Electrolytes For Electrical Devices (e.g., Rectifier, Condenser) Patents (Class 252/62.2)
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Patent number: 8758934Abstract: The present disclosure relates to an electrolyte for a lithium secondary battery, comprising a non-aqueous solvent, a lithium salt and an additive having a perfluoroalkyl group. By including the additive having a specific structure in the electrolyte, the output of the lithium secondary battery can be improved greatly.Type: GrantFiled: December 6, 2013Date of Patent: June 24, 2014Assignee: LG Chem, Ltd.Inventors: Kyoung Ho Ahn, Chul Haeng Lee, Min Jung Kim, Doo Kyung Yang
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Publication number: 20140166921Abstract: Disclosed is a double-center bipyridyl cationic ion liquid prepared by reacting bipyridyl with haloalkane for synthesis of dialkyl bipyridyl halide, and converting the halogen ion in the dialkyl bipyridyl halide to the target anion via an ion-exchange reaction, to give the final target ionic liquid. Also disclosed are an organic electrolyte containing the double-center bipyridyl cationic ion liquid and a preparation method therefor.Type: ApplicationFiled: August 30, 2011Publication date: June 19, 2014Inventors: Mingjie Zhou, Daxi Liu, Yaobing Wang
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Publication number: 20140168858Abstract: Provided is an electroconductive polymer solution containing an electroconductive polymer having high chemical resistance and a high electroconductivity. It is an electroconductive polymer solution, containing an electroconductive polymer having thiophene, aniline, pyrrole, or a derivative thereof as a repeating unit, wherein a dopant or a salt thereof having an amide bond and an anion group is doped into the electroconductive polymer.Type: ApplicationFiled: December 16, 2013Publication date: June 19, 2014Applicant: NEC TOKIN CorporationInventors: Hiroki SATOH, Yasuhisa Sugawara, Hiroyuki Demizu, Yasuhiro Tomioka, Koji Sakata
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Publication number: 20140168857Abstract: The present invention relates to a capacitor comprising an electrode body (1) of an electrode material (2), wherein a dielectric (3) at least partly covers the surface (4) of this electrode material (2) and forms an anode body (5), wherein the anode body (5) is at least partly coated with a solid electrolyte (6) which comprises a conductive polymer, wherein the capacitor comprises at least one polyglycerol; wherein for the ratio of the amount by weight of polyglycerol (Mpg) in the capacitor and the amount by weight of conductive polymer (Mpolymer) in the capacitor: Mpg/Mpolymer>0.15, wherein the polyglycerol contains more than 50 wt. % of a mixture of a tri- and tetraglycerol, based on the total weight of the polyglycerol. The invention also relates to a process for the production of a capacitor, the capacitor obtainable by this process, an electronic circuit, the use of a capacitor and a dispersion.Type: ApplicationFiled: February 24, 2012Publication date: June 19, 2014Applicant: Heraeus Precious Metals GmbH & Co. KGInventors: Armin Sautter, Katrin Asteman, Udo Guntermann, Udo Merker
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Publication number: 20140168855Abstract: The present invention relates to ionic liquids comprising, as cation, a specific phosphonium cation, as anion, a formiate anion, which can be used, alone or as a mixture, to constitute electrolytes for energy storage devices.Type: ApplicationFiled: August 3, 2012Publication date: June 19, 2014Applicants: Universite Francois Rabelais, Commissariat a l'energie atomique et aux ene altInventors: Herve Galiano, Meriem Anouti, Daniel Lemordant, Laure Timperman
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Patent number: 8755169Abstract: An electrochemical capacitor capable of increasing a capacity is proposed. The electrochemical capacitor is a positive electrode and a negative electrode formed over a surface plane of a substrate. Additionally, the electrochemical capacitor has an electrolyte, and the positive electrode and the negative electrode are in contact with a same surface plane of the electrolyte. In other words, the electrochemical capacitor has a positive electrode active material and a negative electrode active material over a surface plane of an electrolyte, a positive electrode current collector which is in contact with the positive electrode active material, and a negative electrode current collector which is in contact with the negative electrode active material. By the aforesaid structure, a capacity of the electrochemical capacitor can be increased.Type: GrantFiled: September 27, 2010Date of Patent: June 17, 2014Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Kazutaka Kuriki, Kiyofumi Ogino, Yumiko Saito
