Abstract: One embodiment of the invention comprises an ion exchange composition formed by reacting unsaturated carbon to carbon moieties pendant from derivatized ion binding cryptands with a support substrate under free radical activation conditions to form a covalent bond therebetween. In another embodiment, a cryptand ion exchange composition is made by covalently bonding unsaturated carbon to carbon moieties pendant from a derivatized ion binding cryptands with unsaturated carbon to carbon moieties pendant from a support substrate under free radical activation conditions to form covalent bond.

Abstract: Uses of cucurbituril derivatives are disclosed.

Abstract: A process for the production of dual-functional ion exchange resins from lignocellulosic agricultural material involving anionization of the lignocellulosic agricultural material with citric acid and then cationization of the lignocellulosic agricultural material with dimethyloldihydroxyethylene urea (DMDHEU) and choline chloride, or cationization of the lignocellulosic agricultural material with DMDHEU and choline chloride and then anionization of the lignocellulosic agricultural material with citric acid.

Abstract: A process and medium for decontamination of water containing anionic species including arsenic and chromium, wherein compounds comprising divalent and trivalent metal oxides and sulfides are used to form surface complexes with contaminants under pH conditions within the range of potable water. In one embodiment natural and synthetic spinels and spinel-like materials are used as the sorbent substance.

Abstract: A method for separating a metal (a) from a metal (2), preferably zirconium from hafnium, which consists in dissolving said metals in an aqueous solution wherein said metals are in a state preventing them from passing through a nanofiltration membrane; treating the aqueous medium with a ligand, for example EDTA, which is complexed with metal (1) and/or metal (2), then in passing the resulting treated medium on a filtering membrane allowing through the ligand-metal complexes, but retaining the metals not complexed with the ligand.

Abstract: Highly pure aqueous solution of ammonia, typically electronics grade for use in semiconductor manufacturing is prepared by passing a solution of ammonia through at least one cation exchange resin bed to remove substantially all of the cation contaminants; subsequently passing the cation exchange resin effluent through at least one anion exchange resin; and recovering an aqueous solution of ammonia product substantially free of ionic contaminants.

Abstract: A process for recovering cyanide from feed material containing cyanide and copper involves the steps of: (a) contacting the feed material with a strong base anion exchange resin whereby copper and cyanide from the feed material are adsorbed onto the resin; (b) contacting the resulting resin with an eluant solution containing free cyanide ion to elute copper and cyanide from the resin; (c) separating the eluted resin from the eluting solution or eluate from step (b); (d) acidifying the eluate from step (b) to precipitate copper; (e) separating the acidified solution from the precipitate in step (d) and alkalizing directly or after concentration the separated solution containing HCN; (f) contacting the eluted resin from step (b) with an acid to condition the resin and remove additional cyanide while leaving most of the copper in the resin phase; (g) converting the HCN solution formed in step (f) to cyanide ion, directly or after concentration of the HCN solution, by the addition of alkali; and (h) returning the

Abstract: The invention generally relates to a process for the recovery or removal of metal species from a solution or slurry comprising the steps of: a) contacting the solution or slurry with a polymeric material, selected from the group consisting of a solid superhydrophilic polyurethane polymer containing a chelating and/or solvating agent, a water-insoluble polymeric chelating agent dispersed in a water-insoluble carrier solution, and a water-soluble polymeric chelating or co-ordinating agent to load the polymeric material with metal species wherein said polymeric material; b) separating the loaded polymeric material from the solution or slurry; and c) recovering or removing the metal from the polymeric material. There is also considered a polymeric material for use in the recovery of metal species from a solution or slurry, the polymeric material comprising a solid superhydrophilic polyurethane polymer containing a chelating or co-ordinating agent and/or a solvating agent.

