Abstract: A novel method for remediating metals includes treating the metals with a mesoporous nanocomposite such as HMS, MCM-41 or MCM-48. The metal is preferably lead but can be at least one metal selected from Pb, Hg, Cd, Zn, Sn, As, Sb, In, Se, Ga, Te, Bi, Ni, Cu, Mo, Ni, Cu, Sr, Ba or Co. The treating is preferably performed at a pH of about 4 to about 12. In the invention, the treating can also include desorbing the metal from the mesoporous nanocomposite at a pH of about 2 or less.

Abstract: Compositions and methods and for contaminants from water are provided. The compositions comprise ferric hydroxide and ferric oxyhydride coated substrates for use in removing the contaminant from the water. Contacting water bearing the contaminant with the substrates can substantially reduce contaminant levels therein. Methods of oxidizing the contaminants in water to facilitate their removal by the ferric hydroxide and ferric oxyhydride coated substrates are also provided. The contaminants include, but are not limited to, arsenic, selenium, uranium, lead, cadmium, nickel, copper, zinc, chromium and vanadium, their oxides and soluble salts thereof.

Abstract: A water treatment apparatus and system, comprising a treatment tank with a plurality of flow-through containers filled with iron shavings. The water is recirculated through the containers of iron shavings in series to treat contaminants, including but not limited to hexavalent chrome. The hexavalent chrome is converted to trivalent chrome via electron transfer between the iron molecules and the chrome molecules. The hydraulic detention time (circulation time) can vary.

Abstract: The use of a coupling agent containing a mercapto, disulfide, tretrasulfide and/or polysulfide end group provides a mercury removal media having increased reactivity, stability, and mercury removal ability. The mercury removal media described herein is prepared by reacting an organophilic clay containing onium ions with a mercapto, disulfide, tetrasulfide, and/or polysulfide end moiety. Alternatively, the clay can be made organophilic by onium ion reaction prior to or simultaneously with the coupling reaction of the mercapto- or sulfide- end group-containing coupling agent.

Abstract: Sorption media for removal of contaminants from fluid streams are provided. The sorption media comprise an active compound bound or linked to a support substrate or matrix. Support substrates can include iron- and alumina-based materials. A method for making sorption media for the removal of contaminants from fluid streams is also described. The method includes selecting a support substrate, and, optionally, providing a doping mixture comprising an active compound. The selected support substrate can be contacted with the doping mixture to form a doped mixture. The doped mixture can be reacted at a predetermined temperature and atmospheric environment for a predetermined duration to form an active media, wherein the active compound is bound or linked to the support substrate.

Abstract: A method for removing mercury from a fluid stream includes the steps of providing a porous composite material comprising a substrate and a plurality of catalyst and/or photocatalyst particles, and contacting substrate with a fluid stream. The porous composite material adsorbs and/or then oxidizes or reduces metallic species including elemental mercury. A fossil fuel fired power plant can include an emission control device comprising the porous composite material to filter flue gas to and thereby minimize mercury emissions into the environment.

Abstract: In the present, a procedure of obtaining adsorbent from a waste material and its use are disclosed. This invention provides a natural waste material, specifically avocado seed, its preparation and use for the filling of columns used in the elimination of contaminants present in wastewater. The particles have an irregular shape and variable size for filling columns of different diameter and length. The adsorbent has the sufficient hardness for avoiding a particle collapse. The material does not rot, is re-generable and ecological. In the present invention the preparation of the adsorbent, its pre-activation, carbonization and application to eliminate the color of textile wastewater is disclosed. The color elimination from textile wastewater, as well as decrease of salts, total suspended solids, chemical oxygen demand (COD) and total organic carbon (TOC), is carried out passing the textile wastewater through a column filled with the prepared adsorbent.

Abstract: An absorbent composition suitable for removing mercury, arsenic or antimony from fluid streams includes 5-50% by weight of a particulate sulphided copper compound, 30-90% by weight of a particulate support material, and the remainder one or more binders, wherein the metal sulphide content of the absorbent, other than copper sulphide, is below 5% by weight.

