Refractory Or Platinum Group Metal Or Alloy Or Silicide Thereof Patents (Class 257/768)
  • Patent number: 7161246
    Abstract: Integrated circuit interconnect alloys having copper, silver or gold as the major constituent element. The resulting reduction in melting temperature allows for improved coverage of high aspect ratio features with reduced deposition pressure. The alloys are used to fabricate interconnects in integrated circuits, such as memory devices. The interconnects can be high aspect ratio features formed using a dual damascene process. The integrated circuits having the interconnects are applicable to semiconductor dies, devices, modules and systems.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: January 9, 2007
    Assignee: Micron Technology, Inc.
    Inventor: Paul A. Farrar
  • Patent number: 7157798
    Abstract: A method for creating a refractory metal and refractory metal nitride cap effective for reducing copper electromigration and copper diffusion is described. The method includes depositing a refractory metal nucleation layer and nitriding at least the upper portion of the refractory metal layer to form a refractory metal nitride. Methods to reduce and clean the copper lines before refractory metal deposition are also described. Methods to form a thicker refractory metal layer using bulk deposition are also described.
    Type: Grant
    Filed: November 8, 2004
    Date of Patent: January 2, 2007
    Assignee: Novellus Systems, Inc.
    Inventors: James A. Fair, Robert H. Havemann, Jungwan Sung, Nerissa Taylor, Sang-Hyeob Lee, Mary Anne Plano
  • Patent number: 7115997
    Abstract: An integrated circuit (IC) chip, semiconductor wafer with IC chips in a number of die locations and a method of making the IC chips on the wafer. The IC chips have plated chip interconnect pads. Each plated pad includes a noble metal plated layer electroplated to a platable metal layer. The platable metal layer may be copper and the noble metal plated layer may be of gold, platinum, palladium, rhodium, ruthenium, osmium, iridium or indium.
    Type: Grant
    Filed: November 19, 2003
    Date of Patent: October 3, 2006
    Assignee: International Business Machines Corporation
    Inventors: Chandrasekhar Narayan, Kevin Shawn Petrarca
  • Patent number: 7098503
    Abstract: In one aspect, the invention includes a method of forming a roughened layer of platinum, comprising: a) providing a substrate within a reaction chamber; b) flowing an oxidizing gas into the reaction chamber; c) flowing a platinum precursor into the reaction chamber and depositing platinum from the platinum precursor over the substrate in the presence of the oxidizing gas; and d) maintaining a temperature within the reaction chamber at from about 0° C. to less than 300° C. during the depositing. In another aspect, the invention includes a platinum-containing material, comprising: a) a substrate; and b) a roughened platinum layer over the substrate, the roughened platinum layer having a continuous surface characterized by columnar pedestals having heights greater than or equal to about one-third of a total thickness of the platinum layer.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: August 29, 2006
    Assignee: Micron Technology, Inc.
    Inventor: Eugene P. Marsh
  • Patent number: 7078733
    Abstract: A layered structure of wire(s) comprising a wiring layer made of a low resistance metal containing aluminum, copper or silver; and an alloy layer made of an intermediate phase containing the low resistance metal and a refractory metal. The refractory metal is molybdenum. There is also formed a layered structure of wire(s) made of an aluminum alloy containing a lanthanoid, wherein a number average crystal grain size is 16.9 nm or more. Crystal grain size may be larger than a mean free path of electrons to provide a layered structure of wire(s) with a reduced resistance.
    Type: Grant
    Filed: March 7, 2003
    Date of Patent: July 18, 2006
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Naoya Sotani, Koji Suzuki, Yoshio Miyai
  • Patent number: 7038318
    Abstract: Various embodiments of the invention described herein reduce contact resistance to a silicon-containing material using a first refractory metal material overlying the silicon-containing material and a second refractory metal material overlying the first refractory metal material. Each refractory metal material is a conductive material containing a refractory metal and an impurity. The first refractory metal material is a metal-rich material, containing a level of its impurity at less than a stoichiometric level. The second refractory metal material has a lower affinity for the impurities than does the first refractory metal material. The second refractory metal material can thus serve as an impurity donor during an anneal or other exposure to heat.
    Type: Grant
    Filed: October 21, 2003
    Date of Patent: May 2, 2006
    Assignee: Micron Technology, Inc.
    Inventors: Ravi Iyer, Yongjun Jeff Hu, Luan Tran, Brent Gilgen
  • Patent number: 7009279
    Abstract: In semiconductor devices, a semiconductor device is provided which is high in reliability while suppressing changes in characteristics such as threshold voltages. In a semiconductor device which has a gate dielectric film above a semiconductor substrate and also has above the gate dielectric film a gate electrode film made of silicon germanium chosen as its main constituent material, or alternatively in a semiconductor device which has beneath the gate dielectric film a channel made of silicon as its main constituent material and which has below the channel a channel underlayer film made of silicon germanium as its main constituent material, a specifically chosen dopant, such as cobalt (Co) or carbon (C) or nitrogen (N), is added to the gate electrode and the channel underlayer film, for use as the unit for suppressing diffusion of germanium in the gate electrode or in the channel underlayer film.
