Using Coil To Generate The Plasma Patents (Class 216/68)
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Method and system for reducing damage to substrates during plasma processing with a resonator source
Publication number: 20020187280Abstract: A method and system for reducing damage to substrates (e.g., wafers) during plasma processing by using a high pressure source. A thin electrostatic shield enables a large number of thin slots to be formed in an electrostatic shield while still being able to excite the plasma. The bottom of the slots and the top of the substrate are separated such that the mean free path of the plasma particles is between 0.5% and 2% of the distance between the bottom of the slots and the substrate holder.Type: ApplicationFiled: June 21, 2002Publication date: December 12, 2002Applicant: TOKYO ELECTRON LIMITEDInventors: Wayne L. Johnson, Murray D. Sirkis -
Publication number: 20020162822Abstract: A method for detecting end-point in a plasma etching process by monitoring plasma impedance changes on a time scale is disclosed. In the method, a plasma etching process is first conducted in a process chamber, while changes in a parameter of plasma impedance in the chamber occurring during the etching process is recorded in a curve on a time scale. An end-point of the plasma etching process is then defined for the etching of a specific material layer at a point where the direction of a slope of the curve changes.Type: ApplicationFiled: May 2, 2001Publication date: November 7, 2002Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.Inventors: Jen-Yuan Yang, Tsai-Yi Chen, Wen-Bin Lin
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Patent number: 6475334Abstract: An inductively coupled plasma dry etching device includes etching chamber 10 and ceramic dome 20. Etching chamber 10 is provided with gate 11 and gas injection port 12. Ceramic ESC stage 31 is provided inside etching chamber 10, and outside etching chamber 10, pressure gauge 13 and pressure controller 40 are connected, and high-frequency power supply 23 is connected to ESC stage 31. First coil 21 and second coil 22 are arranged in helical form on the outside of dome 20 such that turns of one coil lie between turns of the other coil, first coil 21 being connected to second high-frequency power supply 24 and second coil 22 being connected to third high-frequency power supply 25. The high-frequency power supplies are switched at a prescribed time interval.Type: GrantFiled: July 6, 2000Date of Patent: November 5, 2002Assignee: NEC CorporationInventor: Hideki Harano
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Patent number: 6471833Abstract: This invention is directed to a method for rapid plasma etching of materials which are difficult to etch at a high rate. The method is particularly useful in plasma etching silicon nitride layers more than five microns thick. The method includes the use of a plasma source gas that includes an etchant gas and a sputtering gas. Two separate power sources are used in the etching process and the power to each power source as well as the ratio between the flow rates of the etchant gas and sputtering gas can be advantageously adjusted to obtain etch rates of silicon nitride greater than two microns per minute. Additionally, an embodiment of the method of the invention provides a two etch step process which combines a high etch rate process with a low etch rate process to achieve high throughput while minimizing the likelihood of damage to underlying layers. The first etch step of the two-step method provides a high etch rate of about two microns per minute to remove substantially all of a layer to be etched.Type: GrantFiled: May 11, 2001Date of Patent: October 29, 2002Assignee: Applied Materials, Inc.Inventors: Ajay Kumar, Anisul Khan, Jeffrey D Chin, Dragan V Podlesnik
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Patent number: 6471822Abstract: The present invention provides a plasma reactor having a plasma source chamber capable of generating a high density plasma typically utilizing a helicon wave. The plasma is delivered to a process chamber having a workpiece. The present invention may provide a plurality of magnets, each being located longitudinally around an axis perpendicular to the plane of the workpiece to form a magnetic bucket that extends the length of the side wall of the processing chamber and across a workpiece insertion opening and a vacuum pump opening. The magnetic bucket of the present invention may be formed so that the pedestal need not be raised to be within the bucket, or may be formed by permanent magnets oriented with one pole of each magnet facing the interior of the processing chamber, or with opposite poles of adjacent magnets facing each other, thereby forming cusps around the axis perpendicular to the plane of the workpiece. Current carrying conductors may generate all or part of the magnetic bucket.Type: GrantFiled: March 5, 1999Date of Patent: October 29, 2002Assignee: Applied Materials, Inc.Inventors: Gerald Yin, Peter Loewenhardt, Arnold Kholodenko, Hong Chin Shan, Chii Lee, Dan Katz
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Publication number: 20020148812Abstract: The disclosed is a method and apparatus capable of certainly performing a plasma process such as isotropic plasma etching on the whole surface of a particle. A particle (2) is passed through a passage (3) in which inductive coupled plasma is generated and a plasma process is performed on the particle (2). In such a manner, the plasma process on the particle (2) can be performed on the whole surface of the particle (2) in a non-contact manner.Type: ApplicationFiled: June 10, 2002Publication date: October 17, 2002Inventor: Naoki Tamitani
