Abstract: The invention regards a composite for environmental remediation, comprising: —one or more green rust compound(s) or green rust precursor(s), and—one or more biochar(s).

Abstract: Synthetic functionalized additives may comprise a layered magnesium silicate. The layered magnesium silicate may comprise a first functionalized silicate layer comprising a first tetrahedral silicate layer covalently bonded to at least two different functional groups, an octahedral brucite layer, and a second functionalized silicate layer comprising a second tetrahedral silicate layer covalently bonded to at least two different functional groups. A drilling fluid may comprise the synthetic functionalized additive.

Abstract: A device for treating roof runoff has a first tube adapted to be axially aligned with, and in fluid communication with, an outlet of a downpipe. The first tube contains a crushed calcium carbonate media. The device has a second tube in fluid communication with the first tube. The first tube and second tube are arranged such that when a flow of roof runoff from the downpipe is at or below a predetermined flow rate, the flow of roof runoff is directed into the first tube to be treated by the crushed calcium carbonate media contained therein, and when the flow of roof runoff is above the predetermined flow rate, excess flow is diverted into the second tube.

Abstract: Provided herein are hyperbranched polyaminoglycosides, where in some embodiments, the hyperbranched polyaminoglycosides are covalently modified to store and release nitric oxide. Some embodiments pertain to methods of making and use of hyperbranched polyaminoglycosides. In some embodiments, the covalently modified hyperbranched polyaminoglycosides may be tailored to release nitric oxide in a controlled manner and are useful for eradication of both gram positive and gram negative bacteria as well as other microbes.

Abstract: A method of producing a synthetic functionalized additive including the steps of mixing an amount of a magnesium salt with a fluid medium to produce a magnesium-containing fluid, adding an amount of a silane to the magnesium-containing fluid to produce a reactant mix, adding an amount of an aqueous hydroxide to the reactant mix to produce a reaction mixture, mixing the reaction mixture for a mix period, refluxing the reaction mixture for a reflux period to produce a product mix, treating the product mix to separate the synthetic functionalized additive.

Abstract: The present invention refers to the method for synthesis an absorbent material consisting of a phase of tetravalent manganese feroxyhyte (?-Fe(1-x)MnxOOH) with a negatively charged grain surface in which a percentage of iron has been isomorphically substituted by manganese atoms at 0.05-25%. Its' production is carried out in two continuous flow stirred-tank reactors arranged in serial configuration, where mild acidic conditions (pH 5-6) prevail in the first reactor and mild alkaline conditions (pH 9-10) together with high redox potential (600-700 mV) in the second reactor. The material can be used to uptake mercury, as well as other heavy metals from both water and hot gas streams. Specifically, the adsorption capacity is determined by the magnitude of the negative surface charge and the isoelectric point that can be both adjusted by the synthesis process parameters.

Abstract: Aspects described herein relate generally to adsorbent systems and methods for capturing and/or separating organic species (e.g., uncharged organic species) from mixtures with water.

Abstract: The invention relates to a method for removing Cr(VI) ions from an aqueous electrolyte solution, particularly an electrolyte solution for electrochemical metal machining, which comprises the reduction of Cr(VI) to Cr(III) with Fe(II) ions. The Fe(II) ions are added to the electrolyte solution in the form of an aqueous salt solution which has been brought into contact with an ion exchange resin loaded with Fe(II) ions. The invention further relates to a device (1) for electrochemical machining of a workpiece (2) by means of an aqueous electrolyte solution (6), which has an ion exchanger (11) which has been loaded with an ion exchange resin charged with Fe(II) ions.

Abstract: A field groundwater filtering sampling and moving-water flow index measuring device comprises a precipitation tank, an electrode measuring column of moving-water flow, a suction filter unit and a control unit; also provided is a measuring method by adopting the index measuring device. Sample filtering and electrode measuring work in the field groundwater sampling process can be integrally solved, sampling time point selection after well washing is scientifically and automatically achieved, and the sample filtering and collecting efficiency is remarkably improved; and meanwhile, the accuracy of testing various in-situ indexes such as pH value, oxidation reduction potential and the like in groundwater is remarkably improved in the design of moving-water flow electrode measurement. The method has good application prospect and value for carrying out groundwater monitoring and evaluation, remediation and governance, and the like.