    Type: Grant
    Filed: May 12, 2004
    Date of Patent: March 7, 2006
    Assignees: Hitachi, Ltd., Trecenti Technologies, Inc.
    Inventors: Shingo Nasu, Tomio Iwasaki, Hiroyuki Ohta, Yukihiro Kumagai, Shuji Ikeda
  • Patent number: 6998649
    Abstract: A semiconductor light-emitting device capable of attaining a surface plasmon effect while attaining excellent ohmic contact is provided. This semiconductor light-emitting device comprises a semiconductor layer formed on an emission layer, a first electrode layer formed on the semiconductor layer and a second electrode layer, formed on the first electrode layer, having a periodic structure. The first electrode layer is superior to the second electrode layer in ohmic contact with respect to the semiconductor layer, and the second electrode layer contains a metal exhibiting a higher plasma frequency than the first electrode layer.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: February 14, 2006
    Assignee: Sanyo Electric Co., Ltd.
    Inventor: Masayuki Hata
  • Patent number: 6998714
    Abstract: Solder ball bond pads and wire bond pads may be selectively coated so that the wire bond bond pads have a thicker gold coating than the solder ball bond pads. This may reduce the embrittlement of solder ball joints while providing a sufficient thickness of gold for the wire bonding process. In general, gold coatings are desirable on electrical contact surfaces to prevent oxidation. However, the thickness of gold which is necessary on solder ball bond pads may be less and excessive gold may be disadvantageous. Thus, by masking the solder ball bond pads during the gold coating of the wire bond bond pads, a differential gold thickness may be achieved which is more advantageous for each application.
    Type: Grant
    Filed: November 24, 2003
    Date of Patent: February 14, 2006
    Assignee: Micron Technology, Inc.
    Inventor: Patrick W. Tandy
  • Patent number: 6989599
    Abstract: A reliable semiconductor device is provided with a layered interconnect structure that may develop no problem of voids and interconnect breakdowns, in which the layered interconnect structure includes a conductor film and a neighboring film so layered on a semiconductor substrate that the neighboring film is in contact with the conductor film.
    Type: Grant
    Filed: February 23, 1999
    Date of Patent: January 24, 2006
    Assignee: Hitachi, Ltd.
    Inventors: Tomio Iwasaki, Hideo Miura
  • Patent number: 6949827
    Abstract: A method of depositing a thin film on a substrate in a semiconductor device using Atomic Layer Deposition (ALD) process parameters exposes the substrate to at least one adherent material in a quantity sufficient for the material to adsorb onto the substrate and thereby form an initiation layer. The initiation layer presents at least one first reactive moiety which is then chemically reacted with at least one first reaction material using atomic layer deposition conditions to form a second reactive moiety. The second reactive moiety is then chemically reacted with at least one second reaction material under process conditions sufficient to form a reaction layer over the initiation layer. The process may be repeated to form successive reaction layers over the initiation layer. The adherent material constituting the initiation layer is preferably one which is not substantially degraded by the atomic layer deposition parameters.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: September 27, 2005
    Assignee: Micron Technology, Inc.
    Inventors: Gurtej Sandhu, Garo J. Derderian
  • Patent number: 6919636
    Abstract: Leakage, capacitance and reliability degradation of interconnects fabricated in low-k dielectric materials, particularly porous low-k dielectric material, due to penetration by a barrier metal and/or barrier metal precursor during damascene processing is prevented by depositing a conformal, heat stable dielectric sealant layer on sidewalls of the low-k dielectric material defining the damascene opening. Embodiments include forming a dual damascene opening in a porous, low-k organosilicate layer, the organosilicate having a pendant silanol functional group, depositing a siloxane polymer having a silylating functional group which bonds with the pendant silanol group to form the sealant layer, depositing a Ta and/or TaN barrier metal layer by CVD or ALD and filling the opening with Cu or a Cu alloy.
    Type: Grant
    Filed: July 31, 2003
    Date of Patent: July 19, 2005
    Assignee: Advanced Micro Devices, Inc.
    Inventor: E. Todd Ryan
  • Patent number: 6917112
    Abstract: A method for forming a metal/metal oxide structure that includes forming metal oxide regions, e.g.. ruthenium oxide regions, at grain boundaries of a metal layer, e.g., platinum. Preferably, the metal oxide regions are formed by diffusion of oxygen through grain boundaries of the metal layer, e.g., platinum, to oxidize a metal layer thereon, e.g, ruthenium layer. The structure is particularly advantageous for use in capacitor structures and memory devices, such as dynamic random access memory (DRAM) devices.