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Patent number: 6465051Abstract: The invention is embodied in a method of cleaning a plasma reactor by creating a vacuum in the chamber while introducing an etchant gas into the chamber through the gas injection ports, and applying RF energy to a ceiling electrode in the chamber while not necessarily applying RF energy to the coil antenna, so as to strike a predominantly capacitively coupled plasma in the vacuum chamber. In another embodiment the method includes, whenever the reactor is to be operated in an inductive coupling mode, applying RF power to the reactors coil antenna while grounding the ceiling electrode, and whenever the reactor is to be operated in a capacitive coupling mode, applying RF power to the ceiling electrode, and whenever the reactor is to be cleaned, cleaning the reactor by applying RF power to the ceiling electrode and to the coil antenna while introducing an etchant gas into the vacuum chamber.Type: GrantFiled: November 18, 1996Date of Patent: October 15, 2002Assignee: Applied Materials, Inc.Inventors: Turgut Sahin, Fred C. Redeker, Romuald Nowak, Shijian Li, Timothy Dyer, Derek R. Witty
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Patent number: 6444084Abstract: The present invention is embodied in a method of operating an inductively coupled plasma reactor for processing a semiconductor wafer, the reactor including a vacuum chamber for containing the wafer, a process gas source, a semiconductor window electrode facing an interior portion of the chamber, an inductive power radiator on an exterior side of the semiconductor window electrode, the inductive field having a skin depth generally decreasing with the frequency of the RF inductive field and with the density of the plasma in the chamber and generally increasing with the pressure inside the vacuum chamber, the inductive coupling of the RF field tending to approach extinguishment as the skin depth approaches the spacing between the wafer and the window electrode, a method for maintaining an intermediate plasma density inside the chamber without extinguishing the inductive coupling of the RF field, the method including operating the reactor at a selected flow rate of the process gas, a selected chamber pressure anType: GrantFiled: January 10, 2000Date of Patent: September 3, 2002Assignee: Applied Materials, Inc.Inventor: Kenneth Collins
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Patent number: 6444137Abstract: A plasma reactor chamber uses an antenna driven by RF energy (LF, MF, or VHF) which is inductively coupled inside the reactor dome. The antenna generates a high density, low energy plasma inside the chamber for etching oxygen-containing layers overlying non-oxygen-containing layers with high selectivity. Auxiliary RF bias energy applied to the wafer support cathode controls the cathode sheath voltage and controls the ion energy independent of density. Various magnetic and voltage processing enhancement techniques are disclosed, along with other etch processes, deposition processes and combined etch/deposition processes. The disclosed invention provides processing of sensitive devices without damage and without microloading, thus providing increased yields. Etching of an oxygen-containing layer overlying a non-oxygen-containing layer can be achieved with high selectivity.Type: GrantFiled: July 1, 1996Date of Patent: September 3, 2002Assignee: Applied Materials, Inc.Inventors: Kenneth S. Collins, Chan-Lon Yang, Jerry Yuen-Kui Wong, Jeffrey Marks, Peter R. Keswick, David W. Groechel
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Publication number: 20020117472Abstract: A substrate processing apparatus has a chamber with a substrate transport to transport a substrate onto a substrate support in the chamber, a gas supply to provide a gas in the chamber, a gas energizer to energize the gas, and a gas exhaust to exhaust the gas. A controller operates one or more of the substrate support, gas supply, gas energizer, and gas exhaust, to set etching process conditions in the chamber to etch a plurality of substrates, thereby depositing etchant residues on surfaces in the chamber. The controller also operates one or more of the substrate support, gas supply, gas energizer, and gas exhaust, to set cleaning process conditions in the chamber to clean the etchant residues. The cleaning process conditions comprise a volumetric flow ratio of O2 to CF4 of from about 1:1 to about 1:40.Type: ApplicationFiled: February 23, 2001Publication date: August 29, 2002Applicant: Applied Materials, Inc.Inventors: Zhi-Wen Sun, Anbei Jiang, Tuo-Chuan Huang
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Patent number: 6440866Abstract: A general method of the invention is to provide a polymer-hardening precursor piece (such as silicon, carbon, silicon carbide or silicon nitride, but preferably silicon) within the reactor chamber during an etch process with a fluoro-carbon or fluoro-hydrocarbon gas, and to heat the polymer-hardening precursor piece above the polymerization temperature sufficiently to achieve a desired increase in oxide-to-silicon etch selectivity. Generally, this polymer-hardening precursor or silicon piece may be an integral part of the reactor chamber walls and/or ceiling or a separate, expendable and quickly removable piece, and the heating/cooling apparatus may be of any suitable type including apparatus which conductively or remotely heats the silicon piece.Type: GrantFiled: June 16, 2000Date of Patent: August 27, 2002Assignee: Applied Materials, Inc.Inventors: Kenneth S. Collins, Michael Rice, David W. Groechel, Gerald Zheyao Yin, Jon Mohn, Craig A. Roderick, Douglas Buchberger, Chan-Lon Yang, Yuen-Kui Wong, Jeffrey Marks, Peter Keswick
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Patent number: 6436304Abstract: A plasma processing method using helicon wave excited plasma which makes it possible to control a degree of dissociation for a process gas by controlling the source power. In the plasma processing method using helicon wave excited plasma, the source power applied to the plasma generator is set lower than a source power corresponding to a discontinuous change of a characteristic line indicating the dependency of electron density or saturated ion current density on source power.Type: GrantFiled: February 5, 1997Date of Patent: August 20, 2002Assignee: Anelva CorporationInventor: Hiroshi Nogami
