Abstract: An apparatus for use in the treatment of contaminated fluid is provided. The apparatus includes an outer element into which contaminated fluid flows and an inner element positioned in substantial axial alignment within the outer element and in spaced relations thereto. The apparatus also includes, between its ends, a pathway defined by an interior surface of the inner element and along which treated fluid may be directed out from the apparatus. A waste nanoadsorbent material can be provided between the outer element and the inner element, for use in removing contaminants within the fluid flowing through the apparatus. A method for the treatment of contaminated fluid is also provided.

Abstract: Colored wastewater from industries, agriculture and the like is discolored by adjusting pH of the wastewater and filtering the wastewater through a mixture of acid-treated sawdust produced from sawdust which has been disposed of after being used for fungi production and charcoal thereby to remove a color component fraction from the wastewater and through a filter material, for example acid-treated rice husk charcoal, in which autochthonous microorganisms are embedded thereby to absorb color components remaining in the wastewater.

Abstract: The present invention realizes an ion exchange apparatus capable of enhancing the reliability of regeneration operation. Further, the present invention realizes an ion exchange apparatus capable of simplifying the construction of a salt water supply device. The ion exchange apparatus includes a resin bed housing part (2) in which an ion exchange resin bed (5) is housed; a flow passage control valve (3) for switching between a water service operation and a regeneration operation; and a salt water tank (40) for reserving salt water to be used in regeneration, the flow passage control valve (3) being connected to the salt water tank (40) through a salt water supply line (31), in which the salt water supply line (31) is provided with a flow detecting unit (48) for detecting a flow rate in a direction of supplying salt water and a flow rate in a direction of supplying refill water.

Abstract: A process for obtaining one or more than one salt of an organic acid(s), or organic acid(s), from an aqueous sugar stream comprising one or more than one mineral acid and the organic acid(s) is provided. The process comprises introducing the aqueous sugar stream to a separation system comprising one or more beds of anion exchange resin and obtaining a stream therefrom comprising the sugar. The one or more beds of anion exchange resin are then regenerated in one or more stages to produce at least one product stream comprising the organic acid, a salt of the organic acid, or a combination thereof, and a separate outlet stream comprising the mineral acid, a salt of the mineral acid, or a combination thereof. The product stream is then recovered. The separation may be conducted with two separation units, or using a single anion exchange unit.

Abstract: Exemplary systems and methods relating to water treatment are described. One implementation filters water through a moving bed media filter sufficient to decrease the water's turbidity. This implementation simultaneously disinfects the filtered water and at least a portion of the moving bed media filter with ultra violet (UV) energy.

Abstract: A diamine absorbent that contains heat stable salts is regenerated using an ion exchange process wherein the concentration of heat stable salts in the feed stream provided to the cation exchange unit is limited.

Abstract: The invention provides chemically activated valves based on crystalline molecular sieve membranes. Adsorption of a swelling agent within the pores of the molecular sieve crystals limits transport through the membrane. Desorption of the swelling agent can re-establish transport through the membrane. This valving mechanism can be used in methods for storing and dispensing various substances.

Abstract: A multi-stage process for removing dissolved contaminants and suspended solids from water employing a magnetic separation technique. The process includes two tanks and magnetic seed. In the first tank, water is clarified by magnetic technologies and in the second tank dissolved solutes are sorbed on magnetic seed.

Abstract: Described herein are fluid treatment devices for use in tangential flow filtration, comprising a housing unit and a composite material, wherein the composite material comprises: a support member comprising a plurality of pores extending through the support member; and a non-self-supporting macroporous cross-linked gel comprising macropores having an average size of 10 nm to 3000 nm, said macroporous gel being located in the pores of the support member. The invention also relates to a method of separating a substance from a fluid, comprising the step of placing the fluid in contact with an inventive device, thereby adsorbing or absorbing the substance to the composite material contained therein.

Abstract: Methods, devices, and systems, and devices for carrying out sorption (adsorption and absorption) for separating and/or purifying fluid mixtures are disclosed. Medical oxygen generators, dehumidifying units, sorptive heat pumps, ozone generators and Peltier devices are also disclosed. The sorption methods involve pressure swing operation of at least two sorption units. Energy from the desorbing and decompressing fluid is substantially recovered and used within the system.

Abstract: A method and an apparatus for removing dissolved organic substances from an oily water obtained as a by-product from an oilfield, characterized in that an oily water obtained as a by-product from an oilfield by separating a crude oil from a crude oil/brine mixture is brought into contact with an adsorbent to adsorptively remove organic substances dissolved in the water containing oil suspended therein and that the adsorbent is regenerated.