    Type: Grant
    Filed: August 26, 2002
    Date of Patent: July 12, 2005
    Assignee: Micron Technology, Inc.
    Inventors: Cem Basceri, Gurtej Sandhu
  • Patent number: 6917111
    Abstract: A method for fabricating cell plugs of a semiconductor device with cell plugs is disclosed, which increases the operation speed of the semiconductor device by reducing the cell plug resistance of the device. The semiconductor device includes a first insulating interlayer on a semiconductor substrate; a first cell plug on the semiconductor substrate through the first insulating interlayer; a second insulating interlayer on the first insulating interlayer; a silicide contact on a predetermined surface of the first cell plug through the first insulating interlayer; and a second cell plug on the silicide contact through the second insulating interlayer.
    Type: Grant
    Filed: October 31, 2003
    Date of Patent: July 12, 2005
    Assignee: Hynix Semiconductor Inc.
    Inventors: Yoon Jik Lee, Jeong Tae Kim
  • Patent number: 6906370
    Abstract: A semiconductor component having a material-reinforced contact area formed of a metal layer is disclosed. The contact area is jointly formed by a second metal area of a first metal layer and a fourth metal area of a second metal layer which is to be contacted. A thickness of the contact area material is at least twice that of a single metal layer and thereby prevents penetrative etching when a hole is created for contacting the metal layer.
    Type: Grant
    Filed: October 10, 2000
    Date of Patent: June 14, 2005
    Assignee: Infineon Technologies AG
    Inventors: Holger Hübner, Thomas Röhr
  • Patent number: 6906420
    Abstract: The semiconductor device of the present invention includes: a substrate; a first conductor film supported by the substrate; an insulating film formed on the substrate to cover the first conductor film, an opening being formed in the insulating film; and a second conductor film, which is formed within the opening of the insulating film and is in electrical contact with the first conductor film. The second conductor film includes: a silicon-containing titanium nitride layer formed within the opening of the insulating film; and a metal layer formed over the silicon-containing titanium nitride layer. The metal layer is mainly composed of copper.
    Type: Grant
    Filed: December 18, 2003
    Date of Patent: June 14, 2005
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Takeshi Harada
  • Patent number: 6896976
    Abstract: A semiconductor device is disclosed containing a semiconductor die having a trimetal electrode soldered to a substrate by a Sn—Sb solder.
    Type: Grant
    Filed: April 9, 2003
    Date of Patent: May 24, 2005
    Assignee: International Rectifier Corporation
    Inventor: Chuan Cheah
  • Patent number: 6891274
    Abstract: An under-bump-metallurgy layer is provided. The under-bump-metallurgy layer is formed over the contact pad of a chip and a welding lump is formed over the under-ball-metallurgy layer. The under-bump-metallurgy layer comprises an adhesion layer, a barrier layer and a wettable layer. The adhesion layer is directly formed over the contact pad. The barrier layer made from a material such as nickel-vanadium alloy is formed over the adhesion layer. The wettable layer made from a material such as copper is formed over the barrier layer. The wettable layer has an overall thickness that ranges from about 3 ?m to about 8 ?m.
    Type: Grant
    Filed: August 18, 2003
    Date of Patent: May 10, 2005
    Assignee: Advanced Semiconductor Engineering, Inc.
    Inventors: William Tze-You Chen, Ho-Ming Tong, Chun-Chi Lee, Su Tao, Jeng-Da Wu, Chih-Huang Chang, Po-Jen Cheng
  • Patent number: 6882052
    Abstract: A method and structure for forming a refractory metal liner, includes depositing a layer of refractory metal on a first conductive layer, at least half of the depositing being carried out in the presence of an amount of passivating agent that is sufficient to impede subsequent reaction of at least a top half of the layer of refractory metal with the first conductive layer and is less than an amount of passivating agent necessary to form a stoichiometric refractory metal with the passivating agent, and annealing the refractory metal and the first conductive layer in a first element ambient, thereby forming a stoichiometric refractory metal with the first element in at least a portion of the top half of the layer of refractory metal.
    Type: Grant
    Filed: September 20, 2003
    Date of Patent: April 19, 2005
    Assignee: International Business Machines Corporation
    Inventor: William J. Murphy
  • Patent number: 6873020
    Abstract: Integrated circuit electrodes include an alloy of a first metal and a second metal having lower work function than the first metal. The second metal also may have higher oxygen affinity than the first metal. The first metal may be Ru, Ir, Os, Re and alloys thereof, and the second metal may be Ta, Nb, Al, Hf, Zr, La and alloys thereof. Both NMOS and the PMOS devices can include gate electrodes of an alloy of the first metal and the second metal having lower work function than the first metal. The PMOS gate electrode may have a higher percentage of the first metal relative to the second metal than the NMOS gate electrode. Thus, a common material system may be used for gate electrodes for both NMOS and PMOS devices.