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Patent number: 6435196Abstract: The present invention relates to an impurity processing apparatus in which impurities such as phosphorus, boron, or the like are doped in a semiconductor substrate, etc., or a PSG (PhosphoSilicateGlass) film, a BSG (BoroSilicateGlass) film, or a BPSG (BoroPhosphoSilicateGlass) film, or a carbon film, etc. This apparatus includes a chamber having an introduction port for an impurity-containing ion gas which is connected to an impurity-containing gas supply section, a substrate holder supporting a substrate which is to be ion-injected, or doped, or on which a film is formed using the impurity-containing gas, an introduction port of a water-containing gas which is provided upstream of the substrate holder in accordance with a flow direction of the impurity-containing gas, and is connected to a water-containing gas supply section, and first plasma generating means in a space extending from the introduction port for water-containing gas to the substrate holder for converting water-containing gas to a plasma.Type: GrantFiled: December 1, 1999Date of Patent: August 20, 2002Assignees: Canon Sales Co., Inc., Semiconductor Process Laboratory Co., Ltd.Inventors: Noritada Satoh, Kouichi Ohira, Bunya Matsui, Kazuo Maeda
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Patent number: 6435130Abstract: A plasma CVD apparatus comprising a substantially enclosed reaction chamber containing substrate holding means and a cathode electrode arranged therein, wherein a high frequency power from a high frequency power source is supplied to said cathode electrode to generate plasma between said substrate holding means having a subtrate positioned thereon and said cathode electrode whereby plasma-processing said substrate, characterized in that said cathode electrode comprises a plurality of conductor members situated on substantially the same axis which are capacitively coupled by a dielectric member. A plasma-processing method using said cathode electrode.Type: GrantFiled: August 22, 1997Date of Patent: August 20, 2002Assignee: Canon Kabushiki KaishaInventors: Satoshi Takaki, Yoshio Segi, Atsushi Yamagami, Hiroyuki Katagiri, Hitoshi Murayama, Yasuyoshi Takai
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Patent number: 6432318Abstract: An oxide etching recipe including a heavy hydrogen-free fluorocarbon having F/C ratios less than 2 such as C4F6 or C5F8, an oxygen-containing gas such as O2, CO or CO2, a lighter fluorocarbon or hydrofluorocarbon, and a noble diluent gas such as Ar or Xe. The amounts of the first three gases are chosen such that the ratio (F—H)/(C—O) is at least 1.5 and no more than 2. Alternatively, the gas mixture may include the heavy fluorocarbon, carbon tetrafluoride, and the diluent with the ratio of the first two chosen such the ratio F/C is between 1.5 and 2.Type: GrantFiled: February 17, 2000Date of Patent: August 13, 2002Assignee: Applied Materials, Inc.Inventors: Ji Ding, Hidehiro Kojiri, Yoshio Ishikawa, Keiji Horioka, Ruiping Wang, Robert W. Wu, Hoiman Hung
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Publication number: 20020092826Abstract: A high plasma density etch process for etching an oxygen-containing layer overlying a non-oxygen containing layer on a workpiece in a plasma reactor chamber, by providing a chamber ceiling overlying the workpiece and containing a semiconductor material, supplying into the chamber a process gas containing etchant precursor species, polymer precursor species and hydrogen, applying plasma source power into the chamber, and cooling the ceiling to a temperature range at or below about 150 degrees C. The etchant and polymer precursor species contain fluorine, and the chamber ceiling semiconductor material includes a fluorine scavenger precursor material. Preferably, the process gas includes at least one of CHF3 and CH2F2. Preferably, the process gas further includes a species including an inert gas, such as HeH2 or Ar. If the chamber is of the type including a heated fluorine scavenger precursor material, this material is heated to well above the polymer condensation temperature, while the ceiling is cooled.Type: ApplicationFiled: October 31, 2001Publication date: July 18, 2002Inventor: Jian Ding
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Publication number: 20020084034Abstract: The processing with a low gate rate of destruction and high anisotropy is achieved in dry etching. Plasma is generated by ECR resonance of electromagnetic wave which arose by supplying Ultra High Frequency electric power in microstripline 4 arranged on the atmosphere side of a dielectric 2, which separates a vacuum inside and an outside and magnetic field. A conducting layer is etched by this plasma, which is stable and uniform plasma.Type: ApplicationFiled: July 29, 1999Publication date: July 4, 2002Inventors: NAOYUKI KOFUJI, MASAHITO MORI, KEN?apos;ETSU YOKOGAWA, NAOSHI ITABASHI, KAZUNORI TSUJIMOTO, SHIN?apos;ICHI TACHI
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Patent number: 6415198Abstract: A method of etching silicon using a chlorine and sulfur dioxide gas chemistry. An embodiment of the method is accomplished using a 20 to 300 sccm of chlorine and 2 to 100 sccm of sulfur dioxide, regulated to a total chamber pressure of 2-100 mTorr.Type: GrantFiled: June 25, 1999Date of Patent: July 2, 2002Assignee: Applied Materials, Inc.Inventors: Padmapani C. Nallan, Ajay Kumar, Jeffrey D. Chinn
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Patent number: 6409933Abstract: The invention is realized in a plasma reactor for processing a semiconductor workpiece. The reactor includes a vacuum chamber having a side wall and a ceiling, a workpiece support pedestal within the chamber and generally facing the ceiling, a gas inlet capable of supplying a process gas into the chamber and a solenoidal interleaved parallel conductor coil antenna overlying the ceiling and including a first plurality conductors wound about an axis of symmetry generally perpendicular to the ceiling in respective concentric helical solenoids of at least nearly uniform lateral displacements from the axis of symmetry, each helical solenoid being offset from the other helical solenoids in a direction parallel to the axis of symmetry. An RF plasma source power supply is connected across each of the plural conductors.Type: GrantFiled: July 6, 2000Date of Patent: June 25, 2002Assignee: Applied Materials, Inc.Inventors: John Holland, Valentin N. Todorow, Michael Barnes