Abstract: A process for the removal of liquid, gaseous and/or dissolved constituents from a process stream. The process stream is contacted with an adsorbent comprising a first porous material which has been incorporated into a second porous material at least 30 vol. % of the pores of the first and second porous materials of which are filled with an extraction liquid. The affinity between the adsorbent and the constituents to be removed exceeds the affinity between the constituents and the extraction liquid.

Abstract: A magnetic chemical absorbent according to the present invention is provided with a composite, which is constituted of a core substance comprising magnetite fine particles and schwertmannite being precipitated around the core substance to chemically bond therewith. This magnetic chemical absorbent can be produced in a hydrolysis reaction step, in which crystal of schwertmannite is precipitated by means of hydrolysis reaction by heating a solution of ferric salt and thereafter adding a reactive substance thereto, by means of adding magnetite fine particles into the solution after the solution is heated and before the precipitation of the crystal begins. This magnetic chemical absorbent is novel and good one whose absorption capability for harmful ion is upgraded more. In accordance with a waste-liquid treating method using this magnetic chemical substance, it is possible to intend the reduction of burdens in view of environmental and economic aspects. Moreover, this magnetic chemical absorbent is recyclable.

Abstract: An adsorbent for removal of impurities from silicone based solvents is presented. The adsorbent is regenerable for repeated use in cleaning silicone based solvents.

Abstract: A method for removing fluorine gas from a selected environment comprises contacting the fluorine gas with water to generate a solution of hydrofluoric acid and contacting the solution of hydrofluoric acid with an ion exchange resin having an active state operative to exchange selected ions therein for fluoride ions in the solution. The apparatus (200) may include a dual resin setup (222, 223) such that one of the ion-exchange resin can be in the service cycle while the other of the ion-exchange resins undergoes the regeneration and rinse/refill cycles.

Abstract: Systems and methods are disclosed that promote the remediation of contaminated materials that are produced during industrial processes. These systems and methods include heating a material, transferring heat from the material to an industrial process. During this transfer, contaminants may be introduced into the material. These methods may remove the contaminant by treating the material with a surface modified nanoceramic through nanofiltration and/or active sites adsorption/reaction. The surface modified nanoceramic may remove at least part of the contaminant in the material. No cooling required prior to removing the contaminant from the material, which can lead to great energy saving and pollution reduction.

Abstract: This invention is an improved process for operation of evaporative recirculating cooling systems. In addition to reducing the scaling and corrosive tendencies of the water, the method eliminates or reduces discharge from the system without creating any localized corrosive or scaling conditions as a result of the treatment process. The described measurement and control system generally comprises an array of measurements, a means of implementing control logic, and an array of control actions including activating an ion exchange device to treat makeup water. The measurements can include of physical measurements of flow rates, chemical measurements of water composition, and performance-related metrics such as water corrosiveness or scaling tendency. Preferably, the measurements include one or more of pH, conductivity, hardness, alkalinity, corrosiveness, scaling tendency, treatment additive dosage level, and treatment additive residual of the makeup, treated makeup, and recirculating water.

Abstract: Nanoparticle-treated particle packs, such as sand beds, may effectively filter and purify liquids such as waste water. Proppant beds treated with nanoparticles may fixate or reduce fines migration therethrough. When tiny contaminant particles or fines in these fluids flow through the nanoparticle-treated bed or pack, the nanoparticles will capture and hold the tiny contaminant or fines particles within the pack due to the nanoparticles' surface forces, including, but not necessarily limited to van der Waals and electrostatic forces. Nanoparticle-treated beds or packs may be recharged by contacting the bed with an inorganic acid (but not hydrofluoric acid) or an organic acid, and optionally followed by subsequent treatment with hydrofluoric acid. This treating substantially removes the nanoparticles and the fine particulates that have been removed from a fluid (e.g. wastewater being treated, produced fluids in a formation, etc.). The particle pack may then be re-treated or recharged with nanoparticles.

Abstract: Exemplary embodiments of the present invention relate to a fuel filter, system, and method for reduction, manipulation and/or distribution of sulfur containing compounds in a fuel stream of an internal combustion engine. In one exemplary embodiment of the present invention, a method of removing sulfur containing compounds from a fuel stream of an internal combustion engine is provided. The method includes removing sulfur containing compounds from a fuel stream by passing fuel through a fuel filter capable of removing sulfur containing compounds. The method also includes storing the sulfur containing compounds in the fuel filter and releasing portions of the stored sulfur containing compounds into the fuel stream at predetermined intervals of a regeneration cycle of an emission control device.