Abstract: There is provided a hyper-branched polymer represented by the following formula (1) and having a weight-average molecular weight in a range of 1,000 to 1,000,000. In the formula (1), A1 is a group containing an aromatic ring, A2 is a group containing an amide group, A3 is a group containing sulfur, R0 is hydrogen or a substituted or unsubstituted hydrocarbon group having 1 to 10 carbon atoms, ml is in a range of 0.5 to 11, and n1 is in a range of 5 to 100.

Abstract: Selenium nanomaterials and methods of making and using selenium nanomaterials are disclosed herein. In some embodiments, the selenium nanomaterials can advantageously be used, for example, for removing mercury from air and/or water.

Abstract: Adsorbent particle includes iron oxyhydroxide as a main component, wherein 90% or more of volume of particle is constituted of a granular crystal having a crystal grain size of 20 nm or less or a columnar crystal having a width of 10 nm or less and length of 30 nm or less and particle has BET specific surface area of 250 m2/g or more. Above adsorbent particle is produced by a method including a step of generating iron oxyhydroxide by adding base represented by YOH (wherein Y represents a monovalent atom or atomic group) to solution including at least one selected from trivalent iron compounds represented by FeX3 (wherein X represents a monovalent atom or atomic group other than OH) while adjusting pH to pH 3 to 6, wherein solution has total concentration of FeX3, YOH and other electrolytes of 10% by mass or more at completion of the step.

Abstract: A pigment comprising dyed crystalline cellulose particles comprising a crystalline cellulose core having a surface charge, optionally one or more polyelectrolyte layers with alternating charges adsorbed on top of each other on the crystalline cellulose core, the polyelectrolyte layer closest to the core having a charge opposite the surface charge of the core, and at least one organic dye having a charge is provided.

Abstract: A multi-functional composition of matter that is useful for injection into a flue gas stream to rapidly and efficiently remove mercury from the flue gas streams, particularly at above average flue stream temperatures of about 340° F. or higher. The multi-functional composition of matter may include a fixed carbon content of at least about 20 wt. %, a mineral content of from about 20 wt. % to about 50 wt. %, a sum of micropore plus mesopore volume of at least about 0.20 cc/g, a micropore volume to mesopore volume ratio of at least about 0.7, and a tapped density of not greater than about 0.575 g/ml. These compositions may be further characterized by number of particles per gram of the composition of matter such that the composition may have at least about 0.8 billion particles per gram, or even as many as 1.5 billion particles per gram.

Abstract: The disclosure provides a method for selectively removing sulfites, for example bisulfite anionic species, from a beverage comprising free sulfite by providing an effective amount of a non-ionic, solid phase material and contacting the beverage with the solid phase material thereby sequestering the free sulfite on the non-ionic, solid phase material and providing a beverage having a reduced amount of free sulfite that otherwise maintains the general chemical composition with which it started. The disclosure further provides a device for selectively removing sulfite from a beverage comprising a container for receiving a beverage comprising free sulfite, said container enclosing a non-ionic, solid phase material capable of sequestering free sulfite, and a modular apparatus comprising a sulfite capture module and optionally a sediment filter module or an aeration module. Optionally, the non-ionic solid phase material is food-safe.

Abstract: A new iron-based powder containing a plurality of composite particles composed of a ferritic iron or iron-based porous 5 structural particles having at least one particulate friction modifier distributed in the pores and cavities of the structural particles and further containing at least one particulate stabilizer-sealer. The composite particle is especially suited to be used as a functional material in friction formulations such as brake pads and enable replacement of copper or copper-based materials used in such friction 10 material formulations.

Abstract: A volume susceptibility (?s1) of a first dispersoid particle (s1) is obtained. A second dispersoid particle (s2) that is the first dispersoid particle (s1) to which an adsorbate is adsorbed is obtained. A volume susceptibility (?s2) of the second dispersoid particle (s2) is obtained. An amount of a functional group of the first dispersoid particle (s1) is analyzed through obtaining an amount of the adsorbate included in the second dispersoid particle (s2) based on the volume susceptibilities (?s1) and (?s2) of the first and second dispersoid particles (s1) and (s2).