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Patent number: 6395641Abstract: Apparatus and method for an improved etch process. A power source alternates between high and low power cycles to produce and sustain a plasma discharge. Preferably, the high power cycles couple sufficient power into the plasma to produce a high density of ions (≳1011 cm−3) for etching. Preferably, the low power cycles allow electrons to cool off to reduce the average random (thermal) electron velocity in the plasma. Preferably, the low power cycle is limited in duration as necessary to prevent excessive plasma loss to the walls or due to recombination of negative and positive ions. It is an advantage of these and other aspects of the present invention that average electron thermal velocity is reduced, so fewer electrons overcome the plasma sheath and accumulate on substrate or mask layer surfaces. A separate power source alternates between high and low power cycles to accelerate ions toward the substrate being etched. In one embodiment, a strong bias is applied to the substrate in short bursts.Type: GrantFiled: May 16, 2001Date of Patent: May 28, 2002Assignee: Mattson Techonolgy, Inc.Inventor: Stephen E. Savas
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Patent number: 6388382Abstract: The main purpose of the present invention is to suppress deposition of byproducts on an inner wall of a vacuum chamber during wafer processing using plasma generated by an inductive coupling antenna and an electrostatic capacitive coupling antenna which are connected in series at a connection point. Deposition of byproducts on the inner wall of the vacuum chamber can be suppressed by grounding the connection point of the inductive coupling antenna and the electrostatic capacitive coupling antenna via a variable-impedance load and varying an impedance of the variable-impedance load, thereby controlling a ratio of plasma produced in the chamber by electrostatic capacitive coupling discharge.Type: GrantFiled: March 8, 2000Date of Patent: May 14, 2002Assignee: Hitachi, Ltd.Inventors: Akira Doi, Ken Yoshioka, Manabu Edamura, Hideyuki Kazumi, Saburou Kanai, Tsutomu Tetsuka, Masatsugu Arai, Kenji Maeda, Tsunehiko Tsubone
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Patent number: 6383403Abstract: A substrate to be etched is subjected to dry etching by using a dry etching gas containing a perfluorocycloolefin while a plasma with a high density region of at least 1010/cm3 is generated. As the perfluorocycloolefin, those having 3 to 8 carbon atoms, especially 4 to 6 carbon atoms are preferably used.Type: GrantFiled: April 30, 1999Date of Patent: May 7, 2002Assignees: Japan as represented by the Director General of the Agency of Industrial Science and Technology, The Mechanical Social Systems Foundation, Electronic Industries Association of Japan, Nippon Zeon Co., Ltd.Inventors: Akira Sekiya, Toshiro Yamada, Kuniaki Goto, Tetsuya Takagaki
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Patent number: 6379576Abstract: Variable mode plasma system and method for processing a semiconductor wafer. The modulation of the plasma potential relative to the semiconductor wafer is varied for different process steps. A capacitive shield may be selectively grounded to vary the level of capacitive coupling and modulation of the plasma. Process pressures, gases and power level may also be modified for different process steps. Plasma properties may easily be tailored to specific layers and materials being processed on the surface of the wafer. Variable mode processes may be adapted for (i) removal of photoresist after high-dose ion implant, (ii) post metal etch polymer removal, (iii) via clean, and (iv) other plasma enhanced processes.Type: GrantFiled: November 16, 1998Date of Patent: April 30, 2002Assignee: Mattson Technology, Inc.Inventors: Leroy Luo, Rene George, Stephen E. Savas, Craig Ranft, Wolfgang Helle, Robert Guerra
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Patent number: 6368452Abstract: In a plasma treatment apparatus having a plasma reaction chamber whose internal surface is covered with a plasma protection member, the protection member is constituted by a sintered silicon carbide substrate and a silicon carbide coating thereon. The resistivity of the silicon carbide substrate is increased by addition of boron which could contaminate the chamber if liberated by plasma attack of the sintered silicon carbide substrate. The deposited silicon carbide film has high purity and low resistivity and filament grooves are used to partition the silicon carbide film. The filament grooves minimize deleterious effects on the plasma density distribution in the chamber otherwise caused by generation of eddy currents on the surface of the low resistivity silicon carbide film.Type: GrantFiled: June 30, 2000Date of Patent: April 9, 2002Assignee: Lam Research CorporationInventor: Shu Nakajima
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Publication number: 20020038791Abstract: While interior of a vacuum chamber is maintained to a specified pressure by introducing a specified gas from a gas supply unit into the vacuum chamber and simultaneously performing exhaustion by a pump as an exhauster, a high-frequency power of 100 MHz is supplied by an antenna use high-frequency power supply to an antenna provided so as to project into the vacuum chamber, by which plasma is generated in the vacuum chamber. The vacuum chamber grounded, and separated into a region on one side on which the substrate is present and a region on the other side on which the substrate is absent by a punching metal plate nearly all the peripheral portion of which is grounded.Type: ApplicationFiled: October 3, 2001Publication date: April 4, 2002Inventors: Tomohiro Okumura, Yukihiro Maegawa, Izuru Matsuda, Takayuki Kai