Abstract: Selective extraction of one or more metal anions from an aqueous solution, by contacting the aqueous solution with an organic solution including a diquaternary amine, wherein the diquaternary amine has two diquaternary nitrogens spaced at a distance of less than about 10 ?, selectively binding the metal anions to the diquaternary amine, and then separating the organic solution from the aqueous solution, wherein the diquaternary amines having the selectively bound metal anions are concentrated in the organic solution. Alternatively, the diquaternary amines may be adsorbed or chemically bonded to a solid, and the metal anion-containing aqueous solution passed over the solid having the diquaternary amines. Palladium may be selectively extracted by contacting the acidic solution with an iodide and an organic solvent, allowing the palladium to bind to the iodide, and then separating the organic solution from the aqueous solution, concentrating the bound palladium ions in the organic solution.

Abstract: A fiber capable of forming a metal chelate and a process for producing the same are disclosed, wherein the fiber is characterized in that at least one metal chelate-forming compound selected from the group consisting of aminocarboxylic acid, aminocarboxylic acid, thiocarboxylic acid and phosphoric acid, which are reactive with a glycidyl group, is bonded to a molecule of a synthetic fiber through a crosslinkable compound having a reactive double bond and a glycidyl group in its molecule. The chelate-forming fiber is excellent in capturing harmful heavy metal ions and can be easily produced in a simple and safe way at a low cost.

Abstract: A method for removing at least one of chromate and other oxy-metal ions from liquid solutions includes contacting the liquid solution with solid barium compounds as adsorbents so that the at least one of chromate and other oxy-metal ions in liquid solution are subject to an exchange reaction with the anion of solid barium compounds to produce products including at least one of solid barium chromate and oxy-metal barium compounds and are removed from the liquid solution by a liquid-solid separation operation. A method for stabilizing at least one of chromate and other oxy-metal ions that are present in liquid or sludge wastes includes mixing the liquid or sludge wastes with barium compounds in solid form, so that the at least one of chromate and oxy-metal ions are immobilized in a solidified body after curing of the mixture.

Abstract: An in situ process for treating ambient solid materials (e.g., soils, aquifer solids, sludges) by adding one or more divalent metal cations to the ambient solid material. The added divalent metal cations, such as Cu2+ or Zn2+, combine with metal oxide/hydroxides (e.g., ferric oxide/hydroxide or aluminum oxide/hydroxide) already present in the ambient solid material to form an effective sorbent material having a large number of positively-charged surface complexes that binds and immobilizes anionic contaminant species (e.g., arsenic or chromate). Divalent metal cations can be added, for example, by injecting an aqueous solution of CuSO4 into an aquifer contaminated with arsenic or chromate. Also, sludges can be stabilized against leaching of anionic contaminants through the addition of divalent metal cations. Also, an inexpensive sorbent material can be easily formed by mixing divalent metal cations with soil that has been removed from the ground.

Abstract: The invention relates to a method of extracting anions based on metals of groups IV B to VIII of the periodic table from aqueous solutions thereof, wherein compounds of general formula are used as extractants, in which a maximum of two of the R1, R2, R3 and R4 substituents represent hydrogen atoms and the remaining substituents represent identical or different alkyl or aminoakyl groups, which are optionally branched and which contain on average at least 5 C atoms.

Abstract: Minerals that reversibly fix ions, in particular NO3—, i.e. that can exchange one anion for another anion can be used as fertilizers and soil conditioners, as well as for the purification and treatment of water, particularly for the elimination of nitrate. The minerals used are preferably natural or synthetic mixed value metal-metal-hydroxyl salts, e.g. layered double hydroxides (LDHs) that contain exchangeable fixed anions in the intermediary layers. A method for producing anion-exchanging minerals, particularly suitable LDHs, and their use as fertilizers and soil conditioners and for the purification and treatment of water.

Abstract: The present invention provides a process for removing metals from aqueous solutions. This process entails contacting the aqueous solution with at least one neutralizing agent and at least one precipitating agent that preferentially precipitates metals from the aqueous solution. The neutralizing agent is a lithic material that neutralizes the acidity of the aqueous solution to promote the precipitation of metals form the aqueous solution. The precipitating agent is a lithic material that serves as a preferred locus of deposition for the metals precipitated by the neutralizing agent, i.e. those metals precipitated form the aqueous solution during neutralization.