    Type: Grant
    Filed: February 22, 2002
    Date of Patent: March 29, 2005
    Assignee: North Carolina State University
    Inventors: Veena Misra, Huicai Zhong, ShinNam Hong
  • Patent number: 6872639
    Abstract: An integrated circuit has a multi-layer stack such as a gate stack or a digit line stack disposed on a layer comprising silicon. A conductive film is formed on the transition metal boride layer. A process for fabricating such devices can include forming the conductive film using a vapor deposition process with a reaction gas comprising fluorine. In the case of a gate stack, the transition metal boride layer can help reduce or eliminate the diffusion of fluorine atoms from the conductive film into a gate dielectric layer. Similarly, in the case of digit line stacks as well as gate stacks, the transition metal boride layer can reduce the diffusion of silicon from the polysilicon layer into the conductive film to help maintain a low resistance for the conductive film.
    Type: Grant
    Filed: April 17, 2003
    Date of Patent: March 29, 2005
    Assignee: Micron Technology, Inc.
    Inventors: Scott J. DeBoer, Husam N. Al-Shareef
  • Patent number: 6867130
    Abstract: Semiconductor devices exhibiting reduced gate resistance and reduced silicide spiking in source/drain regions are fabricated by forming thin metal silicide layers on the gate electrode and source/drain regions and then selectively resilicidizing the gate electrodes. Embodiments include forming the thin metal silicide layers on the polysilicon gate electrodes and source/drain regions, depositing a dielectric gap filling layer, as by high density plasma deposition, etching back to selectively expose the silicidized polysilicon gate electrodes and resilicidizing the polysilicon gate electrodes to increase the thickness of the metal silicide layers thereon. Embodiments further include resilicidizing the polysilicon gate electrodes including a portion of the upper side surfaces forming mushroom shaped metal silicide layers.
    Type: Grant
    Filed: May 28, 2003
    Date of Patent: March 15, 2005
    Assignee: Advanced Micro Devices, Inc.
    Inventors: Olov B. Karlsson, Simon S. Chan, William G. En, Mark W. Michael
  • Patent number: 6853081
    Abstract: The semiconductor device is formed according to the following steps. A TiN film 71 and a W film 72 are deposited on a silicon oxide film 64 including the inside of a via-hole 66 by the CVD method and thereafter, the W film 72 and TiN film 71 on the silicon oxide film 64 are etched back to leave only the inside of the via-hole 66 and form a plug 73. Then, a TiN film 74, Al-alloy film 75, and Ti film 76 are deposited on the silicon oxide film 64 including the surface of the plug 73 by the sputtering method and thereafter, the Ti film 76, Al-alloy film 75, and TiN film 74 are patterned to form second-layer wirings 77 and 78.
    Type: Grant
    Filed: June 4, 2003
    Date of Patent: February 8, 2005
    Assignee: Hitachi, Ltd.
    Inventors: Yoshitaka Nakamura, Tsuyoshi Tamaru, Naoki Fukuda, Hidekazu Goto, Isamu Asano, Hideo Aoki, Keizo Kawakita, Satoru Yamada, Katsuhiko Tanaka, Hiroshi Sakuma, Masayoshi Hirasawa
  • Patent number: 6835980
    Abstract: A method of depositing a thin film on a substrate in a semiconductor device using Atomic Layer Deposition (ALD) process parameters exposes the substrate to at least one adherent material in a quantity sufficient for the material to adsorb onto the substrate and thereby form an initiation layer. The initiation layer presents at least one first reactive moiety which is then chemically reacted with at least one first reaction material using atomic layer deposition conditions to form a second reactive moiety. The second reactive moiety is then chemically reacted with at least one second reaction material under process conditions sufficient to form a reaction layer over the initiation layer. The process may be repeated to form successive reaction layers over the initiation layer. The adherent material constituting the initiation layer is preferably one which is not substantially degraded by the atomic layer deposition parameters.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: December 28, 2004
    Assignee: Micron Technology, Inc.
    Inventors: Gurtej Sandhu, Garo J. Derderian
  • Patent number: 6833625
    Abstract: For fabricating an interconnect structure formed within an interconnect opening surrounded by dielectric material, the interconnect opening is filled with a conductive fill material comprised of a bulk conductive fill material doped with a first dopant element and a second dopant element that is different from the first dopant element. The dielectric material is comprised of a first dielectric reactant element and a second dielectric reactant element. A diffusion barrier material is formed from a reaction of the first dielectric reactant element and the first dopant element that diffuses from the conductive fill material to the walls to the interconnect opening. In addition, a boundary material is formed from a reaction of the second dielectric reactant element and the second dopant element that diffused from the conductive fill material to the walls of the interconnect opening.