Abstract: A method and apparatus are described for removing iron cations and/or zinc cations from an autodeposition coating bath by passing a limited number of bed volumes through a column containing a gel type SAC IEX resin when iron cations are to be removed and passing a substantially larger number of bed volumes through the column when zinc cations are to be removed. To prevent clogging when zinc cations are being removed the direction of the flow through the column is periodically reversed.

Abstract: One embodiment of the present invention is a method of regenerating an ion exchange medium having a bacterial population, comprising dissolving a salt formulation in water to create a brine and passing the brine through the ion exchange medium during a regenerating cycle, wherein the salt formulation comprises a food-grade acid, at least about 100 ppm of a food-grade surfactant, and at least about 90 wt. % of an inorganic, water-soluble salt of sodium, potassium, or sodium and potassium and wherein the acid and the surfactant are present in the brine in an amount efficacious to kill at least about 65% of gram negative bacteria in the bacterial population as a result of the regenerating cycle.

Abstract: A method for removing and recovering phosphorus from a spent adsorbent medium to result in a regenerated medium and a phosphorus-containing solution useful as a fertilizer.

Abstract: An apparatus and method for determining the end of a service step and the duration of a brine/slow rinse step in a water conditioner having a bed of ion-exchange material. A sensor probe and a reference probe are positioned in the bed of ion-exchange material vertically displaced from each other. Voltage from each of the probes are monitored over a plurality of time intervals. When the percent increase in the impedance ratio exceeds a pre-specified value the end of a service step is identified and a regeneration cycle is initiated. During the regeneration step, the rate of change in the impedance ratio of the sensor probe to the reference probe is calculated and used to detect two peaks in the rate of change of impedance ratio between the sensor probe and the reference probe, followed by terminating the brine/slow rinse step after both peaks have been detected.

Abstract: In the process for producing kraft pulp, performing a potassium ion removal step of flowing an aqueous solution containing ashes recovered from a combustion exhaust gas generated in a black solution combustion step by a dust collector through a packed bed filled with a sodium-type cation exchange organic resin to adsorb and remove potassium ions contained in the aqueous solution; and a regeneration step of treating the cation exchange organic resin used in the potassium ion removal step with a solution consisting essentially of aqueous sodium hydroxide to regenerate the cation exchange resin, where a fraction recovered from the potassium ion removal step which is rich in sodium sulfate and sodium carbonate is recycled to the black solution concentrating step, and a sodium hydroxide effluent recovered from the regeneration step is recycled to a bleaching step and used in a bleaching process.

Abstract: Embodiments of the present invention are directed to porous resins for solid phase extractions. The resins feature at least one hydrophobic component, at least one hydrophilic component and at least one ion exchange functional group. The resins exhibit superior wetting and ion exchange performance.

Abstract: A process for removing DOC (dissolved organic carbon) from a concentrated salt solution containing DOC by contacting the salt solution with a coagulant/flocculant such that the DOC becomes insoluble and removing the insoluble DOC from the salt solution.

Abstract: Ion transport apparatus (e.g. an electrolytic eluent generator or a suppressor for ion chromatography) in which ions in a first chamber are transported to a liquid in second chamber through a wall comprising an ion exchange bead sealed in a bead seat. The wall is capable of transport ions but of substantially blocking bulk liquid flow.

Abstract: A system and method to remove a polluting agent or contaminant, including but not limited to mercury, from the liquid phase of a process system using an adsorbent. In one exemplary embodiment, a magnetic or non-magnetic support with a chemisorbing or physisorbing sorbent is suspended in the liquid phase of a process system, under conditions in which the polluting agent binds to the adsorbent. The pollutant-bearing adsorbent may then be separated from the process system by either physical or magnetic means. The polluting agent may then disassociated from the adsorbent so the adsorbent is regenerated and capable of repeated use.

Abstract: In a method and apparatus for operating and regenerating ion exchange material a wash fluid or elution solution for rinsing the ion exchange material (1) is prepared, there is collected as a by-product of said preparation a first waste stream including cationic species to be eliminated, the ion exchange material (1) is subjected to a wash step in which there is eluted from the ion exchange material by the wash fluid or solution an anionic species to be eliminated and a second waste stream including the anionic species to be eliminated is obtained, the first waste stream (12) and the second waste stream (14) are combined to form a precipitate SW comprising a reaction product of said cationic species and said anionic species, and the precipitate is removed. The method provides an efficient means of eliminating undesired species from a circuit containing an ion exchange material to be regenerated.

Abstract: A process for the removal of residual sulfur compounds from a liquid caustic stream is disclosed. One embodiment of my invention adsorbs disulfides from a caustic stream using an activated carbon adsorbent while another combines both oxidation and adsorption in single step to remove residual sulfur compounds from a rich caustic stream using metal phthalocyanine supported on a solid adsorbent. This process is especially useful as a polishing step in a caustic regeneration process flow scheme.

