Utilizing Mixed Bed Or Amphoteric Material Patents (Class 210/686)
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Patent number: 5378802Abstract: A method of removing ionic impurities from a resist component, comprising the steps of:(a) dissolving said resist component in a solvent;(b) contacting said resist component solution with a fibrous ion exchange resin for a sufficient amount of time to remove at least a portion of said ionic impurities onto said fibrous ion exchange resin; and(c) separating said fibrous ion exchange resin bearing said ionic impurities from said resist component solution.Type: GrantFiled: September 3, 1991Date of Patent: January 3, 1995Assignee: OCG Microelectronic Materials, Inc.Inventor: Kenji Honda
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Patent number: 5354476Abstract: This invention relates to a method for treating water by using a precoated filter.Since the method of the present invention utilizes ion-exchange fibers having an ion-exchange polymer and a reinforcing polymer as the precoating material together with a cation-exchange resin powder and an anion-exchange resin powder, the method made it possible to prominently prolong the lifetime of the precoating material and to improve the quality of the treated water.The method for treating water of the present invention is suited for the treatment of water to be used in, or waste water from atomic power plants, steam power plants, pharmaceutical companies and the like.Type: GrantFiled: December 11, 1992Date of Patent: October 11, 1994Assignee: Toray Industries, Inc.Inventors: Nami Kubo, Masaru Noyori, Shigeki Mori, Tsukasa Ito
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Patent number: 5350523Abstract: An anion exchange method conducted at a high temperature, which comprises using a crosslinked anion exchanger which comprises structural units having a quaternary ammonium group of the following formula (a) and structural units derived from an unsaturated hydrocarbon group-containing crosslinkable monomer, and of which at least 90% of anion exchange groups are present in the form of a group represented by ##STR1## as defined in the following formula (a): ##STR2## wherein R is a --(CH.sub.2).sub.n --group (n=an integer of from 3 to 18) which may include a cyclic hydrocarbon, each of R.sub.1, R.sub.2 and R.sub.3 which are independent from one another, is a C.sub.1 -C.sub.8 hydrocarbon group or a C.sub.1 -C.sub.8 alkanol group, the benzene ring of the formula (a) may be substituted by an alkyl group or a halogen atom, or may be condensed with other aromatic ring, and X is an anion.Type: GrantFiled: August 28, 1992Date of Patent: September 27, 1994Assignees: Mitsubishi Kasei Corporation, Tohoku Electric Power Co., Inc.Inventors: Masao Tomoi, Atsuo Kiyokawa, Hiromasa Ogawa, Teruo Onozuka, Tsuyoshi Ito
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Patent number: 5292439Abstract: A method for preparing an ultrapure water, from which impurities including inorganic salts, organic substances, fine particles and microorganisms are removed, by treatment including an ion exchange treatment, which comprises using an ion exchange resin comprising a copolymer of a polyvinyl compound and a monovinyl aromatic compound which may contain a monovinyl aliphatic compound, as the matrix, at least in a mixed bed ion exchange treatment of the ion exchange treatment, said ion exchange resin used comprising at least a regenerated form ion exchange resin A eluting an organic compound of a molecular weight of less than 3,000 but substantially not eluting an organic compound of a molecular weight of not less than 3,000 when dipped in a hot water at 50.degree. C. for 7 days.Type: GrantFiled: November 22, 1991Date of Patent: March 8, 1994Assignee: Mitsubishi Kasei CorporationInventors: Takamitsu Morita, Junya Watanabe, Toyokazu Sugawara
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Patent number: 5192446Abstract: The invention provides a method for removing transition metal oxides and soluble cation species from condensate at a relatively high removal efficiency. The method includes hydrating a strongly acidic dual morphology cation exchange resin in a macroeticular, desiccated morphology to produce a macroreticular, hydrated morphology. Condensate which is brought into contact with the resin when it is in a hydrogen form is purified. The condensate may, optionally, also be contacted with an anion exchange resin.The invention additionally provides a method for selecting cation exchange resins which are particularly suited for use in removing metal oxides from a condensate stream. The method serves to narrow the field of condidates for pilot-scale resin testing with industrial condensate.Type: GrantFiled: January 24, 1992Date of Patent: March 9, 1993Assignee: The Graver CompanyInventors: Eli Salem, Robert Kunin