    Type: Grant
    Filed: October 21, 2003
    Date of Patent: December 21, 2004
    Assignee: Advanced Micro Devices, Inc.
    Inventors: Pin-Chin C. Wang, Fei Wang
  • Patent number: 6830820
    Abstract: A titanium layer is formed on a substrate with chemical vapor deposition (CVD). First, a seed layer is formed on the substrate by combining a first precursor with a reducing agent by CVD. Then, the titanium layer is formed on the substrate by combining a second precursor with the seed layer by CVD. The titanium layer is used to form contacts to active areas of substrate and for the formation of interlevel vias.
    Type: Grant
    Filed: August 28, 2001
    Date of Patent: December 14, 2004
    Assignee: Micron Technology, Inc.
    Inventors: Gurtej Singh Sandhu, Donald L. Westmoreland
  • Publication number: 20040238965
    Abstract: Provided is a reliable semiconductor device with a layered interconnect structure that may develop no trouble of voids and interconnect breakdowns, in which the layered interconnect structure comprises a conductor film and a neighboring film as so layered on a semiconductor substrate that the neighboring film is contacted with the conductor film.
    Type: Application
    Filed: June 29, 2004
    Publication date: December 2, 2004
    Inventors: Tomio Iwasaki, Hideo Miura
  • Patent number: 6822307
    Abstract: A semiconductor triode comprises a gate electrode provided on a channel layer, wherein there is interposed an insulating metal oxide layer between a top surface of the channel layer and the gate electrode.
    Type: Grant
    Filed: December 26, 2000
    Date of Patent: November 23, 2004
    Assignee: Fujitsu Limited
    Inventors: Mizuhisa Nihei, Yuu Watanabe
  • Patent number: 6812569
    Abstract: A semiconductor device able to maintain a bonding state between a bump and an electrode and having high reliability even under thermal stress, wherein a sealing resin is interposed to bond the electrodes and bumps between a wiring board formed with a plurality of electrodes and an IC chip formed with a plurality of bumps, the bumps being formed under the condition that the following formula is satisfied. 100<((&PHgr;A×F)/H)<125 where &PHgr;A represents the top diameter of a bump bonded with an electrode, H the height of a bump projecting from the IC chip and bonded with an electrode, and F the linear thermal expansion coefficient of the sealing resin.
    Type: Grant
    Filed: September 16, 2002
    Date of Patent: November 2, 2004
    Assignee: Sony Corporation
    Inventors: Satoshi Iwatsu, Noriyuki Honda
  • Patent number: 6806572
    Abstract: A new method and structure for an improved contact using doped silicon is provided. The structures are integrated into several higher level embodiments. The improved contact has low contact resistivity. Improved junctions are thus provided between an IGFET device and subsequent metallization layers. The improvements are obtained through the use of a silicon-germanium (Si—Ge) alloy. The alloy can be formed from depositing germanium onto the substrate and subsequently annealing the contact or by selectively depositing the preformed alloy into a contact opening. The above advantages are incorporated with relatively few process steps.
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: October 19, 2004
    Assignee: Micron Technology, Inc.
    Inventor: Randhir P. S. Thakur
  • Patent number: 6806573
    Abstract: An alloy or composite is deposited in a recess feature of a semiconductor substrate by sputtering an alloy or composite target into a recess, to form a first layer of deposited material. The first layer of deposited material is resputtered at a low angle and low energy, to redeposit the first layer of deposited material onto the bottom of the recess as a second layer of deposited material having a different stoichiometry than that of the first deposited material. In a further embodiment, a sputtering chamber ambient is comprised of argon and nitrogen. In yet a further embodiment, the resputtering step is followed by deposition of at least one layer of material with a different stoichiometry than that of the second deposited layer, to form a “graded” stoichiometry of material deposited in the recess.
    Type: Grant
    Filed: April 5, 2001
    Date of Patent: October 19, 2004
    Assignee: Micron Technology, Inc.
    Inventor: Yongjun Hu
  • Patent number: 6774449
    Abstract: The semiconductor device of the present invention includes: a gallium nitride (GaN) compound semiconductor layer; and a Schottky electrode formed on the GaN compound semiconductor layer, wherein the Schottky electrode contains silicon.
