Abstract: Provided are a piezoelectric ceramic and a piezoelectric device having a larger piezoelectric strain constant and capable of being fired at a lower temperature. A main component of PbA[(Mg1/3Nb2/3)a(Zn1/3Nb2/3)bTicZrd]O3 (a+b+c+d=1, 0.99≦A≦1.01, 0.15≦a+b≦0.5, 0.05≦b≦0.25, 0.2≦c≦0.5, 0.15≦d≦0.6) and 0.01 mass % to 0.8 mass % inclusive of at least one kind selected from the group consisting of Fe, Co, Ni and Cu in the form of oxide per 1 mol of the main component as a first sub-component are comprised. Thereby, a larger piezoelectric strain constant can be obtained, and a firing temperature can be reduced. In the main component, a part of Pb may be replaced with at least one kind selected from the group consisting of Ca, Sr and Ba. Further, as a second sub-component, 0.05 mass % to 1.0 mass % inclusive of at least one kind selected from the group consisting of Sb, Nb and Ta in the form of oxide per 1 mol of the main component may be comprised.

Abstract: A ceramic material having piezoelectric characteristics that can be sintered at low temperature and is suited to various piezoelectric devices. The ceramic material is denoted by the general formula ABOd comprised primarily of Pb, Zr, and Ti; in which A denotes (Pb1-aM1a-b) and B denotes [(M21/3Nb2/3-c)&agr;Zr&bgr;Ti&ggr;] or the formula PbxM31-x[(M41/3Nb2/3)e(Co1/3Nb2/3)f(Zn1/3Nb2/3)gZrhTii]O3. The ceramic material can be prepared by sintering at a temperature of 950° C. or below and has good piezoelectric characteristics, and in particular, good longitudinal elongation (d33) and a low dielectric loss factor (tan &dgr;) even at a high Curie temperature Tc; as well as the ceramic material has a good electromechanical coupling factor (Kp).

Abstract: The invention relates to piezoelectric ceramic materials consisting of lead zirconate titanate and (1) at least one of an alkaline earth pyrochlore and an alkali metal perovskite having the formula AB5+O3, where B is Nb, Ta, or Sb; or (2) an alkaline earth alkali metal perovskite having the formula A(T1+0.25B5+0.75)O3, where A is the alkaline earth metal, T is the alkali metal, and B is Nb, Ta, or Sb. The materials are characterized by excellent heat and time stability.

Abstract: The invention provides a piezoelectric ceramic material comprising a Bi3TiNbO9 crystal and/or an MBi2Nb2O9 crystal which are each a bismuth layer compound, where M represents at least one element selected from Sr, Ba and Ca. The ceramic material contains Bi, Ti, M and Nb as main component elements. The molar ratio as oxides of the main component elements is given by (Bi3−xMx)z (Nb1+yTi1−y)O9 provided that 0<x, y≦0.8 and 0.95≦z≦1.05. When the molar ratio of Ba/(M+Bi) is given by xB/3 and the molar ratio of Ca/(M+Bi) is given by xC/3, it is required that 0≦xB≦0.5 and 0≦xC<0.4. This piezoelectric ceramic material, free from any lead whatsoever, has a sufficiently high Curie point, and exhibits ever more improved piezoelectric properties.

Abstract: Disclosed is a piezoelectric ceramic composition comprising a PZT piezoelectric composition, a B-site of which is substituted with a certain material, and chromium oxide, and a piezoelectric device using the piezoelectric ceramic composition. The piezoelectric ceramic composition has good heat resistance and frequency stability, and reduces a leakage current. There is provided the piezoelectric ceramic composition comprising a main component expressed by Pb[(Co1/2W1/2)xTi1−x−yZry]O3 (wherein, 0.001≦x≦0.04, and 0.35 ≦y≦0.55), Cr2O3 in an amount of 0.01 to 2 wt %, MnO2 in an amount of 0.1 to 0.5 wt %, and an additive in an amount of 0.01 to 2.0 wt %, based on the total weight of the piezoelectric ceramic composition, in which the additive is selected from the group consisting of CoO, MgO, ZnO, Al2O3, Fe2O3, Sb2O3, SnO2, CeO2, Nb2O5, V2O5 and WO3, and mixtures thereof.

