Niobium Base Patents (Class 420/425)
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Patent number: 6409848Abstract: A niobium-based silicide composite exhibiting creep resistance at temperatures equal to or greater than 1150° C. The niobium-based silicide composite comprises at least silicon (Si), hafnium (Hf), titanium (Ti), and niobium (Nb). A concentration ratio of Nb:(Hf+Ti) is equal to or greater than about 1.4. The niobium-based silicide composite exhibits a creep rate less than about 5×10−8s−1 at temperatures up to about 1200° C. and at a stress of about 200 MPa.Type: GrantFiled: August 24, 2000Date of Patent: June 25, 2002Assignee: General Electric CompanyInventors: Bernard Patrick Bewlay, Melvin Robert Jackson
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Publication number: 20020069724Abstract: A nitrogen containing niobium powder is disclosed as well as electrolytic capacitors formed from the niobium powders. Methods to reduce DC leakage in a niobium anode are also disclosed.Type: ApplicationFiled: December 7, 2001Publication date: June 13, 2002Inventor: James A. Fife
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Patent number: 6193856Abstract: A sputtering target comprising a substrate and a target material formed on the substrate, wherein the target material comprises a metal oxide of the chemical formula MOx as the main component, wherein MOx is a metal oxide which is deficient in oxygen as compared with the stoichiometric composition, and M is at least one metal selected from the group consisting of Ti, Nb, Ta, Mo, W, Zr and Hf, a process for its production, and a method for forming a film having a high refractive index.Type: GrantFiled: March 12, 1998Date of Patent: February 27, 2001Assignee: Asahi Glass Company Ltd.Inventors: Otojiro Kida, Akira Mitsui, Eri Suzuki, Hisashi Osaki, Atsushi Hayashi
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Patent number: 6165623Abstract: A flaked niobium powder is disclosed as well as electrolytic capacitors formed from the flaked niobium powders. Niobium powders having a BET surface area of at least about 0.50 m.sup.2 /g are also disclosed and capacitors made therefrom, as well as niobium powders doped with an oxygen content of at least 2,000 ppm. Methods to reduce DC leakage in a niobium anode are also disclosed.Type: GrantFiled: November 3, 1997Date of Patent: December 26, 2000Assignee: Cabot CorporationInventors: James A. Fife, Jane Jia Liu, Roger W. Steele
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Patent number: 6010584Abstract: The shape memory effect is displayed by near-equiatomic ruthenium alloys of Ta or Nb with compositions of Ta.sub.x Ru.sub.1-x where x can be as low as 0.38 and preferably x=0.44 to 0.63 and Nb.sub.x Ru.sub.1-x where x can be as low as 0.25 and preferably x=0.45 to 0.59 which exhibit a transition from the high-temperature cubic phase to a tetragonal phase. These alloys are prepared by melting together tantalum and ruthenium, or niobium and ruthenium, in the above mentioned ratios. A further embodiment of this invention is to alloy NiTi alloys with, one of these two ruthenium-based high-temperature alloys (i.e. either Ta--Ru or Nb--Ru) so as to obtain a similar behavior which will result in an increase in the transition temperature relative to unalloyed Ni--Ti.Type: GrantFiled: September 30, 1997Date of Patent: January 4, 2000Assignee: The United States of America as represented by the Secretary of the NavyInventors: Richard Fonda, Roy Vandermeer, Harry Jones
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Patent number: 5721061Abstract: Si-Fe-Cr base coating alloys that significantly promote the oxidation resistance of niobium-base alloys and intermetallic materials when deposited and reaction bonded to the niobium-base material. The coating alloys are deposited and then reaction bonded to a niobium-base material to yield an oxidation-resistant coating comprising an interaction layer containing at least one oxidation-resistant Si-Fe-Nb-Cr intermetallic phase.Type: GrantFiled: November 15, 1996Date of Patent: February 24, 1998Assignee: General Electric CompanyInventors: Melvin Robert Jackson, Ann Melinda Ritter
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Patent number: 5718777Abstract: An amorphous alloy which is resistant to hot corrosion in sulfidizing and oxidizing atmospheres at high temperatures, consisting of at least one element selected from the group of Al and Cr and at least one element selected from the refractory metals Mo, W, Nb, and Ta, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Fe, Co, Ni and Cu. The addition of Si further improves the alloy's oxidation resistance.Type: GrantFiled: July 23, 1996Date of Patent: February 17, 1998Assignees: Koji Hashimoto, YKK CorporationInventors: Koji Hashimoto, Hiroki Habazaki, Stanislaw Mrowec, Marek Danielewski