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Patent number: 6365063Abstract: In a plasma reactor including a reactor chamber, a workpiece support for holding a workpiece inside the chamber during processing and an inductive antenna, a window electrode proximal a wall of the chamber, the antenna and wall being positioned adjacently, the window electrode being operable as (a) a capacitive electrode accepting RF power to capacitively coupled plasma source power into the chamber, and (b) a window electrode passing Rf power therethrough from said antenna into the chamber to inductively couple plasma source power into the chamber.Type: GrantFiled: July 9, 1999Date of Patent: April 2, 2002Assignee: Applied Materials, Inc.Inventors: Kenneth S Collins, Michael Rice, Farahmand E Askarinam, Douglas A Buchberger, Jr., Craig A Roderick
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Patent number: 6355183Abstract: In a chamber, there are provided a sample stage on which a semiconductor substrate is placed, a gas inlet port for introducing etching gas, and a gas outlet port for exhausting the gas. A slide valve having a valve element which rotates relative to a valve seat is provided between the sample stage and the gas outlet port to adjust the amount of gas exhausted from the gas outlet port with the rotation of the valve element. A spiral coil for generating a high-frequency induction field and thereby changing the etching gas into a plasma is rotatably provided over the chamber. Rotative driving means rotates the spiral coil in response to the rotation of the valve element of the slide valve such that the higher-voltage region of the spiral coil approximately coincides with the exhaust-side region of the slide valve.Type: GrantFiled: August 26, 1999Date of Patent: March 12, 2002Assignee: Matsushita Electric Industrial Co., Ltd.Inventor: Mitsuhiro Ohkuni
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Publication number: 20020027205Abstract: A novel plasma treatment method (800, 814). The method includes forming an rf plasma discharge in a vacuum chamber. The plasma discharge includes an inductive coupling structure, which has a first cusp region at a first end of the structure and a second cusp region at a second end of the structure. In some embodiments, a third cusp region, which is between the first and second cusp regions, can also be included. The first cusp region is provided by a first electro-magnetic source and the second cusp region is provided by a second-electro magnetic source. The first electro-magnetic source and the second electro-magnetic source confines a substantial portion of the rf plasma discharge to a region away from a wall of the vacuum chamber. Accordingly, a plasma discharge is substantially a single ionic species (e.g., H1+) can be formed.Type: ApplicationFiled: June 5, 2001Publication date: March 7, 2002Inventors: Wei Liu, Michael A. Bryan, Ian S. Roth
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Publication number: 20020025388Abstract: This invention relates to plasma processing apparatus and methods. Apparatus includes a chamber, a wafer support, antennae, a control module for controlling the antennae and responsive to associated detectors, which are located in or adjacent the wafer.Type: ApplicationFiled: July 2, 2001Publication date: February 28, 2002Inventors: Jyoti Kiron Bhardwaj, Leslie Michael Lea
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Publication number: 20020008079Abstract: A dry etching method for an iridium electrode, wherein the dry etching method includes depositing an iridium metal film on a substrate, forming a photoresist mask on the metal film in a predetermined pattern, etching the metal film which is not covered with the photoresist mask in the predetermined pattern by generating plasma using an etch gas containing an inert gas and fluorine-based gas, and removing the photoresist mask. Accordingly, no etch residues remain even if a photoresist is used as an etch mask, and it is not necessary to heat a substrate to a high temperature. In addition, since the selectivity of an iridium electrode with respect to a photoresist mask can be increased, an iridium electrode having a satisfactory etch profile can be formed.Type: ApplicationFiled: March 9, 2001Publication date: January 24, 2002Inventor: Chee-won Chung
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Patent number: 6335293Abstract: A system and method for two-sided etch of a semiconductor substrate. Reactive species are generated and flowed toward a substrate for processing. A diverter is positioned between the generation chamber and the substrate. A portion of the reactive species flows through the diverter for processing the front of the substrate. Another portion is diverted around the substrate to the backside for processing. A flow restricter is placed between the substrate and the exhaust system to increase the residence time of reactive species adjacent to the backside.Type: GrantFiled: July 12, 1999Date of Patent: January 1, 2002Assignee: Mattson Technology, Inc.Inventors: Laizhong Luo, Ying Holden, Rene George, Robert Guerra, Allan Wiesnoski, Nicole Kuhl, Craig Ranft, Sai Mantripragada
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Publication number: 20010054601Abstract: A high plasma density etch process for etching an oxygen-containing layer overlying a non-oxygen containing layer on a workpiece in a plasma reactor chamber, by providing a chamber ceiling overlying the workpiece and containing a semiconductor material, supplying into the chamber a process gas containing etchant precursor species, polymer precursor species and hydrogen, applying plasma source power into the chamber, and cooling the ceiling to a temperature range at or below about 150 degrees C. The etchant and polymer precursor species contain fluorine, and the chamber ceiling semiconductor material includes a fluorine scavenger precursor material. Preferably, the process gas includes at least one of CHF3 and CH2F2. Preferably, the process gas further includes a species including an inert gas, such as HeH2 or Ar. If the chamber is of the type including a heated fluorine scavenger precursor material, this material is heated to well above the polymer condensation temperature, while the ceiling is cooled.Type: ApplicationFiled: January 16, 1998Publication date: December 27, 2001Inventor: JIAN DING