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Patent number: 5114592Abstract: The invention involves a process as well as apparatus for the separation of arsenic from waste material. The process includes precipitation of arsenic in the form of low solubility calcium magnesium arsenates by adding calcium and magnesium compounds to the waste, separation of calcium magnesium arsenates, putting the waste in contact with an ion exchanger, regenerating the ion exchanger after reaching the charge limit, adsorptively separating the arsenic by putting the waste in contact with active carbon, and separating the charged active carbon by itself or along with precipitation products. The process allows for a separation of arsenic from waste which is hard to be treated or contains heavy metals such as lead or contains sulfates to residual amounts as low as <0.3 mg As/l.Type: GrantFiled: March 27, 1990Date of Patent: May 19, 1992Assignee: Walhalla-Kalk, Entwichlungs- und Vertriebsgesellschaft mbHInventors: Georg Schuster, Hans Kaestle
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Patent number: 5082567Abstract: Disclosed is a method of regenerating a cationic exchange resin that has been exposed to chlorate ion. The resin is treated with an acidic regenerating solution that contains sulfite ion in an amount at least stoichiometric with the amount of chlorate remaining on the resin. The resin can either be rinsed with water first and then contacted with an acidic regenerating solution containing sulfite, or the resin can be washed with acidic water containing sulfite ion and then treated with an acidic regenerating solution.Type: GrantFiled: November 8, 1990Date of Patent: January 21, 1992Assignee: Occidental Chemical CorporationInventors: Sharon D. Fritts, Tilak V. Bommaraju
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Patent number: 5061374Abstract: An improved deionized water treatment system and method that consists of using a first and second water treatment train wherein the second train improves water quality by reducing particulate and total organic carbon by means of a reverse osmosis membrane assembly. The final pure water having particulate sizes less than one micron and a total organic carbon measure of less than one part per billion.Type: GrantFiled: December 18, 1989Date of Patent: October 29, 1991Assignee: Micron Technology, Inc.Inventor: Vic E. Lewis
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Patent number: 5045291Abstract: Aqueous alkanolamine solution containing alkali metal salts of anions which form heat stable salts with such alkanolamine is reactivated by contacting the solution sequentially with a basic anion exchange resin to remove such anions and an acidic cation ion exchange resin to remove alkali metal ions.Type: GrantFiled: August 6, 1990Date of Patent: September 3, 1991Assignee: Conoco Inc.Inventor: Alfred E. Keller
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Patent number: 5024767Abstract: The present invention relates to a method for purification of liquids. Fur particulars, the present invention relates to a method for purifying more precisely liquids in atomic power related fields, using a mixture of a polymer in which carboxyl groups are grafted onto a polyamide or a polyester as a cation exchanger and an anion exchanger.Type: GrantFiled: January 3, 1990Date of Patent: June 18, 1991Assignee: Toray Industries, Inc.Inventors: Nami Kubo, Toshio Yoshioka, Kouichi Saito, Syunroku Tohyama
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Patent number: 5024766Abstract: The deionized water purification of this invention is a small compact unit which is inserted between the purified deionized water distribution line in a plant water purification system and the inlet of a point of use apparatus. The small compact modular point of use deionized water purification unit reduces the total organic contaminant loading, the particulate loading, and the ionic contaminants in the purified deionized water from the plant purification system. The purification unit of this invention also includes means for sterilization of the point of use deionized water purification unit and a new technique for preventing damage to the ozone generator used in the sterilization process.Type: GrantFiled: November 9, 1988Date of Patent: June 18, 1991Inventor: Shahzad Mahmud
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Patent number: 5022997Abstract: Methods for treating aqueous solutions and for recovering specific chemical products from an aqueous solution by ion exchange or adsorption by passing the aqueous solution through a regenerable filter bed comprising a flocculated mixture of finely divided active particulate material and filter aid materials having a depth of from about 3.0 inches to about 60 inches.Type: GrantFiled: December 18, 1989Date of Patent: June 11, 1991Assignee: The Graver CompanyInventors: Eli Salem, Bruce L. Libutti, Robert Kunin
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Patent number: 4975201Abstract: A process for treatment of power plant condensate water particularly from a boiling water nuclear reactor, where the condensate contains colloidal material, especially oxidized iron from the steam and condensate handling system known as "crud". The colloidal iron level of the condensate is lowered by contacting the condensate water with a mixed bed ion exchange resin in which at least the cation exchange resin has a core/shell morphology which has been prepared by a polymerization of monomer within a multiplicity of free radical-containing matrices.Type: GrantFiled: October 17, 1989Date of Patent: December 4, 1990Assignee: The Dow Chemical CompanyInventor: King W. Ma
