Producing Silicon Carbide Containing Product Patents (Class 264/682)
  • Patent number: 7951324
    Abstract: The method for manufacturing a honeycomb structure includes preparing a material composition containing at least a silicon carbide powder, a binder and an additive; molding the material composition to form a pillar-shaped honeycomb molded body in which a number of cells are placed in parallel with one another in a longitudinal direction with a cell wall therebetween; carrying out a degreasing treatment on the honeycomb molded body; and carrying out a firing treatment on the honeycomb degreased body to manufacture a honeycomb fired body. The additive contains at least one kind selected from the group consisting of alumina, silica, titania, zirconia, magnesia, and a chemical composite containing any of alumina, silica, titania, zirconia and magnesia.
    Type: Grant
    Filed: September 4, 2007
    Date of Patent: May 31, 2011
    Assignee: Ibiden Co., Ltd.
    Inventors: Kazuya Naruse, Daniel Merle, Koji Shimato, Kazutomo Matsui
  • Patent number: 7931853
    Abstract: A process for converting precursor objects into a unitary ceramic object produces, for example, a ceramic, optical scan mirror that is formed from at least two pieces. An optical section has at least one optical surface and at least one attachment surface, and a support section has at least one attachment surface and preferably has a mounting area. The optical and support sections are formed as separate pieces from a precursor material, such as graphite, such that a selected support section can receive any of a plurality of optical sections having different sizes, shapes, or orientations. To form the mirror, the attachment surfaces are placed adjacent each other, and then the sections are converted simultaneously to a ceramic material, such as silicon carbide, to form a monolithic scan mirror.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: April 26, 2011
    Assignee: Poco Graphite, Inc.
    Inventor: Ronald E. Plummer
  • Patent number: 7910082
    Abstract: A method for preparing ordered mesoporous silicon carbide (OMSiC) nanocomposites uses an evaporation-induced self-assembly of a precursor composition that preferably includes a phenolic resin, pre-hydrolyzed tetraethyl orthosilicate, a surfactant, and butanol. The precursor mixture is dried, cross-linked and heated to form ordered mesoporous silicon carbide material having discrete domains of ordered, mesoscale pores.
    Type: Grant
    Filed: August 13, 2008
    Date of Patent: March 22, 2011
    Assignee: Corning Incorporated
    Inventors: Steven Bruce Dawes, Wageesha Senaratne
  • Publication number: 20100247910
    Abstract: The invention relates to powder comprising at least one element M, at least one element A and at least one element X, in the respective proportions (n+1±?1), 1±?2 and n±?3, in which: A is chosen from Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, P, As and S; M is a transition metal; X is chosen from B, C and N; n is an integer equal to 1, 2 or 3; and ?1, ?2 and ?3 independently represent a number ranging from 0 to 0.2, said powder having a mean particle size of less than 500 nm.
    Type: Application
    Filed: May 29, 2007
    Publication date: September 30, 2010
    Applicant: COMMISSARIAT L'ENERGIE ATOMIQUE
    Inventors: Jérôme Canel, François Tenegal
  • Publication number: 20100248930
    Abstract: Methods of forming composite materials include coating particles of titanium dioxide with a substance including boron (e.g., boron carbide) and a substance including carbon, and reacting the titanium dioxide with the substance including boron and the substance including carbon to form titanium diboride. The methods may be used to form ceramic composite bodies and materials, such as, for example, a ceramic composite body or material including silicon carbide and titanium diboride. Such bodies and materials may be used as armor bodies and armor materials. Such methods may include forming a green body and sintering the green body to a desirable final density. Green bodies formed in accordance with such methods may include particles comprising titanium dioxide and a coating at least partially covering exterior surfaces thereof, the coating comprising a substance including boron (e.g., boron carbide) and a substance including carbon.
    Type: Application
    Filed: March 30, 2009
    Publication date: September 30, 2010
    Applicant: BATTELLE ENERGY ALLIANCE, LLC
    Inventors: Thomas M. Lillo, Henry S. Chu, William Harrison, Derek Bailey
  • Patent number: 7799417
    Abstract: A Si—SiC based fired body includes a plurality of silicon carbide (SiC) particles serving as an aggregate, and silicon (Si) which serves as a binder and which is filled into gaps between the above-described silicon carbide particles, wherein the maximum particle diameter of the above-described silicon carbide particles is 0.5 mm or more, the content of silicon is 5 to 40 percent by mass, and the porosity is 0 to 5%. Preferably, the Si—SiC based fired body is in a thick-walled shape having a thickness of 20 to 200 mm.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: September 21, 2010
    Assignees: NGK Insulators, Ltd., NGK Adrec Co., Ltd.