Abstract: The present disclosure provides a method for processing a fluorine-containing aqueous solution. The method comprises a reaction step for mixing in a vertical direction the fluorine-containing aqueous solution and a disiloxane compound represented by a general formula RaRbRcSiOSiRdReRf, wherein Ra, Rb, Rc, Rd, Re and Rf are selected independently from each other from a group consisting of a phenyl group and an alkyl group comprising from 1 to 20 carbon atoms and hydrogen, to react a fluorine ion in the fluorine-containing aqueous solution with the disiloxane compound, obtaining a first reaction liquid containing a monofluorosilane compound represented by general formulas RaRbRcSiF and RdReRfSiF.

Abstract: Method and apparatus for controlling metals in a liquid are described. The liquid is contacted with a hexahydrotriazine and/or a hemiaminal material, and metal is adsorbed from the liquid onto the material. The hexahydrotriazine and/or hemiaminal material may be made from a diamine and an aldehyde.

Abstract: The compound according to the invention is a compound of formula (1) Ax W1-yMOyO3, wherein A is chosen from the group comprising the Li, Na, NH4, K and H cations, and it is characterized in that x and y verify the relationships 0?x?1 and 0?y?0.5, and in that it has a crystalline structure of the hexagonal type with a base of WO6 octahedra, said structure having tunnels delimited by 6, 4 and 3 of said octahedra and oriented along the axis c.

Abstract: A fluid testing system can be used to measure the levels of contaminants in a fluid system. The system can utilize anodic stripping voltammetry or some other chemical, electrical, or electrochemical process to measure the contaminant levels. Wire electrodes may be used to facilitate the tests. Unused portions of the electrode wires can be fed into the test chambers between tests to ensure clean and reliable electrodes for subsequent testing.

Abstract: A cross-linked polymeric resin which contains reacted monomer units of an aniline, a diaminoalkane, and an aldehyde, and which is functionalized with at least one dithiocarbamate moiety. A process for producing the cross-linked polymeric resin whereby an aniline and a diaminoalkane are linked together by Mannich-type polycondensation reactions with an aldehyde. The resulting Mannich-type polycondensation product is converted into the cross-linked polymeric resin through functionalization of one or more amine functional groups with dithiocarbamate moieties. A method for removing heavy metals, such as Hg(II), from an aqueous solution, whereby the cross-linked polymeric resin is contacted with the aqueous solution, and the heavy metal is thus adsorbed onto the cross-linked polymeric resin.

Abstract: Disclosed are sp2 carbon nanogranules with iron incorporated from heavy petroleum residue of a refinery. The nanogranules may be used for improved synthesis of light olefins (C2-C4) from syngas in a single step Fischer Tropsch synthesis to lower olefins, (FTO). The efficient iron incorporated carbon nanogranules derived from low value heavy petroleum residue are very attractive as a catalytic system for direct synthesis of light olefin (C2-C4) from syngas at CO conversion up to 30%.

Abstract: A method for preparing a sorbent precursor, which may be sulphided and used to remove heavy metals such as mercury from fluid streams, includes the steps of: (i) mixing together an inert particulate support material and one or more binders to form a support mixture, (ii) shaping the support mixture by granulation in a granulator to form agglomerates, (iii) coating the agglomerates with a coating mixture powder including a particulate copper compound and one or more binders to form a coated agglomerate, and (iv) drying the coated agglomerate to form a dried sorbent precursor.

Abstract: Method and apparatus for controlling metals in a liquid are described. The liquid is contacted with a hexahydrotriazine and/or a hemiaminal material, and metal is adsorbed from the liquid onto the material. The hexahydrotriazine and/or hemiaminal material may be made from a diamine and an aldehyde.