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Patent number: 4917806Abstract: Water is allowed to flow in parallel into a mixed bed in which an anion exchange resin and a cation exchange resin are disposed in a mixed state and into a single bed in which an anion exchange resin or a cation exchange resin is disposed. As the proportion of the flow rates of water introduced into the two beds is adjusted, the pH and electrical conductivity of water is controlled. Control is effected in such a manner that the pH and electrical conductivity of water are maintained at appropriate levels without using any chemicals.Type: GrantFiled: December 20, 1988Date of Patent: April 17, 1990Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Yoshihiro Matsunaga, Tadao Nishimori, Hiromasa Matsuoka
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Patent number: 4891138Abstract: A method for separating and transferring an ion-exchange resin having the lower specific gravity from an ion-exchange resin having the higher specific gravity in an ion-exchange resin separating tank that is indispensable to a pure or ultrapure water producing plant and which is packed with a mixed bed of ion-exchange resins having different specific gravities is disclosed.Type: GrantFiled: December 24, 1987Date of Patent: January 2, 1990Assignee: Ebara CorporationInventors: Kanroku Chonan, Kazuyuki Koyama, Masahiro Hagiwara
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Patent number: 4876014Abstract: A method for purifying water or other aqueous media in which a stream of the aqueous media is introduced into a fixed bed of a purification media and turbulent flow through the fixed bed is induced to permit intimate contact between the aqueous media and the purification media. Also disclosed is an apparatus for purifying the aqueous media which includes an outer housing having an inlet aperture and an outlet aperture; a multi-chamber purification unit disposed within the housing, and means for measuring the purity of aqueous media treated within the multi-chamber unit.Type: GrantFiled: March 21, 1988Date of Patent: October 24, 1989Assignee: Water Systems Development CorporationInventor: William S. Malson
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Patent number: 4859344Abstract: Rectifying the compressive strength and toxic waste levels of ground water passages is achieved through the formation of a type C fly ash screen reinforcement of the passage.Type: GrantFiled: May 3, 1988Date of Patent: August 22, 1989Assignee: The Dow Chemical CompanyInventors: Lloyd B. Spangle, S. Ebow Coleman
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Patent number: 4853130Abstract: A process for the separation of radioisotopes and stable isotopes and other deleterious materials from radioactive waste and other liquids, wherein the waste stream is passed through a filter/demineralizer septum screen pre-coated with a mixture of finely-divided zeolitic material and finely-divided ion-exchange resin material.Type: GrantFiled: June 17, 1987Date of Patent: August 1, 1989Assignee: Epicor IncorporatedInventors: Philip J. D'Angelo, Richard Hetherington, Joseph J. Rogan
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Patent number: 4786527Abstract: A layer of small-sized particles of an organic ion exchange resin is applied to a support matrix, permeable to liquid, of a filter element (7) which is arranged in a chamber (5) in an ion-exchange filter (1) for filtering of liquids containing radioactive constituents. The filter and a mixer (11), consisting of a tube with a number of stationary mixing elements arranged one after the other in the longitudinal direction of the tube, are arranged in a circulation system (10) for water. The mixing elements successively divide up a material flow, supplied at the inlet end of the mixer, into a number of sub-flows containing different parts of the original material flow and the sub-flows are reunited, before they reach the outlet end of the tube. Suspended ion-exchange resin (13a, 16a) is supplied to the inlet end (11a) of the mixer for the circulating water while the water is being circulated in the circulation system.Type: GrantFiled: April 24, 1987Date of Patent: November 22, 1988Assignee: AB ASEA-AtomInventors: Peter Fejes, Eva Sundell
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Patent number: 4780213Abstract: Filter media having a foraminous sintered metal support structure which exhibits a particle retention pore size in the range of from about 0.5 microns to less than about 5.0 microns and a bubble point test pressure of from 20 to 50 inches of water. A continuous precoat layer of discrete anion and cation exchange resin particles having a minimum diameter of about 10 microns and the following particle size distribution:______________________________________ ______________________________________ Less than 2 Particles greater than 200 microns Less than 2 Particles less than 10 microns ______________________________________is formed upon the sintered metal structure. Liquid is purified by first flowing it through the precoat layer, and then through the pores of the foraminous sintered metal structure.Type: GrantFiled: December 9, 1986Date of Patent: October 25, 1988Assignee: Idreco USA Ltd.Inventor: Bruce J. Ogletree