    Inventors: Tsuneo Komiyama, Osamu Yamakawa, Seiichi Hori
  • Patent number: 7723247
    Abstract: A method of sintering a ZrB2—SiC composite body at ambient pressures, including blending a first predetermined amount of ZrB2 powder with a second predetermined amount of SiC powder, wherein both powders are characterized by the presence of surface oxide impurities. Next the blended powders are mixed to yield a substantially homogeneous powder mixture and a portion of the substantially homogeneous powder mixture is formed into a green body. The body is fired to a first temperature, wherein substantially all surface oxide impurities are reduced and/or volatilized to substantially eliminate oxides from the green body, and the body is heated to a second temperature and sintered to yield a composite body of at least about 99 percent theoretical density and characterized by SiC whisker-like inclusions distributed substantially evenly in a ZrB2 matrix.
    Type: Grant
    Filed: May 12, 2008
    Date of Patent: May 25, 2010
    Inventors: Shi C. Zhang, Gregory E. Hilmas, William G. Fahrenholtz
  • Patent number: 7699903
    Abstract: The present invention relates to a method for production of a porous ceramic body and a corresponding porous ceramic body which can find application, in particular, as filter, or filter membrane in cross-flow filtration. According to the method of the invention, a bimodal ceramic powder mixture is moulded to give a moulded body, which is subsequently recrystallised by conditioning at high temperature, such that the fine particles melt and link the large particles firmly together by deposition thereon, such that, in defined regions (2,3), a porous ceramic body with a homogeneous structure of almost uniform particle size and pore size is formed, whereby the pores provide an interconnected, open, three-dimensional network.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: April 20, 2010
    Assignees: Saint-Gobain Industrie Keramik Rödental GmbH, Liq Tech
    Inventors: Per Stobbe, Udo Hack
  • Patent number: 7648932
    Abstract: The invention relates to a process for the production of a molded porous ceramic article containing ?-SiC, which process comprises the following steps: the preparation of a molded article containing silicon and carbon and the subsequent pyrolysis and siliconization of the article containing silicon and carbon to form SiC. The invention further relates to a molded porous ceramic article containing SiC which has been produced from a molded article containing silicon and carbon.
    Type: Grant
    Filed: July 5, 2006
    Date of Patent: January 19, 2010
    Assignee: Mann+Hummel Innenraumfilter GmbH & Co. KG
    Inventors: Lars Weisensel, Thomas Wolff, Heino Sieber, Peter Greil
  • Publication number: 20090295048
    Abstract: A composite material according to the invention includes X parts by volume of boron carbide, Y parts by volume of silicon carbide, and Z parts by volume of silicon as main components, wherein 10<X<60, 20<Y<70, and 5<Z<30 are satisfied, and grains of 10 ?m or more of the boron carbide and the silicon carbide are 10-50 parts by volume.
    Type: Application
    Filed: April 3, 2009
    Publication date: December 3, 2009
    Applicant: Toto Ltd.
    Inventors: Akio Matsumoto, Shogo Shimada
  • Publication number: 20090256112
    Abstract: A composite material according the invention includes boron carbide, silicon carbide, and silicon as main components, wherein an average grain diameter of boron carbide grains of the composite material is 10 ?m or more and 30 ?m or less.
    Type: Application
    Filed: April 3, 2009
    Publication date: October 15, 2009
    Applicant: Toto Ltd.
    Inventors: Shogo Shimada, Akio Matsumoto, Masami Ando
  • Patent number: 7576035
    Abstract: A pillar-shaped honeycomb structure has a plurality of cells longitudinally placed in parallel with one another with a wall portion therebetween, wherein the honeycomb structure mainly includes inorganic fibers which form the honeycomb structure without lamination interfaces.
    Type: Grant
    Filed: April 7, 2008
    Date of Patent: August 18, 2009
    Assignee: Ibiden Co., Ltd.
    Inventors: Kazushige Ohno, Tomokazu Oya
  • Patent number: 7534388
    Abstract: A ceramic component is disclosed, including a sintered ceramic body from a composition comprising a first ceramic material, and a plurality of inclusions in the ceramic body, each inclusion comprising graphite and a second material.
    Type: Grant
    Filed: March 11, 2005
    Date of Patent: May 19, 2009
    Assignee: Saint-Gobain Ceramics & Plastics, Inc.
    Inventors: Vimal K. Pujari, Jeffrey J. Kutsch
  • Publication number: 20090121197
    Abstract: The invention relates to a sintered material which is based on transition metal diborides and comprises a) as main phase, 90-99% by weight of a fine-grained transition metal diboride or transition metal diboride mixed crystal comprising at least two transition metal diborides or mixtures of such diboride mixed crystals or mixtures of such diboride mixed crystals with one or more transition metal diborides, where the transition metals are selected from sub-groups IV to VI of the Periodic Table, b) as second phase, 1-5% by weight of particulate boron carbide and/or silicon carbide and c) optionally as third phase, up to 5% by weight of a non-continuous, oxygen-containing grain boundary phase.