Abstract: The present application relates to novel chelate resins which contain, as a functional group, quaternary nitrogen atoms in structures of the general formula (I) in which at least one of the radicals R1 to R3 represents an optionally substituted radical of the series consisting of picolyl, methylquinoline or methylpiperidine, m represents an integer from 1 to 4 and M represents the polymer matrix and X represents a counterion of the series consisting of hydroxide OH?, halide, preferably Cl?, Br?, or sulphate SO42?, a process for their preparation and the use thereof, in particular the use of the novel chelate resins in hydrometallurgy and electroplating.

Abstract: A method of producing an adsorption medium to remove at least one constituent from a feed stream. The method comprises dissolving and/or suspending at least one metal compound in a solvent to form a metal solution, dissolving polyacrylonitrile into the metal solution to form a PAN-metal solution, and depositing the PAN-metal solution into a quenching bath to produce the adsorption medium. The at least one constituent, such as arsenic, selenium, or antimony, is removed from the feed stream by passing the feed stream through the adsorption medium. An adsorption medium having an increased metal loading and increased capacity for arresting the at least one constituent to be removed is also disclosed. The adsorption medium includes a polyacrylonitrile matrix and at least one metal hydroxide incorporated into the polyacrylonitrile matrix.

Abstract: A new device, method, and system are disclosed that provide for removal of undesired materials from a contaminated fluid. Materials present in the fluids are kept in motion in one or more filter cassettes that include disc aerators that improve contact times with the sorbents and that rotate the filter media to pump contaminated water through the filter media for treatment of the contaminated fluids. The device and system provide containment of sorbent fines that keeps the filter media free from clogging.

Abstract: A fluid treatment device, system, and process are described that provide a filtered, metal-depleted (treated) fluid. The system includes two pairs of tanks that are piped and valved to allow one pair to fill/react while the other pair decants/discharges, which provides a continuous flow of metal-depleted (treated) fluid. Power requirements are minimal since fluid is pumped at a low head pressure. The design has applications in the potable water, industrial, mining, chemical and environmental sectors.

Abstract: Methods of preparation and application of sulfur functionalized polymers. More particularly, triazine, cyclotriphosphazene and/or phenyl derivatives can be polymerized to form sulfur functionalized polymers. The materials can be used for separating heavy metals from gas and liquid. The invention is a solid extractant or sorbent that upon exposure or contact with a gas and/or liquid can remove contaminates or impurities. The material can be employed as a solid agent to remove mercury and other heavy metal from combustion, calcinations and/or industrial gases. Also, the material can be applied as extracting agent for removing mercury and other heavy metal from a liquid phase. Further, the material can be used for removing/recovering hazardous elements from radioactive nuclear waste; or can be used for removing organic compounds from gases and liquids.

Abstract: Assemblies comprised of mounted flow-through substrates and methods for using and making said assemblies.

Abstract: A heavy metal adsorbent composition configured for use as a mercury adsorbent composition, agent or product is shown. The mercury adsorbent composition comprises a natural diatomite in the form of siliceous frustules of diatoms having a surface punctuated by a series of openings defining frustule structures having sizes in the range of about 0.75 ?m to about 1,000 ?m (rounded to about 1 ?m to about 1,000 ?m). The diatoms have the surfaces thereof treated with an activating material capable of removing mercury by chemical bonding forming surface treated diatoms which when brought into contact with a mercury containing fluid react with mercury to cause mercury to separate from the fluid by chemical bonding to the surface treated diatoms.

Abstract: A method for low-cost arsenic removal from drinking water using chemically prepared bottom ash pre-treated with ferrous sulfate and then sodium hydroxide. Deposits on the surface of particles of bottom ash form of activated iron adsorbent with a high affinity for arsenic. In laboratory tests, a miniscule 5 grams of pre-treated bottom ash was sufficient to remove the arsenic from 2 liters of 2400 ppb (parts per billion) arsenic-laden water to a level below 50 ppb (the present United States Environmental Protection Agency limit). By increasing the amount of pre-treated bottom ash, even lower levels of post-treatment arsenic are expected. It is further expected that this invention supplies a very low-cost solution to arsenic poisoning for large population segments.