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Publication number: 20140160631Abstract: The present invention relates to an electrolyte of an energy storage device. An electrolyte composition in accordance with an embodiment of the present invention includes an electrolyte salt, a carbonate solvent, and at least one nitrile solvent of acetonitrile and propionitrile.Type: ApplicationFiled: March 15, 2013Publication date: June 12, 2014Applicant: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventors: Jae Hoon Hoon CHOI, Ji Sung CHO, Eun Sil KIM, Se Woong PAENG, Bae Kyun KIM
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Publication number: 20140160549Abstract: The invention relates to a colloidal electrolyte composition comprising a polyelectrolyte selected from one or more cationic polymers, a particulate phase forming a colloidal dispersion, and a binder system able to form a cross-linked network upon curing the electrolyte composition. Also, the invention relates to a method of preparation the colloidal electrolyte composition, to an electrochemical cell and to a method of preparation the electrochemical cell.Type: ApplicationFiled: April 5, 2012Publication date: June 12, 2014Applicant: ACREO SWEDISH ICT ABInventors: Mats Sandberg, Anurak Sawatdee, Jessica Åhlin
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Publication number: 20140158928Abstract: A double-center quaternary ammonium salt ion liquid having the structural formula (I), wherein n=2, 3 or 6, Y? is BF4?, PF6?, (FSO2)2N?, (CF3SO2)2N? or CF3S3?. Also provided is a method for preparing a double-center quaternary ammonium salt ion liquid. The double-center quaternary ammonium salt ion liquid has high stability, and thus an electrolyte containing the double center quaternary ammonium salt ion liquid has a high decomposition voltage.Type: ApplicationFiled: August 30, 2011Publication date: June 12, 2014Inventors: Mingjie Zhou, Daxi Liu, Yaobing Wang
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Patent number: 8747690Abstract: A quaternary ammonium salt of the formula (1), a composition containing the quaternary ammonium salt and an organic solvent, and an electrochemical device using the salt wherein R1 and R2 are both methyl and X? is BF4? or N(CF3SO2)2?.Type: GrantFiled: September 13, 2012Date of Patent: June 10, 2014Assignees: Otsuka Chemical Co., Ltd., Stella Chemifa CorporationInventors: Tetsuo Nishida, Yasutaka Tashiro, Megumi Tornisaki, Masashi Yamamoto, Kazutaka Hirano, Akihiro Nabeshima, Hiroaki Tokuda, Kenji Sato, Takashi Higono
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Publication number: 20140154590Abstract: The invention relates to an electrolyte, comprising at least one lithium salt, a solvent, and at least one compound according to general formula (1). The invention further relates to lithium-based energy stores comprising such an electrolyte.Type: ApplicationFiled: August 2, 2012Publication date: June 5, 2014Applicant: WESTFALISCHE WILHELMS UNIVERSITAT MUNSTERInventors: Elisabeth Kramer, Rene Schmitz, Stefano Passerini, Martin Winter
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Publication number: 20140145105Abstract: Disclosed is a dye-sensitized solar cell that includes an ionic liquid electrolyte, having an additive therein to increase durability and decrease the volatile nature of the conventional electrolytes.Type: ApplicationFiled: March 18, 2013Publication date: May 29, 2014Applicant: HYUNDAI MOTOR COMPANYInventors: Yong Jun Jang, Sol Kim, Sang Hak Kim, Ki Chun Lee, In Woo Song
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Solvents and novel electrolytic compositions having a large range of stability and high conductivity
Patent number: 8737039Abstract: The present invention is concerned with novel polar solvents and novel electrolytic compositions comprising such solvents, and having a high range of stability, as required for applications in the field of electrochemistry. The present solvents have a highly polar amide function, and preferably combine with a salt soluble in the solvent and having an anion with a delocalized charge, and at least one polymer, to form an electrolytic composition.Type: GrantFiled: February 7, 2011Date of Patent: May 27, 2014Assignees: ACEP Inc., Centre National de la Recherche Scientifique, Universite de MontrealInventors: Christophe Michot, Dany Brouillette, Daniel Baril, Jean-Yves Bergeron, Michel Armand -