Abstract: The invention comprises ferroelectric vapor deposition targets and to methods of making ferroelectric vapor deposition targets. In one implementation, a ferroelectric physical vapor deposition target has a predominate grain size of less than or equal to 1.0 micron, and has a density of at least 95% of maximum theoretical density. In one implementation, a method of making a ferroelectric physical vapor deposition target includes positioning a prereacted ferroelectric powder within a hot press cavity. The prereacted ferroelectric powder predominately includes individual prereacted ferroelectric particles having a maximum straight linear dimension of less than or equal to about 100 nanometers. The prereacted ferroelectric powder is hot pressed within the cavity into a physical vapor deposition target of desired shape having a density of at least about 95% of maximum theoretical density and a predominate maximum grain size which is less than or equal to 1.0 micron.

Abstract: Mechanochemical fabrication produces electroceramics using oxides as starting materials. The fabrication starts with mixing industrial ceramic oxide powders. Electroceramic phases are formed by reacting the oxide powders in a mechanochemical chamber, which is a wear-resistant cylindrical vial with one or more solid balls inside. The formation of electroceramic phases of pervoskite structure and fine crystallinity are activated by mechanical energy or a combination of mechanical energy and thermal energy. Sintered electroceramic materials and components are fabricated when compacts or green bodies made of the resulting ceramic powders are densified at the sintering temperature.

Abstract: There is disclosed a method of fabricating a piezoelectric ceramics. It can obtain a small grain size and a fine grain phase by forming a combined powder being major components, stirring the combined powder with (COOH)2 water solution, dropping a Pb(NO3)2 water solution into the stirred powder, and forming a PZT powder by calcinations and sintering processes.

Abstract: Chemical vapor deposition (CVD) precursor compositions for forming Zr/Hf doped gate dielectric, ferroelectric, or high dielectric constant (k) metal oxide thin films. The precursor composition in one embodiment comprises a metal precursor having a general formula M(&bgr;-diketonate)2(OR)2, wherein M is Zr or Hf, and R is t-butyl. The precursor composition may also comprise a solvent medium selected from the group consisting of ethers, glymes, tetraglymes, amines, polyamines, alcohols, glycols, aliphatic hydrocarbon solvents, aromatic hydrocarbon solvents, cyclic ethers, and compatible combinations of two or more of the foregoing.

Abstract: A piezoelectric ceramic material having the molar composition Pb(1+c)−x−(3/2a)−1/2(x·b)A1xA2a (Zry(1−x−b−x·z)Ti(1−y)(1−x·b−x·w))(B1bB2zB3w)xO3 is described

Abstract: The disclosed invention relates to piezoelectric rare earth doped Pb(Zr,Ti)O3—Pb(Mn,Sb)O3 compounds including (zPb(ZrwTi(1−w))O3−(1−z)Pb(Mn1/3Sb2/3)O3+REx) where z is ≦0.95, 0.40<w<0.60, and where RE is a rare earth cation dopant, and 0<x<5.0%. The doped compounds have both improved Qm and (k). The RE dopants employed advantageously generate both “hardening” and “softening” effects in doped Pb(Zr,Ti)O3—Pb(Mn,Sb)O3 compounds. The RE doped Pb(Zr,Ti)O3—Pb(Mn,Sb)O3 compounds have advantageously high vibrational velocity compared to pure Pb(Zr,Ti)O3—Pb(Mn,Sb)O3 compounds and commercialized hard PZT. The disclosed invention also relates to piezoelectric devices which include the doped piezoelectric ceramic compounds.

