Abstract: This invention relates to a process for the production of granulates by fluidized bed spray granulation and to a device for this purpose. Liquid starting materials may be converted into granulates by fluidized bed spray granulation. In order to ensure elevated material throughput, numerous nozzles, which are moreover susceptible to plugging and encrustation, must be installed.The disadvantages of known processes may be overcome according to the invention by arranging at least two spray nozzles at least partially directed towards each other in such a manner and the quantity of spray is adjusted in such a manner that their spray jets collide within the fluidized bed and substantially no liquid strike-through occurs onto a surface delimiting the fluidized bed or out of the fluidized bed. The spray jets of two spray nozzles directed towards each other collide frontally or enclose an angle of less than 180.degree.; the angle is preferably between 150.degree. and 180.degree..

Abstract: A process for the production of anionic surfactant granules comprising the steps of:A) Neutralizing an acidic anionic surfactant with a base in a horizontal thin-layer evaporator or thin-layer dryer; andB) Drying the resulting neutralized anionic surfactant in the evaporator or dryer to form surfactant granules; wherein the acidic anionic surfactant and the base taken together have a solids content such that the total quantity of water in the evaporator or dryer at no time exceeds about 15 % by weight and wherein the neutralization and drying are carried out in countercurrent flow with air or an alkaline gas stream at a temperature in the range of from about 120 to about 130.degree. C.

Abstract: A granular detergent product is made by contacting a liquid binder and a solid neutralizing agent. The binder has an acidic component comprising an anionic surfactant acidic precursor and an inorganic acid. The inorganic acid is at least 2.5% by weight of the acidic component. The neutralizing agent and at least some of the binder are granulated in a low-shear granulator.

Abstract: A process for producing a detergent powder or a composition therefore involving partial granulation in a high or low shear granulator followed by granulation in a very low shear mixer, for example a fluid bed is disclosed. The process allows powders to be produced over a wide range of bulk densities without the use of a spray-drying step.

Abstract: A process of forming a granular detergent products, is effected in a gas fluidisation granulator. A fluidised particulate solid material is contacted with a spray of liquid binder. The excess velocity (U.sub.e) of fluidisation gas relative to the mass or volume flux of the spray (q.sub.mliq or q.sub.vliq) when determined at the normalised nozzle-to-bed distance (D.sub.0) is set so that the flux number (FN.sub.m or FN.sub.v) as determined by ##EQU1## (where .rho..sub.p is the particle density) is at a critical value of at least 2 for at least 30% of the process.

Abstract: According to this process, there is used a granulator (10) employing a rotary drum and a fluid bed which is usually employed for producing dense granules for the production of porous granules, For this purpose, the process comprises spraying in this granulator ammonium nitrate in solution and effecting a combined cycle of granulation and drying which causes the formation of pores in the mass of the granules. The drying is then terminated in a drier (20) and the product thereafter is screened and cooled.

Abstract: The present invention is intended for granulation of powder comprising the steps of mixing a powder and a mist of binder by fluidizing air flow, collecting the mixture of the powder and the binder on a filter surface thereby forming a powder layer thereon, peeling off the powder layer from the filter surface thereby crushing the powder layer into pieces, returning the crushed fragments into the fluidizing air flow and mixing them with the mist of binder again, repeating the steps until the desired granule is obtained.

Abstract: There is disclosed a method for detecting clogging of air feed pipes, comprising air feed pipes (15), each having an outlet (13) for jetting air into a granulation section (1), and jetting nozzles (13), each situated at the center of the air outlet of a said air feed pipe for jetting a liquid of a molten raw material (e.g.

Abstract: A process for producing a detergent powder or a composition therefore involving partial granulation in a high or low shear granulator followed by granulation in a very low shear mixer, for example a fluid bed is disclosed. The process allows powders to be produced over a wide range of bulk densities without the use of a spray-drying step.