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Patent number: 4752397Abstract: An improved process is disclosed for the purification of an impure aqueous solution containing heavy metal ions which comprises passing the impure solution through a bed of activated adsorbent containing at least 20 wt. % activated hydrotalcite formed by reacting activated magnesia with an aqueous solution containing ions of aluminate, carbonate, and hydroxyl. The heavy metal ions are removed from the impure aqueous solution by adsorption onto the activated hydrotalcite-containing adsorbent. The adsorbent may be regenerated for reuse and the adsorbed metals recovered by subsequently stripping the metal ions from the adsorbent and recycling the metal ions back to the process of origin. The pH of the effluent may be monitored to determine when the capacity of the adsorbent has been reached and regeneration of the adsorbent should be commenced.Type: GrantFiled: June 30, 1986Date of Patent: June 21, 1988Assignee: Aluminum Company of AmericaInventor: Ajay Sood
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Patent number: 4744825Abstract: In accordance with the invention, an improved process is provided for the efficient removal and recovery of silver from an impure solution containing silver ions which comprises contacting the silver-containing solution with an activated alumina adsorbent to selectively adsorb the silver ions from the solution and the lower the subsequent effluent discharge to less than 1 ppm silver, treating the activated alumina with a regeneration fluid to recover the silver ions from the adsorbent, and reducing the recovered silver ions to metallic silver.Type: GrantFiled: December 4, 1986Date of Patent: May 17, 1988Assignee: Aluminum Company of AmericaInventors: Abraham S. C. Chen, Hubert L. Fleming
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Patent number: 4741834Abstract: Rectifying the compressive strength and toxic waste levels of ground water passages is achieved through the formation of a type C fly ash screen reinforcement of the passage.Type: GrantFiled: May 8, 1986Date of Patent: May 3, 1988Assignee: The Dow Chemical CompanyInventors: Lloyd B. Spangle, S. Ebow Coleman
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Patent number: 4693828Abstract: This invention relates to a method of ion-exchange and/or adsorption, and to a method of producing pure water. More specifically, this invention relates to a method of ion-exchanging and/or adsorbing an unnecessary product or a useful product in a liquid to be treated. Concretely, this invention relates to a method of ion-exchange and/or adsorption and to a method of producing superpure water by first treating the liquid with an ion-exchange resin, and then treating the liquid with an ion-exchange fiber.Type: GrantFiled: May 7, 1986Date of Patent: September 15, 1987Assignee: Toray Industries, Inc.Inventors: Toshio Yoshioka, Seiichi Yoshikawa, Masaharu Shimamura
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Patent number: 4670154Abstract: A mixed resin bed deionizing apparatus for removing toxic or mineral substances from fluid passing through a loading vessel containing a mixed bed of cation and anion resins and a regeneration assembly for regenerating the cation and anion resins for return to the loading vessel, the assembly including a separation vessel for separating the cation and anion resins and two "U"-shaped regeneration vessels, one for regenerating cation resins and one for regenerating aniona resins, the resins being admitted to the regeneration vessels in predetermined amounts which are advanced through the regeneration vessels by removing a predetermined amounts of regenerated resin from the discharge end of the vessel, shifting the remaining resin in the vessel to refill the space in the discharge end and adding a corresponding amount of exhausted or loaded resin to the other end, passing a regenerant through the regeneration vessel counter to the direction of movement of the resin through the regeneration vessel and rinsing theType: GrantFiled: December 2, 1985Date of Patent: June 2, 1987Assignee: UIP Engineered Products CorporationInventors: Lee G. Carlson, Conrad Terrien, Roger Queisser