Abstract: Disclosed is a piezoelectric ceramic composition comprising a PZT piezoelectric composition, a B-site of which is substituted with a certain material, and chromium oxide, and a piezoelectric device using the piezoelectric ceramic composition. The piezoelectric ceramic composition has good heat resistance and frequency stability, and reduces a leakage current. There is provided the piezoelectric ceramic composition comprising a main component expressed by Pb[(Co1/2W1/2)xTi1-x-yZry]O3 (wherein, 0.001≦x≦0.04, and 0.35≦y≦0.55), Cr2O3 in an amount of 0.01 to 2 wt %, MnO2 in an amount of 0.1 to 0.5 wt %, and an additive in an amount of 0.01 to 2.0 wt %, based on the total weight of the piezoelectric ceramic composition, in which the additive is selected from the group consisting of CoO, MgO, ZnO, Al2O3, Fe2O3, Sb2O3, SnO2, CeO2, Nb2O5, V2O5 and WO3, and mixtures thereof.

Abstract: Provided is a piezoelectric ceramic capable of improving its piezoelectric properties. The piezoelectric ceramic comprises a rhombohedral perovskite structure compound such as (Na0.5Bi0.5)TiO3, a tetragonal perovskite structure compound such as BaTiO3 and (K0.5Bi0.5)TiO3 and an orthorhombic perovskite structure compound such as NaNbO3, KNbO3 and CaTiO3, or the rhombohedral perovskite structure compound, the tetragonal perovskite structure compound and a cubic perovskite structure compound such as SrTiO3. Three kinds of perovskite structure compounds having different crystal structures are comprised, so that the piezoelectric properties can be improved. The three kinds of compounds may perfectly form a solid solution or not.

Abstract: The present invention relates to a method for producing a lead zirconate titanate-based ceramic powder containing uniform, fine lead zirconate titanate, using a solid-phase method. The method includes the steps of mixing a lead oxide powder, a zirconium oxide powder, and a titanium oxide powder to form a mixed base powder; and heat-treating the mixed base powder so that lead oxide in the lead oxide powder and titanium oxide in the titanium oxide powder react to produce lead titanate, and that unreacted lead oxide not used in the reaction, the lead titanate produced by the reaction, and zirconium oxide in the zirconium oxide powder react to produce the lead zirconate titanate-based ceramic powder containing lead zirconate titanate.

Abstract: The subject invention includes a composite material comprising a ferroelectric material and a ferromagnetic material having a loss factor (tan &dgr;) for the composite material which includes a dielectric loss factor of the ferroelectric material and a magnetic loss factor of the ferromagnetic material. The composite material achieves the loss factor of from 0 to about 1.0 for a predetermined frequency range greater than 1 MHz. The ferroelectric material has a dielectric loss factor of from 0 to about 0.5 and the ferromagnetic material has a magnetic loss factor of from 0 to about 0.5 for the predetermined frequency range. The ferroelectric material is present in an amount from 10 to 90 parts by volume based on 100 parts by volume of the composite material and the ferromagnetic material is present in an amount from 10 to 90 parts by volume based upon 100 parts by volume of the composite material such that the amount of the ferroelectric material and the ferromagnetic material equals 100 parts by volume.

Abstract: Provided is a piezoelectric ceramic compact useful as a material for a piezoelectric ceramic compact device or the like, having SrBi4Ti4O15 as a main component, containing no or a small amount of lead or lead compound, and exhibiting a Qmax improved to a level permitting practical use application. The piezoelectric ceramic compact includes a bismuth layer compound as a main component composed of Sr, Bi, Ti and oxygen, and when the molar ratio of Sr, Bi and Ti of the bismuth layer compound as the main component is a:b:c, the relations of 0.13≦a/c<0.25 and 3.5≦(2a+3b)/c≦3.75 are satisfied.

Abstract: A piezoelectric ceramic composition with superior dielectric constant, mechanical quality factor Qm and electromechanical coupling factor Kp, and a high power output piezoelectric transformer made from the composition are disclosed. The piezoelectric ceramic composition is composed of Pb [(Sb1/2Nb1/2)x (Zr0.495Ti0.505)1−x] O3+yPbO+zMnO, where x is 0.01-0.05, y is 0.3-0.6 wt %, and z is 0.7 wt % or less.