Abstract: New alkali metal cyanide granulates based on sodium cyanide or potassium cyanide and a method for their preparation are disclosed. Commercially available alkali metal cyanide granulates consist of irregular particles; disadvantages are in particular the tendencies to form dust and to cake. The disclosed alkali metal cyanide granulates demonstrate a reduced tendency to cake and virtually no abrasion. The granulates are characterized by essentially spherical particles with particle diameters in the range 0.1 to 20 mm, a bulk density of more than 600 g/dm.sup.3, an abrasion of less than 1%, and a caking index of at most 4. The granulates can be prepared by fluidized bed spray granulation involving spraying an aqueous solution containing alkali metal cyanide onto alkali metal cyanide nuclei in a fluidized bed and evaporating the water.

Abstract: A process for producing granules from a liquid composition which includes the steps of applying the liquid composition onto solid particles of the same composition circulating in the granulation zone of a granulator, thereby causing particles to grow, discharging a stream of grown particles from the granulation zone, cooling this stream in a cooler, and dividing the stream exiting the cooler, in a size-sorting apparatus, into three streams of grown particles based on size. The stream of desired-sized particles is withdrawn for future use or processing, the stream of undersized particles is returned to the granulation zone and the stream of oversized particles is sent to a size-reducing apparatus for crushing, with the resulting crushed particles recycled back to the cooler located downstream of the granulator and upstream of the size-sorting apparatus.

Abstract: In the production of granules containing anionic surfactants and having a bulk density above 450 g/l by granulation of a surfactant preparation containing a non-surface-active liquid component, the water demand and hence the energy demand for evaporating the water can be reduced if the anionic surfactant in its acid form or a mixture containing one or more anionic surfactants in their acid form and an aqueous alkaline solution are separately treated with a gaseous medium, subsequently sprayed in substantially stoichiometric quantities into the granulation and drying zone either separately or together under a high propellant gas pressure and then granulated and, at the same time, dried, optionally with addition of one or more inorganic or organic solids.

Abstract: The plant for treating powders or granules enables a considerable simplification of the operation of cleaning the filters, and a more efficient centering of the basket container, and includes a tubular casing coupled in a detachable manner to a cover and a base structure. The tubular casing may be rotatable around a horizontal axis on opposing aligned appendages, and the base structure may include a basket resting on a trolley which can be lifted in a guided manner to couple with the bottom edge of the casing. The plant may be used in a wide variety of industrial applications, in particular in the chemical, food and pharmaceutical industries.

Abstract: An apparatus for the preparation of an agglomerated material from a powder or a liquid or both and having a trough-shaped fluidizing path, in the bottom part of which fluidization gas is blown in with an essential component directed towards the center line of the bottom of the path, gives a very advantageous material flow, which makes an effective agglomeration possible under attainment of superior product properties. The apparatus makes it possible by a process according to the invention to carry through the agglomeration with a particularly big powder humidity and a subsequent low re-humidification.

Abstract: A process for producing granules having reduced tackiness by forming granules in a fluidized bed apparatus and then adding a granule stabilizer to the discharge air stream of the apparatus after the granules have emerged from the apparatus.

Abstract: Granules can be prepared from powders of active compounds by the counter-current principle by fluidization in a stream of air and spraying of a solution of adhesive. Dispersions or solutions of active compounds can be granulated in accordance with the invention if the aqueous dispersion or solution is sprayed by the counter-current principle into the gas stream of a fluidizing chamber and is caused to fluidize, the formation of granules being started, in a start-up phase, at 10 to 60% of the maximum gas flow and at only up to 30% of the maximum feed rate of dispersion or solution, and subsequently the feed rate and the gas flow are increased up to the maximum values for the feed rate and the gas flow, and, in the main phase, the formation of granules is continued at maximum gas flow and maximum feed rate.Granules prepared in this way, containing pesticides as the active compounds, can be used as plant protection agents or pest control agents.

Abstract: A process and an apparatus for the continuous crystallization of plastic granules, particularly amorphous plastic granules, in which the granules are introduced into a container and form a granule bed, which is moved downwards by the action of gravity. A hot gas is passed as a primary gas in a countercurrent manner through the granule bed. The granules are kept moving by a stirrer. There is also a gas supply for a secondary gas, which introduces the secondary gas at high speed at several points distributed over the cross-section of the container into the upper area of the granule bed.