Abstract: A description is given here of a novel process for the production of monocarboxylic and polycarboxylic aromatic acids by the catalytic oxidation in homogeneous phase of aromatic compounds carrying at least one oxidizable substituent group attached directly to the carbon atom of the corresponding aromatic nucleus. The process comprises a purification step in which the crude product resulting from the oxidation stage is supplied to a filling column containing a bed of material having a high adsorbent power with respect to hafnium and/or zirconium polyoxides, operating at a temperature of from 200 to 300° C. and at a pressure of from 30 to 90 barg.

Abstract: The invention relates to a composite solid material fixing mineral contaminants, with a metal hexacyanoferrate basis, characterised in that it comprises a solid support coated with a pellicle of an anion-exchange polymer to which is fixed an insoluble metal hexacyanoferrate forming a thin layer. The present invention also relates to the method of preparing the said composite solid material fixing mineral contaminants with a hexacyanoferrate basis. The present invention finally relates to method of fixing, which can be carried out in a column and continuously, of at least one mineral contaminant contained in a solution, on the said composite solid material fixing mineral contaminants. The said solution is in particular a liquid or an effluent originating from the nuclear industry and installations.

Abstract: A method is describe for removing metal ions of interest from aqueous solutions containing low concentrations of the metal ions of interest. The method involves the use of a microbially produced polymer, &ggr;-glutamic acid. The polymer is used in conjunction with tangential flow filtration and results in substantial removal of metal ions.

Abstract: Methods, compositions and devices for purifying polypeptides and/or proteins using metal loaded ligand bound membranes by metal ion affinity chromatography are described.

Abstract: This invention provides a method for treating waste water containing organic bases such as tetramethyl ammonium hydroxide and dissolved metals such as Mo, W, Cu and Ni which are generated from mask cleaning and Mo etching processes. The organic base along with Cu and Ni is first removed preferably by passing the effluent through a cation exchange resin followed by passing the cation exchanged effluent through an anion exchange resin to remove the Mo and W metals. The treated waste water meets federal guidelines for dissolved metal contaminant limits for water discharge to water ways. Alternatively, filtered effluent is directly passed through an anion exchange resin to remove Mo and W and the dissolved TMAH and copper and nickel are removed by cation exchange.

Abstract: A media is used to remove species from aqueous solutions, particularly in the treatment of water to enable it to be suitable for drinking. The media includes a material selected from the group consisting of zirconium hydroxide, titanium hydroxide, hafnium hydroxide and combinations thereof. A preferred form of the media is a layer having an aspect ratio of at least 1:1, more preferably, at least about 10:1. Removed from the water are species selected from the group consisting of arsenate, selenate, chromate, borate, perchlorate, fluoride and combinations thereof. In particular arsenite (As+3) containing species are also removed from water. Arsenite may be removed from water to levels not greater than 10 parts per billion with a single exposure to the media. The media is selective for certain species over others.

Abstract: A method and apparatus for removing arsenic from water at point of entry or point of use particularly for residential application. The point of entry system comprises a first stage having a manganese greensand oxidizer to convert arsenite (As+3) present in the water to arsenate (As+5) and a second stage for passing the water through an anion exchange resin. Each stage includes a control head for automatic regeneration at a predetermined frequency. The manganese greensand is regenerated with a solution of potassium permanganate and the anion exchange resin is regenerated with a salt solution. An alternate embodiment for point of use application comprises a manganese greensand oxidizer cartridge to convert arsenite (As+3) to arsenate (As+5) followed by removal of the arsenate (As+5) with a reverse osmosis system.

Abstract: The present invention provides methods to remove metals from water in a cost effective and efficient manner using an inorganic cross-flow filter.

