Abstract: A method of predicting the stability of a hydrocarbon process stream is disclosed and claimed. The method includes obtaining samples from one or more process streams and measuring the actual stability and the near infrared spectral absorbance of those samples. A classification model is initially developed to identify sample subsets and correlation model is created using the stability and absorbance data by inserting that data into a mathematical function. Online or offline measurements are then taken from the hydrocarbon process stream, the classification model is used initially to identify the subset and corresponding correlation model is used to predict the stability of the stream.

Abstract: This disclosure relates generally to a sampling device, and more particularly, a sampling device that facilitates spectroscopic measurements with a variable path length and the necessary software controlled algorithms and methods for such a device.

Abstract: A method for performing sub-micron optical spectroscopy, using a heated SPM probe and far-field collection optics is described. The enhanced emission characteristics at a sharp heated tip constitute a highly localized wideband IR source. Thus the IR absorption and emission properties of a sample surface adjacent can be observed and measured in the farfield even though the interaction region is sub-micron in scale. . . . providing spatial resolution mapping of sample composition.

Abstract: A method and apparatus for measuring target gas concentrations in an atmosphere. The method and apparatus emit in the atmosphere a laser beam tuned to a molecular absorption line of a target gas, receive a reflected signal affected by gas absorption of the target gas in the atmosphere, divide and direct the received signal into a first optical path and a second optical path including in one of the paths a correlation gas cell filled with a predetermined concentration of the target gas, detect transmitted signals through the first optical path and the second optical path, and calculate a target gas concentration by comparing a first signal transmitted through the first optical path to a second signal transmitted through the second optical path.

Abstract: A system for the detection and analysis of at least one volatile substance in breath samples of a subject, including at least one source of infrared radiation adapted to the wavelength range of specific absorption peaks of said substances, a plurality of reflecting surfaces of said radiation adapted for collimation onto at least one detector providing a plurality of electrical output signals corresponding to the transmission of said radiation within wavelength intervals corresponding to said absorption peaks, at least one measuring cell including a mechanical support structure defining the position of said source, reflecting surfaces and detector, adapted to the reception and disposal of said breath sample, and exposing it to said radiation, at least one electronic signal processing unit with capacity to analyse said signals with respect to pre-programmed information concerning infrared absorption spectra of said substances.

Abstract: The present invention is a method for modifying any synthetically generated assay of a whole crude oil or a portion of a whole crude, such as a condensate or resid material, by using measured crude properties. These measured properties are used to adjust the synthesized assay values to obtain a more accurate representation of the unknown hydrocarbon material.

Abstract: A method and apparatus for measuring target gas concentrations in an atmosphere. The method and apparatus emit in the atmosphere a laser beam tuned to a molecular absorption line of a target gas, receive a reflected signal affected by gas absorption of the target gas in the atmosphere, divide and direct the received signal into a first optical path and a second optical path including in one of the paths a correlation gas cell filled with a predetermined concentration of the target gas, detect transmitted signals through the first optical path and the second optical path, and calculate a target gas concentration by comparing a first signal transmitted through the first optical path to a second signal transmitted through the second optical path.

Abstract: The present invention relates to a method in which grades of oil are refined according to their object from a feed oil. This method has a solvent extraction process that obtains an extracted oil, and a hydrogenation process that subjects the obtained extracted oil to hydrogenation process in the presence of hydrogen and a catalyst to obtain a hydrorefined oil. The solvent extraction conditions are selected by using the poly-aromatic concentration as an index for calculating the concentration of heptane insoluble components in the residue of the extracted oil obtained by the solvent extraction process that cannot be fractionally distilled.

Abstract: The present invention relates to a sealable cell for measuring a liquid sample comprising a spectroscopic probe and a removable cap that can accommodate at least the head of the probe, wherein the internal wall of the cap comprises one or more grooves which are disposed so as to allow a liquid sample to enter the head of the probe and air to escape from the head of the probe to enable improved spectra to be obtained.

Abstract: The present invention provides, e.g., methods to recycle and/or reduce plastic, non-plastic, or a combination thereof, from a waste stream. The methods of the present invention include contacting the plastic waste with infrared (IR) energy at one or more frequencies and at one or more intensities, over a period of time effective to heat plastic present in the plastic waste.