    Type: Application
    Filed: March 12, 2007
    Publication date: May 14, 2009
    Applicant: ESK ERAMICS GmbH & KG
    Inventors: Hubert Thaler, Clemens Schmalzried, Frank Wallmeier, Georg Victor
  • Publication number: 20090075120
    Abstract: Embodiments of the present invention provide composite bodies having a discontinuous graphite preform and at least one silicon-bearing metal alloy infiltrant. Embodiments of the present invention also provide methods for producing such composite bodies. The metal alloy is preferably comprised of aluminum, copper, or magnesium, or combinations thereof. Certain preferred embodiments provide at least one aluminum alloy having from about 5% silicon to about 30% silicon, more preferably from about 11% to about 13% silicon, as an alloying element. Certain presently preferred embodiments provide an aluminum-silicon eutectic composition having about 12.5% silicon. Embodiments of the invention provide composite materials be “tuned” to more closely match thermal expansion characteristics of a number of semiconductor or integrated circuit materials such as, but not limited to, silicon, alumina, aluminum nitride, gallium nitride, and gallium arsenide while also providing high thermal conductivity.
    Type: Application
    Filed: September 13, 2007
    Publication date: March 19, 2009
    Applicant: WmK Technologies, LLC
    Inventors: James A. Cornie, Mark Montesano, Stephen S. Cornie, Himanshu Pokharna
  • Publication number: 20090014925
    Abstract: A method for manufacturing a porous ceramic structure which comprises: mixing a ceramic material, a foamed resin and, if necessary, a forming auxiliary; forming the mixture; and then firing the thus formed body, wherein: a resin of an outer shell of the foamed resin is constituted of a copolymer containing 60 wt % or more of acrylonitrile and 40 wt % or less of methyl methacrylate.
    Type: Application
    Filed: January 11, 2005
    Publication date: January 15, 2009
    Applicant: NGK Insulators, Ltd.
    Inventors: Yasushi Noguchi, Kyoko Makino, Shuuji Ueda
  • Patent number: 7442662
    Abstract: A highly heat-conductive Si-containing material containing a Si phase whose lattice constant at room temperature is controlled at a level of more than 0.54302 nm but 0.54311 nm or less. Firing is conducted using a kiln material containing no B compound. With this highly heat-conductive Si-containing material and the process for production thereof, a reduction in heat conductivity can be prevented and a high heat conductivity can be exhibited stably.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: October 28, 2008
    Assignee: NGK Insulators, Ltd.
    Inventors: Kenji Morimoto, Shinji Kawasaki, Hiroaki Sakai
  • Patent number: 7442414
    Abstract: Methods for producing reinforced carbon nanotubes having a plurality of microparticulate carbide or oxide materials formed substantially on the surface of such reinforced carbon nanotubes composite materials are disclosed. In particular, the present invention provides reinforced carbon nanotubes (CNTs) having a plurality of boron carbide nanolumps formed substantially on a surface of the reinforced CNTs that provide a reinforcing effect on CNTs, enabling their use as effective reinforcing fillers for matrix materials to give high-strength composites. The present invention also provides methods for producing such carbide reinforced CNTs.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: October 28, 2008
    Assignee: The Trustees of Boston College
    Inventors: Zhifen Ren, Jian Guo Wen, Jing Y. Lao, Wenzhi Li
  • Publication number: 20080237942
    Abstract: A method for manufacturing a porous silicon carbide sintered body that includes manufacturing a silicon carbide molded body by using a raw material composition containing at least silicon carbide powder, silicon powder, and a binder. The method further includes carrying out a degreasing treatment on the silicon carbide molded body to manufacture a silicon carbide degreased body, and carrying out a firing treatment on the silicon carbide degreased body to manufacture a porous silicon carbide sintered body. The raw material composition has about 1 to about 3% by weight of the total amount of the silicon carbide powder and the silicon powder in a content of the silicon powder. And, the firing treatment is carried out at a temperature allowing silicon carbide powder to mutually form intergranular necks through counter diffusion.
    Type: Application
    Filed: February 12, 2008
    Publication date: October 2, 2008
    Applicant: IBIDEN CO., LTD.