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Patent number: 5705205Abstract: A process for increasing the yield of natural vanilla flavor. Green vanilla pods are hydrated. The resulting hydrated pods are ground, forming a liquid phase and a solid phase. The resulting ground hydrated product of green vanilla pods is treated with an enzymatic system including at least one enzyme. The enzyme system possesses from about 10 to about 1000 units of beta-glucose activity per gram of green vanilla pods. The ground hydrated green vanilla pods and the enzymatic system are incubated at a temperature of from about 10.degree. C. to about 40.degree. C. for a period of between about 2 hours and about 30 hours sufficient to allow the release of the vanilla flavor. The liquid phase containing the vanilla flavor is separated from the solid phase.Type: GrantFiled: September 16, 1996Date of Patent: January 6, 1998Assignee: Pernod RichardInventor: Pascal Marc Brunerie
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Patent number: 5580431Abstract: A composite wire microelectrode for making electro-chemical measurements, and method of making same. The microelectrode includes an inner conductive sensing wire and an outer tube that is oxidized to form a dielectric, self-healing oxide layer around the sensing wire.Type: GrantFiled: July 20, 1995Date of Patent: December 3, 1996Assignee: Associated Universities, Inc.Inventors: Hugh S. Isaacs, Antonio J. Aldykiewicz, Jr.
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Patent number: 5522945Abstract: A method for making triniobium tin superconductor with improved critical current density is disclosed where an annealed niobium-base substrate is passed through a tin alloy bath containing tin, copper, and bismuth, to coat the substrate with tin and then annealing the coated substrate to form triniobium tin superconductor. A tin alloy bath containing up to twenty weight percent copper and up to one weight percent bismuth is disclosed.Type: GrantFiled: July 1, 1994Date of Patent: June 4, 1996Assignee: General Electric CompanyInventors: Melissa L. Murray, Mark G. Benz, Bruce A. Knudsen
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Patent number: 5482577Abstract: An amorphous alloy which is resistant to hot corrosion in sulfidizing and oxidizing atmospheres at high temperatures, consisting of at least one element selected from the group of Al and Cr and at least one element selected from refractory metals of Mo. W, Nb and Ta, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti, Zr, Fe, Co, Ni and Cu. The addition of Si further improves the alloy oxidation resistance.Type: GrantFiled: October 25, 1994Date of Patent: January 9, 1996Assignees: Koji Hashimoto, YKK CorporationInventors: Koji Hashimoto, Hiroki Habazaki, Stanislaw Mrowec, Marek Danielewski
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Patent number: 5460663Abstract: Amorphous alloys having an extremely high corrosion resistance comprise Cr and at least one element selected from Ta and Nb, as essential components, and are spontaneously passive owing to the formation of stable protective films, even in very corrosive environments such as poorly oxidizing concentrated hydrochloric acid. The amorphous alloy may further include one or more elements appropriately selected from other alloying elements of Al, Ti, Zr, Fe, Co, Ni, Cu, Mo and W. The amorphous alloys have advantageous properties, such as very high corrosion resistance, high corrosion resistance at elevated temperatures and high wear resistance, and, therefore are useful in chemical plants or other industrial and domestic applications.Type: GrantFiled: April 20, 1994Date of Patent: October 24, 1995Assignee: YKK CorporationInventors: Koji Hashimoto, Jinhan Kim, Hideaki Yoshioka, Hiroki Habazaki, Asahi Kawashima, Katsuhiko Asami
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Patent number: 5423680Abstract: A dental alloy is provided which is free of palladium, gallium and copper and which is compatible with a wide variety of composites and porcelain compositions. The alloy has a melting range of between about 870.degree. C. and 1230.degree. C. and a coefficient of thermal expansion of between 15.5.times.10.sup.-6 and 17.5.times.10.sup.-6 in/in/.degree. C. when heated from room temperature to 500.degree. C. The alloy contains between about 40 and 80 percent by weight gold, between 5 and 50 percent by weight of thermal expansion adjuster, between two and 15 percent by weight strengthener and oxide former, up to about 1.5 percent by weight grain refiner, and up to about 0.25 percent by weight deoxidizer.Type: GrantFiled: November 10, 1993Date of Patent: June 13, 1995Assignee: Jeneric/Pentron, IncorporatedInventor: Arun Prasad