Abstract: A flow chamber, imaging objective, condenser and imaging light source as part of an optical system includes an oil-immersion objective and high numerical aperture condenser matched to a rectangular flow chamber. The oil-immersion objective and flow chamber include a high index of refraction immersion oil so as to enhance the optical resolution and optical coupling therethrough. The imaging light source generates light which passes through the condenser, the flow chamber and then the objective before being focused onto an imaging camera. Fluorescence excitation passes through the objective to the flow chamber where the oil immersion configuration enhances the focus and collection of the light back through the objective.

Abstract: A number of reagent-free infrared spectroscopic diagnostic and analytical methods have been established previously, making use of dry biofluid films. For example, this approach has successfully measured high concentration analytes of serum and urine. However, a number of low concentration diagnostically relevant analytes presently elude detection by infrared spectroscopy. This is due in part to their relatively low concentration and in part to spectral interference by other strongly absorbing constituents. The applicability of the technique would be broadened substantially if it were possible to separate and concentrate, lower concentration analytes, e.g. serum creatinine and urine proteins, from the obscuring presence of relatively high concentration compounds. The invention disclosed achieves this is through microfluidic sample preconditioning based upon laminar fluid diffusion interfaces.

Abstract: The present invention relates to a method for quantifying the composition of a product, including: irradiating the product with a radiation source in the near infrared range; receiving radiation which is reflected by or transmitted through the product; providing an output signal corresponding to the intensity of the radiation received at a number of different wavelengths; and determining whether or not the product lies within predetermined integrity criteria on the basis of the output signal using a mathematical method. The moving product contains a solution or homogeneous dispersion and the content of at least one substance contained in the dispersion or solution is quantitatively determined on the basis of the output signal. The invention also relates to a device for carrying out this method.

Abstract: A method and apparatus for determining the concentration of organic acids in formation fluids is provided including pumps for pumping fluids from a subterranean formation into the body of a downhole tool and sources for illuminating the flow with infrared radiation to obtain the infrared absorption or a related parameter at one or more wavelengths, and processors for converting the measured absorption into the concentration of the organic acids, using for example a multi-value calibration matrix which relates IR absorption spectral values to concentration measurement under downhole conditions.

Abstract: A method of predicting the stability of a hydrocarbon process stream is disclosed and claimed. The method includes obtaining samples from one or more process streams and measuring the actual stability and the near infrared spectral absorbance of those samples. A classification model is initially developed to identify sample subsets and correlation model is created using the stability and absorbance data by inserting that data into a mathematical function. Online or offline measurements are then taken from the hydrocarbon process stream, the classification model is used initially to identify the subset and corresponding correlation model is used to predict the stability of the stream.

Abstract: To provide an oil type discrimination method and an oil type discriminator capable of accurately discriminating a type of oil even when light-shielding components exist in the oil and of preventing in advance erroneous discrimination of a mixture of oil. There are provided step S1 in which the transmission spectrum of near infrared light is measured, step S2 in which the transmission spectrum is converted into an absorbance spectrum, a first discrimination step S3 in which between gasoline type and non-gasoline type is discriminated by comparing the difference in absorbance between two wavelengths existing in the vicinities of respective attribute wavelengths of predetermined chemical bonds with 0.

Abstract: A method of identifying and determining the concentrations of multiple species in a gas sample, includes providing a spectrophone assembly having a detector chamber, supplying the gas sample to the detector chamber and simultaneously passing a plurality of radiations of different wavelengths into the detector chamber to produce multiple acoustic resonances of different frequencies. Acoustic resonances in the detector chamber are simultaneously sensed to produce corresponding electrical signals, and the electrical signals are analysed to identify the species present in the gas sample and determine the concentration of each specie.

Abstract: Disclosed are pharmaceutical dosage unit manufacturing process control apparatus and methods. These can include acquiring a plurality of multi-pixel images of a flow of pharmaceutical dosage units at different wavelengths along an axis that is perpendicular to a direction of the flow of pharmaceutical dosage units, processing the images acquired in the step of acquiring, and providing an indication about the flow of pharmaceutical dosage units based on the step of processing.

