Using Thermionic Emission Patents (Class 324/470)
  • Patent number: 8928329
    Abstract: A fast response output signal circuit (10) for a cold cathode gauge is provided to produce a fast response output signal (48) in addition to a voltage output signal (40) that is representative of the pressure in the cold cathode gauge. The fast response output signal (48) is either on or off, thus can be used to trigger a closing of an isolation valve or other responsive action upon a change in pressure that attains or exceeds a certain set point threshold. The fast response output signal is produced and processed with analog circuits, but the set point is produced with a microprocessor. The voltage output signal can be produced as a logarithmic function of the pressure.
    Type: Grant
    Filed: July 26, 2012
    Date of Patent: January 6, 2015
    Assignee: MKS Instruments, Inc.
    Inventors: Bert Downing, Donghua Gu, Neil T. Peacock
  • Publication number: 20140300369
    Abstract: An ion mobility gas detector apparatus including a detector core, an inlet gas path, an exhaust gas path, a source of diluent gas, and at least one or more sensors for measuring temperature, pressure and humidity of gas streams. Further included is a mixing mechanism adapted to mix at least first and second gas streams in response to one or more sensor measurements. A controller is provided for applying drive signals to the detector core.
    Type: Application
    Filed: November 15, 2012
    Publication date: October 9, 2014
    Applicant: Owlstone Limited
    Inventor: Matthew Hart
  • Patent number: 8686709
    Abstract: Apparatus and associate method including a substrate having a first surface; a lid having a second surface; at least one spacer element interposed between the substrate and the lid so as to maintain the first and second surface spaced apart; a partition with a plurality of nanometric size through-openings interposed between the spacer element and the lid defining a first chamber a second chamber fluidically connected together through at least one of the openings; the substrate has at least one first electrode on the first surface and the lid has a second electrode, the first electrode being configured to detect an electric signal associated to the passage of one of said particles through one of the through-openings.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: April 1, 2014
    Assignee: Silicon Biosystems S.p.A.
    Inventors: Marco Tartagni, Michele Rossi, Nicolò Manaresi
  • Patent number: 7609067
    Abstract: Embodiments of the present invention pertain to an electronic portion of a MEMs ion gauge with ion collectors bowed out of plane to form a three dimensional arrangement and a method for forming an electronic portion of a MEMs ion gauge with ion collectors bowed out of plane to form a three dimensional arrangement. In one embodiment, an ion gauge substrate is formed. The electronic portion of the MEMs ion gauge is assembled by coupling a plurality of ion collectors with the ion gauge substrate, wherein the coupling of the plurality of ion collectors with the ion gauge substrate further comprises performing an operation that causes the plurality of ion collectors to be bowed out of plane to form a three dimensional arrangement.
    Type: Grant
    Filed: November 9, 2005
    Date of Patent: October 27, 2009
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Chien-Hua Chen, James McKinnell
  • Publication number: 20030080749
    Abstract: A high-speed corrosion-resistant rotating cylinder electrode test apparatus for monitoring of corrosion rates of metals includes an electrochemical/permeation cell body adapted to contain a fluid whose corrosive effect is to be monitored, the cell body having a base at a lower surface thereof and the base having an aperture therethrough. A counter electrode/reference electrode complex is mounted within the cell. The system further includes a cylindrical working electrode and a rotatable system shaft having a lower portion below the base and extending therefrom through the aperture into the cell body, the working electrode being mounted on an upper portion of the system shaft to be positioned within the cell body for rotation. A cone-shaped cap formed from a corrosion-resistant polymeric material is positioned above the working electrode and extends upwardly a relatively short distance into the fluid to reduce vortex phenomena. A motor is connectable to the system shaft for rotating the system shaft.
    Type: Application
    Filed: October 30, 2001
    Publication date: May 1, 2003
    Inventors: Yahya T. Al-Janabi, Arnold L. Lewis
  • Patent number: 5739699
    Abstract: Electron capture detector for use with an effluent stream from a gas chromatograph includes an electron source means and an adjacent ionization chamber in which electron capture takes place. The active region of the ionization chamber is disposed to receive free electrons and a flow of purge gas. The detector has an inlet port for receiving a sample gas as well as an outlet port for exhausting the sample gas and the purge gas. A collector electrode in the detection chamber is biased so as to collect the free electrons in the absence of electrophilic substance. Electrophilic substances in the detector will reduce the flow of electrons to the collector and generate an ionic current. An insulative member in the form of a flow guide may be located at the portion of the anode so as to permit pulsing of free electrons to the anode but substantially block the ionic current, i.e., to discriminate between the free electrons and the ionic current.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: April 14, 1998
    Assignee: Hewlett-Packard Company
    Inventor: Mahmoud F. Abdel-Rahman
  • Patent number: 5703488
    Abstract: This instrument can measure parameters of a plasma accurately and easily even though the plasma is exited by a high-frequency. The instrument for measuring parameters of a plasma generated in a vacuum chamber by high-frequency discharge at a given frequency comprises a wire (106) for electrically connecting a first electrode (101) arranged in a space where a plasma is produced and a terminal (110) arranged outside the vacuum chamber for taking out signals, and a first insulator (105) so arranged as to cover at least a part of the surface of the wire therewith. The absolute value of the impedance at the given frequency between the first electrode and the ground when looking into the terminal side from the first electrode is five times or more the absolute value of the impedance at the given frequency between the first electrode and the plasma in a state where no direct current flows through the first electrode.