Patent number: 8735004Abstract: An overcharge inhibitor is provided which increases an internal resistance of a battery, being electropolymerized by reaction with a positive electrode at a high potential in overcharging. The overcharge inhibitor is produced by using a polymer containing a polymerizable monomer as a repeating unit. The polymerizable monomer has a functional group that is electropolymerized at a potential of 4.3 to 5.5 V based on a lithium metal reference.Type: GrantFiled: August 18, 2010Date of Patent: May 27, 2014Assignee: Hitachi, Ltd.Inventors: Jinbao Zhao, Norio Iwayasu, Yuki Okuda, Hidetoshi Honbo
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Patent number: 8734668Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.Type: GrantFiled: October 5, 2012Date of Patent: May 27, 2014Assignee: Asahi Kasei Kabushiki KaishaInventors: Vinay Bhat, Gang Cheng, Steven Kaye, Bin Li, Risa Olugbile, Jen-Hsien Yang
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Patent number: 8734667Abstract: This disclosure relates to an electrolyte for an aluminum electrolytic capacitor. An electrolyte according to one embodiment includes a protic fluid and a high dielectric co-solvent or a dipolar aprotic. According to various embodiments, the electrolyte is pH buffered to less than approximately 6.8 pH. The protic fluid includes ethylene glycol and the high dielectric co-solvent includes N-methylformamide, in various embodiments. The disclosure further relates to methods for manufacturing an electrolyte, and capacitors and implantable devices including a supporting electrolyte selected for optimal cation size and charge and anion solubility.Type: GrantFiled: March 8, 2011Date of Patent: May 27, 2014Assignee: Cardiac Pacemakers, Inc.Inventor: Ronald A. Dombro, Jr.
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Patent number: 8730649Abstract: A method for decreasing resistivity of an electrolyte for an electric double-layer capacitor is provided. In this method, an aqueous electrolyte solution comprising LiNO3 and LiOH in a molar ratio of 1:9 to 9:1 is prepared first, and then purged with nitrogen or oxygen. An electric double-layer capacitor having the gas-purging aqueous electrolyte solution above is also provided.Type: GrantFiled: December 30, 2011Date of Patent: May 20, 2014Assignee: Taiwan Textile Research InstituteInventors: Wen-Hsien Ho, Chung-Bo Tsai, Shao-Wei Chieh, Po-Chou Chen, Chia-Hui Lee
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Patent number: 8722255Abstract: A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.Type: GrantFiled: March 27, 2012Date of Patent: May 13, 2014Assignee: Ube Industries, Ltd.Inventors: Koji Abe, Kazuhiro Miyoshi, Takaaki Kuwata
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Publication number: 20140124694Abstract: A method of forming an electrolyte solution involves combining ammonium tetrafluoroborate and a quaternary ammonium halide in a liquid solvent to form a quaternary ammonium tetrafluoroborate and an ammonium halide. The ammonium halide precipitate is removed from the solvent to form an electrolyte solution. The reactants can be added step-wise to the solvent, and the method can include using a stoichiometric excess of the ammonium tetrafluoroborate to form a substantially halide ion-free electrolyte solution.Type: ApplicationFiled: January 13, 2014Publication date: May 8, 2014Applicant: Coming IncorporatedInventor: Kishor Purushottam Gadkaree
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Publication number: 20140127594Abstract: There is provided an electrolyte solution including a solvent formed from a sulfone, and a magnesium salt dissolved in the solvent.Type: ApplicationFiled: September 23, 2013Publication date: May 8, 2014Applicant: Sony CorporationInventors: Yuri Nakayama, Hideki Kawasaki, Hiroyuki Morioka
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Patent number: 8715866Abstract: An electrolyte includes an eutectic mixture composed of (a) a hetero cyclic compound having a predetermined chemistry figure, and (b) an ionizable lithium salt. An electrochemical device having the electrolyte. The eutectic mixture included in the electrolyte exhibits inherent characteristics of an eutectic mixture such as excellent thermal stability and excellent chemical stability, thereby improving the problems such as evaporation, ignition and side reaction of an electrolyte caused by the usage of existing organic solvents.Type: GrantFiled: December 30, 2008Date of Patent: May 6, 2014Assignee: LG Chem, Ltd.Inventors: Byoung-Bae Lee, Jae-Seung Oh, Ji-Won Park, Shin-Jung Choi, Jae-Duk Park, Dong-Su Kim, Hyo-Jin Lee