Abstract: A process for the production of washing- and cleaning-active surfactant granules containing 60 to 70% by weight of surfactant and having an apparent density above 500 g/l, wherein a formulation containing a non-surface-active liquid component and having a liquid to paste-like form under normal pressure at temperatures of 20.degree. to 40.degree. C. is introduced to a fluidized bed and granulated and, at the same time, totally or partially freed from the non-surface-active liquid compound, optionally with addition of an inorganic or organic solid, and wherein the granules are discharged from the fluidized bed via a grading step by a countercurrent air-stream which is adjusted so that only particles above a predetermined size are removed from the granules.

Abstract: Method and apparatus for producing sodium perborate monohydrate by dehydrating sodium perborate tetrahydrate in a fluid bed with heated air. Contact surfaces are arranged inside the fluid bed whose total area is the same as up to 500 times the area of the approach-flow bottom of the fluid bed. The contact surfaces are advantageously designed as heat exchangers whose surface temperature is adjusted to maintain 90.degree. to 110.degree. C. at the contact surfaces. The method results in a sodium perborate monohydrate with especially high abrasion resistance. In addition, the energy requirement is lower than that provided in the previously known method commonly used in the industry.

Abstract: The average size of ammonium sulfate crystals is increased by passing undersized ammonium sulfate crystals through a multistage apparatus in which the crystals are contacted with an aqueous ammonium sulfate spray in a first heated chamber to increase the average size of the crystals, the enlarged crystals thereafter passing through a second heated chamber to dry the enlarged crystals.

Abstract: Invention relates to a process of producing solid sodium cyanide. The process according to the invention is characterized in that an aqueous sodium cyanide solution (1) of 30 to 45% by mass, containing up to 5% by mass solids, is granulated in two process steps in counterflow with heated air, wherein in the first process step a fluidized bed is produced in a fluidized bed granulator (4) by means of hot air (5) from the second process step, in so doing the air being cooled down to a temperature of 60.degree. to 90.degree. C. a sodium cyanide granulate of 2 to 6 mm being set in a classifying discharge duct (16) and the same being dried to a residual moisture of 1.5 to 4% by mass, wherein in the second process step in a further fluidized bed of a drier (14) the granulate produced is dried through an air current (25) with initial temperatures of 150.degree. to 230.degree. C. to a residual moisture settable at liberty of less than 1.5% by mass and is removed by way of a cellular wheel (20 ).

Abstract: The average size of ammonium sulfate crystals is increased by passing undersized ammonium sulfate crystals through a multistage apparatus in which the crystals are contacted with an aqueous ammonium sulfate spray in a first heated chamber to increase the average size of the crystals, the enlarged crystals thereafter passing through a second heated chamber to dry the enlarged crystals.

Abstract: This invention concerns the addition of fibrous alumina material to a phosphor or phosphor mixture before fluidization as a means of increasing the cohesiveness of the phosphor or phosphor mixture. The increase in cohesiveness can be controlled by varying the concentration of the fiber in the mixture.

Abstract: Process for the manufacture of sodium bicarbonate particles having an ovoid or spherical shape, the process preparing an aqueous solution of sodium bicarbonate, which is supersaturated; circulating the aqueous solution supersaturated in sodium bicarbonate through a bed of crystals in order to cause the bed to be a mobile bed in which the crystals are in continuous motion, and to cause crystallization of the sodium bicarbonate particles and at least partial desupersaturation of the aqueous solution supersaturated in sodium bicarbonate to provide a mother liquor and, withdrawing the sodium bicarbonate particles from the bed.

Abstract: Novel processes for incorporating anti-scalant agents having acidic functionalities in zero-P or low phosphate built powder detergents to provide an automatic dishwashing detergent of improved solubility.

Abstract: Sodium perborate tetrahydrate in the form of virtually spherical and compact agglomerates of unit particles of sodium perborate tetrahydrate with a maximum size not exceeding 30 m, process for its manufacture, its use in the manufacture of sodium perborate monohydrate with high resistance to wear, and the resultant sodium perborate monohydrate.