    Type: Grant
    Filed: July 5, 1995
    Date of Patent: December 30, 1997
    Assignee: Tadahiro Ohmi
    Inventors: Tadahiro Ohmi, Masaki Hirayama
  • Patent number: 5426056
    Abstract: A surface ionization detector for detecting organic molecules such as illicit drugs and non-organo-nitrate explosives includes a heated surface and a collector electrode. A sample containing trace amounts of the organic molecules in ambient air is directed over the heated surface maintained at a temperature in the range of 500.degree. C. to 800.degree. C., thereby causing the molecules to decompose into fragments. A polarization voltage between 18 V and 24 V is applied to ionize the fragments which are then collected by the collector electrode. An electrometer connected to the collector electrode measures the current and a change in the current indicates the presence of ionized fragments, and thereby indicates the presence of the organic molecules. The temperature of the heated surface and the polarization voltage are optimized for detection of particular organic molecules.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: June 20, 1995
    Inventor: Sabatino Nacson
  • Patent number: 5389224
    Abstract: A sensor for determining the stoichiometric air to fuel ratio (A/F) at the intake of an internal combustion engine is based on a capacitive device in the exhaust stream which can be used to measure the change in the workfunction of an appropriate material which occurs at the stoichiometric point and which forms one of the two interacting elements of the capacitor. To measure A/F over an extended range about stoichiometry the material whose workfunction changes is made the working electrode of an oxygen concentration cell using a solid electrolyte. Oxygen pumping to and from that surface can change the magnitude of the workfunction allowing for a feedback control method for keeping the workfunction constant despite changes in the A/F so that the required pump current becomes a measure of the A/F.
    Type: Grant
    Filed: July 1, 1993
    Date of Patent: February 14, 1995
    Assignee: Ford Motor Company
    Inventor: Robert E. Hetrick
  • Patent number: 5310474
    Abstract: A sensor for determining the stoichiometric air to fuel ratio (A/F) at the input to the cylinders of an internal combustion engine which is based on measuring the change in the workfunction of a material which occurs when the oxidizing and reducing species in the adjacent gas phase are at or near their stoichiometric ratio. In one method the sensor includes a material which is capable of thermionically emitting alkali metal or other appropriate ions into an exhaust gas atmosphere where they are subsequently collected by a nearby collector electrode and the magnitude of the emission current is measured. The interaction of the emitting surface with the gas phase reversibly changes the workfunction of the emitting surface from large to smaller values as that gas phase is varied through the stoichiometric ratio with respect to the amounts of the oxidizing and reducing species in the gas.
    Type: Grant
    Filed: July 13, 1992
    Date of Patent: May 10, 1994
    Assignee: Ford Motor Company
    Inventors: Robert E. Hetrick, Allen L. Schamp
  • Patent number: 5275712
    Abstract: A sensor determines a wide range of air-to-fuel ratio values (A/F) about the stoichiometric A/F in a gaseous mixture which has oxidizing and reducing species as might be found in an automotive exhaust. The sensor includes a surface that serves simultaneously as the working electrode of a solid-state oxygen concentration cell and as a surface whose workfunction changes from a higher to a lower value as the oxidizing and reducing species in the adjacent gas phase, and in interaction with the surface, pass from an excess oxidizing to the excess reducing condition about the stoichiometric ratio. In one embodiment, the surface exposed to the gas in question is the emitter electrode of a thermionic diode which emits positively charged alkali ions into the exhaust ambient where they are collected by a nearby collector electrode. Changes in the ratio of the oxidizing and reducing species about the stoichiometric ratio produce corresponding changes in the thermionic emission.
    Type: Grant
    Filed: July 14, 1992
    Date of Patent: January 4, 1994
    Assignee: Ford Motor Company
    Inventors: Robert E. Hetrick, Allen L. Schamp
  • Patent number: 5028544
    Abstract: The objects of the invention are attained in an apparatus for performing a method of analysis of organic compounds in chromatography, comprising a chromatographic column sealingly connected with the housing of a surface ionization detector having coaxially arranged inside, a collector and a thermoemitter with current leads, the housing of the surface ionization detector being provided with an opening for an auxiliary gas feed line and an opening for delivering the spent gases. The thermoemitter includes a closed-end sleeve with a heating element in contact with the external non-working surface of the thermoemitter. The collector includes a hollow cylinder spaced from the inner ionizing surface of the thermoemitter, and the outlet portion of the chromatographic column being received inside and throughout the length of the collector.