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: August 10, 2004
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Katsunori Nishii, Yoshito Ikeda, Hiroyuki Masato, Kaoru Inoue
  • Patent number: 6770972
    Abstract: A method for forming within a substrate employed within a microelectronics fabrication an electrical interconnection cross-over bridging between conductive regions separated by non-conductive regions formed within the substrate. There is formed over a substrate provided with conductive and non-conductive regions a blanket dielectric layer and a blanket polysilicon layer. After patterning the polysilicon and dielectric layers. A portion of the dielectric layer at the periphery of the polysilicon layer is etched away, leaving a gap between the polysilicon patterned layer and the underlying substrate contact region. There is formed over the substrate a layer of refractory metal and after rapid thermal annealing, there is formed a surface layer of refractory metal silicide over the surfaces of the polysilicon layer and within the gap between the polysilicon layer and the substrate, completing the electrical connection.
    Type: Grant
    Filed: November 12, 2002
    Date of Patent: August 3, 2004
    Assignee: Taiwan Semiconductor Manufacturing Company
    Inventors: Shih-der Tseng, Kuo-Ho Jao
  • Publication number: 20040145060
    Abstract: An adhesive film having a light colored layer and a dark colored layer is applied to the non-active face of a silicon wafer to protect the wafer when it is singulated into individual dies. The protective film is thick enough to allow laser marking of the die, such that the light colored layer shows through the laser etching of the dark colored layer.
    Type: Application
    Filed: January 23, 2003
    Publication date: July 29, 2004
    Inventor: Christopher J. Dominic
  • Patent number: 6747321
    Abstract: In a semiconductor memory device including memory cells MC with MOS type structure comprising gate electrodes G and source regions S and drain regions D formed in both sides of the gate electrodes G formed on a semiconductor substrate, the source regions S comprise metal silicide layers 121 only in the source contact regions. Even if projected and recessed parts exist in the surface of the source regions S, since the metal silicide layers 121 are not formed on the projected and recessed parts, the metal silicide layers 121 are not disconnected in the projected and recessed parts, and the metal for forming the metal silicide layers 121 does not absorb silicon atom in the source regions S.
    Type: Grant
    Filed: December 17, 2001
    Date of Patent: June 8, 2004
    Assignee: NEC Electronics Corporation
    Inventor: Kohji Kanamori
  • Patent number: 6747343
    Abstract: A leadframe for use with integrated circuit chips comprising a leadframe base made of aluminum or aluminum alloy having a surface layer of zinc; a first layer of nickel on said zinc layer, said first nickel layer deposited to be compatible with aluminum and zinc; a layer of an alloy of nickel and a noble metal on said first nickel layer; a second layer of nickel on said alloy layer, said second nickel layer deposited to be suitable for lead bending and solder attachment; and an outermost layer of noble metal, whereby said leadframe is suitable for solder attachment to other parts, for wire bonding, and for corrosion protection.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: June 8, 2004
    Assignee: Texas Instruments Incorporated
    Inventor: John P. Tellkamp
  • Publication number: 20040104472
    Abstract: The present invention relates to an ultra-thin metal film, an ultra-thin metal multilayer film, and a method of fabricating an ultra-thin metal film or an ultra-thin metal multilayer film. The ultra-thin metal film and the ultra-thin metal multilayer film can be obtained by forming a dielectric film on a conductive base material in a film thickness that causes the significant tunneling effect between metals through the thin dielectric film, or a film thickness whereby the valence electrons and holes of the metal composing the metallic base material and the ultra-thin metal film are affected by the many-body effects, for example, in a film thickness wherein the band-gap width of said dielectric is narrowed; and the ultra-thin metal films are formed on the dielectric grown in the layer-by-layer mode by the deposition method.
    Type: Application
    Filed: September 15, 2003
    Publication date: June 3, 2004
    Inventor: Yoshitada Murata
  • Patent number: 6744105
    Abstract: A core memory array having a plurality of charge trapping dielectric memory devices. The core memory array can include a substrate having a first semiconductor bit line and a second semiconductor bit line formed therein and a body region interposed between the first and the second bit lines. Over the body region can be formed a first dielectric layer disposed, a dielectric charge trapping layer and a second dielectric layer. At least one word line can be disposed over the second dielectric layer, which defines a channel within the body region. Each bit line can include a bit line contact assembly having a locally metalized portion of the bit line and a conductive via traversing a dielectric region.
    Type: Grant
    Filed: March 5, 2003
    Date of Patent: June 1, 2004
    Assignee: Advanced Micro Devices, Inc.