Abstract: The invention relates to a multivariate calibration which can be used when the optical system used for that method does not comprise a multi-channel detector such as a CCD sensor or a line array of photodiodes. An optical system without a multi-channel detector doesn't allow to carry out preprocessing steps. Thus there is the need to carry out these preprocessing steps in another way. It is suggested to partially replace the preprocessing step by a measurement of the optical signal, whereby the measurement comprises transmitting or reflecting the optical signal by an optical element, thereby weighing the optical signal by a spectral weighing function. The advantage of the invention is to teach how such an optical system without a bulky and expensive CCD sensor can be used to carry out a multivariate calibration and preprocessing steps.

Abstract: A method of identifying different brands of peat moss including the steps of separation of the peat and sand by first adding water to the peat and sand mixture to enable the peat to float to the top of the water and the sand to gravitate to the bottom collecting the peat at the surface of the water and drying the peat there after grinding the peat to pass thru a sieve of small mesh then mixing the ground peat with Potassium Bromide (KBr) at a ratio in the neighborhood of 1:20 then grinding said mixture with a mortar and pestle then loading to a sample cell; then loading a ground pure KBr to a reference cell, then scanning and collecting wave spectrums of the references and samples in the range of 4000 to 600 cm?1, collect said spectrums directly from said peat/sand mixtures and dry said peat/sand mixtures in the neighborhood of 105 degrees centigrade for a 24 hour period.

Abstract: An automatic and continuous quantitative analysis method and apparatus capable of accurately and quickly quantifying the concentration of each component of a plurality of known components having close infrared absorption regions and similar infrared absorption curve shapes, included in a measurement sample. As a quantification wave number for each component of the plurality of components, a wave number at a tip of one absorption peak that overlaps as little as possible with absorption peaks in infrared absorption spectra of the other components, selected as a particular absorption peak for the component, is specified.

Abstract: A method of recovering and recycling solvents, comprising, during printing or coating of solvent-recoverable and recyclable printing ink composition comprising solvents, a step of recovering the solvents vaporized in a solvent recovery apparatus, a step of separating the solvents obtained into one or more single solvents and/or one or more azeotropic compositions of two or more solvents by multi-stage distillation, and a step of recycling them as a printing ink raw material and/or dilution solvent raw material.

Abstract: An apparatus for optical sensing of samples includes an optical source, an optical assembly, a sample holder, an objective lens, and a detector. The objective lens collimates light emitted by the sample. Preferably, the optical assembly rotates about an axis, allowing the sensing apparatus to sense results from plural locations on a sample without moving the sample. Moving the sample in a linear direction while rotating the optical assembly allows sensing of an entire sample. Preferably, light from the optical source enters the optical assembly along the axis of rotation. Sensing methods consistent with the invention are also described.

Abstract: A method of inspecting food which can evaluate quality of the food with improved precision includes steps of irradiating probing light having near infrared wavelengths on the food; detecting light diffusively reflected by the food to obtain a reflectance spectrum; obtaining an absorbance spectrum based on the reflectance spectrum; and evaluating the food using the reflectance spectrum and the absorbance spectrum. An apparatus for implementing the method includes: a light source unit to generate probing light which has near infrared wavelengths and illuminates the food; a detector unit to detect light diffusively reflected by the food to obtain a reflectance spectrum of the food; and a processing unit to evaluate the food based on the reflectance spectrum and an absorbance spectrum calculated from the reflectance spectrum.

Abstract: The invention relates to a device for analysing the composition of the contents of a container comprising: transmitter/receiver means (40) of an electromagnetic field having at least several frequencies in a determined frequency range, support means (5) of a container (R) whereof the contents have to be analysed, adapted to ensure precise relative positioning between the transmitter/receiver means (40) and the container (R), means (50) for measuring the complex impedance of the transmitter/receiver means influenced by the load constituted by the container (R) and its contents, representative of the complex dielectric characteristics of the container and its contents, characterised in that it further comprises spectral analysis means of the contents of the container for measuring the absorption of waves by the container and its contents, and means (50) for providing information relative to the nature of the contents of said container (R) as a function of the complex measured impedance and of the absorption m

Abstract: Methods of determining at least one of the degree of skin damage caused by UV light and the degree of physiologically aging of the skin, and methods of estimating at least one of an epidermal skin thickness and a dermal skin thickness by analysis of the near infrared absorption spectrum of skin are disclosed. The near infrared absorption spectrum of skin are analyzed and the obtained analysis result is used for monitoring skin conditions and evaluating cosmetics.