Abstract: The invention provides a method for the preparation of an amorphous silicate of at least one metal from the Group 4 of the Periodic Table of Elements with a total pore volume of at least 0.3 mL/g. The method of preparation involves the use of pore shaping conditions, which can be the use of a pore shaper and optionally an increased precipitation temperature, e.g. at least 60° C. The silicate of the invention is especially suitable in catalytic reactions such as esterifications, Michael additions, transesterifications, (ep)oxidations, hydroxylations, or in absorbance of small inorganic and organic molecules e.g. CO2 or aromatic compounds.

Abstract: Animal feeds and feed components are provided which comprise tunicate material. The tunicate material may be whole tunicate, e.g. washed and/or dried, or a tunicate extract. Preferred tunicate extracts include protein- and/or lipid-enhanced extracts. Also provided are uses of tunicates and tunicate extracts as, or in, animal feeds and methods for feeding animals, e.g. fish, comprising administering feeds containing tunicate material.

Abstract: A remote site has an associated state monitoring sub-system for monitoring environmental conditions of a remote site. A local site has an associated state generating sub-system for setting environmental conditions for life forms at the local site. A communication link connects the sub-systems. In response, to monitoring the state of an environmental condition at the remote site, a corresponding environmental condition is generated at the local site which depends on the monitored state.

Abstract: A PH value detection device for detecting a PH value of a solution includes first and a second electrodes to be inserted into the solution; and a power source configured to apply a bipolar rectangular potential pulse signal to the first and second electrodes. A current detector is connected between the first and second electrodes and is configured to detect a current flowing through the first and second electrodes. A calculator is configured to calculate the PH value of the solution, based on the detected current.

Abstract: Photothermal antibacterial material RMG is provided in the present invention, where R represents aldehyde, di-aldehyde or multi-aldehyde, M is magnetic material, and G is reduced graphene oxide. A method of synthesizing the abovementioned antibacterial material comprises of three steps. At first graphene oxide was synthesized, followed by simultaneous reduction and functionalization with MNPs and eventually an aldehyde is modified on magnetic material to yield magnetic G functionalized glutaraldehyde (RMG). We utilize the photothermal feature of graphene for antibacterial activity, in addition graphene was functionalized with aldehyde for capturing bacteria and with magnetic material to enhance a focusing of light irradiation. Moreover, the magnetic properties of material could help for reusability of antibacterial material.

Abstract: A biomimetic synthesis of antihyperglycemic nanoparticles using silver nitrate and Lavatera cretica is a method for the green synthesis of silver nanoparticles. These nanoparticles may be produced by extraction of fresh L. cretica leaves and mixing and incubation of the resulting L. cretica extract with silver nitrate to produce a nanoparticle composition including the silver nanoparticles. The nanoparticle composition may protect against hyperglycemia.

Abstract: A method of selectively extracting anions from an aqueous solution using an anion encapsulating aggregate formed upon the addition of a solvent, a copper contributor, a hydroxide contributor, a counterion contributor, and pyrazole to an aqueous solution containing the anions, or upon the addition of a solvent, a polymeric chain of [CuII(?-OH)(?-pz)]? and a counterion contributor to the aqueous solution. The aggregates include compounds of the formula cis CuIIx(OR1)y(R2pz)z, where R1 is H or an alkyl group, R2 is H, or an alkyl group or a charged group, pz is pyrazolate and each of x, y, and z is an integer between about 1 and about 40. In addition, ligand-containing anion encapsulating aggregates can be formed by synthesis with a lig-and-bound pyrazole or by substituting the ligand-bound pyrazole for the pyrazole incorporated in the aggregate.

Abstract: The present disclose is directed to a method for controlling iodine levels in wet scrubbers, and, in particular, recirculating wet scrubbers by removing the iodine from the scrubbing solution, such as by using ion exchange, absorption, adsorption, precipitation, filtration, solvent extraction, ion pair extraction, and an aqueous two-phase extraction.

Abstract: A method of preparing nanoparticles from desert date can include providing a metal salt solution comprising metal ions; providing desert date extract solution that comprises a reducing agent, and combining the metal ion solution and the desert date extract solution while stirring at a temperature in the range of 25° C. to 100° C. to produce metal or metal oxide nanoparticles. The metal nanoparticles can be gold nanoparticles. The metal oxide nanoparticles can be zinc oxide nanoparticles. The nanoparticles can be used to inhibit the growth or proliferation of a cancer cell and/or microorganisms.