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Patent number: 4666608Abstract: Method for rendering visible the line of separation between cation exchangers and anion exchangers in mixed-bed filters, in which method an amount of a cation exchanger (anion exchanger) sufficient to form a visible line is added to the cation exchangers and anion exchangers constituting the mixed-bed, the added ion exchanger clearly differing optically from the cation exchanger and anion exchanger used to build up the mixed-bed and having a density 0.01-0.05 g/ml lower (higher) than that of the mixed-bed cation exchanger (mixed-bed anion exchanger), and the resin beads of which predominantly having the same particle sizes as the finest (coarsest) screen fraction of the mixed-bed cation exchanger (mixed-bed anion exchanger).Type: GrantFiled: March 29, 1985Date of Patent: May 19, 1987Assignee: Bayer AktiengesellschaftInventor: Friedrich Martinola
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Patent number: 4663051Abstract: The invention relates to improved methods for regenerating the exhausted anion and cation exchange resins in a mixed bed demineralizer system. The exhausted bed of resin is directed into a separation vessel which contains a buffer volume of anion and cation resins remaining therein from the previous regeneration cycle. The resin in the separation vessel is classified into an upper anion resin layer, a lower cation resin layer and an intermediate layer of intermingled anion and cation resin. The cation resin is transferred from the bottom of the separation vessel to a cation regeneration vessel through a cation transfer conduit having isolation valves associated with the respective ends thereof. The resin transfer is terminated upon the detection of anion resin in the transfer conduit, at which time the isolation valves are closed so as to isolate the bulk of the intermingled anion and cation resin layer in the cation transfer conduit.Type: GrantFiled: October 11, 1985Date of Patent: May 5, 1987Assignee: The Graver CompanyInventors: George C. Flynn, Douglas S. Johnstone
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Patent number: 4648976Abstract: A water demineralizer system and method is provided in which at least three beds of resin particles are connected in series flow arrangement preferably within a single vessel for substantially removing metal ions such as calcium and magnesium from water feed by exchange with hydrogen ions. The raw feed water flows first through an upper cation resin bed, then through an intermediate anion resin bed, and then through a lower bed of mixed cation and anion resins, and preferably flows downwardly through the beds. After the resin beds become saturated with metal ions from the feed water, mainly by calcium and magnesium ions, the beds are regenerated by first backwashing with water, then chemically treating with acid and caustic solution, followed by bed rinsing, air mixing and backflushing with water prior to further use for demineralizing the feed water.Type: GrantFiled: March 7, 1985Date of Patent: March 10, 1987Assignee: Belco Pollution Control CorporationInventor: James Y. Chen
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Patent number: 4614591Abstract: The present invention relates to a method of purifying water for fish-breeding, according to which the water is optionally subjected to sedimentation, is subjected to sand filtration and to oxygenization, and to which the water also is subjected to a treatment with an ion exchanger mixture consisting of 40 to 70 percent clinoptilolite, 30 to 15 percent anion exchanger and 30 to 15 percent cation exchanger, the two latter being of cellulose type. The invention relates furthermore to the ion exchanger mixture mentioned.Type: GrantFiled: December 5, 1984Date of Patent: September 30, 1986Assignee: SRS Water Research Corporation ABInventor: Sven E. Jorgensen
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Patent number: 4568467Abstract: Disclosed is a method of reducing the charging tendency in a flowing non-aqueous liquid which has a dielectric constant of less than about 50, by passing the liquid through an ion exchange resin charged with a weakly polar active group. Also disclosed is a combination of a transformer cooled by flowing organic insulating liquid and an anionic ion exchange resin and means for passing the liquid through the resin.Type: GrantFiled: January 27, 1984Date of Patent: February 4, 1986Assignee: Westinghouse Electric Corp.Inventor: Thottathil V. Oommen
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Patent number: 4564455Abstract: The present invention relates to a method for purifying aqueous solutions or condensate in a three component resin system comprising a mixed bed of a strongly basic anion exchange resin, a strongly acidic cation exchange resin and a weakly acidic cation exchange resin. According to the present method, aqueous solutions can be treated to remove metal ions and corrosion products along with ammonia and other volatile amines so that metal ion leakage is substantially reduced and the run length of the resin system is increased. A method for separating and isolating the resins of the three component system is also described.Type: GrantFiled: December 13, 1983Date of Patent: January 14, 1986Assignee: The Graver CompanyInventors: George C. Flynn, Eli Salem, Robert Kunin