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Patent number: 8709273Abstract: An amorphous carbon having sulfonate group introduced therein is provided which is characterized in that chemical shifts of a condensed aromatic carbon 6-membered ring and a condensed aromatic carbon 6-membered ring having sulfonate group bonded thereto are detected in a 13C nuclear magnetic resonance spectrum and that at least a diffraction peak of carbon (002) face whose half-value width (2?) is in the range of 5 to 30° is detected in powder X-ray diffractometry, and which exhibits proton conductivity. This sulfonated amorphous carbon is very useful as a proton conductor material or solid acid catalyst because it excels in proton conductivity, acid catalytic activity, thermal stability and chemical stability and can be produced at low cost.Type: GrantFiled: September 8, 2004Date of Patent: April 29, 2014Assignee: Tokyo Institute of TechnologyInventors: Michikazu Hara, Kazunari Domen
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Patent number: 8703345Abstract: Disclosed is an electrolyte. The electrolyte includes an amide compound and an ionizable lithium salt. The amide compound has a specific structure in which an amine group is substituted with at least one alkoxyalkyl group and at least one halogen atom is present. The electrolyte has good thermal and chemical stability, a low resistance and a high ionic conductivity. In addition, the electrolyte has a high upper limit of electrochemical window due to its improved oxidation stability. Therefore, the electrolyte can be useful for the fabrication of an electrochemical device. Further disclosed is an electrochemical device including the electrolyte.Type: GrantFiled: September 23, 2011Date of Patent: April 22, 2014Assignee: LG Chem, Ltd.Inventors: Byoung-Bae Lee, Jae-Seung Oh, Sang-Hyun Lee, Kwon-Young Choi, Dong-Su Kim, Yeon-Suk Hong, Hyo-Jin Lee
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Patent number: 8703344Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.Type: GrantFiled: August 30, 2012Date of Patent: April 22, 2014Assignee: Asahi Kasei Kabushiki KaishaInventors: Vinay V. Bhat, Gang Cheng, Steven S. Kaye, Bin Li, Risa Olugbile, Jen-Hsien Yang
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Publication number: 20140103245Abstract: A method of forming an electrolyte solution involves combining ammonium tetrafluoroborate and a quaternary ammonium halide in a liquid solvent to form a quaternary ammonium tetrafluoroborate and an ammonium halide. The ammonium halide precipitate is removed from the solvent to form an electrolyte solution. The reactants can be added step-wise to the solvent, and the method can include using a stoichiometric excess of the ammonium tetrafluoroborate to form a substantially halide ion-free electrolyte solution. Filtration can be done at low temperatures to reduce the amount of excess bromide in the resulting electrolyte.Type: ApplicationFiled: December 20, 2013Publication date: April 17, 2014Inventors: Kishor Purushottam Gadkaree, Satyanarayana Kodali
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Patent number: 8697293Abstract: A non-aqueous electrolyte solution for a lithium secondary battery includes a lithium salt and an organic solvent. Based on 100 parts by weight of the non-aqueous electrolyte solution, the non-aqueous electrolyte solution includes 1 to 5 parts by weight of sultone compound having a carbon-carbon unsaturated bond in a cyclic structure; 1 to 5 parts by weight of cyclic carbonate compound with a vinyl group; 5 to 10 parts by weight of cyclic carbonate compound that is substituted with halogen; and 1 to 5 parts by weight of dinitrile compound. This non-aqueous electrolyte solution improves stability of a SEI film formed on a surface of an anode of a lithium secondary battery and thus improves normal temperature cycle performance and high temperature cycle performance.Type: GrantFiled: April 24, 2009Date of Patent: April 15, 2014Assignee: LG Chem, Ltd.Inventors: So-Young Park, Hee-Gyoung Kang, Joon-Sung Bae
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Patent number: 8697295Abstract: A nonaqueous electrolytic solution that can provide a high energy density nonaqueous electrolyte secondary battery having a high capacity, excellent storage characteristics, and excellent cycle characteristics and suppressing the decomposition of an electrolytic solution and the deterioration thereof when used in a high-temperature environment includes an electrolyte, a nonaqueous solvent, and a compound represented by general formula (1): wherein R1, R2, and R3 each independently represent a hydrogen atom, a cyano group, or an optionally halogen atom-substituted hydrocarbon group having 1 to 10 carbon atoms, with the proviso that R1 and R2 do not simultaneously represent hydrogen atoms.Type: GrantFiled: May 21, 2012Date of Patent: April 15, 2014Assignee: Mitsubishi Chemical CorporationInventors: Takashi Fujii, Youichi Ohashi, Shinichi Kinoshita