Abstract: Provided herein are processes for recovering metal present at low concentration from an acidic aqueous solution, including contacting the acidic aqueous solution with an organic phase solution including one or more 5-(C8 to C14 alkyl)-2-hydroxyaryloxime, thereby extracting at least part of the metal from the acidic aqueous phase; increasing or maintaining the concentration of metal in the organic phase solution by recycling a portion of the organic phase solution containing the metal and contacting the organic phase with an acidic aqueous solution containing the metal; contacting the organic phase solution containing metal with an aqueous phase strip solution comprising an inorganic compound that back-extracts the metal, thereby stripping at least part of the metal from the organic phase solution to the aqueous phase strip solution; and separating the metal from the aqueous phase strip solution, thereby recovering the metal.

Abstract: Method and apparatus for controlling metals in a liquid are described. The liquid is contacted with a hexahydrotriazine and/or a hemiaminal material, and metal is adsorbed from the liquid onto the material. The hexahydrotriazine and/or hemiaminal material may be made from a diamine and an aldehyde.

Abstract: Aqueous catalysts of nanoparticles of precious metals and stabilizers of flavonoid derivatives are used to electrolessly plate metal on non-conductive substrates. Such substrates include printed circuit boards.

Abstract: Methods, systems and designs are provided for removing mercury from crudes. Crude oil is heated to a temperature above 100° C. and held at that temperature for a specified period of time to convert all of the forms of mercury in the oil into the elemental mercury form. The elemental mercury is then stripped from the crude oil by e.g., flashing the hot oil and/or contacting it with a gas phase. This process transfers the elemental mercury from the oil phase into the gas phase. Elemental mercury can then be removed from the gas phase by methods such as condensation, precipitation, or absorption either alone or in combination.

Abstract: Disclosed is a method for preparing a granulated inorganic adsorbent for radionuclides including slurry forming, solidification, drying and hardening, granulation, and washing steps: blending a dihydrogen phosphate, a powdered inorganic adsorbent raw material and a setting time regulator in water to form a slurry; adding sintered magnesia into the slurry, and blending the mixture to form a solidified slurry; setting the solidified slurry on a disk member, and naturally drying to hardening in a specific temperature range to form a hardened solid material; smashing the hardened solid material and performing vibration sieving by using a screen to obtain a granulated inorganic adsorbent for radionuclides containing residual reagents; washing the granulated inorganic adsorbent for radionuclides containing residual reagents with water, to remove the residual reagents to complete preparation, where the adsorption capacity of the granulated inorganic adsorbent for radionuclides thus prepared is in the range of 0.

Abstract: Aqueous catalysts of nanoparticles of precious metals and stabilizers of flavonoid derivatives are used to electrolessly plate metal on non-conductive substrates. Such substrates include printed circuit boards.

Abstract: The present invention relates to a method for granulation of an absorbent and adsorbent granules prepared by the same. The method comprises the steps of blending sodium metasilicate, metakaoline and an inorganic ion exchange material in water to form a slurry; decanting the resulted slurry onto a nylon cloth of 300 to 400 meshes and natural drying at ambient temperature to solidification; then breaking the solidified final product and sieving it by a screen having a mesh size of from 0.2 to 2.5 mm to provide the absorbent granules having excellent absorbability.

Abstract: Means for reducing an arsenic ion concentration in the solution to the degree of ultra trace amount are provided. Ammonium molybdate is supported by a nanostructure material by mixing the nanostructure material, which is obtained after the nanostructure material such as an alumina reacts with a surfactant, in the solution containing the ammonium molybdate. The nanostructure material supporting an arsenic ion adsorption compound such as ammonium molybdate can selectively adsorb and remove trace of arsenic ion in the solution by a room temperature treatment without a water conditioning such as pH control. In our removal system of arsenic, extra posttreatments are not needed because special pretreatments are not carried out, and special heating equipments are not used. Accordingly, our removal system of arsenic can be constructed at low cost. Furthermore, it can supply an arsenic-free solution by be constructed at multi stages.