Abstract: A method of removing impurities from a urea solution comprising contacting the aqueous solution with an ion exchange resin and adsorbing the impurities from the urea solution, and the system therefore.

Abstract: A method for fluid treatment that provides alternative regeneration cycles within the same fluid treatment device. A second alternative regeneration cycle is available within the same device, which has independent cycles or processes from the first regeneration cycle. The first and second regeneration cycles can be programmed at the same time and be programmed to alternatively run based upon the number of individual cycles run, the time the cycles have run, the amount of fluid that has passed through the device, or the concentration of brine and/or chlorine in the fluid within the device.

Abstract: A process for the treatment of effluent, particularly acid mine drainage, is provided which includes the steps of a. neutralising acid; b. removing cations by ion exchange using a cation resin; c. regenerating the cation resin; d. treating the eluates of the cation ion exchange step; e. adsorbing anions from the effluent of the cation removal step using an anion exchange resin; and f. regenerating the anion exchange resin.

Abstract: Processes comprising: providing an anion exchanger at least partially loaded with hexachlorostannate; and contacting the at least partially loaded anion exchanger with a 1 to 10 wt. % hydrochloric acid solution to regenerate the anion exchanger.

Abstract: The invention relates to a method of separating components of a fluid mixture comprising the steps of providing a fluid, providing a sorbent structure (120), sorbing a first component of the fluid, desorbing the first component, and electrokinetically biasing the first component in a direction other than the vector of the fluid mixture.

Abstract: Described herein are compositions and methods useful for the purification of water using dendritic macromolecules. The process involves using dendritic macromolecules (dendrimers) to bind to contaminants, and a filtration step to produce water from which contaminants have been removed or modified. Examples of dendrimers that may be used in the process include cation-binding dendrimers, anion-binding dendrimers, organic compound-binding dendrimers, redox-active dendrimers, biological compound-binding dendrimers, catalytic dendrimers, biocidal dendrimers, viral-binding dendrimers, multi-functional dendrimers, and combinations thereof. The process is readily scalable and provides many options for customization.

Abstract: A method for removing fluorine gas from a selected environment comprises contacting the fluorine gas with water to generate a solution of hydrofluoric acid and contacting the solution of hydrofluoric acid with an ion exchange resin having an active state operative to exchange selected ions therein for fluoride ions in the solution. The apparatus (200) may include a dual resin setup (222, 223) such that one of the ion-exchange resin can be in the service cycle while the other of the ion-exchange resins undergoes the regeneration and rinse/refill cycles.

Abstract: Systems and methods for removing perchlorate load off of ion exchange resins are disclosed. The systems and methods rely upon direct contact between the resin and a liquid product formed by the culturing of perchlorate-destroying microorganisms. These methods can be incorporated into methods for removing perchlorate from aqueous streams. A resin product comprising an anion exchange resin with a coating of perchlorate-destroying microorganisms on its surface is also disclosed.

Abstract: A method of treating water to remove fluoride ions from the water, thereby to reduce the dissolved fluoride content of the water, is provided. The method includes, in a contacting step, contacting water containing dissolved fluoride ions with alumina, to cause the fluoride ions to react with and become bound to the alumina. In a regenerating step, the alumina, when spent, is regenerated to drive off fluoride ions bound thereto. The regenerated alumina is recycled to the contacting step where it is used to remove further fluoride ions from the water. The fluoride ions driven off the alumina in the regenerating step are passed on to downstream processing thereof.

Abstract: A system and method is provided for removing organic matter from water. The method includes contacting the water with a powdered material with an anionic or cationic surface charge and having a particle size of between 0.1 mm and 2 mm. The powdered material is a modified product of natural origin. The system and method also provides for the regeneration of the powdered material in situ and reused.

Abstract: A treatment method of organic compounds included in waste water, comprising the steps of: supplying waste water to an adsorber 2 filled with an adsorbent 3 therein for adsorbing the organic compounds in the waste water by the adsorbent 3 in the adsorber 2, supplying a current between an anode 9 and a cathode 8 in water including an electrolyte in an electrolyzer 6 for electrolyzing the water including an electrolyte, and supplying an electrolyte resulting from electrolysis in the electrolyzer 6 to the adsorbent 3 in the adsorber 2 for contacting the electrolyte with the adsorbent 3, so that the organic compounds adsorbed by the adsorbent 3 are desorbed or decomposed.

