least high selectivity polybenzoxazole membranes or cross-linked polybenzoxazole membranes are applied for a pre-membrane or both the pre-membrane and the secondary membrane. A primary membrane can be from conventional glassy polymers. This multi-stage membrane system can reduce inter-stage compression cost, increase product recovery and product purity for gas, vapor, and liquid separations. It can also save the cost compared to the system using all the high cost polybenzoxazole membranes or cross-linked polybenzoxazole membranes.Type: GrantFiled: December 19, 2011Date of Patent: November 27, 2012Assignee: UOP LLCInventors: Lubo Zhou, Chunqing Liu, Carlos A. Cabrera, Peter K. Coughlin
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Patent number: 8318023Abstract: Contaminating water and/or fuel material may be removed from a stream of internal combustion engine lubricating oil being circulated over parts of an operating engine. A suitable membrane material is supported in a suitable housing. At least a portion of the oil stream is flowed over one side of the membrane and water and/or fuel material diffuses through the membrane to its other side where they are gathered and removed from the housing. The water and fuel material may be recovered separately using different membranes or different regions of a membrane. They may be swept from the membranes and housings using streams of flowing air heated to a pre-selected temperatures using waste engine heat for disposition outside the housing. Application of this practice to other membrane-separable mixtures is described.Type: GrantFiled: September 28, 2009Date of Patent: November 27, 2012Assignee: GM Global Technology Operations LLCInventors: Gregory Mordukhovich, Andrew M. Mance
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Publication number: 20120285889Abstract: The present invention relates to a membrane separation method and a relevant equipment, in particular to a method and an equipment for membrane separation utilizing concentration polarization during membrane filtration process, especially, to a concentration process and equipment and a drawer special for drawing a concentration polarization layer. The direct removal of the concentration polarization layer from membrane surface not only decreases the adverse influence of concentration polarization on membrane separation but also obtains concentrated retention components, thereby significantly improving the ability to maintain membrane flux, solving the twinborn problems concerning concentration polarization and membrane fouling during the membrane separation process, and achieving a high-efficiency concentration for retention components.Type: ApplicationFiled: July 23, 2012Publication date: November 15, 2012Applicant: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY OF SCIENCESInventors: Yinhua Wan, Xiangrong Chen, Zhiguo Su, Guanghui Ma, Xiaoguang Jiao, Fei Shen, Zhanfeng Cui
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Publication number: 20120283489Abstract: A method of removing water from fluid mixtures of the water with other compounds uses selective vapor permeation or pervaporation of the water, as the case may be, from the mixture through a membrane having an amorphous perfluoropolymer selectively permeable layer. The novel process can be applied in such exemplary embodiments as (a) removing water from mixtures of compounds that have relative volatility of about 1-1.1 or that form azeotropic mixtures with water, (b) the dehydration of hydrocarbon oil such as hydraulic fluid to concentrations of water less than about 50 ppm, (c) removing water byproduct of reversible chemical equilibrium reactions to favor high conversion of reactants to desirable products, (d) drying ethanol to less than 0.5 wt. % water as can be used in fuel for internal combustion engines, and (e) controlling the water content to optimum concentration in enzyme-catalyzed chemical reactions carried out in organic media.Type: ApplicationFiled: July 19, 2012Publication date: November 8, 2012Applicant: CMS TECHNOLOGIES HOLDINGS INC.Inventors: Stuart M. Nemser, Sudipto Majumdar, Kenneth J. Pennisi
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Patent number: 8293112Abstract: A method of removing water and/or methanol from fluid mixtures of the water or methanol with other compounds uses vapor permeation or pervaporation of the water or methanol, as the case may be, from the mixture through a membrane having an amorphous perfluoropolymer selectively permeable layer. The novel process can be applied in such exemplary embodiments as (a) removing water or methanol from mixtures of compounds that have relative volatility of about 1-1.1 or that form azeotropic mixtures with water or methanol, (b) the dehydration of hydrocarbon oil such as hydraulic fluid to concentrations of water less than about 50 ppm, (c) removing water and methanol byproducts of reversible chemical reactions thereby shifting equilibrium to favor high conversion of reactants to desirable products, (d) drying ethanol to less than 0.5 wt.Type: GrantFiled: October 26, 2007Date of Patent: October 23, 2012Assignee: CMS Technologies Holdings, Inc.Inventors: Stuart M. Nemser, Sudipto Majumdar, Kenneth J. Pennisi