Abstract: A method for purifying contaminated water involves passing contaminated water through a porous bed of steel slag. The steel slag can be used to remove various contaminants or reduce the concentration of such contaminants, such as heavy metals (for example, hexavalent chromium), chlorinated organic compounds, and certain inorganic anions. The method preferably involves placing an underground barrier of a porous bed of steel slag in a flow path of contaminated groundwater then allowing contaminated groundwater to pass through the barrier to purify the contaminated groundwater. The slag particles may be used as produced with no further grinding necessary, although the slag may be passed through a sieve or sieves to obtain a set of slag particles having a median diameter of about ⅛ inch to 1 inch, and preferably between about ¼ inch to ⅜ inch. Due to the inherent permeability of slag, no additive need be mixed with the slag.

Abstract: The present invention relates to a method of using a protein-polysaccharide complex composition as an adsorbent and filtering aid for in the processing of fluids or solids to absorb or decompose a variety of separable components including halogenated organic compounds such as PCBs and dioxins.

Abstract: Phosphates and chromates are selectively removed from contaminated water by a new class of sorbent, referred to as a Polymeric Ligand Exchanger (PLE). The exchanger bed comprising a styrene-divinylbenzene or polymethacrylate matrix having an electrically neutral chelating functional group with nitrogen or oxygen donor atoms, and a Lewis-acid type metal cation, such as copper, bonded to the chelating functional group in a manner that the positive charges of the metal cation are not neutralized. PLEs are very selective toward phosphates and chromates, chemically stable, and also amenable to efficient regeneration.

Abstract: This invention relates to a method of selectively removing zinc from an effluent, wherein the effluent is passed over an anion exchange column under conditions at which negatively charged zinc complexes are adsorbed to the column material. Subsequently, the zinc is stripped with ammonia from the anion exchanger.

Abstract: The subject matter of the present invention is a process for the purification of a virtually anhydrous organic liquid other than DMSO alone, in order to decrease its content of alkali and alkaline-earth metal and metal cations, characterized in that it consists essentially in placing this organic liquid in contact with one or more cation exchange resins and in then separating from the resin(s) the purified organic liquid, said resin or at least one of said resins being a sulphonic resin in --SO.sub.3 H or --SO.sub.3 NH.sub.4 form based on a polystyrene-divinylbenzene copolymer having a divinylbenzene content of from 50 to 60% by weight, without taking the sulphonic groups into account.

Abstract: A method is provided for removing contaminants from water. The method comprises contacting the contaminants in the water with an organoclay having a positive or negative charge on its surface. Using this method, organic and inorganic contaminants can be removed with such charged organoclays.

Abstract: A chromatographic composition for the selective binding of borate ion comprising support resin particle and polymers containing covalently bonded borate binding carbohydrates wherein said carbohydrates are a mono-, di- or polysaccharide of three to seven alcohol moieties per saccharide unit.

Abstract: A solid phase ligand removes metal cations from solution. The ligand is a branched polyalkyleneimine having a molecular weight of at least about 400, covalently bound to an inorganic support.

Abstract: Composite materials useful for removing metal ions from solutions such as aqueous waste streams comprise an inorganic ceramic support such as silica gel that has active hydroxyl groups. The support is reacted with a silane linking compound or with a titanizing agent. A chelating compound, which can be a thiol or an amine, is attached to the silane or to titanium atoms of the titanized surface of the support.

Abstract: A powerful reducing agent such as hydrazine monohydrate is added to the standard eluent solutions such as NsOH-NaCN with or without alcohol. The kinetics of elution of gold or of silver are thus markedly enhanced.

Abstract: A method for separating .sup.213 Bi from a solution of radionuclides wherein the solution contains a concentration of the chloride ions and hydrogen ions adjusted to allow the formation of a chloride complex. The solution is then brought into contact with an anion exchange resin, whereupon .sup.213 Bi is absorbed from the solution and adhered onto the anion exchange resin in the chloride complex. Other non-absorbing radionuclides such as .sup.225 Ra, .sup.225 Ac, and .sup.221 Fr, along with HCl are removed from the anion exchange resin with a scrub solution. The .sup.213 Bi is removed from the anion exchange resin by washing the anion exchange resin with a stripping solution free of chloride ions and with a reduced hydrogen ion concentration which breaks the chloride anionic complex, releasing the .sup.213 Bi as a cation. In a preferred embodiment of the present invention, the anion exchange resin is provided as a thin membrane, allowing for extremely rapid adherence and stripping of the .sup.213 Bi.