Abstract: A process for measuring the NIR spectrum of a sample using a demountable NIR transmission cell of pathlength 2.5 mm or less, said process comprising: (a) measuring the etalon fringes that arise when NIR light passes through the NIR cell in the absence of a liquid sample, (b) using this to calculate the pathlength of the NIR cell (c) introducing the sample to be analyzed in to the NIR cell, and (d) measuring the NIR spectrum of the sample.

Abstract: An apparatus for optical sensing of samples includes an optical source, an optical assembly, a sample holder, an objective lens, and a detector. The objective lens collimates light emitted by the sample. Preferably, the optical assembly rotates about an axis, allowing the sensing apparatus to sense results from plural locations on a sample without moving the sample. Moving the sample in a linear direction while rotating the optical assembly allows sensing of an entire sample. Preferably, light from the optical source enters the optical assembly along the axis of rotation. Sensing methods consistent with the invention are also described.

Abstract: A system for detection of gas leakage sources. An open-path FTIR detection system is located before the return filter of recirculating air of a factory to detect gas composition of recirculating air and transmits the result to a data server through a communication network. A multi-port extractive FTIR system is located in the factory to collect and detect gas sample of local area air using pipelines located in different areas and transmits the result of gas composition to the data server through the communication network. An IR monitor system obtains the gas composition from the data server through the communication network. A process exhaust management system obtains the gas composition from the IR monitor system through the communication network for the analysis of a gas leakage source.

Abstract: A method and apparatus for optically interrogating a particle comprising obtaining a plurality of optical interrogations from a plurality of orientations relative the particle. In one aspect, the particle is tumbled relative to optical interrogation direction and reflected or transmitted energy is collected and added into a single spectrum that represents a complete spectral composition of the sample.

Abstract: A spectroscopic identification method and system are provided that uses the primary or main spectroscopic features of a source, such as those as arising from chemical functional groups, to describe and distinguish the source. These primary spectroscopic features make up a portion (i.e., are a subset) of the entire spectroscopic data for a particular source but can nevertheless be used as the basis of separating spectra from multiple source. When analyzing spectroscopic data obtained from a sample for one or more sources, the analysis first focuses on the primary spectroscopic features for a source rather than the entire spectra for a source.

Abstract: A sampling device, for example a sampling valve, is disclosed for introduction of samples into an analysis system. The sampling device comprises a turning element provided with a sampling area. The sampling area is configured to retain samples to be analysed. The turning element is arranged for movement between a first position where the sampling area is exposed to material to be sampled for collection of samples and a second position where samples are released for use by the analysis system.

Abstract: A method and apparatus for optically interrogating a particle comprising obtaining a plurality of optical interrogations from a plurality of orientations relative the particle. In one aspect, the particle is tumbled relative to optical interrogation direction and reflected or transmitted energy is collected and weight of one or several seeds is derived.

Abstract: The invention provides a method for determining fuel quality and ethanol content. A mobile fuel analysis apparatus including a vehicle is provided. A database includes near-infrared spectra of standard fuel from a plurality of suppliers to establish correlation between quality parameter and the spectra of the oils. A near-infrared spectrometer is equipped on the vehicle and transported to a fuel distribution point. A near-infrared spectrum of a fuel sample is collected from the fuel distribution point. The collected spectrum is compared to the near-infrared spectra in the database, and converted into corresponding quality parameters.

Abstract: The present invention relates to a device for analyzing the composition of the contents of a receiver comprising: means (40) for emitting/receiving an electromagnetic field at a variable frequency over a determined frequency range, means (22) for supporting a container (R), the contents of which should be analyzed, adapted in order to provide relative accurate positioning between the emitting/receiving means (40) and the container (R), means (50) capable of measuring the complex impedance of the emitting/receiving means influenced by the load formed by the container (R) and its contents, representative of the complex dielectric characteristics of the container and of its contents, and means (50) capable or providing a piece of information related to the measured complex impedance and consequently to the nature of the contents of said container.