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Publication number: 20140098466Abstract: An electrolyte system suitable for use in an energy storage device (such as a supercapacitor), and energy devices which comprising the electrolyte system which is made up of an ionic liquid, such as Li or EMI TFSI and a stabilising amount of a stabilising additive. The stabilising additive preferably contains nitrile and or aromatic (benzene) groups, and may be advantageously benzonitrile, cinnamonitrile or succinonitrile. The stabilising additive stabilises the energy storage device against ESR rise and/or capacitance loss but does not adversely affect other performance characteristics of the ionic liquid.Type: ApplicationFiled: May 7, 2012Publication date: April 10, 2014Applicant: CAP-XX LIMITEDInventors: Alexander Bilyk, Phillip Brett Aitchison, Allan Godsk Larsen, John Chi Hung Nguyen, Nicole van der Laak
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Publication number: 20140097375Abstract: The present disclosure is directed to an elastic polymer having characteristics of swelling by absorbing liquid and, and applications of preparation of gel electrolyte and absorbing the liquid by the polymer. The polymer is obtained by binding a poly(oxyethlene) L-NHm with a compound R being one elected from the group consisting of an acid, an anhydride and a combination thereof.Type: ApplicationFiled: April 9, 2013Publication date: April 10, 2014Applicant: National Taiwan UniversityInventors: KUO-CHUNG HO, Jiang-Jen Lin, Rui-Xuan Dong, Chung-Te Liu, Sheng-Yen Shen, Hsin-Wei Chen, Po-Ta Shih
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Publication number: 20140098467Abstract: An electroconductive polymer having high electroconductivity, an electroconductive polymer aqueous solution, and an electroconductive polymer film are provided. Further, a solid electrolytic capacitor having a reduced ESR and a method for producing the same are provided. An electroconductive polymer according to an exemplary embodiment of the invention contains a monomolecular organic acid having one anion group and one or more hydrophilic group.Type: ApplicationFiled: May 30, 2012Publication date: April 10, 2014Inventors: Yasuhisa Sugawara, Tomoki Nobuta, Yuji Yoshida, Satoshi Suzuki, Yasuhiro Tomioka
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Publication number: 20140097376Abstract: The present invention refers to using the principal of a room temperature molten ionic liquid, to an electrolyte, to devices comprising the ionic liquid co-melting, and to the preparation of a room temperature ionic liquid via various physical and chemical methods. The room temperature molten ionic liquid comprises at least two component salts, at least one of which is not molten at room temperature, but, if combined with another salt, is in the molten state at room temperature.Type: ApplicationFiled: December 12, 2013Publication date: April 10, 2014Applicant: Ecole Polytechnique Federale de Lausanne (EPFL)Inventors: Jing Zhang, Chengcheng Xi, Yiming Cao, Feifei Gao, Peng Wang, Shaik Mohammad Zakeeruddin, Michael Graetzel
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Publication number: 20140092529Abstract: Provided are an electroconductive polymer solution in which the carbon material has excellent dispersibility, an electroconductive polymer material which has a high electroconductivity and which can be produced by a simple method, and a solid electrolytic capacitor and a method for producing the same which has a low ESR without increasing a leakage current. An electroconductive polymer solution according to an exemplary embodiment of the invention contains an electroconductive polymer, a polysulfonic acid or a salt thereof which functions as a dopant to the electroconductive polymer, a mixture of a polyacid and a carbon material, and a solvent.Type: ApplicationFiled: February 27, 2012Publication date: April 3, 2014Applicant: NEC TOKIN CORPORATIONInventors: Tomoki Nobuta, Yasuhisa Sugawara, Yuji Yoshida, Satoshi Suzuki, Yasuhiro Tomioka
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Patent number: 8685562Abstract: A nonaqueous electrolytic solution that can provide a battery that is low in gas generation, has a large capacity, and is excellent in storage characteristics and cycle characteristics. The solution contains an electrolyte, a nonaqueous solvent dissolving the electrolyte, 0.001 vol % to 5 vol % of a compound represented by Formula (1), and further contains at least one compound selected from the group consisting of cyclic carbonate compounds having carbon-carbon unsaturated bonds, cyclic carbonate compounds having fluorine atoms, monofluorophosphates, and difluorophosphates. In Formula (1), R1 to R3 each independently represent an alkyl group having 1 to 12 carbon atoms, optionally substituted by a halogen atom; and n is an integer of 0 to 6.Type: GrantFiled: February 15, 2012Date of Patent: April 1, 2014Assignee: Mitsubishi Chemical CorporationInventors: Minoru Kotato, Shinichi Kinoshita