Abstract: Granule production is based on particle growth in a fluidized bed (4), in which the liquid starting product is sprayed into the fluidized bed and the finished granular particle is discharged from the fluidized bed (4) with classification. The classification is carried out with the aid of a classifying air flow which is divided into individual single flows (6) to each of which is assigned a zigzag classifier module (7, 17) and a spray nozzle (5) or a group of spray nozzles. The course of the classifying process is such that the granular particles which are too small and have not yet reached the desired diameter are thrown back into the fluidized bed (4) by a return shaft (9, 18) seated on each of the zigzag classifier modules (7, 17) in parallel or radial zones without cross-mixing, in which the relatively small particles impinge at a relatively large distance from the return shaft (9, 18) and the large particles, which have already grown close to the discharge size, impinge at a relatively small distance.

Abstract: This invention relates to a process for treatment of pigments and the compositions of treated pigments using the disclosed process. Particularly, this invention describes a process for producing non-dusty, free flowing, granular pigment materials in which the pigment is treated by a water-dissipatable polyester. The treated pigment materials generally exhibit high dispersibility in water and polar solvent systems. Dispersions of such materials provide film-forming characteristics, water-resistivity and excellent adhesion when applied to the skin. The pigment materials prepared by the disclosed process are suitable for incorporation in paints, inks, cosmetic bases, liquid make-ups or other cosmetic preparations such as mascara.

Abstract: Uniform spherical granules are produced from powder raw material without utilizing an agglomerating liquid by repeatedly and alternately compacting a dry powder raw material within a granulating vessel to cohesively form agglomerates of the material and fluidizing the powder material within the vessel to break up and form the agglomerates gradually into a uniform spherical shape.

Abstract: A method of carrying out a chemical reaction in a fluidized bed reactor is provided wherein the reactants include at least one finely sub-divided reactant having a particle size substantially smaller than that of the particles constituting the fluidized bed. The reactor includes a downcomer compartment and a riser compartment operated such that the fluidized bed particles circulate by moving down the downcomer compartment and up the riser compartment. The finely divided solid reactant is introduced, either as such, or in an agglomerated form, into the central or upper region of the fluidized bed in the downcomer compartment such that it becomes entrained in the downwardly moving fluidized bed in the downcomer compartment and moves countercurrent to the fluidizing gas towards the lower end of the riser compartment. The reaction products which may be, or include, fine divided solids are carried out of the top of the reactor from the riser compartment.

Abstract: Process for producing sodium perborate monohydrate by dehydration of sodium perborate tetrahydrate using a current of air which is initially damp in a first phase of dehydration then dry in a second phase of dehydration.The sodium perborate monohydrate obtained can be used in washing powders for textiles. No diagrams.

Abstract: The spray drying of a solution containing hydrogen peroxide and sodium metaborate to obtain primary particles which are immediately conveyed after leaving the drying zone to a granulating device and are then granulated in the presence of free and/or perborate water of crystallization. The granulated materials are dried, if necessary. The generally amorphous primary particles are converted into granulated materials with at least partially crystalline structure and significantly improved shelf life. The work is performed with advantage in a spray dryer with integrated fluid bed or in a compressing granulating device. The method is suitable for preparing perborate granulated materials with an active oxygen content of over 10% by weight, especially perborate monohydrate granular materials with 14 to 16% by weight active oxygen. A rapidly dissolving product is produced with an acceptable apparent weight for ease in packaging.

Abstract: A pelletized form of silica which is sufficiently dust free and highly dispersible in rubber formulations. The pelletized silica is produced by a process which involves pelletizing a mixture of silica and water in an inclined mixer and drying the pelletized product in a fluidized bed dryer.

Abstract: Described is a device for obtaining a foam spray-dried product of predetermined bulk density. Thereto a nozzle for spraying a foaming gas comprising liquid is surrounded by a tube for supplying a gas which comprises dry particulate material to the jet of nozzle.Means are present to accurately control the ratio of solids in the liquid to be sprayed and the dry particulate material.The method described that the dry particulate material is made to collide with the jet from the nozzle and that the speed of the gas transporting said dry material is lower than 20 m/sec and preferably from 6 to 12 m/sec.