Abstract: The present invention provides a method for measuring a lubricant's total basicity by measuring one or more preselected infrared absorption bands of a lubricant and correlating the measured bands to the basicity. Preferably, the measured bands are due to carbonate or sulfate species in the lubricant.

Abstract: A chemical imaging system is provided which uses a near infrared radiation microscope. The system includes an illumination source which illuminates an area of a sample using light in the near infrared radiation wavelength and light in the visible wavelength. A multitude of spatially resolved spectra of transmitted, reflected, emitted or scattered near infrared wavelength radiation light from the illuminated area of the sample is collected and a collimated beam is produced therefrom. A near infrared imaging spectrometer is provided for selecting a near infrared radiation image of the collimated beam. The filtered images are collected by a detector for further processing. The visible wavelength light from the illuminated area of the sample is simultaneously detected providing for the simultaneous visible and near infrared chemical imaging analysis of the sample. Two efficient means for performing three dimensional near infrared chemical imaging microscopy are provided.

Abstract: A laser spectroscopy system can determine the identity and/or quantity of a component of a fluid at a remote location such as downhole in a wellbore or inside a pipeline, particularly at high temperature, e.g. from about 75 to 175° C. The system includes a fiber laser doped with a rare earth element (e.g. Nd3+, Tm3+, Er3+, Th3+, Ho3+, Yb3+, Pr3+) and generates light in a wavelength between about 900 to about 3000 nm. The system may analyze a drilling mud such as an oil based mud or crude oil, and may detect components such as methane, ethane, carbon dioxide, hydrogen sulfide and the like.

Abstract: Light, such as from an analyte-wavelength converter or other optical sensor, is propagated to a detector or transmission structure with an entry surface and with output positions such as in an exit surface. For example, the position of light output by such a detector can be used to detect presence of an analyte such as a biomolecule or chemical. Or relative quantities of photons provided at positions of the exit surface can indicate analyte information such as presence, absence, quantity, or concentration. The detector or transmission structure can have a laterally varying energy transmission function, such as with a constant gradient or a step-like gradient. At the exit surface of the transmission structure, a photosensor array or position sensor can sense transmitted light or output photons, and, in response, circuitry can provide signals indicating the analyte information.

Abstract: The present invention relates to a method for quantifying the composition of a product, including: irradiating the product with a radiation source in the near infrared range; receiving radiation which is reflected by or transmitted through the product; providing an output signal corresponding to the intensity of the radiation received at a number of different wavelengths; and determining whether or not the product lies within predetermined integrity criteria on the basis of the output signal using a mathematical method. The moving product contains a solution or homogeneous dispersion and the content of at least one substance contained in the dispersion or solution is quantitatively determined on the basis of the output signal. The invention also relates to a device for carrying out this method.

Abstract: A mixture ratio detecting apparatus comprises: a light source which emits light including light of an infrared region; a first light detecting unit which detects the light of the infrared region from the light source; a second light detecting unit which detects light of a region having a range different from that of the first light detecting unit; and a control unit which outputs a signal pertaining to a mixture ratio based on signals from the first light detecting unit and the second light detecting unit, and controls the light source, the first light detecting unit, and the second light detecting unit.

Abstract: Disclosed are pharmaceutical dosage unit manufacturing process control apparatus and methods. These can include acquiring a plurality of multi-pixel images of a flow of pharmaceutical dosage units at different wavelengths along an axis that is perpendicular to a direction of the flow of pharmaceutical dosage units, processing the images acquired in the step of acquiring, and providing an indication about the flow of pharmaceutical dosage units based on the step of processing.

Abstract: An improved elemental mercury analyzer utilizes a fluorescence assembly in combination with a fluorescence quenching reduction mechanism to detect the concentration of elemental mercury within an emission gas sample, via fluorescence of the mercury within the gas sample, while minimizing fluorescence quenching of the gas sample. In one arrangement, the analyzer contains the emission gas sample under a vacuum or negative pressure while detecting fluorescence of the elemental mercury within the emission gas sample. By performing fluorescence detection of the emission gas sample at reduced pressure relative to the pressure of the as-sampled emission gas, the analyzer reduces the number of particle collisions within the emission gas sample over a certain period of time. Such collisional deactivation, and/or the addition of oxygen depleted gas such as nitrogen to the gas sample, reduces fluorescence quenching of the emission gas sample, improving accuracy of detection of mercury.