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Patent number: 5411611Abstract: A method for forming a wrought product from a starting metal such as tantalum, niobium, and alloys thereof. A consumable electrode is coated with at least a first alloy layer by means which provide for uniform thickness. Sufficient power is applied to the electrode body to induce arcing to cause the starting metal and alloy layers to melt and pool in a crucible. The uniform layer on the electrode body provides a means for delivering minute quantities of alloy into a larger quantity of starting metal and facilitates a uniform and consistent arc which promotes mixing of the alloy and starting material in the crucible. The electrode body is consumed at an improved rate without an associated decrease in the final ingot yield weight. The pooled metal is allowed to solidify into an ingot. The ingot is then formed into a wrought product.Type: GrantFiled: August 5, 1993Date of Patent: May 2, 1995Assignee: Cabot CorporationInventors: Prabhat Kumar, Louis Huber, Robert Engleman, Charles Heatley
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Patent number: 5380375Abstract: An amorphous alloy which is resistant to hot corrosion in sulfidizing and oxidizing atmospheres at high temperatures, consisting of Cr and at least one element selected from refractory metals of Nb and Ta, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti, Zr, Fe, Co, Ni and Cu. The addition of Si further improves the alloy's oxidation resistance.Type: GrantFiled: November 24, 1993Date of Patent: January 10, 1995Assignees: Koji Hashimoto, Yoshida Kogyo K.K.Inventors: Koji Hashimoto, Hiroki Habazaki, Stanislaw Mrowec, Marek Danielewski
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Patent number: 5368813Abstract: Oxidation and sulfidation resistant alloys and mixtures including chromium and niobium as well as oxidation and sulfidation resistant articles including chromium and niobium present as either an alloy or a mixture are provided. A method for preparing an oxidation and sulfidation resistant article by preparing a material including chromium and niobium and either forming an article directly from the chromium and niobium containing material or forming the article from a base material and coating the material with a coating including a chromium and niobium-containing material is provided.Type: GrantFiled: May 24, 1993Date of Patent: November 29, 1994Assignee: Massachusetts Institute of Technology, a MA Corp.Inventors: Linn W. Hobbs, Chuxin Zhou, Julia C. Duncan
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Patent number: 5284531Abstract: A method of making a tantalum capacitor of improved specific capacitance (and volumetric efficiency) is described. Short tantalum fibers are precipitated out of a carrier liquid to form a felt, or tumbled to form fiber containing particles, and in either case subsequently bonded so as to form a felt or particles containing the fibers in random orientation in substantially non-aligned array. These particles or felt are heated to bond the fibers together, purify and (optionally) cylindricalize them. The felt or particles can be processed in conventional fashion thereafter to form the capacitor. Cylindricalized fibers and pellets of increased surface area are also described.Type: GrantFiled: March 10, 1993Date of Patent: February 8, 1994Assignee: Cabot CorporationInventor: James A. Fife
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Patent number: 5171379Abstract: A wrought metal alloy product having a tantalum or niobium base metal, 10 to 1000 ppm silicon, and 10 to 10000 ppm yttrium nitride. Fine uniform grain size contributes to improved ductility.Type: GrantFiled: May 15, 1991Date of Patent: December 15, 1992Assignee: Cabot CorporationInventors: Prabhat Kumar, Charles E. Mosheim
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Patent number: 5049355Abstract: Process for producing a ductile, high strength, oxide dispersion hardened sintered alloy based on a metal having a high melting point. In the past, oxide dispersion has played only a minor role in comparison with other known processes for increasing strength. The process disclosed permits cost effective production of metallic materials which possess a strength hitherto unattainable by oxide dispersion and a higher ductility than prior art materials. As a result, the metallic and nonmetallic foreign components in the sintered alloy can be restricted to the relatively small quantities of dispersoids and any dissolved residual oxygen. The process consists in an annealing treatment and calls for a specific choice of basis metal and suitable oxide dispersoid.Type: GrantFiled: January 8, 1990Date of Patent: September 17, 1991Assignee: Schwarzkopf Development CorporationInventors: Udo Gennari, Wolfgang Glatzle