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Patent number: 4540493Abstract: A process for treating wash water from the manufacture of terephthalic acid, wherein the wash water includes terephthalic acid, metal catalyst, and organic acid byproducts. The process includes the steps of passing the wash water through a filter medium to remove undissolved terephthalic acid solids, passing the filtered water through a cation exchange resin in hydrogen ion form to remove the metal catalysts, and passing the water through an anion exchange resin to remove dissolved terephthalic acid and dissolved organic acid byproducts. The treated water and certain components removed from the wash water are recovered and reused in the manufacture of additional terephthalic acid. An apparatus in which the process is practiced is also described and, after a quantity of wash water has been treated, the apparatus is regenerated with regenerants that are also recovered and reused in the manufacture of additional terephthalic acid.Type: GrantFiled: November 30, 1983Date of Patent: September 10, 1985Assignee: Ecolochem, Inc.Inventors: Richard C. Dickerson, William S. Miller
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Patent number: 4523996Abstract: A ferromagnetic material is integrally incorporated with each of the ionic beads of one component of a mixed ionic resin bed containing more than one ionic bead component, such that the one ionic bead component can be separated from the other component by attraction to a magnetic field. Ionic beads containing a ferromagnetic material are attracted to an inhomogeneous magnetic field while other ionic beads devoid of the ferromagnetic material are not so attracted. In another embodiment, a ferromagnetic material having a specific Curie temperature may be incorporated with one ionic bead component while the other bead component contains a different ferromagnetic material having a different Curie temperature.Type: GrantFiled: February 22, 1984Date of Patent: June 18, 1985Assignee: Westinghouse Electric Corp.Inventors: Robert G. Charles, William M. Hickam
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Patent number: 4519916Abstract: The invention relates to a process for internal regeneration of mixed bed filters in which, after the exhausted ion exchanger mass has been separated into the two components and these have been regenerated and washed out, the exchanger layer in the region of the cation exchanger/anion exchanger interface is selectively removed from the mixed bed filter, the cation exchanger remaining in the filter is mixed with the anion exchanger remaining in the filter for the new loading stage, the ion exchanger mass removed from the filter is added again, when the work cycle has ended, to the exhausted ion exchanger mass before or during the separation into cation exchanger and anion exchanger, and, after the separation, the loading stage is started again with the regeneration of the cation exchanger and anion exchanger; and also to a mixed bed filter for carrying out the process.Type: GrantFiled: March 22, 1984Date of Patent: May 28, 1985Assignee: Bayer AktiengesellschaftInventor: Friedrich Martinola
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Patent number: 4478722Abstract: An improved ion retardation method for separating mixtures of salts in aqueous solution is disclosed. In this method, an ion retardation resin containing excess strong base groups is employed wherein the strong base groups have associated therewith a counteranion for which the strong base group has less affinity than for the anion of the salt which is last eluted from the resin.Type: GrantFiled: October 4, 1983Date of Patent: October 23, 1984Assignee: The Dow Chemical CompanyInventor: W. Steven Boom
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Patent number: 4472282Abstract: A mixed bed polishing process for regeneration of an exhausted mixed resin bed of cation exchange and anion exchange resins of different densities comprising the steps of scrubbing with air the exhausted mixed resin bed and adding into the mixed resin bed inert resins having a density intermediate the densities of the cation exchange and anion exchange resins. The exhausted mixed resin bed is backwashed to separate into three layers the cation exchange, anion exchange and inert resins. The anion exchange resins are transferred to an anion regenerator; and then, the inert resins are transferred to an inert resin storage tank. The cation exchange resins are regenerated with acid; and then, the anion exchange resins are regenerated with caustic regenerant. The regenerated cation exchange and regenerated anion exchange resins are separately rinsed, and then, mixed together and rinsed.Type: GrantFiled: December 7, 1981Date of Patent: September 18, 1984Assignee: Crane Co.Inventor: George J. Crits