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Publication number: 20010050265Abstract: The invention generally provides an apparatus and a method of removing metal oxides, particularly copper oxides and aluminum oxides, from a substrate surface. Primarily, the invention eliminates sputtering of copper oxide from the bottom of an interconnect feature onto the side walls of an interconnect feature, thereby preventing diffusion of the copper atom through the dielectric material and degradation of the device. The invention also eliminates sputtering of the copper oxides onto the chamber side walls that may eventually flake off and cause defects on the substrate. The method of reducing metal oxides from a substrate surface comprises placing the substrate within a plasma processing chamber, flowing a processing gas comprising hydrogen into the chamber, and maintaining a plasma of the processing gas within the chamber through inductive coupling.Type: ApplicationFiled: May 21, 1998Publication date: December 13, 2001Inventors: BARNEY M. COHEN, GILBERT HAUSMANN, VIJAY PARKHE, ZHENG XU
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Patent number: 6322661Abstract: A plasma confinement arrangement for controlling the volume of a plasma while processing a substrate inside a process chamber using a plasma enhanced process is disclosed. The arrangement includes a first magnetic bucket having a plurality of first magnetic elements. The first magnetic elements being configured for producing a first magnetic field inside the process chamber. The arrangement further includes a second magnetic bucket having a plurality of second magnetic elements. The second magnetic elements being configured for producing a second magnetic field inside the process chamber. The second magnetic field being configured to combine with the first magnetic field to produce a resultant magnetic field between the first magnetic bucket and the second magnetic bucket. The resultant magnetic field being configured to permit by-product gas from the processing to pass through while substantially confining the plasma within a volume defined at least by the process chamber and the resultant magnetic field.Type: GrantFiled: November 15, 1999Date of Patent: November 27, 2001Assignee: Lam Research CorporationInventors: Andrew D. Bailey, III, Alan M. Schoepp, Nicolas Bright
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Patent number: 6312616Abstract: A method of etching polysilicon using a fluorinated gas chemistry to provide an etch rate in excess of 10,000 Å/min and a photoresist selectivity of better than 3:1. The method is accomplished using a combination of a fluorinated gas and a fluorocarbon gas, e.g., 50-60 sccm of SF6, 1-40 sccm of CHF3, and 40-50 sccm of O2 with a total chamber pressure of 4-60 mTorr. The power applied to the etch chemistry to produce an etching plasma is 400-1500 watts of inductive source power (at 13.56 MHz) via an inductively coupled antenna and 200-1500 watts (at 12.56 MHz) of cathode bias power applied via a cathode electrode within a wafer support pedestal. The pedestal supporting the wafer was maintained at 0-50 degrees C.Type: GrantFiled: December 3, 1998Date of Patent: November 6, 2001Assignee: Applied Materials, Inc.Inventors: Jeffrey Chinn, Taeho Shin, Nam-Hun Kim
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Patent number: 6310577Abstract: An antenna adapted to apply a uniform electromagnetic field with high energy density to a volume of gas. The antenna includes an input node for receiving electrical energy and a first coil for radiating electromagnetic energy into the gas. The first coil is connected to the input node on one end thereof and is grounded on the opposite side to cause flux to flow in a first direction. A second coil is included for radiating electromagnetic energy into the gas. The second coil is also connected to the input node on one end thereof and grounded on the opposite side to flow in the first direction. Multiple number of coils can be added to form an antenna. In an illustrative application, the antenna is used in a plasma processing system comprising a vacuum chamber, a gas disposed within the vacuum chamber, and a dielectric disposed around the vacuum chamber. The inventive antenna is mounted around the dielectric tube and radiates electromagnetic energy into the gas.Type: GrantFiled: August 24, 1999Date of Patent: October 30, 2001Assignee: Bethel Material ResearchInventor: Yunju Ra
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Patent number: 6274502Abstract: An apparatus for plasma etching comprises a chamber, a gas inlet port provided in the chamber to introduce etching gas into the chamber, a gas outlet port provided in a side portion of the chamber to exhaust the gas from said chamber, a sample stage provided within the chamber, and a spiral coil disposed externally of the chamber and in opposing relation with the sample stage to generate a plasma composed of the etching gas with a high-frequency induction field. The higher-voltage region of the spiral coil and the exhaust-side region of the sample stage are positioned on substantially the same side relative to the center axis of the chamber.Type: GrantFiled: December 1, 1998Date of Patent: August 14, 2001Assignee: Matsushita Electronics CorporationInventor: Mitsuhiro Ohkuni