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Patent number: 5030300Abstract: An amorphous aluminum-refractory metal alloy with special characteristics such as high corrosion resistance, high wear resistance and considerable toughness, consisting of Al and at least one element selected from refractory metals of Ta, Nb, Mo and W, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti and Zr.Type: GrantFiled: December 21, 1989Date of Patent: July 9, 1991Assignees: Yoshida Kogyo K.K., Koji HashimotoInventors: Koji Hashimoto, Hideaki Yoshioka, Katsuhiko Asami, Asahi Kawashima
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Patent number: 5028390Abstract: A superalloy composition comprising niobium, an element selected from the group consisting of rhenium and technetium, and, optionally, an element selected from the lanthanide and actinide series, scandium, yttrium and lanthanum.Type: GrantFiled: July 27, 1989Date of Patent: July 2, 1991Inventor: Stuart L. Adelman
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Patent number: 5026522Abstract: An alloy is provided which has good operating strength and ductility at temperatures of 2000.degree. to 2500.degree. F. and density of between 7.0 and 7.3. The alloy contains niobium titanium and hafnium in concentrations as set forth below:______________________________________ Concentration in Atom % Ingredient From To ______________________________________ Niobium balance essentially Titanium 35 45 Hafnium 10 15.Type: GrantFiled: December 22, 1988Date of Patent: June 25, 1991Assignee: General Electric CompanyInventors: Melvin R. Jackson, Shyh-Chin Huang
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Patent number: 5006307Abstract: An alloy having high strength at high temperature is provided. The alloy has the following approximate composition in atom percent:______________________________________ niobium balance titanium 40-48% aluminum 12-22% hafnium 0.Type: GrantFiled: December 5, 1988Date of Patent: April 9, 1991Assignee: General Electric CompanyInventor: Melvin R. Jackson
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Patent number: 5000913Abstract: An alloy is provided having exceptional strength at very high temperatures of 1200.degree. C. and higher.Type: GrantFiled: December 5, 1988Date of Patent: March 19, 1991Assignee: General Electric CompanyInventor: Melvin R. Jackson
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Patent number: 4990308Abstract: An alloy having a niobium titanium base and aluminum and chromium additives is provided. The alloy has superior strength and ductility at high temperatures.Type: GrantFiled: December 5, 1988Date of Patent: February 5, 1991Assignee: General Electric CompanyInventor: Melvin R. Jackson
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Patent number: 4983358Abstract: A niobium-aluminum base alloy having improved oxidation resistance at high temperatures and consisting essentially of 48%-52% niobium, 36%-42% aluminum, 4%-10% chromium, 0%-2%, more preferably 1%-2%, silicon and/or tungsten with tungsten being preferred, and 0.1%-2.0% of a rare earth selected from the group consisting of yttrium, ytterbium and erbium. Parabolic oxidation rates, k.sub.p, at 1200.degree. C. range from about 0.006 to 0.032 (mg/cm.sup.2).sup.2 /hr. The new alloys also exhibit excellent cyclic oxidation resistance.Type: GrantFiled: September 13, 1989Date of Patent: January 8, 1991Assignee: Sverdrup Technology, Inc.Inventors: Mohan G. Hebsur, Joseph R. Stephens
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Patent number: 4980244Abstract: Alloy compositions suitable for use in protecting refractory base alloy compositions are disclosed. The coating is formed of an alloy containing chromium, ruthenium and aluminum and which may contain iron, cobalt and nickel. The coating is found to be highly resistant to oxidation.Type: GrantFiled: April 24, 1989Date of Patent: December 25, 1990Assignee: General Electric CompanyInventor: Melvin R. Jackson
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Patent number: 4954169Abstract: Earth acid metal powders, such as tantalum or niobium, useful in the production of electrolytic capacitors and other electronic components, are agglomerates of sintered compacts, wherein the mean grain size of the agglomerates is no more than 2.0 .mu.m, determined by the Fisher Sub-Sieve Sizer, and wherein the agglomerates consist of primary individual agglomerated particles of mean grain size of no more than 0.7 .mu.m.Type: GrantFiled: June 12, 1989Date of Patent: September 4, 1990Assignee: Bayer AktiengesellschaftInventor: Dieter Behrens