    Inventor: Shoji TAKAMATSU
  • Publication number: 20080199388
    Abstract: A method for manufacturing a diamond composite, includes: a) mixing diamonds with additives, the mixture comprising at least 50 wt % and less than 95 wt % of diamonds and more than 5 wt % additives; b) forming a work piece from the mixture using a pressure of at least 100 Mpa; c) heating the formed work piece to at least 300° C. for removing possible water and wholly or partially removing additives; d) heating the work piece and controlling the heating temperature and heating time so that a certain desired amount of graphite is created by graphitization of diamonds, wherein the amount of graphite created by graphitization is 3-50 wt % of the amount of diamond; e) infiltrating silicon or silicon alloy into the work piece.
    Type: Application
    Filed: August 6, 2007
    Publication date: August 21, 2008
    Inventors: Lena Svendsen, Jie Zheng, Fredrik Meurling, Tomas Rostvall
  • Patent number: 7413701
    Abstract: Clutch linings comprising fiber-reinforced ceramic materials which contain short carbon fibers and whose matrix has a mass fraction of at least 40% of silicon carbide, process for producing them and their use in clutch systems, in particular for motor vehicles.
    Type: Grant
    Filed: August 17, 2004
    Date of Patent: August 19, 2008
    Assignee: SGL Carbon AG
    Inventors: Andreas Kienzle, Mario Krupka, Gustavo Cabello, Jens Rosenloecher
  • Patent number: 7404922
    Abstract: A powdery mixture of fine SiC powder with one or more oxide sintering additives of Al2O3, Y2O3, SiO2 and CaO is blended and uniformly dispersed in a polymeric SiC precursor to prepare a matrix-forming polymeric slurry. A preform of SiC fiber, which has quasi-stoichiometric composition with high crystallinity, is impregnated with the polymeric slurry and then hot-pressed at a temperature of 1600° C. or higher in presence of a liquid phase. Since the heat-resistant SiC fiber is used as strengthening fiber, the prepreg is sintered to a dense SiC composite excellent in mechanical properties by one-step hot-pressing.
    Type: Grant
    Filed: October 25, 2001
    Date of Patent: July 29, 2008
    Assignee: Japan Science and Technology Corporation
    Inventors: Akira Kohyama, Yutai Katoh
  • Patent number: 7381673
    Abstract: A composite material according to the present invention, is composed of SiC, SiO2, at least one out of Al and Si, with He leak rate of 1.3×10?10 Pa·m3/sec or below, thereby providing a composite material, which has a higher vacuum air-tightness, an excellent thermal conductivity, an adjustable coefficient of thermal expansion, small variation in strength and higher reliability, and a method for manufacturing the composite material, and a wafer holding member including the composite material.
    Type: Grant
    Filed: October 27, 2004
    Date of Patent: June 3, 2008
    Assignee: Kyocera Corporation
    Inventors: Kiyoshi Yokoyama, Naoko Itonaga
  • Publication number: 20080093779
    Abstract: Pressureless sintering of silicon carbide with fracture toughness in excess of about 4 MPa-m1/2 as measured by the single-edge precracked beam (SEPB) technique while maintaining a density greater than 3.1 g/cc for compositions with SiC greater than about 94 wt. % is made possible through the use of metallic Al to promote sintering and grain growth. Boron and carbon may be used as traditional sintering aids, with nitrogen to suppress grain growth, and additions of yttrium and/or lanthanide elements to promote intergranular fracture.
    Type: Application
    Filed: August 31, 2006
    Publication date: April 24, 2008
    Inventors: Raymond Ashton Cutler, Roger Marc Flinders, Darin Ray
  • Patent number: 7335331
    Abstract: Compositions and methods of making ceramic plates are described. The compositions are water-based slurries that include filler material, one or more clay components, one or more strength or processing additives, and/or a carbon source. The filler material can include a first grade of boron carbide having a relatively large average particle size, a second grade of boron carbide having an intermediate average particle size, a third grade of boron carbide having a fine average particle size, and/or a silicon carbide having a fine average particle size. The methods of the invention involve casting and drying the slurry to make a substantially dry preform, providing a silicon loaf having a solid form for supporting one or more preforms, placing the substantially dry preform on top of the silicon loaf inside of an infiltration furnace and heating the substantially dry preform and loaf to melt silicon within the loaf and infiltrate the perform to create a ceramic plate.
    Type: Grant
    Filed: March 1, 2005
    Date of Patent: February 26, 2008
    Inventors: Dana M. Husnay, Noah A. Nichelson
  • Patent number: 7314593
    Abstract: Improved silicon carbide powder is prepared by carbothermal reduction of silica by introducing ?-SiC powder simultaneously with iron in the starting composition resulting into a precursor powder which after complete reduction contains at least 90% SiC preferably rich in the ?-phase. The main advantage, among others, is cost effectiveness. Silicon carbide powder finds wide usage in the manufacture of products suitable for refractory and engineering applications.