Abstract: A series of optical spectral sensors is based on a combination of solid-state sources (illumination) and detectors housed within an integrated package that includes the interfacing optics and acquisition and processing electronics. The focus is on low cost and the fabrication of the sensor is based on techniques that favor mass production. Materials and components are selected to support low-cost, high volume manufacturing of the sensors. Spectral selectivity is provided by the solid-state source(s) thereby eliminating the need for expensive spectral selection components. The spectral response covers the range from the visible (400 nm) to the mid-infrared (25,000 nm/25.0 ?m), as defined by the availability of suitable low-cost solid-state source devices. A refractive optical system is employed, primarily in an internal reflection mode, allowing a selection of sample handling tools, including, but not restricted to internal reflectance and transmittance.

Abstract: A fire detector and method for generating an alarm signal in response to a fire uses an NDIR sensor to generate a detector signal based upon one or more absorption bands selected from the 15.1? absorption band of CO2, the 6.27? absorption band of H2O and the 4.67? absorption band for CO and generates an alarm signal when a signal processor receives the detector signal and a preselected criterion is met that is indicative of the onset of a fire based upon an analysis of the detector signal using a detection algorithm that relies upon a trending pattern of the detector signal such as recognizing a substantial drop in the detector signal strength. The fire detector has a waveguide sample chamber (which can be of a re-entrant design) with at least one opening covered by a thin filtering membrane and a heat exchanger thermally connected to the sample chamber with at least one opening covered by another thin filtering membrane.

Abstract: Spectroscopic systems and methods are disclosed for determining levels of at least one analyte in blood undergoing hemodialysis. In one aspect, the invention employs Raman spectroscopy to monitor and/or control hemodialysis. In one embodiment, the system uses a laser light directed to circulating blood from a patient undergoing dialysis to make Raman spectral measurements. For example, the laser light can be directed into a segment of the dialysis tubing. The system can utilize unique Raman spectroscopic signature of one or more analytes, e.g., urea, to identify and quantify such analytes against a whole blood background. Based on the spectral response, the concentration of the analytes can be monitored and/or used to control hemodialysis.

Abstract: The invention relates to a mobile remote detection device for accumulations of methane, comprising an emitter device having a light source in order to generate light, the wavelength of said light source being tuned with the spectral signature of methane, whereby the light can be directed onto a measuring field. The detection device also comprises a detector device for detecting backscattered light, and an evaluation device. The aim of the invention is to improve the remote detection device in such a manner that it has a high degree of measuring sensitivity with a compact and stable structure. According to the invention, the light source generates light with a wavelength at which methane is absorbed, wherein the wavelength lies between 3200 nm and 3300 nm, and the light source has an optical parametric oscillator with injection seeding, the oscillator being associated with a pump laser.

Abstract: A method for measuring the amount of an organic substance in a food product with infrared electromagnetic radiation.

Abstract: A method of infrared-optically determining the concentration of at least one analyte in a liquid sample, wherein the infrared absorption of the analyte(s) is measured and compared with a standard, which is characterized in that the liquid sample is sampled with an infrared radiation of high light density, wherein the infrared radiation has a sharp intensity peak at at least one wave length, as well as an arrangement for the infrared-optical transmission determination of the concentration of at least one analyte in a liquid sample, with a sample cuvette flowed through by the sample liquid, the sample cuvette being arranged in the radiation path between a radiation source for providing the infrared radiation and a detector for measuring the infrared absorption induced by the analyte in the sample cuvette.

Abstract: A chemical imaging system is provided which uses a near infrared radiation microscope. The system includes an illumination source which illuminates an area of a sample using light in the near infrared radiation wavelength and light in the visible wavelength. A multitude of spatially resolved spectra of transmitted, reflected, or emitted or scattered near infrared wavelength radiation light from the illuminated area of the sample is collected and a collimated beam is produced therefrom. A near infrared imaging spectrometer is provided for selecting a near infrared radiation images of the collimated beam. The spectrometer comprises a liquid crystal tunable filter. The filtered selected images are collected by a detector for further processing. The visible wavelength light from the illuminated area of the sample is simultaneously detected providing for the simultaneous visible and near infrared chemical imaging analysis of the sample.