Abstract: A method of separating one or more valuable metal cations from an ionic solution by (a) contacting the ionic solution with an activated photoisomerizable host molecule containing a photoisomerizable moiety and a host moiety, where the photoisomerizable moiety has first and second states, and where the host moiety has a greater affinity for a metal cation when the photoisomerizable moiety is in the first state (active binding state) than when the photoisomerizable moiety is in the second state (release state), so that an ion-host molecule association is formed, and (b) separating the ion-host molecule association from the ionic solution. Also disclosed are photoisomerizable host molecules, a method of recovering valuable metals from a waste stream using the photoisomerizable host molecules, and an apparatus comprising a photoisomerizable host molecule attached to a support.

Abstract: Disclosed herein is a method of preparing hyperbranched polyamidoamine particles, including: a) preparing a polyamidoamine precursor mixture from a multifunctional amine monomer and a multifunctional acrylamide monomer; and b) polymerizing the polyamidoamine precursor mixture into cross-linked hyperbranched polyamidoamine particles using reverse phase suspension polymerization. Also, hyperbranched polyamidoamine particles prepared by the method are provided, which can remove heavy metals in an aqueous solution without the need for an ultrafiltration apparatus.

Abstract: The present invention refers to a method for the synthesis of an adsorbing material consisting of a single-phase tetravalent manganese feroxyhite (?-Fe(1-x)MnxOOH), in which a percentage of 0.05 to 25% of iron atoms has been isomorphically substituted by Mn(IV) atoms. Its production takes place in a continuous two-stage flow reactor at weakly acidic conditions (pH 4-7) and high redox (300-800 mV). The material can be used for the removal of both pentavalent and trivalent arsenic as well as other heavy metals form water. More specifically, its adsorption capacity and selectivity depending on the trivalent and pentavalent arsenic water content, are determined by the manganese percentage and the compact or hollow morphology of its structural unit which can be both controlled by the parameters of the synthesis procedure.

Abstract: Porous polymeric networks and composite materials comprising metal nanoparticles distributed in the polymeric networks are provided. Also provided are methods for using the polymeric networks and the composite materials in liquid- and vapor-phase waste remediation applications. The porous polymeric networks, are highly porous, three-dimensional structures characterized by high surface areas. The polymeric networks comprise polymers polymerized from aldehydes and phenolic molecules.

Abstract: A method for producing an ammonium tungstate aqueous solution includes the steps of: adding sulfuric acid to a solution containing tungstate ions; bringing the solution having the sulfuric acid added therein, into contact with an anion exchange resin; and bringing the anion exchange resin into contact with an aqueous solution containing ammonium ions.

Abstract: In a device and a process for purifying water which is contaminated with sulphate ions and heavy metal ions, the water is collected in a water reservoir and a substance having basic activity in water is fed to the water reservoir in such a manner that a precipitant having heavy metal ions is precipitated from the water, wherein at least a subquantity of water is taken off from the water reservoir and is separated into pure water which is substantially freed from sulphate ions and heavy metal ions and dirty water which is enriched with sulphate ions and heavy metal ions. The dirty water is at least in part recirculated to the water reservoir, as a result of which a concentration of sulphate ions in the water reservoir is achieved such that a precipitant having sulphate ions is precipitated from the water.

Abstract: The present invention concerns the elimination of heavy metals, in particular mercury and possibly arsenic and lead, present in a gaseous or liquid effluent by means of a capture mass comprising a support essentially based on alumina obtained by the gel method and at least one element selected from the group constituted by copper, molybdenum, tungsten, iron, nickel and cobalt. The invention is advantageously applicable to the treatment of gas of industrial origin, synthesis gas, natural gas, gas phase condensates and liquid hydrocarbon feeds.

Abstract: Method for the stabilization of contaminants within a material selected from soils, mining tailings and by-products, sludge wastes and industrial wastes, by mixing the material with an alum sludge composition. The composition includes one or more aluminum compound(s) and/or complex(es) together with a reactive carbon material.