Abstract: The present invention relates to a unit suitable for the through-flow of a fluid medium at least partially filled with an adsorbent/catalyst in pellet form consisting essentially of iron oxide and/or iron oxyhydroxides, solidified with oxides and/or (oxy)hydroxides of the elements Al, Mg and Ti, the pellets or granules based on iron oxides and/or iron oxyhydroxides and iron(III) hydroxide for the absorbent/catalyst, and processes for their production and their use.

Abstract: The present invention relates to a method of producing novel chelate resins based on crosslinked polymer beads starting with methacrylic compounds, containing aminomethyl groups and/or aminomethyl nitrogen heterocyclic groups as functional groups, that have a high uptake capacity for heavy metals and rapid kinetics.

Abstract: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.

Abstract: This invention relates to cellulose II phosphate which may be partly carbamidated, and also to a metal-adsorbing material making use of the same. This cellulose II phosphate efficiently adsorbs metal ions in a solution, and can be used as a metal-adsorbing material and in a metal-adsorbing system.

Abstract: Process for the selective removal of Iridium carbonylation catalyst metal and/or at least one promoter selected from ruthenium, osmium and rhenium from a liquid composition comprising a carbonylation product, iridium carbonylation catalyst metal and/or the promoter metal, corrosion metals and optionally alkali or alkaline earth metals. The process is carried out by contacting the liquid composition with a chelating resin to remove at least a portion of the iridium carbonylation catalyst metal and/or at least one promoter metal contained in the liquid composition. The chelating resin contains at least one thiourea functional group. The process is suitable for treating process streams obtained in the production of carboxylic acids and/or carboxylic anhydrides.

Abstract: A mercury absorbent comprising a metal sulphide, a support material, a first binder and a second binder, wherein the first binder is a cement binder and the second binder is a high aspect ratio binder having an aspect ratio >2. A mercury removal process comprises contacting a mercury containing feed stream with the absorbent.

Abstract: Chars may be produced by carbonization or pyrolysis of poultry manure. Chars produced from poultry manure by the method described herein exhibit enhanced activity for metal ion adsorption.

Abstract: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.

Abstract: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.

Abstract: A nanopore reactive adsorbent composite material, which may be a porous adsorbent comprising a chemically surface face modified gel, has a composition and micro structure, which integrals ion exchange components such as hydroxy apatite.

Abstract: The present invention relates to methods of making and using and compositions of metal nanoparticles formed by green chemistry synthetic techniques. For example, the present invention relates to metal nanoparticles formed with solutions of plant extracts and use of these metal nanoparticles in removing contaminants from soil and groundwater and other contaminated sites. In some embodiments, the invention comprises methods of making and using compositions of metal nanoparticles formed using green chemistry techniques.

Abstract: A system for chemically decontaminating radioactive material.

Abstract: A sorbent composition comprising a vanadium compound and a ZrO2 support material is disclosed. Methods of making and using the composition to remove heavy metals or heavy metal containing compounds from a fluid stream are also provided. Such methods are particularly useful in the removal of mercury and mercury compounds from flue gas streams produced from the combustion of hydrocarbon-containing materials such as coal and petroleum fuels.

Abstract: The present invention relates to pellets or granules based on iron oxides and/or iron oxyhydroxides and iron(III) hydroxide, a unit suitable for the through-flow of a fluid medium at least partially filled with an adsorbent/catalyst in pellet form consisting essentially of iron oxide and/or iron oxyhydroxide embedded in an iron hydroxide matrix, processes for their production comprising filtering, drying and shaping steps and their processes of their use.

Abstract: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.

Abstract: The present invention relates to heat-stable anion exchangers based on at least one aromatic monomer and at least one crosslinker having structural elements of the general formula (I) where Ak, Ak?, Ak? are in each case independently of one another identically or differently a C1-C18-alkyl radical, n is an even number between 5 and 18, x+y=2, where x is equal to 0 or 1, and X is Cl, Br, OH, HCO3, HSO4, ½ (SO4), ½ CO3, NO3, F, H2PO4, ½ HPO4, ? PO4 with the result that these anion exchangers, preferably in the OH form, withstand a working temperature of at least 60° C., preferably of at least 80° C., over a relatively long time, a process for production thereof and also use thereof.