Abstract: A piezoelectric ceramic composition with superior mechanical quality factor Qm and electromechanical coupling factor Kp, and a high power output piezoelectric transformer made from the composition are disclosed. The piezoelectric ceramic composition according to the present invention is composed of Pb1−aSra[(Ni1/2W1/2)b(Mn1/3Nbz/3)c(Zr1−xTix)1−b−c]O3+kPbO, where a is 0-0.06, b is 0.01-0.05, c is 0.01-0.09, x is 0.47-0.53, and k is 0.1-0.7 wt %.

Abstract: A piezoelectric ceramic composition and a piezoelectric element in which cracks and chips are not likely to occur during working even if the thicknesses are reduced, are provided. The piezoelectric ceramic composition contains as a primary component, a complex oxide having a perovskite structure, composed of at least Pb, Zr, Ti, Mn, Nb and O, and represented by general formula ABO3, in which the total molar quantity of elements constituting A is smaller than the total molar quantity of elements constituting B, and Si is present as a secondary component at the content of about 0.010 wt % to 0.090 wt %, in terms of SiO2, relative to the primary component.

Abstract: The object of the present invention is to provide a solution and a method for forming a ferroelectric film capable of forming a uniform film free from uneven coating (striation).

Abstract: The Invention relates to piezoelectric ceramic materials with a base consisting of lead zirconate titanate. Said materials are characterised by the excellent heat- and time-stability of the functional characteristics.

Abstract: An electro-optically deactivated transmissive material comprises a plurality of chemicals which are sufficient, in combination, to enable formation of an electro-optic material having an index of refraction that is responsive to an electric field. The chemicals are combined with a glassifier so as to form a transmissive material that is less responsive to the electric field than said electro-optic material. The deactivated material has substantially the same refractive index as the electro-optic material in the absence of an electric field. In a preferred embodiment, the deactivated material is arranged with active material to form an optical switch.

Abstract: A piezoelectric ceramic composition in which the mechanical quality factor Qm and the electromechanical coupling factor Kp are superior, and a high power output piezoelectric transformer made of it are disclosed.

Abstract: A method of synthesizing a PGO spin-coating precursor solution includes utilizing the starting materials of lead acetate trihydrate (Pb(OAc)2.3H2O) and germanium alkoxide (Ge(OR)4(R=C2H5 and CH(CH3)2)). The organic solvent is di(ethylene glycol) ethyl ether. The mixed solution of lead and di(ethylene glycol) ethyl ether is heated in an atmosphere of air at a temperature no greater than 185° C., and preferably no greater than 190° C. for a time period in a range of thirty minutes to four hours. During the heating step the color of the solution is monitored to determine when the reaction is complete and when decomposition of the desired product begins to take place. The solution is then added to germanium di(ethylene glycol) ethyl ether to make the PGO spin-coating solution. This second step also entails heating the solution to a temperature no greater than 190° C. for a time period in a range of 0.5 to 2.0 hours.

Abstract: A piezoelectric ceramic material is provided which can form a sintered piezoelectric ceramic compact having a low electromechanical coupling coefficient, a low resonant resistance and a low temperature dependence of the resonant frequency. The piezoelectric ceramic material is a solid solution having a primary component composed of PbTiO3, PbZrO3 and Pb(MaXMdY)O3, in which Ma is at least one bivalent element or trivalent element, and Md is at least one pentavalent element or hexavalent element, and the ratio X/Y of the Ma content X to the Md content Y is larger than the stoichiometric ratio. Preferred is Ma being Mn, Md being at least one of Nb, Sb, Ta and W, and when the contents of Mn, Nb, Sb, Ta and W are represented by A, B, C, D and E, respectively, 0.525≦A/(B+C+D+2E)≦1, and about 20 mole percent or less of the element Pb being replaced by at least one of Ca, Ba, Sr and La.