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Patent number: 8287735Abstract: The invention provides a method for the purification of a liquid by membrane distillation comprising: passing a heated vapourising stream of a liquid (retentate stream) through a retentate channel along a porous hydrophobic membrane (10), whereby vapour of the liquid flows via the pores of the membrane to the other side of said membrane, and condensing said vapour on the other side of said membrane to give a distillate stream in a distillate channel (5) which distillate is created by passing the heat of condensation (latent heat) towards a condenser surface (3), said condenser surface forming a non-porous separation between a feed stream of the liquid to be purified and said distillate stream, which feed stream is passed through a feed channel (2) in counter-current with the retentate stream, in which feed channel a space material (4) is arranged whereby at least part of the latent heat is transferred via the condenser surface to the feed stream, and whereby a positive liquid pressure difference is applied beType: GrantFiled: October 31, 2007Date of Patent: October 16, 2012Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNOInventors: Jan Hendrik Hanemaaijer, Albert Edward Jansen, Jolanda Van Medevoort, Hans De Jong, Eric Van Sonsbeek, Engelbert Peter Jurrie Jan Koele, Jan Willem Assink
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Patent number: 8282708Abstract: Methods for the purification of steam, systems for purifying steam, methods for measuring and/or controlling steam flow rates, and uses for purified steam are provide. Also provided are substantially gas-impermeable membranes, such as perfluorinated ionomers (e.g., perfluoroethylene-sulfonic-acid/tetrafluoroethylene membranes), having a high ratio of water vapor permeation relative to gas permeation through the membrane. Also provided are methods of operation of such membranes at relatively high operating temperatures for the purification of steam and for operation of such membranes at relatively low temperature and sub-atmospheric pressures for the purification of steam. In a preferred embodiment, the system 400 for purifying steam comprises heater 404 for creating a source of a steam feed, and a purification device 416 for housing a substantially gas-impermeable membrane 424. In the operation of system 400, water, such as deionized water, is added to vessel 402 to provide a source of the steam feed.Type: GrantFiled: September 12, 2006Date of Patent: October 9, 2012Assignee: RASIRCInventors: Jeffrey J. Spiegelman, Richard D. Blethen
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Publication number: 20120234756Abstract: Disclosed is a method of controlling a real-time oxidation-reduction potential in a hot water system to inhibit corrosion in the hot water system. The method includes defining one or more operational protective zones in the hot water system. One or more of the operational protective zones includes an oxidation-reduction potential probe that is operable to measure a real-time oxidation-reduction potential in the hot water system at operating temperature and pressure. The probe transmits the measured real-time potential to the controller, which assesses and interprets the transmitted potential to determine whether it conforms to an oxidation-reduction potential setting. If the measured potential does not conform the oxidation-reduction potential setting, the controller is operable to feed or remove one or more active chemical species into or from the hot water system and further operable to change at least one system parameter.Type: ApplicationFiled: April 9, 2012Publication date: September 20, 2012Inventors: Peter D. Hicks, David A. Grattan
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Publication number: 20120228222Abstract: Separation processes using forward osmosis are disclosed generally involving the extraction of a solvent from a first solution to concentrate a solute therein by using a second concentrated solution to draw the solvent from the first solution across a semi-permeable membrane. One or both of the solute and solvent may be a desired product. By manipulating the equilibrium of the soluble and insoluble species of solute within the second solution, a saturated second solution can be used to generate osmotic pressure on the first solution. The various species of solute within the second solution can be recovered and recycled through the process to affect the changes in equilibrium and eliminate waste products. Enhanced efficiency may result from using low grade waste heat from industrial or commercial sources.Type: ApplicationFiled: March 14, 2012Publication date: September 13, 2012Applicant: Yale UniversityInventors: Robert L. McGinnis, Menachem Elimelech
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Publication number: 20120228225Abstract: The present invention relates to a method for contemporaneously recovering ammonia and carbon dioxide from an aqueous solution thereof, possibly comprising their condensates, in a synthesis process of urea, characterized in that it comprises a hydrophobic microporous membrane distillation phase of an aqueous solution comprising ammonia, carbon dioxide and their saline compounds or condensates, said distillation being carried out at a temperature ranging from 50 to 250° C. and a pressure ranging from 50 KPa to 20 MPa absolute, with the formation of a residual aqueous solution, possibly comprising urea, and a gaseous permeate stream, comprising ammonia, carbon dioxide and water. The present invention also relates to an apparatus for effecting the above method and a production process of urea which comprises the above method.Type: ApplicationFiled: September 1, 2010Publication date: September 13, 2012Applicant: SAIPEM S.p.A.Inventors: Paolo Casara, Alessandro Gianazza