Abstract: A composition comprising a vanadium oxide compound and an alkali metal promoter loaded onto a porous support material is disclosed. Methods of making and using the composition to remove heavy metals or heavy metal containing compounds from a fluid stream are also provided. Such methods are particularly useful in the removal of mercury and mercury compounds from flue gas streams produced from the combustion of hydrocarbon-containing materials such as coal and petroleum fuels.

Abstract: The present invention provides magnetically responsive activated carbon, and a method of forming magnetically responsive activated carbon. The method of forming magnetically responsive activated carbon typically includes providing activated carbon in a solution containing ions of ferrite forming elements, wherein at least one of the ferrite forming elements has an oxidation state of +3 and at least a second of the ferrite forming elements has an oxidation state of +2, and increasing pH of the solution to precipitate particles of ferrite that bond to the activated carbon, wherein the activated carbon having the ferrite particles bonded thereto have a positive magnetic susceptibility. The present invention also provides a method of filtering waste water using magnetic activated carbon.

Abstract: A composition and process are described that provide for selective capture of targeted materials, including metals and chemical targets. The composition includes an activated carbon scaffold that is chemically modified to include ligands with a high affinity for selective capture of metals and chemical targets. The invention finds use, e.g., as heavy metal sorbents, as catalyst supports, in analytical applications such as ion chromatography, and in devices such as analytical instruments and chemical sensors.

Abstract: Systems and methods for use of magnesium hydroxide, either directly or through one or more precursors, doped with a divalent or trivalent metal cation, for removing arsenic from drinking water, including water distribution systems. In one embodiment, magnesium hydroxide, Mg(OH)2 (a strong adsorbent for arsenic) doped with a divalent or trivalent metal cation is used to adsorb arsenic. The complex consisting of arsenic adsorbed on Mg(OH)2 doped with a divalent or trivalent metal cation is subsequently removed from the water by conventional means, including filtration, settling, skimming, vortexing, centrifugation, magnetic separation, or other well-known separation systems. In another embodiment, magnesium oxide, MgO, is employed, which reacts with water to form Mg(OH)2. The resulting Mg(OH)2 doped with a divalent or trivalent metal cation, then adsorbs arsenic, as set forth above. The method can also be used to treat human or animal poisoning with arsenic.

Abstract: An apparatus for use in the treatment of contaminated fluid is provided. The apparatus includes an outer element into which contaminated fluid flows and an inner element positioned in substantial axial alignment within the outer element and in spaced relations thereto. The apparatus also includes, between its ends, a pathway defined by an interior surface of the inner element and along which treated fluid may be directed out from the apparatus. A waste nanoadsorbent material can be provided between the outer element and the inner element, for use in removing contaminants within the fluid flowing through the apparatus. A method for the treatment of contaminated fluid is also provided.

Abstract: To provide a recovery agent for recovering arsenic, fluorine, lead, and selenium from a solution containing environmentally hazardous substances including arsenic and fluorine. A porous iron oxide having a particle size of 10 to 100 ?m and a specific surface area of 50 m2/g or larger determined by three-point BET method is introduced into a solution containing the environmentally hazardous substances. Alternatively, a solution containing the environmentally hazardous substances is passed through a column filled with the porous iron oxide. Thus, the environmentally hazardous substances are recovered from the solution.

Abstract: An apparatus for use in the treatment of contaminated fluid is provided. The apparatus includes a body portion, made from a mixture of a waste adsorbent material and a binder material, for use in the removal of contaminants. The adsorbent material may be a nanosorbent material manufactured from self-assembled monolayers on mesoporous supports (SAMMS). The binder material, on the other hand, may include any thermoplastic material capable of binding the adsorbent material together to subsequently provide a composite material that can be shaped into a block. A method for treatment of contaminated fluid is also provided.

Abstract: A mixed extractant solvent that includes at least one dialkyloxycalix[4]arenebenzocrown-6 compound, 4?,4?,(5?)-di-(t-butyldicyclohexano)-18-crown-6, at least one modifier, and, optionally, a diluent. The dialkyloxycalix[4]arenebenzocrown-6 compound is 1,3-alternate-25,27-di(octyloxy)calix[4] arenebenzocrown-6, 1,3-alternate-25,27-di(decyloxy)calix[4]arene-benzocrown-6, 1,3-alternate-25,27-di(dodecyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(2-ethylhexyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(3,7-dimethyloctyl-1-oxy)calix[4] arenebenzocrown-6, 1,3-alternate-25,27-di(4-butyloctyl-1-oxy)calix[4]arenebenzocrown-6, or combinations thereof. The modifier is a primary alcohol. A method of separating cesium and strontium from an aqueous feed is also disclosed, as are dialkyloxycalix[4]arenebenzocrown-6 compounds and an alcohol modifier.