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Patent number: 6273022Abstract: Apparatus and method for inductively coupling electrical power to a plasma in a semiconductor process chamber. In a first aspect, an array of induction coils is distributed over a geometric surface having a circular transverse section. Each coil has a transverse section which is wedge-shaped so that the adjacent sides of any two adjacent coils in the array are approximately parallel to a radius of the circular transverse section of the geometric surface. The sides of adjacent coils being parallel enhances the radial uniformity of the magnetic field produced by the coil array. In a second aspect, electrostatic coupling between the induction coils and the plasma is minimized by connecting each induction coil to the power supply so that the turn of wire of the coil which is nearest to the plasma is near electrical ground potential. In one embodiment, the near end of each coil connects directly to electrical ground. In second and third embodiments, two coils are connected in series at the near end of each coil.Type: GrantFiled: March 14, 1998Date of Patent: August 14, 2001Assignee: Applied Materials, Inc.Inventors: Bryan Y. Pu, Hongching Shan, Claes Bjorkman, Kenny Doan, Mike Welch, Richard Raymond Mett
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Patent number: 6270634Abstract: This invention is directed to a method for rapid plasma etching of materials which are difficult to etch at a high rate. The method is particularly useful in plasma etching silicon nitride layers more than five microns thick. The method includes the use of a plasma source gas that includes an etchant gas and a sputtering gas. Two separate power sources are used in the etching process and the power to each power source as well as the ratio between the flow rates of the etchant gas and sputtering gas can be advantageously adjusted to obtain etch rates of silicon nitride greater than two microns per minute. Additionally, an embodiment of the method of the invention provides a two etch step process which combines a high etch rate process with a low etch rate process to achieve high throughput while minimizing the likelihood of damage to underlying layers. The first etch step of the two-step method provides a high etch rate of about two microns per minute to remove substantially all of a layer to be etched.Type: GrantFiled: October 29, 1999Date of Patent: August 7, 2001Assignee: Applied Materials, Inc.Inventors: Ajay Kumar, Anisul Khan, Jeffrey D Chinn, Dragan Podlesnik
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Patent number: 6270687Abstract: An RF plasma etch reactor having an etch chamber with electrically conductive walls and a protective layer forming the portion of the walls facing the interior of the chamber. The protective layer prevents sputtering of material from the chamber walls by a plasma formed within the chamber. The etch reactor also has an inductive coil antenna disposed within the etch chamber which is used to generate the plasma by inductive coupling. Like the chamber walls, the inductive coil antenna is constructed to prevent sputtering of the material making up the antenna by the plasma. The coil antenna can take on any configuration (e.g. location, shape, orientation) that is necessary to achieve a desired power deposition pattern within the chamber. Examples of potential coil antenna configurations for achieving the desired power deposition pattern include constructing the coil antenna with a unitary or a segmented structure.Type: GrantFiled: April 27, 2000Date of Patent: August 7, 2001Assignee: Applied Materials, Inc.Inventors: Yan Ye, Donald Olgado, Avi Tepman, Diana Ma, Gerald Zheyao Yin, Peter Loewenhardt, Jeng Hwang, Steve S. Y. Mak
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Patent number: 6267121Abstract: An improved seasoning process for a plasma etching chamber is described. This has been achieved by increasing the RF power to both the wafer and the walls of the chamber during seasoning. Additionally, the gas that is used is at a pressure of about 10 mTorr and has the following composition: chlorine about 90% and oxygen about 10%. By observing the optical emission spectrum during seasoning (notably lines due to the SiClx species) it is confirmed that, under these conditions, seasoning is completed by using only a single wafer for about 100 seconds.Type: GrantFiled: February 11, 1999Date of Patent: July 31, 2001Assignee: Taiwan Semiconductor Manufacturing CompanyInventors: Cheng-Hao Huang, Ming-Shuo Yen, Shih-Fang Chen, Wen-Hsiang Tang, Pei-Hung Chen
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Publication number: 20010008226Abstract: An integrated in situ oxide etch process particularly useful for a counterbore dual-damascene structure over copper having in one inter-layer dielectric level a lower nitride stop layer, a lower oxide dielectric, a lower nitride stop layer, an upper oxide dielectric layer, and an anti-reflective coating (ARC). The process is divided into a counterbore etch and a trench etch with photolithography for each, and each step is preferably performed in a high-density plasma reactor having an inductively coupled plasma source primarily generating the plasma and a capacitively coupled pedestal supporting the wafer and producing the bias power. The counterbore etch preferably includes at least four substeps of opening the ARC, etching through the upper oxide and nitride layers, selectively etching the lower oxide layer but stopping on the lower nitride layer, and a post-etch treatment for removing residue.Type: ApplicationFiled: November 30, 1998Publication date: July 19, 2001Inventors: HOIMAN HUNG, JOSEPH P. CAULFIELD, SUM-YEE BETTY TANG, JIAN DING, TIANZONG XU
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Patent number: 6254738Abstract: Variable reactances in an impedance-matching box for an RF coil, in a plasma deposition system for depositing a film of sputtered target material on a substrate, can be varied by rotating inductor cores during the deposition process so that the RF coil and substrate heating, and the film deposition, are more uniform due to “time-averaging” of the RF voltage distributions along the RF coil.Type: GrantFiled: March 31, 1998Date of Patent: July 3, 2001Assignee: Applied Materials, Inc.Inventors: Bradley O. Stimson, Kenneth Smyth, Praburam Gopalraja