    Inventors: Cinti Xiaohua Chen, Hiroyuki Kinoshita, Jeff P. Erhardt, Weidong Qian, Jean Yee-Mei Yang
  • Patent number: 6720212
    Abstract: Disclosed is a method of ball grid array packaging, comprising the steps of providing a semiconductor die having a metal conductors thereon, covering said metal conductors with an insulative layer, etching through said insulative layer so as to provide one or more openings to said metal conductors, depositing a compliant material layer, etching through said compliant material layer so as to provide one or more openings to said metal conductors, depositing a substantially homogenous conductive layer, patterning said conductive layer so as to bring at least one of said metal conductors in electrical contact with one or more pads, each said pad comprising a portion of said conductive layer disposed upon said compliant material, and providing solder balls disposed upon said pads. Also disclosed is the apparatus made from the method.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: April 13, 2004
    Assignee: Infineon Technologies AG
    Inventors: Werner Robl, Thomas Goebel, Axel Christoph Brintzinger, Gerald Friese
  • Publication number: 20040051179
    Abstract: In one aspect, the invention includes a method of forming a roughened layer of platinum, comprising: a) providing a substrate within a reaction chamber; b) flowing an oxidizing gas into the reaction chamber; c) flowing a platinum precursor into the reaction chamber and depositing platinum from the platinum precursor over the substrate in the presence of the oxidizing gas; and d) maintaining a temperature a within the reaction chamber at from about 0° C. to less than 300° C. during the depositing. In another aspect, the invention includes a platinum-containing material, comprising: a) a substrate; and b) a roughened platinum layer over the substrate, the roughened platinum layer having a continuous surface characterized by columnar pedestals having heights greater than or equal to about one-third of a total thickness of the platinum layer.
    Type: Application
    Filed: August 13, 2003
    Publication date: March 18, 2004
    Inventor: Eugene P. Marsh
  • Patent number: 6707097
    Abstract: A method for forming a refractory metal-silicon-nitrogen capacitor in a semiconductor structure and the structure formed are described. In the method, a pre-processed semiconductor substrate is first positioned in a sputtering chamber. Ar gas is then flown into the sputtering chamber to sputter deposit a first refractory metal-silicon-nitrogen layer on the substrate from a refractory metal silicide target, or from two targets of a refractory metal and a silicon. N2 gas is then flown into the sputtering chamber until that the concentration of N2 gas in the chamber is at least 35% to sputter deposit a second refractory metal-silicon-nitrogen layer on top of the first refractory metal-silicon-nitrogen layer. The N2 gas flow is then stopped to sputter deposit a third refractory metal-silicon-nitrogen layer on top of the second refractory metal-silicon-nitrogen layer. The multi-layer stack of the refractory metal-silicon-nitrogen is then photolithographically formed into a capacitor.
    Type: Grant
    Filed: January 16, 2003
    Date of Patent: March 16, 2004
    Assignee: International Business Machines Corporation
    Inventors: Cyril Cabral, Jr., Lawrence Clevenger, Louis Hsu, Keith Kwong Hon Wong
  • Patent number: 6703668
    Abstract: A local interconnect structure that includes a silicon spacer. After deposition of polysilicon gates and formation of spacers on a semiconductor substrate, photolithography and oxide etch steps are performed to remove a portion of a spacer along a segment of the gate where local interconnection is to be formed. A thin screen oxide layer is deposited over the wafer, followed by the formation of diffusion regions. A silicon layer (either amorphous or polycrystalline) is then deposited. The silicon layer is then selectively etched so as to form a silicon spacer along the segment of the gate where local interconnection is to be formed. A conventional SALICIDE process is performed, leading to simultaneous silicidation of the diffusion region, the gate, and the silicon spacer. The resulting local interconnect electrically connects the gate and the diffusion region.
    Type: Grant
    Filed: June 6, 2000
    Date of Patent: March 9, 2004
    Assignee: Koninklijke Philips Electronics N.V.
    Inventors: Xi-Wei Lin, Emmanuel de Muizon
  • Patent number: 6700199
    Abstract: A gold-silver alloy bonding wire for a semiconductor device is provided. The bonding wire contains: a Au-Ag alloy including 5-40% Ag by weight in Au having a purity of 99.999% or greater; at least one element of a first group consisting of Pd, Rh, Pt, and Ir in an amount of about 50-10,000 ppm by weight; at least one element of a second group consisting of B, Be, and Ca in an amount of about 1-50 ppm by weight; at least one element of a third group consisting of P, Sb, and Bi in an amount of about 1-50 ppm by weight; and at least one element of a fourth group consisting of Mg, TI, Zn, and Sn in an amount of about 5-50 ppm by weight. The bonding wire is highly reliable with a strong tensile strength at room temperature and high temperature and favourable bondability. When the bonding wire is looped, no rupture occurs in a ball neck region. Also, no chip cracking occurs since the ball is soft.
    Type: Grant
    Filed: March 7, 2003
    Date of Patent: March 2, 2004
    Assignee: MK Electron Co., Ltd.