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Patent number: 4880482Abstract: A highly corrosion-resistant amorphous Cu alloys with at least one element selected from the group of Ta and Nb and other Cu-Ta alloys with at least one element selected from the group of Nb, Ti and Zr, wherein the total content of alloying elements other than Cu ranges from 15 to 85 at %.Type: GrantFiled: April 19, 1988Date of Patent: November 14, 1989Assignees: Mitsui Engineering & Shipbuilding Co., Ltd., Koji HashimotoInventors: Koji Hashimoto, Kimikado Miura, Katsuhiko Asami, Asahi Kawashima
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Patent number: 4854980Abstract: A nickel-based glassy alloy composition including Mo and one or more of Nb, Ta, and Zr, exhibiting high hardness and high crystallization temperatures.Type: GrantFiled: December 17, 1987Date of Patent: August 8, 1989Assignee: GTE Laboratories IncorporatedInventors: Ramaswamy V. Raman, Shih C. Hsu
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Patent number: 4623408Abstract: Nitrogen-containing amorphous alloys having a combination of superior properties which are highly valuable and desirable for ferromagnetic materials or superconducting materials are produced by sputtering metallic materials and nitrogen compounds containing semi-metal or semiconducting metal, such as boron or silicon, without requiring the use of nitrogen gas. The produced alloy has a novel structure, represented by the formula:MxLyNz(wherein M is at least one metal or alloy; L is at least one semimetal or semiconducting element; and x, y and z are fractional atomic percentages totaling 100 (i.e., x+y+z=100) and the value of y+z being 10 or more and the respective values of x, y, z being not zero).Type: GrantFiled: January 16, 1985Date of Patent: November 18, 1986Assignees: Hideaki Karamon, Research Development Corporation of JapanInventors: Hideaki Karamon, Keiichi Ogawa
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Patent number: 4623402Abstract: The metal composition and the process for producing same relate to the art of alloy metallurgy.The metal composition based on metals of VIII Group and nitrides of metals of III-VII Groups is characterized in that at least one alloy containing at least one metal of VIII Group and at least one metal of III-VII Groups are disintegrated to powder, placed into a nitrogen-containing atmosphere with an excess of nitrogen, burning is initiated by way of a local ignition of the mixture at any point thereof and the excess of nitrogen is maintained till completion of the reaction.The metal composition and process for producing same according to the present invention are useful in the manufacture of hard alloys based on refractory or high-melting compounds.Type: GrantFiled: December 21, 1983Date of Patent: November 18, 1986Assignees: Nauchno-Issledovatelsky Institut Prikladnoi Matematiki Pri Tomskom Gosudarstvennov Universitete, Institut Khimicheskoi Fiziki Akademii Nauk SSSRInventors: Jury M. Maximov, Mansur K. Ziatdinov, Anatoly D. Kolmakov, Larisa G. Raskolenko, Alexandr G. Merzhanov, Inna P. Borovinskaya, Fedor I. Dubovitsky
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Patent number: 4594104Abstract: The present invention provides a method for producing a consolidated article composed of a transition metal alloy. The method includes the step of selecting a rapidly solidified alloy which is at least about 50% glassy. The alloy is formed into a plurality of alloy bodies, and these alloy bodies are compacted at a pressing temperature of not more than about 0.6 Ts (solidus temperature in .degree.C.) to consolidate and bond the alloy bodies together into a glassy metal compact having a density of at least about 90% T.D. (theoretical density). The compacted glassy alloy bodies are then heat treated at a temperature generally ranging from about 0.55-0.85 Ts, but, in any case, above the alloy crystallization temperature, for a time sufficient to produce a fine grain crystalline alloy structure in the compacted article.Type: GrantFiled: April 26, 1985Date of Patent: June 10, 1986Assignee: Allied CorporationInventor: Derek Reybould
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Patent number: 4465511Abstract: NbSn.sub.2 is made by passing NbCl.sub.5 volatilized in an argon stream at 550.degree. C. to liquid tin. The product precipitates as a solid, while the tin chloride by product is carried away by the argon. Nb.sub.6 Sn.sub.5 is made from this NbSn.sub.2 by reacting it with more niobium halide vapor. NbSn.sub.2 or Nb.sub.6 Sn.sub.5 are useful intermediates in making the Al5-structure superconductor Nb.sub.3 Sn.Type: GrantFiled: November 15, 1983Date of Patent: August 14, 1984Assignee: National Research Development CorporationInventors: Frank R. Sale, Huseyin Yorucu