Abstract: A modified PbZrTiO3 perovskite crystal material thin film, wherein the PbZrTiO3 perovskite crystal material includes crystal lattice A-sites and B-sites at least one of which is modified by the presence of a substituent selected from the group consisting of (i) A-site substituents consisting of Sr, Ca, Ba and Mg, and (ii) B-site substituents selected from the group consisting of Nb and Ta. The perovskite crystal thin film material may be formed by liquid delivery MOCVD from metalorganic precursors of the metal components of the thin film, to form PZT and PSZT, and other piezoelectric and ferroelectric thin film materials. The thin films of the invention have utility in non-volatile ferroelectric memory devices (NV-FeRAMs), and in microelectromechanical systems (MEMS) as sensor and/or actuator elements, e.g., high speed digital system actuators requiring low input power levels.

Abstract: A piezoelectric ceramic composition capable of obtaining a piezoelectric member that can provide a sufficient sintering density even by firing at a low temperature besides only allowing small amount of Pb to be evaporated by firing to reduce deterioration of electrical characteristics, wherein the piezoelectric member comprises a perovskite structure oxide of the piezoelectric ceramic composition containing Pb, Ti, Zr, Ma (Ma represents at least one of Cr, Mn, Fe and Co) and Md (Md represents at least one of Nb, Sb, Ta and W), and wherein a represents the total content (in mole) of Ma, and b, c, d and e (in mole) represent the contents of Sb, Nb, Ta and W, respectively, and 0.50<a/(b+c+d+2e).

Abstract: A piezoelectric ceramic composition for a surface acoustic wave device which can improve the electromechanical coupling coefficient is provided. The piezoelectric ceramic composition for a surface acoustic wave device is represented by the formula PbaZrxTiy(NimMnnNb⅔)zO3, wherein x+y+z=1, 0.93≦a≦1.02, 0.32≦x≦0.50, 0.41≦y≦0.54, 0.03≦z≦0.21 and 0.24≦m+n≦0.67.

Abstract: The piezoelectric ceramic includes oxide represented by (Pb1−aAa)s[Zn1/3Nb2/3)w(Mn1/3B2/3)xTiyZrz]O3. A represents at least one element in the group comprising Ca, Sr and Ba. B represents at least one element in the group comprising Nb, Sb and Ta and a, s, w, x, y and z are within a range of 0≦a≦0.1, 0.9≦s<1.0, 0.2≦w/x≦3.0, 0.1≦y≦0.5 and 0.2≦z≦0.6, respectively and w+x+y+z=1. Therefore, the high mechanical strength can be attained easily and reasonably and also the excellent piezoelectric properties are attained without grinding calcined powder or a hot press.

Abstract: The invention is a novel fullerene-added lead zirconate titanate and a method of producing the same, wherein zirconium alkoxide, titanium alkoxide and lead acetate are dissolved in an organic solvent with a stabilizer to form a colloidal solution or sol. The colloidal solution is added with fullerene, gelatinized, dried and fired at a relatively low temperature, for example, 400 to 500° C., whereby a perovskite phase can effectively be formed at a temperature lower than in conventional methods.

Abstract: When a piezoelectric material is manufactured by hydrothermal method, the proper amount of lead contained in the piezoelectric film can be ensured and decreases in piezoelectric characteristics can be prevented. A method for manufacturing a piezoelectric material expressed by the formula ABO3, containing an element “a” as the element expressed by A above, and having a perovskite crystal structure, comprises a first step of producing an oxide containing an element “a′”, and a second step of producing a piezoelectric material by subjecting the oxide produced in the first step to a hydrothermal processing using an aqueous solution containing the element “a”, wherein the amount of the element “a”, contained in the piezoelectric material produced in the second step is increased over the amount of the element “a” contained in the oxide produced in the first step.

Abstract: There is provided a composition of piezoelectric porcelain which is composed as x(Pb2Sb2O7)½. (1−x)[Pba(ZryTiz)O3] (provided that 0.98≦a≦0.999, 0.005≦x≦0.05, 0.50≦y≦0.54, 0.46≦z≦0.50, y+z=1) is a main component, and to the weight of 1 mol of the main component, 0.1 to 1.0 wt % of at least one kind of W, Sb, Nb, and Ta in terms of WO3, Sb2O3, Nb2O5, and Ta2O5 is added as a sub component, and 0.01 to 0.1 wt % of Si in terms of SiO2 is added as a further sub component.