Abstract: A method of treating process gases by cooling the process gas in the reactor so as to bring the process gas into contact with fluidized solid particles which are separated from the process gas after treating and mainly recirculated back to the reactor, in which method the process gas to be treated is mixed either simultaneously or at a short interval with both recirculated solid particles and gas, which gas, at least partly, is process gas which has been treated and from which solid particles have been separated after treatment, and in which method at least one of the components, i.e. solid particles or gas, to be mixed with the treated gas is cooler than the process gas to be treated.

Abstract: By agglomeration in a high speed mixer spherical granules having a desired granule size distribution are obtained by supplying the agglomeration liquid by means of an atomizer wheel axially positioned in the high speed mixer and by controlling the quantity and evaporation of said liquid in consideration of the changes occurring with respect to water binding ability of the agglomerates during compaction. An apparatus for carrying out the method includes a mixer bowl with an impeller on a central shaft through the bottom of the bowl and an atomizer with an atomizer wheel with its shaft in alignment with the shaft of the impeller.

Abstract: Low bulk density, soda ash-based, nonphosphate laundry detergents are prepared by (a) loading nonaqueous liquid surfactant onto substantially anhydrous, hydratable soda ash particles, (b) turbulently dispersing the surfactant-loaded particles into an inert gaseous medium while wetting the dispersed particles with an atomized stream of dilute aqueous sodium silicate or with separate atomized streams of water and concentrated aqueous sodium silicate, and (c) recovering the resultant particulate detergent. Preferably, natural soda ash is used in the process, and both nonionic and anionic surfactants are loaded onto the soda ash, in that order.

Abstract: Compositions suitable for use as detergents comprise a non-silicate-coated alkali metal phosphate salt hydrated to at least about 50% by weight, and an inorganic salt selected from alkali metal carbonates and sulfates. The compositions for use in, e.g. dishwashing, have improved solubility and dispersion characteristics.

Abstract: The spray drying of a solution containing hydrogen peroxide and sodium metaborate to obtain primary particles which are immediately conveyed after leaving the drying zone to a granulating device and are then granulated in the presence of free and/or perborate water of crystallization. The granulated materials are dried, if necessary. The generally amorphous primary particles are converted into granulated materials with at least partially crystalline structure and significantly improved shelf life. The work is performed with advantage in a spray dryer with integrated fluid bed or in a compressing granulating device. The method is suitable for preparing perborate granulated materials with over 10% by wt., especially perborate monohydrate granular materials with 14-16% by wt. active oxygen.

Abstract: A process and apparatus for removing hydrogen sulfide from high pressure gas and recovering liquid sulfur, which includes reacting the H.sub.2 S with sulfite ions and an acetic acid-acid salt buffering system in an aqueous stream whereby liquid sulfur is formed, producing an effluent gas stream containing residual H.sub.2 S and an effluent aqueous stream containing the liquid sulfur, extracting the residual H.sub.2 S from the gaseous effluent stream, and using the extracted H.sub.2 S as well as H.sub.2 S recovered from the effluent aqueous stream as a source of sulfite ions for circulation to the reaction step, and as a source for additional liquid and solid sulfur. Apparatus and methods are also disclosed for recovering solid sulfur from a gaseous stream containing gaseous sulfur by contacting the gaseous stream with sulfur particles in a fluidized bed.

Abstract: Particulate material is discharged continuously from fluidized bed reactors by passing the material emerging at the lowest point of the fluidized bed through a zone which is narrower than the fluidized bed and in which a gas stream flows counter-current to the material, the pressure of the gas stream being above the pressure of the fluidized zone.

Abstract: A device for preparing a very homogeneous and finely divided fine-ceramics mass from ceramic raw materials, liquids, aggregates, and similar materials, whereby the starting materials are finely ground, and liquid is added and later partly removed. The starting materials are ground dry or moist and all or some of the starting materials are first allowed to fall free in and through an upright container while being contacted with all or some of the liquid, which is injected in subject to turbulence, and then agglomerated into a granulate.