Abstract: A process for removing contaminating levels of hexavalent chromium ion ?Cr(VI)! from a concentrated aqueous solution of sodium sulfate. That process includes providing a vessel containing a water-insoluble adsorption medium having a plurality of polymerized pyridyl-containing adsorption sites. An influent of an aqueous solution of about 1.0 to about 2.0 molar (e.g., saturated) sodium sulfate having a total hexavalent chromium ion concentration of up to about 1000 parts per million, to the vessel to contact the insoluble adsorption medium. The solution is maintained in contact with that insoluble adsorption medium for a time period sufficient for the medium to bind the hexavalent chromium ions in the contacting solution. The resulting aqueous solution is discharged from the vessel as an effluent having a total hexavalent chromium ion concentration whose ratio to the total hexavalent chromium ion concentration of the influent is about zero to about 25.0.times.10.sup.-6.

Abstract: A method for the making and use of a porous, preferably dimensionally stable, hydrophobic polymer for the extraction of metal ions from an aqueous solution, with the polymer being in the form of a regenerative granulate or powder having an average particle diameter of from 0.1 to 10 mm and pores of from 0.1 to 50 .mu.m, which is obtained by the dissolving of a polymer, with heating, at a temperature above the upper critical demixing temperature Tc in a complexing agent containing hydrophobic liquid, followed by lowering of the temperature, resulting in a porous polymer filled with the hydrophobic liquid, and the mechanical diminution of the solidified mass is disclosed. Favorable results have been attained using polypropylene as the hydrophobic polymer, bis(2,4,4-trimethylpentyl)thio acid as the complexing agent, and with a mixture of dibenzyl toluene and/or polypropylene glycol ether being part of the hydrophobic liquid.

Abstract: A method of treating and disposing of waste water containing salt, such as the brine that results from production of oil and/or gas wells, which includes introducing the waste water into a reverse osmosis unit to produce concentrated brine, and passing the concentrated brine through a combustion heat evaporator wherein said combustion heat is generated in a submerged combustion evaporator or exhaust gases from an internal combustion engine to power a waste heat evaporator to produce a further concentrated brine. The concentrated brine from the combustion heat evaporator can then be mixed with a liquid such as the waste water that is introduced into the reverse osmosis unit. The resulting product can then be injected into a subterranean formation for purposes of disposal. The method allows the volume of the waste water to be significantly reduced while also increasing the salt concentration of the waste water.

Abstract: The invention is a process of removing metal ion contaminants from an organic solution, especially one having acid labile components. The process comprises modifying a cationic exchange resin by treatment with ammonia or amine and contacting said modified ion exchange resin with an organic solution containing metal ion contaminants. The process is especially useful for treating photoresist compositions.

Abstract: Anion exchange resins including at least two positively charged sites and a ell-defined spacing between the positive sites are provided together with a process of removing anions or anionic metal complexes from aqueous solutions by use of such resins. The resins can be substituted poly(vinylpyridine) and substituted polystyrene.

Abstract: The present invention, relates to the recovery of zinc values from an acidic solution containing hydrocyanic acid. The zinc is recovered as complex zinc cyanide anions which may, if desired, be recycled for the (selective) preliminary removal or separation of adsorbed copper values from an (strong or weak base) anion exchange material, the anion exchange material additionally being loaded with adsorbed cyanide complexes of precious metal values such as gold and silver. The invention, further relates to the recovery of cyanide values associated with copper cyanide complexes which are adsorbed on or taken up by an (strong or weak base) anion exchange material; the recovered cyanide values, for example, being available for recycling to a cyanide leach stage for leaching additional metal values from an ore or the like.

Abstract: Selenium exists in oil refinery stripped sour water as selenocyanate and can be effectively removed using an acrylic, strong base, anion exchange column or stannous chloride. The acrylic, strong base, anion exchange column can also be employed to remove arsenic, iron, and vanadium from an aqueous fluid.