Abstract: A piezoelectric element includes a ceramic substrate, a piezoelectric(s) made of a ceramic composition composed mainly of a PbMg⅓Nb⅔O3—PbZrO3—PbTiO3 ternary system solid solution composition represented by the following general formula (1) and containing 0.05 to 10.0% by weight, based on the ceramic composition, of NiO, and electrodes electrically connected to the piezoelectric.

Abstract: Provided are a piezoelectric element by which a pressure of a better displacement is obtained, a process for producing the same and an ink jet recording head having the piezoelectric element.

Abstract: A piezoelectric ceramic is provided which has a very low loss and superior workability in micro-fabrication. The piezoelectric ceramic contains at least Pb, Mn, Nb, Ti and Zr as primary metal components, in which, when the composition of the piezoelectric ceramic is represented by the formula Pbx{(MnaNbb)yTizZr(1−Y−z)}O3, the x, y, z, a, and b are, on a molar basis, such that 0.95≦x≦0.995, 0.055≦y≦0.10, 0.40≦z≦0.55, 2.01≦b/a≦2.40, and a+b=1. In addition, the average grain diameter of the sintered piezoelectric ceramic is about 2 &mgr;m or less.

Abstract: A piezoelectric ceramic composition and a piezoelectric element in which cracks and chips are not likely to occur during working even if the thicknesses are reduced, are provided. The piezoelectric ceramic composition contains as a primary component, a complex oxide having a perovskite structure, composed of at least Pb, Zr, Ti, Mn, Nb and O, and represented by general formula ABO3, in which the total molar quantity of elements constituting A is smaller than the total molar quantity of elements constituting B, and Si is present as a secondary component at the content of about 0.010 wt % to 0.090 wt %, in terms of SiO2, relative to the primary component.

Abstract: A perovskite compound of the formula, (Na½Bi½)1−xMx(Ti1−yM′y)O3±z, where M is one or more of Ca, Sr, Ba, Pb, Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; and M′ is one or more of Zr, Hf, Sn, Ge, Mg, Zn, Al, Sc, Ga, Nb, Mo, Sb, Ta, W, Cr, Mn, Fe, Co and Ni, and 0.01<x<0.3, and 0.01<y<0.3, and z<0.1 functions as an electromechanically active material. The material may possess electrostrictive or piezoelectric characteristics.

Abstract: A piezoelectric material exhibiting a high Curie point and a high displacement at a low drive voltage is provided. The piezoelectric material contains as a main component a composite oxide and is expressed by the general formula [Pb{1−x1−x2−&agr;(x1−x2)}, A1x1, A2x2]{(Tiy, Zrz) (1−&bgr;(x1−x2)−&ggr;), (Y0.5, Nb0.5)&ggr;}O3, where y +z=1, 1.15 <z/y<1.30 and 0<&ggr;<0.1; and A1, A2, x1, x2 satisfy any of the conditions (i) A1 is at least selected one of Ce and La, A2 is K, 0.02≦x1<0.08, 0≦x2≦0.05 (0.02≦x1+x2≦0.1, x1≦x2) and &agr;=0, &bgr;=0.25 or &agr;=0.5, &bgr;=0, and (ii) A1 is Sr, A2 is Ba, 0.03 ≦x1≦0.05, 0.03≦x2≦0.05 (|x1−x2|≦0.01), and &agr;=0, &bgr;=0.

Abstract: A piezoelectric ceramic composition in which the dielectric constant, the mechanical quality factor Qm and the electromechanical coupling factor Kp are superior, and a high power output piezoelectric transformer made of it are disclosed.