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Patent number: 8262778Abstract: The invention relates to polymeric ultrafiltration or microfiltration membranes of, for instance, poly(ethylene chlorotrifluoroethylene) (HALAR®), PVDF or PP, incorporating PVME or vinyl methyl ether monomers. The PVME may be present as a coating on the membrane or dispersed throughout the membrane or both. The membranes are preferably hydrophilic with a highly asymmetric structure with a reduced pore size and/or absence of macrovoids as a result of the addition of PVME. The PVME maybe cross-linked. The invention also relates to methods of hydrophilising membranes and/or preparing hydrophilic membranes via thermal or diffusion induced phase separation processed.Type: GrantFiled: August 10, 2011Date of Patent: September 11, 2012Assignee: Siemens Industry, Inc.Inventors: Daniel Mullette, Joachim Muller, Neeta Patel
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Patent number: 8262779Abstract: The present invention discloses microporous aluminophosphate (AlPO4) molecular sieve membranes and methods for making and using the same. The microporous AlPO4 molecular sieve membranes, particularly small pore microporous AlPO-14 and AlPO-18 molecular sieve membranes, are prepared by three different methods, including in-situ crystallization of a layer of AlPO4 molecular sieve crystals on a porous membrane support, coating a layer of polymer-bound AlPO4 molecular sieve crystals on a porous membrane support, and a seeding method by in-situ crystallization of a continuous second layer of AlPO4 molecular sieve crystals on a seed layer of AlPO4 molecular sieve crystals supported on a porous membrane support.Type: GrantFiled: August 16, 2010Date of Patent: September 11, 2012Assignee: UOP LLCInventors: Chunqing Liu, Stephen T. Wilson, David A. Lesch
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Patent number: 8256626Abstract: A composite membrane is provided for the separation of water with at least one separation layer of cross-linked polyvinyl alcohol, with the separation layer being subjected in a separate process step to a post-crosslinking operation with an acid or an acid-releasing compound and at least one dialdehyde.Type: GrantFiled: September 18, 2009Date of Patent: September 4, 2012Assignee: Souzer Chemtech GmbHInventors: Andreas Hübner, Elena Gonzalez Diaz, Michael Frania
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Publication number: 20120211421Abstract: Systems and methods for lowering levels of carbon dioxide and other atmospheric pollutants are provided. Economically viable systems and processes capable of removing vast quantities of carbon dioxide and other atmospheric pollutants from gaseous waste streams and sequestering them in storage-stable forms are also discussed.Type: ApplicationFiled: March 1, 2012Publication date: August 23, 2012Inventors: KYLE SELF, Kasra Farsad, Robert W. Elliott, Brian Curtis, Srikanth Bellur, Miguel Fernandez, Philip Brian Tuet
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Publication number: 20120210869Abstract: The present invention relates to a membrane, in particular to a hollow fiber membrane comprising a membrane, comprising at least two layers, wherein the at least two layers each comprise at least one layer forming material comprising at least one polymer and the at least two layers differ from each other with respect to the layer forming material, wherein the at least two layers are at least partly covalently and delamination free bonded to each other. The present invention relates furthermore to a method of production of the said membrane as well as to its use.Type: ApplicationFiled: December 20, 2011Publication date: August 23, 2012Applicant: FRESENIUS MEDICAL CARE DEUTSCHLAND GMBHInventors: Christian Finkler, Rainer Fislage, Torsten Keller, Igor Raiko, Roland Sander
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Polymer membranes prepared from aromatic polyimide membranes by thermal treating and UV crosslinking
Patent number: 8241501Abstract: The present invention discloses a new type of high performance polymer membranes prepared from aromatic polyimide membranes by thermal treating and crosslinking and methods for making and using these membranes. The polymer membranes were prepared from aromatic polyimide membranes by thermal treating under inert atmosphere followed by crosslinking preferably by using a UV radiation source. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The membranes showed significantly improved selectivity and permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The membranes can be fabricated into any convenient geometry and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used for other applications such as for catalysis and fuel cell applications.Type: GrantFiled: June 22, 2011Date of Patent: August 14, 2012Assignee: UOP LLCInventors: Chunqing Liu, Peter K. Coughlin, Man-Wing Tang, Raisa Minkov, Lubo Zhou