Abstract: An apparatus and process for removing impurities from silicone based solvents is presented. The apparatus and process use an adsorbent for removing contaminants from the solvent, and when the adsorbent is sufficiently loaded with contaminants, the adsorbent is regenerated. The regeneration process entails a two stage heating process for recovery of solvent and removal of contaminants.

Abstract: The invention relates to chemical industry and can be used for extracting perchlorate-ion from a highly concentrated processing solution having a complex nitrate-chloride-sulphate-iodate composition. The inventive method for extracting perchlorate-ion from an aqueous solution comprises passing the solution through a highly basic anionite and subsequent regeneration of the said anionite in a metal salt aqueous solution. The anionite in the nitrate form is used as an anionite, and its regeneration is performed in an aqueous solution of alkali or alkali-earth metal nitrate at the temperature of 0-60° C.

Abstract: A method of extracting sparingly soluble organic contaminants from a water or gas stream is provided. Contaminants are removed from a contaminant stream by passing the stream through hydrophilic polyurethane or a composite comprising an open cell hydrophobic polyurethane foam having a plurality of surfaces defining a plurality of pores which have disposed thereon a coating of a substantially open cell hydrophilic polyurethane foam. The hydrophilic polyurethane or composite may then be regenerated when saturated with contaminant.

Abstract: A process for purifying a liquid from a dissolved solute includes the exposure of the liquid to a material absorbing the liquid in preference to the dissolved solute. The dissolved solute is adsorbed onto the material. Through exposure of the dissolved solute adsorbed on said material to output of an ionization source, solute release from the material occurs. Purification of the liquid to remove the dissolved solute occurs through the release of the liquid from said material separate from the release of the dissolved solute. A system for purifying a liquid from a dissolved solute includes a super absorbent polymer within a housing. A pH source is provided to released purified absorbed liquid portion A via a first outlet in the housing for collecting the released absorbed liquid portion A. An ionization source releases solute absorbed liquid portion B that is collected as a solute rich adsorbed liquid portion B.

Abstract: Improved systems and methods for removing the load of perchlorate and other oxyanions off of ion exchange resins through bioregeneration are disclosed. The improved systems and methods rely upon direct contact between the resin and a liquid product containing enrichment cultures of or pure strains of perchlorate-destroying microorganisms. Controlled temperatures also lead to improvements as do upflow conditions leading to bed expansion. These methods can be incorporated into methods for removing perchlorate from aqueous streams.

Abstract: The present invention includes a porous ceramic material for use in removing aqueous contaminants from water. The ceramic material is formed by drying particular types of clay-water mixtures from air dry to 600° C. The clay is then calcined at between 700° C. and 1175° C. Finally, the clay is processed to a size larger than colloidal. The present invention also includes a system for removing pollutants from water consisting of a container filled with the porous ceramic material. The container may be serially connected to other containers and may be disposed on a trailer for portability. The present invention further includes a method of removing pollutants from water consisting of directing the contaminated water though a system containing the porous ceramic material. The porous ceramic material may be regenerated for further use by directing an acidic solution over the porous ceramic material.

Abstract: An electrolytic method is provided for purifying an aqueous stream, including at least one contaminant ion. In one embodiment, the eluent stream flows through a purifying flow channel, including ion exchange bed, an electric field is applied through the flowing eluent stream in the purifying flow channel, and the contaminant ion is removed from the eluent stream. In another embodiment, no electric field is applied and the ion exchange bed is periodically regenerated. Two beds may be used with one bed on line while the other bed is regenerated followed by a reversal of flow.

Abstract: The invention relates to treating unwanted moderately saline water for producing useful water. The treated water is also suitable for human and livestock consumption. The process includes passing moderately saline waters having 0.05% or more weight and less than 1.00% by weight of the salts of Na, Ca, Mg, Fe, Cl, SO4, or CO3 or combinations thereof through an ion exchange media (FIG. 2). The ion exchange media is pre-treated to be saturated with multivalent cations such as calcium (Ca2+) or magnesium (Mg2+) ions (FIG. 2). After passing through the ion exchange media, the effluent has decreased sodium cations and increased calcium and/or magnesium cations compared to the pre-treated moderately saline water (FIG. 2). As the moderately saline waters pass through the ion exchange media, the sodium content of the media rises as the multivalent cation content lowers until the media is unacceptable for further water treatment and must be regenerated.

Abstract: A method is described that relates to reducing amounts of regenerant waste or increasing the concentration of regenerant waste from ion exchange processes. A method is described that may allow a batch ion exchange process to compete on these factors with continuous or simulated continuous ion exchange processes, and/or to improve the efficiency in operation continuous or simulated continuous ion exchange processes. A specific application addressed is the treatment of water in the Coal Bed Methane Process.