Abstract: The present invention relates to the use of inorganic salts for increasing the adsorption of oxoanions and/or thioanalogues thereof to metal-doped ion exchangers, preferably to iron oxide/iron oxyhydroxide-containing ion exchangers, preferably from water or aqueous solutions, and also the conditioning of these metal-doped ion exchangers having increased adsorption behaviour toward oxoanions and/or thioanalogues thereof by using inorganic salts with the exception of amphoteric ion exchangers which have both acidic and basic groups as functional groups.

Abstract: A method and apparatus for the removal of metals and cleanup of roof top storm water runoff comprising a drum structure which includes at least two media beds for filtering the storm water runoff. The first media bed filters out particles of toxic metals and metal ions are absorbed on the media material in the first media bed.

Abstract: The present invention relates to a process for the purification of water by adding surface-reacted natural calcium carbonate or an aqueous suspension comprising surface-reacted calcium carbonate and having a pH greater than 6.0 measured at 20° C., to the medium, wherein the surface-reacted calcium carbonate is a reaction product of natural calcium carbonate with carbon dioxide and one or more acids and the use of the surface-reacted natural calcium carbonate for this process.

Abstract: The present invention relates to a process for the purification of water, wherein a surface-reacted natural calcium carbonate is brought into contact with the water to be purified, the surface-reacted natural calcium carbonate being the reaction product of a natural calcium carbonate with an acid and carbon dioxide, which is formed in situ by the acid treatment and/or supplied externally.

Abstract: A process for removing mercury from an aqueous stream using a supported selenium and sulfur material is disclosed.

Abstract: The purpose of the invention is to remove copper selectively from a concentrated zinc sulphate solution by ion exchange. The method enables a significant reduction in the use of zinc powder during the solution purification of zinc sulphate solution and makes possible to avoid usage of arsenic or antimony trioxides as a precipitation chemical. The method is to be combined with the chloride removal that occurs as a sub-stage of solution purification.

Abstract: Material composed of a polyazacycloalkane grafted on polypropylene fibres. Process for the preparation of this material. Process for removing metal cations present in a liquid by bringing this liquid into contact with the said material.

Abstract: The present invention relates to products and methods for removing or recovering substances from aqueous solution. Titanic acid product is used as adsorption material for several substances, for example impurities or contaminants, such as arsenic, lead, fluorine or phosphate. The present invention also relates to a granule for removing substances from aqueous solution and a filter assembly comprising titanic acid or said granule.

Abstract: A method of reclaiming a well completion brine solution by using an organic chelant that is capable of discriminating between (i) iron and non-zinc heavy metals; and (ii) calcium and zinc. The chelant contains a functional group selected from the group —CO2H or —PO(R21)R20 or a salt or ester thereof, —C(O)—, —OE, —SE, —N?C(R2)R3, EO—N?C(R2)R3, —N(R2)R3, and —N(C(O)R1)R2 group optionally substituted with a —COOH or —PO(R21)R20 or a salt or ester thereof, —SE or —OE group, wherein R2 and R3 are independently selected from E or forms, with nitrogen, phosphorous, oxygen or sulfur, a heterocyclic ring; E is R1 or —H; R1 is a C1-C30 alkyl or aralkyl group or a derivative thereof and R20 and R21 are independently selected from —OH, —OR1 and R1.

Abstract: An arsenic removal process where arsenic 3 is oxidized to arsenic 5 where the water is passed upflow through a bed of manganese dioxide (MnO2) at a sufficient flow rate such that the MnO2 bed is fluidized whereby precipitating or precipitated iron and/or manganese and/or any other suspended solids will pass through the bed. The suspended matter is then removed by passing the water through disposable or reusable filters. The oxidized arsenic is then removed by passing the water through applicable arsenic removal media.