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Patent number: 8685572Abstract: An organic electrolyte including a lithium salt; an organic solvent; and a flavone-based or flavanon-based compound, and a lithium battery including the organic electrolyte.Type: GrantFiled: February 2, 2011Date of Patent: April 1, 2014Assignee: Samsung SDI Co., Ltd.Inventors: Dong-joon Lee, Young-gyoon Ryu, Seok-soo Lee, Dong-min Im
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Patent number: 8684576Abstract: The present invention provides a solid electrolytic capacitor having a low ESR, excellent heat resistance, and reliability used under a high temperature condition. On the dielectric layer of the capacitor element, 2-alkyl-2,3-dihydro-thieno[3,4-b][1,4]dioxine monomer is subject to oxidation polymerization to provide a first conductive polymer layer. Then, 2,3-dihydro-thieno[3,4-b][1,4]dioxine or a monomer mixture of 2,3-dihydro-thieno[3,4-b][1,4]dioxine and 2-alkyl-2,3-dihydro-thieno[3,4-b][1,4]dioxine is subject to oxidation polymerization to provide a second conductive polymer layer. The formation of the first conductive polymer layer and the second conductive polymer layer is alternatively repeated. The first conductive polymer and the second conductive polymer serve as a solid electrolyte to provide a solid electrolytic.Type: GrantFiled: November 22, 2010Date of Patent: April 1, 2014Assignee: Tayca CorporationInventors: Ryosuke Sugihara, Yuhei Tsurumoto, Kazuto Fujihara
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Publication number: 20140085774Abstract: An electrolyte includes an organic solvent, a solute and a compound represented by chemical formula [1], both contained in the organic solvent. R1 and R2 represent a methyl group or an ethyl group; R3 represents a functional group having a straight chain including three or more carbon atoms and a hydroxyl group bonded to a terminal carbon; C represents a carbon atom; H represents a hydrogen atom; 0 represents an oxygen atom; and N represents a nitrogen atom.Type: ApplicationFiled: June 25, 2012Publication date: March 27, 2014Inventors: Seiji Takagi, Hideki Shimamoto, Hiroyuki Matsumura, Nao Matsumura
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Publication number: 20140084203Abstract: An object of the present invention is to provide a method for producing a material for at least any one of an energy device and an electrical storage device, the method being able to form a dense nanostructure, and the material for at least any one of an energy device and an electrical storage device. Disclosed is a method for producing a material for at least any one of an energy device and an electrical storage device, the method including the steps of: treating a raw material including a vitrifiable element with alkali, and solidifying the alkali-treated raw material in a temperature condition of 15 to 30° C.Type: ApplicationFiled: May 16, 2012Publication date: March 27, 2014Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, NATIONAL UNIVERSITY CORPORATION NAGOYA INSTITUTE OF TECHNOLOGYInventors: Masayoshi Fuji, Takashi Shirai, Yuki Matsushita
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Patent number: 8673399Abstract: Titania is a semiconductor and photocatalyst that is also chemically inert. With its bandgap of 3.2 and greater, to activate the photocatalytic property of titania requires light of about 390 nm wavelength, which is in the ultra-violet, where sunlight is very low in intensity. A method and devices are disclosed wherein stress is induced and managed in a thin film of titania in order to shift and lower the bandgap energy into the longer wavelengths that are more abundant in sunlight. Applications of this stress-induced bandgap-shifted titania photocatalytic surface include photoelectrolysis for production of hydrogen gas from water, photovoltaics for production of electricity, and photocatalysis for detoxification and disinfection.Type: GrantFiled: June 10, 2008Date of Patent: March 18, 2014Assignee: Nanoptek CorporationInventors: John M. Guerra, Lukas M. Thulin, Amol N. Chandekar