Abstract: A fluidized bed apparatus comprises a chamber having a perforated floor, a spray nozzle located in the chamber above the perforated floor, whereby material to be granulated is introduced into the chamber in the form of a solution or dispersion, means for passing heated gas upward through said perforated floor, whereby solid particles of said material are formed in said chamber, particle size-reducing means outside of said chamber, whereby particles larger than a first predetermined size are reduced in size, a screw shaft located above said perforated floor and communicating with said size-reducing means, whereby particles are withdrawn from said chamber and conveyed to said size-reducing means, a pipe having one end located downstream of said size-reducing means and its other end communicating with said chamber, and means for generating a flow of air whereby particles smaller than a second predetermined size exiting from said size-reducing means are returned through said pipe to said chamber.

Abstract: The process of the present invention for preparing granules of alumina includes pretreating an alumina powder by admixing with cold water in a mixer at a temperature below room temperature, e.g., such as below about 20.degree. C., to form a pretreated alumina having a pore volume saturated with water and further having a surface area of gel structure, and agglomerating the pretreated alumina in a fluidized bed to form granules. The process is particularly suited to producing activated alumina in macroporous granules. The process in one aspect further includes a cold hopper for cooling alumina powder prior to the pretreating step.

Abstract: A particulate hydrated trisodium phosphate composition useful in heavy duty cleansers has a core and shell structure, the shell being of trisodium phosphate hexahydrate and the core comprising trisodium orthophosphate dodecahydrate and sodium hydroxide. The composition may be made by prilling to form an intermediate body with solid shell and a liquid or solid/liquid core followed by further cooling.

Abstract: In a rotation granulator, the injection nozzles for the powder are provided along the jacket surface of the granulator container over the rotary table, so that the powder will arrive directly in the range of the stronger flow. In order to prevent any interruptions of the operation due to the filter part, a two-chamber system is proposed in which the first and second chambers may be alternately cut off. This makes it possible to operate the installation without any interruption. In order to control the air supply, the rotary table is mounted so that it may be moved up and down, in order that the width of the air gap between the rotary table and the inner wall of the conical casing may be adjusted. Lastly, a device for taking of samples provides a system of sluices or channels by which the low-pressure space of the granulator is actively prevented from being in direct contact with the free atmosphere.

Abstract: A free-flowing granulate of a powder-form or fine-grained component and a liquid component; the granulate containing at least 20% by weight of the liquid component, is prepared by moving the powder-form or fine-grained component in a mixer-granulator, adding the liquid component while mixing until a moist granulate having a particle size of at most 1.5 mm is obtained, subsequently coarsening the granulate thus obtained with an increase in temperature to a particle size of from 0.4 to 4 mm and optionally coating this coarse granulate with another powder-form and/or fine-grained component at 60.degree. to 90.degree. C. The optionally coated granulate is converted by lowering the treatment temperature into a dry-looking, free-flowing, coarse-grained product, which if desired, may be coated with another powder-form and/or fine-grained material. Despite the high percentage of a liquid component, the granulate thus obtained appears as a dry granulate and is free-flowing.

Abstract: The process of the present invention for preparing granules of alumina includes pretreating an alumina powder by admixing with cold water in a mixer at a temperature below room temperature, e.g., such as below about 20.degree. C., to form a pretreated alumina having a pore volume saturated with water and further having a surface area of gel structure, and agglomerating the pretreated alumina in a fluidized bed to form granules sized in the range of about 1-3 mm. The process is particularly suited to producing activated alumina in macroporous granules. The process in one aspect further includes a cold hopper for cooling alumina powder prior to the pretreating step.

Abstract: A method and apparatus for granulation in which particulate feed material is charged into a rotary cylindrical vessel (12) having its axis disposed horizontally, and respective cover plate (16,18) at each end for retaining the feed material, and a treatment gas and a process liquid is passed into the vessel during rotation of the latter.

Abstract: A method for treating the fine-grained spend absorbent (primarily calcium sulfite and calcium sulfate) from a dry flue gas desulfurization process. The absorbent, having a small amount of binder therein, is oxidized in a fluidized bed reactor at a temperature in the range from about 700.degree. C. to about 1000.degree. C. to produce a dry essentially fully oxidized pelletized calcium sulfate product.Calcium sulfate pellets having an average diameter of from about 0.5 mm to 5 mm and containing from about 1% to about 3%, by weight, of binder constituents, are composed of agglomerated calcium sulfate particles having an average diameter of from about 50.mu. to about 100.mu. bound to each other by the binder constituents.