Abstract: A composition comprising a crosslinked, highly porous body derived from a water-soluble hydrogel polymer, said porous body being characterized in that it has an open-celled three-dimensional lattice structure, a density of less than about 1.0 g/cm.sup.3, a surface area of equal to or greater than about 300 m.sup.2 /g, a compression strength of equal to or less than about 10 percent yield at 300 psi, and an average pore diameter of less than about 500 Angstroms, wherein said hydrogel polymer is selected from the group consisting of alginates, gums, starch, dextrins, agar, gelatins, casein, collagen, polyvinyl alcohol, polyethylenimine, acrylate polymers, starch/acrylate copolymers, and mixtures and copolymers thereof; and a metal extractant.The composition may be used in removing and/or recovering metal ions from aqueous streams.

Abstract: Acids contaminated with multi-valent metal salts are purified by a process which involves treatment in an acid sorption unit (ASU) and a nanofiltration unit (NFU). The feed solution can first be delivered to the ASU, which produces two solutions, one high in acid concentration and the other high in metal salt concentration. The high acid concentration solution can be treated in the NFU to produce an acid end product and a reject metal salt solution which can be recirculated to the feed of the NFU. Alternatively, the high metal salt solution can be treated in the NFU, and its permeate recirculated to the ASU as eluate. In an alternative configuration, the feed is delivered first to the NFU. In all cases, the membrane reject solution from the NFU is recirculated to increase the metal salt concentration. A second NFU can be used to process the solution from the ASU which contains a high metal salt concentration.

Abstract: A method of preferential removal of cesium cations from aqueous solutions containing other inorganic cations. Deltahaedral heteroborane anions are added to the solution to form a salt with the cesium cations which then precipitates from the solution. The remaining dissolved Cs-deltahaedral heteroborane anion salt is then quantitatively sorbed on active charcoal to remove it from the solution.

Abstract: A process for the removal of species containing metallic ions from effluents by yeast cell walls. The yeasts used are selected from Saccharomyces cerevisae, Saccharomyces uvarum and Saccharomyces lipolytica. According to the process, the washed yeast cell walls are first treated by a water soluble aldehyde and after sorbing the metallic ions, the yeast cell walls may regenerated by a mineral acid or a chelate solution such as ethylene-diamine tetraacetic acid, releasing the sorbed metal ions. According to a preferred embodiment, water containing acetone or alcohol is used for washing the yeast cell walls. The sorption by the yeast cell walls is carried out at a pH in the range of 1 to 13 and preferably in the range of 4 to 7. The most preferred aldehyde is selected from formaldehyde and glutaraldehyde or any mixture thereof. The metal sorption process may be carried out batchwise or continuously. In the continuous process, the yeast cell walls are immobilized on porous glass, purified sand or polymers.

Abstract: A method of treating photoprocessing wash water, comprising in sequence, the steps of:A) contacting the wash water with an acrylic anion exchange resin to remove silver thiosulfate complex in the water; andB) contacting the water from step A) with an oxidizing agent that converts thiosulfate ions to sulfate ions.C) recirculating continuously through the photoprocessing wash tank and steps A) and B).

Abstract: A process is described by which a chemical species is sorbed into the channels of a host phase which is then heated to affect an irreversible phase transformation of the host phase which seals the chemical species within its crystal structure. The host phase is an insoluble solid, non-toxic and stable both to the chemical species it encases and its environment.

Abstract: The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering .sup.99 Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of .sup.99 TcO.sub.4.sup.- from aqueous solutions into organic solvents or mixed organic/polar media, extraction of .sup.99 Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester .sup.99 Tc from those liquids.

Abstract: Adsorbent media are prepared by contacting support material with iron containing solutions, followed by drying to coat the support material with iron. Support materials such as sand and olivine are described. The adsorbent material can be used to remove metal contaminants and natural organic matter from water.

Abstract: A process for removing complexed or chelated ions from an aqueous solution using a cationic chelating resin in the sodium form. The process is particularly useful for removing metal ions chelated during a metal plating process with specific utility for recovering cadmium from a cadmium cyanide complex.