    Type: Grant
    Filed: October 27, 2004
    Date of Patent: January 1, 2008
    Assignee: Council of Scientific and Industrial Research
    Inventors: Siddhartha Bandyopadhyay, Himadri Sekhar Maity
  • Publication number: 20070267777
    Abstract: Process for producing bodies from ceramic materials using silicon carbide, comprising the steps: configuration of fiber-reinforced porous bodies (1, 5) that consist of carbon on a base (2) that is inert relative to liquid silicon, the bodies having cavities (3) that are accessible from the exterior or surface recesses (3?), and the cavities (3) being closed at the bottom in the porous bodies or the surface recesses (3?) together with the base (2) forming a reservoir that is sealed at the bottom; heating the configuration by introduction of energy to melt the silicon (6) that is present in the reservoir; and infiltrating the melted silicon in the bodies (1, 5) and reaction of the silicon with the carbon to form silicon carbide; and use of the thus produced bodies as brake disks and as clutch driving disks.
    Type: Application
    Filed: May 18, 2007
    Publication date: November 22, 2007
    Applicant: Audi AG
    Inventors: Andreas Kienzle, Johann Daimer
  • Patent number: 7275309
    Abstract: A method of manufacturing an electrical-resistance heating element includes forming sintered ceramics or calcined ceramics, forming an electrode on the sintered ceramics or the calcined ceramics, and forming a ceramic base material having mainly a high melting point metal on the electrode embedded therein, thereby forming a heating element with built-in electrode.
    Type: Grant
    Filed: July 30, 2004
    Date of Patent: October 2, 2007
    Assignee: NGK Insulators, Ltd.
    Inventors: Hiroto Matsuda, Kazuhiro Nobori, Yutaka Mori
  • Patent number: 7244685
    Abstract: A silicon carbide porous body of the present invention, comprising silicon carbide particles and metallic silicon bonded together in such a manner that pores are retained between the silicon carbide particles and/or between the silicon carbide particle and metallic silicon, wherein an oxide phase containing oxides of silicon, aluminum, and alkaline earth metal is buried in at least some of fine pore portions having a minimum distance of 10 ?m or less between the surfaces of the silicon carbide particles or between the surfaces of the silicon carbide particle and metallic silicon among the pores, and a ratio of a total volume of portions in which the oxide phase is not buried among the fine pore portions is 20% or less with respect to a total volume of portions in which the oxide phase is not buried among the pores including the fine pore portions.
    Type: Grant
    Filed: November 19, 2003
    Date of Patent: July 17, 2007
    Assignee: NGK Insulators, Ltd.
    Inventors: Masahiro Furukawa, Nobuyuki Tanahashi, Kenji Morimoto, Shinji Kawasaki
  • Patent number: 7238308
    Abstract: A process form producing ceramic composites comprising metal carbides, which comprises the steps production of a porous carbon-containing intermediate body, infiltration of the intermediate body with the melt of a carbon-forming metal, reaction of at least part of the carbon of the intermediate body with the carbide-forming metal to form a metal carbide, with at least part of the carbide-formed metal being supplied via at least one wick made of porous carbon material having pore channels and the wick being produced by carbonization of wood materials or of essentially unidirectionally reinforced CFRP, such wicks and their use in the abovementioned process.
    Type: Grant
    Filed: March 14, 2003
    Date of Patent: July 3, 2007
    Assignee: Audi AG
    Inventor: Jens Rosenloecher
  • Patent number: 7214342
    Abstract: A method for manufacturing a silicon carbide composite body and includes the steps of forming a slurry including silicon carbide and a carbonaceous precursor, adding to the slurry composite granules containing a carbonaceous binder and carbon black, drying the slurry, shaping the dried slurry and sintering the dried and shaped slurry at a temperature of at least 2000° C. to form a body containing silicon carbide and non-graphitic carbon. The invention further relates to the composite body formed and the mixture prior to sintering.
    Type: Grant
    Filed: July 23, 2004
    Date of Patent: May 8, 2007
    Assignee: Schunk Ingenieurkeramik GmbH
    Inventors: Arthur Lynen, Rinn Guenter
  • Patent number: 7186360
    Abstract: Ceramic composite materials have unidirectional alignment of the reinforcing fibers. The ratio of the volume of the fiber strands of the reinforcing fibers to the volume of the matrix is at least 0.5. A process for their production involves initially coating the fiber strands or rovings of the reinforcing fibers with a sacrificial polymer. The coated fiber strands are processed with binder resins into unidirectionally reinforced CFK molded parts. The formed CFK bodies are carbonized to form CFC bodies. The CFC bodies are then silicized with liquid silicon. The liquid silicon diffuses into the pores formed in the CFC body and combines there at least partially with the carbon to form silicon carbide. The sacrificial polymer is pyrolized. The ceramic composite materials also can be used in fiber-reinforced ceramic structural parts.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: March 6, 2007
    Assignee: SGL Carbon AG
    Inventor: Bodo Benitsch
  • Patent number: 7169336
    Abstract: A method for preparing powder granules by a liquid condensation process comprising preparing a slurry by mixing powders, a binding agent and a binding agent soluble solvent, dropping the slurry to a binding agent insoluble solvent to fix the binding agent so that the binding agent can not be released to a surface of a droplet of the slurry, coagulating the droplet by solvent exchange between the soluble solvent inside the droplet and the insoluble solvent at the surface of the droplets, and separating the coagulated droplet from the insoluble solvent, drying it and completely removing a residual solvent.