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Patent number: 4448693Abstract: A process for the partial desalination of water with a combination of weakly acid cation exchangers in free acid form and basic anion exchangers in hydrogen carbonate form, both present in aqueous suspensions, and subsequent regeneration of the charged ion exchanger material. The partial desalination is effected with a combination or mixture of a weakly acid cation exchanger material and a basic anion exchanger material. Depending on the combination or mixing ratio of the two exchangers, non-equivalent quantities of neutral salt cations and anions are removed from the water. The regeneration of both exchangers together is effected exclusively with the aid of CO.sub.2.Type: GrantFiled: January 28, 1982Date of Patent: May 15, 1984Assignee: Kernforschungszentrum Karlsruhe GmbHInventors: Brigitte Kiehling, Wolfgang Holl
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Patent number: 4434058Abstract: A cooling arrangement particularly for cooling electrical devices having water cooled electric conductors with deionized cooling water in a closed cooling system which contains a parallel loop with a mixed bed filter in which an anion exchanger in OH form is provided which can be connected parallel with the mixed bed filter as well as in series with the mixed bed filter, permitting the cooling system to be run with the cooling water having an increased pH-value range which can be preferably 8 to 8.4.Type: GrantFiled: July 17, 1981Date of Patent: February 28, 1984Assignee: Siemens AktiengesellschaftInventors: Horst W. Emshoff, Walter K/u/ sebauch
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Patent number: 4432878Abstract: The invention relates to a cooling arrangement, particularly for cooling electrical devices with water-cooled electric conductors, with deionized cooling water (deionate) and a closed cooling system which contains a parallel loop with a mixed-bed filter. According to the invention, the mixed-bed filter is preceded by an alkalizing cation exchanger and an anion exchanger in OH-form, and the mixed-bed filter is provided with a bypass. With this arrangement, the cooling water can be run in a higher pH-value range which for generators may preferentially be about 8 to 8.4.Type: GrantFiled: June 30, 1981Date of Patent: February 21, 1984Assignee: Siemens AktiengesellschaftInventors: Horst W. Emshoff, Walter Kusebauch
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Patent number: 4430226Abstract: A water treatment cartridge and method for producing ultrapure water is described. The cartridge comprises a container having therein a particulate admixture of activated carbon and mixed bed ion exchange resins. A source of water, preferably pretreated, is passed through the container, preferably following treatment by one or more cartridges containing mixed bed ion exchange resins. The carbon in the admixed cartridge removes residual organic contamination from the water and the resins remove ionic contamination from the carbon, without re-introducing organic material to the water.Type: GrantFiled: March 9, 1981Date of Patent: February 7, 1984Assignee: Millipore CorporationInventors: Ramesh S. Hegde, Gary C. Ganzi
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Patent number: 4402725Abstract: A fertilizer for the long term and uniform supply of plants with nutrient ions comprising a covalently crosslinked hydrogel in which are embedded ion exchangers which are laden with plant nutrients; furthermore a process for the long term and uniform supply of plants with nutrient ions wherein a covalently crosslinked hydrogel in which are embedded ion exchangers which are laden with plant nutrients is applied to the plants or their environment.Type: GrantFiled: March 6, 1981Date of Patent: September 6, 1983Assignee: Bayer AktiengesellschaftInventors: Harold Heller, Dietmar Schapel, Claus Hentschel, Manfred Dahm
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Patent number: 4395335Abstract: A method of reproduction of a filter demineralizer for a cleanup of a condensate backwashes the filter demineralizer to separate ion-exchange resin therefrom. Backwash used for backwashing, and including the ion-exchange resin, is recirculated in a course including a crud removal apparatus to remove the crud thereby providing reproduced ion-exchange resin. On the filter demineralizer from which the ion-exchange resin has been removed, New ion-exchange resin is precoated to form a new ion-exchange resin layer, and then the reproduced ion-exchange resin is deposited on the new ion-exchange resin layer by passing the backwash through the new ion-exchange resin layer.Type: GrantFiled: February 28, 1979Date of Patent: July 26, 1983Assignee: Hitachi, Ltd.Inventor: Toru Saito
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Patent number: 4387026Abstract: An automated plant for the regeneration of exhausted cation exchange material and exhausted anion exchange material involves the use of novel pretreatment and separation procedures, the use of novel regeneration processes, neutralization of waste chemicals and the use of novel cylinder recharging procedures. Electronic process controls are used to effect automatic operation.Type: GrantFiled: January 26, 1981Date of Patent: June 7, 1983Assignee: Biolab Equipment Ltd.Inventor: Charles F. Woolacott