    Type: Grant
    Filed: October 14, 1988
    Date of Patent: July 2, 1991
    Inventors: Utkur K. Rasulev, Erkinzhan G. Nazarov, Valery O. Sidelnikov, Rustam N. Evtukhov, Shavkat S. Alimkhodzhaev, Bakhtiyar M. Tashpulatov, Gulsara B. Khudaeva
  • Patent number: 4902977
    Abstract: A gas ionization type vacuum gauge for testing the internal vacuum levels to below 10.sup.-6 torr is disclosed which uses a multipactor discharge means as the source for the electron current used to ionize residual gas molecules. The invention comprises an RF field enhancing cavity which can be constructed of high-vacuum-compatible materials, able to withstand bake-out microwave temperatures and a negatively biased ion collection wave, wire, or grid. A simple ceramic RF feed-through permits simple and noninvasive pressure measurements. The device can be made much smaller than conventional gauges.
    Type: Grant
    Filed: January 10, 1989
    Date of Patent: February 20, 1990
    Assignee: University of Utah
    Inventors: Michael B. Kenny, Larry R. Barnett, Richard W. Grow, J. Mark Baird
  • Patent number: 4839143
    Abstract: An ion mobility spectrometer, ionization detector and mass spectrometer is described having a reaction region, and means for introducing a sample gas, liquid or solid samples into the reaction region and an electrolyte in the reaction region of an alkali salt heated to a predetermined temperature, such as room temperature to 1000.degree. C., to provide a chemical reaction between the alkali atoms, cations or complement anions with the sample to provide product ions. The invention provides a non-radioactive ionization source and provides a means for ionization of a broad class of compounds.
    Type: Grant
    Filed: February 15, 1985
    Date of Patent: June 13, 1989
    Assignee: Allied-Signal Inc.
    Inventors: Kishore N. Vora, Donald N. Campbell, Robert C. Davis, Jr., Glenn E. Spangler, Julio A. Reategui
  • Patent number: 4689574
    Abstract: An apparatus is disclosed for analyzing trace elements in a gas sample. A unique feedback system is provided for accurately regulating and sensing the pressure supplied to the ion chamber of the device. The feedback system is capable of compensating for a wide range of input gas pressures. The apparatus also includes an improved closed ion source which is resistant to corrosion and aids in the reduction of noise. In addition, a method is disclosed to calibrate the detector for accurately scaling the measurements of trace elements.
    Type: Grant
    Filed: November 14, 1985
    Date of Patent: August 25, 1987
    Assignee: UTI Instrument Co.
    Inventors: Kuo-Chin Lin, Frederick P. Pickett
  • Patent number: 4508685
    Abstract: The invention relates to a modified-flame thermionic detector for gas chromatographs, of the type including a burner nozzle, an excitation electrode and a collecting electrode. The electrical connections of the nozzle and the excitation electrode can be changed at the operator's will, together with the spatial position of the excitation electrode with respect to the flame and the collector, to find out the presence of certain compounds, leaving all other conditions of analysis performance and detector supply unaltered. This allows obtaining chromatograms of unknown samples under different conditions of the detector configuration, to put into evidence the presence of certain compounds in the sample by comparing peaks of chromatograms obtained under said different operating conditions of the detector.
    Type: Grant
    Filed: May 26, 1982
    Date of Patent: April 2, 1985
    Assignee: Carlo Erba Strumentazione S.p.A.
    Inventors: Giorgio Sisti, Giuseppe Verga
  • Patent number: 4304997
    Abstract: An electron capture detector in which a thermionic source such as a filament provides electrons for the reaction in a source chamber having a port that connects to a detection chamber having a collector. Guard gas is introduced into the source chamber and sample gas into the detection chamber, and an exhaust port is provided in the detection chamber.
    Type: Grant
    Filed: February 27, 1979
    Date of Patent: December 8, 1981
    Assignee: Hewlett-Packard Company
    Inventors: James J. Sullivan, William P. Kruger, Douglass McManigill, Armand P. Neukermans
  • Patent number: 4264817
    Abstract: An electron capture detector in which electrons for the reaction are supplied by a filament in a cylinder through which guard gas is passed. Apertures in the cylinder permit electrons from the filament to pass into an annular space surrounding the cylinder and between it and a collector. Sample gas is passed between the aperture and the collector, the pressures being such as to be capable of minimizing the diffusion of sample gas to the filament.
    Type: Grant
    Filed: February 27, 1979
    Date of Patent: April 28, 1981
    Assignee: Hewlett-Packard Company
    Inventors: Armand P. Neukermans, Douglass McManigill