    Type: Grant
    Filed: March 10, 2003
    Date of Patent: January 30, 2007
    Assignee: Korea Institute of Science and Technology
    Inventors: Hae-Weon Lee, Joo-Sun Kim, Jong-Ho Lee, Hue-Sup Song, Jang-Yong You, Dong-Seuk Lee, Jang-Won Heo, Hyun-Ick Shin
  • Patent number: 7150850
    Abstract: The present invention provides a sintered silicon carbide jig production method capable of simply increasing the purity of a sintered silicon carbide jig. A method of producing a sintered silicon carbide jig comprising a process in which a second sintered body is heated at a temperature rising rate of 3 to 5° C./min up to heating treatment temperature selected in the range of 2200 to 2300° C. under an argon atmosphere, kept at the same heating treatment temperature for 3 hours, and cooled at a temperature lowering rate of 2 to 3° C./min down to 1000° C.
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: December 19, 2006
    Assignee: Bridgestone Corporation
    Inventor: Fumio Odaka
  • Patent number: 7151066
    Abstract: A silicon nitride wear resistant member is composed of a ceramic sintered body containing 55 to 75 mass % of silicon nitride, 12 to 28 mass % of silicon carbide, 3 to 15 mass % of at least one element selected from the group consisting of Mo, W, Ta, and Nb in terms of silicide thereof, and 5 to 15 mass % of grain boundary phase composed of a rare earth element-Si—Al—O—N, the wear resistant member having an electrical resistance of 107 to 104 ?·cm, a porosity of 1% or less, and a three point bending strength of 900 MPa or more. The wear resistant member has a predetermined electric resistance (electro-conductivity) in addition to the high strength and toughness inherent in silicon nitride per se, especially has a high sliding characteristic. Also, a method of manufacturing the wear resistant member is provided.
    Type: Grant
    Filed: April 2, 2003
    Date of Patent: December 19, 2006
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Michiyasu Komatsu, Kimiya Miyashita
  • Patent number: 7128850
    Abstract: Composite materials containing silicon, titanium, carbon, and nitrogen, formed by spark plasma sintering of ceramic starting materials to a high relative density, demonstrate unusually high electrical conductivity as well as high-performance mechanical and chemical properties including hardness, fracture toughness, and corrosion resistance. This combination of electrical, mechanical, and chemical properties makes these composites useful as electrical conductors in applications where high-performance materials are needed due to exposure to extreme conditions such as high temperatures, mechanical stresses, and corrosive environments.
    Type: Grant
    Filed: June 2, 2003
    Date of Patent: October 31, 2006
    Assignee: The Regents of the University of California
    Inventors: Ren-Guan Duan, Joshua D. Kuntz, Amiya K. Mukherjee
  • Patent number: 7077991
    Abstract: Densified composites of silicon nitride, silicon carbide, and boron nitride that exhibit high creep resistance are obtained by sintering a mixture of amorphous powders of silicon nitride, silicon carbide, and boron nitride in the presence of an electric field under high pressure. The grain size in the resulting composite is less than 100 nanometers for all components of the composite, and the composite exhibits high creep resistance.
    Type: Grant
    Filed: February 6, 2004
    Date of Patent: July 18, 2006
    Assignee: The Regents of the University of California
    Inventors: Julin Wan, Amiya K. Mukherjee, Matthew J. Gasch
  • Patent number: 7067077
    Abstract: Carbon-silicon carbide brake preforms are manufactured by carbonizing a blend of carbon (e.g., polyacrylonitrile) fibers and thermosetting pitch resin, optionally along with a lubricant such as graphite,.to provide an intermediate product having open porosity and subsequently filling the pores of the intermediate product with silicon by a melt infiltration process. Molded articles that consist principally of carbon, that have relatively high strength and resistance to decomposition by frictional heat, and that are suitable for melt infiltration with silicon, are produced by, e.g.
    Type: Grant
    Filed: April 27, 2004
    Date of Patent: June 27, 2006
    Assignee: Honeywell International Inc.