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Patent number: 8673504Abstract: The objective of the present invention is to prevent deterioration and expanding of anode active material and to improve charge-discharge cycle characteristics in a non-aqueous electrolyte secondary battery comprising an anode of which current collector has thereon a thin layer of an anode active material containing a metal. To solve this problem, in a non-aqueous electrolyte secondary battery wherein a thin layer of anode active material containing a metal which absorbs and discharges lithium is formed on a current collector and the thin layer of the anode active material is divided into columns by a gap formed along the thickness thereof, a compound represented by the following formula is contained in the non-aqueous electrolyte. A-N?C?O In the above formula, A represents an element or a group other than hydrogen.Type: GrantFiled: May 3, 2012Date of Patent: March 18, 2014Assignees: SANYO Electric Co., Ltd., Mitsubishi Chemical CorporationInventors: Keiji Saisho, Hidekazu Yamamoto, Masahiro Takehara
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Patent number: 8675347Abstract: Disclosed are an aluminum electrolytic capacitor having low impedance properties and a long service life, and an electrolytic solution which enables to give such capacitor. The electrolytic solution contains a solvent containing water, a phosphorus oxoacid ion-generating compound which can generate a phosphorus oxoacid ion in an aqueous solution, and a chelating agent which can coordinate with aluminum to form an aqueous aluminum chelate complex. The electrolytic solution further contains a compound selected from the group consisting of azelaic acid and an azelaic acid salt, and a compound selected from the group consisting of formic acid, a formic acid salt, adipic acid, an adipic acid salt, glutaric acid and a glutaric acid salt. The content of azelaic acid and/or the azelaic acid salt is at least 0.03 moles per kg of the solvent.Type: GrantFiled: July 11, 2009Date of Patent: March 18, 2014Assignee: Nippon Chemi-Con CorporationInventors: Masao Sakakura, Junichi Kawakami, Kazuma Okura, Shingo Takeuchi, Masashi Ozawa, Kenji Tamamitsu
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Patent number: 8668838Abstract: The present invention provides an electric double layer capacitor that has a high withstand voltage, is more resistant to degradation, and also has good cycle characteristics. The present invention relates to an electrolytic solution for an electric double layer capacitor, comprising: (I) a solvent for dissolving an electrolyte salt; and (II) an electrolyte salt, wherein the solvent (I) for dissolving an electrolyte salt includes propylene carbonate and at least one selected from the group consisting of a fluorine-containing chain carbonate and a fluorine-containing chain ether. The present invention also relates to an electric double layer capacitor comprising the electrolytic solution.Type: GrantFiled: October 26, 2009Date of Patent: March 11, 2014Assignee: Daikin Industries, Ltd.Inventors: Kenzou Takahashi, Meiten Koh, Mai Koyama
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Patent number: 8663492Abstract: A method of forming an electrolyte solution involves combining ammonium tetrafluoroborate and a quaternary ammonium halide in a liquid solvent to form a quaternary ammonium tetrafluoroborate and an ammonium halide. The ammonium halide precipitate is removed from the solvent to form an electrolyte solution. The reactants can be added step-wise to the solvent, and the method can include using a stoichiometric excess of the ammonium tetrafluoroborate to form a substantially halide ion-free electrolyte solution.Type: GrantFiled: November 20, 2012Date of Patent: March 4, 2014Assignee: Corning IncorporatedInventor: Kishor Purushottam Gadkaree
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Patent number: 8652682Abstract: A battery capable of improving the cycle characteristics is provided. The battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution is impregnated in a separator provided between the cathode and the anode. The electrolytic solution contains an ionic compound such as (2,2-difluoromalonate oxalate)lithium borate and [bis(3,3,3-trifluoromethyl)glycolate oxalate]lithium borate as an electrolyte salt. In the ionic compound, an anion has an asymmetric structure, and a ligand having an oxygen chelate structure in the anion has a halogen as an element. In the battery, the chemical stability of the electrolytic solution is improved, compared to a battery in which the electrolytic solution contains bis(oxalate)lithium borate or the like as an electrolyte salt.Type: GrantFiled: October 15, 2007Date of Patent: February 18, 2014Assignee: Sony CorporationInventors: Masayuki Ihara, Hiroyuki Yamaguchi, Tadahiko Kubota