    Inventors: Jeong-Tak Moon, Jong-Soo Cho, Dong-Ho Joung
  • Patent number: 6693354
    Abstract: Metal nitride and metal oxynitride extrusions often form on metal silicides. These extrusions can cause short circuits and degrade processing yields. The present invention discloses a method of selectively removing such extrusions. In one embodiment, a novel wet etch comprising an oxidizing agent and a chelating agent selectively removes the extrusions from a wordline in a memory array. In another embodiment, the wet etch includes a base that adjusts the pH of the etch to selectively remove certain extrusions relative to other substances in the wordline. Accordingly, new metal silicide structures can be used to form novel wordlines and other types of integrated circuits.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: February 17, 2004
    Assignee: Micron Technology Inc.
    Inventors: Gary Chen, Li Li, Yongjun Jeff Hu
  • Patent number: 6690055
    Abstract: A method of forming a rhodium-containing layer on a substrate, such as a semiconductor wafer, using complexes of the formula LyRhYz is provided. Also provided is a chemical vapor co-deposited platinum-rhodium alloy barriers and electrodes for cell dielectrics for integrated circuits, particularly for DRAM cell capacitors. The alloy barriers protect surrounding materials from oxidation during oxidative recrystallization steps and protect cell dielectrics from loss of oxygen during high temperature processing steps. Also provided are methods for CVD co-deposition of platinum-rhodium alloy diffusion barriers.
    Type: Grant
    Filed: August 30, 2000
    Date of Patent: February 10, 2004
    Assignee: Micron Technology, Inc.
    Inventors: Stefan Uhlenbrock, Eugene P. Marsh
  • Patent number: 6690072
    Abstract: A method (and structure) of forming a vertically-self-aligned silicide contact to an underlying SiGe layer, includes forming a layer of silicon of a first predetermined thickness on the SiGe layer and forming a layer of metal on the silicon layer, where the metal layer has a second predetermined thickness. A thermal annealing process at a predetermined temperature then forms a silicide of the silicon and metal, where the predetermined temperature is chosen to substantially preclude penetration of the silicide into the underlying SiGe layer.
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: February 10, 2004
    Assignee: International Business Machines Corporation
    Inventors: Cyril Cabral, Jr., Roy A. Carruthers, Kevin K. Chan, Jack O. Chu, Guy Moshe Cohen, Steven J. Koester, Christian Lavoie, Ronnen A. Roy
  • Patent number: 6690094
    Abstract: A contact interface having a substantially continuous profile along a bottom and lower sides of the active surface of the semiconductor substrate formed within a contact opening is provided. The contact interface is formed by depositing a layer of conductive material, such as titanium, using both a high bias deposition and a low bias deposition. The high bias and low bias deposition may be effected as a two-step deposition or may be accomplished by changing the bias from a high level to a low level during deposition, or vice versa. The conductive material may be converted to a silicide by an annealing process to form the contact interface.
    Type: Grant
    Filed: November 20, 2002
    Date of Patent: February 10, 2004
    Assignee: Micron Technology, Inc.
    Inventors: Randle D. Burton, Shane Leiphart
  • Patent number: 6690093
    Abstract: A metal contact structure of a semiconductor device and a method for forming the same, wherein an upper conductive layer is formed by etching a metal layer, which fills a contact hole and is formed on the entire surface of an interlayer dielectric film and etching is stopped when barrier metal layers under the metal layer is exposed. Then, after forming spacers on the sidewalls of an upper conductive layer, the barrier metal layers (a barrier layer and an ohmic layer) are removed using the spacers as etching masks. Therefore, it is possible to prevent problems due to etch mask misalignment, such as 1) an etching gas of the metal layer permeating through the ohmic layer and 2) defects such as contact resistance changes that occur when spacers cover a contact hole even though the upper conductive layer does not completely cover that contact hole.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: February 10, 2004
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Tae-hyuk Ahn, Myeong-cheol Kim
  • Patent number: 6667552
    Abstract: Multi-level semiconductor devices are formed with reduced parasitic capacitance without sacrificing structural integrity or electromigration performance by removing the inter-layer dielectrics and depositing a metal silicide to line the interconnection system. Embodiments include a semiconductor device comprising a dielectric sealing layer, e.g., silicon nitride, between the substrate and first patterned metal layer, tungsten silicide lining the interconnection system and dielectric protective layers, e.g., a silane derived oxide bottommost protective layer, on the uppermost metallization level.
    Type: Grant
    Filed: February 18, 1999
    Date of Patent: December 23, 2003
    Assignee: Advanced Micro Devices, Inc.
    Inventor: Matthew S. Buynoski
  • Patent number: 6661064
    Abstract: An integrated circuit memory fabrication process and structure, in which salicidation is performed on the periphery (and optionally on the ground lines) of a memory chip, but not on the transistors of the memory cells.
    Type: Grant
    Filed: November 26, 2002
    Date of Patent: December 9, 2003
    Assignee: STMicroelectronics, Inc.
    Inventors: Robert Louis Hodges, Loi Ngoc Nguyen