    Inventor: Paul E. Gray
  • Patent number: 7056467
    Abstract: Disclosed herein is a method for producing a thin sheet of an Al—SiC composite material, which comprises the steps of: mixing aluminum powders and SiC powders to give spraying powders; and plasma-spraying the spraying powders on a graphite substrate to form a thin sheet. According to the method of the present invention, the composite material having low thermal expansion coefficient, high thermal conductivity and low density, which is suitable for use as a thermal management material for electronic devices, can be produced by a simple production process.
    Type: Grant
    Filed: September 2, 2003
    Date of Patent: June 6, 2006
    Inventors: Suk Bong Kang, Kwang Jun Euh, Manchang Gui
  • Patent number: 7029613
    Abstract: Densified composites of silicon nitride and silicon carbide that exhibit high creep resistance are obtained by mechanically activating a mixture of amorphous powders of silicon nitride and silicon carbide and sintering the mechanically activated mixture in the presence of an electric field under high pressure. The grain size in the resulting composite is less than 100 nanometers for all components of the composite, and the composite exhibits high creep resistance.
    Type: Grant
    Filed: September 8, 2003
    Date of Patent: April 18, 2006
    Assignee: The Regents of the University of California
    Inventors: Julin Wan, Matthew J. Gasch, Amiya K. Mukherjee
  • Patent number: 7029511
    Abstract: A honeycomb structure 1 has a large number of through-holes 3 divided by partition walls 2 and extending in the axial direction, characterized in that the honeycomb structure contains a Si phase having a lattice constant controlled at 0.54302 to 0.54311 nm at room temperature. A process for producing the honeycomb structure 1, includes a firing step of firing a precursor of honeycomb structure, wherein the precursor contains a Si phase and the firing step is conducted using a furnace material free from any boron-containing compound. A process for producing the honeycomb structure 1, includes a firing step of firing a precursor of honeycomb structure, wherein a reduction percentage of Si content in Si phase after firing step relative to Si content in Si phase before firing step is suppressed at 10% by mass or less. Having an improved thermal conductivity, the honeycomb structure is superior in thermal shock resistance.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: April 18, 2006
    Assignee: NGK Insulators, Ltd.
    Inventors: Shuichi Ichikawa, Takashi Harada, Aiko Otsuka, Yukihisa Wada, Yoshinori Yamamoto
  • Patent number: 7015165
    Abstract: The invention provides exemplary silicon carbide ceramic bodies and processes for making such ceramic bodies. In one embodiment, a raw batch for producing a ceramic body includes a silicon carbide slurry and agglomerates of particles defining a dry lubricant mixture. The mixture includes a binder and a dry lubricant such as graphite, with a majority of the agglomerates having a shape that is generally spherical.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: March 21, 2006
    Assignee: CoorsTek, Inc.
    Inventor: Eric G. Wilkins
  • Patent number: 6939506
    Abstract: Fully dense, diamond-silicon carbide composites are prepared from ball-milled microcrystalline diamond/amorphous silicon powder mixture. The ball-milled powder is sintered (P=5-8 GPa, T=1400K-2300K) to form composites having high fracture toughness. A composite made at 5 GPa/1673K had a measured fracture toughness of 12 MPa·m1/2. By contrast, liquid infiltration of silicon into diamond powder at 5 GPa/1673K produces a composite with higher hardness but lower fracture toughness. X-ray diffraction patterns and Raman spectra indicate that amorphous silicon is partially transformed into nanocrystalline silicon at 5 GPa/873K, and nanocrystalline silicon carbide forms at higher temperatures.
    Type: Grant
    Filed: May 30, 2003
    Date of Patent: September 6, 2005
    Assignee: The Regents of the University of California
    Inventors: Jiang Qian, Yusheng Zhao
  • Patent number: 6913716
    Abstract: Disclosed is a method for manufacturing composite granules having a homogeneous particle distribution, comprising powders of multimodal particle size distribution and phenol resins, and a method for manufacturing green bodies having homogeneous microstructure without particle separation from the granules.
    Type: Grant
    Filed: August 5, 2002
    Date of Patent: July 5, 2005
    Assignee: Korea Institute of Science and Technology
    Inventors: Hae-Weon Lee, Huesup Song, Jongho Lee, Joosun Kim, Hyunick Shin
  • Patent number: 6887421
    Abstract: A method for bonding an electrically conductive silicon carbide structure to an electrically conductive siliconized silicon carbide structure by temporarily securing the siliconized silicon carbide structure to the silicon carbide structure; placing the silicon carbide structure with secured siliconized silicon carbide structure into an induction heating furnace having an induction coil which heats electrically conductive material in the furnace when sufficient electrical power at a frequency of from about 300 to about 1000 KC is passed through the coil; and causing sufficient electrical power at a frequency of from about 300 to about 1000 KC to be passed through the coil to raise the temperature of the siliconized silicon carbide structure and silicon carbide structure to a temperature above about 1500° C.