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Patent number: 4378439Abstract: A process for the demineralization of a bicarbonate- or bisulphite-bearing saline solution by means of amphoteric thermally regenerable ion-exchange resins and comprising the regeneration of the resins using as a regenerating agent a solution which is more acidic by a chosen amount than is the saline solution.Type: GrantFiled: March 6, 1978Date of Patent: March 29, 1983Assignee: ICI Australia LimitedInventor: Norman H. Pilkington
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Patent number: 4376706Abstract: In the removal of chromium and zinc, the combination of an anion exchange resin and cation exchange resin in a single vessel, the anion exchange resin being selective of chromium in its chromate and dichromate ionic forms, and the cation exchange resin being an intermediate acid cation exchange resin with a phosphonic acid functional group on a cross-linked polystyrene matrix, having the repeating structural formula: ##STR1## selective of zinc in its ionic form, said single vessel, having distributors selected from the group of inlet distributors, regenerant distributors, subsurface washers, collectors, disposed therein, and inlets and outlets for the addition or removal of effluent, water and regenerant.Type: GrantFiled: December 15, 1980Date of Patent: March 15, 1983Assignee: Petro-Metals Recovery Systems LimitedInventors: Terrence I. Scott, Vincent H. Westlake, Michael K. Bridle
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Patent number: 4349442Abstract: A receptacle has therein a lower bed of mixed anionic and cationic ion exchange resins and an upper bed of cationic ion exchange resins. The upper bed rests directly on the lower bed without any mechanical separation therebetween. Regeneration of the upper bed is achieved by removing the upper bed from the receptacle without removal of the lower bed. An output is located adjacent the boundary between the upper and lower beds. Pressure is exerted on the upper surface of the upper bed, and simultaneously a thin substantially horizontal spray of water is directed along a horizontal plane which is adjacent the boundary, thereby directing the water spray and the cationic resins of the upper bed through the outlet. The cationic resins are regenerated and returned to the receptacle to reform the upper bed. Prior to return of the regenerated cationic ions, the lower bed is dried by draining water therefrom to prevent the returning cationic resins from mixing with the resins from the lower bed.Type: GrantFiled: April 7, 1981Date of Patent: September 14, 1982Assignee: DegremontInventors: Christian Barraque, Jayantilal D. Darji
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Patent number: 4335000Abstract: Chromate ions present in aqueous solutions, e.g. cooling tower blowdown water or liquors obtained from the electrolysis of aqueous sodium chloride solutions, are substantially completely removed by passing the solution through an intimate mixture of an anion exchange resin in the chloride form and a weak cation exchange resin in a conditioned hydrogen form.Type: GrantFiled: February 4, 1980Date of Patent: June 15, 1982Assignee: Pennwalt CorporationInventors: Jesse G. Grier, Jimmie R. Hodges
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Patent number: 4329225Abstract: A mixed bed deionizer unit which provides in situ regeneration through the use of two compact multi-valve assemblies and an intermediate manifold which are automatically controlled to supply backwash water, chemical draw for cleansing both cation and anion resins simultaneously and rinsing water in a sequentially controlled manner. An internal water and chemical distribution system in the mixed bed tank is provided which has both input distribution and output drainage capabilities.Type: GrantFiled: December 29, 1980Date of Patent: May 11, 1982Assignee: Water Refining Company, Inc.Inventors: Stephen H. Davis, Daniel W. Simpson
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Patent number: 4312956Abstract: Flocs prepared by mixing cationic and anionic emulsion ion exchange resins are useful as a filtration and deionization medium. Flocs prepared from weakly acidic and weakly basic emulsion ion exchange resins may be regenerated thermally.Type: GrantFiled: June 18, 1979Date of Patent: January 26, 1982Assignee: Rohm and Haas CompanyInventors: Berni P. Chong, Eric G. Isacoff, James W. Neely
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Patent number: RE34112Abstract: A process for treatment of power plant condensate water particularly from a boiling water nuclear reactor, where the condensate contains colloidal material, especially oxidized iron from the steam and condensate handling system known as "crud". The colloidal iron level of the condensate is lowered by contacting the condensate water with a mixed bed ion exchange resin in which at least the cation exchange resin has a core/shell morphology which has been prepared by a polymerization of monomer within a multiplicity of free radical-containing matrices.Type: GrantFiled: June 27, 1991Date of Patent: October 27, 1992Assignee: The Dow Chemical CompanyInventor: King W. Ma