Abstract: Low loss piezoelectric ceramic compositions cofirable with silver at a reduced sintering temperature and methods for producing the such compositions are provided. The compositions are binary piezoelectric ceramic compositions having a first component which is characterized by about 95.0 to about 99.5 weight percent of a system represented by a general formula Pb(ZrxTi1−x)O3+y wt % MnO2 in which x and y represent weight percentages and wherein x is within a range from 0.0 to about 1.0, and y is within a range from about 0.1 to about 1.0. The compositions also have 0.5 to 5.0 wt % of a second component represented by the general formula w wt % Bi2O3−z wt % CdO in which w and z represent weight percentages and wherein w is within a range from about 0.1 to about 1.0, and z is within a range from about 0.1 to about 2.0. The piezoelectric ceramic compositions are non-reactive with a silver electrode layer when cofired therewith at sintering temperatures of about 900° C.

Abstract: A piezoelectric ceramic material able to form a piezoelectric ceramic sintered body having such characteristics as a small electromechanical coupling coefficient, small resonant resistance and small temperature dependency of the resonant frequency that is required for designing a narrow-band filter is represented by principal component of the general formula of (PbaSrb)(ZrcTidMneNbf)O3 and having a composition satisfying the following relations of 0.93≦a≦1.01, 0.01≦b≦0.04, 0.37≦c≦0.47, 0.48≦d≦0.58, 0.0105≦e≦0.06, 0.02≦f≦0.06 and 1.05≦2e/f≦2, and comprising sub-components of about 0.003% to 0.1% by weight of each of SiO2 and Al2O3 relative to the principal component.

Abstract: The present invention provides a sensor material for measuring physical parameters capable of configuring a sensor capable of directly measuring a high value of physical parameters such as high stress or high pressure without employing a pressure resistance container.

Abstract: A piezoelectric buzzer formed by using a piezoelectric ceramic having both a higher heat resistance and a higher piezoelectric characteristics than those of a conventional product. The piezoelectric buzzer 10 of the present invention has a metal plate 12. Formed on the metal plate 12 is a piezoelectric ceramic 14. Further, formed on the piezoelectric ceramic 14 is an electrode 16. The piezoelectric composition forming the piezoelectric ceramic is a piezoelectric ceramic composition characterized in that about 0.2 to 2 mol % of the Pb atoms of a lead zirconate titanate (PZT) represented by the composition formula PbA[(TixZr1-x)a(SnyCr1-y)bSbc]O3 has been displaced by La, wherein 0.94≦A≦1.02, 0.46≦x≦0.51, 0.01≦y≦0.5, 0.01≦b≦0.03, 0.01≦c≦0.04,a+b+c=1.

Abstract: A piezoelectric sintered ceramic made of (a) 100 parts by weight of main components having a composition represented by the general formula: (Pb1−yMy)(ZrzTi1−z)O3, wherein M is at least one element selected from the group consisting of Sr, Ba and Ca, and y and z are numbers satisfying 0.01≦y≦0.10, and 0.51≦z≦0.56, respectively; (b) 0.05-1.0 parts by weight, as Fe2O3, of Fe; and (c) 10-1000 ppm of Ag.

Abstract: Manganese oxide and tantalum oxide are added to a piezoelectric ceramic composition based on lead zinc-niobate titanate zirconate. The composition is suitable for piezo-electric transformers since its mechanical quality factor (Qm) is improved without reducing its electromechanical coupling coefficient (k31), and good high-power properties and high mechanical strength are obtained. In another embodiment, manganese oxide and at least one of antimony oxide and niobium oxide are added to a piezoelectric ceramic composition based on lead zinc-niobate titanate zirconate.

Abstract: Composition for piezoelectric ceramics includes a main component and a sub component. The main component is expressed with a general expression of aPb(Mg⅓Nb⅔)O3-bPb(Yb⅓Nb⅔)O3-cPbTiO3-dPbZrO3, where a+b+c+d=1, 0.01≦a≦0.07, 0.01≦b≦0.07, 0.35≦c≦0.55, and 0.4≦d≦0.6. The sub component contains 0.1 to 0.7 wt % of Mn in terms of manganese oxide, 0.01 to 0.3 wt % of Cr in terms of chromium oxide and 0.05 to 0.5 wt % of Co in terms of cobalt oxide per the weight of 1 mol of main component.