    Type: Grant
    Filed: January 14, 2002
    Date of Patent: May 3, 2005
    Assignee: Redunndant Materials, Inc.
    Inventors: Michael P. Dunn, Brian M. Tierney
  • Publication number: 20040262821
    Abstract: A method of producing a sintered silicon carbide using a reaction sintering method, comprising: (1) dissolving and dispersing a silicon carbide powder in a solvent to produce a mixed powder slurry, (2) flowing the resulted mixed powder into a mold and drying it to obtain a green body, (3) temporarily sintering the green body in one of a vacuum atmosphere or inert gas atmosphere at 1200 to 1900° C. to obtain a temporarily sintered first body, (4) impregnating the resulted temporarily sintered first body with a phenol resin as a carbon source, (5) temporarily sintering the resulted carbon source-impregnated temporarily sintered first body in one of a vacuum atmosphere or inert gas atmosphere at 900 to 1400° C.
    Type: Application
    Filed: April 16, 2004
    Publication date: December 30, 2004
    Inventor: Fumio Odaka
  • Publication number: 20040238794
    Abstract: Metal-ceramic composite materials made by an infiltration technique have now been prepared using microwave energy as the heat source for thermal processing. Specifically, microwave energy has been used to heat and melt a source of silicon metal, which in turn has infiltrated carbon-containing preforms to make reaction-bonded silicon carbide composites, respectively. Both the time-at-temperature as well as the overall thermal cycle time have been greatly reduced, implying a large cost savings.
    Type: Application
    Filed: May 30, 2003
    Publication date: December 2, 2004
    Inventors: Prashant G. Karandikar, Michael K. Aghajanian, Luis Ortiz
  • Publication number: 20040242399
    Abstract: Fully dense, diamond-silicon carbide composites are prepared from ball-milled microcrystalline diamond/amorphous silicon powder mixture. The ball-milled powder is sintered (P=5-8 GPa, T=1400K-2300K) to form composites having high fracture toughness. A composite made at 5 GPa/1673K had a measured fracture toughness of 12 MPa·m1/2. By contrast, liquid infiltration of silicon into diamond powder at 5 GPa/1673K produces a composite with higher hardness but lower fracture toughness. X-ray diffraction patterns and Raman spectra indicate that amorphous silicon is partially transformed into nanocrystalline silicon at 5 GPa/873K, and nanocrystalline silicon carbide forms at higher temperatures.
    Type: Application
    Filed: May 30, 2003
    Publication date: December 2, 2004
    Inventors: Jiang Qian, Yusheng Zhao
  • Patent number: 6818085
    Abstract: A process for producing a fiber-reinforced, ceramic structural component comprising high-temperature resistant fibers which are reaction-bonded to a matrix of silicon carbide comprises the steps of coating bundles of fibers with pyrolysable binder and solidifying the binder, producing mixtures of fiber bundles, fillers and binders, pressing the mixtures to produce a pressed body, pyrolysing the pressed body under the exclusion of oxygen to form a porous, carbon-containing preform, infiltrating the preform with a silicon melt to form the silicon carbide matrix, in which various pressing compounds are produced, which contain fibers of different quality and in different proportions and different coatings. These pressing compounds are arranged at different levels and in different spatial directions in the press mould during the filling of the press mould. After the pressing, the regions produced in this way are retained in the press mould.
    Type: Grant
    Filed: May 30, 2002
    Date of Patent: November 16, 2004
    Assignee: DaimlerChrysler AG
    Inventors: Thomas Behr, Manfred Kurbjuhn, Robert Michal, Michael Niestegge, Karl-Ludwig Weisskopf
  • Patent number: 6805034
    Abstract: Silicon infiltration technology is used to produce ceramic bodies having utility as ballistic armor. In a first aspect of the invention, the ballistic armor includes a reaction-bonded silicon carbide body (RBSC). Good ballistic performance can be advanced by loading the permeable mass or preform to be infiltrated to a high degree with one or more hard fillers, and by limiting the size of the largest particles making up the mass. In a second aspect, the silicon infiltration technology, e.g., siliconizing or reaction-bonding, is used to bond silicon carbide fibers to at least the back surface of a ceramic armor body, thereby enhancing ballistic stopping power. A third aspect of the invention pertains to the ability to engineer RBSC bodies such that there is little dimensional change during processing, thereby permitting high dimensional reproducibility in large-scale production.
    Type: Grant
    Filed: November 1, 2002
    Date of Patent: October 19, 2004
    Assignee: M Cubed Technologies, Inc.
    Inventors: Allyn L. McCormick, Michael K. Aghajanian