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Patent number: 6255221Abstract: Disclosed are methods and systems for etching dielectric layers in a high density plasma etcher. A method includes providing a wafer having a photoresist mask over a dielectric layer in order to define at least one contact via hole or open area that is electrically interconnected down to the silicon substrate of the wafer. The method then proceeds to inserting the wafer into the high density plasma etcher and pulsed application a TCP power source of the high density plasma etcher. The pulsed application includes ascertaining a desired etch performance characteristic, which includes photoresist selectivity and etch rate which is associated with a continuous wave application of the TCP source. Then, selecting a duty cycle of the pulsed application of the TCP source and scaling a peak power of the pulsed application of the TCP source in order to match a cycle-averaged power that would be delivered by the continuous wave application of the TCP source.Type: GrantFiled: December 17, 1998Date of Patent: July 3, 2001Assignee: Lam Research CorporationInventors: Eric A. Hudson, Jaroslaw W. Winniczek, Joel M. Cook, Helen L. Maynard
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Patent number: 6248251Abstract: A plasma etch apparatus (10) such as that for etching wafers in the manufacture of semiconductors includes a vacuum chamber (15) surrounded by a cylindrical dielectric wall (13). A coil (20) surrounds the chamber outside of the wall and is energized with medium frequency RF energy which is inductively coupled into the chamber to energize a plasma in the chamber to etch a semiconductor wafer (16) on a support (17) in the chamber. A generally cylindrical Faraday shield (30) surrounds the outside of the chamber in contact with the outside of the wall between the wall and the coil. The shield has a plurality of axially oriented slits (32) therein closely spaced around the shield and extending less than the height of the shield. One slit or gap (31) extends the full height of the shield and interrupts an otherwise continuous conductive path around the circumference of the chamber.Type: GrantFiled: February 19, 1999Date of Patent: June 19, 2001Assignee: Tokyo Electron LimitedInventor: Edward L. Sill
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Patent number: 6248250Abstract: The present invention adheres to an optimized coil-domed geometry including a particular dome apex height range relative to the dome base and a particular wafer position range relative to the dome apex.Type: GrantFiled: July 21, 1997Date of Patent: June 19, 2001Assignee: Applied Materials Inc.Inventors: Hiroji Hanawa, Gerald Zheyao Yin, Diana Xiaobing Ma, Philip M. Saizman, Peter K. Loewenhardt, Allen Zhao
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Patent number: 6238588Abstract: The invention is embodied in a method of processing a semiconductor workpiece in a plasma reactor chamber, including supplying a polymer and etchant precursor gas containing at least carbon and fluorine into the chamber at a first flow rate sufficient of itself to maintain a gas pressure in the chamber in a low pressure range below about 20 mT, supplying a relatively non-reactive gas into the chamber at second flow rate sufficient about one half or more of the total gas flow rate into the chamber, in combination with the first flow rate of the precursor gas, to maintain the gas pressure in the chamber in a high pressure range above 20 mT, and applying plasma source power into the chamber to form a high ion density plasma having an ion density in excess of 1010 ions per cubic centimeter.Type: GrantFiled: October 21, 1996Date of Patent: May 29, 2001Assignee: Applied Materials, Inc.Inventors: Kenneth Collins, David Groechel, Raymond Hung, Michael Rice, Gerald Yin, Jian Ding, Chunshi Cui
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Patent number: 6231776Abstract: The present invention provides a technique, including a method and apparatus, for etching a substrate in the manufacture of a device. The apparatus includes a chamber and a substrate holder disposed in the chamber. The substrate holder has a selected thermal mass to facilitate changing the temperature of the substrate to be etched during etching processes. That is, the selected thermal mass of the substrate holder allows for a change from a first temperature to a second temperature within a characteristic time period to process a film. The present technique can, for example, provide different processing temperatures during an etching process or the like.Type: GrantFiled: September 10, 1998Date of Patent: May 15, 2001Inventor: Daniel L. Flamm
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Patent number: 6231777Abstract: A pulse voltage of duty ratio 5% or below and repetition frequency 400 KHz or above is supplied in order to suppress the notch, charge build-up damage, subtrench and bowing due to the electron shading phenomenon. Thus, a cycle for accelerating electrons occurs in the substrate bias, so that the electron shading phenomenon does not occur.Type: GrantFiled: October 26, 1995Date of Patent: May 15, 2001Assignee: Hitachi, Ltd.Inventors: Naoyuki Kofuji, Shin Arai, Kazunori Tsujimoto, Tatsumi Mizutani, Keizo Suzuki, Kenichi Mizuishi
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Patent number: 6228229Abstract: A method and apparatus for generating a plasma by inductively coupling electromagnetic energy into the plasma. In one embodiment, first and second antenna coils are disposed about the circumference of the plasma containment area. The first and second antenna coils are relatively spaced along the longitudinal axis of the plasma containment area. A current is generated in the first and second antenna coils. A phase shift regulating network establishes a difference between the phase of the current in the first antenna and the phase of the current in the second antenna. The phase difference corresponds to the phase difference required to launch a helicon wave in the plasma. In a second embodiment, a chamber shield is made of a conductive material and is coupled to the RF source such that the shield functions as an RF antenna. The shield may be coupled in series to a coil surrounding the shield to increase the resultant flux density.Type: GrantFiled: March 27, 1998Date of Patent: May 8, 2001Assignee: Applied Materials, Inc.Inventors: Ivo J. Raaijmakers, Bradley O. Stimson, John Forster