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Publication number: 20140043731Abstract: A conductive composition according to the present invention contains a conductive polymer (A) having a sulfonic acid group and/or a carboxyl group; and an alkali metal hydroxide and/or an alkaline earth metal hydroxide (B). In such a conductive composition, the amount of the hydroxide (B) is set at 0.2˜0.65 mol per 1 mol of a repeating unit that contains a sulfonic acid group and/or a carboxyl group in the conductive polymer (A).Type: ApplicationFiled: April 20, 2012Publication date: February 13, 2014Applicant: Mitsubishi Rayon Co., Ltd.Inventors: Kohei Yamada, Takahiro Sakai, Masashi Uzawa, Youko Sasata, Akira Yamazaki
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Publication number: 20140034869Abstract: Replacing liquid electrolytes with solid or quasi-solid electrolytes facilitates the production of photovoltaic cells using continuous manufacturing processes, such as roll-to-roll or web processes, thus creating inexpensive, lightweight photovoltaic cells using flexible plastic substrates.Type: ApplicationFiled: October 4, 2013Publication date: February 6, 2014Applicant: Merck Patent GmbHInventors: Kethinni Chittibabu, Savvas Hadjikyriacou
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Publication number: 20140030610Abstract: The present invention provides a nonaqueous electrolytic solution capable of improving electrochemical characteristics at high temperatures, which comprises at least one organic phosphorus compound represented by the following general formula (I), an energy storage device using the nonaqueous electrolytic solution, and a specific organic phosphorus compound. (In the formula, R1 and R2 each independently represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an alkoxy group, a cycloalkoxy group, an alkenyloxy group, an alkynyloxy group, a halogenoalkyl group, a halogenoalkoxy group, an aryl group, or an aryloxy group; R3 and R4 each independently represent a hydrogen atom, a halogen atom, or an alkyl group; m is an integer of from 1 to 4, n is 0 or 1, q is 1 or 2. When q is 1 and n is 0, X represents an alkoxy group, an alkynyloxy group, an alkyloxyalkoxy group, an aryloxy group, etc.Type: ApplicationFiled: April 12, 2012Publication date: January 30, 2014Applicant: UBE Industries, LtdInventors: Koji Abe, Kei Shimamoto
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Publication number: 20140029165Abstract: Provided is an electric double-layer capacitor excellent in long-term reliability, particularly in suppressing its expansion, and a non-aqueous electrolytic solution for the electric double-layer capacitor.Type: ApplicationFiled: March 29, 2012Publication date: January 30, 2014Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Kenzou Takahashi, Meiten Koh, Hideo Sakata, Emi Yamamoto
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Publication number: 20140027663Abstract: An electrolyte mixture for an electrolytic capacitor is provided. The electrolyte mixture includes a conjugated polymer, a polyether and a nitrogen-containing compound, or includes the conjugated polymer, the polyether and a nitrogen-containing polymer, or includes the conjugated polymer and a polyether with nitrogen-containing functional groups. The electrolyte mixture provides a very high static capacitance for an electrolytic capacitor having the same.Type: ApplicationFiled: July 26, 2013Publication date: January 30, 2014Applicant: Industrial Technology Research InstituteInventors: Yi-Chang Du, Li-Duan Tsai, Hung-Chung Chien
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Publication number: 20140029166Abstract: An electrolyte mixture for electrolytic capacitor is disclosed. The electrolyte mixture includes a conductive polymer and a nitrogen-containing polymer. The nitrogen-containing polymer includes a cyclic nitrogen-containing polymer, a polymer with primary amine group, a polymer with secondary amine group, a polymer with tertiary amine group, a polymer with quaternary ammonium group, or a combination thereof.Type: ApplicationFiled: July 26, 2013Publication date: January 30, 2014Applicant: Industrial Technology Research InstituteInventors: Hung-Chung Chien, Li-Duan Tsai, Yi-Chang Du
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Publication number: 20140026950Abstract: Provided are a gel electrolyte and a dye-sensitized solar cell with the same. The dye-sensitized solar cell may include a first electrode, a second electrode, and an electrolyte interposed between the first and second electrodes. The electrolyte may include a solvent, a hole conductor having an ester functional group, and a polymer material transforming the solvent from a liquid state to a gel state.Type: ApplicationFiled: January 10, 2013Publication date: January 30, 2014Applicant: Electronics and Telecommunications Research InstituteInventor: Electronics and Telecommunications Research Institute